JP2005219353A - Nozzle plate, method of manufacturing the same, and method of manufacturing inkjet head - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To enhance the flexibility of a manufacturing process of an inkjet head and to improve an ejection characteristic of ink. <P>SOLUTION: A punch 45 is hit to a substrate 91 from the side of the rear face to form a projection 94 on the front face and a recess 93 on the rear face. Next, the projection 94 on the front face of the substrate 91 is removed to make the front face flat. After that, the substrate 91 is punched out by means of a punch 46 to form an ink ejection nozzle 10 passing from the front face side to the recess 93. Lastly, an electronic beam is projected on the front face of the substrate 91 to form a water-repellent layer 92 of an amorphous layer. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

  The present invention relates to a nozzle plate having an ink ejection surface for ejecting ink onto a printing medium, a nozzle plate manufacturing method, and an inkjet head manufacturing method.

  An inkjet head that discharges ink onto a printing medium generally has a laminated structure in which thin metal plates are laminated. In the ink jet head, there are formed a large number of ink flow paths including nozzles (ink discharge holes) for discharging ink and pressure chambers communicating with the nozzles, and actuators are arranged at positions facing the pressure chambers. Has been. When each actuator is driven, the volume of the corresponding pressure chamber decreases, and the reduced volume of ink is ejected from the nozzle. At this time, if the remaining ink is attached in the vicinity of the opening of the nozzle, the ejection of the ink may be hindered. Further, when cleaning is performed by wiping the ink ejection surface with a rubber blade, the ink may not be efficiently removed. Therefore, it is preferable that a water repellent film is formed on the ink ejection surface. This water-repellent film is known to be formed by, for example, Teflon (registered trademark) -containing Ni plating.

  In order to form such a water-repellent film on the ink ejection surface, it is necessary to perform a plating process on the ink ejection surface. However, in order to perform the plating process, it is necessary to immerse the base material masked in the area other than the ink discharge surface in the plating liquid layer, so that the nozzle plate is attached only to the ink discharge surface with the nozzle plate assembled to the inkjet head. It is difficult to perform the plating process. Therefore, in this case, the plating process must be performed on the nozzle plate alone. Thus, when the water repellent film is formed by plating, there is a problem that the degree of freedom of the manufacturing process of the ink jet head is remarkably limited.

  For example, as shown in FIG. 13, when a water repellent film 53 is formed by plating on the ink ejection surface of the nozzle plate 51 in which the ink ejection holes 52 serving as nozzles are formed, the water repellent film 53 is formed. Grows in a direction perpendicular to the ink ejection surface. On the other hand, at the opening of the ink discharge hole 52, the water repellent film 53 grows in a direction perpendicular to the ink discharge surface, and also grows in a direction parallel to the ink discharge surface. Therefore, the edge of the water repellent film 53 protrudes from the ink discharge hole 52 and an overhang is formed in the ink discharge hole 52. Further, even when the entire inner wall surface of the ink discharge hole 52 is masked in an attempt to form the water repellent film 53 only on the ink discharge surface, the growth of the water repellent film 53 in the direction parallel to the ink discharge surface is not limited. The overhang is formed in a protruding state. However, if an overhang is formed in the ink discharge hole 52, the ink discharge is obstructed by the edge of the water-repellent film 53, and the landing position of the ink droplet becomes unstable, resulting in poor ink discharge characteristics. There's a problem.

  Further, as another method for forming a water repellent film, a technique for forming an amorphous diamond film having a water repellent effect on the surface of a base material by plasma CVD using a hydrocarbon gas is disclosed (see Patent Document 1). . The plasma CVD method is a method in which a raw material gas is brought into a plasma state with a high frequency to promote a chemical reaction, and a raw material is deposited on the surface of a base material to form a film.

Japanese Patent Laid-Open No. 10-296973 (FIG. 2)

  In the above-described technique, since it is not necessary to immerse the base material in the plating solution layer in order to form the water repellent film, it is possible to adopt a configuration such as forming the water repellent film after the nozzle plate is assembled to the ink jet head. . For this reason, the freedom degree of the manufacturing process of an inkjet head can be raised compared with the case where a water-repellent film is formed by plating. However, there is no change in forming a water-repellent film on the surface of the base material on the ink discharge surface, and still overhangs at the opening of the ink discharge hole as in the case of forming the water-repellent film by plating. There is a problem that is formed.

  Accordingly, a main object of the present invention is to provide a nozzle plate manufacturing method and an ink jet head manufacturing method capable of increasing the degree of freedom of the manufacturing process of the ink jet head.

  Another object of the present invention is to provide a nozzle plate having excellent ink ejection characteristics.

Means and effects for solving the problems

  The nozzle plate manufacturing method of the present invention has a laminated structure in which a plurality of plates are laminated, and in an ink jet head that ejects ink onto a printing medium, ink ejection holes for constituting the laminated structure and ejecting ink A method of manufacturing a nozzle plate, which is a plate on which is formed, wherein a step of forming the ink discharge hole for discharging ink to the nozzle plate, and the ink discharge hole formed by the hole forming step And an amorphization step of amorphizing at least the region around the opening of the ink discharge hole.

  According to this, since the water repellent layer can be formed on the ink discharge surface even after the nozzle plate is assembled to another unit, the degree of freedom in the manufacturing process of the inkjet head can be increased. Further, since the ink discharge surface itself of the nozzle plate is amorphized, the opening of the ink discharge hole does not have an overhang. Thereby, excellent ink ejection characteristics can be obtained.

  In the present invention, it is preferable that all of the ink discharge surface is amorphized in the amorphization step. According to this, since all of the ink discharge surfaces are amorphized, cleaning of the ink discharge surfaces by wiping can be performed efficiently.

  In the present invention, in the amorphization step, only the outer peripheral region of the ink ejection hole on the ink ejection surface may be amorphized. According to this, since the area to be amorphized is small, the time and cost for the amorphization process can be reduced.

  In the present invention, it is preferable that in the amorphization step, at least a part of the inner wall surface of the ink discharge hole is further amorphized. According to this, since the ink meniscus is formed inside the ink discharge hole, it is possible to suppress the ink remaining on the ink discharge surface which may be generated by discharging the ink. Therefore, ink is smoothly ejected from the ink ejection holes, and the ink ejection characteristics can be further improved.

  In addition, in the present invention, it is preferable that in the amorphization step, the ink ejection surface is amorphized by irradiating an electron beam or a laser beam. According to this, an arbitrary region can be amorphized with high accuracy by precisely controlling the irradiation position of the electron beam or laser beam.

  The nozzle plate of the present invention has a laminated structure in which a plurality of plates are laminated, and an ink ejection hole for ejecting ink is formed in the inkjet head that ejects ink onto a printing medium. In the nozzle plate, which is a plate, the area around the opening of the ink discharge hole is amorphized on the ink discharge surface where the ink discharge hole opens.

  According to this, since the ink discharge surface itself of the nozzle plate is amorphized, there is no overhang at the opening of the ink discharge hole. Therefore, excellent ink ejection characteristics can be obtained.

  In the present invention, in the thickness direction of the nozzle plate, it has a two-layer structure in which an amorphous layer formed by amorphizing the nozzle plate base material itself and a base material of the nozzle plate are laminated. Preferably it is. According to this, since the ink ejection surface itself is amorphized without changing the outer shape of the base material, the ink ejection characteristics are not impaired.

  An inkjet head manufacturing method according to the present invention is a manufacturing method of an inkjet head that has a laminated structure in which a plurality of plates are stacked and ejects ink onto a printing medium, and ejects ink onto a nozzle plate. A hole forming step for forming holes, an amorphizing step for amorphizing at least a region around the opening of the ink discharge hole on the ink discharge surface where the ink discharge hole formed in the hole forming step is opened, and the ink The nozzle plate includes a pressure chamber that communicates with the outside through the opening of the discharge hole, and has a plurality of ink flow paths from the ink supply port to which ink is supplied to the opening of the ink discharge hole. And a flow path unit forming step of forming a flow path unit by stacking a plurality of metal plates.

  According to this, since the ink discharge surface itself of the nozzle plate is amorphized, there is no overhang at the opening of the ink discharge hole. Therefore, excellent ink ejection characteristics can be obtained. Further, since the ink ejection surface is amorphized in the state of the nozzle plate alone, the amorphization process can be performed efficiently. In addition, since a defective product in which the ink discharge surface is insufficiently amorphized can be excluded at the stage of producing the nozzle plate, the overall yield can be improved.

  An inkjet head manufacturing method according to the present invention is a manufacturing method of an inkjet head that has a laminated structure in which a plurality of plates are stacked and ejects ink onto a printing medium, and ejects ink onto a nozzle plate. A plurality of ink flow paths from an ink supply port to which ink is supplied to an opening of the ink discharge hole, including a hole forming step for forming a hole and a pressure chamber communicating with the outside through the opening of the ink discharge hole; A flow path unit forming step of forming a flow path unit by laminating the nozzle plate and a plurality of metal plates so as to have a path therein; and the ink of the flow path unit formed by the flow path unit formation step An amorphous film that amorphizes at least the area around the opening of the ink discharge hole on the ink discharge surface where the discharge hole opens. And a gasification process.

  According to this, since the ink discharge surface itself of the nozzle plate is amorphized, there is no overhang at the opening of the ink discharge hole. Thereby, excellent ink ejection characteristics can be obtained. Further, since the ink ejection surface is amorphized in a state where the nozzle plate is stacked on the flow path unit, it is possible to prevent the amorphized ink ejection surface from being damaged in other processes.

  In the present invention, the flow path unit forming step includes a laminated structure forming step of forming a laminated structure by laminating the plurality of metal plates, the laminated structure formed in the laminated structure forming step, and And a laminating step of laminating the nozzle plates. According to this, the ink ejection surface can be amorphized in the state of the nozzle plate alone, or the ink ejection surface can be amorphized in the state where the laminated structure and the nozzle plate are laminated, so the degree of freedom in the manufacturing process can be increased. Can be high.

  Further, in the present invention, the individual electrode disposed at a position facing the pressure chamber, the common electrode formed so as to straddle the pressure chamber, and the piezoelectric sheet are combined with the piezoelectric sheet by the individual electrode and the common electrode. Forming an actuator unit by stacking so as to sandwich the actuator, and joining the flow channel unit and the actuator unit by aligning and joining the individual electrodes to the pressure chamber It is preferable to further include a process. According to this, an ink jet head that does not impair ink ejection characteristics can be manufactured.

  Hereinafter, preferred embodiments of the present invention will be described with reference to the drawings.

  FIG. 1 is an exploded perspective view of an ink jet head including a nozzle plate according to a first embodiment of the present invention. In addition, the area | region shown with the dashed-two dotted line in a figure is an area | region where the actuator unit 2 is arrange | positioned. The ink jet head 101 is applied to an ink jet printer that forms an image by ejecting ink onto a printing medium. As shown in FIG. 1, the inkjet head 101 has a laminated structure in which a flow path unit 1 and an actuator unit 2 are laminated. And the flexible flat cable 40 for electrically connecting with the control apparatus with which an inkjet printer is provided is joined to the opposite side (upper surface side) of the joint surface side (lower surface side) with the flow path unit 1 of the actuator unit 2. .

  Next, the flow path unit 1 will be described with reference to FIGS. 2 to 4 and 6. FIG. 2 is an exploded perspective view of the flow path unit 1. FIG. 3 is a partially enlarged view of FIG. FIG. 4 is a partial plan view of the ink ejection surface of the nozzle plate 4. 6 is a cross-sectional view of the inkjet head 101 taken along line VI-VI shown in FIG. As will be described in detail later, the flow path unit 1 includes a common ink chamber 18 into which ink is supplied from an ink tank (not shown) and a plurality of ink discharge holes 10 that discharge ink from the common ink chamber 18. Ink flow path 19 (see FIG. 6). As shown in FIGS. 2 and 3, the flow path unit 1 includes a cavity plate 3, a base plate 4, manifold plates 6 and 7, and a nozzle plate 9, and has a stacked structure in which these are stacked. Each of the plates 3, 4, 6, 7, 9 has a substantially rectangular shape with a thickness of 50 μm to 150 μm, and is joined in a state of being laminated by an adhesive applied to each planar region. In this embodiment, the flow path unit 1 is formed using 42% nickel alloy steel plates for the plates 3, 4, 6 and 7 and SUS430 for the nozzle plate 9.

  A plurality of pressure chambers 11 arranged in a staggered pattern in two rows along the longitudinal direction are formed in the center in the short direction of the cavity plate 3. The pressure chamber 11 has a substantially rectangular shape, and is arranged so that its longitudinal direction is perpendicular to the longitudinal direction of the cavity plate 3. A hole 11 a is formed at the end of the cavity plate 3 in the longitudinal direction of the pressure chamber 11, and a restriction channel 11 b that communicates only with the space on the lower surface side of the cavity plate 3 is formed at the opposite end. ing. A hole 17 having an elliptical shape is formed at one end of the cavity plate 3 in the longitudinal direction. At the bottom of the hole 17, holes 15 a and 15 b are formed along the short direction of the cavity plate 3 of the hole 17. A filter (not shown) for filtering the ink supplied from the ink tank is disposed in the hole 17.

  At the center in the short direction of the base plate 4, two rows of holes 12 a arranged in a staggered pattern along the longitudinal direction are formed. Further, holes 13 arranged in a line along the longitudinal direction are formed on both sides of the base plate 4 in the short direction. Furthermore, holes 16a and 16b are formed in one end of the base plate 4 in the longitudinal direction along the short direction. The hole 16 a is disposed at a position corresponding to the hole 15 a of the cavity plate 3, and the hole 16 b is disposed at a position corresponding to the hole 15 b of the cavity plate 3.

  Manifolds 6a and 6b, which are holes, are formed on both sides of the short side direction of the manifold plate 6 so as to extend along the longitudinal direction. On both sides of the manifold plate 7 in the short direction, manifolds 7a and 7b, which are holes, are formed so as to extend along the longitudinal direction. One end portions of the manifolds 6 a and 7 a are disposed at positions corresponding to the holes 16 a of the base plate 4, and one end portions of the manifolds 6 b and 7 b are disposed at positions corresponding to the holes 16 b of the base plate 4. Further, the manifolds 6 a, 6 b, 7 a, 7 b are arranged at positions corresponding to the respective rows of the holes 13 of the base plate 4. As shown in FIG. 6, the manifold plates 6 and 7 are joined, so that the manifolds 6 a, 6 b, 7 a, and 7 b constitute a common ink chamber 18. A plurality of holes 12b and 12c are respectively formed in the center of the short sides of the manifold plates 6 and 7 so as to correspond to the holes 12a of the base plate 4 along the longitudinal direction.

  A plurality of ink ejection holes 10 are formed in the center in the short direction of the nozzle plate 9 so as to correspond to the holes 12c of the manifold plate 7 along the longitudinal direction. As shown in FIGS. 4 and 6, a water repellent layer 92 is formed on the ink ejection surface of the nozzle plate 9 by amorphizing the entire surface by irradiation with an electron beam. That is, the nozzle plate 9 has a two-layer structure in which a surface layer in which the base material SUS430 itself is amorphized and exhibits water repellency is formed on the ink ejection surface.

  With such a configuration, in the flow path unit 1, the common ink chamber 18 formed by the manifolds 6a and 7a (6b and 7b) as shown in FIG. 11, a plurality of ink flow paths 19 are formed to reach the ink ejection holes 10 through the holes 12a, 12b, and 12c.

  Next, the actuator unit 2 will be described with reference to FIG. FIG. 5 is an exploded partial perspective view of the actuator unit 2. As shown in FIG. 5, the actuator unit 2 includes two piezoelectric sheets 21, two piezoelectric sheets 22, and a top sheet 23, and includes two piezoelectric sheets 21 and two piezoelectric sheets 22. Are stacked one after another, and then a top sheet 23 is stacked. In FIG. 5, the piezoelectric sheets 21 and 22 stacked on the lower side are omitted.

  The top sheet 23 is a rectangular sheet member made of an insulating material, and a plurality of connection terminals 26 connected to signal electrodes provided in the flexible flat cable 40 and ground electrodes provided in the flexible flat cable 40. And a plurality of connection terminals 27 connected to each other. The connection terminals 26 are arranged along the longitudinal direction at both lateral ends on the top sheet 23. The connection terminals 27 are arranged at both ends of the array integrally with the array of connection terminals 26. Further, a groove 30a extending in the thickness direction is formed on a side surface orthogonal to the connection terminal 26 of the top sheet 23, and extending in the thickness direction on a side surface orthogonal to the connection terminal 27 of the top sheet 23. A recessed groove 31a is formed. And the edge part of the connecting terminals 26 and 27 is arrange | positioned so that it may be exposed to the ditch | grooves 30a and 31a.

  The piezoelectric sheet 22 is a sheet member having a rectangular shape made of lead zirconate titanate (PZT), and is electrically connected to the connection terminals 27 and a plurality of dummy electrodes 29 electrically connected to the connection terminals 26. The common electrode 25 is provided. The dummy electrodes 29 are arranged along the longitudinal direction at both lateral ends on the piezoelectric sheet 22 so as to correspond to the connection terminals 26 of the top sheet 23. The common electrode 25 is disposed so as to spread over the central portion on the piezoelectric sheet 22 and is disposed at both ends of the array so as to be integrated with the array of dummy electrodes 29 so as to correspond to the connection terminals 27 of the top sheet 23. The end electrode 25a is provided. Further, a concave groove 30b extending in the thickness direction is formed on the side surface orthogonal to the dummy electrode 29 of the piezoelectric sheet 22, and extends in the thickness direction on the side surface orthogonal to the end electrode 25a of the piezoelectric sheet 22. A concave groove 31b is formed. The dummy electrodes 29 and the end electrodes 25a are arranged so that the ends thereof are exposed in the concave grooves 30b and 31b.

  The piezoelectric sheet 21 is a sheet member having a rectangular shape made of PZT, and includes a plurality of individual electrodes 24 electrically connected to the connection terminals 26 and dummy electrodes 28 electrically connected to the connection terminals 27. ing. The individual electrodes 24 are arranged along the longitudinal direction at both lateral ends on the piezoelectric sheet 21 so as to correspond to the connection terminals 26 of the top sheet 23. The individual electrode 24 extends to the vicinity of the center of the piezoelectric sheet 21 so as to correspond to the pressure chamber 11 of the flow path unit 1 (see FIG. 6). The dummy electrodes 28 are integrated with the arrangement of the individual electrodes 24 so as to correspond to the connection terminals 27 of the top sheet 23 and are arranged at both ends of the arrangement. Further, a concave groove 30c extending in the thickness direction is formed on the side surface of the piezoelectric sheet 21 orthogonal to the individual electrode 24, and extends in the thickness direction on the side surface of the piezoelectric sheet 21 orthogonal to the dummy electrode 28. A recessed groove 31c is formed. And the edge part of the individual electrode 24 and the dummy electrode 28 is arrange | positioned so that it may be exposed to the ditch | groove 30c, 31c.

  By laminating the two piezoelectric sheets 21, the two piezoelectric sheets 22 and the top sheet 23, the concave grooves 30 a to 30 c and the concave grooves 31 a to 31 c are integrated to extend the side surface of the actuator unit 2 in the thickness direction. The existing concave grooves 30 and 31 are formed. A conductive paste is applied to the grooves 30 and 31.

  Here, the operation of the actuator unit 2 will be described. In the inkjet head 101 according to the present embodiment, the piezoelectric sheets 21 and 22 are polarized in the thickness direction. Accordingly, when an electric field is applied to the piezoelectric sheets 21 and 22 in the polarization direction by setting the individual electrode 24 to a potential different from that of the common electrode 25, the portion to which the electric field is applied functions as an active layer, and the thickness direction, that is, the stacking direction. Try to stretch or shrink. In the present embodiment, three voltage sheets 21 and 22 that act as active layers are laminated, and the displacement in the thickness direction of each layer is superimposed.

  Here, for example, when the potential of the signal electrode of the flexible flat cable 40 to which the connection terminal 26 of the top sheet 23 is connected is set to a positive or negative predetermined potential such that the direction of the electric field is the same as the polarization direction. The plurality of piezoelectric sheets 21 and 22 tend to be deformed so as to extend in the thickness direction. At this time, as shown in FIG. 6, since the lower surface of the lowermost piezoelectric sheet 21 is fixed to the upper surface of the cavity plate 3 that partitions the pressure chamber 11, the piezoelectric sheets 21 and 22 protrude toward the pressure chamber 11 side. It deforms as follows. For this reason, the volume of the pressure chamber 11 is reduced, the pressure of the ink in the pressure chamber 11 is increased, and ink is ejected from the ink ejection holes 10 communicating with the pressure chamber 11. Thereafter, when the individual electrode 24 is returned to the same potential as the common electrode 25, the piezoelectric sheets 21 and 22 return to their original shape and the volume of the pressure chamber 11 returns to the original volume, so that ink is sucked from the common ink chamber 18 side. .

  Next, a method for manufacturing the inkjet head 101 will be described with reference to FIGS. FIG. 7 is a diagram illustrating a manufacturing process of the nozzle plate 9. FIG. 9 is a diagram showing a manufacturing process of the inkjet head.

  First, a method for manufacturing the nozzle plate 9 will be described. In this nozzle plate manufacturing method, as shown in FIG. 7E, an ink discharge hole 10 formed on a substrate 91 for discharging ink, and an ink discharge surface having a small opening area of the ink discharge hole 10 of the substrate 91. The nozzle plate 9 is provided with a water repellent layer 92 formed on a surface (hereinafter referred to as a front surface, and a surface opposite to the front surface). The substrate 91 is a metal (for example, stainless steel) plate having a rectangular shape. The thickness of the substrate 91 is, for example, about 70 μm.

  First, after applying a lubricant to the back surface of the substrate 91 by a method such as spraying, as shown in FIG. 7A, a punch 45 having a tapered tip is formed from the back surface side of the substrate 91. As a result, on the back surface side of the substrate 91, a tapered concave portion 93 that is tapered toward the front surface side is formed. Further, on the surface side of the substrate 91, when the recess 93 is formed, the substrate 91 is plastically deformed to form a convex portion 94 that is pushed out to the surface side by the punch 45. Next, as shown in FIG. 7B, the convex portions 94 are removed by polishing with a grinding machine or the like, and the surface of the substrate 91 is flattened.

  Thereafter, a lubricant is applied to the surface of the substrate 91 by a method such as spraying, and then a cylindrical punch 46 is driven from the surface side of the substrate 91 as shown in FIG. Thereby, in the surface of the substrate 91, a hole 95 penetrating to the concave portion 93 is formed (a hole making step). In this way, since the punch 46 is driven from the surface side of the substrate 91 to penetrate the substrate 91, no burr is generated on the surface side of the substrate 91.

  The hole 95 is formed in a straight shape. Therefore, as shown in FIG. 7E, the ink ejection hole 10 is composed of a concave portion 93 formed in a tapered shape on the surface side and a straight hole 95 extending from the concave portion 93 to the surface side. become. Thus, since the concave portion 93 is formed in a tapered shape, ink is smoothly guided into the ink discharge hole 10 from an ink supply source (not shown) connected to the concave portion 93 of the ink discharge hole 10, and the substrate 91. Ink is ejected to the front surface side. Further, since the hole 95 is formed in a straight shape, the uniformity of the ejection speed of the ink ejected from the ink ejection hole 10 is ensured, and the ink landing accuracy is improved.

Then, as shown in FIG. 7D, the surface of the substrate 91 is repeatedly irradiated with an electron beam 30 times under irradiation conditions of an energy density of 6 J / cm ² and an irradiation time of ² μsec. Thereby, the surface of the substrate 91 is melted to be in an amorphous state. Thereafter, by rapidly cooling the surface of the substrate 91, the surface of the substrate 91 is solidified while maintaining an amorphous state, and a water-repellent layer 92 that is an amorphous layer is formed as shown in FIG. Amorphization process). In this way, the two-layer nozzle plate 9 in which the water repellent layer 92 is formed on the surface of the substrate 91 is completed. Here, the film thickness of the water repellent layer 92 is, for example, about 1 μm.

  Here, the water repellency of the water repellent layer will be described. The water repellency of the water repellent layer is expressed by the contact angle θ. The contact angle θ refers to an angle formed between the liquid and the surface of the solid (here, the water repellent layer 92 or the substrate 91) viewed from the liquid (here, the ink) (see FIG. 8). ). That is, when the contact angle is close to 180 °, the solid surface repels water and the water droplets are almost spherical. On the other hand, when the contact angle is close to 0 °, water is wet and spread on the solid surface. Therefore, it can be evaluated that the larger the contact angle, the higher the water repellency of the solid surface. The static contact angle of the water repellent layer 92 with respect to pure water is about 90 °. The static contact angle of the substrate 91 with respect to pure water is about 60 °, the contact angle of the water repellent layer 92 is larger than the contact angle of the substrate 91, and the water repellent layer 92 has higher water repellency than the substrate 91. It can be said. That is, the water repellency of the surface of the nozzle plate 9 can be increased by forming the water repellent layer 92. In this way, by forming the water repellent layer 92 on the surface of the substrate 91 provided with the ink ejection holes 10, the ink ejected from the ink ejection holes 10 adheres to the periphery of the opening of the ink ejection holes 10, Next, it is possible to prevent the landing accuracy from deteriorating due to interference with the ejected ink.

  Further, in the present embodiment, unlike the case of growing a water-repellent film on the surface of the nozzle plate 9 using a material different from the base material of the nozzle plate 9 as in the plating method or the CVD method, the ink discharge holes No overhang is formed in the 10 openings. That is, in the present embodiment, the arrangement state of the constituent elements of the nozzle plate 9 only changes before and after the ink discharge surface is amorphized. Therefore, there is almost no change in the outer shape at least in the vicinity of the ink ejection holes 10, and it is possible to more effectively prevent the landing accuracy from being lowered due to interference with the ejected ink.

  As described above, in the present embodiment, the substrate 91 is hardly deburred, but may be deburred as necessary. This deburring can be performed by a known method such as electrolytic polishing, fluid polishing, grinding with a lapping machine, magnetic polishing, or cleaning with low frequency ultrasonic waves.

  Next, a method for manufacturing the inkjet head 101 using the nozzle plate 9 manufactured by the above-described method will be described. First, holes and recesses as shown in FIG. 2 are formed by performing etching processing, punching processing, and the like on the four plates of the cavity plate 3, the base plate 4, and the manifold plates 6 and 7, respectively. The holes 15a and 15b of the cavity plate 3, the holes 16a and 16b of the base plate 4, the one ends of the manifolds 6a and 6b of the manifold plate 6, and the one ends of the manifolds 7a and 7b of the manifold plate 7 correspond to each other. The four plates 3, 4, 6, 7 are arranged so that the holes 11 a of the cavity plate 3, the holes 12 a of the base plate 4, the holes 12 b of the manifold plate 6, and the holes 12 c of the manifold plate 7 correspond to each other. Align each other and laminate via an epoxy-based thermosetting adhesive. Thereafter, the four plates 3, 4, 6, and 7 are joined to each other by applying pressure to a temperature higher than the curing temperature of the thermosetting adhesive and heating. In this way, the laminated structure 1a as shown in FIG. 9A is produced (laminated structure forming step). Further, in a process different from the process of manufacturing the laminated structure 1a, the nozzle plate 9 on which the water repellent layer 92 is formed is manufactured by the method described above.

  Next, the hole 12 c of the manifold plate 7 and the ink discharge hole 10 of the nozzle plate 9 correspond to each other, and an ink flow path 19 that reaches the ink discharge hole 10 through the pressure chamber 11 is formed inside the flow path unit 1. Thus, the laminated structure 1a and the nozzle plate 9 are aligned with each other. And after laminating | stacking via an epoxy-type thermosetting adhesive, it heats and pressurizing to the temperature more than the curing temperature of a thermosetting adhesive, and the laminated structure 1a and the nozzle plate 9 are joined (lamination | stacking). Process). Thereby, the flow path unit 1 as shown in FIG.9 (b) is produced (flow path unit formation process).

  In addition, the actuator unit 2 is created in a process separate from the process of producing the flow path unit 1. Specifically, first, on the surface of a total of five green sheets, which are the top sheet 23, the two piezoelectric sheets 21, and the two piezoelectric sheets 22, respectively, the portions to be terminals and electrodes as shown in FIG. The paste (metal material) is applied by screen printing. Then, after these green sheets are dried, the piezoelectric sheets 21 and 22 are alternately laminated, and the top sheet 23 is laminated on the uppermost layer. Thereafter, the connection terminal 26 of the top sheet 23, the dummy electrode 29 of the piezoelectric sheet 22, and the individual electrode 24 of the piezoelectric sheet 21 correspond to each other, and the connection terminal 27 of the top sheet 23 and the end electrode of the piezoelectric sheet 22. 25a and the dummy electrode 28 of the piezoelectric sheet 21 are aligned so as to correspond to each other, and are pressed and integrated in the stacking direction. At this time, the concave grooves 30 and 31 are formed on the side surface of the laminate to be the actuator unit 2. After firing the laminated body thus integrated, a conductive paste is applied to the concave grooves 30, 31, and further fired. In this way, the actuator unit 2 as shown in FIG. 9B is produced (actuator creating process).

  Finally, as shown in FIG. 9C, the flow path unit 1 and the actuator unit 2 are separated from each other by the overlapping portion of the individual electrode 24 and the common electrode 25 of the actuator unit 2. While being aligned so as to be in a position corresponding to the above, they are laminated via a thermosetting adhesive. Then, it heats, pressurizing to the temperature more than the curing temperature of a thermosetting adhesive, and joins the flow path unit 1 and the actuator unit 2 (joining process). In this way, the inkjet head 101 is completed.

  As described above, in the nozzle plate 9 of the first embodiment, the water repellent layer 92 is formed by making the ink ejection surface itself amorphous. Therefore, the nozzle plate 9 does not have an overhang at the opening of the ink discharge hole 10. Thereby, excellent ink ejection characteristics can be obtained. Further, since the water repellent layer 92 has high durability, it is not peeled off by wiping for cleaning the ink discharge surface. Furthermore, since the water repellent layer 92 is formed over the entire ink discharge surface, the ink discharge surface can be efficiently cleaned by wiping.

  Further, a water repellent layer 92 is formed on the nozzle plate 9 by irradiating the ink ejection surface with an electron beam. Therefore, the water-repellent layer 92 can be accurately formed in any region by precisely controlling the irradiation position of the electron beam.

  Further, the nozzle plate 9 has a two-layer structure in which a water repellent layer 92 formed by amorphizing the substrate 91 and the substrate 91 are laminated in the thickness direction. Therefore, since the water repellent layer 92 is formed by amorphizing the surface of the substrate 91 without changing the thickness of the substrate 91, the ink ejection characteristics are not impaired.

  Further, in the manufacturing method of the ink jet head 101 of the first embodiment, after the flow path unit 1 is manufactured by laminating the nozzle plate 9 on which the water-repellent layer 92 is previously formed in a single state with the laminated structure 1a. Then, the flow path unit 1 and the actuator unit 2 are laminated and completed. Therefore, the water repellent layer 92 can be formed efficiently. Moreover, since the defective product in which the formation of the water-repellent layer 92 is insufficient can be excluded at the stage of producing the nozzle plate 9, the overall yield can be improved.

  In addition, the manufacturing method of the above-mentioned inkjet head 101 is an example, and is not limited to this. Here, a modified example of the method of manufacturing the inkjet head 101 will be described with reference to FIG.

  First, as shown in FIG. 10A, the substrate 91 (the water repellent layer 92 on the ink ejection surface of the nozzle plate 9) on which the cavity plate 3, the base plate 4, the manifold plates 6, 7 and the plurality of ink ejection holes 10 are formed. The flow path unit 1 is manufactured by stacking the layers on which the liquid crystal is not formed. Next, as shown in FIG. 10B, the actuator unit 2 is formed by laminating two piezoelectric sheets 21, two piezoelectric sheets 22, and a top sheet 23 by a process different from the manufacturing process of the flow path unit 1. Is made. Further, the surface of the substrate 91 is irradiated with an electron beam. As a result, a water repellent layer 92 is formed on the surface of the substrate 91 as shown in FIG. Thereafter, the flow path unit 1 and the actuator unit 2 are laminated to complete the ink jet head 101.

  As described above, after forming the flow path unit 1 by laminating a plurality of plates, the water repellent layer 92 is formed on the surface of the substrate 91, thereby preventing the water repellent layer 92 from being damaged in other steps. Can do.

  Further, the nozzle plate 9 can form the water-repellent layer 92 on the ink ejection surface even when the nozzle plate 9 is in a single state or when the nozzle plate 9 and the laminated structure 1a are laminated. . Accordingly, the degree of freedom in the manufacturing process of the ink jet head can be increased.

  In the ink jet head manufacturing process shown in FIG. 10, the water repellent layer 92 may be formed on the surface of the substrate 91 after laminating the flow path unit 1 and the actuator unit 2 manufactured in separate processes. Good.

  In addition, when the water repellent layer 92 is formed on the ink ejection surface of the nozzle plate 9, stress may remain between the base material substrate 91 and the amorphous water repellent layer 92. If this residual stress is large, the nozzle plate 9 itself is warped and bent, making it difficult to stack with other members. Therefore, forming the water-repellent layer 92 on the ink ejection surface in a state where the nozzle plate 9 is laminated with another plate is also effective from the viewpoint of facilitating lamination with the other plate of the nozzle plate 9. . That is, since the nozzle plate 9 is previously laminated with other plates and the water-repellent layer 92 is formed with a high rigidity as a whole, the lamination process for assembling the inkjet head 101 is facilitated.

  Next, a second embodiment of the present invention will be described with reference to FIG. FIG. 11 is a partial plan view of the ink ejection surface of the nozzle plate according to the second embodiment of the present invention.

  The nozzle plate of the second embodiment of the present invention is mainly different from the nozzle plate of the first embodiment in that the nozzle plate 9 of the first embodiment covers the entire ink discharge surface. Although the water repellent layer 92 is formed, the nozzle plate 209 of the second embodiment is that the water repellent layer 292 is formed only on a part of the ink ejection surface. The other configuration of the nozzle plate 209, the manufacturing method thereof, and the manufacturing method of the ink jet head provided with the nozzle plate 209 are substantially the same as those in the first embodiment, and thus detailed description thereof is omitted.

  In the nozzle plate 209 of the second embodiment, as shown in FIG. 11, the water repellent layer 292 is formed by irradiating only the outer peripheral area of the ink ejection hole 210 on the ink ejection surface thereof. According to the second embodiment, the same effects as those of the first embodiment can be obtained. In the nozzle plate 209, since the water repellent layer 292 is formed only in the outer peripheral region of the ink discharge hole 210, the time and cost required for forming the water repellent layer 292 can be reduced.

  Next, a third embodiment of the present invention will be described with reference to FIG. FIG. 12 is a partial cross-sectional view in the thickness direction of the ink discharge hole of the nozzle plate according to the third embodiment of the present invention.

  The nozzle plate of the third embodiment of the present invention is mainly different from the nozzle plate of the first embodiment in that the nozzle plate 9 of the first embodiment is water repellent only on its ink ejection surface. Although the layer 92 is formed, the nozzle plate 309 of the third embodiment is that a water repellent layer 392 is also formed in the vicinity of the ink discharge surface of the inner wall surface of the ink discharge hole 310. The other configuration of the nozzle plate 309, the manufacturing method thereof, and the manufacturing method of the ink jet head provided with the nozzle plate 309 are substantially the same as those in the first embodiment, and thus detailed description thereof is omitted.

  The nozzle plate 309 of the third embodiment is perpendicular to the ink ejection surface as shown in FIG. 12A with respect to the surface of the substrate 391 on which a plurality of ink ejection holes 310 are formed by the drilling step. A direction electron beam is irradiated, and an electron beam inclined to a predetermined angle with respect to the ink ejection surface is irradiated. In this way, as shown in FIG. 12B, the nozzle plate 309 having the water repellent layer 392 formed on the ink discharge surface and the vicinity of the ink discharge surface of the inner wall surface of the ink discharge hole 310 is produced.

  According to the third embodiment, the same effect as that of the first embodiment can be obtained. In the nozzle plate 309, a water repellent layer 392 is formed on the ink discharge surface and the vicinity of the ink discharge surface of the inner wall surface of the ink discharge hole 310. As a result, an ink meniscus is formed inside the ink ejection hole 310, so that it is possible to suppress ink remaining on the ink ejection surface, which may occur when ink is ejected. Accordingly, since the ink is smoothly ejected from the ink ejection hole 310, the ink ejection characteristics can be further improved.

  The preferred embodiments of the present invention have been described above. However, the present invention is not limited to the above-described embodiments, and various design changes can be made as long as they are described in the claims.

  In the first to third embodiments described above, the ink ejection surface of the nozzle plate is amorphized by irradiating the electron beam, but the amorphization means is not limited to this. For example, the ink discharge surface may be made amorphous by irradiating a laser beam.

  In the first embodiment, when the water repellent layer is formed over the entire ink discharge surface, in the second embodiment, the water repellent layer is formed only in the outer peripheral region of the ink discharge hole. In the third embodiment, the case where the water repellent layer is formed on the ink discharge surface and the vicinity of the ink discharge surface of the inner wall surface of the ink discharge hole is described in the third embodiment. The region where is formed is not limited to these. The effect of the present invention can be obtained as long as a water repellent layer is formed at least in the outer peripheral region of the ink ejection hole.

  In the first to third embodiments described above, the five plates of the cavity plate, the base plate, the two manifold plates, and the nozzle plate that constitute the flow path unit are bonded to each other by a thermosetting adhesive. However, the method of joining these plates is not limited to this, and may be joined by diffusion joining, for example. Moreover, the joining method may differ for each plate.

  In the first to third embodiments described above, the cavity plate, the base plate, the manifold plate, and the holes and the recesses of each plate of the nozzle plate that form the flow path unit are described by punching. The method of forming the holes and the recesses is not limited to this. For example, it may be formed by performing etching and half etching using a photoresist patterned on each plate as a mask, or by performing laser processing.

  In the first to third embodiments described above, a case is described in which a 42% nickel alloy steel plate is used for the cavity plate, the base plate, and the manifold plate, and SUS430 is used for the nozzle plate. I can't. For example, you may make it comprise a flow path unit using 42% nickel alloy steel plate for all these plates. In this case, it is possible to prevent the flow path unit from warping or bending due to the difference in expansion coefficient between the plates.

It is a disassembled perspective view of the inkjet head containing the nozzle plate which concerns on 1st Embodiment. It is a disassembled perspective view of the flow-path unit shown in FIG. It is the elements on larger scale of the flow-path unit shown in FIG. FIG. 2 is a partial plan view of an ink discharge surface of a nozzle plate shown in FIG. FIG. 2 is an exploded partial perspective view of the actuator unit shown in FIG. 1. It is sectional drawing of the inkjet head in the VI-VI line shown in FIG. It is a figure which shows the manufacturing process of the nozzle plate shown in FIG. It is explanatory drawing of a contact angle. It is a figure which shows the manufacture process of the inkjet head shown in FIG. It is a figure which shows the modification of the manufacturing process of the inkjet head shown in FIG. It is a partial top view of the ink discharge surface of the nozzle plate concerning the 2nd Embodiment of this invention. It is a thickness direction partial sectional view in the ink discharge hole of the nozzle plate concerning the 3rd Embodiment of this invention. It is a thickness direction fragmentary sectional view in the ink discharge hole of the conventional nozzle plate.

Explanation of symbols

DESCRIPTION OF SYMBOLS 1 Flow path unit 2 Actuator unit 9 Nozzle plate 10 Ink discharge hole 11 Pressure chamber 19 Ink flow path 21, 22 Piezoelectric sheet 24 Individual electrode 25 Common electrode 91 Substrate 92 Water repellent layer 101 Inkjet head

Claims (11)

Nozzle plate which has a laminated structure in which a plurality of plates are laminated and is a plate in which ink ejection holes for ejecting ink are formed in the inkjet head for ejecting ink onto a printing medium. A manufacturing method of
Forming a hole for discharging the ink to the nozzle plate;
A nozzle plate manufacturing comprising: an amorphization step of amorphizing at least a region around the opening of the ink discharge hole on an ink discharge surface where the ink discharge hole formed by the hole forming step opens. Method.   2. The nozzle plate manufacturing method according to claim 1, wherein in the amorphization step, all of the ink discharge surface is amorphized. 3.   2. The nozzle plate manufacturing method according to claim 1, wherein, in the amorphization step, only the outer peripheral region of the ink discharge hole on the ink discharge surface is amorphized.   The nozzle plate manufacturing method according to claim 1, wherein in the amorphization step, at least a part of the inner wall surface of the ink discharge hole is further amorphized.   5. The nozzle plate manufacturing method according to claim 1, wherein, in the amorphization step, the ink discharge surface is amorphized by irradiating an electron beam or a laser beam. Nozzle plate which has a laminated structure in which a plurality of plates are laminated and is a plate in which ink ejection holes for ejecting ink are formed in the inkjet head for ejecting ink onto a printing medium. Because
A nozzle plate characterized in that at least an area around the opening of the ink discharge hole is amorphized on an ink discharge surface where the ink discharge hole opens.   The nozzle plate has a two-layer structure in which an amorphous layer formed by amorphizing the base material of the nozzle plate and a base material of the nozzle plate are laminated in the thickness direction of the nozzle plate. The nozzle plate according to claim 6. A method of manufacturing an inkjet head having a laminated structure in which a plurality of plates are laminated and discharging ink onto a printing medium,
A hole forming step for forming ink discharge holes for discharging ink to the nozzle plate;
An amorphization step of amorphizing at least a region around the opening of the ink discharge hole on the ink discharge surface where the ink discharge hole formed in the hole forming step opens;
Including a pressure chamber communicating with the outside through the opening of the ink discharge hole, and having therein a plurality of ink flow paths from an ink supply port to which ink is supplied to the opening of the ink discharge hole. An inkjet head manufacturing method comprising: a flow path unit forming step of forming a flow path unit by laminating a nozzle plate and a plurality of metal plates. A method for manufacturing an inkjet head having a laminated structure in which a plurality of plates are laminated and discharging ink to a printing medium,
A hole forming step for forming ink discharge holes for discharging ink to the nozzle plate;
Including a pressure chamber communicating with the outside through the opening of the ink discharge hole, and having therein a plurality of ink flow paths from an ink supply port to which ink is supplied to the opening of the ink discharge hole. A flow path unit forming step of forming a flow path unit by laminating a nozzle plate and a plurality of metal plates;
An amorphization step of amorphizing at least a region around the opening of the ink discharge hole on an ink discharge surface where the ink discharge hole of the flow path unit formed by the flow path unit forming step opens. An inkjet head manufacturing method characterized by the above. The flow path unit forming step includes
A laminated structure forming step of forming a laminated structure by laminating the plurality of metal plates;
The inkjet head manufacturing method according to claim 8, further comprising a lamination step of laminating the laminated structure formed in the laminated structure forming step and the nozzle plate. An individual electrode disposed at a position facing the pressure chamber, a common electrode formed so as to straddle the pressure chamber, and a piezoelectric sheet are stacked so that the piezoelectric sheet is sandwiched between the individual electrode and the common electrode. Forming an actuator unit with an actuator unit forming step;
The bonding step of aligning and bonding the flow path unit and the actuator unit so that the individual electrodes are opposed to the pressure chamber. 2. A method for producing an inkjet head according to item 1.

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