Nothing Special   »   [go: up one dir, main page]

JP2005071674A - Battery pack - Google Patents

Battery pack Download PDF

Info

Publication number
JP2005071674A
JP2005071674A JP2003296900A JP2003296900A JP2005071674A JP 2005071674 A JP2005071674 A JP 2005071674A JP 2003296900 A JP2003296900 A JP 2003296900A JP 2003296900 A JP2003296900 A JP 2003296900A JP 2005071674 A JP2005071674 A JP 2005071674A
Authority
JP
Japan
Prior art keywords
cooling
refrigerant
assembled battery
battery
unit
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2003296900A
Other languages
Japanese (ja)
Other versions
JP4349037B2 (en
Inventor
Hiroshi Kawai
博 河合
Koji Fujiki
康二 藤木
Yukihiro Kimoto
幸博 木本
Naomi Awano
直実 粟野
Masafumi Otsuka
雅史 大塚
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Denso Corp
Original Assignee
Denso Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Denso Corp filed Critical Denso Corp
Priority to JP2003296900A priority Critical patent/JP4349037B2/en
Publication of JP2005071674A publication Critical patent/JP2005071674A/en
Application granted granted Critical
Publication of JP4349037B2 publication Critical patent/JP4349037B2/en
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Images

Classifications

    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

Landscapes

  • Secondary Cells (AREA)
  • Battery Mounting, Suspending (AREA)

Abstract

<P>PROBLEM TO BE SOLVED: To provide a battery pack with a simple structure and provide the battery pack having high cooling efficiency. <P>SOLUTION: This battery pack has a plurality of unit cells and a plurality of bus bars to electrically connect each unit cell. (1) Each bus bar has a cooling fin which also works as a cooling member to each unit cell. In other words, by giving the bus bar, which is an essential constituent element, a function as the cooling member, the number of the constituent elements is reduced. Then, it has an advantage that a new cost for improving heat transfer is not required. (2) Each cooling fin is arranged along the flowing direction of a cooling medium, and each fin is arranged by shifting between adjoining each cooling member so that they do not completely overlap with the flowing direction of the cooling medium. That is to say, since the cooling fin is arranged along the flowing direction of the cooling medium, it does not obstruct the flow of the cooling medium. Then, by shifting the cooling fin between the adjoining cooling members, a turbulent flow is generated in the cooling medium and cooling capability can be demonstrated to the maximum extent. <P>COPYRIGHT: (C)2005,JPO&NCIPI

Description

本発明は、冷却手段に特長をもつ組電池に関し、特に大電流を流す二次電池を単位電池にもつ組電池に関する。   The present invention relates to an assembled battery having a feature in cooling means, and more particularly to an assembled battery having a secondary battery that allows a large current to flow in a unit battery.

近年、電気自動車、ハイブリッド自動車などの電動車両の開発が活発に行われている。この電動車両の駆動用電源として、性能、信頼性、安全性に優れた二次電池の要望が高まっている。   In recent years, electric vehicles such as electric vehicles and hybrid vehicles have been actively developed. As a power source for driving this electric vehicle, there is an increasing demand for a secondary battery excellent in performance, reliability, and safety.

これらの電動車両において、駆動用電源には高い電力密度を有することが求められる。この駆動用電源として、高い電力密度を得るために、複数の単位電池を直列及び/又は並列に接続した組電池が用いられている。   In these electric vehicles, the driving power source is required to have a high power density. In order to obtain a high power density, an assembled battery in which a plurality of unit batteries are connected in series and / or in parallel is used as the driving power source.

ところで電動車両に組電池を適用する場合、組電池には大電流が流れ発電要素における発熱が生じる。この発熱により各単位電池の発電要素が過熱・損傷し、電池性能が低下するようになる。このため組電池には大電流による発熱に対し、電池の畜熱を防ぐことを目的とした放熱対策が必要となっていた。   By the way, when an assembled battery is applied to an electric vehicle, a large current flows through the assembled battery and heat is generated in the power generation element. Due to this heat generation, the power generation element of each unit battery is overheated and damaged, and the battery performance is lowered. For this reason, the assembled battery needs to have a heat dissipation measure for the purpose of preventing the livestock heat of the battery against heat generated by a large current.

従来の組電池の冷却手段としては、組電池を構成する複数の電池のそれぞれの間に冷媒が通過できる通路を設けた状態で拘束し、その間に冷媒を通すことによって電池を冷却する方法が開示されている(特許文献1)。また、組電池を構成する各電池の電池ケースの中に伝熱板を埋設し、その伝熱板の一部を突出させ、その部分を適当な冷却手段にて冷却する手段が開示されている(特許文献2)。   As a conventional battery pack cooling means, there is disclosed a method of cooling a battery by restraining it in a state where a passage through which a refrigerant can pass is provided between each of a plurality of batteries constituting the battery pack, and passing the refrigerant between them. (Patent Document 1). Further, a means is disclosed in which a heat transfer plate is embedded in the battery case of each battery constituting the assembled battery, a part of the heat transfer plate is protruded, and the portion is cooled by an appropriate cooling means. (Patent Document 2).

しかしながら、特許文献1に記載の組電池は、単位電池それぞれの間に冷媒通路を設けた状態で冷媒を通す隙間を設ける必要があり、組電池の体積エネルギー密度が低下する。そして、特許文献2の組電池は電池ケースを介して伝熱するために、冷却効率が充分でないおそれがある。   However, in the assembled battery described in Patent Document 1, it is necessary to provide a gap through which the refrigerant is passed in a state where the refrigerant passage is provided between the unit batteries, and the volume energy density of the assembled battery is reduced. And since the assembled battery of patent document 2 transfers heat through a battery case, there exists a possibility that cooling efficiency may not be enough.

そこで、特許文献3では単位電池が有する端子部材に冷却部材を接合し冷却効率を向上させた組電池が開示されている。
特開2003−7355号公報 特開2003−36819号公報 特開2002−56904号公報
Therefore, Patent Document 3 discloses an assembled battery in which a cooling member is joined to a terminal member included in a unit battery to improve cooling efficiency.
JP 2003-7355 A JP 2003-36819 A JP 2002-56904 A

しかしながら、特許文献3の組電池では構造が複雑になりコストが上昇する問題がある。また、組電池に要求される性能向上の観点から、更なる冷却効率の向上が求められている。   However, the assembled battery of Patent Document 3 has a problem that the structure is complicated and the cost increases. Further, further improvement in cooling efficiency is required from the viewpoint of performance improvement required for the assembled battery.

そこで上記実情に鑑み本発明では、構成の簡単な組電池を提供することを第1の解決すべき課題とする。また、冷却効率の高い組電池を提供することを第2の解決すべき課題とする。   Accordingly, in view of the above circumstances, the present invention has a first problem to be solved to provide an assembled battery with a simple configuration. In addition, providing a battery pack with high cooling efficiency is a second problem to be solved.

(1)上記第1の課題を解決する本発明の組電池は、発電要素である電極体及び該電極体に対して電力の授受を行う端子部材をもつ複数の単位電池と、該各単位電池の該端子部材間を電気的に接続する複数のバスバーと、を有する組電池であって、
該各バスバーは冷却フィンをもち、該各単位電池を冷却する冷却部材を兼ねることを特徴とする。
(1) An assembled battery of the present invention that solves the first problem includes an electrode body that is a power generation element, a plurality of unit batteries each having a terminal member that transmits and receives power to the electrode body, and the unit batteries. A plurality of bus bars for electrically connecting the terminal members;
Each bus bar has a cooling fin, and also serves as a cooling member for cooling each unit battery.

つまり、組電池を構成するに当たり必須の構成要素であるバスバーに対して冷却部材としての機能をもたせることで構成要素を減らしたものである。また、バスバーは大電流を流す部材であるので端子部材との間で充分な電気的接合が為されており伝熱性も良いと考えられるので、伝熱性を向上するための新たなコストを要さないという利点がある。   That is, the constituent elements are reduced by providing a function as a cooling member to the bus bar which is an essential constituent element in configuring the assembled battery. In addition, since the bus bar is a member through which a large current flows, sufficient electrical connection is made with the terminal member and the heat transfer is considered to be good, so that a new cost is required to improve the heat transfer. There is no advantage.

(2)また、上記第2の課題を解決する本発明の組電池は、発電要素である電極体及び該電極体に対して電力の授受を行う端子部材をもつ複数の単位電池と、該各単位電池の該端子部材間を電気的に接続する複数のバスバーと、該各単位電池のそれぞれに接続され冷媒に放熱することで該単位電池を冷却する冷却フィンをもつ複数の冷却部材と、を有する組電池であって、
該各冷却フィンは冷媒の流れ方向に沿って配設し、冷媒の流れ方向に対して完全に重ならないように隣接する該各冷却部材間でずらして配設したことを特徴とする。
(2) Moreover, the assembled battery of the present invention that solves the second problem includes an electrode body that is a power generation element, a plurality of unit batteries each having a terminal member that transmits and receives power to the electrode body, A plurality of bus bars that are electrically connected between the terminal members of the unit battery, and a plurality of cooling members that are connected to each of the unit batteries and have cooling fins that cool the unit battery by radiating heat to the refrigerant. An assembled battery comprising:
The cooling fins are arranged along the flow direction of the refrigerant, and are arranged so as to be shifted between the adjacent cooling members so as not to completely overlap the flow direction of the refrigerant.

冷却部材の冷却フィンに対して冷媒を流すことにより冷却を行う場合に、冷却フィンは冷媒の流れ方向に沿って配設することで、冷媒の流れを妨げない。そして、隣接する冷却部材間で冷却フィンをずらすことで冷媒の流れに僅かな乱流を発生させ、冷媒の冷却能力を最大限に発揮できるとともに、単位電池毎の冷却能力のばらつきを小さくできる。   When cooling is performed by flowing a refrigerant to the cooling fins of the cooling member, the cooling fins are arranged along the flow direction of the refrigerant so as not to disturb the flow of the refrigerant. Further, by shifting the cooling fins between adjacent cooling members, a slight turbulent flow is generated in the refrigerant flow, so that the cooling capacity of the refrigerant can be maximized and the variation in the cooling capacity of each unit cell can be reduced.

そして、前述したように、部品点数を減らすことができるので、前記バスバーが前記冷却部材を兼ねることが好ましい。   As described above, since the number of parts can be reduced, it is preferable that the bus bar also serves as the cooling member.

また、前記冷却部材は冷媒の流れ方向に対して垂直方向における断面形状が所定間隔で繰り返し単位をもち、隣接する前記冷却部材間の該冷却フィンのずれは該所定間隔の半分であることが好ましい。連続して配設される冷却部材間の重なりを所定間隔の半分にすることで、冷媒の流れ方向における両者の重なりを最小限にできるので、冷媒の流れに対する抵抗を最小限にしながら冷却効率を向上できる。   Further, it is preferable that the cooling member has a cross-sectional shape in a direction perpendicular to the flow direction of the refrigerant having a repeating unit at a predetermined interval, and a deviation of the cooling fin between the adjacent cooling members is half of the predetermined interval. . Since the overlap between the continuously arranged cooling members is half of the predetermined interval, the overlap between the two in the refrigerant flow direction can be minimized, so that the cooling efficiency can be improved while minimizing the resistance to the refrigerant flow. It can be improved.

(3)更に上述の組電池において、前記各冷却部材は1以上の組に分けられ、且つ該組毎に冷媒の流れ方向に連続して並べて配設されており、更に該冷却部材の該組毎に冷媒の流れを整える冷媒ダクトを備えることが好ましい。冷媒ダクトにより冷媒の流れを適正に制御できる。また、前記冷媒ダクトは冷媒の流れ方向に対して所定角度をもって配設され且つ冷媒の流れを一部妨げる仕切板をもつことが好ましい。仕切板により冷媒の流れの一部に乱流を発生することで冷却効率を向上できる。   (3) Further, in the above-described assembled battery, each of the cooling members is divided into one or more groups, and each of the groups is continuously arranged in the refrigerant flow direction. It is preferable to provide a refrigerant duct for adjusting the flow of the refrigerant every time. The refrigerant flow can be appropriately controlled by the refrigerant duct. Moreover, it is preferable that the said refrigerant | coolant duct has a partition plate arrange | positioned with a predetermined angle with respect to the flow direction of a refrigerant | coolant, and obstructing a part of refrigerant | coolant flow. Cooling efficiency can be improved by generating a turbulent flow in a part of the refrigerant flow by the partition plate.

本実施形態の組電池はバスバーにより単位電池の端子部材間を電気的に接合している。単位電池は発電要素である電極体とその電極体に対して電力の授受を行う端子部材をもつ。単位電池の種類としては限定しないが二次電池に適用することが望ましく、特にエネルギー密度が高いニッケル水素二次電池、リチウム二次電池に適用することが望ましい。本実施形態の組電池は冷媒を流すことで単位電池を冷却する冷却部材を有する。冷媒としては空気などの流体が採用できる。   In the assembled battery of this embodiment, the terminal members of the unit battery are electrically joined by the bus bar. The unit battery has an electrode body that is a power generation element and a terminal member that transmits and receives power to the electrode body. Although it does not limit as a kind of unit battery, applying to a secondary battery is desirable, and applying to a nickel-hydrogen secondary battery and a lithium secondary battery with a high energy density especially is desirable. The assembled battery of this embodiment has a cooling member that cools the unit battery by flowing a refrigerant. A fluid such as air can be used as the refrigerant.

(第1形態)
バスバーは冷却フィンをもっており、冷却部材を兼ねる。その結果、本組電池の部品点数が削減できる。また、組電池における発熱源である電極体との間で電気的接続が充分に行われているので、特に追加の手段・方法を採用することなく熱的接続についても充分に確保できる。
(First form)
The bus bar has cooling fins and also serves as a cooling member. As a result, the number of parts of the assembled battery can be reduced. In addition, since the electrical connection is sufficiently performed with the electrode body which is a heat generation source in the assembled battery, the thermal connection can be sufficiently ensured without employing any additional means / method.

バスバーは単位電池間に流れる電流の大きさによりその形状(特に断面積)が決定される。バスバーはすべて冷却フィンをもつことが必須ではないが大多数のバスバーは冷却フィンをもつ。バスバーを構成する素材は限定しないが、組電池の配設される雰囲気において安定な素材であり、電気伝導性及び熱伝導性に優れた素材が望ましい。例えば、銅、アルミニウム、ステンレス、銅合金などである。バスバーがもつ冷却フィンは、プレス成形、押し出し成形、鋳造などにより一体的に成形されるか、ろう付、溶接などにより一体的に接合されることが冷却性能向上の観点から好ましい。   The shape (particularly the cross-sectional area) of the bus bar is determined by the magnitude of the current flowing between the unit cells. It is not essential that all bus bars have cooling fins, but most bus bars have cooling fins. Although the material which comprises a bus-bar is not limited, The material which is stable in the atmosphere by which an assembled battery is arrange | positioned, and the material excellent in electrical conductivity and heat conductivity is desirable. For example, copper, aluminum, stainless steel, copper alloy and the like. It is preferable from the viewpoint of improving the cooling performance that the cooling fins of the bus bar are integrally formed by press molding, extrusion molding, casting or the like, or integrally joined by brazing, welding, or the like.

更に冷却フィンに空気などの冷媒を流すための冷却ファンなどをもつことが好ましい。また、冷媒の流れを適正に制御するために冷媒の流れを導き整流する冷媒ダクトにより冷却フィンを覆うことが好ましい。冷媒ダクトは冷媒の流れ方向に所定角度をもって配設される仕切板をもつことが好ましい。仕切板は例えば冷媒の流れに垂直方向に配設された板状体であり、冷媒の流れを乱すことで冷却効率を向上する。   Furthermore, it is preferable to have a cooling fan or the like for flowing a coolant such as air through the cooling fin. Further, in order to appropriately control the refrigerant flow, it is preferable to cover the cooling fin with a refrigerant duct that guides and rectifies the refrigerant flow. The refrigerant duct preferably has a partition plate disposed at a predetermined angle in the refrigerant flow direction. The partition plate is, for example, a plate-like body disposed in a direction perpendicular to the refrigerant flow, and improves the cooling efficiency by disturbing the refrigerant flow.

(第2形態)
本実施形態の組電池は冷却フィンをもつ冷却部材を有し、それぞれの単位電池に接続される。冷却フィンは冷媒の流れ方向に沿って配設される。例えば、冷却フィンは板状体であり、冷媒が流れる方向に沿ってその板状体を向け、所定間隔を介して配設される。その結果、冷却フィン同士は平行に配設される。冷却部材を構成する素材は限定しないが、組電池の配設される雰囲気において安定な素材であり、熱伝導性に優れた素材が望ましい。例えば、銅、アルミニウム、ステンレス、銅合金などである。冷却部材がもつ冷却フィンは、プレス成形、押し出し成形、鋳造などにより一体的に成形されるか、ろう付、溶接などにより一体的に接合されることが冷却性能向上の観点から好ましい。
(Second form)
The assembled battery of this embodiment has a cooling member having cooling fins and is connected to each unit battery. The cooling fins are disposed along the flow direction of the refrigerant. For example, the cooling fin is a plate-like body, and the plate-like body is directed along the direction in which the refrigerant flows, and is disposed at a predetermined interval. As a result, the cooling fins are arranged in parallel. Although the material which comprises a cooling member is not limited, the material which is stable in the atmosphere by which an assembled battery is arrange | positioned, and the material excellent in heat conductivity is desirable. For example, copper, aluminum, stainless steel, copper alloy and the like. The cooling fins of the cooling member are preferably formed integrally by press molding, extrusion molding, casting, or the like, or integrally joined by brazing, welding, or the like from the viewpoint of improving cooling performance.

各冷却部材は、冷媒が流れる方向に対する断面形状ができるだけ重ならないように、ずらしている。ずらす程度は僅かでよい。例えば、冷却部材(特に冷却フィンの部分)は、冷媒の流れ方向に対して垂直方向における断面形状が所定間隔で繰り返し単位をもつような形状を採用し、隣接する冷却部材間での冷却フィンのずれをその所定間隔の半分とすることで、効果的な冷却作用を発揮できる。つまり、冷媒が冷却フィンの間を通過した後、次の冷却フィンに衝突することを繰り返すことで冷媒と冷却フィンとを最大限接触させることができ効果的に冷却作用を発揮できる。   The cooling members are shifted so that the cross-sectional shapes with respect to the direction in which the refrigerant flows do not overlap as much as possible. The amount of shifting may be slight. For example, the cooling member (particularly the cooling fin portion) adopts a shape in which the cross-sectional shape in the direction perpendicular to the refrigerant flow direction has a repeating unit at a predetermined interval, and the cooling fin between the adjacent cooling members An effective cooling action can be exhibited by setting the deviation to half of the predetermined interval. That is, after the refrigerant has passed between the cooling fins, the refrigerant and the cooling fin can be brought into maximum contact with each other by repeating the collision with the next cooling fin, and the cooling action can be effectively exhibited.

更に、前述の第1形態と同様にバスバーが冷却部材を兼ねることで部品点数を削除できる。また、冷却フィンに空気などの冷媒を流すための冷却ファンなどをもつことが好ましい。また、冷媒の流れを適正に制御するために冷媒の流れを導き整流する冷媒ダクトにより冷却フィンを覆うことが好ましい。冷媒ダクトは冷媒の流れ方向に所定角度をもって配設される仕切板をもつことが好ましい。仕切板は例えば冷媒の流れに垂直方向に配設された板状体であり、冷媒の流れを乱すことで冷却効率を向上する。   Further, the number of parts can be eliminated by having the bus bar also serve as a cooling member as in the first embodiment. Moreover, it is preferable to have a cooling fan or the like for flowing a coolant such as air through the cooling fin. Further, in order to appropriately control the refrigerant flow, it is preferable to cover the cooling fin with a refrigerant duct that guides and rectifies the refrigerant flow. The refrigerant duct preferably has a partition plate disposed at a predetermined angle in the refrigerant flow direction. The partition plate is, for example, a plate-like body disposed in a direction perpendicular to the refrigerant flow, and improves the cooling efficiency by disturbing the refrigerant flow.

〔実施例1〕
(構成)
本発明の組電池について図面に基づき以下詳細に説明する。図1〜3に示すように、本実施形態の組電池は、単位電池1を複数個、積層した積層体1a及び1bを有している。単位電池1は角形電池であり、厚み方向に積層して積層体1a及び1bを形成する。単位電池1は上部端面の両端部に電極をもつ。積層体1a及び1bを構成する各単位電池1間の対応する電極同士は、冷却部材を兼ねたバスバー10a及び10bで接続しており、最終的には総端子5及び6から電力を授受する。
[Example 1]
(Constitution)
The assembled battery of the present invention will be described below in detail with reference to the drawings. As shown in FIGS. 1-3, the assembled battery of this embodiment has the laminated bodies 1a and 1b which laminated | stacked the unit battery 1 in multiple numbers. The unit battery 1 is a prismatic battery, and is laminated in the thickness direction to form laminates 1a and 1b. The unit cell 1 has electrodes at both ends of the upper end surface. Corresponding electrodes between the unit cells 1 constituting the stacked bodies 1a and 1b are connected by bus bars 10a and 10b which also serve as cooling members, and finally, power is transferred from the total terminals 5 and 6.

バスバー10a及び10bはそれぞれ金属板を折り曲げて形成した部材であり、所定間隔にて3つの山及び3つの谷が交互に形成される。つまり、冷却部材(バスバー10a及び10b)は冷媒の流れ方向における断面形状が所定間隔(山と山、谷と谷との間)で繰り返し単位をもつ。そして、積層体1a及び1bを構成する単位電池1に接続された各バスバー10a及び10bは、隣接する単位電池1間にてバスバー10a及び10bの山部分と谷部分とが重なるように、所定間隔の半分だけずらして固定されている。なお、バスバー10a及び10bと単位電池1の端子部材との接続は超音波溶接にて行っている。   Each of the bus bars 10a and 10b is a member formed by bending a metal plate, and three peaks and three valleys are alternately formed at predetermined intervals. In other words, the cooling members (bus bars 10a and 10b) have a repeating unit with a predetermined interval (between peaks and peaks and between valleys and valleys) in the cross-sectional shape in the refrigerant flow direction. And each bus bar 10a and 10b connected to the unit battery 1 which comprises the laminated bodies 1a and 1b is a predetermined space | interval so that the peak part and trough part of bus bar 10a and 10b may overlap between the adjacent unit batteries 1. FIG. It is fixed by shifting by half. The bus bars 10a and 10b and the terminal member of the unit battery 1 are connected by ultrasonic welding.

単位電池1は、図4に示すように、発電要素である電極体12と端子部材14及び15とをラミネートフィルムからなる樹脂ケース11で封止して形成している。端子部材14及び15は上端部が直角に折れ曲がっている。樹脂ケース11内には電解液を注入してある。電解液はガス排出部材13から注入し、電解液注入後、ガス排出部材13のガス排出口をラミネートフィルムの封止により塞いでいる。各単位電池1にはそれぞれガス排出部材13をもち、積層体1a及び1bとした場合に、直線上に並んでいる。ガス排出部材13のガス排出口にはガスを外部に誘導するガス排出パイプ3a及び3bが取り付けられている。   As shown in FIG. 4, the unit battery 1 is formed by sealing an electrode body 12 that is a power generation element and terminal members 14 and 15 with a resin case 11 made of a laminate film. The upper ends of the terminal members 14 and 15 are bent at a right angle. An electrolytic solution is injected into the resin case 11. The electrolyte is injected from the gas discharge member 13, and after the injection of the electrolyte, the gas discharge port of the gas discharge member 13 is closed with a laminate film. Each unit battery 1 has a gas discharge member 13 and is arranged in a straight line when the stacked bodies 1a and 1b are formed. Gas discharge pipes 3 a and 3 b for guiding the gas to the outside are attached to the gas discharge port of the gas discharge member 13.

図1及び5に示すように、積層体1a及び1bはベース9上にエンドプレート92a及び92b、拘束バンド4a及び4bによって固定されている。エンドプレート92a及び92bは積層体1a及び1bを狭持するようにベース9上にねじ止めされている。積層体1a及び1bは、エンドプレート92a及び92bの間で、保護プレート16及び板バネ17を両端に介して狭持されている。保護プレート16及び板バネ17により積層体1a及び1bは単位電池1の積層方向に保持されている。   As shown in FIGS. 1 and 5, the laminated bodies 1a and 1b are fixed on the base 9 by end plates 92a and 92b and restraint bands 4a and 4b. The end plates 92a and 92b are screwed onto the base 9 so as to sandwich the stacked bodies 1a and 1b. The laminated bodies 1a and 1b are sandwiched between the end plates 92a and 92b via the protective plate 16 and the leaf spring 17 at both ends. The stacked bodies 1 a and 1 b are held in the stacking direction of the unit cells 1 by the protection plate 16 and the leaf spring 17.

積層体1a及び1bの側面を拘束バンド4a及び4bが保持する。拘束バンド4a及び4bの両端にはピン8が接続されており、それぞれエンドプレート92a及び92bの両端に設けられた嵌合穴に嵌合される。   Restraint bands 4a and 4b hold the side surfaces of the laminated bodies 1a and 1b. Pins 8 are connected to both ends of the restraining bands 4a and 4b, and are fitted into fitting holes provided at both ends of the end plates 92a and 92b, respectively.

積層体1a及び1bを収納するケース7がベース9に固定される。ケース7の内面と、積層体1a及び1bの上面とで区画する空間は冷媒の流れを制御する冷媒ダクトとして作用する。つまり、この空間に冷媒としての空気を導き、効率的に冷却フィン間に流している。更に、ケース7に設けられたダクト仕切板71及び72により積層体1aと積層体1bとで独立して冷媒が流れるダクトを形成する。また、ケース7には冷媒としての空気の導入口が設けられている。更に、ケース7の内面上方には冷却フィンの上端部に達する程度の仕切板18が設けられている。   A case 7 that houses the laminates 1 a and 1 b is fixed to the base 9. A space defined by the inner surface of the case 7 and the upper surfaces of the laminates 1a and 1b acts as a refrigerant duct that controls the flow of the refrigerant. That is, air as a refrigerant is guided to this space and efficiently flows between the cooling fins. Furthermore, the duct partition plates 71 and 72 provided in the case 7 form a duct through which refrigerant flows independently between the laminate 1a and the laminate 1b. The case 7 is provided with an inlet for air as a refrigerant. Further, a partition plate 18 is provided above the inner surface of the case 7 so as to reach the upper end of the cooling fin.

(作用効果)
本実施例の組電池は使用によって発熱する。組電池における発熱は主に発電要素である電極体12部分であると考えられる。電極体12部分で発生した熱は、熱伝導によりバスバー10a及び10bの冷却フィンにまで到達する。バスバー10a及び10bは電池からの出力に耐えられる程度に充分に端子部材14及び15に接続されているので、これらの間の熱抵抗は充分に小さい値である。
(Function and effect)
The assembled battery of this embodiment generates heat when used. Heat generation in the assembled battery is considered to be mainly in the electrode body 12 portion that is a power generation element. The heat generated in the electrode body 12 reaches the cooling fins of the bus bars 10a and 10b by heat conduction. Since the bus bars 10a and 10b are sufficiently connected to the terminal members 14 and 15 to withstand the output from the battery, the thermal resistance between them is a sufficiently small value.

冷却フィンには図5左方から冷媒としての空気が流入する。流入する空気により冷却フィンの熱が持ち去られる。ここで、バスバー10a及び10bがもつ冷却フィンは隣接する単位電池1間にて、ある程度ずらされているので、流入する冷媒は冷却フィンの間を冷却フィンにぶつかりながら流れる。その結果、冷媒の流れは乱流になり、効率的に冷却作用を発揮できる。   Air as a refrigerant flows into the cooling fin from the left side of FIG. The heat of the cooling fin is carried away by the inflowing air. Here, the cooling fins of the bus bars 10a and 10b are shifted to some extent between the adjacent unit cells 1, so that the inflowing refrigerant flows between the cooling fins while colliding with the cooling fins. As a result, the flow of the refrigerant becomes turbulent and can efficiently exhibit a cooling action.

なお、ガス排出部材13は単位電池1の内圧が何らかの原因により上昇した場合に単位電池1内外を連通してガスを排出し、単位電池1の内圧を低下させる作用をもつ。ガス排出部材13のガス排出口から排出されたガスは、ガス排出パイプ3a及び3bを通ってケース7の外に誘導される。   The gas discharge member 13 has a function of reducing the internal pressure of the unit cell 1 by discharging gas through the inside and outside of the unit cell 1 when the internal pressure of the unit cell 1 is increased for some reason. The gas discharged from the gas discharge port of the gas discharge member 13 is guided out of the case 7 through the gas discharge pipes 3a and 3b.

〔変形例〕
上記実施例1の単位電池1に代えて、図6に示すような、金属ケース19をもつ単位電池2を用いている。単位電池2は、図8に示すように、単位電池1と同様の電極体12をもつ。図7及び8に示すように、電極体12には板状の端子部材22及び24をもつ。これらは、図9に示すように、金属ケース19内に収納される。金属ケース19の上蓋21には電解液注入口20及びガス排出部材23が形成されている。
[Modification]
Instead of the unit battery 1 of the first embodiment, a unit battery 2 having a metal case 19 as shown in FIG. 6 is used. As shown in FIG. 8, the unit battery 2 has an electrode body 12 similar to that of the unit battery 1. As shown in FIGS. 7 and 8, the electrode body 12 has plate-like terminal members 22 and 24. These are housed in a metal case 19 as shown in FIG. An electrolyte solution inlet 20 and a gas discharge member 23 are formed in the upper lid 21 of the metal case 19.

端子部材22及び24の先端部には冷却部材を兼ねるバスバー25a及び25bが接続される。バスバー20a及び20bはバスバー10a及び10bとほぼ同様の冷却フィンをもつ。冷却フィンの配置(隣接する単位電池2間でずらすこと)もほぼ同様である(図9)。   Bus bars 25a and 25b that also serve as cooling members are connected to the tip portions of the terminal members 22 and 24, respectively. The bus bars 20a and 20b have substantially the same cooling fins as the bus bars 10a and 10b. The arrangement of the cooling fins (shifting between adjacent unit cells 2) is almost the same (FIG. 9).

実施例の組電池の分解斜視図である。It is a disassembled perspective view of the assembled battery of an Example. 実施例の組電池の積層体及びその周辺の平面概略図である。It is the plane schematic of the laminated body of the assembled battery of an Example, and its periphery. 実施例の組電池を構成する1つの単位電池の概略図である。It is the schematic of one unit battery which comprises the assembled battery of an Example. 実施例の単位電池を構成する電極体及び端子部材を示す概略図である。It is the schematic which shows the electrode body and terminal member which comprise the unit battery of an Example. 実施例の組電池の一部断面図である。It is a partial cross section figure of the assembled battery of an Example. 変形例の組電池を構成する1つの単位電池の概略図である。It is the schematic of one unit battery which comprises the assembled battery of a modification. 変形例の組電池を構成する1つの単位電池内部の概略図である。It is the schematic inside one unit battery which comprises the assembled battery of a modification. 変形例の組電池を構成する1つの単位電池内部の概略図である。It is the schematic inside one unit battery which comprises the assembled battery of a modification. 変形例の組電池を構成する1つの単位電池の概略図である。It is the schematic of one unit battery which comprises the assembled battery of a modification. 変形例の組電池の積層体及びその周辺の平面概略図である。It is the plane schematic diagram of the laminated body of the assembled battery of a modification, and its periphery.

符号の説明Explanation of symbols

1、2…単位電池 1a、1b…積層体 11…樹脂ケース 12…電極体 13、23…ガス排出部材 14、15、22、24…端子部材、16…保護プレート 17…板バネ 19…金属ケース 20…電解液注入口 21…上蓋
10a、10b、25a、25b…冷却部材
3a、3b…ガス排出パイプ
4a、4b…拘束バンド
5、6…総端子
7…ケース 18…仕切板
8…ピン
9…ベース 92a、92b…エンドプレート
DESCRIPTION OF SYMBOLS 1, 2 ... Unit battery 1a, 1b ... Laminated body 11 ... Resin case 12 ... Electrode body 13, 23 ... Gas exhaust member 14, 15, 22, 24 ... Terminal member, 16 ... Protection plate 17 ... Plate spring 19 ... Metal case DESCRIPTION OF SYMBOLS 20 ... Electrolyte injection port 21 ... Upper cover 10a, 10b, 25a, 25b ... Cooling member 3a, 3b ... Gas exhaust pipe 4a, 4b ... Restraint band 5, 6 ... Total terminal 7 ... Case 18 ... Partition plate 8 ... Pin 9 ... Base 92a, 92b ... End plate

Claims (6)

発電要素である電極体及び該電極体に対して電力の授受を行う端子部材をもつ複数の単位電池と、該各単位電池の該端子部材間を電気的に接続する複数のバスバーと、を有する組電池であって、
該各バスバーは冷却フィンをもち、該各単位電池を冷却する冷却部材を兼ねることを特徴とする組電池。
A plurality of unit cells each having an electrode body that is a power generation element and a terminal member that transmits and receives power to the electrode body; and a plurality of bus bars that electrically connect the terminal members of each unit battery. An assembled battery,
Each bus bar has a cooling fin and also serves as a cooling member for cooling each unit battery.
発電要素である電極体及び該電極体に対して電力の授受を行う端子部材をもつ複数の単位電池と、該各単位電池の該端子部材間を電気的に接続する複数のバスバーと、該各単位電池のそれぞれに接続され冷媒に放熱することで該単位電池を冷却する冷却フィンをもつ複数の冷却部材と、を有する組電池であって、
該各冷却フィンは冷媒の流れ方向に沿って配設し、冷媒の流れ方向に対して完全に重ならないように隣接する該各冷却部材間でずらして配設したことを特徴とする組電池。
A plurality of unit cells each having an electrode body that is a power generation element and a terminal member that transmits and receives power to the electrode body; a plurality of bus bars that electrically connect the terminal members of each unit battery; A plurality of cooling members having cooling fins that are connected to each of the unit cells and radiate heat to the refrigerant to cool the unit cells,
The assembled battery is characterized in that the cooling fins are arranged along the flow direction of the refrigerant, and are shifted between the adjacent cooling members so as not to completely overlap the flow direction of the refrigerant.
前記バスバーが前記冷却部材を兼ねる請求項2に記載の組電池。   The assembled battery according to claim 2, wherein the bus bar also serves as the cooling member. 前記冷却部材は冷媒の流れ方向に対して垂直方向における断面形状が所定間隔で繰り返し単位をもち、
隣接する前記冷却部材間の該冷却フィンのずれは該所定間隔の半分である請求項2又は3に記載の組電池。
The cooling member has a repeating unit at a predetermined interval in a cross-sectional shape in a direction perpendicular to the flow direction of the refrigerant,
The assembled battery according to claim 2 or 3, wherein a deviation of the cooling fin between the adjacent cooling members is half of the predetermined interval.
前記各冷却部材は1以上の組に分けられ、且つ該組毎に冷媒の流れ方向に連続して並べて配設されており、
更に該冷却部材の該組毎に冷媒の流れを整える冷媒ダクトを備える請求項1〜4のいずれかに記載の組電池。
Each of the cooling members is divided into one or more sets, and each of the cooling members is continuously arranged in the flow direction of the refrigerant.
Furthermore, the assembled battery in any one of Claims 1-4 provided with the refrigerant | coolant duct which arranges the flow of a refrigerant | coolant for every group of this cooling member.
前記冷媒ダクトは冷媒の流れ方向に対して所定角度をもって配設され且つ冷媒の流れを一部妨げる仕切板をもつ請求項5に記載の組電池。   The assembled battery according to claim 5, wherein the refrigerant duct includes a partition plate that is disposed at a predetermined angle with respect to a flow direction of the refrigerant and partially blocks the flow of the refrigerant.
JP2003296900A 2003-08-20 2003-08-20 Assembled battery Expired - Lifetime JP4349037B2 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2003296900A JP4349037B2 (en) 2003-08-20 2003-08-20 Assembled battery

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2003296900A JP4349037B2 (en) 2003-08-20 2003-08-20 Assembled battery

Publications (2)

Publication Number Publication Date
JP2005071674A true JP2005071674A (en) 2005-03-17
JP4349037B2 JP4349037B2 (en) 2009-10-21

Family

ID=34402911

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2003296900A Expired - Lifetime JP4349037B2 (en) 2003-08-20 2003-08-20 Assembled battery

Country Status (1)

Country Link
JP (1) JP4349037B2 (en)

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006344572A (en) * 2005-05-10 2006-12-21 Nec Lamilion Energy Ltd Manufacturing method for electric device module and electric device module
JP2008234936A (en) * 2007-03-19 2008-10-02 Denso Corp Battery pack
JP2008258027A (en) * 2007-04-05 2008-10-23 Denso Corp Collective battery
DE102009011659A1 (en) 2008-03-05 2009-09-10 DENSO CORPORATION, Kariya-shi Battery unit for vehicles
JP2009252417A (en) * 2008-04-02 2009-10-29 Denso Corp Battery cooling device
JP2009252652A (en) * 2008-04-09 2009-10-29 Denso Corp Battery pack
JP2010097824A (en) * 2008-10-16 2010-04-30 Denso Corp Battery cooler
JP2010113961A (en) * 2008-11-06 2010-05-20 Denso Corp Battery pack
JP2010244732A (en) * 2009-04-01 2010-10-28 Denso Corp Battery system
US20110020686A1 (en) * 2009-02-24 2011-01-27 Yazaki Corporation Cooling system for battery pack
JP2011507199A (en) * 2007-12-20 2011-03-03 ダイムラー・アクチェンゲゼルシャフト Battery with case and heat conducting plate
US8007933B2 (en) 2007-06-20 2011-08-30 Toyota Jidosha Kabushiki Kaisha Vehicle power storage unit and vehicle
WO2012062644A1 (en) 2010-11-12 2012-05-18 Avl List Gmbh Cell connector
CN102820494A (en) * 2011-06-09 2012-12-12 索尼公司 Battery module, electronic apparatus, electric power storage system, electric power system, and electric vehicle
FR3011129A1 (en) * 2013-09-24 2015-03-27 Valeo Systemes Thermiques BATTERY MODULE FOR ELECTRIC OR HYBRID VEHICLE FOR COOLING CELLS, AND BATTERY THEREFOR
JP2015176793A (en) * 2014-03-17 2015-10-05 本田技研工業株式会社 power storage device
GB2529612A (en) * 2014-06-25 2016-03-02 R & D Vehicle Systems Ltd Device for a battery assembly
CN107394305A (en) * 2017-06-25 2017-11-24 安徽机电职业技术学院 A kind of battery heat dissipation device of electric automobile
JP2018018755A (en) * 2016-07-29 2018-02-01 株式会社デンソー Battery pack
WO2018235473A1 (en) * 2017-06-22 2018-12-27 株式会社デンソー Terminal cooling device
CN111082187A (en) * 2020-01-08 2020-04-28 浙江吉利新能源商用车集团有限公司 Battery package cooling device
WO2021072466A1 (en) * 2019-10-14 2021-04-22 Miba Emobility Gmbh Rechargeable battery
CN112868129A (en) * 2018-09-25 2021-05-28 本田技研工业株式会社 Battery module
CN114421086A (en) * 2021-12-29 2022-04-29 杰锋汽车动力系统股份有限公司 Automobile power lithium ion battery module structure
WO2023284886A1 (en) * 2021-07-14 2023-01-19 珠海冠宇动力电池有限公司 Battery pack
US11942659B2 (en) 2021-03-04 2024-03-26 Lg Energy Solution Ltd. Battery module and battery pack including the same

Cited By (39)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2006344572A (en) * 2005-05-10 2006-12-21 Nec Lamilion Energy Ltd Manufacturing method for electric device module and electric device module
JP2008234936A (en) * 2007-03-19 2008-10-02 Denso Corp Battery pack
JP2008258027A (en) * 2007-04-05 2008-10-23 Denso Corp Collective battery
US8007933B2 (en) 2007-06-20 2011-08-30 Toyota Jidosha Kabushiki Kaisha Vehicle power storage unit and vehicle
JP2011507199A (en) * 2007-12-20 2011-03-03 ダイムラー・アクチェンゲゼルシャフト Battery with case and heat conducting plate
DE102009011659A1 (en) 2008-03-05 2009-09-10 DENSO CORPORATION, Kariya-shi Battery unit for vehicles
US20090226800A1 (en) * 2008-03-05 2009-09-10 Denso Corporation Battery unit for vehicles
US8475951B2 (en) 2008-03-05 2013-07-02 Denso Corporation Battery unit for vehicles
JP4661895B2 (en) * 2008-04-02 2011-03-30 株式会社デンソー Battery cooling device
JP2009252417A (en) * 2008-04-02 2009-10-29 Denso Corp Battery cooling device
US8906530B2 (en) 2008-04-02 2014-12-09 Denso Corporation Battery unit with blower
JP2009252652A (en) * 2008-04-09 2009-10-29 Denso Corp Battery pack
JP2010097824A (en) * 2008-10-16 2010-04-30 Denso Corp Battery cooler
JP2010113961A (en) * 2008-11-06 2010-05-20 Denso Corp Battery pack
US20110020686A1 (en) * 2009-02-24 2011-01-27 Yazaki Corporation Cooling system for battery pack
US8597843B2 (en) * 2009-02-24 2013-12-03 Yazaki Corporation Cooling system for battery pack
JP2010244732A (en) * 2009-04-01 2010-10-28 Denso Corp Battery system
DE102010016265B4 (en) 2009-04-01 2022-05-12 Denso Corporation Battery system with an assembled battery
WO2012062644A1 (en) 2010-11-12 2012-05-18 Avl List Gmbh Cell connector
JP2012256521A (en) * 2011-06-09 2012-12-27 Sony Corp Battery module, electronic apparatus, power system, and electric vehicle
CN102820494A (en) * 2011-06-09 2012-12-12 索尼公司 Battery module, electronic apparatus, electric power storage system, electric power system, and electric vehicle
US9005801B2 (en) 2011-06-09 2015-04-14 Sony Corporation Battery module, electronic apparatus, electric power storage system, electric power system, and electric vehicle
CN102820494B (en) * 2011-06-09 2016-03-16 索尼公司 Battery module, electronic installation, power storage system and electric power system
FR3011129A1 (en) * 2013-09-24 2015-03-27 Valeo Systemes Thermiques BATTERY MODULE FOR ELECTRIC OR HYBRID VEHICLE FOR COOLING CELLS, AND BATTERY THEREFOR
WO2015043869A1 (en) * 2013-09-24 2015-04-02 Valeo Systemes Thermiques Battery module for an electric or hybrid vehicle to ensure the cooling of the cells, and associated battery
JP2015176793A (en) * 2014-03-17 2015-10-05 本田技研工業株式会社 power storage device
GB2529612A (en) * 2014-06-25 2016-03-02 R & D Vehicle Systems Ltd Device for a battery assembly
JP2018018755A (en) * 2016-07-29 2018-02-01 株式会社デンソー Battery pack
US11444353B2 (en) 2016-07-29 2022-09-13 Denso Corporation Battery pack
WO2018235473A1 (en) * 2017-06-22 2018-12-27 株式会社デンソー Terminal cooling device
CN107394305A (en) * 2017-06-25 2017-11-24 安徽机电职业技术学院 A kind of battery heat dissipation device of electric automobile
CN112868129A (en) * 2018-09-25 2021-05-28 本田技研工业株式会社 Battery module
CN112868129B (en) * 2018-09-25 2023-10-27 本田技研工业株式会社 battery module
WO2021072466A1 (en) * 2019-10-14 2021-04-22 Miba Emobility Gmbh Rechargeable battery
CN111082187A (en) * 2020-01-08 2020-04-28 浙江吉利新能源商用车集团有限公司 Battery package cooling device
US11942659B2 (en) 2021-03-04 2024-03-26 Lg Energy Solution Ltd. Battery module and battery pack including the same
WO2023284886A1 (en) * 2021-07-14 2023-01-19 珠海冠宇动力电池有限公司 Battery pack
CN114421086A (en) * 2021-12-29 2022-04-29 杰锋汽车动力系统股份有限公司 Automobile power lithium ion battery module structure
CN114421086B (en) * 2021-12-29 2024-06-11 杰锋汽车动力系统股份有限公司 Automobile power lithium ion battery module structure

Also Published As

Publication number Publication date
JP4349037B2 (en) 2009-10-21

Similar Documents

Publication Publication Date Title
JP4349037B2 (en) Assembled battery
JP4308515B2 (en) Battery module
JP5540114B2 (en) Medium or large battery pack with improved cooling efficiency
JP5577459B2 (en) Cooling member having compact structure and excellent stability, and battery module having the same
JP5916500B2 (en) Assembled battery
JP5307250B2 (en) Battery module having cooling means, and (medium or large) battery pack including the same
KR101597403B1 (en) Battery
JP6780018B2 (en) Cooling array for energy storage
KR101112442B1 (en) Battery Module Assembly of Improved Cooling Efficiency
EP2416438B1 (en) Battery module having improved safety
US8852782B2 (en) Battery pack having novel structure
EP2509150B1 (en) Battery module having excellent cooling efficiency and compact structure and middle or large-sized battery pack
JP2004362879A (en) Collective battery
US11296377B2 (en) Cover for an electrochemical cell with enhanced heat conduction
EP3836293A1 (en) Battery module and battery pack including same
JP2014170697A (en) Battery pack
JP2014130780A (en) Battery module and battery unit
JP2009252473A (en) Cooling structure of power storage device and vehicle
JP7098191B2 (en) Battery module
JP2014127402A (en) Battery module
KR102034495B1 (en) Battery Comprising Cooling Member
CN218241977U (en) Heat exchanger and battery package, vehicle that have it
JP7078010B2 (en) Fuel cell unit
KR20230082218A (en) Secondary battery module
KR20140015840A (en) Battery cell for secondary battery

Legal Events

Date Code Title Description
A621 Written request for application examination

Free format text: JAPANESE INTERMEDIATE CODE: A621

Effective date: 20051205

A977 Report on retrieval

Free format text: JAPANESE INTERMEDIATE CODE: A971007

Effective date: 20070621

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20080124

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20080321

A131 Notification of reasons for refusal

Free format text: JAPANESE INTERMEDIATE CODE: A131

Effective date: 20081111

A521 Request for written amendment filed

Free format text: JAPANESE INTERMEDIATE CODE: A523

Effective date: 20090113

TRDD Decision of grant or rejection written
A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

Effective date: 20090630

A01 Written decision to grant a patent or to grant a registration (utility model)

Free format text: JAPANESE INTERMEDIATE CODE: A01

A61 First payment of annual fees (during grant procedure)

Free format text: JAPANESE INTERMEDIATE CODE: A61

Effective date: 20090713

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120731

Year of fee payment: 3

R151 Written notification of patent or utility model registration

Ref document number: 4349037

Country of ref document: JP

Free format text: JAPANESE INTERMEDIATE CODE: R151

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20120731

Year of fee payment: 3

FPAY Renewal fee payment (event date is renewal date of database)

Free format text: PAYMENT UNTIL: 20130731

Year of fee payment: 4

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

R250 Receipt of annual fees

Free format text: JAPANESE INTERMEDIATE CODE: R250

EXPY Cancellation because of completion of term