JP2010265562A - Agent for treating thin paper and thin paper - Google Patents
Agent for treating thin paper and thin paper Download PDFInfo
- Publication number
- JP2010265562A JP2010265562A JP2009117768A JP2009117768A JP2010265562A JP 2010265562 A JP2010265562 A JP 2010265562A JP 2009117768 A JP2009117768 A JP 2009117768A JP 2009117768 A JP2009117768 A JP 2009117768A JP 2010265562 A JP2010265562 A JP 2010265562A
- Authority
- JP
- Japan
- Prior art keywords
- component
- thin paper
- mass
- texture
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 104
- -1 fatty acid ester Chemical class 0.000 claims abstract description 58
- 239000004094 surface-active agent Substances 0.000 claims abstract description 34
- 125000002947 alkylene group Chemical group 0.000 claims abstract description 27
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 26
- 229930195729 fatty acid Natural products 0.000 claims abstract description 26
- 239000000194 fatty acid Substances 0.000 claims abstract description 26
- 150000002430 hydrocarbons Chemical group 0.000 claims abstract description 21
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 claims abstract description 13
- 238000002844 melting Methods 0.000 claims abstract description 11
- 230000008018 melting Effects 0.000 claims abstract description 11
- 239000002736 nonionic surfactant Substances 0.000 claims abstract description 10
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 9
- 125000004432 carbon atom Chemical group C* 0.000 claims description 29
- 238000012545 processing Methods 0.000 claims description 25
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 150000001413 amino acids Chemical class 0.000 claims description 9
- 150000001298 alcohols Chemical class 0.000 claims description 8
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 abstract description 14
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 abstract description 10
- 150000002148 esters Chemical class 0.000 abstract description 4
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 abstract 1
- 230000001105 regulatory effect Effects 0.000 abstract 1
- 239000002245 particle Substances 0.000 description 44
- 238000002156 mixing Methods 0.000 description 37
- 238000011156 evaluation Methods 0.000 description 35
- 239000000203 mixture Substances 0.000 description 33
- 239000007788 liquid Substances 0.000 description 25
- 229920001296 polysiloxane Polymers 0.000 description 25
- 230000000694 effects Effects 0.000 description 23
- 150000004665 fatty acids Chemical class 0.000 description 16
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 15
- 230000000052 comparative effect Effects 0.000 description 13
- 239000000047 product Substances 0.000 description 13
- 239000004711 α-olefin Substances 0.000 description 13
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 12
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 12
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 12
- 239000003921 oil Substances 0.000 description 12
- 235000019198 oils Nutrition 0.000 description 12
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000003755 preservative agent Substances 0.000 description 7
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 6
- 239000002253 acid Substances 0.000 description 6
- 150000001720 carbohydrates Chemical class 0.000 description 6
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 6
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 6
- 235000011187 glycerol Nutrition 0.000 description 6
- 150000002500 ions Chemical class 0.000 description 6
- GLDOVTGHNKAZLK-UHFFFAOYSA-N octadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCO GLDOVTGHNKAZLK-UHFFFAOYSA-N 0.000 description 6
- 230000002335 preservative effect Effects 0.000 description 6
- 229920006395 saturated elastomer Polymers 0.000 description 6
- 235000021314 Palmitic acid Nutrition 0.000 description 5
- 235000021355 Stearic acid Nutrition 0.000 description 5
- 125000000217 alkyl group Chemical group 0.000 description 5
- 150000008051 alkyl sulfates Chemical class 0.000 description 5
- 238000013329 compounding Methods 0.000 description 5
- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 5
- 229930195733 hydrocarbon Natural products 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- WQEPLUUGTLDZJY-UHFFFAOYSA-N n-Pentadecanoic acid Natural products CCCCCCCCCCCCCCC(O)=O WQEPLUUGTLDZJY-UHFFFAOYSA-N 0.000 description 5
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 5
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 5
- 229920001223 polyethylene glycol Polymers 0.000 description 5
- 239000008117 stearic acid Substances 0.000 description 5
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 5
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 4
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 4
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 4
- 239000002202 Polyethylene glycol Substances 0.000 description 4
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 4
- 230000002421 anti-septic effect Effects 0.000 description 4
- 239000002518 antifoaming agent Substances 0.000 description 4
- 238000000576 coating method Methods 0.000 description 4
- 239000003240 coconut oil Substances 0.000 description 4
- 235000019864 coconut oil Nutrition 0.000 description 4
- 239000000839 emulsion Substances 0.000 description 4
- 238000005187 foaming Methods 0.000 description 4
- 239000000463 material Substances 0.000 description 4
- 239000002994 raw material Substances 0.000 description 4
- 238000000926 separation method Methods 0.000 description 4
- 229910052708 sodium Inorganic materials 0.000 description 4
- 239000011734 sodium Substances 0.000 description 4
- 239000000600 sorbitol Substances 0.000 description 4
- 235000010356 sorbitol Nutrition 0.000 description 4
- PRAKJMSDJKAYCZ-UHFFFAOYSA-N squalane Chemical compound CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 4
- 125000001273 sulfonato group Chemical group [O-]S(*)(=O)=O 0.000 description 4
- AKEJUJNQAAGONA-UHFFFAOYSA-N sulfur trioxide Chemical compound O=S(=O)=O AKEJUJNQAAGONA-UHFFFAOYSA-N 0.000 description 4
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 3
- 239000004386 Erythritol Substances 0.000 description 3
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 3
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 3
- 239000005977 Ethylene Substances 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
- 239000005639 Lauric acid Substances 0.000 description 3
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 3
- 241000282320 Panthera leo Species 0.000 description 3
- 239000004264 Petrolatum Substances 0.000 description 3
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 3
- 206010040880 Skin irritation Diseases 0.000 description 3
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 3
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 3
- TVXBFESIOXBWNM-UHFFFAOYSA-N Xylitol Natural products OCCC(O)C(O)C(O)CCO TVXBFESIOXBWNM-UHFFFAOYSA-N 0.000 description 3
- 229910001413 alkali metal ion Inorganic materials 0.000 description 3
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 3
- 150000001342 alkaline earth metals Chemical class 0.000 description 3
- 239000011248 coating agent Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 3
- SMVRDGHCVNAOIN-UHFFFAOYSA-L disodium;1-dodecoxydodecane;sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O.CCCCCCCCCCCCOCCCCCCCCCCCC SMVRDGHCVNAOIN-UHFFFAOYSA-L 0.000 description 3
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 3
- 235000019414 erythritol Nutrition 0.000 description 3
- 229940009714 erythritol Drugs 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 229940057995 liquid paraffin Drugs 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- HEBKCHPVOIAQTA-UHFFFAOYSA-N meso ribitol Natural products OCC(O)C(O)C(O)CO HEBKCHPVOIAQTA-UHFFFAOYSA-N 0.000 description 3
- 229940066842 petrolatum Drugs 0.000 description 3
- 235000019271 petrolatum Nutrition 0.000 description 3
- 229910052700 potassium Inorganic materials 0.000 description 3
- 239000011591 potassium Substances 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000036556 skin irritation Effects 0.000 description 3
- 231100000475 skin irritation Toxicity 0.000 description 3
- 239000000811 xylitol Substances 0.000 description 3
- HEBKCHPVOIAQTA-SCDXWVJYSA-N xylitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)CO HEBKCHPVOIAQTA-SCDXWVJYSA-N 0.000 description 3
- 235000010447 xylitol Nutrition 0.000 description 3
- 229960002675 xylitol Drugs 0.000 description 3
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 description 2
- GVJHHUAWPYXKBD-UHFFFAOYSA-N (±)-α-Tocopherol Chemical compound OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 2
- 229940058015 1,3-butylene glycol Drugs 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 2
- QFOHBWFCKVYLES-UHFFFAOYSA-N Butylparaben Chemical compound CCCCOC(=O)C1=CC=C(O)C=C1 QFOHBWFCKVYLES-UHFFFAOYSA-N 0.000 description 2
- 239000004215 Carbon black (E152) Substances 0.000 description 2
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- IYFATESGLOUGBX-YVNJGZBMSA-N Sorbitan monopalmitate Chemical compound CCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O IYFATESGLOUGBX-YVNJGZBMSA-N 0.000 description 2
- HVUMOYIDDBPOLL-XWVZOOPGSA-N Sorbitan monostearate Chemical compound CCCCCCCCCCCCCCCCCC(=O)OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O HVUMOYIDDBPOLL-XWVZOOPGSA-N 0.000 description 2
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 2
- 235000019437 butane-1,3-diol Nutrition 0.000 description 2
- 229960000541 cetyl alcohol Drugs 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- NOPFSRXAKWQILS-UHFFFAOYSA-N docosan-1-ol Chemical compound CCCCCCCCCCCCCCCCCCCCCCO NOPFSRXAKWQILS-UHFFFAOYSA-N 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 235000019197 fats Nutrition 0.000 description 2
- 239000008103 glucose Substances 0.000 description 2
- 229960001031 glucose Drugs 0.000 description 2
- 235000001727 glucose Nutrition 0.000 description 2
- 239000012535 impurity Substances 0.000 description 2
- 239000011256 inorganic filler Substances 0.000 description 2
- 229910003475 inorganic filler Inorganic materials 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 230000014759 maintenance of location Effects 0.000 description 2
- LXCFILQKKLGQFO-UHFFFAOYSA-N methylparaben Chemical compound COC(=O)C1=CC=C(O)C=C1 LXCFILQKKLGQFO-UHFFFAOYSA-N 0.000 description 2
- JXTPJDDICSTXJX-UHFFFAOYSA-N n-Triacontane Natural products CCCCCCCCCCCCCCCCCCCCCCCCCCCCCC JXTPJDDICSTXJX-UHFFFAOYSA-N 0.000 description 2
- GOQYKNQRPGWPLP-UHFFFAOYSA-N n-heptadecyl alcohol Natural products CCCCCCCCCCCCCCCCCO GOQYKNQRPGWPLP-UHFFFAOYSA-N 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
- 235000021313 oleic acid Nutrition 0.000 description 2
- 229920000136 polysorbate Polymers 0.000 description 2
- QELSKZZBTMNZEB-UHFFFAOYSA-N propylparaben Chemical compound CCCOC(=O)C1=CC=C(O)C=C1 QELSKZZBTMNZEB-UHFFFAOYSA-N 0.000 description 2
- 150000004671 saturated fatty acids Chemical class 0.000 description 2
- 230000001953 sensory effect Effects 0.000 description 2
- 239000001570 sorbitan monopalmitate Substances 0.000 description 2
- 235000011071 sorbitan monopalmitate Nutrition 0.000 description 2
- 229940031953 sorbitan monopalmitate Drugs 0.000 description 2
- 239000001587 sorbitan monostearate Substances 0.000 description 2
- 235000011076 sorbitan monostearate Nutrition 0.000 description 2
- 229940035048 sorbitan monostearate Drugs 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 229940032094 squalane Drugs 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 150000008053 sultones Chemical class 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- 235000021122 unsaturated fatty acids Nutrition 0.000 description 2
- 150000004670 unsaturated fatty acids Chemical class 0.000 description 2
- HOVAGTYPODGVJG-UVSYOFPXSA-N (3s,5r)-2-(hydroxymethyl)-6-methoxyoxane-3,4,5-triol Chemical compound COC1OC(CO)[C@@H](O)C(O)[C@H]1O HOVAGTYPODGVJG-UVSYOFPXSA-N 0.000 description 1
- ALSTYHKOOCGGFT-KTKRTIGZSA-N (9Z)-octadecen-1-ol Chemical compound CCCCCCCC\C=C/CCCCCCCCO ALSTYHKOOCGGFT-KTKRTIGZSA-N 0.000 description 1
- JXNPEDYJTDQORS-HZJYTTRNSA-N (9Z,12Z)-octadecadien-1-ol Chemical compound CCCCC\C=C/C\C=C/CCCCCCCCO JXNPEDYJTDQORS-HZJYTTRNSA-N 0.000 description 1
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 1
- FDCJDKXCCYFOCV-UHFFFAOYSA-N 1-hexadecoxyhexadecane Chemical compound CCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCC FDCJDKXCCYFOCV-UHFFFAOYSA-N 0.000 description 1
- HBXWUCXDUUJDRB-UHFFFAOYSA-N 1-octadecoxyoctadecane Chemical compound CCCCCCCCCCCCCCCCCCOCCCCCCCCCCCCCCCCCC HBXWUCXDUUJDRB-UHFFFAOYSA-N 0.000 description 1
- OWEGMIWEEQEYGQ-UHFFFAOYSA-N 100676-05-9 Natural products OC1C(O)C(O)C(CO)OC1OCC1C(O)C(O)C(O)C(OC2C(OC(O)C(O)C2O)CO)O1 OWEGMIWEEQEYGQ-UHFFFAOYSA-N 0.000 description 1
- UUIVKBHZENILKB-UHFFFAOYSA-N 2,2-dibromo-2-cyanoacetamide Chemical compound NC(=O)C(Br)(Br)C#N UUIVKBHZENILKB-UHFFFAOYSA-N 0.000 description 1
- WGHAPLWNJPAJDE-UHFFFAOYSA-N 2-(2-bromoacetyl)oxyethyl 2-bromoacetate Chemical compound BrCC(=O)OCCOC(=O)CBr WGHAPLWNJPAJDE-UHFFFAOYSA-N 0.000 description 1
- HUHGPYXAVBJSJV-UHFFFAOYSA-N 2-[3,5-bis(2-hydroxyethyl)-1,3,5-triazinan-1-yl]ethanol Chemical compound OCCN1CN(CCO)CN(CCO)C1 HUHGPYXAVBJSJV-UHFFFAOYSA-N 0.000 description 1
- LUYIHWDYPAZCNN-UHFFFAOYSA-N 2-butyl-1,2-benzothiazol-3-one Chemical compound C1=CC=C2C(=O)N(CCCC)SC2=C1 LUYIHWDYPAZCNN-UHFFFAOYSA-N 0.000 description 1
- 229940100555 2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- DBTMGCOVALSLOR-UHFFFAOYSA-N 32-alpha-galactosyl-3-alpha-galactosyl-galactose Natural products OC1C(O)C(O)C(CO)OC1OC1C(O)C(OC2C(C(CO)OC(O)C2O)O)OC(CO)C1O DBTMGCOVALSLOR-UHFFFAOYSA-N 0.000 description 1
- QGSRKGWCQSATCL-UHFFFAOYSA-N 4,5-dichloro-3h-1,3-dithiol-2-one Chemical compound ClC=1SSC(=O)C=1Cl QGSRKGWCQSATCL-UHFFFAOYSA-N 0.000 description 1
- 229940100484 5-chloro-2-methyl-4-isothiazolin-3-one Drugs 0.000 description 1
- GUBGYTABKSRVRQ-XLOQQCSPSA-N Alpha-Lactose Chemical compound O[C@@H]1[C@@H](O)[C@@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@H](O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-XLOQQCSPSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- ZZZCUOFIHGPKAK-UHFFFAOYSA-N D-erythro-ascorbic acid Natural products OCC1OC(=O)C(O)=C1O ZZZCUOFIHGPKAK-UHFFFAOYSA-N 0.000 description 1
- RXVWSYJTUUKTEA-UHFFFAOYSA-N D-maltotriose Natural products OC1C(O)C(OC(C(O)CO)C(O)C(O)C=O)OC(CO)C1OC1C(O)C(O)C(O)C(CO)O1 RXVWSYJTUUKTEA-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-QTVWNMPRSA-N D-mannopyranose Chemical compound OC[C@H]1OC(O)[C@@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-QTVWNMPRSA-N 0.000 description 1
- HMFHBZSHGGEWLO-SOOFDHNKSA-N D-ribofuranose Chemical compound OC[C@H]1OC(O)[C@H](O)[C@@H]1O HMFHBZSHGGEWLO-SOOFDHNKSA-N 0.000 description 1
- 102000002322 Egg Proteins Human genes 0.000 description 1
- 108010000912 Egg Proteins Proteins 0.000 description 1
- 206010016322 Feeling abnormal Diseases 0.000 description 1
- 229930091371 Fructose Natural products 0.000 description 1
- 239000005715 Fructose Substances 0.000 description 1
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QKKXKWKRSA-N Lactose Natural products OC[C@H]1O[C@@H](O[C@H]2[C@H](O)[C@@H](O)C(O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@H]1O GUBGYTABKSRVRQ-QKKXKWKRSA-N 0.000 description 1
- GUBGYTABKSRVRQ-PICCSMPSSA-N Maltose Natural products O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@@H]1O[C@@H]1[C@@H](CO)OC(O)[C@H](O)[C@H]1O GUBGYTABKSRVRQ-PICCSMPSSA-N 0.000 description 1
- 241000047703 Nonion Species 0.000 description 1
- 235000019482 Palm oil Nutrition 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 229920001213 Polysorbate 20 Polymers 0.000 description 1
- MUPFEKGTMRGPLJ-RMMQSMQOSA-N Raffinose Natural products O(C[C@H]1[C@@H](O)[C@H](O)[C@@H](O)[C@@H](O[C@@]2(CO)[C@H](O)[C@@H](O)[C@@H](CO)O2)O1)[C@@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 MUPFEKGTMRGPLJ-RMMQSMQOSA-N 0.000 description 1
- PYMYPHUHKUWMLA-LMVFSUKVSA-N Ribose Natural products OC[C@@H](O)[C@@H](O)[C@@H](O)C=O PYMYPHUHKUWMLA-LMVFSUKVSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- CZMRCDWAGMRECN-UGDNZRGBSA-N Sucrose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO)O1 CZMRCDWAGMRECN-UGDNZRGBSA-N 0.000 description 1
- 229930006000 Sucrose Natural products 0.000 description 1
- MUPFEKGTMRGPLJ-UHFFFAOYSA-N UNPD196149 Natural products OC1C(O)C(CO)OC1(CO)OC1C(O)C(O)C(O)C(COC2C(C(O)C(O)C(CO)O2)O)O1 MUPFEKGTMRGPLJ-UHFFFAOYSA-N 0.000 description 1
- 229930003268 Vitamin C Natural products 0.000 description 1
- 229930003427 Vitamin E Natural products 0.000 description 1
- 239000004480 active ingredient Substances 0.000 description 1
- 150000001336 alkenes Chemical class 0.000 description 1
- HMFHBZSHGGEWLO-UHFFFAOYSA-N alpha-D-Furanose-Ribose Natural products OCC1OC(O)C(O)C1O HMFHBZSHGGEWLO-UHFFFAOYSA-N 0.000 description 1
- WQZGKKKJIJFFOK-PHYPRBDBSA-N alpha-D-galactose Chemical compound OC[C@H]1O[C@H](O)[C@H](O)[C@@H](O)[C@H]1O WQZGKKKJIJFFOK-PHYPRBDBSA-N 0.000 description 1
- 125000003277 amino group Chemical group 0.000 description 1
- 239000010775 animal oil Substances 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 150000001450 anions Chemical group 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 235000006708 antioxidants Nutrition 0.000 description 1
- PYMYPHUHKUWMLA-WDCZJNDASA-N arabinose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)C=O PYMYPHUHKUWMLA-WDCZJNDASA-N 0.000 description 1
- PYMYPHUHKUWMLA-UHFFFAOYSA-N arabinose Natural products OCC(O)C(O)C(O)C=O PYMYPHUHKUWMLA-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 235000013871 bee wax Nutrition 0.000 description 1
- 239000012166 beeswax Substances 0.000 description 1
- DMSMPAJRVJJAGA-UHFFFAOYSA-N benzo[d]isothiazol-3-one Chemical compound C1=CC=C2C(=O)NSC2=C1 DMSMPAJRVJJAGA-UHFFFAOYSA-N 0.000 description 1
- 229940050390 benzoate Drugs 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- SRBFZHDQGSBBOR-UHFFFAOYSA-N beta-D-Pyranose-Lyxose Natural products OC1COC(O)C(O)C1O SRBFZHDQGSBBOR-UHFFFAOYSA-N 0.000 description 1
- GUBGYTABKSRVRQ-QUYVBRFLSA-N beta-maltose Chemical compound OC[C@H]1O[C@H](O[C@H]2[C@H](O)[C@@H](O)[C@H](O)O[C@@H]2CO)[C@H](O)[C@@H](O)[C@@H]1O GUBGYTABKSRVRQ-QUYVBRFLSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 229940067596 butylparaben Drugs 0.000 description 1
- 239000006227 byproduct Substances 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 239000004359 castor oil Substances 0.000 description 1
- 235000019438 castor oil Nutrition 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 239000003093 cationic surfactant Substances 0.000 description 1
- 150000001768 cations Chemical group 0.000 description 1
- DHNRXBZYEKSXIM-UHFFFAOYSA-N chloromethylisothiazolinone Chemical compound CN1SC(Cl)=CC1=O DHNRXBZYEKSXIM-UHFFFAOYSA-N 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 230000018044 dehydration Effects 0.000 description 1
- 238000006297 dehydration reaction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 229940105990 diglycerin Drugs 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000002612 dispersion medium Substances 0.000 description 1
- 229960000735 docosanol Drugs 0.000 description 1
- LQZZUXJYWNFBMV-UHFFFAOYSA-N dodecan-1-ol Chemical compound CCCCCCCCCCCCO LQZZUXJYWNFBMV-UHFFFAOYSA-N 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 235000013345 egg yolk Nutrition 0.000 description 1
- 210000002969 egg yolk Anatomy 0.000 description 1
- 229940093476 ethylene glycol Drugs 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 229930182830 galactose Natural products 0.000 description 1
- WIGCFUFOHFEKBI-UHFFFAOYSA-N gamma-tocopherol Natural products CC(C)CCCC(C)CCCC(C)CCCC1CCC2C(C)C(O)C(C)C(C)C2O1 WIGCFUFOHFEKBI-UHFFFAOYSA-N 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 229960005150 glycerol Drugs 0.000 description 1
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000008101 lactose Substances 0.000 description 1
- JXNPEDYJTDQORS-UHFFFAOYSA-N linoleyl alcohol Natural products CCCCCC=CCC=CCCCCCCCCO JXNPEDYJTDQORS-UHFFFAOYSA-N 0.000 description 1
- FYGDTMLNYKFZSV-UHFFFAOYSA-N mannotriose Natural products OC1C(O)C(O)C(CO)OC1OC1C(CO)OC(OC2C(OC(O)C(O)C2O)CO)C(O)C1O FYGDTMLNYKFZSV-UHFFFAOYSA-N 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- HOVAGTYPODGVJG-UHFFFAOYSA-N methyl beta-galactoside Natural products COC1OC(CO)C(O)C(O)C1O HOVAGTYPODGVJG-UHFFFAOYSA-N 0.000 description 1
- 235000010270 methyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004292 methyl p-hydroxybenzoate Substances 0.000 description 1
- BEGLCMHJXHIJLR-UHFFFAOYSA-N methylisothiazolinone Chemical compound CN1SC=CC1=O BEGLCMHJXHIJLR-UHFFFAOYSA-N 0.000 description 1
- 229960002216 methylparaben Drugs 0.000 description 1
- 230000003020 moisturizing effect Effects 0.000 description 1
- 229940055577 oleyl alcohol Drugs 0.000 description 1
- XMLQWXUVTXCDDL-UHFFFAOYSA-N oleyl alcohol Natural products CCCCCCC=CCCCCCCCCCCO XMLQWXUVTXCDDL-UHFFFAOYSA-N 0.000 description 1
- 238000006384 oligomerization reaction Methods 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 125000001477 organic nitrogen group Chemical group 0.000 description 1
- 125000001741 organic sulfur group Chemical group 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 239000002540 palm oil Substances 0.000 description 1
- 229940056211 paraffin Drugs 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- 239000012169 petroleum derived wax Substances 0.000 description 1
- 235000019381 petroleum wax Nutrition 0.000 description 1
- 239000000049 pigment Substances 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 239000000249 polyoxyethylene sorbitan monopalmitate Substances 0.000 description 1
- 235000010483 polyoxyethylene sorbitan monopalmitate Nutrition 0.000 description 1
- 239000001818 polyoxyethylene sorbitan monostearate Substances 0.000 description 1
- 235000010989 polyoxyethylene sorbitan monostearate Nutrition 0.000 description 1
- 229920001451 polypropylene glycol Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229950008882 polysorbate Drugs 0.000 description 1
- 235000010232 propyl p-hydroxybenzoate Nutrition 0.000 description 1
- 239000004405 propyl p-hydroxybenzoate Substances 0.000 description 1
- 229960004063 propylene glycol Drugs 0.000 description 1
- 235000013772 propylene glycol Nutrition 0.000 description 1
- 229960003415 propylparaben Drugs 0.000 description 1
- MUPFEKGTMRGPLJ-ZQSKZDJDSA-N raffinose Chemical compound O[C@H]1[C@H](O)[C@@H](CO)O[C@@]1(CO)O[C@@H]1[C@H](O)[C@@H](O)[C@H](O)[C@@H](CO[C@@H]2[C@@H]([C@@H](O)[C@@H](O)[C@@H](CO)O2)O)O1 MUPFEKGTMRGPLJ-ZQSKZDJDSA-N 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 229960002920 sorbitol Drugs 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 229940012831 stearyl alcohol Drugs 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 238000006277 sulfonation reaction Methods 0.000 description 1
- HHVIBTZHLRERCL-UHFFFAOYSA-N sulfonyldimethane Chemical compound CS(C)(=O)=O HHVIBTZHLRERCL-UHFFFAOYSA-N 0.000 description 1
- TUNFSRHWOTWDNC-HKGQFRNVSA-N tetradecanoic acid Chemical compound CCCCCCCCCCCCC[14C](O)=O TUNFSRHWOTWDNC-HKGQFRNVSA-N 0.000 description 1
- 238000005979 thermal decomposition reaction Methods 0.000 description 1
- 235000015112 vegetable and seed oil Nutrition 0.000 description 1
- 239000008158 vegetable oil Substances 0.000 description 1
- 235000019154 vitamin C Nutrition 0.000 description 1
- 239000011718 vitamin C Substances 0.000 description 1
- 235000019165 vitamin E Nutrition 0.000 description 1
- 229940046009 vitamin E Drugs 0.000 description 1
- 239000011709 vitamin E Substances 0.000 description 1
- 239000001993 wax Substances 0.000 description 1
- 230000037303 wrinkles Effects 0.000 description 1
- FYGDTMLNYKFZSV-BYLHFPJWSA-N β-1,4-galactotrioside Chemical compound O[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@H](CO)O[C@@H](O[C@@H]2[C@@H](O[C@@H](O)[C@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O FYGDTMLNYKFZSV-BYLHFPJWSA-N 0.000 description 1
Landscapes
- Sanitary Thin Papers (AREA)
- Paper (AREA)
Abstract
Description
本発明は薄葉紙処理剤及び薄葉紙に関する。 The present invention relates to a thin paper treating agent and a thin paper.
従来、トイレットペーパーやティッシュペーパー等の薄葉紙においては、より柔らかな使用感が求められ、柔らかな使用感を実現する様々な試みが行われている。
例えば、ティッシュペーパー等の薄葉紙の表面に、柔らかさ、さらさら感等の風合いを向上する薄葉紙処理剤を塗布する等の後処理により、薄葉紙の風合いの改善が試みられている。薄葉紙処理剤としては、保湿性を付与するため、多価アルコール（グリセリン、多糖類等）を基剤とし、これに滑らかさや柔らかさを付与するために、各種カチオン系界面活性剤や炭化水素、油脂、高級アルコール等の油分を配合したり（特許文献１）、さらさらした滑らか感を付与するために、パウダーを配合する提案がなされている（特許文献２）。
Conventionally, soft paper is required for thin paper such as toilet paper and tissue paper, and various attempts have been made to realize a soft feeling.
For example, attempts have been made to improve the texture of thin paper by post-treatment such as applying a thin paper treatment agent that improves the texture such as softness and smoothness to the surface of thin paper such as tissue paper. The thin paper treatment agent is based on polyhydric alcohols (glycerin, polysaccharides, etc.) to provide moisture retention, and various cationic surfactants, hydrocarbons, There have been proposals for blending oils such as fats and oils, higher alcohols (Patent Document 1), and blending powders to give a smooth and smooth feeling (Patent Document 2).
しかしながら、上述のような従来提案されている薄葉紙処理剤においても、柔らかさ、さらさら感等の風合い（肌触り）の改善効果は必ずしも十分とはいえなかった。加えて、薄葉紙処理剤には、液体組成物としての均一な状態を保つ（液安定性）ことが要求される。
そこで、本発明は、液安定性を保ちつつ、柔らかさ、さらさら感等の風合いのさらなる改善が図れる薄葉紙処理剤及び風合いが改善された薄葉紙を提供することを目的とする。
However, even the conventionally proposed thin paper treatment agents as described above have not always been sufficient in improving the texture (texture) such as softness and smoothness. In addition, the thin paper treatment agent is required to maintain a uniform state as a liquid composition (liquid stability).
Therefore, an object of the present invention is to provide a thin paper treating agent capable of further improving the texture such as softness and smoothness while maintaining liquid stability, and a thin paper with improved texture.
本発明の薄葉紙処理剤は、下記（Ａ）成分と、（Ｂ）成分と、（Ｃ）成分とを含有し、（Ａ）／［（Ａ）＋（Ｂ）］で表される質量比が０．０９〜０．９０、（Ｃ）／［（Ａ）＋（Ｂ）＋（Ｃ）］で表される質量比が０．６０〜０．９９５であることを特徴とする。
（Ａ）成分：炭化水素基の炭素数が１４〜２２であり、融点が２０℃以上であるアルキレンオキシドが付加されていないソルビタン脂肪酸エステル
（Ｂ）成分：硫酸エステル系界面活性剤、スルホン酸系界面活性剤、アミノ酸型界面活性剤、炭素数８〜２２のアルコールのアルキレンオキシド付加型非イオン性界面活性剤からなる群から選ばれる少なくとも１種
（Ｃ）成分：多価アルコール
The thin paper treating agent of the present invention contains the following component (A), component (B), and component (C), and a mass ratio represented by (A) / [(A) + (B)]. The mass ratio represented by 0.09 to 0.90, (C) / [(A) + (B) + (C)] is 0.60 to 0.995.
(A) Component: Sorbitan fatty acid ester having a hydrocarbon group having 14 to 22 carbon atoms and a melting point of 20 ° C. or higher and not added with alkylene oxide (B) Component: sulfate ester surfactant, sulfonic acid type At least one selected from the group consisting of surfactants, amino acid type surfactants, alkylene oxide addition type nonionic surfactants of alcohols having 8 to 22 carbon atoms (C) component: polyhydric alcohol
本発明の薄葉紙処理剤は、下記（Ａ）成分と、（Ｂ）成分と、（Ｃ）成分と、（Ｄ）成分とを含有し、（Ａ）／［（Ａ）＋（Ｂ）＋（Ｄ）］で表される質量比が０．０９〜０．９０、（Ｃ）／［（Ａ）＋（Ｂ）＋（Ｃ）＋（Ｄ）］で表される質量比が０．６０〜０．９９５、（Ｄ）／［（Ｂ）＋（Ｄ）］で表される質量比が０．８０以下であることを特徴とする。
（Ａ）成分：炭化水素基の炭素数が１４〜２２であり、融点が２０℃以上であるアルキレンオキシドが付加されていないソルビタン脂肪酸エステル
（Ｂ）成分：硫酸エステル系界面活性剤、スルホン酸系界面活性剤、アミノ酸型界面活性剤、炭素数８〜２２のアルコールのアルキレンオキシド付加型非イオン性界面活性剤からなる群から選ばれる少なくとも１種
（Ｃ）成分：多価アルコール
（Ｄ）成分：炭化水素基の炭素数が８〜２２のアルキレンオキシド付加型ソルビタンエステル
The thin paper treating agent of the present invention contains the following component (A), component (B), component (C), and component (D), and (A) / [(A) + (B) + ( D)] is 0.09 to 0.90, and the mass ratio represented by (C) / [(A) + (B) + (C) + (D)] is 0.60. The mass ratio represented by 0.995, (D) / [(B) + (D)] is 0.80 or less.
(A) Component: Sorbitan fatty acid ester having a hydrocarbon group having 14 to 22 carbon atoms and a melting point of 20 ° C. or higher and not added with alkylene oxide (B) Component: sulfate ester surfactant, sulfonic acid type At least one selected from the group consisting of surfactants, amino acid type surfactants, alkylene oxide addition type nonionic surfactants of alcohols having 8 to 22 carbon atoms (C) component: polyhydric alcohol (D) component: Alkylene oxide addition type sorbitan ester having 8 to 22 carbon atoms of hydrocarbon group
本発明の薄葉紙処理剤は、（Ｅ）成分：水を含有し、（Ｅ）／［（Ｃ）＋（Ｅ）］で表される質量比が０．００１〜０．６０であることが好ましい。 The thin paper treating agent of the present invention contains (E) component: water, and the mass ratio represented by (E) / [(C) + (E)] is preferably 0.001 to 0.60. .
本発明の薄葉紙は、前記の本発明の薄葉紙処理剤で処理してなることを特徴とする。 The thin paper of the present invention is characterized by being treated with the thin paper treating agent of the present invention.
本発明の薄葉紙処理剤は、液安定性が良好であり、薄葉紙に使用すると、柔らかさ、さらさら感等の風合いが良好な薄葉紙を得られる。 The thin paper treating agent of the present invention has good liquid stability, and when used for thin paper, a thin paper having a good texture such as softness and smooth feeling can be obtained.
（薄葉紙処理剤）
本発明の薄葉紙処理剤は、下記（Ａ）成分と、（Ｂ）成分と、（Ｃ）成分とを含有する。
(Thin paper processing agent)
The thin paper treating agent of the present invention contains the following component (A), component (B), and component (C).
［（Ａ）成分：炭化水素基の炭素数が１４〜２２であり、融点が２０℃以上であるアルキレンオキシドが付加されていないソルビタン脂肪酸エステル］
本発明の（Ａ）成分は、炭化水素基の炭素数が１４〜２２であり、融点が２０℃以上であるソルビタン脂肪酸エステルであって、アルキレンオキシドが付加されていないものである。ここで、融点は、医薬部外品原料規格、融点測定法の第２法により測定される融点である。（Ａ）成分のソルビタン脂肪酸エステルは、脂肪酸と、ソルビトール又はソルビトール分子内縮合物のエステルであり、一般に市販されている公知のものを使用できる。
[Component (A): Sorbitan fatty acid ester to which an alkylene oxide having a hydrocarbon group having 14 to 22 carbon atoms and a melting point of 20 ° C. or higher is not added]
The component (A) of the present invention is a sorbitan fatty acid ester having a hydrocarbon group having 14 to 22 carbon atoms and a melting point of 20 ° C. or higher, and having no alkylene oxide added thereto. Here, melting | fusing point is melting | fusing point measured by the 2nd method of a quasi-drug raw material specification and melting | fusing point measuring method. The sorbitan fatty acid ester of the component (A) is an ester of fatty acid and sorbitol or a sorbitol intramolecular condensate, and publicly known ones can be used.
（Ａ）成分のソルビタン脂肪酸エステルを構成する脂肪酸（以下、脂肪酸部ということがある）は、その炭化水素基の炭素数が１４〜２２であり、好ましくは１６〜１８である。
前記脂肪酸部の炭化水素基は、直鎖であってもよく分岐鎖であってもよい。
加えて、前記脂肪酸部は、飽和脂肪酸であってもよいし、不飽和脂肪酸であってもよい。
(A) The fatty acid (henceforth a fatty acid part) which comprises the sorbitan fatty acid ester of a component has 14-22 carbon atoms, Preferably it is 16-18.
The hydrocarbon group of the fatty acid part may be linear or branched.
In addition, the fatty acid part may be a saturated fatty acid or an unsaturated fatty acid.
このような（Ａ）成分としては、例えば、ミリスチン酸、パルミチン酸、ステアリン酸、イソステアリン酸、オレイン酸等の脂肪酸と、ソルビタンとのモノ−、ジ−、トリ−エステル化物及びこれらの混合物等が挙げられ、中でも、パルミチン酸もしくはステアリン酸と、ソルビタンとのエステル化合物又はこれらの混合物が好ましく、モノステアリン酸ソルビタン又はモノパルミチン酸ソルビタンがより好ましい。このような（Ａ）成分を用いることで、薄葉紙処理剤としたときに後述する会合体粒子が形成され、薄葉紙処理剤をさらさら感、柔らかさといった薄葉紙の風合い向上に優れるものとすることができる。 Examples of such component (A) include mono-, di-, tri-esterified products of fatty acids such as myristic acid, palmitic acid, stearic acid, isostearic acid, oleic acid, and sorbitan, and mixtures thereof. Among them, an ester compound of palmitic acid or stearic acid and sorbitan or a mixture thereof is preferable, and sorbitan monostearate or sorbitan monopalmitate is more preferable. By using such a component (A), aggregated particles described later are formed when the thin paper treatment agent is used, and the thin paper treatment agent can be excellent in improving the texture of the thin paper such as a dry feeling and softness. .
薄葉紙処理剤中の（Ａ）成分の配合量は、処理対象とする薄葉紙の材質や求める品質、他の成分の配合量等を考慮して決定でき、例えば、０．２５〜２０質量％で決定することが好ましく、０．５〜１５質量％がより好ましく、１〜１０質量％がさらに好ましい。（Ａ）成分の配合量が０．２５質量％未満であると薄葉紙の風合い改善が図りにくく、２０質量％を超えても（Ａ）成分による風合い改善の効果が飽和し、さらなる風合い改善効果の向上が望めないためである。（Ａ）成分の配合量が０．５〜１５質量％であれば、目的とする風合い改善効果を得られると共に、薄葉紙処理剤の粘度が過度に高くならず、薄葉紙処理剤の輸送時や使用時における取り扱いが良好である。さらに、（Ａ）成分の配合量が１〜１０質量％であれば、薄葉紙のさらさら感及び柔らかさの大幅な向上が図れる。 The blending amount of the component (A) in the thin paper treatment agent can be determined in consideration of the material of the thin paper to be processed, the quality required, the blending amount of other components, and the like, for example, determined at 0.25 to 20% by mass. It is preferably 0.5 to 15% by mass, more preferably 1 to 10% by mass. When the blending amount of the component (A) is less than 0.25% by mass, it is difficult to improve the texture of the thin paper, and even if it exceeds 20% by mass, the effect of improving the texture by the component (A) is saturated, This is because improvement cannot be expected. When the blending amount of the component (A) is 0.5 to 15% by mass, the desired texture improving effect can be obtained, and the viscosity of the thin paper treatment agent is not excessively high, and the thin paper treatment agent is transported or used. Good handling at the time. Furthermore, if the blending amount of the component (A) is 1 to 10% by mass, the smoothness and softness of the thin paper can be greatly improved.
［（Ｂ）成分：硫酸エステル系界面活性剤、スルホン酸系界面活性剤、アミノ酸型界面活性剤、炭素数８〜２２のアルコールのアルキレンオキシド付加型非イオン界面活性剤からなる群から選ばれる少なくとも１種］
（Ｂ）成分は、硫酸エステル系界面活性剤（以下、（ｂ１）成分）、スルホン酸系界面活性剤（以下、（ｂ２）成分）、アミノ酸型界面活性剤（以下、（ｂ３）成分）、炭素数８〜２２のアルコールのアルキレンオキシド付加型非イオン界面活性剤（以下、（ｂ４）成分）からなる群から選ばれる少なくとも１種である。中でも、（ｂ１）成分、（ｂ２）成分、（ｂ４）成分が好ましい。（Ｂ）成分を配合することで、薄葉紙処理剤は、薄葉紙の風合い改善が図れる。
[(B) component: at least selected from the group consisting of sulfate ester surfactants, sulfonic acid surfactants, amino acid surfactants, alkylene oxide addition nonionic surfactants of alcohols having 8 to 22 carbon atoms 1 type]
Component (B) is a sulfate ester surfactant (hereinafter referred to as component (b1)), a sulfonic acid surfactant (hereinafter referred to as component (b2)), an amino acid type surfactant (hereinafter referred to as component (b3)), It is at least one selected from the group consisting of an alkylene oxide addition type nonionic surfactant of an alcohol having 8 to 22 carbon atoms (hereinafter referred to as component (b4)). Among these, the component (b1), the component (b2), and the component (b4) are preferable. By blending the component (B), the thin paper treating agent can improve the texture of the thin paper.
＜（ｂ１）成分：硫酸エステル系界面活性剤＞
（ｂ１）成分である硫酸エステル系界面活性剤は、分子内に硫酸エステル基を含有するアニオン界面活性剤であり、例えば、アルキル硫酸塩、ポリオキシエチレンアルキルエーテル硫酸塩等が挙げられる。中でも、さらさら感の向上の観点から、アルキル硫酸塩、ポリオキシエチレンアルキルエーテル硫酸塩が好ましい。
アルキル硫酸塩のアルキル基の炭素数は特に限定されないが、例えば、平均炭素数８〜１８が好ましく、１２〜１５がより好ましい。上記範囲内であれば、後述する会合体粒子がより安定的に分散されるためである。
また、アルキル硫酸塩を構成する対イオンとしては、ナトリウム、カリウム等のアルカリ金属イオン；マグネシウム等のアルカリ土類金属；アンモニウムイオン；モノエタノールアミン、ジエタノールアミン、トリエタノールアミン等のアルカノールアミン等が挙げられる。
このようなアルキル硫酸塩の中でもラウリル硫酸ナトリウムが特に好ましい。
<(B1) component: sulfate ester-based surfactant>
The (b1) component sulfate ester surfactant is an anionic surfactant containing a sulfate ester group in the molecule, and examples thereof include alkyl sulfates and polyoxyethylene alkyl ether sulfates. Of these, alkyl sulfates and polyoxyethylene alkyl ether sulfates are preferred from the viewpoint of improving the smooth feeling.
Although carbon number of the alkyl group of an alkyl sulfate is not specifically limited, For example, 8-18 average carbon number is preferable and 12-15 are more preferable. This is because the aggregated particles described later are more stably dispersed within the above range.
The counter ions constituting the alkyl sulfate include alkali metal ions such as sodium and potassium; alkaline earth metals such as magnesium; ammonium ions; alkanolamines such as monoethanolamine, diethanolamine and triethanolamine. .
Among such alkyl sulfates, sodium lauryl sulfate is particularly preferable.
ポリオキシエチレンアルキルエーテル硫酸塩のアルキル基の炭素数は特に限定されず、例えば、平均炭素数８〜１８が好ましく、１２〜１６がより好ましい。上記範囲内であれば、後述する会合体粒子がより安定的に分散されるためである。
ポリオキシエチレンアルキルエーテル硫酸塩のエチレンオキサイド（ＥＯ）の付加モル数は特に限定されないが、例えば、平均付加モル数１〜３が好ましく、平均付加モル数３がより好ましい。上記範囲内であれば、後述する会合体粒子がより安定的に分散されるためである。
また、ポリオキシエチレンアルキルエーテル硫酸塩を構成する対イオンとしては、ナトリウム、カリウム等のアルカリ金属イオン；マグネシウム等のアルカリ土類金属；アンモニウムイオン；モノエタノールアミン、ジエタノールアミン、トリエタノールアミン等のアルカノールアミン等が挙げられる。
このようなポリオキシエチレンアルキルエーテル硫酸塩としては、ポリオキシエチレン（ＥＯ平均付加モル数１〜３）ラウリルエーテル硫酸ナトリウムが好ましく、ポリオキシエチレン（ＥＯ平均付加モル数３）ラウリルエーテル硫酸ナトリウムが特に好ましい。
The number of carbon atoms of the alkyl group of the polyoxyethylene alkyl ether sulfate is not particularly limited, and for example, an average carbon number of 8 to 18 is preferable, and 12 to 16 is more preferable. This is because the aggregated particles described later are more stably dispersed within the above range.
The number of moles of ethylene oxide (EO) added to the polyoxyethylene alkyl ether sulfate is not particularly limited. For example, the average number of moles added is preferably 1 to 3, and the average number of moles added 3 is more preferable. This is because the aggregated particles described later are more stably dispersed within the above range.
The counter ions constituting the polyoxyethylene alkyl ether sulfate include alkali metal ions such as sodium and potassium; alkaline earth metals such as magnesium; ammonium ions; alkanolamines such as monoethanolamine, diethanolamine and triethanolamine Etc.
As such polyoxyethylene alkyl ether sulfate, polyoxyethylene (EO average addition mole number 1 to 3) sodium lauryl ether sulfate is preferable, and polyoxyethylene (EO average addition mole number 3) sodium lauryl ether sulfate is particularly preferable. preferable.
＜（ｂ２）成分：スルホン酸系界面活性剤＞
（ｂ２）成分であるスルホン酸系界面活性剤は、スルホン酸塩基（−ＳＯ３Ｍ；Ｍは対イオンを示す。）を有する界面活性剤である。Ｍで表される対イオンとしては、ナトリウム、カリウム等のアルカリ金属イオン；マグネシウム等のアルカリ土類金属；アンモニウムイオン；モノエタノールアミン、ジエタノールアミン、トリエタノールアミン等のアルカノールアミン等が挙げられる。
（ｂ２）成分としては、例えば、アルキルベンゼンスルホン酸塩、α−オレフィンスルホン酸塩、アルカンスルホン酸塩、α−スルホ脂肪酸エステル塩等が挙げられる。中でも、さらさら感の向上の観点からα−オレフィンスルホン酸塩が好ましい。
<(B2) component: sulfonic acid surfactant>
The sulfonic acid surfactant as the component (b2) is a surfactant having a sulfonate group (—SO 3 M; M represents a counter ion). Examples of the counter ion represented by M include alkali metal ions such as sodium and potassium; alkaline earth metals such as magnesium; ammonium ions; alkanolamines such as monoethanolamine, diethanolamine and triethanolamine.
Examples of the component (b2) include alkylbenzene sulfonates, α-olefin sulfonates, alkane sulfonates, α-sulfo fatty acid ester salts, and the like. Among these, α-olefin sulfonate is preferable from the viewpoint of improving the smooth feeling.
（ｂ２）成分の構造中の炭素数は、好ましくは８〜２２、さらに好ましくは１０〜２０である。
（ｂ２）成分としては、例えば下記一般式によってそれぞれ表されるα−スルホ脂肪酸エステル塩（一般式（１））、α−オレフィンスルホン酸塩（一般式（２））、アルキルベンゼンスルホン酸塩（一般式（３））等が挙げられ、中でも、一般式（２）で表されるα−オレフィンスルホン酸塩が好ましい。
(B2) Carbon number in the structure of component becomes like this. Preferably it is 8-22, More preferably, it is 10-20.
Examples of the component (b2) include α-sulfo fatty acid ester salts (general formula (1)), α-olefin sulfonates (general formula (2)), alkylbenzene sulfonates (general (Alpha) -olefin sulfonate represented by General formula (2) is especially preferable.
［式中、Ｒ１、Ｒ２はそれぞれ独立してアルキル基を示し、Ｍ１は対イオンを示す。］ [Wherein, R 1, R 2 represents an alkyl group independently, M 1 is shows a counterion. ]
前記一般式（１）で表されるα−スルホ脂肪酸エステル塩において、Ｒ１の炭素数は８〜１８が好ましい。Ｒ２の炭素数は１〜６が好ましい。Ｍ１は、上記Ｍと同様のものが挙げられる。 In the α-sulfo fatty acid ester salt represented by the general formula (1), the carbon number of R 1 is preferably 8-18. The number of carbon atoms in R 2 is 1-6 are preferable. M 1 may be the same as M.
［式中、Ｒ３、Ｒ４はそれぞれ独立にアルキル基を示し、ｎは０以上の整数であり、Ｍ２、Ｍ３はそれぞれ独立に対イオンを示す。］ [Wherein, R 3 and R 4 each independently represents an alkyl group, n is an integer of 0 or more, and M 2 and M 3 each independently represent a counter ion. ]
前記一般式（２）で表されるα−オレフィンスルホン酸塩は、Ｒ３及びＲ４の炭素数は９〜１５が好ましい。ｎは０〜５が好ましい。Ｍ２及びＭ３は、上記Ｍと同様のものが挙げられる。
係るα−オレフィンスルホン酸塩は、アルケンスルホン酸塩（６０〜７０質量％）と、ヒドロキシアルカンスルホン酸塩（３０〜４０質量％）との混合物である。
また、係るα−オレフィンスルホン酸は、例えばエチレンのオリゴマー化、ｎ−パラフィンの脱水素化、アルコールの脱水、又は石油ワックスの熱分解で得られたα−オレフィンを３酸化イオウ等のスルホン化剤でスルホン化することにより得ることができる。
原料のα−オレフィンは、一般に炭素数の異なるオレフィンの混合物である。
なお、α−オレフィンスルホン酸は、前記α−オレフィンを３酸化イオウ等のスルホン化剤でスルホン化して得られるが、アルケンスルホン酸及びサルトンが生成し、当該サルトンはアルカリ性条件下で加水分解し、ヒドロキシアルカンスルホン酸が生じるため、これらの混合物となる。
また、前記α−オレフィンスルホン酸塩は、不純物または副生物として硫酸ナトリウム、ジスルホネート、未反応α−オレフィンを含むものを包含する。
In the α-olefin sulfonate represented by the general formula (2), R 3 and R 4 preferably have 9 to 15 carbon atoms. n is preferably 0 to 5. Examples of M 2 and M 3 are the same as those described above for M.
The α-olefin sulfonate is a mixture of an alkene sulfonate (60 to 70% by mass) and a hydroxyalkane sulfonate (30 to 40% by mass).
In addition, the α-olefin sulfonic acid is a sulfonating agent such as sulfur trioxide obtained from an α-olefin obtained by, for example, ethylene oligomerization, n-paraffin dehydrogenation, alcohol dehydration, or thermal decomposition of petroleum wax. It can be obtained by sulfonation with.
The raw material α-olefin is generally a mixture of olefins having different carbon numbers.
The α-olefin sulfonic acid is obtained by sulfonating the α-olefin with a sulfonating agent such as sulfur trioxide. Alken sulfonic acid and sultone are produced, and the sultone is hydrolyzed under alkaline conditions. Hydroxyalkanesulfonic acid is produced, resulting in a mixture of these.
The α-olefin sulfonates include those containing sodium sulfate, disulfonate, and unreacted α-olefin as impurities or by-products.
［式中、Ｒ５はアルキル基を示し、Ｍ４は対イオンを示す。］ [Wherein, R 5 represents an alkyl group, and M 4 represents a counter ion. ]
前記一般式（３）で表されるアルキルベンゼンスルホン酸塩において、Ｒ５の炭素数は１０〜１５が好ましい。Ｍ４は、上記Ｍと同様のものが挙げられる。 In the alkylbenzene sulfonate represented by the general formula (3), R 5 preferably has 10 to 15 carbon atoms. Examples of M 4 include the same as M described above.
＜（ｂ３）成分：アミノ酸型界面活性剤＞
（ｂ３）成分であるアミノ酸型界面活性剤は、アニオン部分としてカルボキシル基、カチオン部分としてアミノ基を有する両面界面活性剤であり、例えば、脂肪酸−Ｎ−メチルタウリン酸、脂肪酸アシル−Ｎ−グルタミン酸塩、脂肪酸−Ｎ−メチル−β−アラニン塩、脂肪酸−Ｎ−メチルグリシン塩、脂肪酸−Ｌ−アルギニン等が挙げられ、中でも、脂肪酸−Ｎ−メチルタウリン酸、脂肪酸アシル−Ｎ−グルタミン酸塩、脂肪酸−Ｎ−メチル−β−アラニン塩、脂肪酸−Ｎ−メチルグリシン塩が好ましい。
<(B3) Component: Amino Acid Type Surfactant>
The amino acid type surfactant which is the component (b3) is a double-sided surfactant having a carboxyl group as an anion moiety and an amino group as a cation moiety, such as fatty acid-N-methyltauric acid, fatty acid acyl-N-glutamate. , Fatty acid-N-methyl-β-alanine salt, fatty acid-N-methylglycine salt, fatty acid-L-arginine, etc., among others, fatty acid-N-methyltauric acid, fatty acid acyl-N-glutamate, fatty acid- N-methyl-β-alanine salt and fatty acid-N-methylglycine salt are preferred.
［（ｂ４）成分：炭素数８〜２２のアルコールのアルキレンオキシド付加型非イオン界面活性剤］
（ｂ４）成分は、炭素数８〜２２のアルコール（以下、高級アルコールということがある）のアルキレンオキシド付加物である、非イオン界面活性剤である。
高級アルコールは直鎖であってもよく、分岐鎖を有していてもよい。
高級アルコールとしては、例えば、オクチルアルコール、ラウリルアルコール、ミスチルアルコール、セチルアルコール、オクタデシルアルコール（ステアリルアルコール）、イソセチルアルコール、イソステアリルアルコール、オレイルアルコール、リノリルアルコール等が挙げられ、中でも、風合い改善効果の向上の観点から、ベヘニルアルコール、ステアリルアルコール、セチルアルコールが好ましい。
[Component (b4): Alkylene oxide addition type nonionic surfactant of alcohol having 8 to 22 carbon atoms]
The component (b4) is a nonionic surfactant that is an alkylene oxide adduct of an alcohol having 8 to 22 carbon atoms (hereinafter sometimes referred to as a higher alcohol).
The higher alcohol may be a straight chain or may have a branched chain.
Examples of higher alcohols include octyl alcohol, lauryl alcohol, mistyl alcohol, cetyl alcohol, octadecyl alcohol (stearyl alcohol), isocetyl alcohol, isostearyl alcohol, oleyl alcohol, and linoleyl alcohol. From the viewpoint of improving the above, behenyl alcohol, stearyl alcohol, and cetyl alcohol are preferable.
付加するＡＯの種類は特に限定されないが、エチレンオキサイド（ＥＯ）、プロピレンオキサイド（ＰＯ）、ブチレンオキサイド（ＢＯ）等から選ばれるアルキレンオキシド（ＡＯ）を単独あるいは、混合（ブロック、ランダム）付加したものが挙げられる。中でも、風合い向上の観点から、ＥＯの単独付加又はＥＯとＰＯとの混合付加が好ましく、ＥＯの単独付加がより好ましい。
ＡＯの付加モル数は、特に限定されないが平均付加モル数２〜５０が好ましく、平均付加モル数２〜４０がより好ましい。
The type of AO to be added is not particularly limited, but an alkylene oxide (AO) selected from ethylene oxide (EO), propylene oxide (PO), butylene oxide (BO), etc., alone or mixed (block, random) is added. Is mentioned. Among these, from the viewpoint of improving the texture, EO single addition or mixed addition of EO and PO is preferable, and EO single addition is more preferable.
The number of added moles of AO is not particularly limited, but an average added mole number of 2 to 50 is preferable, and an average added mole number of 2 to 40 is more preferable.
（ｂ４）成分のＨＬＢは特に限定されないが、１０以上であることが好ましい。このような（ｂ４）成分を用いることで、さらさら感の向上が図れるためである。なお、ＨＬＢは、Ｇｒｉｆｆｉｎの方法により求められる値である（吉田、進藤、大垣、山中共編、「新版界面活性剤ハンドブック」、工業図書株式会社、１９９１年、第２３４頁参照）。 The HLB of the component (b4) is not particularly limited, but is preferably 10 or more. This is because the use of such a component (b4) can improve the smooth feeling. In addition, HLB is a value calculated | required by the method of Griffin (see Yoshida, Shindo, Ogaki, Yamanaka co-edition, "New edition surfactant handbook", Kogyoshosho, 1991, 234 pages).
薄葉紙処理剤中の（Ｂ）成分の配合量は、処理対象とする薄葉紙の材質や求める品質、他の成分の配合量等を考慮して決定でき、例えば、０．２５〜２０質量％の範囲で決定することが好ましく、０．５〜１５質量％がより好ましく、１〜１０質量％がさらに好ましい。（Ｂ）成分の配合量が０．２５質量％未満であると、薄葉紙の風合い改善が図りにくいためである。（Ｂ）成分の配合量が２０質量％を超えても、（Ｂ）成分による風合い改善の効果が飽和し、さらなる風合いの向上が望めないと共に、薄葉紙処理剤の粘度が高くなりすぎて、使用上の不都合が大きくなるおそれがあるためである。加えて、（Ｂ）成分の配合量が０．５〜１５質量％であれば、目的とする風合い改善効果を得られると共に、薄葉紙処理剤の粘度が過度に高くならず、薄葉紙処理剤の輸送時や使用時における取り扱い（取り扱い性）が良好である。 The blending amount of the component (B) in the thin paper treating agent can be determined in consideration of the material and desired quality of the thin paper to be treated, the blending amount of other components, and the like, for example, in the range of 0.25 to 20% by mass. Is preferably determined, more preferably 0.5 to 15% by mass, and still more preferably 1 to 10% by mass. This is because it is difficult to improve the texture of the thin paper when the blending amount of the component (B) is less than 0.25% by mass. Even if the blending amount of the component (B) exceeds 20% by mass, the effect of improving the texture by the component (B) is saturated, and further improvement of the texture cannot be expected, and the viscosity of the thin paper treatment agent becomes too high. This is because the above inconvenience may increase. In addition, if the blending amount of the component (B) is 0.5 to 15% by mass, the desired texture improving effect can be obtained, and the viscosity of the thin paper treatment agent is not excessively increased. Good handling (handleability) during use and use.
［（Ｃ）成分：多価アルコール］
（Ｃ）成分は、多価アルコールである。（Ｃ）成分は親水性成分であり、主として基剤として機能する。また、（Ｃ）成分を配合することにより、薄葉紙の風合い、特に保湿性により、柔らかさ、しっとり感が向上する。
（Ｃ）成分は、２価以上のアルコールであれば特に限定することなく用いることができる。中でも２〜３価のアルコールが好ましく、特に３価のアルコールが好ましい。また、炭素数は、適度な親水性の確保によって保水力が向上し、風合いも向上することから、２〜１０であることが好ましい。
このような（Ｃ）成分としては、例えば、グリセリン、ジグリセリン、エチレングリコール、プロピレングリコール、１，３−ブチレングリコール、ポリグリセリン、ポリエチレングリコール、ポリプロピレングリコール、ソルビトール、キシリトール、エリスリトール等が挙げられ、中でもグリセリン、プロピレングリコール、１，３−ブチレングリコール、ポリエチレングリコールが好ましく、グリセリン、プロピレングリコール、ポリエチレングリコールがより好ましい。（Ｃ）成分は１種単独で又は２種以上を適宜組み合わせて使用できる。
[(C) component: polyhydric alcohol]
(C) A component is a polyhydric alcohol. The component (C) is a hydrophilic component and mainly functions as a base. Further, by blending the component (C), the softness and moist feeling are improved due to the texture of the thin paper, particularly the moisture retention.
The component (C) can be used without particular limitation as long as it is a dihydric or higher alcohol. Among these, a divalent alcohol is preferable, and a trivalent alcohol is particularly preferable. Further, the carbon number is preferably 2 to 10 because water retention is improved by ensuring appropriate hydrophilicity and texture is improved.
Examples of such component (C) include glycerin, diglycerin, ethylene glycol, propylene glycol, 1,3-butylene glycol, polyglycerin, polyethylene glycol, polypropylene glycol, sorbitol, xylitol, and erythritol. Glycerin, propylene glycol, 1,3-butylene glycol, and polyethylene glycol are preferable, and glycerin, propylene glycol, and polyethylene glycol are more preferable. (C) A component can be used individually by 1 type or in combination of 2 or more types.
薄葉紙処理剤中の（Ｃ）成分の配合量は、処理対象とする薄葉紙の材質や求める品質、他の成分の配合量等を考慮して決定でき、例えば、３０〜９９．５質量％の範囲で決定することが好ましい。上記範囲内とすることで、風合いとして柔らかさとさらさら感が両立する。また上限値以下とすることで会合体粒子が安定した分散状態となる。 The blending amount of the component (C) in the thin paper treating agent can be determined in consideration of the material of the thin paper to be treated, the desired quality, the blending amount of other components, and the like, for example, in the range of 30 to 99.5% by mass. It is preferable to determine by. By setting it within the above range, both softness and smooth feeling can be achieved. Moreover, the aggregated particles are in a stable dispersed state by being below the upper limit value.
［（Ｄ）成分：炭化水素基の炭素数が８〜２２のアルキレンオキシド付加型ソルビタン酸エステル］
（Ｄ）成分は、炭化水素基の炭素数が８〜２２のアルキレンオキシド付加型ソルビタン酸エステルである。（Ｄ）成分は、（Ｂ）成分と同じように界面活性剤の機能を有する、ものの、界面活性能が比較的低いため、単に（Ｂ）成分と置き換えても（Ａ）成分と安定な会合体粒子を形成し、分散安定化することができない。しかしながら、（Ｂ）成分に（Ｄ）成分を併用することで、会合体粒子をより安定に保つことができる。このため、液安定性を保ちつつ、さらさら感と柔らかさをより向上できる。（Ｄ）成分は、炭化水素基の炭素数が８〜２２の脂肪酸とアルキレンオキシドを付加したソルビタンとのエステル化合物であり、ツィーン又はポリソルベート類とも呼ばれる。
[Component (D): alkylene oxide addition type sorbitan acid ester having 8 to 22 carbon atoms of hydrocarbon group]
The component (D) is an alkylene oxide addition type sorbitan acid ester having 8 to 22 carbon atoms in the hydrocarbon group. The component (D) has the same surfactant function as the component (B), but its surface activity is relatively low, so even if it is simply replaced with the component (B), it is stable with the component (A). It is impossible to form coalesced particles and stabilize the dispersion. However, the aggregate particles can be kept more stable by using the component (D) in combination with the component (B). For this reason, a smooth feeling and softness can be improved more, maintaining liquid stability. The component (D) is an ester compound of a fatty acid having a hydrocarbon group having 8 to 22 carbon atoms and sorbitan to which an alkylene oxide is added, and is also referred to as a tween or polysorbate.
（Ｄ）成分のソルビタン脂肪酸エステルを構成する脂肪酸部は、その炭化水素基の炭素数が８〜２２であり、好ましくは１２〜１８である。
前記脂肪酸部の炭化水素基は、直鎖であってもよく分岐鎖であってもよい。
加えて、前記脂肪酸部は、飽和脂肪酸であってもよいし、不飽和脂肪酸であってもよい。
(D) The fatty acid part which comprises the sorbitan fatty acid ester of a component has 8-22 carbon atoms of the hydrocarbon group, Preferably it is 12-18.
The hydrocarbon group of the fatty acid part may be linear or branched.
In addition, the fatty acid part may be a saturated fatty acid or an unsaturated fatty acid.
このような（Ｄ）成分として、例えば、ラウリン酸、ステアリン酸、イソステアリン酸、パルミチン酸、オレイン酸、ヤシ油脂肪酸等の脂肪酸と、ＥＯ、ＰＯ、ＢＯ等のアルキレンオキシドを単独あるいは、混合（ブロック、ランダム）付加したアルキレンオキシド付加ソルビタンとのモノ−、ジ−、トリ−エステル化物及びこれらの混合物が挙げられる。中でも、ラウリン酸、パルミチン酸、ステアリン酸、イソステアリン酸もしくはヤシ油脂肪酸と、エチレンオキシド付加ソルビタンとのエステル化物又はこれらの混合物が好ましく、ラウリン酸、パルミチン酸もしくはステアリン酸と、エチレンオキシド付加ソルビタンのエステル化合物又はこれらの混合物がより好ましい。 As such component (D), for example, fatty acids such as lauric acid, stearic acid, isostearic acid, palmitic acid, oleic acid and coconut oil fatty acid, and alkylene oxides such as EO, PO and BO are used alone or in combination (blocked). (Random) mono-, di-, tri-esterified products with adducted alkylene oxide adsorbed sorbitan and mixtures thereof. Among them, an esterified product of lauric acid, palmitic acid, stearic acid, isostearic acid or coconut oil fatty acid and ethylene oxide-added sorbitan or a mixture thereof is preferable, and an ester compound of lauric acid, palmitic acid or stearic acid and ethylene oxide-added sorbitan or These mixtures are more preferred.
（Ｄ）成分に付加されているＡＯとしては、ＥＯが好ましい。
（Ｄ）成分のＥＯの平均付加モル数は特に限定されないが、平均付加モル数６〜１６０が好ましく、１０〜８０がより好ましく、１５〜６０がさらに好ましい。上記範囲内であれば、薄葉紙の滑らかさを向上できる。
As AO added to the component (D), EO is preferable.
(D) Although the average addition mole number of EO of a component is not specifically limited, 6-160 average addition mole number is preferable, 10-80 are more preferable, and 15-60 are more preferable. If it is in the said range, the smoothness of a thin paper can be improved.
薄葉紙処理剤中の（Ｄ）成分の配合量は、処理対象とする薄葉紙の材質や求める品質、他の成分の配合量等を勘案して決定でき、例えば、０．２５〜２０質量％の範囲で決定することが好ましく、０．５〜１５質量％がより好ましく、１〜１０質量％がさらに好ましい。０．２５質量％未満であると、薄葉紙の風合い改善効果の向上が図れず、２０質量％を超えて配合しても、風合い改善効果が飽和し、さらなる風合いの向上が望めないためである。 The blending amount of the component (D) in the thin paper treating agent can be determined in consideration of the material and desired quality of the thin paper to be treated, the blending amount of other components, and the like, for example, in the range of 0.25 to 20% by mass. Is preferably determined, more preferably 0.5 to 15% by mass, and still more preferably 1 to 10% by mass. If the amount is less than 0.25% by mass, the improvement of the texture improvement effect of the thin paper cannot be achieved, and even if the amount exceeds 20% by mass, the improvement effect of the texture is saturated and further improvement of the texture cannot be expected.
＜（Ｅ）成分：水＞
（Ｅ）成分である水は、特に限定されないが、水に含まれる不純物の影響を抑えるため、例えば、イオン交換水、純水等を使用することが好ましい。（Ｅ）成分を配合することで、薄葉紙処理剤の粘度が調節され、薄葉紙への塗布等の処理工程での取り扱いが容易になる。
薄葉紙処理剤中の（Ｅ）成分の配合量は、薄葉紙処理剤の粘度等を勘案して決定することができる。
<(E) component: water>
Although the water which is (E) component is not specifically limited, In order to suppress the influence of the impurity contained in water, it is preferable to use ion-exchange water, a pure water, etc., for example. (E) By mix | blending a component, the viscosity of a thin paper processing agent is adjusted and the handling in processing processes, such as application | coating to a thin paper, becomes easy.
The amount of component (E) in the thin paper treatment agent can be determined in consideration of the viscosity of the thin paper treatment agent.
［任意成分］
薄葉紙処理剤には、本発明の目的を損なわない範囲で、任意成分として、ポリシロキサン、油性成分、消泡剤、防腐剤、糖類等を配合することができる。
[Optional ingredients]
In the thin paper treating agent, polysiloxane, an oily component, an antifoaming agent, a preservative, saccharides, and the like can be blended as optional components within a range not impairing the object of the present invention.
＜ポリシロキサン＞
ポリシロキサン（以下、（Ｆ）成分ということがある）としては、例えば、ジメチルシリコーン、ジメチルシリコーンエマルジョン、ポリエーテル変性シリコーン、アミノ変性シリコーン、アミド変性シリコーン、フェニル変性シリコーン、アルキル変性シリコーン、カルビノール変性シリコーン、無機フィラー複合コンパウンド型シリコーン、カチオン性シリコーン及びこれらの混合物が挙げられる。薄葉紙処理剤は、（Ｆ）成分を配合することで、薄葉紙の摩擦を低減し、さらさら感をさらに向上できる。
（Ｆ）成分は、中でも、ジメチルシリコーン、ジメチルシリコーンエマルジョン、無機フィラー複合コンパウンド型シリコーン、ポリエーテル変性シリコーン、アミノ変性シリコーン又はこれらの混合物が好ましい。このような（Ｆ）成分を配合することで、風合い改善効果のさらなる向上が図れる。さらに、（Ｆ）成分としては、ジメチルシリコーン、ジメチルシリコーンエマルジョン、ポリエーテル変性シリコーン、アミノ変性シリコーン又はこれらの混合物がより好ましい。このような（Ｆ）成分を配合することで、製造時又は薄葉紙の処理時における薄葉紙処理剤の泡立ちを抑制できると共に、薄葉紙処理剤の液安定性の向上が図れる。
<Polysiloxane>
Examples of the polysiloxane (hereinafter sometimes referred to as the component (F)) include dimethyl silicone, dimethyl silicone emulsion, polyether-modified silicone, amino-modified silicone, amide-modified silicone, phenyl-modified silicone, alkyl-modified silicone, and carbinol-modified. Examples include silicone, inorganic filler composite compound type silicone, cationic silicone, and mixtures thereof. By adding the component (F), the thin paper treating agent can reduce the friction of the thin paper and further improve the smooth feeling.
The component (F) is preferably dimethyl silicone, dimethyl silicone emulsion, inorganic filler composite compound type silicone, polyether-modified silicone, amino-modified silicone, or a mixture thereof. By blending such a component (F), the texture improvement effect can be further improved. Furthermore, as the component (F), dimethyl silicone, dimethyl silicone emulsion, polyether-modified silicone, amino-modified silicone, or a mixture thereof is more preferable. By blending such a component (F), foaming of the thin paper treatment agent at the time of production or processing of the thin paper can be suppressed, and the liquid stability of the thin paper treatment agent can be improved.
薄葉紙処理剤中の（Ｆ）成分の配合量は、薄葉紙に求める風合いに応じて決定でき、例えば、０．０１〜１０質量％が好ましく、０．０５〜７．５質量％がより好ましく、０．１〜５質量％がさらに好ましい。（Ｆ）成分の配合量が０．０１質量％未満であると、目的とする風合い改善効果が得られにくく、１０質量％を超えても風合い改善効果が飽和し、さらなる風合いの向上が望めないためである。さらに、（Ｆ）成分の配合量が０．０５〜７．５質量％であれば、薄葉紙処理剤は、液安定性を維持しながら、薄葉紙の風合い改善効果の向上が図れる。 The blending amount of the component (F) in the thin paper treating agent can be determined according to the texture desired for the thin paper, and is preferably 0.01 to 10% by mass, more preferably 0.05 to 7.5% by mass, and 0 More preferably, the content is 1 to 5% by mass. When the blending amount of the component (F) is less than 0.01% by mass, it is difficult to obtain the desired texture improvement effect, and even if it exceeds 10% by mass, the texture improvement effect is saturated and further improvement in texture cannot be expected. Because. Furthermore, if the compounding quantity of (F) component is 0.05-7.5 mass%, the thin paper processing agent can aim at the improvement of the texture improvement effect of a thin paper, maintaining liquid stability.
＜油性成分＞
油性成分としては、流動パラフィン、ワセリン、スクワラン等の炭化水素類、ミツロウ等のろう類、ヒマシ油、パーム油、ヤシ油、オリーブ油等の植物油、卵黄油、ラード等の動物油等が挙げられる。中でも、流動パラフィン、ワセリン、スクワラン等の炭化水素類が好ましく、流動パラフィン、ワセリンが特に好ましい。このような油性成分を配合することで、薄葉紙の滑らかさを向上すると共に保湿力を向上する。加えて、薄葉紙への塗布等の処理工程において、薄葉紙処理剤の泡立ちを抑制できる。
<Oil component>
Examples of the oil component include hydrocarbons such as liquid paraffin, petrolatum and squalane, waxes such as beeswax, vegetable oils such as castor oil, palm oil, coconut oil and olive oil, animal oils such as egg yolk oil and lard. Of these, hydrocarbons such as liquid paraffin, petrolatum and squalane are preferred, and liquid paraffin and petrolatum are particularly preferred. By blending such an oil component, the smoothness of the thin paper is improved and the moisturizing power is improved. In addition, foaming of the thin paper processing agent can be suppressed in processing steps such as application to thin paper.
薄葉紙処理剤中の油性成分の配合量は、薄葉紙に求める風合いに応じて決定でき、例えば、０．０１〜１０質量％が好ましく、０．０５〜５質量％が好ましい。油脂成分の配合量が０．０１質量％未満であると風合い向上効果や泡立ち抑制の効果が発揮されにくく、１０質量％を超えても風合い改善の効果が飽和し、さらなる風合いの向上が望めないためである。さらに油性成分の配合量が０．０５〜５質量％であれば、薄葉紙処理剤は、液安定性を維持しながら、薄葉紙の風合い改善効果の向上が図れる。 The blending amount of the oil component in the thin paper treating agent can be determined according to the texture required for the thin paper, and is preferably 0.01 to 10% by mass, and preferably 0.05 to 5% by mass. If the blending amount of the oil and fat component is less than 0.01% by mass, the effect of improving the texture and the effect of suppressing foaming are hardly exhibited, and even if the amount exceeds 10% by mass, the effect of improving the texture is saturated and further improvement of the texture cannot be expected. Because. Furthermore, if the blending amount of the oil component is 0.05 to 5% by mass, the thin paper treating agent can improve the texture improving effect of the thin paper while maintaining the liquid stability.
＜消泡剤＞
消泡剤としては、エタノール等が挙げられ、中でもポリシロキサンが好ましい。消泡剤を配合することで、製造時又は薄葉紙の処理時における薄葉紙処理剤の泡立ちを抑制できる。
<Antifoaming agent>
Examples of the antifoaming agent include ethanol, and among them, polysiloxane is preferable. By blending the antifoaming agent, foaming of the thin paper processing agent during production or processing of the thin paper can be suppressed.
＜防腐剤＞
防腐剤としては、例えば、安息香酸塩、メチルパラベン、プロピルパラベン、ブチルパラベン等のオキシ安息香酸系；ヘキサヒドロ−１，３，５−トリス（２−ヒドロキシエチル）−Ｓ−トリアジンに代表される有機窒素系；１，２−ベンゾイソチアゾリン−３−オン、２−メチル−４−イソチアゾリン−３−オン、５−クロロ−２−メチル−４−イソチアゾリン−３−オン、２−ｎ−オクチル−４−イソチアゾリン、Ｎ−ブチル−１，２−ベンズイソチアゾリン−３−オン等に代表される有機窒素硫黄系；１，２−ビス（ブロモアセトキシ）エタン、２，２−ジブロモ−３−ニトリロプロピオンアミド、ビストリブロモメチルスルホンに代表されるような有機ブロム系；４，５−ジクロロ−１，２−ジチオール−３−オンに代表されるような有機硫黄系等の化合物を用いた防腐剤を用いることができる。
<Preservative>
Examples of the preservative include oxybenzoic acid series such as benzoate, methylparaben, propylparaben, and butylparaben; organic nitrogen represented by hexahydro-1,3,5-tris (2-hydroxyethyl) -S-triazine System; 1,2-benzisothiazolin-3-one, 2-methyl-4-isothiazolin-3-one, 5-chloro-2-methyl-4-isothiazolin-3-one, 2-n-octyl-4-isothiazoline Organic nitrogen sulfur-based compounds represented by N-butyl-1,2-benzisothiazolin-3-one; 1,2-bis (bromoacetoxy) ethane, 2,2-dibromo-3-nitrilopropionamide, bistribromo Organic bromine systems such as methylsulfone; as represented by 4,5-dichloro-1,2-dithiol-3-one Preservatives with a compound of organic sulfur, or the like can be used.
薄葉紙処理剤中の防腐剤の配合量は、特に限定されないが、例えば、０．００５〜２質量％が好ましく、０．０１〜０．５質量％がより好ましい。防腐剤の配合量が０．００５質量％未満であると防腐効果が得られにくく、２質量％を超えても防腐効果が飽和し、さらなる防腐効果の向上が望めないためである。さらに防腐剤の配合量が０．０１〜０．５質量％であると、防腐効果の達成と経済性とを両立できる。 Although the compounding quantity of the preservative in a thin paper processing agent is not specifically limited, For example, 0.005-2 mass% is preferable and 0.01-0.5 mass% is more preferable. This is because if the blending amount of the preservative is less than 0.005% by mass, it is difficult to obtain the antiseptic effect, and if it exceeds 2% by mass, the antiseptic effect is saturated and further improvement of the antiseptic effect cannot be expected. Furthermore, when the compounding amount of the preservative is 0.01 to 0.5% by mass, it is possible to achieve both the achievement of the antiseptic effect and the economy.
＜糖類＞
糖類としては、例えば、アラビノース、リボース、キシリトール、エリトリトール、グルコース、メチルグルコシド、マンノース、ガラクトース、フルクトース、ソルビトール、マルトース、ラクトース、スクロース、ラフィノース及びマルトトリオース、エリトリトール、キシリトール、グルコース等が挙げられる。これらの糖類は、１種単独で又は２種以上を適宜組み合わせて配合できる。
薄葉紙処理剤中の糖類の配合量は、特に限定されないが、例えば、０．００５〜１９．５質量％が好ましく、０．０１〜１５質量％がより好ましい。糖類の配合量が０．００５質量％未満であると、風合い向上効果が得られにくく、１９．５質量％を超えても、糖類の配合による風合い向上効果は飽和し、さらなる防腐効果の向上が望めないためである。
さらに、糖類の配合量が０．０１〜１５質量％であれば、薄葉紙処理剤は、液安定性を維持しながら、薄葉紙の風合い改善効果の向上が図れる。
<Sugar>
Examples of the saccharide include arabinose, ribose, xylitol, erythritol, glucose, methyl glucoside, mannose, galactose, fructose, sorbitol, maltose, lactose, sucrose, raffinose and maltotriose, erythritol, xylitol, glucose and the like. These saccharides can be blended singly or in appropriate combination of two or more.
Although the compounding quantity of the saccharide | sugar in a thin paper processing agent is not specifically limited, For example, 0.005-19.5 mass% is preferable and 0.01-15 mass% is more preferable. When the blending amount of the saccharide is less than 0.005% by mass, it is difficult to obtain a texture improving effect. It is because it cannot be expected.
Furthermore, if the compounding quantity of saccharides is 0.01-15 mass%, the thin paper processing agent can aim at the improvement of the texture improvement effect of thin paper, maintaining liquid stability.
＜その他＞
その他の任意成分としては、ビタミンＣやビタミンＥ等の抗酸化剤、香料、消臭剤、色素、エキス類等が挙げられる。
<Others>
Examples of other optional components include antioxidants such as vitamin C and vitamin E, fragrances, deodorants, pigments and extracts.
［配合比率］
薄葉紙処理剤中の（Ａ）成分、（Ｂ）成分、（Ｄ）成分の合計は、０．５〜６０質量％が好ましく、１〜５０質量％がより好ましく、２〜３０質量％がさらに好ましい。上記範囲内であれば、（Ａ）成分と、（Ｂ）成分との併用による効果、さらには（Ｄ）成分を併用する効果が十分に発揮され、薄葉紙の風合い改善が図れると共に、液安定性が図れる。
加えて、薄葉紙処理剤に（Ｅ）成分を配合する場合、薄葉紙処理剤中の（Ａ）成分、（Ｂ）成分、（Ｄ）成分の合計は、１〜６０質量％が好ましく、２〜５０質量％がより好ましく、４〜３０質量％がさらに好ましい。上記範囲内であれば、（Ａ）成分と、（Ｂ）成分との併用による効果、さらには（Ｄ）成分を併用する効果が十分に発揮され、薄葉紙の風合い改善が図れる。
[Combination ratio]
0.5-60 mass% is preferable, as for the sum total of (A) component in a thin paper processing agent, (B) component, (D) component, 1-50 mass% is more preferable, and 2-30 mass% is further more preferable. . If it is within the above range, the effect of the combined use of the component (A) and the component (B), and further the effect of using the component (D) in combination are sufficiently exhibited, and the texture of the thin paper can be improved and the liquid stability Can be planned.
In addition, when (E) component is mix | blended with a thin paper processing agent, 1-60 mass% is preferable, and the sum total of (A) component in a thin paper processing agent, (B) component, (D) component is 2-50. % By mass is more preferable, and 4 to 30% by mass is more preferable. If it is in the said range, the effect by combined use of (A) component and (B) component, and also the effect of using together (D) component will fully be exhibited, and the texture of thin paper can be improved.
薄葉紙処理剤における（Ａ）成分の配合比率は、（Ｄ）成分を配合しない場合、（Ａ）／［（Ａ）＋（Ｂ）］の質量比を０．０９〜０．９０、好ましくは０．１３〜０．８、さらに好ましくは０．２３〜０．７５の範囲とする。上記範囲内とすることで０．１〜５μｍ直径の会合体粒子を形成し、さらさら感に優れた風合いを付与する薄葉紙処理剤とすることができる。（Ａ）成分が下限未満では会合体粒子が形成されない場合があり、上限を超えると分散せずに凝集物となってしまうことがある。
また、薄葉紙処理剤に（Ｄ）成分を配合する場合には、（Ａ）／［（Ａ）＋（Ｂ）＋（Ｄ）］の質量比を０．０９〜０．９０、好ましくは０．１３〜０．８、さらに好ましくは０．２３〜０．７５の範囲とする。上記範囲内とすることで０．１〜５μｍ直径の会合体粒子を形成し、さらさら感に優れた風合いを付与する薄葉紙処理剤とすることができる。（Ａ）成分が下限値未満では会合体粒子が形成されない場合があり、上限値を超えると分散せずに凝集物となってしまうことがある。
The blending ratio of the component (A) in the thin paper treating agent is 0.09 to 0.90, preferably 0 when the (D) component is not blended, and the mass ratio of (A) / [(A) + (B)]. .13 to 0.8, and more preferably 0.23 to 0.75. By setting it within the above range, an aggregated particle having a diameter of 0.1 to 5 μm can be formed, and a thin paper treating agent imparting a texture with a smooth feeling can be obtained. When the component (A) is less than the lower limit, aggregate particles may not be formed. When the component exceeds the upper limit, the aggregate may be formed without being dispersed.
Moreover, when (D) component is mix | blended with a thin paper processing agent, mass ratio of (A) / [(A) + (B) + (D)] is 0.09-0.90, Preferably it is 0.8. The range is 13 to 0.8, more preferably 0.23 to 0.75. By setting it within the above range, an aggregated particle having a diameter of 0.1 to 5 μm can be formed, and a thin paper treating agent imparting a texture with a smooth feeling can be obtained. When the component (A) is less than the lower limit value, aggregate particles may not be formed. When the component exceeds the upper limit value, the aggregate particles may be formed without being dispersed.
薄葉紙処理剤における（Ｃ）成分の配合比率は、（Ｄ）成分を配合しない場合、（Ｃ）／［（Ａ）＋（Ｂ）＋（Ｃ）］の質量比を０．６０〜０．９９５、好ましくは０．７０〜０．９９、さらに好ましくは０．８０〜０．９８の範囲とする。上記範囲内とすることで、風合いとして柔らかさとさらさら感が両立する。また上限値以下とすることで会合体粒子が安定した分散状態となる。
また、薄葉紙処理剤に（Ｄ）成分を配合する場合には、（Ｃ）／［（Ａ）＋（Ｂ）＋（Ｃ）＋（Ｄ）］の質量比を０．６０〜０．９９５、好ましくは０．７０〜０．９９、さらに好ましくは０．８０〜０．９８の範囲とする。上記範囲内とすることで、風合いとして柔らかさとさらさら感が両立する。また上限値以下とすることで会合体粒子が安定した分散状態となる。
The blending ratio of the component (C) in the thin paper treating agent is such that when the component (D) is not blended, the mass ratio of (C) / [(A) + (B) + (C)] is 0.60 to 0.995. , Preferably 0.70 to 0.99, more preferably 0.80 to 0.98. By setting it within the above range, both softness and smooth feeling can be achieved. Moreover, the aggregated particles are in a stable dispersed state by being below the upper limit value.
When the component (D) is blended with the thin paper treating agent, the mass ratio of (C) / [(A) + (B) + (C) + (D)] is 0.60 to 0.995, The range is preferably 0.70 to 0.99, more preferably 0.80 to 0.98. By setting it within the above range, both softness and smooth feeling can be achieved. Moreover, the aggregated particles are in a stable dispersed state by being below the upper limit value.
薄葉紙処理剤に（Ｄ）成分を配合する場合、（Ｄ）成分の配合比率は（Ｄ）／［（Ｂ）＋（Ｄ）］の質量比を０．８０以下、好ましくは０．１０〜０．７０、さらに好ましくは０．２０〜０．５０の範囲とする。（Ｄ）成分の配合により、風合いとしてさらさら感と柔らかさがより両立する。上記上限値以下とすることにより所望の粒子径の会合体粒子を安定的に形成し、安定した分散状態とすることができる。 When (D) component is mix | blended with a thin paper processing agent, the mixture ratio of (D) component is 0.80 or less, preferably 0.10-0 of the mass ratio of (D) / [(B) + (D)]. .70, more preferably 0.20 to 0.50. By blending the component (D), the feeling of smoothness and softness are more compatible as a texture. By setting it to the upper limit value or less, aggregated particles having a desired particle diameter can be stably formed and a stable dispersed state can be obtained.
薄葉紙処理剤における（Ｅ）成分の配合比率は、（Ｅ）／［（Ｃ）＋（Ｅ）］の質量比を０．００１〜０．６０、好ましくは０．０１〜０．５０、より好ましくは０．０５〜０．３０の範囲とする。上記上限値以下とすることで０．１〜５μｍ直径の会合体粒子を安定的に形成し、安定した分散状態とすることができる。上記上限値を超える（Ｅ）成分を配合すると、会合体粒子の粒子径が大きくなり、薄葉紙処理剤が分離するおそれがある。 The blending ratio of the component (E) in the thin paper treating agent is a mass ratio of (E) / [(C) + (E)] of 0.001 to 0.60, preferably 0.01 to 0.50, more preferably. Is in the range of 0.05-0.30. By setting it to the upper limit or less, aggregated particles having a diameter of 0.1 to 5 μm can be stably formed, and a stable dispersed state can be obtained. When the component (E) exceeding the above upper limit is blended, the particle diameter of the aggregated particles becomes large and the thin paper treating agent may be separated.
［薄葉紙処理剤の製造方法］
薄葉紙処理剤の製造方法は、上述の各成分を混合又は分散媒に分散して製造することができる。混合又は分散は、公知の方法を用いることができる。
[Manufacturing method of thin paper treatment agent]
The method for producing the thin paper treating agent can be produced by mixing or dispersing the above-described components in a dispersion medium. A known method can be used for mixing or dispersing.
薄葉紙処理剤は、２０℃におけるｐＨが３〜９であることが好ましく、ｐＨ４〜８がより好ましい。ｐＨ３未満であると、薄葉紙処理剤中の各成分が加水分解され所望する風合い改善効果が得られない場合があると共に、薄葉紙処理剤で処理した薄葉紙の使用時に皮膚への刺激（皮膚刺激性）が懸念される。ｐＨ９を超えると、皮膚刺激性の懸念がある。ｐＨ４〜８であれば、肌に対してよりやさしく、低刺激になり好ましい。
薄葉紙処理剤のｐＨは、水酸化ナトリウム、塩酸、クエン酸等のｐＨ調整剤により調整できる。
The thin paper treating agent preferably has a pH of 3 to 9 at 20 ° C, more preferably a pH of 4 to 8. If the pH is less than 3, each component in the thin paper treatment agent may be hydrolyzed and the desired texture-improving effect may not be obtained, and skin irritation during use of the thin paper treated with the thin paper treatment agent (skin irritation) Is concerned. Above pH 9, there is a concern of skin irritation. A pH of 4 to 8 is preferable because it is gentler to the skin and less irritating.
The pH of the thin paper treating agent can be adjusted with a pH adjusting agent such as sodium hydroxide, hydrochloric acid, or citric acid.
（薄葉紙）
本発明の薄葉紙は、上述した薄葉紙処理剤で処理したものである。
薄葉紙処理剤を適用する薄葉紙は特に限定されず、従来公知の抄紙法で得られた紙を用いることができる。薄葉紙処理剤を適用する薄葉紙は、１プライであってもよいし、２プライ（２枚重ねで１組）、３プライ、４プライ又はそれ以上であってもよい。複数プライ（２プライ以上）とする場合、表面を構成する薄葉紙のみが薄葉紙処理剤で処理されていてもよいし、全ての薄葉紙が薄葉紙処理剤で処理されていてもよい。
(Thin paper)
The thin paper of the present invention is processed with the above-mentioned thin paper processing agent.
The thin paper to which the thin paper treating agent is applied is not particularly limited, and paper obtained by a conventionally known paper making method can be used. The thin paper to which the thin paper treating agent is applied may be one ply, two plies (one set of two stacked sheets), three plies, four plies or more. In the case of a plurality of plies (two or more plies), only the thin paper constituting the surface may be treated with the thin paper treating agent, or all the thin paper may be treated with the thin paper treating agent.
薄葉紙とは、ごく薄く漉いた紙（和紙、洋紙）を意味し、好ましくは秤量１０〜４５ｇ／ｍ２、さらに好ましくは１０〜２２ｇ／ｍ２のものである。このような薄葉紙としては、トイレットペーパーやティッシュペーパー、ペーパータオル等の家庭用、食器、包装、衛生等の業務用に用いるものが挙げられ、好ましくは家庭用薄葉紙である。ここで、家庭用薄葉紙とは、ティッシュペーパー、トイレットペーパー、ペーパータオル、生理用品、ちり紙等の総称とする。 Thin paper means very thin paper (Japanese paper, Western paper), preferably 10 to 45 g / m 2 , more preferably 10 to 22 g / m 2 . Examples of such thin paper include household paper such as toilet paper, tissue paper, and paper towel, and those used for business use such as tableware, packaging, and hygiene, and household thin paper is preferable. Here, household thin paper is a general term for tissue paper, toilet paper, paper towels, sanitary products, dust paper, and the like.
そして、好ましくは本発明に適用する薄葉紙処理剤をそのまま、又は必要に応じて水（好ましくはイオン交換水）で適宜希釈して二次処理剤とし、これを処理対象とする薄葉紙の表面に塗布し、乾燥すると、本発明の薄葉紙処理剤で処理してなる薄葉紙が得られる。 Preferably, the thin paper treatment agent applied to the present invention is used as it is or appropriately diluted with water (preferably ion exchange water) as a secondary treatment agent, and this is applied to the surface of the thin paper to be treated. When dried, a thin paper obtained by treating with the thin paper treating agent of the present invention is obtained.
薄葉紙処理剤の塗布量は、水を除いた有効成分換算質量で、薄葉紙の乾燥重量に対して１〜５０質量％、好ましくは５〜３０質量％、さらには１０〜２５質量％とすることが好ましい。上記下限値以上とすることにより、目的とする風合い向上効果が向上する。上記上限値以下にすることにより、シワ等薄葉紙の外観を損なう傾向を抑制できる。また、経済的に有利である。 The coating amount of the thin paper treatment agent is 1-50% by mass, preferably 5-30% by mass, and more preferably 10-25% by mass, based on the dry weight of the thin paper, in terms of active ingredient equivalent mass excluding water. preferable. By setting it to the above lower limit or more, the desired texture improving effect is improved. By setting it to the upper limit value or less, the tendency to impair the appearance of thin paper such as wrinkles can be suppressed. Moreover, it is economically advantageous.
塗布方法は、従来公知の方法、例えば、ロール転写法、スプレー塗布法等の任意の方法を採用できる。中でも、塗布量の安定、品質の安定、歩留まり向上の観点から、ロール転写法が好ましい。 As a coating method, a conventionally known method such as a roll transfer method or a spray coating method can be adopted. Among these, the roll transfer method is preferable from the viewpoint of stable coating amount, stable quality, and improved yield.
上述のとおり、本発明の薄葉紙処理剤で薄葉紙を処理することにより、柔らかさ、さらさら感等の風合いが良好な薄葉紙が得られる。
このような、薄葉紙の風合い向上は、（Ｃ）成分が薄葉紙に付着することで、薄葉紙に柔らかさを与え、発現する。さらに、（Ｃ）成分中で、主に（Ａ）成分と（Ｂ）成分とが会合体粒子を形成し、該会合体粒子が薄葉紙に付着する。会合体粒子の存在は、顕微鏡による観察で、薄葉紙処理剤中に直径０．１〜５μｍの粒子を確認できる。この会合体粒子が、薄葉紙の表面に存在することで、薄葉紙にパウダーを塗布したような、さらさら感を付与できる。薄葉紙処理剤は、会合体粒子の粒子径が比較的小さいため、該会合体粒子が均一に分散した状態を維持でき、高い液安定性を有する。さらに、さらさら感の付与のためのパウダー類を含有しないため、製造時、保管時又は使用時における分級を防止できる。
As described above, by treating the thin paper with the thin paper treating agent of the present invention, a thin paper having a good texture such as softness and smooth feeling can be obtained.
Such improved texture of the thin paper is manifested by imparting softness to the thin paper by the component (C) adhering to the thin paper. Further, in the component (C), the component (A) and the component (B) mainly form aggregate particles, and the aggregate particles adhere to the thin paper. Presence of the aggregated particles can be confirmed by observation with a microscope with particles having a diameter of 0.1 to 5 μm in the thin paper treating agent. The presence of the aggregate particles on the surface of the thin paper can give a smooth feeling as if the powder was applied to the thin paper. Since the particle size of the aggregated particles is relatively small, the thin paper treating agent can maintain a state where the aggregated particles are uniformly dispersed, and has high liquid stability. Furthermore, since powders for imparting a smooth feeling are not contained, classification during production, storage, or use can be prevented.
本発明の薄葉紙処理剤は、家庭で使用される家庭用薄葉紙の処理に適している。本発明の薄葉紙処理剤で処理した薄葉紙は、例えばパーソナルケア用途及び家庭用品クリーニングに好適な拭き取り製品、ティッシュ等の紙製品（薄葉紙）等に好適に利用することができる。 The tissue paper treating agent of the present invention is suitable for processing household tissue paper used at home. The thin paper treated with the thin paper treating agent of the present invention can be suitably used for, for example, wipe products suitable for personal care use and household goods cleaning, paper products such as tissue (thin paper), and the like.
以下に実施例を用いて本発明をさらに詳しく説明するが、本発明はこれら実施例に限定されるものではない。
（使用原料）
以下に、実施例に用いた使用原料を示す。
Hereinafter, the present invention will be described in more detail using examples, but the present invention is not limited to these examples.
(Raw material)
The raw materials used in the examples are shown below.
［（Ａ）成分：炭化水素基の炭素数が１４〜２２であり、融点が２０℃以上であるアルキレンオキシドが付加されていないソルビタン脂肪酸エステル］
・（Ａ−１）モノステアリン酸ソルビタン：ＥＭＡＬＥＸ ＳＰＥ−１００Ｓ、日本エマルジョン株式会社製
・（Ａ−２）モノパルミチン酸ソルビタン：ＮＩＫＫＯＬ ＳＰ−１０Ｖ、日光ケミカルズ株式会社製
[Component (A): Sorbitan fatty acid ester to which an alkylene oxide having a hydrocarbon group having 14 to 22 carbon atoms and a melting point of 20 ° C. or higher is not added]
(A-1) sorbitan monostearate: EMALEX SPE-100S, manufactured by Nippon Emulsion Co., Ltd. (A-2) sorbitan monopalmitate: NIKKOL SP-10V, manufactured by Nikko Chemicals Co., Ltd.
［（Ａ’）成分：（Ａ）成分の比較品］
・（Ａ’−１）ヤシ油脂肪酸ソルビタン：ＮＩＫＫＯＬ ＳＬ−１０ 日光ケミカルズ株式会社製
[(A ′) component: comparative product of component (A)]
・ (A'-1) Coconut oil fatty acid sorbitan: NIKKOL SL-10 manufactured by Nikko Chemicals Co., Ltd.
［（Ｂ）成分：硫酸エステル系界面活性剤、スルホン酸系界面活性剤、アミノ酸型界面活性剤、炭素数８〜２２のアルコールのアルキレンオキシド付加型非イオン界面活性剤からなる群から選ばれる少なくとも１種］
・（Ｂ−１）α−オレフィンスルホン酸ナトリウム：（ｂ２）成分、Ｋリポラン ＰＪ−４００、ライオン株式会社製
・（Ｂ−２）ポリオキシエチレン（ＥＯ３）ラウリルエーテル硫酸ナトリウム：（ｂ１）成分、テイカポールＮＥ−１２７０（純分；７０質量％、水分；３０質量％）、テイカ株式会社製
・（Ｂ−３）ラウリン酸−Ｎメチルグリシン塩：（ｂ３）成分、ソイポンＳＬＰ、川研ファインケミカル株式会社製
・（Ｂ−４）ポリオキシエチレン（ＥＯ３０）ステアリルエーテル：（ｂ４）成分、エマレックス６３０、日本エマルジョン株式会社製
・（Ｂ−５）ポリオキシエチレン（ＥＯ３０）セチルエーテル：（ｂ４）成分、エマレックス１３０、日本エマルジョン株式会社製
・（Ｂ−６）ポリオキシエチレン（ＥＯ２５）イソセチルエーテル：（ｂ４）成分、エマレックス１６２５、日本エマルジョン株式会社製
[(B) component: at least selected from the group consisting of sulfate ester surfactants, sulfonic acid surfactants, amino acid surfactants, alkylene oxide addition nonionic surfactants of alcohols having 8 to 22 carbon atoms 1 type]
(B-1) sodium α-olefin sulfonate: (b2) component, K lipolane PJ-400, manufactured by Lion Corporation. (B-2) polyoxyethylene (EO3) sodium lauryl ether sulfate: (b1) component, Teikapol NE-1270 (pure content: 70% by mass, moisture: 30% by mass), manufactured by Teika Co., Ltd. (B-3) Lauric acid-N methylglycine salt: (b3) component, Soypon SLP, Kawaken Fine Chemical Co., Ltd. (B-4) Polyoxyethylene (EO30) stearyl ether: (b4) component, Emalex 630, manufactured by Nippon Emulsion Co., Ltd. (B-5) Polyoxyethylene (EO30) cetyl ether: (b4) component, EMALEX 130, manufactured by Nippon Emulsion Co., Ltd. (B-6) Polyoxyethylene (EO25) Iso Chirueteru: (b4) component, Emma Rex 1625, manufactured by Nippon Emulsion Co., Ltd.
［（Ｃ）成分：多価アルコール］
・（Ｃ−１）グリセリン：食品添加物グリセリン（水分；０．１質量％）、ライオン株式会社製
・（Ｃ−２）ポリエチレングリコール：ＰＥＧ＃３００Ｋ、ライオン株式会社製
・（Ｃ−３）プロピレングリコール：プロピレングリコール、旭硝子株式会社製
[(C) component: polyhydric alcohol]
・ (C-1) Glycerin: Food additive glycerin (water content: 0.1% by mass), manufactured by Lion Corporation ・ (C-2) Polyethylene glycol: PEG # 300K, manufactured by Lion Corporation ・ (C-3) Propylene Glycol: Propylene glycol, manufactured by Asahi Glass Co., Ltd.
［（Ｄ）成分：炭化水素基の炭素数が８〜２２のアルキレンオキシド付加型ソルビタン脂肪酸エステル］
・（Ｄ−１）モノラウリン酸ポリオキシエチレンソルビタン（ＥＯ２０）：ノニオン ＬＴ−２２１、日本油脂株式会社製
・（Ｄ−２）モノパルミチン酸ポリオキシエチレンソルビタン（ＥＯ２０）：ＮＩＫＫＯＬ ＴＰ−１０ＥＸ、日光ケミカルズ株式会社製
・（Ｄ−３）モノステアリン酸ポリオキシエチレンソルビタン（ＥＯ６）：ＮＩＫＫＯＬ ＴＳ−１０６Ｖ、日光ケミカルズ株式会社製
[(D) component: alkylene oxide addition type sorbitan fatty acid ester having 8 to 22 carbon atoms of hydrocarbon group]
(D-1) Polyoxyethylene sorbitan monolaurate (EO20): Nonion LT-221, manufactured by NOF Corporation (D-2) Polyoxyethylene sorbitan monopalmitate (EO20): NIKKOL TP-10EX, Nikko Chemicals (D-3) Polyoxyethylene sorbitan monostearate (EO6): NIKKOL TS-106V, manufactured by Nikko Chemicals
［（Ｅ）成分：水］
（Ｅ）成分には、イオン交換水を用いた。
[(E) component: water]
(E) Ion exchange water was used for the component.
［（Ｆ）成分：ポリキシロサン］
・（Ｆ−１）ポリエーテルシリコーン：ＳＨ３７７１Ｍ、東レダウコーニング株式会社製
・（Ｆ−２）シリコンエマルジョン：ＫＭ−７０、信越化学工業株式会社製
[(F) component: polyxylosan]
(F-1) Polyether silicone: SH3771M, manufactured by Toray Dow Corning Co., Ltd. (F-2) Silicone emulsion: KM-70, manufactured by Shin-Etsu Chemical Co., Ltd.
（評価方法）
［薄葉紙風合い評価］
各例の薄葉紙処理剤を４０℃の恒温槽に２時間保存した。これをスプレー容器に入れ、未処理のティッシュペーパー（未処理薄葉紙：坪量１２ｇ／ｍ２の２プライ品、大王製紙株式会社製のティッシュペーパー「エリエール」（商品名）、寸法；縦１９７ｍｍ×横２２９ｍｍ）に、スプレーで均一に塗布した後、恒温恒湿室（温度２５℃、湿度６５％ＲＨ）内で２４時間放置して乾燥処理し、評価用薄葉紙を得た。薄葉紙処理剤の塗布量は、前記評価用薄葉紙の質量が、前記未処理薄葉紙の質量の１１０％となるように調整した。このように得られた評価用薄葉紙について、風合いを評価した。
薄葉紙風合い評価は、５人のパネラが、評価用薄葉紙のさらさら感と柔らかさについて、官能評価を行った。官能評価は、下記評価基準に従い、評価用薄葉紙と未処理薄葉紙との比較により評価した。
(Evaluation methods)
[Thin paper texture evaluation]
The thin paper treating agent of each example was stored in a constant temperature bath at 40 ° C. for 2 hours. This is put in a spray container, untreated tissue paper (untreated thin paper: 2-ply product with a basis weight of 12 g / m 2 , tissue paper “Erière” (trade name) manufactured by Daio Paper Co., Ltd., dimensions: 197 mm × width 229 mm), and uniformly applied by spraying, left to dry in a constant temperature and humidity chamber (temperature 25 ° C., humidity 65% RH) for 24 hours to obtain a thin paper for evaluation. The amount of the thin paper treating agent applied was adjusted so that the mass of the evaluation thin paper was 110% of the mass of the untreated thin paper. The texture of the thin paper for evaluation thus obtained was evaluated.
In the evaluation of the texture of the thin paper, five panelists performed a sensory evaluation on the smoothness and softness of the thin paper for evaluation. The sensory evaluation was evaluated by comparing the thin paper for evaluation with the untreated thin paper according to the following evaluation criteria.
＜評価基準＞
対象品に比べ、極めて良好 ：４点
対象品に比べ、良好 ：３点
対象品に比べ、やや良好 ：２点
対象品と同等以下 ：１点
<Evaluation criteria>
Very good compared to the target product: 4 points Good compared to the target product: 3 points Slightly better than the target product: 2 points Less than or equal to the target product: 1 point
そして、この得られた５人分の点数を合計し、以下の基準で◎〜×を判定した。
＜判定基準＞
合計１７点以上〜２０点 ：◎
合計１４点以上〜１７点未満 ：○〜◎
合計１１点以上〜１４点未満 ：○
合計８点以上〜１１点未満 ：△
合計５点以上〜８点未満 ：×
Then, the scores for the five persons obtained were totaled, and ◎ to × were determined according to the following criteria.
<Criteria>
Total 17 points to 20 points: ◎
14 points or more and less than 17 points in total: ○ to ◎
Total 11 points or more and less than 14 points: ○
8 points or more and less than 11 points in total: △
Total 5 points or more and less than 8 points: ×
［液安定性の評価］
薄葉紙処理剤を２５℃条件下で、１日間保存し、分離の有無を目視で判定し、下記の基準で評価した。
＜評価基準＞
乳白色均一で分離なし ：◎
ほぼ均一で分離なし ：○
僅かに分離が認められる：△
完全に分離している ：×
[Evaluation of liquid stability]
The thin paper treating agent was stored at 25 ° C. for 1 day, visually judged for the presence or absence of separation, and evaluated according to the following criteria.
<Evaluation criteria>
Milky white uniform and no separation: ◎
Almost uniform and no separation: ○
Slight separation is observed:
Fully separated: ×
［粒子径の測定］
光学顕微鏡（オリンパス株式会社製）を用いて、会合体粒子の粒子径を測定した。測定値は、観察される粒子２０個の粒子直径を計測し、その平均値として求めた。なお、表中、２５℃で流動性がなく固化したものは「固体」と表示した。
[Measurement of particle size]
The particle diameter of the aggregated particles was measured using an optical microscope (manufactured by Olympus Corporation). The measured value was obtained as an average value obtained by measuring the diameter of 20 observed particles. In the table, a solidified product having no fluidity at 25 ° C. was indicated as “solid”.
（実施例１〜６）
表１の組成に従い、２００ｍｌビーカーに、（Ｃ）成分、（Ａ）成分、（Ｂ）成分の順に所定量を投入し、油浴中で７０℃まで加温し、攪拌・混合した。この時、ｐＨが３〜９の範囲外であった場合は、１Ｎ水酸化ナトリウム又はクエン酸を用いてｐＨを調整し、目的とする薄葉紙処理剤を得た。得られた薄葉紙処理剤について、薄葉紙風合い評価、液安定性評価を行った。なお、表中、（Ｂ−２）成分は、純分としての組成を記載し、（Ｂ−２）に含まれる水分は、イオン交換水と併せて（Ｅ）成分として記載した（以降において同じ）。
(Examples 1-6)
In accordance with the composition shown in Table 1, predetermined amounts of component (C), component (A) and component (B) were charged in a 200 ml beaker in this order, heated to 70 ° C. in an oil bath, and stirred and mixed. At this time, when the pH was out of the range of 3 to 9, the pH was adjusted with 1N sodium hydroxide or citric acid to obtain the intended thin paper treatment agent. About the obtained thin paper processing agent, thin paper texture evaluation and liquid stability evaluation were performed. In the table, the component (B-2) describes the composition as a pure component, and the water contained in (B-2) is described as the component (E) together with ion-exchanged water (the same applies hereinafter). ).
（実施例７〜９、１４〜１７、２１）
表１〜３の組成に従い、（Ｂ）成分投入の後、さらに（Ｄ）成分、（Ｅ）成分を投入した以外は実施例１と同様に薄葉紙処理剤を調製し、薄葉紙風合い評価、液安定性評価を行った。
(Examples 7-9, 14-17, 21)
According to the composition of Tables 1 to 3, after the component (B) was added, a thin paper treatment agent was prepared in the same manner as in Example 1 except that the component (D) and the component (E) were added. Sex evaluation was performed.
（実施例１０〜１３）
表２の組成に従い、（Ｂ）成分投入の後、さらに（Ｅ）成分を投入した以外は実施例１と同様に薄葉紙処理剤を調製し、薄葉紙風合い評価、液安定性評価を行った。
(Examples 10 to 13)
According to the composition of Table 2, a thin paper treating agent was prepared in the same manner as in Example 1 except that the component (E) was further added after the component (B) was added, and the texture evaluation and the liquid stability were evaluated.
（実施例１８）
表３の組成に従い、（Ｂ）成分投入の後、さらに（Ｄ）成分、（Ｅ）成分、（Ｆ）成分を配合した以外は実施例１と同様に薄葉紙処理剤を調製し、薄葉紙風合い評価、液安定性評価を行った。
(Example 18)
According to the composition of Table 3, a thin paper treating agent was prepared in the same manner as in Example 1 except that (D) component, (E) component, and (F) component were further blended after component (B) was added, and the texture of the thin paper was evaluated. The liquid stability was evaluated.
（実施例１９）
表３の組成に従い、２００ｍｌビーカーに、（Ａ）成分、（Ｂ）成分、（Ｄ）成分の順に所定量を投入し、油浴中で６０℃まで加温し、攪拌・混合した。その後、この混合物と等量の（Ｃ）成分を６０℃に加温し、これに、（Ａ）成分と（Ｂ）成分と（Ｄ）成分の混合物を撹拌下で添加した。さらに、残りの（Ｃ）成分を添加した。この時、ｐＨが３〜９の範囲外であった場合は、１Ｎ水酸化ナトリウム又はクエン酸を用いてｐＨを調整し、目的とする薄葉紙処理剤を得た。得られた薄葉紙処理剤について、薄葉紙風合い評価、液安定性評価を行った。
(Example 19)
In accordance with the composition of Table 3, predetermined amounts of component (A), component (B), and component (D) were charged in a 200 ml beaker in this order, heated to 60 ° C. in an oil bath, and stirred and mixed. Thereafter, an equivalent amount of the component (C) to this mixture was heated to 60 ° C., and a mixture of the component (A), the component (B), and the component (D) was added thereto with stirring. Further, the remaining component (C) was added. At this time, when the pH was out of the range of 3 to 9, the pH was adjusted with 1N sodium hydroxide or citric acid to obtain the intended thin paper treatment agent. About the obtained thin paper processing agent, thin paper texture evaluation and liquid stability evaluation were performed.
（実施例２０）
残りの（Ｃ）成分を添加した後、さらに（Ｅ）成分を配合した以外は、実施例１９と同様にして薄葉紙処理剤を得た。得られた薄葉紙処理剤について、薄葉紙風合い評価、液安定性評価を行った。
(Example 20)
After adding the remaining component (C), a thin paper treating agent was obtained in the same manner as in Example 19 except that the component (E) was further added. About the obtained thin paper processing agent, thin paper texture evaluation and liquid stability evaluation were performed.
（比較例１）
表３の組成に従い、２００ｍｌビーカーに、（Ｃ）成分を配合しないことを除き実施例１と同様に薄葉紙処理剤を調製し、薄葉紙風合い評価、液安定性評価を行った。
(Comparative Example 1)
According to the composition of Table 3, a thin paper treatment agent was prepared in the same manner as in Example 1 except that the component (C) was not blended in a 200 ml beaker, and a thin paper texture evaluation and liquid stability evaluation were performed.
（比較例２）
表３の組成に従い、２００ｍｌビーカーに、（Ｂ）成分を配合しないことを除き実施例１と同様に薄葉紙処理剤を調製し、薄葉紙風合い評価、液安定性評価を行った。
(Comparative Example 2)
According to the composition of Table 3, a thin paper treatment agent was prepared in the same manner as in Example 1 except that the component (B) was not blended in a 200 ml beaker, and a thin paper texture evaluation and liquid stability evaluation were performed.
（比較例３）
表３の組成に従い、２００ｍｌビーカーに、（Ａ）成分を配合しないことを除き実施例１と同様に薄葉紙処理剤を調製し、薄葉紙風合い評価、液安定性評価を行った。
(Comparative Example 3)
According to the composition of Table 3, a thin paper treatment agent was prepared in the same manner as in Example 1 except that the component (A) was not blended in a 200 ml beaker, and the evaluation of the thin paper texture and the liquid stability were performed.
（比較例４〜９）
表４の組成に従い、（Ｃ）成分を添加した後に、イオン交換水を配合した以外は実施例１と同様に薄葉紙処理剤を調製し、薄葉紙風合い評価、液安定性評価を行った。
(Comparative Examples 4 to 9)
According to the composition of Table 4, after adding the component (C), a thin paper treatment agent was prepared in the same manner as in Example 1 except that ion-exchanged water was added, and a thin paper texture evaluation and liquid stability evaluation were performed.
（比較例１０）
表４の組成に従い、（Ａ）成分に換えて、（Ａ’）成分を配合した以外は、実施例１と同様に薄葉紙処理剤を調製し、薄葉紙風合い評価、液安定性評価を行った。
(Comparative Example 10)
According to the composition of Table 4, a thin paper treating agent was prepared in the same manner as in Example 1 except that the component (A ′) was blended in place of the component (A), and the texture of the thin paper was evaluated and the liquid stability was evaluated.
（比較例１１）
表４の組成に従い、２００ｍｌビーカーに、（Ａ）成分、（Ｄ）成分の順に所定量秤取り、油浴中で６０℃まで加温し、攪拌・混合した。その後、（Ａ）成分、（Ｄ）成分を合わせたものに、６０℃に加温した（Ｃ）成分を添加した。この混合物と等量のイオン交換水を６０℃に加温し、これに、（Ａ）成分と（Ｄ）成分の混合物を撹拌下で添加した。さらに、残りの（Ｅ）成分を添加した。この時、ｐＨが３〜９の範囲外であった場合は、１Ｎ水酸化ナトリウム又はクエン酸を用いてｐＨを調整し、目的とする薄葉紙処理剤を得た。得られた薄葉紙処理剤について、薄葉紙風合い評価、液安定性評価を行った。
(Comparative Example 11)
According to the composition shown in Table 4, a predetermined amount of component (A) and component (D) was weighed in a 200 ml beaker in this order, heated to 60 ° C. in an oil bath, stirred and mixed. Then, (C) component heated at 60 degreeC was added to what combined (A) component and (D) component. An equivalent amount of ion-exchanged water to this mixture was heated to 60 ° C., and a mixture of the component (A) and the component (D) was added thereto with stirring. Furthermore, the remaining (E) component was added. At this time, when the pH was out of the range of 3 to 9, the pH was adjusted with 1N sodium hydroxide or citric acid to obtain the intended thin paper treatment agent. About the obtained thin paper processing agent, thin paper texture evaluation and liquid stability evaluation were performed.
表１〜４において、（Ｄ）成分を含まない薄葉紙処理剤において、（Ａ）／［（Ａ）＋（Ｂ）＋（Ｄ）］質量比は（Ａ）／［（Ａ）＋（Ｂ）］質量比を表し、（Ｃ）／［（Ａ）＋（Ｂ）＋（Ｃ）＋（Ｄ）］質量比は（Ｃ）／［（Ａ）＋（Ｂ）＋（Ｃ）］質量比を表す。
表１〜４に示すとおり、本発明の薄葉紙処理剤及び該薄葉紙処理剤で処理した薄葉紙である実施例１〜２１は、いずれも液安定性を損なうことなく、さらさら感、柔らかさ共に評価「○」以上であり、薄葉紙の風合いを向上できた。加えて、実施例１〜２１は、粒子径０．５〜４．１μｍの粒子（会合体粒子）が確認できた。
（Ｃ）成分を配合していない比較例１は、会合体粒子の粒子径が２５μｍであり、さらさら感、柔らかさの評価が共に「×」であった。一方、（Ｃ）／［（Ａ）＋（Ｂ）＋（Ｃ）＋（Ｄ）］質量比を０．９９５超とした比較例７、８では、会合体粒子を確認できず、さらさら感、柔らかさの評価が共に「×」であった。
（Ａ）／［（Ａ）＋（Ｂ）＋（Ｄ）］質量比を０．０９未満とした比較例３、４では、いずれも会合体粒子の存在を確認できず、さらさら感、柔らかさの評価は実施例１〜２１に比べて劣るものであった。（Ａ）／［（Ａ）＋（Ｂ）＋（Ｄ）］質量比を０．９０超とした比較例２、５、６、９では、会合体粒子の粒子径が１０００μｍ以上あるいは薄葉紙処理剤が固化した。
（Ａ）成分に換えて、炭化水素基の炭素数が８〜１２の（Ａ’−１）を配合した比較例１０では、会合体粒子の存在を確認できず、さらさら感、柔らかさの評価は実施例１〜２１に比べて劣るものであった。また、（Ｂ）成分を配合せず、（Ｄ）成分を配合した比較例１１では、粒子径５０μｍの会合体粒子を確認できたが、液安定性は「×」であり、風合い評価は「△」又は「×」であった。
以上の結果から、本発明の薄葉紙処理剤は、（Ａ）〜（Ｃ）成分を特定の比率で配合することで、適切な粒子径の会合体粒子が形成され、風合いの向上が図れることが判った。
In Tables 1-4, (A) / [(A) + (B) + (D)] mass ratio is (A) / [(A) + (B) in the thin paper processing agent which does not contain (D) component. ] Represents a mass ratio, and (C) / [(A) + (B) + (C) + (D)] mass ratio represents (C) / [(A) + (B) + (C)] mass ratio. To express.
As shown in Tables 1 to 4, Examples 1 to 21 which are the thin paper treatment agent of the present invention and the thin paper treated with the thin paper treatment agent were evaluated for both smooth feeling and softness without impairing the liquid stability. ○ ”and above, and the texture of thin paper was improved. In addition, in Examples 1 to 21, particles (aggregate particles) having a particle size of 0.5 to 4.1 μm were confirmed.
In Comparative Example 1 in which the component (C) was not blended, the particle size of the aggregated particles was 25 μm, and both the smooth feeling and the evaluation of softness were “x”. On the other hand, in Comparative Examples 7 and 8 in which the mass ratio of (C) / [(A) + (B) + (C) + (D)] was more than 0.995, the aggregated particles could not be confirmed, Both of the evaluations of softness were “x”.
In Comparative Examples 3 and 4 in which the mass ratio (A) / [(A) + (B) + (D)] was less than 0.09, the presence of aggregated particles could not be confirmed, and the feeling of smoothness and softness was not observed. Evaluation of was inferior to Examples 1-21. In Comparative Examples 2, 5, 6, and 9 in which the mass ratio (A) / [(A) + (B) + (D)] exceeds 0.90, the aggregate particle size is 1000 μm or more, or a thin paper treatment agent Solidified.
In Comparative Example 10 in which (A′-1) having 8 to 12 carbon atoms in the hydrocarbon group was used in place of the component (A), the presence of the aggregated particles could not be confirmed, and the smoothness and softness were evaluated. Was inferior to Examples 1-21. Further, in Comparative Example 11 in which the component (B) was not blended and the component (D) was blended, aggregated particles having a particle diameter of 50 μm were confirmed, but the liquid stability was “x”, and the texture evaluation was “ Δ ”or“ × ”.
From the above results, the thin paper treating agent of the present invention can form aggregated particles having an appropriate particle size and improve the texture by blending the components (A) to (C) at a specific ratio. understood.
Claims (4)
（Ａ）成分：炭化水素基の炭素数が１４〜２２であり、融点が２０℃以上であるアルキレンオキシドが付加されていないソルビタン脂肪酸エステル
（Ｂ）成分：硫酸エステル系界面活性剤、スルホン酸系界面活性剤、アミノ酸型界面活性剤、炭素数８〜２２のアルコールのアルキレンオキシド付加型非イオン性界面活性剤からなる群から選ばれる少なくとも１種
（Ｃ）成分：多価アルコール The following (A) component, (B) component, and (C) component are contained, and the mass ratio represented by (A) / [(A) + (B)] is 0.09-0.90, A thin paper treating agent, wherein a mass ratio represented by (C) / [(A) + (B) + (C)] is 0.60 to 0.995.
(A) Component: Sorbitan fatty acid ester having a hydrocarbon group having 14 to 22 carbon atoms and a melting point of 20 ° C. or higher and not added with alkylene oxide (B) Component: sulfate ester surfactant, sulfonic acid type At least one selected from the group consisting of surfactants, amino acid type surfactants, alkylene oxide addition type nonionic surfactants of alcohols having 8 to 22 carbon atoms (C) component: polyhydric alcohol
（Ａ）成分：炭化水素基の炭素数が１４〜２２であり、融点が２０℃以上であるアルキレンオキシドが付加されていないソルビタン脂肪酸エステル
（Ｂ）成分：硫酸エステル系界面活性剤、スルホン酸系界面活性剤、アミノ酸型界面活性剤、炭素数８〜２２のアルコールのアルキレンオキシド付加型非イオン性界面活性剤からなる群から選ばれる少なくとも１種
（Ｃ）成分：多価アルコール
（Ｄ）成分：炭化水素基の炭素数が８〜２２のアルキレンオキシド付加型ソルビタンエステル The following (A) component, (B) component, (C) component, and (D) component are contained, and the mass represented by (A) / [(A) + (B) + (D)] The mass ratio represented by the ratio 0.09 to 0.90, (C) / [(A) + (B) + (C) + (D)] is 0.60 to 0.995, (D) / A thin paper treating agent, wherein the mass ratio represented by [(B) + (D)] is 0.80 or less.
(A) Component: Sorbitan fatty acid ester having a hydrocarbon group having 14 to 22 carbon atoms and a melting point of 20 ° C. or higher and not added with alkylene oxide (B) Component: sulfate ester surfactant, sulfonic acid type At least one selected from the group consisting of surfactants, amino acid type surfactants, alkylene oxide addition type nonionic surfactants of alcohols having 8 to 22 carbon atoms (C) component: polyhydric alcohol (D) component: Alkylene oxide addition type sorbitan ester having 8 to 22 carbon atoms of hydrocarbon group
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009117768A JP5412178B2 (en) | 2009-05-14 | 2009-05-14 | Thin paper treatment agent and thin paper |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2009117768A JP5412178B2 (en) | 2009-05-14 | 2009-05-14 | Thin paper treatment agent and thin paper |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2010265562A true JP2010265562A (en) | 2010-11-25 |
| JP5412178B2 JP5412178B2 (en) | 2014-02-12 |
Family
ID=43362769
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2009117768A Active JP5412178B2 (en) | 2009-05-14 | 2009-05-14 | Thin paper treatment agent and thin paper |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP5412178B2 (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018016906A (en) * | 2016-07-28 | 2018-02-01 | ライオン・スペシャリティ・ケミカルズ株式会社 | Drug for tissue paper, and tissue paper |
| JP2018109244A (en) * | 2016-12-28 | 2018-07-12 | ミヨシ油脂株式会社 | Method for producing paper treatment agent and method for improving texture of paper |
| JP7309972B1 (en) | 2022-06-03 | 2023-07-18 | ミヨシ油脂株式会社 | Paper processing agent, paper using the same, and method for improving texture of paper |
| JP7508354B2 (en) | 2020-12-09 | 2024-07-01 | ミヨシ油脂株式会社 | Paper treatment agent and paper using the same |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05156596A (en) * | 1991-12-03 | 1993-06-22 | Kouno Seishi Kk | Fiber web having high water retention and production thereof |
| JPH09500691A (en) * | 1993-05-13 | 1997-01-21 | ザ、プロクター、エンド、ギャンブル、カンパニー | Tissue paper treated with a mixture of ternary biodegradable softeners |
| JP2004067586A (en) * | 2002-08-06 | 2004-03-04 | Chisso Corp | Antimicrobial agent composition and antimicrobial sheet-like article using the same |
| JP2008006273A (en) * | 2006-06-02 | 2008-01-17 | Lion Corp | Tissue paper |
| JP2008073118A (en) * | 2006-09-19 | 2008-04-03 | Lion Corp | Hygienic tissue paper and hygienic tissue paper product |
-
2009
- 2009-05-14 JP JP2009117768A patent/JP5412178B2/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH05156596A (en) * | 1991-12-03 | 1993-06-22 | Kouno Seishi Kk | Fiber web having high water retention and production thereof |
| JPH09500691A (en) * | 1993-05-13 | 1997-01-21 | ザ、プロクター、エンド、ギャンブル、カンパニー | Tissue paper treated with a mixture of ternary biodegradable softeners |
| JP2004067586A (en) * | 2002-08-06 | 2004-03-04 | Chisso Corp | Antimicrobial agent composition and antimicrobial sheet-like article using the same |
| JP2008006273A (en) * | 2006-06-02 | 2008-01-17 | Lion Corp | Tissue paper |
| JP2008073118A (en) * | 2006-09-19 | 2008-04-03 | Lion Corp | Hygienic tissue paper and hygienic tissue paper product |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2018016906A (en) * | 2016-07-28 | 2018-02-01 | ライオン・スペシャリティ・ケミカルズ株式会社 | Drug for tissue paper, and tissue paper |
| JP2018109244A (en) * | 2016-12-28 | 2018-07-12 | ミヨシ油脂株式会社 | Method for producing paper treatment agent and method for improving texture of paper |
| JP7508354B2 (en) | 2020-12-09 | 2024-07-01 | ミヨシ油脂株式会社 | Paper treatment agent and paper using the same |
| JP7309972B1 (en) | 2022-06-03 | 2023-07-18 | ミヨシ油脂株式会社 | Paper processing agent, paper using the same, and method for improving texture of paper |
| WO2023234252A1 (en) * | 2022-06-03 | 2023-12-07 | ミヨシ油脂株式会社 | Paper treatment agent and paper using same, and method for improving paper texture |
| JP2023177872A (en) * | 2022-06-03 | 2023-12-14 | ミヨシ油脂株式会社 | Paper treatment agent, and paper and method for improving feeling of paper using the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP5412178B2 (en) | 2014-02-12 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5291796B2 (en) | Emulsion composition, method for softening fiber structure using emulsion composition, and fibrous substrate treated with emulsion composition | |
| KR100542169B1 (en) | Soft Tissue Achieved by Applying a Solid Hydrophilic Lotion | |
| JP5162117B2 (en) | Sanitary tissue paper products | |
| JP5694660B2 (en) | Chemical liquid for wiping wet sheet and wiping wet sheet containing the same | |
| JP2007203288A (en) | Cosmetic emulsion capable of being prepared at low temperature, and having low-viscosity and long-term stability | |
| US9757322B2 (en) | Liquid cosmetic | |
| JP5412178B2 (en) | Thin paper treatment agent and thin paper | |
| US4759875A (en) | Oxo-derived mild surfactant blends | |
| JP6036188B2 (en) | Cleansing cream | |
| JP2008006273A (en) | Tissue paper | |
| CN101166507A (en) | Novel skin care formulation | |
| JP2007107173A (en) | Paper tissue-treating agent | |
| CN104822817B (en) | Bar composition and manufacturing method | |
| JP6555595B2 (en) | Method for reducing critical micelle concentration | |
| US6906014B2 (en) | Stabilized topical composition | |
| JP5049653B2 (en) | Tissue processing agent | |
| JP4932412B2 (en) | Tissue paper | |
| JP2006342096A (en) | Composition for scalp | |
| JP2016193979A (en) | Liquid detergent composition | |
| PT101531B (en) | ACID MICROEMULATIVE COMPOSITION CONTAINING AN ALPHA-HYDROXY-ALIFATIC ACID AND AN AMINO-ALKYLENE-PHOSPHONIC ACID. | |
| JP2006118089A (en) | Tissue paper-treating agent and tissue paper | |
| JP7309972B1 (en) | Paper processing agent, paper using the same, and method for improving texture of paper | |
| TWI421305B (en) | Emulsion composition, methods of softening fibrous structures using the same, and fibrous substrate treated therewith | |
| JP2002536388A (en) | Microemulsion containing alkyl sulfate and / or alkanol ammonium salt of alkyl sulfate polyalkylene glycol ether | |
| JP2007254430A (en) | Hydrophilic liquid cosmetic |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20120215 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20130121 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20130129 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20130328 |
|
| TRDD | Decision of grant or rejection written | ||
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20131015 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20131111 |
|
| R150 | Certificate of patent or registration of utility model |
Ref document number: 5412178 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
| S111 | Request for change of ownership or part of ownership |
Free format text: JAPANESE INTERMEDIATE CODE: R313115 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R360 | Written notification for declining of transfer of rights |
Free format text: JAPANESE INTERMEDIATE CODE: R360 |
|
| R360 | Written notification for declining of transfer of rights |
Free format text: JAPANESE INTERMEDIATE CODE: R360 |
|
| R371 | Transfer withdrawn |
Free format text: JAPANESE INTERMEDIATE CODE: R371 |
|
| S531 | Written request for registration of change of domicile |
Free format text: JAPANESE INTERMEDIATE CODE: R313531 |
|
| R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
| R350 | Written notification of registration of transfer |
Free format text: JAPANESE INTERMEDIATE CODE: R350 |