JP2010228815A - Biaxially drawn blow molded bottle - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a biaxially drawn blow molded bottle having a bottom prevented from being deformed and sagged and from being unstable under the gravity and heat from a content even when the bottle is heated with a hot warmer or the like. <P>SOLUTION: The biaxially drawn blow molded bottle 1 has a recess 6 formed of a tapered peripheral wall 4 sloping toward the bottle interior of a bottom 3 and a top wall 5 continuous to the upper end of the peripheral wall. The tapered peripheral wall 4 is formed of a first peripheral wall 4b on the ground contact surface 17 side of a truncated conical cylindrical shape and a second peripheral wall 4a on the top wall 5 side which are continuous to each other and has a first bottom wall 3a and a second bottom wall 3c continuous to each other from the ground contact surface 17 to a barrel part 2 while the angles in the cross-section of the peripheral wall surface are different from each other. The first bottom wall 3a is an annular tapered bottom wall, and the second bottom wall 3c is an annular curved bottom wall. A plug part 91 is not whitened. The distance from the ground contact surface 17 of the recess 6 to the top wall 5 is 25-40% of the barrel diameter, and the annular ground contact diameter of the lower end of the recess 6 is 50-75% of the barrel diameter. <P>COPYRIGHT: (C)2011,JPO&INPIT

Description

  The present invention relates to a biaxially stretched blow molded soot using a polyethylene terephthalate resin or the like, and more particularly to a biaxially stretched blow molded soot having a bottom structure capable of withstanding heating by a hot warmer or the like.

  In general, a beverage is filled in a plastic container, heated by a hot warmer device or the like, and provided to consumers.

Japanese Patent Application Laid-Open No. 08-104313

  (Prior Art) Conventionally, in a biaxially stretched blow-molded cage made of polyethylene terephthalate, FIG. 13 shows a cross-sectional view of the bottom of the conventional biaxially-stretched blow molded cage, and FIG. As shown in the bottom view, the central portion of the bottom portion is recessed into the heel through the peripheral wall 22 to give the heel self-supporting property. However, since the biaxially stretched blow-molded mold tends to be insufficiently stretched as compared with the side wall 24 of the bowl, when the liquid content is heated to a high temperature, it is affected by the gravity and heat from the contents. As it reaches the ground contact surface of the heel, it hangs down and the sitting position of the heel tends to worsen (see Patent Document 1).

  In a hot warmer device, a metal bowl containing a beverage heated to about 65 ° C. and a plastic bowl containing a beverage heated to about 55 ° C. are generally housed together and heated. The hot warmer device is operated so that the temperature of the heating plate is set to 100 to 120 ° C. and the heating plate is turned off when the ambient temperature reaches a predetermined temperature. When the product is sold and an additional product is put into the hot warmer device, the heating plate is turned on, and the temperature of the contents rises to about 70 to 75 ° C. For this reason, the plastic soot may be heated to 75 ° C. exceeding the glass transition point Tg = 67 ° C. of the polyethylene terephthalate resin.

  The object of the present invention is to fill a beverage in a plastic container, heat it with a hot warmer device, etc., and provide it to the consumer, and the bottom part droops under the influence of gravity and heat from the heated contents. It is to provide a biaxially-stretched blow-molded cage that does not deteriorate sitting.

  The present invention according to claim 1 solves the above-described problem, and is a biaxially-stretched blow-molded cage used for a warming container having a body diameter of 55 to 70 mm comprising a plug part, a body part, and a bottom part. The bottom of the tapered peripheral wall is provided with a recessed portion that is recessed toward the interior of the ridge comprising a tapered peripheral wall inclined toward the interior of the ridge and a top wall connected to the upper end thereof. The tapered peripheral wall has a truncated conical cylinder-shaped first peripheral wall on the grounded surface side and a second peripheral wall on the top wall side that are connected to each other, and the first peripheral wall and the second peripheral wall The angle with respect to the ground plane in the peripheral wall sectional view is different from each other, the distance from the ground plane to the top wall is 25 to 40% of the trunk diameter of the trunk portion, and the diameter of the ground plane is It is 50 to 75% of the trunk diameter, and it is A first bottom wall and a second bottom wall connected to each other toward the body portion, the first bottom wall being an annular tapered bottom wall, and the second bottom wall being a longitudinal section of the biaxially stretched blow-molded bowl An annular curved bottom wall that curves toward the outside of the shape, the trunk portion having a lateral rib for increasing the side wall strength below, and the top wall of the depression is located above the lateral rib. The plug portion of the biaxially stretched blow-molded jar is not whitened, the biaxially stretched blow-molded jar is made of polyethylene terephthalate resin, and a beverage is filled into the biaxially stretched blow-molded jar, When the temperature is kept at 75 ° C. to 80 ° C. exceeding the glass transition point of the polyethylene terephthalate resin by a hot warmer device, the depressed portion of the bottom part hangs down and the sitting of the biaxially stretched blow molded bag is poor. Of becoming And gist biaxial stretch blow molding bottles, characterized that no.

  The biaxially-stretched blow-molded scissors 1 of the present invention of claim 1 are affected by gravity and heat from the heated contents in the hot warmer device for a long time, and the depressions hang down downward. It has the advantage that it does not worsen sitting.

[BRIEF DESCRIPTION OF THE DRAWINGS] It is a side view of the biaxially-stretched blow molding cage | basket which shows one Example of this invention. [BRIEF DESCRIPTION OF THE DRAWINGS] It is a bottom view of the biaxial extending | stretching blow-molding cage | basket which shows one Example of this invention. It is sectional drawing of the bottom part in the biaxial extending | stretching blow-molding cage | basket which shows one Example of this invention. [BRIEF DESCRIPTION OF THE DRAWINGS] It is a perspective view of the biaxial extending | stretching blow molding cage | basket which shows one Example of this invention. It is sectional drawing of the bottom part principal part in the biaxially-stretched blow molding cage | basket which shows one Example of this invention, and is explanatory drawing explaining the effect which prevents the drooping part of a bottom part even if the internal pressure raises by heating. It is sectional drawing which shows the state which inserted the parison in the blow molding die in the shaping | molding process of the biaxially-stretched blow molding cage | basket of this invention. It is sectional drawing which shows the manufacturing process of the parison of the biaxially-stretched blow molding cage | basket of this invention. It is sectional drawing which shows the state hold | gripped with the mouth part type | mold of the parison shape | molded in FIG. It is principal part sectional drawing which shows the process of crystallizing the inner side of the opening part of the parison of FIG. FIG. 10 is a cross-sectional view of a principal part showing a process of crystallizing the outside of the mouth portion of the parison of FIG. 9. FIG. 10 is an enlarged cross-sectional view of the main part of the mouth part of the bag that has been blown and molded after the mouth part is crystallized in FIGS. It is a graph showing the elapsed time of the heating with respect to the biaxial stretching blow-molding cage | basket | rod vs. gate part depth change rate. It is sectional drawing of the bottom part in the conventional biaxial stretching blower. FIG. 14 is a bottom view of the biaxially stretched blow-molded cage shown in FIG. 13.

  Hereinafter, embodiments of the present invention will be described in detail with reference to the drawings.

  The biaxially stretched blow-molded jar according to the present invention can be formed as a heating container having a body diameter of 55 to 70 mm. In the biaxially stretched blow molded cage 1 according to the present invention of claim 1, as shown in FIGS. 1 to 4, a tapered peripheral wall 4 inclined toward the interior of the bowl at the center of the bottom 3 and a ceiling connected to the upper end thereof. A recessed portion 6 that is recessed toward the inside of the ridge formed by the wall 5, and has an annular grounding surface 17 at the lower end of the tapered peripheral wall 4, and the tapered peripheral wall 4 has a truncated conical cylindrical shape connected to each other. The first peripheral wall 4b on the ground contact surface 17 side and the second peripheral wall 4a on the ceiling wall 5 side are formed, and the angles of the first peripheral wall 4b and the second peripheral wall 4a with respect to the ground contact surface in the peripheral wall cross-sectional views are different from each other. The first bottom wall 3a and the second bottom wall 3c are connected to each other from the ground contact surface 17 toward the body portion 2, and the first bottom wall 3a is an annular tapered bottom wall, 2 bottom wall 3c is outside the longitudinal cross-sectional shape of the biaxially stretched blow-molded cage 1 A selfish curved annular curved bottom wall. In the case of the conventional product, the distance from the ground contact surface 17 of the biaxially stretched blow-molded bowl 1 of the depressed portion 6 to the top wall 5 is 23% or less of the trunk diameter (for example, 15 mm with respect to the trunk diameter of 66 mm). On the other hand, it is formed as high as 25 to 40% of the trunk diameter, and the annular grounding diameter at the lower end of the depression 6 is set to 50 to 75% of the trunk diameter, and the mountain shape of the depression 6 is suddenly changed. As a result, the liquid contents are heated to a high temperature, and the depressions are prevented from drooping downward due to the influence of gravity and heat from the contents, and the sitting of the heel is prevented, and the liquid content is 75 ° C. to 80 ° C. It can withstand long-term heat retention under temperature, and the depressed part of the bottom part hangs down during heat preservation by hot warmer equipment, so that the sitting of the heel does not worsen, and it is used as a heating container with a body diameter of 55 to 70 mm. be able to.

Further, in the biaxially stretched blow-molded rod 1, an inflection point 3d is provided between a first bottom wall 3a that is an annular tapered bottom wall of the bottom portion 3 and a second bottom wall 3c that is a curved bottom wall on the outside thereof.
Due to the presence of such an inflection point 3d, the clogged portion 6 of the bottom portion 3 can be pushed up and capped after filling the content, and then the content can be sealed and packaged in a reduced pressure state by removing the bottom pushing force. . As a result, even if the internal pressure rises due to heating by the hot warmer device, the internal pressure rise starts from the reduced pressure state, so that the gate portion at the center of the bottom portion 3 is less protruded, and the sagging portion 6 of the bottom portion 3 of the present invention is prevented from sagging. The effect to do can be further enhanced.

  FIG. 1 is a side view of a biaxially stretched blow-molded rod 1 showing one embodiment of the present invention. FIG. 2 is a bottom view of the biaxially stretched blow-molded rod 1 showing one embodiment of the present invention. FIG. 3 is a cross-sectional view of the bottom portion of the biaxially stretched blow-molded punch 1 showing one embodiment of the present invention. FIG. 4 is a perspective view of a biaxially stretched blow-molded rod 1 showing one embodiment of the present invention.

As shown in FIGS. 1 to 4, the biaxially stretched blow molded cage 1 of the present invention is made of polyethylene terephthalate resin and is used for a small cage (capacity 240 ml to 360 ml) having a body diameter of 55 to 70 mm, preferably 60 to 70 mm. . The biaxially stretched blow-molded ridge 1 includes a depressed portion 6 that is depressed toward the inside of the ridge, which includes a tapered peripheral wall 4 that is inclined toward the inside of the ridge and a top wall 5 that is connected to the upper end thereof. A gate portion (not shown) exists in the center of the top wall portion 5. An annular grounding surface 17 is provided at the lower end of the tapered peripheral wall 4, and the tapered peripheral wall 4 includes a first peripheral wall 4 b on the grounded surface 17 side and a second peripheral wall 4 a on the top wall 5 side connected to each other. Further, the angles of the first peripheral wall 4b and the second peripheral wall 4a with respect to the ground contact surface 17 in the peripheral wall cross-sectional views are different from each other. Reference numeral 2 denotes the body of the heel. A first bottom wall 3a and a second bottom wall 3c connected to each other from the ground contact surface 17 toward the body portion 2 are provided. The first bottom wall 3a is an annular tapered bottom wall, and the second bottom wall 3c is biaxially extended. It is set as the cyclic | annular curved bottom wall curved toward the outer side of the longitudinal cross-sectional shape of the blow molding cage | basket 1. As shown in FIG.
The distance from the ground plane 17 to the top wall 5 is 25 to 40% of the trunk diameter of the trunk section 2, and the diameter of the ground plane 17 is 50 to 75% of the trunk diameter of the trunk section 2. Further, the body portion 2 is provided with a lateral rib 11 for increasing the side wall strength below, and the top wall 5 of the depressed portion 6 is positioned above the lateral rib 11. In this way, when the beverage is filled in the biaxially stretched blow molded basket 1 and kept at a temperature of 75 ° C. to 80 ° C. exceeding the glass transition point of the polyethylene terephthalate resin by a hot warmer device when provided to the consumer In addition, the depressed portion 6 of the bottom 3 does not hang down and the sitting of the biaxially stretched blow-molded rod 1 does not deteriorate.

  If the distance H is less than 25% of the body diameter, the depression will hang down under the influence of gravity and heat from the heated contents until the depression reaches the ground contact surface, and the saddle will not sit well. On the other hand, if the distance H exceeds 40% of the body diameter, the stability of the moldability is deteriorated and the shape of the bottom 3 is difficult to be obtained, which is not preferable.

  The tapered peripheral wall 4 has an annular grounding surface 17 at the lower end of the tapered peripheral wall 4 and is inclined with respect to the grounding surface of the ridge standing from the grounding surface 17 through the transition region 3b from about 3 mm from the grounding surface. The tapered peripheral wall 4 includes a first peripheral wall 4b on the grounding surface 17 side and a second peripheral wall 4a on the top wall 5 side that are connected to each other, and the circumference of the first peripheral wall 4b and the second peripheral wall 4a. In the wall cross-sectional view, the angles with respect to the ground contact surface are different from each other, and the inclination angle of the first peripheral wall 4b and the second peripheral wall 4a is suitably 45 ° to 70 °.

  Moreover, it is not preferable that the ground contact diameter R is smaller than 50% of the trunk diameter because the heel tends to fall on a heating plate with an inclination such as a hot warmer. On the other hand, when the ground contact diameter R is larger than 75% of the body diameter, it is easy to hang down until the depressed portion reaches the ground contact surface due to the influence of gravity and heat from the heated contents.

  As a characteristic of the biaxially stretched blow-molded bowl 1, a ceiling wall 5 having a small diameter is supported by a tapered peripheral wall 4, and the ceiling wall 5 is positioned above the lateral rib 11 provided below the body side wall for increasing the strength. Let On the other hand, in the conventional container, the portion corresponding to the top wall 5 is located at a height equal to or lower than the lateral ribs 11. Moreover, since the recessed part 6 of the bottom part 3 was made into the high and simple shape in this way, the extending | stretching rate of the part from the top wall 5 to the bottom part 3 can be raised, and this led to the heat-resistant improvement of a bag. Conceivable.

The biaxially stretched blow-molded ridge 1 has a depressed portion 6 that is depressed toward the inside of the ridge, which includes a tapered peripheral wall 4 that is inclined toward the inside of the ridge and a top wall 5 that is connected to the upper end thereof. The tapered peripheral wall 4 has an annular grounding surface 17 at the lower end thereof, and the tapered circumferential wall 4 is connected to each other in a truncated conical cylindrical grounding surface 17 side first peripheral wall 4b and top wall 5 side second peripheral wall. 4a, and the angles of the first peripheral wall 4b and the second peripheral wall 4a with respect to the ground plane in the peripheral wall cross-sectional views are different from each other.
And the distance H from the ground-contacting surface 17 of the biaxially-stretched blow molding basket 1 of the depression part 6 to the top wall 5 shall be 25-40% of a trunk | drum diameter, Preferably it is 25-35%. An annular ground contact diameter R at the lower end of the depressed portion 6 is 50 to 75%, preferably 55 to 70% of the trunk diameter. Not only is the mechanical strength of the bottom 3 secured by the tapered peripheral wall 4, but the distance H from the ground contact surface 17 to the top wall 5 of the biaxially stretched blow-molded bowl 1 of the depression 6 is 23 of the conventional body diameter. %, The liquid content is heated to a high temperature, and the depression 6 hangs down under the influence of gravity and heat from the content to prevent the sitting of the heel from being worsened. It can withstand long-time heat retention at a temperature of 80 ° C., and the depressed portion 6 of the bottom portion 3 hangs down, so that the sitting of the heel does not worsen, and can be used as a hot warmer heating container.

  In addition, according to FIG. 5, a sectional view of the main part of the bottom 3 in the biaxially stretched blow-molded scissors 1 of the present invention will explain the effect of preventing the bottom part from sagging even if the internal pressure rises due to heating. It is desirable to provide an inflection point 3d between the first bottom wall 3a which is an annular tapered bottom wall of the bottom portion 3 and the second bottom wall 3c which is a curved bottom wall on the outside thereof. Due to the presence of such an inflection point 3d, after filling the contents, a force is applied to the bottom portion 3 to push the bottom portion 3 toward the ground plane 17, and the bottom portion 3 is deformed into the shape indicated by the alternate long and short dash line 18. The contents can be sealed and packaged in a reduced pressure state by removing the force that pushes the bottom 3 after capping in a state where the depression 6 is pushed up. As a result, even if the internal pressure rises due to heating by the hot warmer device, the internal pressure rise starts from the reduced pressure state, so that the gate portion at the center of the bottom portion 3 is less protruded and the depression 6 of the bottom portion 3 is prevented from drooping. It can be further increased.

  FIG. 6 is a cross-sectional view showing a state in which a parison is inserted into the blow mold in the molding process of the biaxially stretched blow mold 1.

  As shown in FIG. 6, the biaxially stretched blow-molded rod 1 can be manufactured by inserting an injection-molded parison 9 made of polyethylene terephthalate into a mold 10 and blow-molding it. In that case, since the shape of the bottom part of the shaping | molding die 10 is comparatively simple, a housing can be shape | molded easily. The biaxially stretched blow-molded ridge 1 can be formed by a square ridge (square tube ridge), but a round ridge (a ridge having a multi-sided cylindrical body having six or more faces or a cylindrical body) It has better moldability.

  In addition, as a warming kite for hot-warmer equipment or the like, it is desirable to crystallize (whiten) the plug portion 91 (region from the top surface of the kite to the bottom of the support ring), but it is crystallized (whitened). It does not have to be. This is because, with a warming warmer such as a hot-warmer device, a temperature above the glass transition temperature is applied to the warming process, so that the warming plug 91 is deformed and the hermetic seal with the cap is This is because there is a possibility that the contents may be rotted or the liquid leakage may occur, and it is desirable to crystallize the plug portion 91 in order to eliminate this.

  The plug portion 91 may be crystallized by a method of crystallizing the entire plug portion 91 as in the conventional method. Preferably, the plug portion 91 other than the support ring and the transition portion following the rear portion are crystallized. Is good. In the case where the support ring is left uncrystallized and the plug portion 91 is crystallized, the support ring remains amorphous. Also has the advantage that it will not break.

  As a method of making the plug portion 91 in which the plug portion 91 other than the support ring and the transition portion following the rear portion are crystallized, (1) a method of performing heat crystallization treatment on the plug portion 91 at the stage of the parison, (2 ) A method of subjecting the plug portion 91 to heat crystallization after blow molding, and (3) heat treatment only inside the plug portion 91 at the stage of parison, and then outside the plug portion 91 other than the support ring after blow molding. There is a method of heat treatment. Hereinafter, each method will be described.

  (1) A method of performing heat crystallization treatment on the plug portion 91 at the parison stage. First, as shown in FIG. 7, the parison 9 is molded by a normal injection molding method using an injection molding die 12 including a mouth portion die 121, an injection cavity die 122, and an injection core die 123.

  When the molded parison 9 is cooled to a temperature lower than the glass transition temperature, the injection core mold 123 and the injection cavity mold 122 are released. At this time, as shown in FIG. 8, the mouth part mold 121 keeps holding the plug part 91 of the parison 9.

  Next, as shown in FIG. 9, the parison 9 gripped by the mouth mold 121 is preferably placed in the cooling mold 13. At that time, it is preferable to cool not only the mouth mold 121 but also the body and bottom of the parison 9. The cooling temperature should just be lower than the crystallization temperature of resin, and specifically about 10-50 degreeC is preferable.

  In a state where the parison is cooled from the outside as described above, the rod heater 14 is inserted from the plug portion 91 of the parison 9 as shown in FIG. 9, and the transition portion to the trunk portion below the plug portion 91 and the support ring 92 is inserted. 93 is heated from the inside, and only the inner part of the transition part 93 to the trunk part below the plug part 91 and the support ring 92 is crystallized to form the crystallized part 19a. At this time, it is preferable to heat the parison so that the surface temperature becomes 100 to 190 ° C. It can carry out by heat-processing at 100-190 degreeC. In that case, when the temperature is lower than 100 ° C., the resin of the plug portion 91 does not crystallize. On the other hand, when the temperature exceeds 190 ° C., the crystallization is slowed and the parison is softened and easily deformed. Further, the heating time is set so that the resin causes partial crystallization, and specifically, about 0.5 to 3 minutes is preferable.

  Next, the mouth mold 121 is removed from the parison 9, and the support ring 92 is held by the support ring molds 16a and 16b as shown in FIG. In this state, the plug portion 91 is heated by the ring heater 15 from the outside. In that case, heating from the outside of the plug portion 91 may be performed using a hot air heater, an infrared heater or the like instead of the ring heater. The heating temperature may be about 100 to 190 ° C. as described above. Further, it may be sufficient time for the non-crystalline resin in the outer layer of the plug portion 91 to crystallize, but specifically, it is preferably about 0.5 to 3 minutes. At this time, the support ring molds 16a and 16b are preferably cooled to a temperature lower than the crystallization temperature of the resin. Specifically, the cooling temperature of the support ring 91 is preferably about 10 to 40 ° C.

  By heating the plug portion 91 by such a method, as shown in FIG. 11, the resin in the support ring 92 remains amorphous, and the other plug portions 91 are crystallized. 19b shows a non-crystallized part.

  The support ring 92 is easily deformed by its own weight when heated, but as shown in FIG. 10, the support ring 92 is held by the support ring molds 16a and 16b in the course of the heat treatment, so that deformation is prevented.

  Subsequently, the parison 9 obtained in this way is blow-molded by a normal method, but at this time, a steep thickness difference does not occur from the transition portion 93 to the lower shoulder portion.

  (2) A method of subjecting the plug portion 91 to a heat crystallization treatment after blow molding. After blow molding of the cocoon, the cocoon is taken out from the die that is held by the mouth mold 121 and subjected to the following heat crystallization treatment. In the heat crystallization process, the bag held by the mouth mold 121 is placed in a cooling mold, and a heater is inserted from the pot plug 91 in the same manner as in the above-described method (1). The part is heated from the inside, and the resin in that part is crystallized. The heating crystallization condition may be the method (1).

  Next, after the mouth mold 121 is released from the heel, the heel support ring 92 is gripped by the support ring dies 16a and 16b. In this state, the plug portion 91 is heated from the outside to crystallize the amorphous resin in the outer layer of the plug portion 91. The heat crystallization conditions may be the same as in the method (1).

  (3) A method of crystallizing only the inside of the plug portion 91 at the stage of the parison and then crystallizing the outside of the plug portion 91 other than the support ring after blow molding. After the parison is manufactured, the injection core mold 123 and the injection cavity mold 122 are removed while the parison is held by the mouth mold 121, and the plug portion 91 and the transition portion are heated from the inside to crystallize the resin at that portion. The heat crystallization conditions may be the same as in the method (1).

  After blow molding using the parison, the heel support ring 92 is held by the support ring molds 16a and 16b. In this state, the plug portion 91 other than the support ring 92 is heated from the outside to crystallize the amorphous resin in the outer layer of the plug portion 91. The heating crystallization condition may be the method (1).

  As a molding resin for the biaxially stretched blow molded cage 1, a polyester resin composed of a saturated dicarboxylic acid and a saturated dihydric alcohol can be applied. Examples of saturated dicarboxylic acids include terephthalic acid, isophthalic acid, phthalic acid, naphthalene-1,4- or 2,6 dicarboxylic acid, diphenyl ether-4,4′-dicarboxylic acid, diphenyldicarboxylic acids, diphenoxyethanediethanedicarboxylic acids, etc. Aromatic dicarboxylic acids, aliphatic dicarboxylic acids such as adipic acid, sebacic acid, azelaic acid, decane-1,10-dicarboxylic acid, and the like can be used. In addition, saturated dihydric alcohols include fats such as ethylene glycol, propylene glycol, trimethylene glycol, tetramethylene glycol, diethylene glycol, polyethylene glycol, polypropylene glycol, polytetramethylene glycol, hexamethylene glycol, dodecamethylene glycol, and neopentyl glycol. Group glycol, 2,2-bis (4′-β-hydroxyethoxyphenyl) propane, other aromatic diols, and the like can be used. As such a polyester resin comprising a saturated dicarboxylic acid and a saturated dihydric alcohol, it is preferable to use polyethylene terephthalate comprising terephthalic acid and ethylene glycol.

  In addition, the biaxially stretched blow molded cage 1 can also be formed as a two-layer or three-layer multilayer molded cage. That is, oxygen barrier such as polyethylene terephthalate / MXD6, MXD6 + cobalt salt, PGA (polyglycolic acid), EVOH (ethylene vinyl alcohol copolymer) or PEN (polyethylene naphthalate) is obtained by two-color extrusion molding or two-color injection molding. A multilayer bag having oxygen barrier properties and ultraviolet barrier properties may be formed by extrusion molding a three-layer parison of resin / polyethylene terephthalate having heat resistance and ultraviolet barrier properties, followed by blow molding.

  Alternatively, a hot-warmer container having a barrier property can be formed by attaching an in-mold label forming label to a blow mold and performing in-mold label biaxial stretching blow molding.

  The in-mold label forming label is composed of a base material layer and an adhesive layer, and the adhesive layer is composed of a heat-adhesive material that is softened at 130 ° C. or lower and adheres to the surface of the stretch blow molded article.

  Here, as a heat-adhesive material, (a) low density polyethylene, medium density polyethylene, high density polyethylene, linear low density polyethylene, ethylene-α olefin copolymer polymerized using a metallocene catalyst, polypropylene, ethylene- Vinyl acetate copolymer, ionomer resin, ethylene-ethyl acrylate copolymer, ethylene-methyl methacrylic acid copolymer, ethylene-acrylic acid copolymer, ethylene-methacrylic acid copolymer, ethylene-propylene copolymer, Polyolefin resins such as methylpentene polymer, polyethylene or polypropylene modified with acrylic acid, methacrylic acid, maleic anhydride, fumaric acid or other unsaturated carboxylic acid, poly (meth) acrylic resin, thermoplastic Polyester tree One or a plurality of thermoplastic polyamide-based resins, (b) an unstretched or stretched plastic film such as polyethylene, polypropylene or polyethylene terephthalate having a heat seal layer, (c) an ethylene-vinyl acetate copolymer A hot-melt adhesive layer containing (d) a heat sealant layer containing ethylene-vinyl acetate copolymer or the like can be applied.

  The base material layer includes a barrier layer, an ultraviolet ray prevention layer, a light shielding layer, a printing base material layer, and the like.

  Next, the present invention will be described with reference to examples and comparative examples.

(Example 1) Using a polyethylene terephthalate resin, by biaxial stretching blow molding, as shown in FIG. 1 thru | or 4, the taper shape which has a trunk | drum diameter 66mm and inclines toward the inside of a collar in the center part of the bottom part 3. As shown in FIGS. 2 and 3, the tapered peripheral wall 4 is provided with a recessed portion 6 having a shape recessed toward the inside of the ridge formed by the peripheral wall 4 and the top wall 5 connected to the upper end of the peripheral wall 4. The ground contact surface in the sectional view of the peripheral wall surface of the first peripheral wall 4b and the second peripheral wall 4a, which is composed of a first peripheral wall 4b on the ground conical surface 17 side and a second peripheral wall 4a on the top wall 5 side. And the distance H from the ground contact surface 17 to the top wall 5 of the biaxially stretched blow-molded bowl 1 of the depression 6 is 20 mm (30.3% of the trunk diameter), and the depression 6 The ring-shaped grounding diameter R at the lower end of the arm is 40 mm (the trunk diameter is 60.6 mm). ) And the inner volume of 350 ml (was molded biaxially stretch blow molding bottles 1 height 163 mm) and Contents 280 ml (height 136 mm).
350 ml of water was put into a tub with an internal volume of 350 ml, and 280 ml of water was put into a tub with an internal volume of 280 ml, and placed in a thermostatic bath at a temperature of 80 ° C. and left for 10 hours. However, under the influence of gravity and heat from the heated contents, the bottom part hangs down and the sitting does not worsen.

(Example 2) The distance H from the ground contact surface 17 to the top wall 5 of the biaxially stretched blow-molded cage 1 of the depressed portion 6 is 17.5 mm (26.5% of the trunk diameter), and the lower end of the depressed portion 6 is The ring-shaped grounding diameter R was the same as that of Example 1, except that the inner volume was 350 mm (height 163 mm) and the inner volume 280 ml (height 136 mm) was 40 mm (60.6% of the body diameter).
350 ml of water was put into a tub with an inner volume of 350 ml, and 280 ml of water was put into a tub with an inner volume of 280 ml, placed in a thermostat at 78 ° C. and left for 10 hours. However, under the influence of gravity and heat from the heated contents, the bottom part hangs down and the sitting does not worsen.

(Example 3) The distance H from the ground contact surface 17 of the biaxially stretched blow-molded bowl 1 of the depressed portion 6 to the top wall 5 is 17.5 mm (26.5% of the body diameter), and the annular shape at the lower end of the depressed portion 6 The ground contact diameter R was set to 45 mm (68.1% of the body diameter), and the inner volume was 350 ml (height 163 mm) and the inner volume was 280 ml (height 136 mm).
350 ml of water was put into a tub with an inner volume of 350 ml, and 280 ml of water was put into a tub with an inner volume of 280 ml, placed in a thermostat at 75 ° C. and left for 10 hours. However, under the influence of gravity and heat from the heated contents, the bottom part hangs down and the sitting does not worsen.

(Comparative example 1) The distance H from the ground contact surface 17 of the biaxially-stretched blow molding rod 1 of the depressed portion 6 to the top wall 5 is 15 mm (22.7% of the trunk diameter), and the annular grounding at the lower end of the depressed portion 6 The diameter R was set to 50 mm (75.7% of the body diameter), and the same as Example 1 except that the inner capacity was 350 ml (height 163 mm).
350 ml of water was placed in this basket, placed in a constant temperature bath at 75 ° C. and left for 10 hours. As a result, under the influence of the gravitational force and heat from the heated contents, the bottom part hangs down until it reaches the ground contact surface, and the seating becomes worse.

(Comparative example 2) The distance H from the ground contact surface 17 of the biaxially-stretched blow molding cage 1 of the depressed portion 6 to the top wall 5 is 16.5 mm (25% of the trunk diameter), and the annular grounding at the lower end of the depressed portion 6 The diameter R was set to 53 mm (80% of the body diameter), and the same as Example 1 except that the inner capacity was 350 ml (height 163 mm).
350 ml of water was placed in this basket, placed in a constant temperature bath at 75 ° C. and left for 10 hours. As a result, under the influence of the gravitational force and heat from the heated contents, the bottom part hangs down until it reaches the ground contact surface, and the seating becomes worse.

FIG. 12 is a graph showing the elapsed time of heating versus the rate of change in the depth of the gate portion of the biaxially stretched blow-molded reed 1, and the contents in a constant temperature layer (DN43 manufactured by Yamato Scientific Co., Ltd.) maintained at 75 ° C. (Heating) elapsed time when heating a basket with an object vs. gate part depth change rate ((the initial value of the distance from the grounding part of the basket to the gate part at the center of the basket (hereinafter referred to as the gate part depth)) The graph of the measured value of the gate depth of the ridge after heating) / the initial value of the gate depth × 100 (%)) is shown. The gate depth was measured using a depth cage manufactured by Mitutoyo Corporation. In FIG. 12,-●-indicates Comparative Example 1, -O- indicates Comparative Example 2,-▲-indicates Example 1, -x- indicates Example 2, and-♦-indicates Example 3. In FIG.
As is apparent from this figure, in the case of Examples 1 to 3, the gate change rate after 10 hours of heating is 70% or less, and the depressed portion 6 of the bottom portion 3 hangs down until it reaches the grounding surface 17 and the sitting becomes worse. It never happened. On the other hand, in the case of Comparative Examples 1 and 2, when heating was continued for 10 hours, the gate change rate reached 100%, and the depressed portion 6 of the bottom portion 3 hanged down to reach the grounding surface 17 and the sitting of the heel became worse.

  The biaxially stretched blow-molded bowl 1 according to the present invention can be effectively used as a sales container for heating and selling a beverage by a hot warmer device or the like.

1: Biaxially stretched blow molded cage 2: Body of cage 3: Bottom 3a: First bottom wall 3b: Transition region 3c: Second bottom wall 3d: Inflection point 4: Tapered peripheral wall 4a: Second peripheral wall 4b: First peripheral wall 5: Top wall 6: Depressed part 7: Transition area 8: Transition area 9: Parison 91: Mouth part 92: Support ring 93: Transition part to the trunk part below the support ring 92 10: Blow molding die 11 : Horizontal rib 12: Injection mold 121: Mouth mold 122: Injection cavity mold 123: Injection core mold 13: Cooling mold 14: Rod heater 15: Ring heater 16a: Support ring mold 16b: Support ring mold 17: Grounding surface 18 : Line indicating the contour of the bottom pressed and deformed toward the ground plane 19a: Crystallized region 19b: Non-crystallized region 21: Bottom 22: Peripheral wall 23: Inside of ridge 24: Side wall of heel 2 5: depression

Claims (1)

  In a biaxially stretched blow molded cocoon used for a heating container having a body diameter of 55 to 70 mm comprising a plug part, a body part, and a bottom part, a tapered peripheral wall inclined toward the inside of the heel part at the center part of the bottom part; A truncated conical cylindrical shape having a recessed portion that is recessed toward the inside of the ridge formed of a top wall connected to the upper end thereof, and having an annular grounding surface at the lower end of the tapered peripheral wall, the tapered peripheral wall being connected to each other The first peripheral wall on the ground surface side and the second peripheral wall on the top wall side, and the angles of the first peripheral wall and the second peripheral wall with respect to the ground surface in the peripheral wall cross-sectional views are different from each other, The distance from the ground plane to the top wall is 25 to 40% of the trunk diameter of the trunk section, the diameter of the ground plane is 50 to 75% of the trunk diameter of the trunk section, and the trunk plane to the trunk section A first bottom wall and a second bottom wall connected to each other The first bottom wall is an annular tapered bottom wall, and the second bottom wall is an annular curved bottom wall curved toward the outside of the longitudinal cross-sectional shape of the biaxially stretched blow-molded bowl, A lateral rib for lowering the side wall strength is provided below, the top wall of the depressed portion is located above the lateral rib, and the plug portion of the biaxially stretched blow-molded bowl is not whitened. A temperature of 75 ° C. above the glass transition point of the polyethylene terephthalate resin when the axially stretched blow molded basket is made of polyethylene terephthalate resin and the beverage is filled in the biaxially stretched blow molded mold and provided to the consumer by a hot warmer device. The biaxially-stretched blow-molded scissors are characterized in that the depressed portion of the bottom does not hang down even when kept at a temperature of 80 to 80 ° C., and the sitting of the biaxially-stretched blow-molded scissors does not deteriorate.

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