JP2008029689A - Aldehyde gas filter - Google Patents
Aldehyde gas filter Download PDFInfo
- Publication number
- JP2008029689A JP2008029689A JP2006207986A JP2006207986A JP2008029689A JP 2008029689 A JP2008029689 A JP 2008029689A JP 2006207986 A JP2006207986 A JP 2006207986A JP 2006207986 A JP2006207986 A JP 2006207986A JP 2008029689 A JP2008029689 A JP 2008029689A
- Authority
- JP
- Japan
- Prior art keywords
- silver
- manufactured
- iron
- removal
- nacalai tesque
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 125000002485 formyl group Chemical class [H]C(*)=O 0.000 title claims abstract description 16
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims abstract description 45
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims abstract description 15
- 229910052709 silver Inorganic materials 0.000 claims abstract description 15
- 239000004332 silver Substances 0.000 claims abstract description 15
- OVMJVEMNBCGDGM-UHFFFAOYSA-N iron silver Chemical compound [Fe].[Ag] OVMJVEMNBCGDGM-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 abstract description 24
- 238000003912 environmental pollution Methods 0.000 abstract description 6
- 230000008030 elimination Effects 0.000 abstract 1
- 238000003379 elimination reaction Methods 0.000 abstract 1
- IKHGUXGNUITLKF-UHFFFAOYSA-N Acetaldehyde Chemical compound CC=O IKHGUXGNUITLKF-UHFFFAOYSA-N 0.000 description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 20
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 18
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 16
- 239000007789 gas Substances 0.000 description 14
- 239000000126 substance Substances 0.000 description 13
- SQGYOTSLMSWVJD-UHFFFAOYSA-N silver(1+) nitrate Chemical compound [Ag+].[O-]N(=O)=O SQGYOTSLMSWVJD-UHFFFAOYSA-N 0.000 description 12
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 9
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 8
- 229910052782 aluminium Inorganic materials 0.000 description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 8
- 239000007864 aqueous solution Substances 0.000 description 8
- 230000000052 comparative effect Effects 0.000 description 8
- RGPUVZXXZFNFBF-UHFFFAOYSA-K diphosphonooxyalumanyl dihydrogen phosphate Chemical compound [Al+3].OP(O)([O-])=O.OP(O)([O-])=O.OP(O)([O-])=O RGPUVZXXZFNFBF-UHFFFAOYSA-K 0.000 description 8
- AMWRITDGCCNYAT-UHFFFAOYSA-L hydroxy(oxo)manganese;manganese Chemical compound [Mn].O[Mn]=O.O[Mn]=O AMWRITDGCCNYAT-UHFFFAOYSA-L 0.000 description 8
- MVFCKEFYUDZOCX-UHFFFAOYSA-N iron(2+);dinitrate Chemical compound [Fe+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MVFCKEFYUDZOCX-UHFFFAOYSA-N 0.000 description 8
- NDVLTYZPCACLMA-UHFFFAOYSA-N silver oxide Chemical compound [O-2].[Ag+].[Ag+] NDVLTYZPCACLMA-UHFFFAOYSA-N 0.000 description 8
- 235000010413 sodium alginate Nutrition 0.000 description 8
- 229940005550 sodium alginate Drugs 0.000 description 8
- 239000000661 sodium alginate Substances 0.000 description 8
- 238000000034 method Methods 0.000 description 7
- 229910001961 silver nitrate Inorganic materials 0.000 description 6
- 150000001412 amines Chemical class 0.000 description 5
- 230000000694 effects Effects 0.000 description 5
- 239000000243 solution Substances 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 5
- CIWBSHSKHKDKBQ-JLAZNSOCSA-N Ascorbic acid Chemical compound OC[C@H](O)[C@H]1OC(=O)C(O)=C1O CIWBSHSKHKDKBQ-JLAZNSOCSA-N 0.000 description 4
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 4
- 150000002506 iron compounds Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 150000004690 nonahydrates Chemical class 0.000 description 4
- 229920002620 polyvinyl fluoride Polymers 0.000 description 4
- 229910001923 silver oxide Inorganic materials 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- IKHGUXGNUITLKF-XPULMUKRSA-N acetaldehyde Chemical compound [14CH]([14CH3])=O IKHGUXGNUITLKF-XPULMUKRSA-N 0.000 description 3
- 239000003054 catalyst Substances 0.000 description 3
- 239000000706 filtrate Substances 0.000 description 3
- 238000001914 filtration Methods 0.000 description 3
- 238000005342 ion exchange Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 230000007935 neutral effect Effects 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 238000001179 sorption measurement Methods 0.000 description 3
- ATRRKUHOCOJYRX-UHFFFAOYSA-N Ammonium bicarbonate Chemical compound [NH4+].OC([O-])=O ATRRKUHOCOJYRX-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- 241000208125 Nicotiana Species 0.000 description 2
- 235000002637 Nicotiana tabacum Nutrition 0.000 description 2
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 2
- 239000001099 ammonium carbonate Substances 0.000 description 2
- 235000012501 ammonium carbonate Nutrition 0.000 description 2
- 229960005070 ascorbic acid Drugs 0.000 description 2
- 235000010323 ascorbic acid Nutrition 0.000 description 2
- 239000011668 ascorbic acid Substances 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 229940044631 ferric chloride hexahydrate Drugs 0.000 description 2
- NQXWGWZJXJUMQB-UHFFFAOYSA-K iron trichloride hexahydrate Chemical compound O.O.O.O.O.O.[Cl-].Cl[Fe+]Cl NQXWGWZJXJUMQB-UHFFFAOYSA-K 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000000691 measurement method Methods 0.000 description 2
- 229910044991 metal oxide Inorganic materials 0.000 description 2
- 150000004706 metal oxides Chemical class 0.000 description 2
- WSFSSNUMVMOOMR-NJFSPNSNSA-N methanone Chemical compound O=[14CH2] WSFSSNUMVMOOMR-NJFSPNSNSA-N 0.000 description 2
- 239000004570 mortar (masonry) Substances 0.000 description 2
- 230000027756 respiratory electron transport chain Effects 0.000 description 2
- 229940100890 silver compound Drugs 0.000 description 2
- 150000003379 silver compounds Chemical class 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000003463 adsorbent Substances 0.000 description 1
- 230000000274 adsorptive effect Effects 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 238000000975 co-precipitation Methods 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000001877 deodorizing effect Effects 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 229910001873 dinitrogen Inorganic materials 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000002149 energy-dispersive X-ray emission spectroscopy Methods 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002505 iron Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- SZQUEWJRBJDHSM-UHFFFAOYSA-N iron(3+);trinitrate;nonahydrate Chemical compound O.O.O.O.O.O.O.O.O.[Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O SZQUEWJRBJDHSM-UHFFFAOYSA-N 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 150000002894 organic compounds Chemical class 0.000 description 1
- VFWRGKJLLYDFBY-UHFFFAOYSA-N silver;hydrate Chemical compound O.[Ag].[Ag] VFWRGKJLLYDFBY-UHFFFAOYSA-N 0.000 description 1
- GGCZERPQGJTIQP-UHFFFAOYSA-N sodium;9,10-dioxoanthracene-2-sulfonic acid Chemical compound [Na+].C1=CC=C2C(=O)C3=CC(S(=O)(=O)O)=CC=C3C(=O)C2=C1 GGCZERPQGJTIQP-UHFFFAOYSA-N 0.000 description 1
- 239000002759 woven fabric Substances 0.000 description 1
Landscapes
- Disinfection, Sterilisation Or Deodorisation Of Air (AREA)
- Catalysts (AREA)
Abstract
Description
本発明は、アルデヒド類ガスの優れた除去フィルターに関し、更に詳しくは、常温で長期にわたって除去性能を維持できるアルデヒド類ガス除去フィルターに関する。 The present invention relates to an excellent removal filter for aldehyde gases, and more particularly to an aldehyde gas removal filter that can maintain removal performance over a long period of time at room temperature.
従来より、建物の室内や自動車の車内等におけるタバコ臭の除去を主目的とした脱臭フィルターが広く用いられている。これらは、タバコ臭の主成分であるアセトアルデヒド、あるいはシックハウスの原因物質であるホルムアルデヒド等の除去を目的とするものであり、これらのフィルターに含有される除去剤は多くの検討がなされている。 2. Description of the Related Art Conventionally, a deodorizing filter mainly used for removing tobacco odor in a room of a building or an automobile is widely used. These are intended to remove acetaldehyde, which is the main component of tobacco odor, or formaldehyde, which is a causative substance of sick house, and many studies have been made on the remover contained in these filters.
活性炭は各種有機物質を吸着除去する除去剤として古くから知られているが、低分子で高極性の有機物（例えば、アセトアルデヒド、ホルムアルデヒド等）は十分吸着除去することができず、上述の用途に用いる場合は、活性炭にアミン類やアスコルビン酸等を担持させて吸着除去能を高めたものが用いられている。 Activated charcoal has long been known as a remover for adsorbing and removing various organic substances, but it cannot sufficiently adsorb and remove low-molecular and high-polarity organic substances (for example, acetaldehyde, formaldehyde, etc.) and is used for the above-mentioned applications. In such a case, activated carbon having amines, ascorbic acid or the like supported on the activated carbon to enhance the adsorption removal ability is used.
このように、アミン類を担持させたものとしては、例えば、アニリンを用いたものや（例えば特許文献１参照）、エタノール系アミン等を用いたものが開示されている（例えば特許文献２参照）。 Thus, as what carried amines, what used aniline (for example, refer to patent documents 1), and what used ethanol system amine etc. are indicated (for example, refer to patent documents 2). .
しかしながら、アミン類を担持させる技術は、担持アミン類の状態は不安定であることから、熱的および経時的な化学変化による失活が起こりやすく、長期にわたって満足すべき除去性能を発現することが困難であるという問題がある。また、アスコルビン酸においても、吸湿すると空気中で容易に酸化分解され、失活してしまい性能劣化が起こるという問題がある。 However, the technology for supporting amines is unstable in the state of the supported amines, and thus is easily deactivated due to thermal and chemical changes over time, and can exhibit satisfactory removal performance over a long period of time. There is a problem that it is difficult. In addition, ascorbic acid also has a problem that when it absorbs moisture, it is easily oxidized and decomposed in the air and deactivated, resulting in performance deterioration.
一方、アルデヒド類ガスの除去剤として、酸化鉄等の金属酸化物が近年注目を集めている。前記金属酸化物として、例えば、酸化鉄、銀担持アルミナがある（例えば非特許文献１参照）。 On the other hand, metal oxides such as iron oxide have recently attracted attention as aldehyde gas removers. Examples of the metal oxide include iron oxide and silver-carrying alumina (see Non-Patent Document 1, for example).
しかしながら、かかる酸化鉄、もしくは銀担持アルミナは、十分な除去活性を得るためには、高温条件が必要であり、一般生活における温湿度領域では、除去活性が低く、十分な除去性能が得られないという問題がある。 However, such iron oxide or silver-carrying alumina requires high temperature conditions in order to obtain sufficient removal activity, and the removal activity is low in the temperature and humidity range in general life, and sufficient removal performance cannot be obtained. There is a problem.
また、銀酸化物粒子とマンガン酸化物粒子からなるマンガン酸化物含有物、および、酸化鉄によるホルムアルデヒドの分解除去が開示されている（例えば特許文献３参照）。しかしながら、かかるマンガン酸化物含有物は、ＰＲＴＲ第一種指定化学物質であるマンガン酸化物が含有されており、環境汚染の懸念があるという問題がある。また、開示されている酸化鉄（Ｆｅ２Ｏ３）のみでは、一般生活における温湿度領域では活性が低く、十分な除去性能を得られないという問題がある。 Further, a manganese oxide-containing material composed of silver oxide particles and manganese oxide particles, and decomposition removal of formaldehyde with iron oxide are disclosed (for example, see Patent Document 3). However, such a manganese oxide-containing material contains a manganese oxide which is a PRTR type 1 designated chemical substance, and there is a problem that there is a concern of environmental pollution. Further, only the disclosed iron oxide (Fe 2 O 3 ) has a problem that the activity is low in the temperature and humidity range in general life, and sufficient removal performance cannot be obtained.
また、吸着性多孔質担体に銀及び／又は銀化合物を担持して成ることを特徴とする悪臭物質除去用触媒が開示されている（例えば特許文献４参照）。しかしながら、かかる悪臭物質除去用触媒では一般生活における温湿度領域における活性が低く、十分な除去性能を得られないという問題がある。 Moreover, a malodorous substance removal catalyst characterized by comprising silver and / or a silver compound supported on an adsorptive porous carrier is disclosed (for example, see Patent Document 4). However, such a malodorous substance removal catalyst has a problem that its activity in the temperature and humidity range in general life is low and sufficient removal performance cannot be obtained.
上述のとおり、一般生活における温湿度領域で、環境汚染への影響が低く、かつ、長期にわたって除去性能を維持できるアルデヒド類ガス除去フィルターは見当たらないのが現状である。ここで言う、一般生活における温湿度領域とは、温度範囲でおおよそ−３０〜５０℃、湿度範囲でおおよそ２０〜９５ＲＨ％のことである。 As described above, there is no aldehyde gas removal filter that has a low influence on environmental pollution and can maintain removal performance over a long period of time in the temperature and humidity range in general life. The temperature / humidity region in general life referred to here is approximately −30 to 50 ° C. in the temperature range and approximately 20 to 95 RH% in the humidity range.
本発明は上記従来技術の課題を背景になされたものであり、一般生活における温湿度領域で長期にわたって満足すべき除去性能を発現することができ、かつ、環境汚染への影響が低いアルデヒド類ガス除去フィルターを提供することを目的とする。 The present invention has been made against the background of the above-described prior art, and can exhibit satisfactory removal performance over a long period of time in the temperature and humidity range in general life and has low influence on environmental pollution. An object is to provide a removal filter.
本発明者らは上記課題を解決するため、鋭意研究した結果、遂に本発明を完成するに到った。すなわち本発明は、（１）銀元素（Ａｇ）と鉄元素（Ｆｅ）をＡｇ／Ｆｅ（モル比）＝０．００１〜１の範囲で含有し、かつ、（２）ＢＥＴ比表面積が５０ｍ２／ｇ以上であることを特徴とする銀−鉄系除去剤を含有するアルデヒド類ガス除去フィルターである。 As a result of intensive studies to solve the above problems, the present inventors have finally completed the present invention. That is, the present invention contains (1) a silver element (Ag) and an iron element (Fe) in the range of Ag / Fe (molar ratio) = 0.001 to 1, and (2) a BET specific surface area of 50 m 2. / G or more is an aldehyde gas removal filter containing a silver-iron removal agent.
本発明によるアルデヒド類ガス除去フィルターは、銀元素（Ａｇ）と鉄元素（Ｆｅ）をＡｇ／Ｆｅ（モル比）＝０．００１〜１の範囲で含有し、かつ、ＢＥＴ比表面積が５０ｍ２／ｇ以上である銀−鉄系除去剤を含有しているため、一般生活における温湿度領域で、長期にわたっての高性能な除去が可能であり、また、環境汚染への影響が少ないという利点を有する。 The aldehyde gas removal filter according to the present invention contains silver element (Ag) and iron element (Fe) in a range of Ag / Fe (molar ratio) = 0.001 to 1, and a BET specific surface area of 50 m 2 /. Since it contains a silver-iron-based removal agent that is greater than or equal to g, it has the advantage that high-performance removal over a long period of time is possible in the temperature and humidity range in general life, and there is little impact on environmental pollution. .
以下、本発明を詳細に説明する。本発明におけるアルデヒド類ガス除去フィルターは銀−鉄系除去剤を含有することが好ましい。銀−鉄系除去剤のフィルター全体に対する含有比率、および、銀−鉄系除去剤を除くその他の成分については特に限定しない。その他の成分としては、活性炭等の一般的な吸着剤、触媒等の他に、不織布、織布、ペーパー等といったフィルター基材、および、それらをつなぎ合わせるバインダー、結着剤が含まれる。 Hereinafter, the present invention will be described in detail. The aldehyde gas removal filter in the present invention preferably contains a silver-iron-based removal agent. The content ratio of the silver-iron-based remover to the entire filter and other components other than the silver-iron-based remover are not particularly limited. As other components, in addition to a general adsorbent such as activated carbon, a catalyst, and the like, a filter base material such as a nonwoven fabric, a woven fabric, and a paper, and a binder and a binder for connecting them are included.
前記銀−鉄系除去剤において、銀元素（Ａｇ）と鉄元素（Ｆｅ）をＡｇ／Ｆｅ（モル比）＝０．００１〜１の範囲で含有することが好ましい。より好ましくは、０．０１〜０．５である。さらに好ましくは、０．１〜０．５である。銀元素（Ａｇ）のみ、もしくは、鉄元素（Ｆｅ）のみを含有する有機化合物除去剤では一般生活における温湿度領域において十分な除去性能は実現できない。しかしながら、銀元素（Ａｇ）と鉄元素（Ｆｅ）をＡｇ／Ｆｅ（モル比）＝０．００１〜１の範囲で含有すると、その相乗効果により非常に高い除去性能を実現することができることを本発明者は見出した。相乗効果のメカニズムは明確ではないが、次の（１）〜（４）のように推測される。つまり、最初に、（１）アルデヒド類ガスが鉄元素上に捕捉される、さらに、（２）鉄元素上に捕捉されたアルデヒド類ガスが鉄の電子授受作用により活性化され分解されやすい状態になる、最後に、（３）そのごく近傍に位置する銀元素により、鉄元素上で活性化されたアルデヒド類ガスが分解される。その際、（４）近傍に位置する鉄元素からの電子授受作用を受け、銀元素においても、その分解力が向上していると考えられる。Ａｇ／Ｆｅ（モル比）が１より大きい場合と、鉄元素が銀元素により被覆され、前記相乗効果のメカニズムにおける（１）、および、（２）が阻害されてしまい、相乗効果が小さくなり、その結果、十分な除去性能が実現できなくなる。一方、Ａｇ／Ｆｅ（モル比）が０．００１より小さいと、銀化合物が少な過ぎるため、前記相乗効果のメカニズムにおける（３）の影響が小さくなり、結果として、十分な除去性能が実現できなくなる。 The silver-iron-based removal agent preferably contains silver element (Ag) and iron element (Fe) in a range of Ag / Fe (molar ratio) = 0.001 to 1. More preferably, it is 0.01-0.5. More preferably, it is 0.1-0.5. With an organic compound remover containing only silver element (Ag) or only iron element (Fe), sufficient removal performance cannot be realized in the temperature and humidity range in general life. However, when silver element (Ag) and iron element (Fe) are contained in the range of Ag / Fe (molar ratio) = 0.001 to 1, it is possible to realize very high removal performance due to the synergistic effect. The inventor found out. The mechanism of the synergistic effect is not clear, but is presumed as the following (1) to (4). That is, first, (1) the aldehyde gas is trapped on the iron element, and (2) the aldehyde gas trapped on the iron element is activated and easily decomposed by the electron transfer function of iron. Finally, (3) the aldehyde gas activated on the iron element is decomposed by the silver element located in the very vicinity thereof. At that time, (4) it is considered that the decomposing power is improved also in the silver element due to the electron transfer action from the iron element located in the vicinity. When Ag / Fe (molar ratio) is larger than 1, the iron element is coated with silver element, and (1) and (2) in the mechanism of the synergistic effect are inhibited, and the synergistic effect is reduced, As a result, sufficient removal performance cannot be realized. On the other hand, if Ag / Fe (molar ratio) is less than 0.001, the amount of silver compound is too small, and the influence of (3) in the mechanism of the synergistic effect is reduced, and as a result, sufficient removal performance cannot be realized. .
前記銀−鉄系除去剤におけるＢＥＴ比表面積は、５０ｍ２／ｇ以上であることが好ましい。ＢＥＴ比表面積が５０ｍ２／ｇ以上であれば、低温での高い除去性能を実現することができることを本発明者は見出したからである。より好ましくは１００ｍ２／ｇ以上であり、更に好ましくは１５０ｍ２／ｇ以上である。ＢＥＴ比表面積の上限は特に限定するものではないが、１０００ｍ２／ｇ以下であることが好ましい。この範囲を超えると、除去性能はほとんど変化しない一方で、製造が非常に困難になるという不都合が生じるからである。 It is preferable that the BET specific surface area in the said silver-iron type removal agent is 50 m < 2 > / g or more. This is because the present inventor has found that if the BET specific surface area is 50 m 2 / g or more, high removal performance at low temperatures can be realized. More preferably, it is 100 m < 2 > / g or more, More preferably, it is 150 m < 2 > / g or more. The upper limit of the BET specific surface area is not particularly limited, but is preferably 1000 m 2 / g or less. If this range is exceeded, the removal performance is hardly changed, but the disadvantage is that manufacturing becomes very difficult.
本発明における銀−鉄系除去剤の製造方法は特に定めない。例えば、酸化銀と酸化鉄を乳鉢等で機械的に混合する方法、銀塩、鉄塩および有機酸を含有する溶液を乾燥、焼成して製造する方法、酸化鉄粒子の分散液中で酸化銀を沈殿させる方法、酸化鉄と酸化銀を同時に沈殿させる共沈法等が挙げられる。 The method for producing the silver-iron-based removal agent in the present invention is not particularly defined. For example, a method of mechanically mixing silver oxide and iron oxide in a mortar or the like, a method of drying and baking a solution containing silver salt, iron salt and organic acid, silver oxide in a dispersion of iron oxide particles And a coprecipitation method in which iron oxide and silver oxide are simultaneously precipitated.
本発明におけるアルデヒド類ガス除去フィルターの形状に関しては特に定めない。例えば、ハニカム形状、プリーツ形状等の一般的なフィルター形状が挙げられる。 The shape of the aldehyde gas removal filter in the present invention is not particularly defined. For example, common filter shapes, such as a honeycomb shape and a pleat shape, are mentioned.
以下、実施例によって本発明の作用効果をより具体的に示す。下記実施例は本発明方法を限定するものではなく、前・後記の趣旨に沿って設計変更することはいずれも本発明の技術的範囲に含まれるものである。 Hereinafter, the effects of the present invention will be described more specifically by way of examples. The following examples do not limit the method of the present invention, and any design change in accordance with the gist of the preceding and following description is within the technical scope of the present invention.
（ＢＥＴ比表面積の測定方法）
除去剤サンプルを約１００ｍｇ採取し、１２０℃で１２時間真空乾燥した後、秤量した。自動比表面積装置ジェミニ２３７５（マイクロメリティックス社製）を使用し、液体窒素の沸点（−１９５．８℃）における窒素ガスの吸着量を相対圧が０．０２〜０．９５の範囲で徐々に高めながら４０点測定し、上記サンプルの吸着等温線を作製した。相対圧０．０２〜０．１５での結果をＢＥＴプロットし、重量当りのＢＥＴ比表面積［ｍ２／ｇ］を求めた。
(Measurement method of BET specific surface area)
About 100 mg of a remover sample was collected, vacuum-dried at 120 ° C. for 12 hours, and weighed. Using an automatic specific surface area device Gemini 2375 (manufactured by Micromeritics), the adsorption amount of nitrogen gas at the boiling point of liquid nitrogen (-195.8 ° C.) is gradually increased in a range of relative pressure of 0.02 to 0.95. The sample was measured at 40 points while increasing the temperature to obtain an adsorption isotherm of the sample. The results at a relative pressure of 0.02 to 0.15 were BET plotted to determine the BET specific surface area [m 2 / g] per weight.
（アセトアルデヒド除去性能の測定方法）
５Ｌのテドラーバッグ中にアセトアルデヒド１００ｐｐｍを含む温度２５℃、湿度５０ＲＨ％の空気、および、１ｃｃの大きさのフィルターサンプルを封入した。中に入っているフィルターサンプルとアセトアルデヒドを含む空気が十分に接触、反応するように、テドラーバッグを適宜振った。なお、テドラーバッグ周囲の雰囲気温度は２５℃とした。３時間後のテドラーバッグ内のアセトアルデヒドガス濃度をＦＩＤ付きガスクロマトグラフにて測定し、反応前後のアセトアルデヒドの濃度変化からアセトアルデヒド除去量［ｍｇ］を求め、これをフィルターサンプルの大きさで割ることにより、除去容量［ｍｇ／ｃｃ］を算出した。
(Method for measuring acetaldehyde removal performance)
In a 5 L Tedlar bag, air having a temperature of 25 ° C. containing 100 ppm of acetaldehyde, air having a humidity of 50 RH%, and a filter sample having a size of 1 cc were enclosed. The Tedlar bag was shaken appropriately so that the filter sample contained therein and the air containing acetaldehyde sufficiently contacted and reacted. The ambient temperature around the Tedlar bag was 25 ° C. Measure the acetaldehyde gas concentration in the Tedlar bag after 3 hours with a gas chromatograph with FID, determine the acetaldehyde removal amount [mg] from the change in the concentration of acetaldehyde before and after the reaction, and divide this by the size of the filter sample. The capacity [mg / cc] was calculated.
（Ａｇ／Ｆｅ比の測定方法）
エネルギー分散型蛍光Ｘ線分析装置（ＳＨＩＭＡＤＺＵ製ＥＤＸ−８００）を使用し、ＦＰ法（ファンダメンタルパラメータ法）で、除去剤サンプルの銀元素、および、鉄元素の含有率（重量分率）を測定した。さらに、得られた含有率をモル分率に変換した後、銀元素モル分率を鉄元素モル分率で割ることによりＡｇ／Ｆｅ比（モル比）を算出した。
(Measurement method of Ag / Fe ratio)
Using an energy dispersive X-ray fluorescence spectrometer (EDX-800 manufactured by SHIMADZU), the content (weight fraction) of the silver element and iron element of the remover sample was measured by the FP method (fundamental parameter method). . Furthermore, after converting the obtained content rate into a mole fraction, the Ag / Fe ratio (molar ratio) was calculated by dividing the silver element mole fraction by the iron element mole fraction.
（実施例１）
硝酸鉄（ＩＩＩ）九水和物（和光純薬社製）５ｇ、硝酸銀（ナカライテスク社製）２１ｍｇ、クエン酸（ナカライテスク社製）２．３８ｇを１０ｍｌのイオン交換水に溶解させ、６０分間撹拌した。その水溶液を真空乾燥した後、電気炉で温度３００℃条件下１時間焼成処理を施したところ除去剤が得られた。得られた除去剤について、ＢＥＴ比表面積、Ａｇ／Ｆｅ比を測定した。
さらに、得られた除去剤６０ｍｇ、リン酸二水素アルミニウム（ナカライテスク社製）２０ｍｇ、アルギン酸ナトリウム（ナカライテスク社製）２０ｍｇをイオン交換水１ｍｌ中に投入し、よく撹拌して、ペーストが得られた。前記ペースト中に４３０セル／ｉｎｃｈ２のセル数を有するアルミ製ハニカム２ｃｃを投入し、ペースト全量をハニカム上に添着した。さらに、１２０℃条件で乾燥して、フィルターサンプルが得られた。得られたフィルターサンプルについてアセトアルデヒド除去性能を測定した。
(Example 1)
Iron nitrate (III) nonahydrate (manufactured by Wako Pure Chemical Industries, Ltd.) 5 g, silver nitrate (manufactured by Nacalai Tesque) 21 mg, citric acid (manufactured by Nacalai Tesque) 2.38 g are dissolved in 10 ml of ion-exchanged water for 60 minutes. Stir. The aqueous solution was vacuum-dried and then baked in an electric furnace at a temperature of 300 ° C. for 1 hour to obtain a remover. About the obtained removal agent, BET specific surface area and Ag / Fe ratio were measured.
Further, 60 mg of the obtained removing agent, 20 mg of aluminum dihydrogen phosphate (manufactured by Nacalai Tesque), and 20 mg of sodium alginate (manufactured by Nacalai Tesque) were put into 1 ml of ion-exchanged water and stirred well to obtain a paste. It was. 2 cc of an aluminum honeycomb having a cell number of 430 cells / inch 2 was put into the paste, and the whole paste was adhered onto the honeycomb. Furthermore, it dried on 120 degreeC conditions, and the filter sample was obtained. The filter sample obtained was measured for acetaldehyde removal performance.
（実施例２）
塩化第２鉄六水和物（ナカライテスク社製）１３．５ｇを６０ｍｌのイオン交換水に溶解させ、３０％過酸化水素水（ナカライテスク社製）５．０ｇ添加した後、１５分間撹拌した。その後、炭酸アンモニウム（ナカライテスク社製）１２．０ｇを含有する水溶液１００ｍｌをゆっくりと添加した。添加後、１時間撹拌した。得られた溶液を濾別し、イオン交換水で濾液が中性になるまで水洗した後、８０℃、窒素気流下で一昼夜乾燥したところ、鉄化合物が得られた。
硝酸銀（ナカライテスク社製）６３８ｍｇを３００ｍｌのイオン交換水に溶解させ、上記で得られた鉄化合物３．０ｇを添加し、よく撹拌した。さらに、２％水酸化ナトリウム水溶液１５ｇをゆっくりと添加し、終夜撹拌した。得られた溶液を濾別し、イオン交換水で濾液が中性になるまで水洗した後、８０℃、窒素気流下で一昼夜乾燥したところ、除去剤が得られた。得られた除去剤について、ＢＥＴ比表面積、Ａｇ／Ｆｅ比を測定した。
さらに、得られた除去剤６０ｍｇ、リン酸二水素アルミニウム（ナカライテスク社製）２０ｍｇ、アルギン酸ナトリウム（ナカライテスク社製）２０ｍｇをイオン交換水１ｍｌ中に投入し、よく撹拌して、ペーストが得られた。前記ペースト中に４３０セル／ｉｎｃｈ２のセル数を有するアルミ製ハニカム２ｃｃを投入し、ペースト全量をハニカム上に添着した。さらに、１２０℃条件で乾燥して、フィルターサンプルが得られた。得られたフィルターサンプルについてアセトアルデヒド除去性能を測定した。
(Example 2)
13.5 g of ferric chloride hexahydrate (manufactured by Nacalai Tesque) was dissolved in 60 ml of ion-exchanged water, 5.0 g of 30% hydrogen peroxide (manufactured by Nacalai Tesque) was added, and the mixture was stirred for 15 minutes. . Thereafter, 100 ml of an aqueous solution containing 12.0 g of ammonium carbonate (manufactured by Nacalai Tesque) was slowly added. After the addition, the mixture was stirred for 1 hour. The obtained solution was separated by filtration, washed with ion-exchanged water until the filtrate became neutral, and then dried at 80 ° C. under a nitrogen stream for 24 hours to obtain an iron compound.
638 mg of silver nitrate (manufactured by Nacalai Tesque) was dissolved in 300 ml of ion exchange water, and 3.0 g of the iron compound obtained above was added and stirred well. Further, 15 g of 2% aqueous sodium hydroxide solution was slowly added and stirred overnight. The obtained solution was separated by filtration, washed with ion exchange water until the filtrate became neutral, and then dried at 80 ° C. under a nitrogen stream for 24 hours to obtain a remover. About the obtained removal agent, BET specific surface area and Ag / Fe ratio were measured.
Further, 60 mg of the obtained removing agent, 20 mg of aluminum dihydrogen phosphate (manufactured by Nacalai Tesque), and 20 mg of sodium alginate (manufactured by Nacalai Tesque) were put into 1 ml of ion-exchanged water and stirred well to obtain a paste. It was. 2 cc of an aluminum honeycomb having a cell number of 430 cells / inch 2 was put into the paste, and the whole paste was adhered onto the honeycomb. Furthermore, it dried on 120 degreeC conditions, and the filter sample was obtained. The filter sample obtained was measured for acetaldehyde removal performance.
（実施例３）
塩化第２鉄六水和物（ナカライテスク社製）１３．５ｇを６０ｍｌのイオン交換水に溶解させ、３０％過酸化水素水（ナカライテスク社製）５．０ｇ添加した後、１５分間撹拌した。その後、炭酸アンモニウム（ナカライテスク社製）１２．０ｇを含有する水溶液１００ｍｌをゆっくりと添加した。添加後、１時間撹拌した。得られた溶液を濾別し、イオン交換水で濾液が中性になるまで水洗した後、８０℃、窒素気流下で一昼夜乾燥したところ、鉄化合物が得られた。
酸化銀（Ｉ）（和光純薬工業製）４３５ｍｇと上記で得られた鉄化合物３．０ｇをメノウ乳鉢で混合し、除去剤を得た。得られた除去剤について、ＢＥＴ比表面積、Ａｇ／Ｆｅ比を測定した。
さらに、得られた除去剤６０ｍｇ、リン酸二水素アルミニウム（ナカライテスク社製）２０ｍｇ、アルギン酸ナトリウム（ナカライテスク社製）２０ｍｇをイオン交換水１ｍｌ中に投入し、よく撹拌して、ペーストが得られた。前記ペースト中に４３０セル／ｉｎｃｈ２のセル数を有するアルミ製ハニカム２ｃｃを投入し、ペースト全量をハニカム上に添着した。さらに、１２０℃条件で乾燥して、フィルターサンプルが得られた。得られたフィルターサンプルについてアセトアルデヒド除去性能を測定した。
(Example 3)
13.5 g of ferric chloride hexahydrate (manufactured by Nacalai Tesque) was dissolved in 60 ml of ion-exchanged water, 5.0 g of 30% hydrogen peroxide (manufactured by Nacalai Tesque) was added, and the mixture was stirred for 15 minutes. . Thereafter, 100 ml of an aqueous solution containing 12.0 g of ammonium carbonate (manufactured by Nacalai Tesque) was slowly added. After the addition, the mixture was stirred for 1 hour. The obtained solution was separated by filtration, washed with ion-exchanged water until the filtrate became neutral, and then dried at 80 ° C. under a nitrogen stream for 24 hours to obtain an iron compound.
435 mg of silver (I) oxide (manufactured by Wako Pure Chemical Industries, Ltd.) and 3.0 g of the iron compound obtained above were mixed in an agate mortar to obtain a remover. About the obtained removal agent, BET specific surface area and Ag / Fe ratio were measured.
Further, 60 mg of the obtained removing agent, 20 mg of aluminum dihydrogen phosphate (manufactured by Nacalai Tesque), and 20 mg of sodium alginate (manufactured by Nacalai Tesque) were put into 1 ml of ion-exchanged water and stirred well to obtain a paste. It was. 2 cc of an aluminum honeycomb having a cell number of 430 cells / inch 2 was put into the paste, and the whole paste was adhered onto the honeycomb. Furthermore, it dried on 120 degreeC conditions, and the filter sample was obtained. The filter sample obtained was measured for acetaldehyde removal performance.
（実施例４）
硝酸鉄（ＩＩＩ）九水和物（和光純薬社製）５ｇ、硝酸銀（ナカライテスク社製）１．０５ｇ、クエン酸（ナカライテスク社製）２．３８ｇを１０ｍｌのイオン交換水に溶解させ、６０分間撹拌した。その水溶液を真空乾燥した後、電気炉で温度３００℃条件下１時間焼成処理を施したところ除去剤が得られた。得られた除去剤について、ＢＥＴ比表面積、Ａｇ／Ｆｅ比を測定した。
さらに、得られた除去剤６０ｍｇ、リン酸二水素アルミニウム（ナカライテスク社製）２０ｍｇ、アルギン酸ナトリウム（ナカライテスク社製）２０ｍｇをイオン交換水１ｍｌ中に投入し、よく撹拌して、ペーストが得られた。前記ペースト中に４３０セル／ｉｎｃｈ２のセル数を有するアルミ製ハニカム２ｃｃを投入し、ペースト全量をハニカム上に添着した。さらに、１２０℃条件で乾燥して、フィルターサンプルが得られた。得られたフィルターサンプルについてアセトアルデヒド除去性能を測定した。
Example 4
Iron nitrate (III) nonahydrate (manufactured by Wako Pure Chemical Industries, Ltd.) 5 g, silver nitrate (manufactured by Nacalai Tesque) 1.05 g, citric acid (manufactured by Nacalai Tesque) 2.38 g are dissolved in 10 ml of ion-exchanged water, Stir for 60 minutes. The aqueous solution was vacuum-dried and then baked in an electric furnace at a temperature of 300 ° C. for 1 hour to obtain a remover. About the obtained removal agent, BET specific surface area and Ag / Fe ratio were measured.
Further, 60 mg of the obtained removing agent, 20 mg of aluminum dihydrogen phosphate (manufactured by Nacalai Tesque), and 20 mg of sodium alginate (manufactured by Nacalai Tesque) were put into 1 ml of ion-exchanged water and stirred well to obtain a paste. It was. 2 cc of an aluminum honeycomb having a cell number of 430 cells / inch 2 was put into the paste, and the whole paste was adhered onto the honeycomb. Furthermore, it dried on 120 degreeC conditions, and the filter sample was obtained. The filter sample obtained was measured for acetaldehyde removal performance.
（比較例１）
硝酸鉄（ＩＩＩ）九水和物（和光純薬社製）５ｇ、クエン酸（ナカライテスク社製）２．３８ｇを１０ｍｌのイオン交換水に溶解させ、６０分間撹拌した。その水溶液を真空乾燥した後、電気炉で温度３００℃条件下１時間焼成処理を施したところ除去剤サンプルが得られた。得られた除去剤サンプルについて、ＢＥＴ比表面積、Ａｇ／Ｆｅ比を測定した。
さらに、得られた除去剤６０ｍｇ、リン酸二水素アルミニウム（ナカライテスク社製）２０ｍｇ、アルギン酸ナトリウム（ナカライテスク社製）２０ｍｇをイオン交換水１ｍｌ中に投入し、よく撹拌して、ペーストが得られた。前記ペースト中に４３０セル／ｉｎｃｈ２のセル数を有するアルミ製ハニカム２ｃｃを投入し、ペースト全量をハニカム上に添着した。さらに、１２０℃条件で乾燥して、フィルターサンプルが得られた。得られたフィルターサンプルについてアセトアルデヒド除去性能を測定した。
(Comparative Example 1)
5 g of iron (III) nitrate nonahydrate (manufactured by Wako Pure Chemical Industries, Ltd.) and 2.38 g of citric acid (manufactured by Nacalai Tesque) were dissolved in 10 ml of ion-exchanged water and stirred for 60 minutes. The aqueous solution was vacuum-dried and then subjected to a baking treatment for 1 hour at a temperature of 300 ° C. in an electric furnace to obtain a remover sample. About the obtained removal agent sample, the BET specific surface area and Ag / Fe ratio were measured.
Further, 60 mg of the obtained removing agent, 20 mg of aluminum dihydrogen phosphate (manufactured by Nacalai Tesque), and 20 mg of sodium alginate (manufactured by Nacalai Tesque) were put into 1 ml of ion-exchanged water and stirred well to obtain a paste. It was. 2 cc of an aluminum honeycomb having a cell number of 430 cells / inch 2 was put into the paste, and the whole paste was adhered onto the honeycomb. Furthermore, it dried on 120 degreeC conditions, and the filter sample was obtained. The filter sample obtained was measured for acetaldehyde removal performance.
（比較例２）
硝酸銀（ナカライテスク社製）１．０５ｇ、クエン酸（ナカライテスク社製）２．３８ｇを１０ｍｌのイオン交換水に溶解させ、６０分間撹拌した。その水溶液を真空乾燥した後、電気炉で温度３００℃条件下１時間焼成処理を施したところ除去剤サンプルが得られた。得られた除去剤サンプルについて、ＢＥＴ比表面積、Ａｇ／Ｆｅ比を測定した。
さらに、得られた除去剤６０ｍｇ、リン酸二水素アルミニウム（ナカライテスク社製）２０ｍｇ、アルギン酸ナトリウム（ナカライテスク社製）２０ｍｇをイオン交換水１ｍｌ中に投入し、よく撹拌して、ペーストが得られた。前記ペースト中に４３０セル／ｉｎｃｈ２のセル数を有するアルミ製ハニカム２ｃｃを投入し、ペースト全量をハニカム上に添着した。さらに、１２０℃条件で乾燥して、フィルターサンプルが得られた。得られたフィルターサンプルについてアセトアルデヒド除去性能を測定した。
(Comparative Example 2)
1.05 g of silver nitrate (manufactured by Nacalai Tesque) and 2.38 g of citric acid (manufactured by Nacalai Tesque) were dissolved in 10 ml of ion-exchanged water and stirred for 60 minutes. The aqueous solution was vacuum-dried and then subjected to a baking treatment for 1 hour at a temperature of 300 ° C. in an electric furnace to obtain a remover sample. About the obtained removal agent sample, the BET specific surface area and Ag / Fe ratio were measured.
Further, 60 mg of the obtained removing agent, 20 mg of aluminum dihydrogen phosphate (manufactured by Nacalai Tesque), and 20 mg of sodium alginate (manufactured by Nacalai Tesque) were put into 1 ml of ion-exchanged water and stirred well to obtain a paste. It was. 2 cc of an aluminum honeycomb having a cell number of 430 cells / inch 2 was put into the paste, and the whole paste was adhered onto the honeycomb. Furthermore, it dried on 120 degreeC conditions, and the filter sample was obtained. The filter sample obtained was measured for acetaldehyde removal performance.
（比較例３）
硝酸鉄（ＩＩＩ）九水和物（和光純薬社製）５ｇ、硝酸銀（ナカライテスク社製）３．１５ｇ、クエン酸（ナカライテスク社製）２．３８ｇを１０ｍｌのイオン交換水に溶解させ、６０分間撹拌した。その水溶液を真空乾燥した後、電気炉で温度３００℃条件下１時間焼成処理を施したところ除去剤サンプルが得られた。得られた除去剤サンプルについて、ＢＥＴ比表面積、Ａｇ／Ｆｅ比を測定した。
さらに、得られた除去剤６０ｍｇ、リン酸二水素アルミニウム（ナカライテスク社製）２０ｍｇ、アルギン酸ナトリウム（ナカライテスク社製）２０ｍｇをイオン交換水１ｍｌ中に投入し、よく撹拌して、ペーストが得られた。前記ペースト中に４３０セル／ｉｎｃｈ２のセル数を有するアルミ製ハニカム２ｃｃを投入し、ペースト全量をハニカム上に添着した。さらに、１２０℃条件で乾燥して、フィルターサンプルが得られた。得られたフィルターサンプルについてアセトアルデヒド除去性能を測定した。
(Comparative Example 3)
Iron nitrate (III) nonahydrate (manufactured by Wako Pure Chemical Industries, Ltd.) 5 g, silver nitrate (manufactured by Nacalai Tesque) 3.15 g, citric acid (manufactured by Nacalai Tesque) 2.38 g are dissolved in 10 ml of ion exchange water, Stir for 60 minutes. The aqueous solution was vacuum-dried and then subjected to a baking treatment for 1 hour at a temperature of 300 ° C. in an electric furnace to obtain a remover sample. About the obtained removal agent sample, the BET specific surface area and Ag / Fe ratio were measured.
Further, 60 mg of the obtained removing agent, 20 mg of aluminum dihydrogen phosphate (manufactured by Nacalai Tesque), and 20 mg of sodium alginate (manufactured by Nacalai Tesque) were put into 1 ml of ion-exchanged water and stirred well to obtain a paste. It was. 2 cc of an aluminum honeycomb having a cell number of 430 cells / inch 2 was put into the paste, and the whole paste was adhered onto the honeycomb. Furthermore, it dried on 120 degreeC conditions, and the filter sample was obtained. The filter sample obtained was measured for acetaldehyde removal performance.
（比較例４）
硝酸鉄（ＩＩＩ）九水和物（和光純薬社製）５ｇ、硝酸銀（ナカライテスク社製）１．０５ｇ、クエン酸（ナカライテスク社製）２．３８ｇを１０ｍｌのイオン交換水に溶解させ、６０分間撹拌した。その水溶液を真空乾燥した後、電気炉で温度６００℃条件下２時間焼成処理を施したところ除去剤サンプルが得られた。得られた除去剤サンプルについて、ＢＥＴ比表面積、Ａｇ／Ｆｅ比を測定した。
さらに、得られた除去剤６０ｍｇ、リン酸二水素アルミニウム（ナカライテスク社製）２０ｍｇ、アルギン酸ナトリウム（ナカライテスク社製）２０ｍｇをイオン交換水１ｍｌ中に投入し、よく撹拌して、ペーストが得られた。前記ペースト中に４３０セル／ｉｎｃｈ２のセル数を有するアルミ製ハニカム２ｃｃを投入し、ペースト全量をハニカム上に添着した。さらに、１２０℃条件で乾燥して、フィルターサンプルが得られた。得られたフィルターサンプルについてアセトアルデヒド除去性能を測定した。
(Comparative Example 4)
Iron nitrate (III) nonahydrate (manufactured by Wako Pure Chemical Industries, Ltd.) 5 g, silver nitrate (manufactured by Nacalai Tesque) 1.05 g, citric acid (manufactured by Nacalai Tesque) 2.38 g are dissolved in 10 ml of ion-exchanged water, Stir for 60 minutes. The aqueous solution was vacuum-dried and then baked in an electric furnace at a temperature of 600 ° C. for 2 hours to obtain a remover sample. About the obtained removal agent sample, the BET specific surface area and Ag / Fe ratio were measured.
Further, 60 mg of the obtained removing agent, 20 mg of aluminum dihydrogen phosphate (manufactured by Nacalai Tesque), and 20 mg of sodium alginate (manufactured by Nacalai Tesque) were put into 1 ml of ion-exchanged water and stirred well to obtain a paste. It was. 2 cc of an aluminum honeycomb having a cell number of 430 cells / inch 2 was put into the paste, and the whole paste was adhered onto the honeycomb. Furthermore, it dried on 120 degreeC conditions, and the filter sample was obtained. The filter sample obtained was measured for acetaldehyde removal performance.
結果を表１に示す。表１より明らかなように、本発明である実施例１〜４は、鉄元素（Ｆｅ）のみの場合（比較例１）、銀元素（Ａｇ）のみの場合（比較例２）、Ａｇ／Ｆｅ（モル比）が１より大きい場合（比較例３）と比較して高除去性能であることが分かる。また、ＢＥＴ比表面積が小さい場合（比較例４）も、本発明である実施例４と比較して性能が低いことが分かる。 The results are shown in Table 1. As is clear from Table 1, Examples 1 to 4 according to the present invention have a case of only iron element (Fe) (Comparative Example 1), a case of only silver element (Ag) (Comparative Example 2), and Ag / Fe. It can be seen that the removal performance is higher than when the (molar ratio) is larger than 1 (Comparative Example 3). In addition, when the BET specific surface area is small (Comparative Example 4), it can be seen that the performance is lower than that of Example 4 of the present invention.
本発明によるアルデヒド類ガス除去フィルターは、銀元素（Ａｇ）と鉄元素（Ｆｅ）をＡｇ／Ｆｅ（モル比）＝０．００１〜１の範囲で含有し、かつ、ＢＥＴ比表面積が５０ｍ２／ｇ以上である銀−鉄系除去剤を含有しているため、一般生活における温湿度領域で、長期にわたっての高性能な除去が可能であり、また、環境汚染への影響が少ないという利点を有するフィルターを提供できるものである。
The aldehyde gas removal filter according to the present invention contains silver element (Ag) and iron element (Fe) in a range of Ag / Fe (molar ratio) = 0.001 to 1, and a BET specific surface area of 50 m 2 /. Since it contains a silver-iron-based removal agent that is greater than or equal to g, it has the advantage that high-performance removal over a long period of time is possible in the temperature and humidity range in general life, and there is little impact on environmental pollution. A filter can be provided.
Claims (1)
Aldehyde gas removal containing a silver-iron-based remover, wherein the molar ratio of silver element to iron element is in the range of 0.001 to 1, and the BET specific surface area is 50 m 2 / g or more. filter.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006207986A JP4760599B2 (en) | 2006-07-31 | 2006-07-31 | Aldehyde gas removal filter |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP2006207986A JP4760599B2 (en) | 2006-07-31 | 2006-07-31 | Aldehyde gas removal filter |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JP2008029689A true JP2008029689A (en) | 2008-02-14 |
| JP4760599B2 JP4760599B2 (en) | 2011-08-31 |
Family
ID=39119700
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP2006207986A Expired - Fee Related JP4760599B2 (en) | 2006-07-31 | 2006-07-31 | Aldehyde gas removal filter |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP4760599B2 (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04200638A (en) * | 1990-11-30 | 1992-07-21 | Hitachi Ltd | Catalyst for oxidization or decomposition of gas containing odorous component and its application product |
| JPH07171348A (en) * | 1993-12-22 | 1995-07-11 | Toyota Central Res & Dev Lab Inc | Exhaust gas purification system for internal combustion engine using alcohol fuel |
| JP2002028489A (en) * | 2000-07-14 | 2002-01-29 | Toyobo Co Ltd | Adsorption and decomposition agent of aldehydes and producing method thereof |
| JP2002079099A (en) * | 2000-09-04 | 2002-03-19 | Toyobo Co Ltd | Gas removing material |
| JP2002306581A (en) * | 2001-04-11 | 2002-10-22 | Nissan Motor Co Ltd | Deodorant and method of preparation for the same |
-
2006
- 2006-07-31 JP JP2006207986A patent/JP4760599B2/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH04200638A (en) * | 1990-11-30 | 1992-07-21 | Hitachi Ltd | Catalyst for oxidization or decomposition of gas containing odorous component and its application product |
| JPH07171348A (en) * | 1993-12-22 | 1995-07-11 | Toyota Central Res & Dev Lab Inc | Exhaust gas purification system for internal combustion engine using alcohol fuel |
| JP2002028489A (en) * | 2000-07-14 | 2002-01-29 | Toyobo Co Ltd | Adsorption and decomposition agent of aldehydes and producing method thereof |
| JP2002079099A (en) * | 2000-09-04 | 2002-03-19 | Toyobo Co Ltd | Gas removing material |
| JP2002306581A (en) * | 2001-04-11 | 2002-10-22 | Nissan Motor Co Ltd | Deodorant and method of preparation for the same |
Also Published As
| Publication number | Publication date |
|---|---|
| JP4760599B2 (en) | 2011-08-31 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| TWI826408B (en) | A catalyst for catalyzing formaldehyde oxidation and the preparation and use of the same | |
| CN108290142B (en) | Composite composition for harmful gas removal containing copper-manganese catalyst | |
| JPH05168682A (en) | Deodorant and manufacture thereof | |
| CN111054178A (en) | Formaldehyde removal purification material and preparation method and application thereof | |
| JP2008104845A (en) | Deodorizer, its manufacture method, and deodorizing filter | |
| JP6349736B2 (en) | Acid gas adsorption / removal filter | |
| JP5503155B2 (en) | Carbon monoxide removal filter | |
| JP4760599B2 (en) | Aldehyde gas removal filter | |
| JP6759565B2 (en) | Aldehyde removal catalyst and its manufacturing method, aldehyde gas removal method | |
| WO1996022827A1 (en) | Deodorant material, process for producing the same, and method of deodorization | |
| JP2002263449A (en) | Activated carbon filter | |
| JP5706476B2 (en) | Carbon monoxide oxidation catalyst and production method thereof | |
| JP3546766B2 (en) | Deodorizing catalyst | |
| JP4923571B2 (en) | Aldehyde gas scavenger | |
| JP2007209527A (en) | Method for oxidizing and removing aldehyde gas | |
| JP5017779B2 (en) | Organic compound adsorption remover and method for producing the same | |
| JP2009279522A (en) | Oxide catalyst and method for preparing oxide catalyst, as well as deodorant and deodorizing filter | |
| JP2016034620A (en) | Metal oxide catalyst and deodorant | |
| JP2002079099A (en) | Gas removing material | |
| JP2007175598A (en) | Aldehydes gas removing agent | |
| JP5982964B2 (en) | Sulfur oxide remover | |
| CN114210314B (en) | Double-precursor carbon-based catalyst, preparation method thereof and application of double-precursor carbon-based catalyst in removing formaldehyde and mercury | |
| JP2017148764A (en) | Aldehyde removing catalyst composition, manufacturing method therefor and a removing method of aldehyde gas | |
| WO2011161834A1 (en) | NOx PURGING CATALYST | |
| JP2002028486A (en) | Adsorption and decomposition agent of aldehydes and producing method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20090727 |
|
| A977 | Report on retrieval |
Free format text: JAPANESE INTERMEDIATE CODE: A971007 Effective date: 20110202 |
|
| A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20110208 |
|
| A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20110408 |
|
| A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20110510 |
|
| A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20110523 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140617 Year of fee payment: 3 |
|
| FPAY | Renewal fee payment (event date is renewal date of database) |
Free format text: PAYMENT UNTIL: 20140617 Year of fee payment: 3 |
|
| LAPS | Cancellation because of no payment of annual fees |