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Publication number
JP2008300244A5
JP2008300244A5 JP2007146220A JP2007146220A JP2008300244A5 JP 2008300244 A5 JP2008300244 A5 JP 2008300244A5 JP 2007146220 A JP2007146220 A JP 2007146220A JP 2007146220 A JP2007146220 A JP 2007146220A JP 2008300244 A5 JP2008300244 A5 JP 2008300244A5
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Japan
Prior art keywords
secondary battery
electrolyte secondary
active material
aqueous electrolyte
positive electrode
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JP2007146220A
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Japanese (ja)
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JP2008300244A (en
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Priority to JP2007146220A priority Critical patent/JP2008300244A/en
Priority claimed from JP2007146220A external-priority patent/JP2008300244A/en
Publication of JP2008300244A publication Critical patent/JP2008300244A/en
Publication of JP2008300244A5 publication Critical patent/JP2008300244A5/ja
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Claims (10)

活物質を含む活物質層を有する非水電解液二次電池用正極において、該活物質層に、該活物質とは別にLiNi1-xTix2(式中、0<x<0.7である)で表される化合物が含有されていることを特徴とする非水電解液二次電池用正極。 In the positive electrode for a non-aqueous electrolyte secondary battery having an active material layer containing an active material, LiNi 1-x Ti x O 2 (where 0 <x <0. 7), and a positive electrode for a non-aqueous electrolyte secondary battery. 前記活物質が、リチウム遷移金属複合酸化物(但し、LiNi1-xTix2(式中、0<x<0.7である)を除く)からなる請求項1記載の非水電解液二次電池用正極。 The non-aqueous electrolyte according to claim 1, wherein the active material comprises a lithium transition metal composite oxide (excluding LiNi 1-x Ti x O 2 (where 0 <x <0.7)). Secondary battery positive electrode. 前記化合物のX線回折パターンにおける(003)面と(104)面とのピーク比であるI(003)/I(104)が0.4〜0.9である請求項1又は2記載の非水電解液二次電池用正極。   3. The non-specificity according to claim 1, wherein I (003) / I (104), which is a peak ratio between the (003) plane and the (104) plane in the X-ray diffraction pattern of the compound, is 0.4 to 0.9. Positive electrode for water electrolyte secondary battery. 前記活物質の量に対する前記化合物の量の割合が5〜30重量%である請求項1ないし3の何れかに記載の非水電解液二次電池用正極。   The positive electrode for a non-aqueous electrolyte secondary battery according to any one of claims 1 to 3, wherein a ratio of the amount of the compound to the amount of the active material is 5 to 30% by weight. LiNi1-xTix2(式中、0<x<0.7である)で表される化合物からなることを特徴とする非水電解液二次電池用正極活物質の添加剤。 An additive for a positive electrode active material for a non-aqueous electrolyte secondary battery, comprising a compound represented by LiNi 1-x Ti x O 2 (where 0 <x <0.7). 請求項1ないし4の何れかに記載の正極を備えた非水電解液二次電池。   A non-aqueous electrolyte secondary battery comprising the positive electrode according to claim 1. Si又はSnを含む材料からなる負極活物質を含む活物質層を有する負極を備えた請求項6記載の非水電解液二次電池。   The nonaqueous electrolyte secondary battery according to claim 6, comprising a negative electrode having an active material layer containing a negative electrode active material made of a material containing Si or Sn. 前記負極の活物質層が、Si又はSnを含む負極活物質の粒子を含有し、該粒子の表面の少なくとも一部がリチウム化合物の形成能の低い金属材料で被覆されていると共に、該金属材料で被覆された該粒子どうしの間に空隙が形成されている請求項7記載の非水電解液二次電池。   The active material layer of the negative electrode contains particles of a negative electrode active material containing Si or Sn, and at least a part of the surface of the particles is coated with a metal material having a low ability to form a lithium compound, and the metal material The nonaqueous electrolyte secondary battery according to claim 7, wherein voids are formed between the particles coated with. 請求項6ないし8のいずれかに記載の非水電解液二次電池に対して充電を行うときに、該電池を組み立てた後に初めて行う充電である予備充電のカットオフ電位を、Li/LiWhen charging the nonaqueous electrolyte secondary battery according to any one of claims 6 to 8, the precharge cutoff potential, which is charging performed for the first time after the battery is assembled, is Li / Li. ++ を基準として4.2〜5.0Vに設定することを特徴とする非水電解液二次電池の調整方法。The non-aqueous electrolyte secondary battery adjustment method is characterized in that the voltage is set to 4.2 to 5.0 V with reference to. 予備充電より後の充電である初回以降の充電のカットオフ電圧を、予備充電のカットオフ電圧と同じか又はそれよりも設定して充電を行う請求項9記載の非水電解液二次電池の調整方法。The non-aqueous electrolyte secondary battery according to claim 9, wherein the charge is performed by setting a cut-off voltage of charge after the first time that is charge after the pre-charge to be equal to or higher than the cut-off voltage of the pre-charge. Adjustment method.
JP2007146220A 2007-05-31 2007-05-31 Positive electrode for nonaqueous electrolyte secondary battery Withdrawn JP2008300244A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2007146220A JP2008300244A (en) 2007-05-31 2007-05-31 Positive electrode for nonaqueous electrolyte secondary battery

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Application Number Priority Date Filing Date Title
JP2007146220A JP2008300244A (en) 2007-05-31 2007-05-31 Positive electrode for nonaqueous electrolyte secondary battery

Publications (2)

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JP2008300244A JP2008300244A (en) 2008-12-11
JP2008300244A5 true JP2008300244A5 (en) 2009-02-05

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JP2007146220A Withdrawn JP2008300244A (en) 2007-05-31 2007-05-31 Positive electrode for nonaqueous electrolyte secondary battery

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Families Citing this family (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPWO2010113268A1 (en) * 2009-03-31 2012-10-04 三菱重工業株式会社 Lithium ion secondary battery and battery system
JP5532296B2 (en) * 2009-06-24 2014-06-25 トヨタ自動車株式会社 Lithium secondary battery and manufacturing method thereof
US9666896B2 (en) 2009-11-25 2017-05-30 Mitsui Mining & Smelting Co., Ltd. Positive electrode for nonaqueous secondary battery
WO2015016548A1 (en) 2013-07-30 2015-02-05 주식회사 엘지화학 Cathode mix for secondary battery having irreversible additive
CN114788065A (en) * 2020-09-21 2022-07-22 株式会社Lg新能源 Method for activating lithium secondary battery and lithium secondary battery

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