JP2009261359A - Method for producing carbon dioxide-containing soft jelly-like drink packaged in hermetically sealed container - Google Patents
Method for producing carbon dioxide-containing soft jelly-like drink packaged in hermetically sealed container Download PDFInfo
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- JP2009261359A JP2009261359A JP2008117079A JP2008117079A JP2009261359A JP 2009261359 A JP2009261359 A JP 2009261359A JP 2008117079 A JP2008117079 A JP 2008117079A JP 2008117079 A JP2008117079 A JP 2008117079A JP 2009261359 A JP2009261359 A JP 2009261359A
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- carbon dioxide
- gelling agent
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- jelly
- beverage
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- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 title claims abstract description 78
- 239000001569 carbon dioxide Substances 0.000 title claims abstract description 39
- 229910002092 carbon dioxide Inorganic materials 0.000 title claims abstract description 39
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 25
- 235000015110 jellies Nutrition 0.000 claims abstract description 45
- 239000008274 jelly Substances 0.000 claims abstract description 45
- 239000003349 gelling agent Substances 0.000 claims abstract description 43
- 229920001817 Agar Polymers 0.000 claims abstract description 28
- 239000008272 agar Substances 0.000 claims abstract description 26
- 239000002994 raw material Substances 0.000 claims abstract description 25
- 238000010438 heat treatment Methods 0.000 claims abstract description 14
- 235000013361 beverage Nutrition 0.000 claims description 58
- 235000010419 agar Nutrition 0.000 claims description 26
- 239000011259 mixed solution Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 15
- 239000000243 solution Substances 0.000 claims description 10
- 235000010493 xanthan gum Nutrition 0.000 claims description 10
- 239000000230 xanthan gum Substances 0.000 claims description 10
- 229920001285 xanthan gum Polymers 0.000 claims description 10
- 229940082509 xanthan gum Drugs 0.000 claims description 10
- 229920000161 Locust bean gum Polymers 0.000 claims description 8
- 235000010420 locust bean gum Nutrition 0.000 claims description 8
- 239000000711 locust bean gum Substances 0.000 claims description 8
- 229920002148 Gellan gum Polymers 0.000 claims description 7
- 235000013305 food Nutrition 0.000 claims description 7
- 235000010492 gellan gum Nutrition 0.000 claims description 7
- 239000000216 gellan gum Substances 0.000 claims description 7
- 239000007788 liquid Substances 0.000 abstract description 29
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 26
- 238000000034 method Methods 0.000 abstract description 12
- 238000002156 mixing Methods 0.000 abstract description 11
- 238000002844 melting Methods 0.000 abstract description 6
- 230000008018 melting Effects 0.000 abstract description 6
- 238000007789 sealing Methods 0.000 abstract description 3
- 238000005520 cutting process Methods 0.000 abstract description 2
- 210000003254 palate Anatomy 0.000 abstract 1
- 239000006188 syrup Substances 0.000 description 13
- 235000020357 syrup Nutrition 0.000 description 13
- 239000000843 powder Substances 0.000 description 11
- 239000010902 straw Substances 0.000 description 9
- 235000000346 sugar Nutrition 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 6
- 229910052782 aluminium Inorganic materials 0.000 description 6
- 235000015203 fruit juice Nutrition 0.000 description 6
- 235000014171 carbonated beverage Nutrition 0.000 description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 4
- 159000000007 calcium salts Chemical class 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 230000035622 drinking Effects 0.000 description 4
- PJVXUVWGSCCGHT-ZPYZYFCMSA-N (2r,3s,4r,5r)-2,3,4,5,6-pentahydroxyhexanal;(3s,4r,5r)-1,3,4,5,6-pentahydroxyhexan-2-one Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O.OC[C@@H](O)[C@@H](O)[C@H](O)C(=O)CO PJVXUVWGSCCGHT-ZPYZYFCMSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000000796 flavoring agent Substances 0.000 description 3
- 235000019634 flavors Nutrition 0.000 description 3
- 238000001879 gelation Methods 0.000 description 3
- 150000007524 organic acids Chemical class 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 230000001954 sterilising effect Effects 0.000 description 3
- 238000004659 sterilization and disinfection Methods 0.000 description 3
- 235000005979 Citrus limon Nutrition 0.000 description 2
- 244000131522 Citrus pyriformis Species 0.000 description 2
- 241001672694 Citrus reticulata Species 0.000 description 2
- 229930091371 Fructose Natural products 0.000 description 2
- RFSUNEUAIZKAJO-ARQDHWQXSA-N Fructose Chemical compound OC[C@H]1O[C@](O)(CO)[C@@H](O)[C@@H]1O RFSUNEUAIZKAJO-ARQDHWQXSA-N 0.000 description 2
- 239000005715 Fructose Substances 0.000 description 2
- 235000017537 Vaccinium myrtillus Nutrition 0.000 description 2
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- 235000010418 carrageenan Nutrition 0.000 description 2
- 239000000679 carrageenan Substances 0.000 description 2
- 229920001525 carrageenan Polymers 0.000 description 2
- 229940113118 carrageenan Drugs 0.000 description 2
- 239000003086 colorant Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 239000003205 fragrance Substances 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 239000000451 gelidium spp. gum Substances 0.000 description 2
- 210000000214 mouth Anatomy 0.000 description 2
- 238000010979 pH adjustment Methods 0.000 description 2
- 150000008163 sugars Chemical class 0.000 description 2
- UHVMMEOXYDMDKI-JKYCWFKZSA-L zinc;1-(5-cyanopyridin-2-yl)-3-[(1s,2s)-2-(6-fluoro-2-hydroxy-3-propanoylphenyl)cyclopropyl]urea;diacetate Chemical compound [Zn+2].CC([O-])=O.CC([O-])=O.CCC(=O)C1=CC=C(F)C([C@H]2[C@H](C2)NC(=O)NC=2N=CC(=CC=2)C#N)=C1O UHVMMEOXYDMDKI-JKYCWFKZSA-L 0.000 description 2
- LUEWUZLMQUOBSB-FSKGGBMCSA-N (2s,3s,4s,5s,6r)-2-[(2r,3s,4r,5r,6s)-6-[(2r,3s,4r,5s,6s)-4,5-dihydroxy-2-(hydroxymethyl)-6-[(2r,4r,5s,6r)-4,5,6-trihydroxy-2-(hydroxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-4,5-dihydroxy-2-(hydroxymethyl)oxan-3-yl]oxy-6-(hydroxymethyl)oxane-3,4,5-triol Chemical compound O[C@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H](CO)O[C@@H](O[C@@H]2[C@H](O[C@@H](OC3[C@H](O[C@@H](O)[C@@H](O)[C@H]3O)CO)[C@@H](O)[C@H]2O)CO)[C@H](O)[C@H]1O LUEWUZLMQUOBSB-FSKGGBMCSA-N 0.000 description 1
- WVXRAFOPTSTNLL-NKWVEPMBSA-N 2',3'-dideoxyadenosine Chemical compound C1=NC=2C(N)=NC=NC=2N1[C@H]1CC[C@@H](CO)O1 WVXRAFOPTSTNLL-NKWVEPMBSA-N 0.000 description 1
- FHVDTGUDJYJELY-UHFFFAOYSA-N 6-{[2-carboxy-4,5-dihydroxy-6-(phosphanyloxy)oxan-3-yl]oxy}-4,5-dihydroxy-3-phosphanyloxane-2-carboxylic acid Chemical compound O1C(C(O)=O)C(P)C(O)C(O)C1OC1C(C(O)=O)OC(OP)C(O)C1O FHVDTGUDJYJELY-UHFFFAOYSA-N 0.000 description 1
- 244000215068 Acacia senegal Species 0.000 description 1
- 244000144730 Amygdalus persica Species 0.000 description 1
- 235000007119 Ananas comosus Nutrition 0.000 description 1
- 244000099147 Ananas comosus Species 0.000 description 1
- 235000004936 Bromus mango Nutrition 0.000 description 1
- 240000008886 Ceratonia siliqua Species 0.000 description 1
- 235000013912 Ceratonia siliqua Nutrition 0.000 description 1
- 240000000560 Citrus x paradisi Species 0.000 description 1
- 206010013911 Dysgeusia Diseases 0.000 description 1
- 229920002581 Glucomannan Polymers 0.000 description 1
- 229920002907 Guar gum Polymers 0.000 description 1
- 229920000084 Gum arabic Polymers 0.000 description 1
- 240000003394 Malpighia glabra Species 0.000 description 1
- 235000014837 Malpighia glabra Nutrition 0.000 description 1
- 240000007228 Mangifera indica Species 0.000 description 1
- 235000014826 Mangifera indica Nutrition 0.000 description 1
- 240000008790 Musa x paradisiaca Species 0.000 description 1
- 244000183278 Nephelium litchi Species 0.000 description 1
- 235000011158 Prunus mume Nutrition 0.000 description 1
- 244000018795 Prunus mume Species 0.000 description 1
- 235000006040 Prunus persica var persica Nutrition 0.000 description 1
- 241000220324 Pyrus Species 0.000 description 1
- 235000009184 Spondias indica Nutrition 0.000 description 1
- 240000004584 Tamarindus indica Species 0.000 description 1
- 235000004298 Tamarindus indica Nutrition 0.000 description 1
- 244000269722 Thea sinensis Species 0.000 description 1
- 235000003095 Vaccinium corymbosum Nutrition 0.000 description 1
- 241000219094 Vitaceae Species 0.000 description 1
- ZNOZWUKQPJXOIG-XSBHQQIPSA-L [(2r,3s,4r,5r,6s)-6-[[(1r,3s,4r,5r,8s)-3,4-dihydroxy-2,6-dioxabicyclo[3.2.1]octan-8-yl]oxy]-4-[[(1r,3r,4r,5r,8s)-8-[(2s,3r,4r,5r,6r)-3,4-dihydroxy-6-(hydroxymethyl)-5-sulfonatooxyoxan-2-yl]oxy-4-hydroxy-2,6-dioxabicyclo[3.2.1]octan-3-yl]oxy]-5-hydroxy-2-( Chemical compound O[C@@H]1[C@@H](O)[C@@H](OS([O-])(=O)=O)[C@@H](CO)O[C@H]1O[C@@H]1[C@@H]2OC[C@H]1O[C@H](O[C@H]1[C@H]([C@@H](CO)O[C@@H](O[C@@H]3[C@@H]4OC[C@H]3O[C@H](O)[C@@H]4O)[C@@H]1O)OS([O-])(=O)=O)[C@@H]2O ZNOZWUKQPJXOIG-XSBHQQIPSA-L 0.000 description 1
- 235000010489 acacia gum Nutrition 0.000 description 1
- 239000000205 acacia gum Substances 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 229940072056 alginate Drugs 0.000 description 1
- 235000010443 alginic acid Nutrition 0.000 description 1
- 229920000615 alginic acid Polymers 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 235000021015 bananas Nutrition 0.000 description 1
- 235000021014 blueberries Nutrition 0.000 description 1
- 239000004227 calcium gluconate Substances 0.000 description 1
- 229960004494 calcium gluconate Drugs 0.000 description 1
- 235000013927 calcium gluconate Nutrition 0.000 description 1
- MKJXYGKVIBWPFZ-UHFFFAOYSA-L calcium lactate Chemical compound [Ca+2].CC(O)C([O-])=O.CC(O)C([O-])=O MKJXYGKVIBWPFZ-UHFFFAOYSA-L 0.000 description 1
- 239000001527 calcium lactate Substances 0.000 description 1
- 235000011086 calcium lactate Nutrition 0.000 description 1
- 229940041131 calcium lactate gluconate Drugs 0.000 description 1
- NEEHYRZPVYRGPP-UHFFFAOYSA-L calcium;2,3,4,5,6-pentahydroxyhexanoate Chemical compound [Ca+2].OCC(O)C(O)C(O)C(O)C([O-])=O.OCC(O)C(O)C(O)C(O)C([O-])=O NEEHYRZPVYRGPP-UHFFFAOYSA-L 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 239000000498 cooling water Substances 0.000 description 1
- 238000007599 discharging Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003995 emulsifying agent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 235000013373 food additive Nutrition 0.000 description 1
- 239000002778 food additive Substances 0.000 description 1
- 235000020803 food preference Nutrition 0.000 description 1
- 235000003599 food sweetener Nutrition 0.000 description 1
- 229940046240 glucomannan Drugs 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 235000021021 grapes Nutrition 0.000 description 1
- 235000010417 guar gum Nutrition 0.000 description 1
- 239000000665 guar gum Substances 0.000 description 1
- 229960002154 guar gum Drugs 0.000 description 1
- 235000012907 honey Nutrition 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- 229910052500 inorganic mineral Inorganic materials 0.000 description 1
- 235000014058 juice drink Nutrition 0.000 description 1
- 238000002372 labelling Methods 0.000 description 1
- 239000011707 mineral Substances 0.000 description 1
- 235000010755 mineral Nutrition 0.000 description 1
- 235000016023 orange carbonate Nutrition 0.000 description 1
- 239000003002 pH adjusting agent Substances 0.000 description 1
- 235000021017 pears Nutrition 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 239000003765 sweetening agent Substances 0.000 description 1
- 229940088594 vitamin Drugs 0.000 description 1
- 235000013343 vitamin Nutrition 0.000 description 1
- 239000011782 vitamin Substances 0.000 description 1
- 229930003231 vitamin Natural products 0.000 description 1
- 150000003722 vitamin derivatives Chemical class 0.000 description 1
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- Non-Alcoholic Beverages (AREA)
Abstract
Description
本発明は、ゲル化剤としての寒天と飲料原料液とから構成される柔らかなゲル状飲料(以下「ソフトゼリー状飲料」という)に炭酸ガスを吸収させてなる密閉容器入り炭酸ガス含有ソフトゼリー状飲料の製造方法に関し、特に密閉容器を軽く数回振ってゼリーを破砕した後容器から排出させて飲用するかまたはストローを容器内に差し込んでゼリーを吸引して飲用するタイプの密閉容器入り炭酸ガス含有ソフトゼリー状飲料の配合と製造方法に関する。 The present invention relates to a soft jelly containing carbon dioxide in a sealed container in which a soft gel beverage (hereinafter referred to as “soft jelly beverage”) composed of agar as a gelling agent and a beverage raw material liquid is absorbed. In particular, the closed container is a type of carbonated drink in which a sealed container is shaken a few times to crush the jelly and then discharged from the container for drinking, or a straw is inserted into the container to suck and drink the jelly. The present invention relates to a blending and manufacturing method of a gas-containing soft jelly beverage.
炭酸ガス含有飲料あるいは炭酸ガス含有飲料中に細片状(チップ状)のゼリーを加えた飲料は市場において周知の飲料である。 Beverages containing carbon dioxide gas or beverages obtained by adding strip-like (chip-like) jelly to carbon dioxide gas-containing beverages are well-known beverages on the market.
近年食品に対する嗜好が多様化するにつれ、従来から存在する飲食物にあきたらず新規な形態の飲食物を求める傾向が特に若年層に強まっており、缶、カップ等の密閉容器入り飲料においてもこの傾向にあわせて新規な形態のものが現れている。 In recent years, as food preferences have diversified, the tendency to seek new forms of food and drinks, which are not related to existing foods and drinks, has become particularly strong, and even in beverages in cans, cups and other closed containers New forms appear in line with trends.
特願2001−021300号公報には、密閉容器入り炭酸ガス含有飲料の分野において、このような傾向に合致した新規なソフトゼリー状飲料を提供することを目的として、易溶性寒天、キサンタンガム、ローカストビーンガム、糖類および有機酸を組合せてゼリーを作り、このゼリーを細片状に裁断し、この細片状ゼリーと、糖類および酸味料を含むシロップ液に炭酸ガスを吸収させた炭酸ガス含有シロップ液とを容器に充填し密封した後加熱処理を施してゼリーを溶融させ、溶融したゼリーとシロップ液とを混合均一化した後冷却することを特徴とする密閉容器入り炭酸ガス含有ソフトゼリー状飲料の製造方法が開示されている。 Japanese Patent Application No. 2001-021300 discloses easily soluble agar, xanthan gum, locust bean for the purpose of providing a novel soft jelly-like beverage that meets such a tendency in the field of carbon dioxide gas-containing beverages in sealed containers. Carbon dioxide-containing syrup solution in which jelly is made by combining gum, sugar and organic acid, this jelly is cut into strips, and carbon dioxide is absorbed into this strip-like jelly and syrup solution containing sugars and acidulants Of a soft jelly-like beverage containing a carbon dioxide gas in a sealed container, wherein the jelly is melted by applying a heat treatment, and the molten jelly and the syrup liquid are mixed and homogenized and then cooled. A manufacturing method is disclosed.
この方法によって製造された炭酸ガス含有ソフトゼリー状飲料は、缶等密閉容器の内容物である飲料全体が柔らかなゼリーの塊となっており、容器にストローを差込んでゼリーを吸引するか、あるいは容器を開封する前に軽く容器を振って容器内のゼリーを破砕した後容器を開封してゼリーを飲用することができる飲料であるが、炭酸ガス含有飲料を容器に充填、密封した後の寒天等のゲル化剤の溶融温度が85℃〜90℃の高温であり、このような高温で炭酸含有飲料を密封した容器を加熱すると内圧が高まりバックリングを起こす危険があるので、外部に加圧を施し内圧との均衡を保たせる熱水加圧レトルトを必要とし、工業的生産において、既設の炭酸飲料製造ラインに加えて高価な熱水加圧レトルト装置を設けなければならず、製造コストが増大するという問題点を有していた。 The soft jelly-like beverage containing carbon dioxide gas produced by this method is a soft jelly lump that is the contents of a sealed container such as a can, and sucks the jelly by inserting a straw into the container, Alternatively, it is a beverage that can be shaken lightly before crushing the container to crush the jelly in the container and then open the container to drink the jelly, but after filling and sealing the carbon dioxide containing beverage in the container Since the melting temperature of gelling agents such as agar is as high as 85 ° C. to 90 ° C., heating a container sealed with a carbonated beverage at such a high temperature may increase the internal pressure and cause buckling. A hot water pressurizing retort is required to maintain a balance with the internal pressure, and in industrial production, an expensive hot water pressurizing retort device must be installed in addition to the existing carbonated beverage production line. Strike there has been a problem of increasing.
また、上記の方法では、ゲル化剤のゼリーを裁断して5mm角程度のキューブ状に均一形状化しなければならず、このための工程を必要としていた。また、シロップと水を混合したものにカーボネーターで炭酸を含有せしめた後キューブ状のゲル化剤ゼリーを充填するという別個の工程を必要としていた。したがって製造工程が複雑となり、この点でも製造コストが増大するという問題点を有していた。 In the above method, the gelling agent jelly must be cut into a uniform shape of about 5 mm square cube, which requires a process for this purpose. In addition, a separate process is required in which a mixture of syrup and water is made to contain carbonic acid with a carbonator and then filled with a cube-shaped gelling agent jelly. Therefore, the manufacturing process becomes complicated, and this also has a problem that the manufacturing cost increases.
さらに、上記の方法では、充填時、キューブゼリーは缶内で均等に分散しているとは限らず、むしろ沈んでいる場合が多く、そのため、溶融時は、溶けたゲル化剤とその他シロップ部分が分離している状態にあり、ゲル化剤が凝固し始める前に混合する必要があるので、キューブゼリーが溶融したゲル化剤が凝固へ向かいはじめの温度にあるうちに、5回転以上缶を回転させ、シロップとの混合を行わなければならす、工程が一層複雑化するという問題点を有していた。また、その際の温度は80℃前後であり、衝撃による炭酸の活性化で内圧が高まり、バックリング等を起こすおそれもあった。
本発明は、上記の製造法における従来技術の問題点を解決することを目的としてなされたものであって、寒天をゲル化剤とする炭酸ガス含有ソフトゼリー状飲料として充分な味覚、食感を保ちながら、高価な熱水レトルト装置を設ける必要がなく、溶融温度が低いゲル化剤に限定することもない、またゲル化剤をキューブ状に裁断する工程を必要としない簡素化された製造工程を使用することができる上に、密閉容器を軽く数回振ってゼリーを破砕した後容器から排出させて飲用するかまたはストローを容器内に差し込んでゼリーを吸引して飲用するタイプの密閉容器入り炭酸ガス含有ソフトゼリー状飲料の製造に好適な製造方法を提供しようとするものである。 The present invention was made for the purpose of solving the problems of the prior art in the above production method, and has a sufficient taste and texture as a carbon dioxide-containing soft jelly-like beverage containing agar as a gelling agent. Simplified manufacturing process that does not require an expensive hot water retort device, is not limited to a gelling agent having a low melting temperature, and does not require a step of cutting the gelling agent into a cube shape while maintaining In addition to crushing the jelly several times by lightly shaking the sealed container and then discharging it from the container for drinking, or by inserting a straw into the container and sucking the jelly for drinking An object of the present invention is to provide a production method suitable for producing a carbon dioxide-containing soft jelly beverage.
上記課題を解決するために、本発明者は鋭意研究と実験を重ねた結果、ゲル化剤として粉体の寒天を水に分散して原料液に直接投入し混合した混合液に炭酸ガスを含有せしめ、容器に充填、密封した後蒸気レトルトによる加熱を行えば、混合液の殺菌と同時に寒天が溶解してソフトゼリー状飲料が得られることを見出し、本発明に到達した。 In order to solve the above-mentioned problems, the present inventor has conducted extensive research and experiments, and as a gelling agent, powder agar is dispersed in water and directly charged into the raw material liquid. It has been found that if the container is filled and sealed and then heated by steam retort, the agar dissolves simultaneously with the sterilization of the mixed solution to obtain a soft jelly-like beverage.
すなわち、上記課題を解決する本発明の密閉容器入り炭酸ガス含有ソフトゼリー状飲料または食品の製造方法は、ゲル化剤として製品の0.1〜0.25%w/vの粉体寒天を原材料液に添加混合し、該混合液を容器に充填する前または後に炭酸ガスを含有させ、次いで該混合液を容器に充填、密封した後蒸気式レトルトにより105℃〜110℃、5分間以上加熱することによりゲル化剤を溶解させるとともに該混合液を殺菌することを特徴とするものである。 That is, the method for producing a carbonated gas-containing soft jelly-like beverage or food in a sealed container according to the present invention that solves the above-mentioned problems is based on 0.1 to 0.25% w / v of powder agar as a raw material Add to and mix with the liquid, and before or after filling the liquid mixture into the container, contain carbon dioxide gas, then fill and seal the liquid mixture into the container, and then heat it at 105 to 110 ° C for 5 minutes or more with a steam retort Thus, the gelling agent is dissolved and the mixed solution is sterilized.
また本発明の第2の構成は、ゲル化剤として寒天以外に、ローカストビーンガム、キサンタンガム、ジェランガムのうち1種、または、2種類以上を組み合わせてなることを特徴とするものである。 In addition, the second configuration of the present invention is characterized in that, in addition to agar as a gelling agent, one or two or more of locust bean gum, xanthan gum and gellan gum are combined.
本発明によれば、ゲル化剤として寒天0.1%(w/v)〜0.25%(w/v)を使用し、密閉容器入り炭酸ガス含有飲料を105℃〜110℃、5分間以上蒸気レトルトによる加熱処理を施してゲル化剤を溶融させることにより、密閉容器を軽く数回振ってゼリーを破砕した後容器から排出させて飲用するタイプ(以下シェイクタイプという)またはストローを容器内に差し込んでゼリーを吸引して飲用するタイプ(以下ストロータイプという)の密閉容器入り炭酸ガス含有ソフトゼリー状飲料を製造することができる。 According to the present invention, 0.1% (w / v) to 0.25% (w / v) agar is used as a gelling agent, and a carbon dioxide-containing beverage in a sealed container is placed at 105 ° C to 110 ° C for 5 minutes. By heat-treating with steam retort and melting the gelling agent, shake the sealed container several times and crush the jelly, then discharge it from the container (hereinafter referred to as shake type) or a straw in the container It is possible to produce a soft jelly-like beverage containing a carbon dioxide gas in a sealed container of a type (hereinafter referred to as a straw type) that is inserted into the container and sucked to drink the jelly.
また、ゲル化剤は、蒸気レトルトによる加熱処理を施すことによって飲料中に溶融し、これによって高価な熱水レトルト装置を設ける必要がなくなり、製造コストを低減することができる。 In addition, the gelling agent is melted in the beverage by performing a heat treatment with a steam retort, which eliminates the need to provide an expensive hot water retort device, thereby reducing the manufacturing cost.
また、ゲル化剤はゲル化した後キューブ状に裁断することなく、ゲル化剤の粉末の形で飲料原料液に混合するので、従来技術のようにゲル化したゲル化剤をキューブ状に裁断する工程を別工程として必要とせず、この点でも製造方法を簡素化することができ、製造コストを一層低減することができる。 In addition, the gelling agent is mixed into the beverage raw material liquid in the form of a gelling agent powder without being cut into cubes after gelling, so the gelling agent gelled as in the prior art is cut into cubes In this respect, the manufacturing method can be simplified and the manufacturing cost can be further reduced.
本発明の一つの特徴は、ゲル化剤として飲料総量の0.1%w/v〜0.25%w/vの粉体寒天を使用することである。
粉体寒天の使用量については、臨界性があり、寒天の使用量が0.1%w/v未満ではゲル化が充分でなく、また0.25%w/v以上であると、ストロータイプのソフトゼリー状飲料の場合はストローを差し込んで飲用することができるが、シェイクタイプのソフトゼリー状飲料の場合は、容器を5回以上振ってもゼリーが充分に破砕されず容器からの排出に手間取り、容器を押して排出する必要がある場合が生じるので、シェイクタイプとしては好ましくない。より好ましい範囲は0.1〜0.20%w/v、もっとも好ましい範囲は0.1〜0.15%w/vである。
One feature of the present invention is the use of 0.1% w / v to 0.25% w / v powder agar as the gelling agent.
The amount of powder agar used is critical. If the amount of agar used is less than 0.1% w / v, gelation is not sufficient, and if it is 0.25% w / v or more, a straw type In the case of soft jelly-like beverages, a straw can be inserted to drink, but in the case of shake-type soft jelly-like beverages, even if the container is shaken five times or more, the jelly is not sufficiently crushed and discharged from the container. Since it may be necessary to evacuate the container and push the container, it is not preferable as a shake type. A more preferable range is 0.1 to 0.20% w / v, and a most preferable range is 0.1 to 0.15% w / v.
本発明の製造方法においては、寒天以外に、ローカストビーンガム、キサンタンガム、ジェランガムのうち1種、または、2種類以上を組み合わせて使用することができる。 In the production method of the present invention, in addition to agar, one or more of locust bean gum, xanthan gum and gellan gum can be used.
ローカストビーンガムも多くの種類があるが、105℃以下で溶融するタイプが殆どな為、問題はない。このタイプのローカストビーンガムとしては、市販されているものが容易に入手できるので好適である。 There are many types of locust bean gum, but since most types melt at 105 ° C or lower, there is no problem. As this type of locust bean gum, a commercially available one is suitable because it can be easily obtained.
またキサンタンガムおよびジェランガムは飲料の食感を向上させる効果があるので添加することが好ましい。 Xanthan gum and gellan gum are preferably added because they have an effect of improving the texture of the beverage.
寒天以外のゲル化剤の使用量については、ローカストビーンガムの使用量は、飲料総量の0.05〜0.15%w/vの範囲、キサンタンガムは飲料総量の0.02〜0.05%w/vの範囲、ジェランガムについては0.03〜0.1%w/vの範囲で使用することが好ましい。ゲル化剤の使用量が上記下限値未満では目的とするゲル化が不十分となる一方使用量が上記上限値を超えると、ゼリー状態において硬度が高まるため、シェイクタイプでは飲用する際に容器から出難くなるおそれが生じ、また食感が悪くなる。 Regarding the amount of gelling agent other than agar, the amount of locust bean gum used is in the range of 0.05 to 0.15% w / v of the total beverage amount, and xanthan gum is 0.02 to 0.05% of the total beverage amount. The w / v range and gellan gum are preferably used in the range of 0.03 to 0.1% w / v. If the amount of gelling agent used is less than the above lower limit, the intended gelation will be insufficient, while if the amount used exceeds the above upper limit, the hardness will increase in the jelly state, so in the shake type from the container when drinking There is a risk that it may be difficult to get out, and the texture becomes worse.
上記以外にも、原材料に対応したよりよい食感を表現するために、場合によりκカラギナン、ιカラギナン、λカラギナン、グアーガム、タマリンドガム、ファーセレラン、アルギン酸塩、グルコマンナン、アラビアガム等を添加してもよい。
本発明の製造方法においては、飲料の容器への充填・密封後の加熱処理が105℃で5分以上であるので、本発明の炭酸ガス含有ソフトゼリー状飲料に使用する飲料原料液は、この温度範囲の温度で殺菌が完了する種類の飲料であれば特に制限はない。本発明を適用するのに好適な飲料の中で果汁飲料としては、ブルーベリー、レモン、グレープフルーツ、うめ、ピーチ、パイナップル、グレープ、ビルベリー、洋ナシ、マンゴー、アセロラ、カルカム、バナナ、オレンジ、ライチ等がある。
In addition to the above, in order to express a better texture corresponding to the raw materials, in some cases, κ carrageenan, ι carrageenan, λ carrageenan, guar gum, tamarind gum, fur celerane, alginate, glucomannan, gum arabic etc. Also good.
In the production method of the present invention, since the heat treatment after filling and sealing the beverage container is 105 ° C. or more for 5 minutes or longer, the beverage raw material liquid used for the carbon dioxide-containing soft jelly beverage of the present invention is If it is a kind of drink which sterilization completes at the temperature of a temperature range, there will be no restriction | limiting in particular. Among the beverages suitable for applying the present invention, juice drinks include blueberries, lemons, grapefruits, ume, peaches, pineapples, grapes, bilberries, pears, mangoes, acerola, calcum, bananas, oranges, litchis, etc. is there.
本発明の製造方法においては、加熱により寒天、キサンタンガムをゲル状に硬化させるために、ゲル化剤および飲料原料液の少なくとも一方にカルシウム塩を含有させることが好ましい。食品添加物表示許可品として使用可能なカルシウム塩としては、乳酸カルシウム、グルコン酸カルシウム等を挙げることができる。 In the production method of the present invention, in order to cure agar and xanthan gum in a gel state by heating, it is preferable to contain a calcium salt in at least one of the gelling agent and the beverage raw material liquid. Examples of calcium salts that can be used as food additive labeling products include calcium lactate and calcium gluconate.
カルシウム塩の使用量は、飲料総量の3−10mmol/lの範囲とすることが好ましい。カルシウム塩の使用量が上記下限値未満では寒天およびキサンタンガムのゲル化が充分でない場合が生じ、また使用量が上記上限値を超えるとゼリー状態において硬度が高まるため、シェイクタイプの場合飲用する際に容器から出難くなるおそれが生じ、またミネラル臭が強くなったりして食感が悪くなる。 The amount of calcium salt used is preferably in the range of 3-10 mmol / l of the total beverage. If the amount of calcium salt used is less than the above lower limit value, gelation of agar and xanthan gum may not be sufficient, and if the amount used exceeds the above upper limit value, the hardness will increase in the jelly state. There is a risk that it will be difficult to get out of the container, and the mineral odor will become strong, resulting in poor texture.
飲料原料液が果汁飲料の場合は、原料となる果汁に、炭酸ガス含有飲料として美味なものを提供するため、甘味料としての糖類および酸味料としての有機酸を加えることが好ましい。糖類としては果糖ブドウ糖液糖が特に好ましく、有機酸としてはクエン酸が特に好ましい。 When the beverage raw material liquid is a fruit juice beverage, it is preferable to add a sugar as a sweetener and an organic acid as an acidulant to provide a delicious beverage as a carbon dioxide-containing beverage to the fruit juice as a raw material. As the sugar, fructose-glucose liquid sugar is particularly preferable, and as the organic acid, citric acid is particularly preferable.
また、pH調整のためにクエン酸ナトリウムを加えてもよく、その他飲料の味覚、食感等を調整するために香料等を適宜加えることができる。 Moreover, sodium citrate may be added for pH adjustment, and a fragrance | flavor etc. can be suitably added in order to adjust the taste, food texture, etc. of other drinks.
また飲料原料液が紅茶、コーヒー等非果汁飲料の場合も、飲料の種類に応じて、pH調整剤、乳化剤、ビタミン剤等を適宜加えることができる。 Moreover, also when a drink raw material liquid is non-fruit juice drinks, such as tea and coffee, a pH adjuster, an emulsifier, a vitamin agent, etc. can be added suitably according to the kind of drink.
これらゲル化剤以外の飲料原料液添加用原材料の添加量は飲料の種類やpH調整等の必要に応じて異なるものである。 The addition amount of the raw material for adding beverage raw material liquid other than these gelling agents varies depending on the type of beverage and pH adjustment.
次に炭酸ガス含有混合液の調製方法および混合液の加熱処理について説明する。
果汁等の飲料原料に必要に応じ糖類、酸味料等の添加物を添加した飲料原料液を調製する。一方純水をデアレーターで処理して純水中に含まれる余分なガス成分を排出した後、飲料原料液と純水を任意の配合比率で混合する。寒天その他のゲル化剤は飲料原料液と純水の混合前に飲料原料液に粉末状で添加してもよく、混合後に混合液中に粉末状で添加してもよい。添加されたゲル化剤は水膨潤した状態で混合液中に散在している。既設の炭酸飲料製造ラインを使用する場合はライン上に設けられたカーボネーターによりこの混合液に炭酸を含有せしめ、炭酸ガス含有混合液を調製する。
Next, a method for preparing a carbon dioxide-containing mixed solution and a heat treatment for the mixed solution will be described.
A beverage raw material liquid is prepared by adding additives such as sugars and acidulants to beverage raw materials such as fruit juice as necessary. On the other hand, after treating pure water with a dearator to discharge excess gas components contained in pure water, the beverage raw material liquid and pure water are mixed at an arbitrary blending ratio. Agar and other gelling agents may be added in powder form to the beverage raw material solution before mixing the beverage raw material solution and pure water, or may be added in powder form to the mixed solution after mixing. The added gelling agent is scattered in the mixed solution in a swollen state with water. When using an existing carbonated beverage production line, carbon dioxide is contained in this mixed solution by a carbonator provided on the line to prepare a carbon dioxide-containing mixed solution.
また、炭酸飲料製造ラインを使用する以外の方法としては、上記の方法で調製した純水にカーボネーター等で炭酸ガスを含有せしめて炭酸水とし、この炭酸水と飲料原料液を任意の配合比率で混合することにより炭酸ガス含有混合液としてもよい。カーボネーター等で液に炭酸ガスを含有せしめる場合は、炭酸の溶解時にホーミングの発生や、低混合率化することを避けるため、液を4℃以下に冷却しておくことが好ましい。
また、炭酸ガスは原材料液を容器に充填後原材料液に含有させても良い。
Moreover, as a method other than using the carbonated beverage production line, carbonated gas is contained in the pure water prepared by the above method with a carbonator or the like to obtain carbonated water, and this carbonated water and beverage raw material liquid are mixed at any ratio. It is good also as a carbon dioxide gas containing liquid mixture by mixing by. When carbon dioxide is added to the liquid with a carbonator or the like, the liquid is preferably cooled to 4 ° C. or lower in order to avoid generation of homing or lowering of the mixing ratio when carbonic acid is dissolved.
Carbon dioxide gas may be contained in the raw material liquid after the raw material liquid is filled in the container.
次に、こうして調製した炭酸ガス含有混合液を缶、カップ、食缶等の容器に充填し密封した後レトルト装置によって、加熱時処理槽内部圧力0.05MPa〜0.1MPaの加圧下で105℃~110℃で5分間以上加熱加圧処理を施すことによってゲル化剤を混合液中に溶融させるとともに必要な殺菌を行う。必要な加熱が終了したら容器を製品温度30℃以下まで冷却してソフトゼリー状飲料製品とする。冷却時処理槽内部圧力は0.05MPa〜0.15MPaが好ましい。 冷却時においては、圧縮空気、および冷却水の排気調整注入により加圧を行うことが好ましい。 Next, the carbon dioxide-containing mixture prepared in this manner is filled in a container such as a can, a cup, or a food can and sealed, and then heated by a retort device at 105 ° C. under a pressure of 0.05 MPa to 0.1 MPa when heated. The gelling agent is melted in the mixed solution by applying heat and pressure treatment at ~ 110 ° C for 5 minutes or more and necessary sterilization is performed. When necessary heating is completed, the container is cooled to a product temperature of 30 ° C. or lower to obtain a soft jelly-like beverage product. The treatment tank internal pressure during cooling is preferably 0.05 MPa to 0.15 MPa. At the time of cooling, it is preferable to pressurize by exhaust gas adjustment injection of compressed air and cooling water.
以下本発明の実施例について説明する。 Examples of the present invention will be described below.
実施例1〜3
実施例1としてハチミツレモン炭酸ゼリー、実施例2としてミカン炭酸ゼリー、実施例3としてブドウ炭酸ゼリーをそれぞれ以下の方法により製造した。実施例1〜3はいずれも250gアルミ缶または280gアルミ缶入りストロータイプの炭酸ガス含有ソフトゼリー飲料であり、生産数量はそれぞれ7000L仕込みである。
Examples 1-3
Honey lemon carbonate jelly as Example 1, mandarin orange jelly as Example 2, and grape carbonate jelly as Example 3 were produced by the following methods, respectively. Examples 1 to 3 are 250 g aluminum cans or 280 g aluminum can-containing straw type carbon dioxide-containing soft jelly beverages, each with a production quantity of 7000 L.
1.配合
各実施例のゲル化剤とシロップ(原材料液)の配合は下表1のとおりである。
1. Blending The blending of the gelling agent and syrup (raw material solution) in each example is as shown in Table 1 below.
2.処置
(1)純水に果糖ぶどう糖液糖を混合し、この混合液に寒天、ローカストビーンガム、キサンタンガム、ジェランガムからなるゲル化剤粉体を果糖粉体と粉体混合し、純水に分散の後、添加した。
(2)次にこの混合液に果汁を投入した。
(3)また上記配合中の酸および塩類を80℃前後の熱水で溶解した後20℃に冷却したものを前記混合液に添加した。
(4)さらに着色料および香料を混合液に添加して混合シロップ液を調合した。この時の温度は20℃であった。
(5)この混合液を4〜10℃に冷却した後カーボネーターに送り炭酸ガスを混合液中に含有せしめた(製品ボリューム1.8〜2.0相当)。
(6)次いで、炭酸ガス含有混合液を250gアルミ缶、または280gアルミ缶に充填・巻締めた。
(7)次いで、缶を蒸気式レトルト装置に送り、加熱時処理槽内部圧力0.05MPaの加圧下で105℃で6分間加熱することによりゲル化剤を溶解するとともに混合液を殺菌した。
(8)次いで、缶を25℃まで冷却して缶入り炭酸ガス含有飲料とした。冷却開始時の処理槽内部圧力は0.11MPaに調整した。
2. Treatment (1) Fructose-glucose liquid sugar is mixed with pure water, and a gelling agent powder composed of agar, locust bean gum, xanthan gum, and gellan gum is mixed with the fructose powder and dispersed in pure water. Later added.
(2) Next, fruit juice was added to this mixed solution.
(3) Further, the acid and salts in the above composition were dissolved in hot water at around 80 ° C. and then cooled to 20 ° C., and then added to the mixed solution.
(4) Further, a colorant and a flavor were added to the mixed solution to prepare a mixed syrup solution. The temperature at this time was 20 ° C.
(5) The mixed solution was cooled to 4 to 10 ° C. and then sent to a carbonator to contain carbon dioxide gas in the mixed solution (equivalent to a product volume of 1.8 to 2.0).
(6) Next, the carbon dioxide-containing mixed solution was filled into a 250 g aluminum can or a 280 g aluminum can and wound.
(7) Next, the can was sent to a steam retort apparatus, and the gelling agent was dissolved by heating at 105 ° C. for 6 minutes under an internal pressure of 0.05 MPa during heating, and the mixture was sterilized.
(8) Next, the can was cooled to 25 ° C. to obtain a canned carbon dioxide-containing beverage. The internal pressure of the treatment tank at the start of cooling was adjusted to 0.11 MPa.
3.製品評価
実施例1,2,3のいずれの飲料もシェイクタイプには適さない硬度の炭酸ゼリーで、外装に伸縮式のストローを添付して販売形態とした。
各飲料炭酸ゼリーの食感は、切れが良く、さっぱりとした破裂感のあるゼリーで、フレーバーリリースも良好であった。また炭酸の感じはゼリーの破裂と同時に口腔内で炭酸が広がる感じがあり、良好であった。
男性と女性からなる8人〜10人のパネルにより実施例1〜3の試飲を行った結果は下表2のとおりである。
3. Product Evaluation All beverages of Examples 1, 2, and 3 were made of carbonated jelly having a hardness not suitable for the shake type, and a stretchable straw was attached to the exterior to make a sales form.
The texture of each beverage carbonated jelly was crisp and refreshing, and the flavor release was also good. The feeling of carbonation was good because there was a feeling that carbonation spreads in the oral cavity at the same time as the jelly burst.
The results of tasting Examples 1 to 3 using a panel of 8 to 10 men and women are shown in Table 2 below.
実施例3および4
実施例4としてミカン炭酸ゼリー、実施例5としてブドウ炭酸ゼリーをそれぞれ以下の方法により製造した。実施例4、5はいずれも280gアルミ缶入りシェイクタイプの炭酸ガス含有ソフトゼリー飲料であり、生産数量はそれぞれ1000Lずつの仕込み量であった。
Examples 3 and 4
A mandarin orange carbonate jelly as Example 4 and a grape carbonate jelly as Example 5 were produced by the following methods, respectively. Examples 4 and 5 were both shake-type carbon dioxide-containing soft jelly beverages containing 280 g aluminum cans, and the production quantities were 1000 L each.
1. 配合
各実施例のゲル化剤とシロップ(原材料液)の配合は下表3のとおりである。
1. Blending The blending of the gelling agent and syrup (raw material solution) in each example is as shown in Table 3 below.
2.処置
(1)純水に果糖ぶどう糖液糖を混合し、この混合液に寒天、ローカストビーンガム、キサンタンガム、ジェランガムからなるゲル化剤粉体を果糖粉体と粉体混合して添加して分散させた。
(2)次にこの混合液に果汁、酸および塩類、着色料、香料を投入した。酸および塩類を80℃前後の熱水で溶解した後20〜30℃に冷却したものを前記混合液に添加した。こうして60%シロップ液を調合した。
この時の温度は20℃であった。
(3)この混合液を5〜10℃に冷却した。
(4)ガスボリューム4.4kg/cm2の炭酸水を調整し、この炭酸水をシロップ:炭酸水=3:2の比率でシロップと混合した。この時の炭酸水の液温は1〜5℃であった。
(5)次いで、炭酸水含有混合液を280gアルミ缶に充填・巻締めた後炭酸水とシロップ液を混合させるため、缶を10回転させた。
(6)次いで、缶を蒸気式レトルト装置に送り、加熱時処理槽内部圧力0.05MPaの加圧下で105℃で6分間加熱することによりゲル化剤を溶解するとともに混合液を殺菌した。
(7)次いで、缶を25℃まで冷却して缶入り炭酸ガス含有飲料とした。冷却開始時の処理槽内部圧力は0.11MPaに調整した。
2. Treatment (1) Mix fructose-glucose liquid sugar with pure water, and add and disperse the gelling powder composed of agar, locust bean gum, xanthan gum and gellan gum mixed with fructose powder. It was.
(2) Next, fruit juice, acids and salts, coloring agents, and fragrances were added to the mixed solution. What melt | dissolved the acid and salts with the hot water around 80 degreeC, and then cooled to 20-30 degreeC was added to the said liquid mixture. A 60% syrup solution was thus prepared.
The temperature at this time was 20 ° C.
(3) The mixed solution was cooled to 5 to 10 ° C.
(4) Carbonated water having a gas volume of 4.4 kg / cm 2 was prepared, and this carbonated water was mixed with syrup at a ratio of syrup: carbonated water = 3: 2. The temperature of the carbonated water at this time was 1 to 5 ° C.
(5) Next, the carbonated water-containing mixed solution was filled into a 280 g aluminum can and wound, and then the can was rotated 10 times to mix the carbonated water and the syrup solution.
(6) Next, the can was sent to a steam retort device, and the gelling agent was dissolved by heating at 105 ° C. for 6 minutes under an internal pressure of 0.05 MPa during heating, and the mixture was sterilized.
(7) Next, the can was cooled to 25 ° C. to obtain a canned carbon dioxide-containing beverage. The internal pressure of the treatment tank at the start of cooling was adjusted to 0.11 MPa.
3.製品評価
実施例3、4のいずれの飲料も、軽く5〜10回縦方向へのシェイキングで小さいゼリー粒状または塊に分解され、缶口より排出された。また液状になりすぎてはいなかった。
各飲料炭酸ゼリーの食感は、しっかりとしたゼリー感があり、塊が破砕するたびに炭酸が心地よい刺激を与えた。
男性と女性からなる11人のパネルにより実施例4、5の試飲を行った結果は下表4のとおりである。
3. Product Evaluation Both beverages of Examples 3 and 4 were lightly broken into small jelly granules or lumps by shaking in the vertical direction 5 to 10 times and discharged from the can mouth. It was not too liquid.
The texture of each beverage carbonated jelly had a firm jelly feel, and each time the lump was crushed, the carbonate gave a pleasant stimulus.
The results of tasting Examples 4 and 5 using a panel of 11 persons consisting of men and women are shown in Table 4 below.
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