JP2003226637A - Cleansing sheet - Google Patents

Abstract

<P>PROBLEM TO BE SOLVED: To provide a cleansing sheet having good foamability and cleansing power and neither skin irritancy nor a stretched skin feeling in use, mitigating skin drabness after use, and improving skin gloss and resilience. <P>SOLUTION: This cleansing sheet is obtained by coating or impregnating (d) a microporous sheet with a cleansing preparation comprising (a) ≥40 mass% of a surfactant, (b) at least one component selected from tocopherols, retinol, retinol acetate, retinol palmitate, vitamin A oil, β-carotene, ascorbic acid compounds, etc., and (c) at least one component, i.e., the extract, squeezed oil and distilled oil from material(s) selected from the group consisting of prune, orange, rose hip, adlay, adlay bud, safflower, hop, wheat embryo bud, rice bud, evening primrose, camellia, raspberry, blueberry, wildberry, ginseng, peach fruit, peppermint, soapwort, sage, Jew's-ear, seaweed, and brown sugar (unrefined sugar). This cleansing sheet is used in foaming by adding (hot) water thereto. <P>COPYRIGHT: (C)2003,JPO

Description

Detailed Description of the Invention

[0001]

TECHNICAL FIELD The present invention relates to good initial foaming, excellent detergency, no tension or irritation during use, excellent moist feeling after use, and reduction of dull skin. The present invention relates to a cleaning sheet that enhances skin gloss and elasticity.

[0002]

2. Description of the Related Art Recently, the problems to be solved by the invention
The development of sheet-type cosmetics in which the sheet is impregnated with cosmetics and cleaning agents and which can be used once is active. For example,
A large number of sheet-like pack materials for removing dirt from square plugs using a water-soluble resin have been commercialized. When using such a product, apply an appropriate amount of water to dissolve the resin, stick it on the skin, dry it for a certain period of time, and then peel it off to attach the dirt of the cork plug to the sheet and directly check with the eyes. It is very popular because its effects are obvious from what you can do. Sheet-shaped cosmetics impregnated with moisturizing cosmetics and gelled products using a water-soluble polymer are on the market.

On the other hand, a cleaning sheet such as a makeup remover sheet is easy to use since it can be used only once, is convenient to carry, and is easy to remove makeup without using water. Is accepted by users and the number of users is increasing.

However, the above-mentioned cleaning sheet has problems that sufficient cleaning power cannot be obtained as compared with ordinary cleaning agents, that the skin becomes sticky after use, and that it dries.

Therefore, the object of the present invention is to provide good initial foaming, excellent detergency, no tension and irritation during use, excellent moist feeling after use, and reduction of dullness of skin, It is to provide a cleaning sheet that enhances the gloss and elasticity of the skin.

[0006]

Means for Solving the Problems As a result of intensive studies conducted by the present inventors in view of such a situation, (a) a surfactant of 40 mass% or more, (b) acetic acid-dl-α-tocopherol, Nicotinic acid-dl-α-tocopherol, dl-α
-Tocopherol, dl-σ-tocopherol, retinol, retinol acetate, retinol palmitate, vitamin A oil, β-carotene, ascorbic acid, sodium ascorbate, ascorbic acid glycoside, L-ascorbyl stearate, L-ascorbine Acid sulfate disodium, ascorbyl dipalmitate,
Ascorbyl palmitate, cyanocobalamin, ergocalciferol, cholecalciferol, biotin,
Thiamine hydrochloride, thiamine nitrate, riboflavin, riboflavin butyrate, pyridoxine dicaprylate, pyridoxine dipalmitate, pyridoxine dilaurate, orotic acid, at least one compound selected from the group consisting of menadione, (c) prune, orange, From rosehip, coix, coix germination, safflower, hops, wheat haiga, rice haiga, evening primrose, camellia, raspberry, blueberry, wildberry, raspberry, ginseng, peach fruit, peppermint, saponflower, sage, jellyfish, seaweed, brown sugar At least one of an extract of a substance selected from the group consisting of
(D) a cleaning agent containing at least one of the above, which is applied or impregnated into a sheet base material having pores such as a porous nonwoven fabric, an open-pore foam, or a woven fabric, and water for use. Or, a cleaning sheet that is used by adding hot water and foaming
Good initial foaming, excellent cleaning power, no tension and irritation to the skin when used, excellent moist feeling after use, reduced dullness of skin, gloss and elasticity of skin Therefore, the present invention has been completed by the fact that it can be used anywhere water or hot water can be used.

That is, the first invention is (a) 40% by mass or more of a surfactant, (b) acetic acid-dl-α-tocopherol, nicotinic acid-dl-α-tocopherol, dl.
-Α-tocopherol, dl-σ-tocopherol, retinol, retinol acetate, retinol palmitate,
Vitamin A oil, β-carotene, ascorbic acid, sodium ascorbate, ascorbic acid glycoside, L-ascorbyl stearate, disodium L-ascorbate sulfate, ascorbyl dipalmitate, ascorbyl palmitate, cyanocobalamin, ergo Calciferol, cholecalciferol, biotin, thiamine hydrochloride, thiamine nitrate, riboflavin,
At least one compound selected from the group consisting of riboflavin butyrate, pyridoxine dicaprylate, pyridoxine dipalmitate, pyridoxine dilaurate, orotic acid, and menadione, (c) prunes, oranges, rosehips, pearl barley, pearl barley germination, safflower , Hops, wheat haiga, rice haiga, evening primrose, camellia, raspberry, blueberry, wild berry, raspberry, ginseng, peach fruit, peppermint, saponflower, sage, jellyfish, seaweed, brown sugar extract of substance selected from the group At least one of compressed oil, distilled oil
(D) a porous non-woven fabric, Japanese paper, a porous film, a foam having continuous pores, or a sheet base material having fine pores of a woven fabric, which is coated with or impregnated with a cleaning agent containing at least one species. It is a characteristic cleaning sheet that is used by adding water or hot water and foaming it when using.

The second aspect of the present invention is a detergent containing 30 to 70% by mass of an amphoteric surfactant as a surfactant and / or a higher fatty acid amide propylamine oxide having 8 to 22 carbon atoms. It is in the cleaning sheet above.

The third aspect of the present invention is a cleaning agent further containing 1 to 15% by mass of polyoxyalkylene glyceryl ether (wherein the alkylene has 2 and / or 3 carbon atoms) for cleaning. On the sheet.

In a fourth aspect of the present invention, the cleaning agent is (d) a porous non-woven fabric, a continuous pore foam, Japanese paper, a porous film,
² to 50 g / m ^{2 is} impregnated with respect to the area of a foamed body having continuous pores or a sheet base material having pores of a woven fabric,
Further, the above-mentioned cleaning sheet is characterized in that it is in a dry state with a loss on drying of 2 to 30% by mass.

In a fifth aspect of the present invention, (d) the size of the pores formed on the sheet substrate surface of the porous non-woven fabric, Japanese paper, porous film, foam having continuous pores, or fiber knitted fabric. 0.1 to 9 mm ² and porous non-woven fabric, Japanese paper,
The above-mentioned cleaning sheet is characterized in that the weight of the sheet base material of the porous film, the foam having continuous pores, or the knitted fabric is 20 to 120 g / m ² .

The sixth aspect of the present invention further provides a cleaning agent containing 70
The above-mentioned cleaning sheet is characterized by containing a fragrance having a fragrance retaining property even under a drying condition of ˜125 ° C. for 30 to 250 seconds.

In a seventh aspect of the present invention, the mass of water or hot water added to the cleaning sheet at the time of use is 2 to 20 times the final mass of the cleaning sheet, and the skin is massaged with the foamed cleaning sheet. The method for using the cleaning sheet is characterized by being used while being used.

[0014]

DETAILED DESCRIPTION OF THE INVENTION The details of the configuration of the present invention will be described below.

The surfactant (a) used in the present invention may be any one as long as it has a surfactant effect. It is a surfactant generally used as a general detergent, for example, an anionic surfactant, a cationic surfactant, a nonionic surfactant, an amphoteric surfactant,
One, two or more types of semipolar surfactants can be used. More specifically, fatty acid soap, L-acyl sulfonate, alkyl sulfonate, alkyl allyl sulfonate, alkyl naphthalene sulfonate, alkyl sulfate, alkyl ether sulfate, alkyl amide sulfate,
Anionic surfactants such as alkyl phosphates, alkyl amide phosphates, alkyloyl alkyl taurine salts, N-acyl amino acid salts, sulfosuccinates, perfluoroalkyl phosphates; stearyl trimethyl ammonium chloride, stearyl trimethyl bromide Ammonium,
Cationic surfactants such as alkyltrimethylammonium chloride such as cetostearyltrimethylammonium chloride, distearyldimethylammonium chloride, stearyldimethylbenzylammonium chloride, behenyltrimethylammonium bromide; alkanolamide lauric acid, POE sorbitan fatty acid ester, POE glycerin fatty acid Nonionic surfactants such as ester and POE fatty acid ester, carboxybetaine type, amidobetaine type, sulfobetaine type, hydroxysulfobetaine type,
Amidosulfobetaine type, phosphobetaine type, aminocarboxylic acid salt type, imidazoline derivative type, amidoamine type amphoteric surfactants; lauric acid amidopropyldimethylamine oxide, myristic acid amidopropyldimethylamine oxide, palmitic acid amidopropyldimethylamine Examples thereof include semipolar surface active agents such as oxides, oleic acid amidopropyldimethylamine oxide, stearic acid amidopropyldimethylamine oxide, isostearic acid amidopropyldimethylamine oxide and the like. Further, natural surfactants such as saponin and sugar-based surfactants can also be used. Among them, an amphoteric surfactant and a carbon number of 8 from the viewpoints of foaming, cleanability, feeling of use without sticking feeling, adhesion of detergent to a porous non-woven fabric or knitted fabric, and precipitation of surfactant after drying. -22 higher fatty acid amidopropylamine oxides are preferred. From the viewpoint of foamability and detergency, the total amount of the surfactant is 40% by mass or more, preferably 40 to 80% by mass, as the content in the dry detergent. Preferably, an amphoteric surfactant as a surfactant and / or a higher fatty acid amide propylamine oxide having 8 to 22 carbon atoms is contained in the detergent in an amount of 30 to 70% by mass. As the amount of application to the sheet base material such as the porous non-woven fabric after drying the detergent containing the surfactant, with respect to the area of the sheet base material,
² to 50 g / m ² is preferable, and 7 to 30 is particularly preferable.
It is g / m ² . Further, polyoxyalkylene glyceryl ether (wherein alkylene has 2 and / or 3 carbon atoms,
5 to 50 is preferable as the number of added moles), and it is preferable to add it in the range of 1 to 15% by mass (based on the dry state of the detergent) in the detergent so that the skin feels smooth. Is preferred. Further, as the dry state of the cleaning sheet, it is preferable to dry the cleaning sheet so that the loss on drying of the cleaning sheet is in the range of 2 to 30% by mass. When the product is in a dry state within this range, the product does not become sticky and the fragrance contained in the detergent is less likely to be dispersed.

In the present invention, as the component (b), acetic acid-dl-α-tocopherol, nicotinic acid-dl-α-
Tocopherol, dl-α-tocopherol, dl-σ
-Tocopherol, retinol, retinol acetate, retinol palmitate, vitamin A oil, β-carotene, ascorbic acid, sodium ascorbate, ascorbic acid glycoside, L-ascorbic acid stearic acid ester, L-ascorbic acid sulfuric acid disodium salt, Ascorbyl dipalmitate, Ascorbyl palmitate, Cyanocobalamin, Ergocalciferol, Cholecalciferol, Biotin, Thiamine hydrochloride, Thiamine nitrate, Riboflavin, Riboflavin butyrate,
At least one or more of dicaprylic acid pyridoxine, dipalmitic acid pyridoxine, dilauric acid pyridoxine, orotic acid, menadione, and (c) as components, prunes, oranges, rose hips, adlays, adlays, safflowers, hops, wheat hyga, rice hyga At least one of: Primrose, camellia, camellia, raspberry, blueberry, wildberry, raspberry, ginseng, peach fruit, peppermint, saponum, sage, jellyfish, seaweed, brown sugar, compressed oil, distilled oil
By blending at least one of the above in the detergent, the moist feeling after use and the dullness of the skin can be reduced, and the gloss and elasticity of the skin can be obtained. The extract of the component (c) is, for example, a plant leaf,
Each raw material such as flowers, fruits, stems, rhizomes, and whole plants is extracted with water, an organic solvent, a mixed solution thereof, a dried powder of the extracted solution, or an excipient such as dextrin. In addition, as for orange, rosehip, adlay, safflower, hop, wheat hyga, rice hyga, evening primrose, camellia, etc., pressed oil, distilled oil, or refined oil may be used if necessary. The blending amount of each of these components (b) and (c) is preferably 0.0001 to 10.0 in terms of pure content or dry residue in the dried detergent.
It is% by mass. In order to enhance the effect, (b) component acetic acid-dl-α-tocopherol, nicotinic acid-dl
-Α-tocopherol, dl-α-tocopherol, d
l-σ-tocopherol, retinol, retinol acetate, retinol palmitate, vitamin A oil, β-carotene, ascorbic acid, sodium ascorbate, ascorbic acid glycoside, L-ascorbic acid stearic acid ester, L-ascorbic acid sulfuric acid ester Disodium, ascorbyl dipalmitate, ascorbyl palmitate, cyanocobalamin, ergocalciferol,
Cholecalciferol, biotin, thiamine hydrochloride, thiamine nitrate, riboflavin, riboflavin butyrate, dicaprylic acid pyridoxine, dipalmitic acid pyridoxine, dilauric acid pyridoxine, orotic acid, menadione, at least three kinds, and (c) component is two kinds or more. It is even better to combine.

The sheet substrate having pores (d) used for impregnating the detergent in the present invention includes:
Nonwoven fabric made of natural fibers such as cotton, hemp and wool, cellulosic fibers such as rayon and acetate, synthetic fibers such as polyethylene, polypropylene, polyurethane, polyacryl, polyester, polyvinylidene chloride, polyvinyl chloride and nylon. Examples include Japanese paper, porous films, foams having continuous pores, and knitted or woven fabrics of the above fibers, which may be a single substance or a mixture of two or more thereof. In addition, if necessary, for example, a non-woven fabric, a porous film, a foam sheet, a Japanese paper, a woven fabric, a single layer of cotton and a laminate thereof having water permeability and water insolubility or water decomposability Any known material can be used. These monolayers or laminates may be covered with fibers by flocking, or may have a surface characteristic changed by secondary processing such as uneven embossing. In addition, porous films made of polyethylene, polypropylene, polyurethane, polyacryl, polyester, polyvinylidene chloride, polyvinyl chloride, nylon, polyolefin, etc. and foam sheets of various materials with continuous pores (polyurethane, cellulose, etc.) are also used. it can. Among the above-mentioned sheet base materials, porous non-woven fabrics and knitted fabrics are particularly preferable from the viewpoint of ease of use.

The size of each of the pores formed on the surface of the sheet base material having pores of the above-mentioned porous non-woven fabric, Japanese paper, porous film, foam having continuous pores, or woven fabric is the same as that of the cleaning agent and water. Is a size such that it can pass freely and assists foaming when rubbed with a hand, preferably a size of a hole that allows water in the range of 0.1 to 9 mm ² to pass through, and more preferably It is 0.2 to ⁵ mm ² . The weight of the sheet base material is 2
It is preferably from 0 to 120 g / m ² , and by using such a material, foaming is particularly good at the time of use, the cleaning sheet is easily spread, and the gripping property with a hand is excellent, which is preferable. 50-100g / m for water-insoluble
^2. If it is water-decomposable, 60-80 g / m ² is particularly preferable in terms of usability and cost.

In the cleaning sheet of the present invention, if necessary, other components usually used in cosmetics can be appropriately combined and used. For example, crystalline cellulose, magnesium carbonate, dibasic calcium phosphate, tribasic calcium phosphate, calcium monohydrogen phosphate, magnesium phosphate, sodium metaphosphate, aluminum hydroxide, magnesium hydroxide, calcium pyrophosphate, which are generally used as excipients. , Sodium pyrophosphate, sodium citrate, calcium citrate, citric acid, cis-umbellic acid, kojic acid, sodium hexametaphosphate, sodium carbonate, calcium lactate, calcium lactate, zinc sulfate, red iron oxide, calcium sulfate, titanium oxide, diatomaceous earth, silica Magnesium aluminum silicate, aluminum silicate, kaolin, zinc white; preservatives, pigments, fragrances; substances derived from plants and animals other than the essential components of the present invention, glycyrrhizin and its derivatives, γ-aminobutyric acid, and other agents; Polyhydric alcohols such as ethylene glycol, diethyl glycol, dipropylene glycol, polyethylene glycol, polypropylene glycol, 1,3-butylene glycol, propylene glycol and glycerin; silicic anhydride, hydrous silicic acid, gypsum, calcined gypsum, magnesium carbonate, Exothermic agents such as magnesium sulfate, magnesium chloride, zeolite, hydrotalcite, and synthetic aluminum silicate; hot sensation agents such as capsicum tincture, capsicum extract, ginger tincture, ginger extract, capsaicin, vanillyl alcohol alkyl ether; thickener Cosmetic ingredients standards such as moisturizers, antioxidants, sequestering agents, etc., mixing criteria for different cosmetic types, official standards for food additives, Japanese Pharmacopoeia and cosmetic ingredients, if there are precedents for use, they may be appropriately blended as necessary. . In the present invention, the polyhydric alcohol is 5 to 5 among the above components.
It is preferable to add 50% by mass.

In the cleaning sheet of the present invention, 70 to 125 is used.
By blending a fragrance having a fragrance-retaining property even under a dry condition of 30 to 250 seconds at 30 ° C. into a cleaning agent and applying and impregnating it on a sheet base material, comfort and a mental effect can be obtained at the time of use, and thus the fragrance is blended. Preferably. As the type of fragrance, a fragrance for solid soap, etc., which is less likely to be vaporized when dried and has excellent heat resistance, is selected. 30-250 at 70-125 ° C
Examples of the fragrances that can withstand the dry condition of seconds and have excellent retention and residual odor include various fragrances such as the following woodian bar, sandal note, musk, and floral. These fragrances are appropriately selected from one kind or two or more kinds and are mixed in the detergent as a fragrance.

(Woodian bar) 1- (2-t-butylcyclohexyloxy) -2-butanol (Amber core), 3α, 6,6,9α-tetramethyldodecahydronaphtho [2,1-b] furan (Ambro Xan),
7-Acetyl-1,2,3,4,5,6,7,8-octahydro-1,1,6,7-tetramethylnaphthalene (iso-e-super), 7-cyclohexadecenolide (ambreto Lid), cedryl methyl ether (cedra amber), cedryl methyl ketone (beltfix), 2
-(2,4-Dimethylcyclohex-3-en-1-yl) -5-methyl-5- (1-methylpropyl) -1,
3-dioxane (caranal) and the like. The blending amount in these fragrances is preferably 20 to 50% by mass.

(Sandal Note) Sandalwood oil, α-santalol, β-santalol, 3-methyl-5- (2,2,3-trimethyl-3-cyclopentene-
1-yl) -pentan-2-ol (Sandaloa), 2-
Ethyl- (2,2,3-trimethyl-3-cyclopenten-toyl) -2-buten-1-ol (bacdanol),
3,3 Dimethyl-5- (2,2,3-trimethyl-3-cyclopenten-1-yl) -4-penten-2-ol (polysanthol), 2-methyl-4- (2,2,3-
Trimethyl-3-cyclopenten-1-yl) -2-buten-1-ol (sandal mysole core) and the like. The compounding amount in these fragrances is preferably 1 to 20% by mass.

(Musknote) 3-methylcyclopentadecanone (muscon), 9-cyclopentadecene-1-
On (civetone), cyclopentadecanone, cyclopentadecanolide, 5-cyclohexadecen-1-one (T
MII), ethylene brushlate (Musk T), ethylene dodecanedioate (C14 musk), 5-tert-butyl-1,2,3trimethyl-4,6-dinitrobenzene (musktivetine), 6-acetyl 1,1, A few
3,5 Hexamethylindane (Phantrid), 4-
Acetyl dimethyl-6-t-butyl 11 dimethyl indane (celestrid), 6 acetyl-1,1,2,4,4,
7-hexamethyltetralin (tonalid), hexamethylhexahydro, cyclopentabenzopyran 4,6,6,
7,8,8 (Garac Solid) and the like. The compounding amount in these fragrances is preferably 5 to 30% by mass.

(Floral note) Rose oil, rose absolute, geranium oil, 4- (4-hydroxy-4-methyl-pentyl-3-cyclohexene-1-carboxaldehyde (liral), etc. Combinations in these perfumes. The amount is preferably 20-60% by weight.

The blending amount of the above-mentioned fragrance in the dried detergent is preferably 0.001 to 0.8% by mass.

Further, in the present invention, in order to prevent the surfactant, the plant extract and the fragrance from being deteriorated or discolored during the drying process of the product or the storage of the product, tocopherol acetate, gallic acid or its ester, dibutyl. Hydroxytoluene,
Antioxidants such as sodium bisulfite, ascorbic acid or its derivatives, erythorbic acid or its salts, butylhydroxyanisole; edetic acid and its salts, tartaric acid, citric acid and its salts, sodium polyphosphate, sodium metaphosphate, etc. It is preferable to add 0.001 to 0.5% by mass of the agent to the dry cleaning agent. It is particularly preferable to add an antioxidant.

In the cleaning sheet of the present invention, the weight loss on drying at 105 ° C. for 3 hours is in the range of 2 to 30% by mass,
Suitable for cleanliness during use, ease of handling, and protection from microbial contamination. Then, a sheet such as a non-woven fabric, which is applied or impregnated, and dried if necessary, is preferably filled in a sealed container to prevent the influence of moisture in the outside air. Further, it is preferable to dry under a drying condition such that the loss on drying is 2% by mass or more in view of the scent of the product and the strength of the scent during use. Further, the amount of water and hot water added to the cleaning sheet at the time of use is preferably 2 to 20 times the product weight in order to obtain a sufficiently pleasant scent and foaming. The cleaning sheet of the present invention can be applied to face, hair,
It is used for washing the whole body, and it is particularly preferable to wash the skin while massaging the skin with a foamed washing sheet. As described above, this product has a feature that it is convenient for carrying.

[0028]

EXAMPLES The present invention will be described in detail below based on examples and comparative examples.

Example 1 Comparative Examples 1 to 3 Impregnated with a cleaning agent having the final composition after drying shown in Table 2 below.
The cleaning sheet was prepared. Table 2 for sheet production
Dissolve the components of the composition consisting of 3.5 times the amount of water,
Porous ester, rayon, polypropylene
Non-woven fabric (80g / m², 1.5 mm x 2.0 mm thin
Porosity: Made in Japan Vilene) and impregnated at 85 ° C for 12 minutes
Dry with a dryer, 100 g / m²Loss on drying (105
(° C, 3 hours, the same applies hereinafter) 8.0 mass% product of Example 1
Got Similarly, tocopherol acetate and retino acetate
, Ascorbic acid, cyanocobalamin, ergocar
Ciferol, biotin, thiamine acetate, dicapryl
Acid pyridoxine, orotic acid, menadione is not mixed
Comparative example 2 was dried with a dryer to 100 g / m. ²
Prepare the product so that the loss on drying is 8.0% by mass.
It was Also, as Comparative Example 3, the prune extract was prepared in Comparative Example 2.
Prepared according to Comparative Example 2 without the orange extract
did. These are 16 cm x 16 cm (about 2.5 g: non-woven)
The cloth was cut into 2.0 g and a cleaning agent of 0.5 g).
About 2 using the above products with the cooperation of 20 in-house panelists
Wash face once a week (use while massage), use
Subsequent evaluations will be evaluated by a questionnaire survey, with 5 points for each item.
did. Questionnaire items are good foaming, good fragrance, washing
Purity, lack of tension after use, moisturizing, softening of skin
Improvement of corners, skin gloss, elasticity, comprehensive evaluation (no stimulating feeling
Is evaluated on a scale of 5 points, and the average of the points is shown.
The higher the score, the better the evaluation.
The same applies to inspection. ).

The fragrances used in Examples 1 to 10 and Comparative Examples 1 to 4 and having a fragrance retaining property under dry conditions have the compositions shown in Table 1 below.

[0031] (Table 1) (Fragrance name) (Mass part) -------------------------------------------------- ------------ Linalool 50 Methyl dihydro jasmonate 100 α-hexyl cinnamic aldehyde 80 1- (2-t-butylcyclohexyloxy) -2   -Butanol (Ambercore) 10 3α, 6,6,9α-Tetramethyldodecahydronaphtho   [2,1-b] furan (ambroxane) 10% 10 7-acetyl-1,2,3,4,5,6,7,8-octahydro-   1,1,6,7-tetramethylnaphthalene   (Iso E Super) 130 7-Cyclohexadecenolide (Ambretride) 10 Cedryl methyl ether (Cedra Amber) 20 Cedryl methyl ketone (Beltfix) 60 2- (2,4-dimethylcyclohex-3-en-1-yl)   -5-methyl-5- (1-methylpropyl) -1,3   -Dioxane (caranal) 5 Sandalwood oil 25 α-Santa Roll 5 β-Santa Roll 5 3-methyl-5- (2,2,3-trimethyl-3-   Cyclopenten-1-yl) -pentane-   2-all (Sanda Roa) 5 2-ethyl- (2,2,3-trimethyl-3-cyclopentene-   Toyl) -2-buten-1-ol (Bacdanol) 5 3,3 dimethyl-5- (2,2,3-trimethyl-3-   Cyclopenten-1-yl) -4-pentene-   2-all (Polysanthol) 10 2-methyl-4- (2,2,3-trimethyl-3-   Cyclopenten-1-yl) -2-butene-1   -All (Sandal Mysore Core) 10 3-Methylcyclopentadecanone (Muscon) 10% 5 9-Cyclopentadecen-1-one (Civetone) 10% 5 Cyclopentadecanone 5 Cyclopentadecanolide 10 5-Cyclohexadecen-1-one (TMII) 20 Ethylene brush rate (Musk T) 20 Ethylene dodecanedioate (C14 musk) 5 5-tert-butyl-1,2,3trimethyl-4,6-   Dinitrobenzene (musktivetin) 10 6-Acetyl 1,1,2,3,3,5 hexamethylindane   (Fantrid) 5 4-Acetyldimethyl-6-t-butyl 11 dimethylindane   (Celestrid) 5 6-acetyl-1,1,2,4,4,7-hexamethyltetralin   (Tonnarid) 10 Hexamethylhexahydro, cyclopentabenzopyran 4,6,6,7,8,8 (Garac Solid) 100 Rose oil 10 Rose Absolute 10 Geranium oil 50 4- (4-hydroxy-4-methyl-pentyl-3-   Cyclohexene-1-carboxaldehyde (liral) 80 Benzyl acetate 30 pt-butyl-α-methylhydrocinnamic aldehyde (Liliar) 80 1000 in total

[0032] (Table 2) Raw material ingredients Amount (parts by mass)                                       Example 1 Comparative Example 1 Comparative Example 2 -------------------------------------------------- ----------------- 2-alkyl-N-carboxymethyl-N-hydro   Xyethyl imidazolinium betaine 45.0 20.0 45.0 Coconut oil fatty acid amide propyl betaine 15.0 10.0 15.0 1,3-butylene glycol 10.0 25.0 10.0 Polyethylene glycol 400 10.0 25.0 10.0 Polyethylene glycol 1500 7.0 7.0 7.0 Propylene glycol 4.0 4.0 4.0 Polyoxyethylene     Glyceryl (26EO) 3.0 3.0 3.0 Isopropyl methylphenol 0.02 0.02 0.02 Citric acid 0.3 0.3 0.3 Sodium citrate 0.02 0.02 0.02 Paraben 0.2 0.2 0.2 Acetic acid-dl-α-tocopherol 0.1 0.1- Retinol acetate 0.1 0.1- Ascorbic acid 0.1 0.1- Cyanocobalamin 0.1 0.1- Ergocalciferol 0.05 0.05 − Biotin 0.05 0.05 − Thiamine hydrochloride 0.05 0.05 − Pyridoxine dicaprylate 0.01 0.01- Orotic acid 0.01 0.01- Menadione 0.01 0.01- Prune extract 0.1-0.2 Orange extract 0.1-0.2 Fragrance 0.2 0.2 0.2 Edetate disodium 0.02 0.02 0.02 Water 8.0 8.0 8.0 -------------------------------------------------- ----------------- Total 103.54 103.34 103.16

From the results of the questionnaire in Table 3 below, it is clear that the product of Example 1 of the present invention is superior to Comparative Examples 1 to 3 in all of its various properties. (Table 3) Example 1 Comparative Example 1 Comparative Example 2 Comparative Example 3 ---------------------------------- -------------------------------- Good foaming 4.1 2.4 3.2 3.2 Good scent 3.2 3.0 3.1 3.2 Detergency (makeup removal) 3.5 2.2 3.5 3.5 No stickiness after use 3.6 3.5 2.8 2.9 Moisture 3.8 3.8 3.0 3.0 Reduction of dullness 3.5 3.1 2.7 2.5 Skin gloss 3.9 3.1 3.2 2.8 Elasticity 4.1 2 9.9 2.9 2.7 Overall evaluation 4.0 3.1 2.9 2.8

Example 2 A cleaning sheet impregnated with a cleaning agent having the final composition after drying shown in Table 4 below was prepared. In preparing the sheet, the components having the composition shown in Table 4 were dissolved in 3.5 times the amount of water, and this liquid was made of 60% rayon and 40% pulp having a weight of 80 g / m ² and a nonwoven fabric (1.0 mm × 1.5 mm). No. 3, manufactured by Sansho Paper Industry Co., Ltd.) by spraying, dried at 95 ° C. for 11 minutes in a dryer, and dried at a coating amount of 100 g / m ^{2 to} reduce loss on drying.
0% by mass, which is 16 cm x 16 cm (about 2.5
g: Nonwoven fabric (2.0 g), detergent (0.5 g) was cut to obtain the product of Example 2. With regard to the product, with the cooperation of 20 in-house panelists, the product was continuously used for face washing, and a questionnaire survey was conducted on the evaluation after use (Table 6).

[0035] (Table 4) Raw material ingredients Amount (parts by mass) -------------------------------------------------- -------------- 2-alkyl-N-carboxymethyl-N-   Hydroxyethyl imidazolinium betaine 40.0 Lauroylmethyl-α-alanine   Sodium 15.0 Coconut oil fatty acid diethanolamide 5.0 Polyethylene glycol 200 10.0 Polyethylene glycol 1500 10.0 Propylene glycol 4.0 Polyoxyethylene glyceryl (26EO) 10.0 Isopropyl methylphenol 0.02 Citric acid 0.2 Sodium citrate 0.02 Paraben 0.2 Nicotinic acid-dl-α-tocopherol 0.2 Retinol palmitate 0.0001 Sodium ascorbate 0.3 Cholecalciferol 0.001 Biotin 0.03 Thiamine nitrate 0.005 Riboflavin 0.001 Pyridoxine dipalmitate 0.01 Menadione 0.01 Rosehip extract 0.1 Safflower extract 0.05 Hop extract 0.05 Wheat haiga oil 0.01 Coix extract 0.05 Fragrance 0.4 Edetate disodium 0.02 Water 5.0 -------------------------------------------------- ---------------- Total 100.6771

Examples 3 to 6 Cleaning sheets impregnated with the cleaning agent having the final composition after drying shown in Table 5 below were prepared. In preparing the sheet, the components having the composition shown in Table 5 were dissolved in 3.5 times the amount of water, and this solution was made of 60% rayon and 40% pulp and had a weight of 80 g / m ² and was a nonwoven fabric (1.0 mm × 1.5 mm). No., manufactured by Sansho Paper Industry Co., Ltd.) by spraying, and dried in a dryer at 95 ° C. for 11 minutes to give a coating amount of 100 g / m ² , and these are 1
The product of Examples 3 to 6 was obtained by cutting into 6 cm × 16 cm (about 2.5 g: nonwoven fabric 2.0 g, cleaning agent 0.5 g). With regard to these products, with the cooperation of 20 in-house panelists, they were continuously used for face washing, and a questionnaire survey was conducted on the evaluation after use (Table 6).

[0037] (Table 5)                                             Mixing amount (parts by mass) Raw Material Components Example 3 Example 4 Example 5 Example 6 -------------------------------------------------- ----------------- Lauric acid amidopropylamine   Oxide 50.0 40.0 30.0 20.0 Lauroylmethyl-α-alanine   Sodium 5.0 --- Lauryl dimethylamino acetic acid betaine 5.0-15.0 20.0 β-lauryl aminopropionic acid   Sodium-10.0-5.0 Coconut oil fatty acid diethanolamide 5.0 --- Coconut oil fatty acid methylalanine   Sodium solution − − 5.0 Same as left Polyoxyethylene (5) coconut oil fatty acid   Diethanolamide-5.0 --- Polyoxyethylene lauric acid   Monoethanolamide-5.0 5.0 Same as left Amidopropyl laurate   Betaine-5.0 10.0 Same as on the left Polyethylene glycol 200 10.0 Same as left Same as left Same as left Polyethylene glycol 1500 10.0 Same as left Same as left Same as left Propylene glycol 4.0 Same as left Same as left Same as left Polyoxyethylene   Glyceryl (26EO) 10.0 Same as left Same as left Same as left Isopropylmethylphenol 0.05 Same as left Same as left Same as left Citric acid 0.35 Same as left Same as left Same as left Sodium citrate 0.02 Same as left Same as left Same as left Paraben 0.2 Same as left Same as left Same as left dl-α-tocopherol 0.1 0.1 --- dl-σ-tocopherol --- 0.1 Same as left Vitamin A oil 0.01 0.01 − − β-carotene --- 0.005 Same as the left L-ascorbic acid sulfate   Disodium 0.05 − − − Ascorbyl dipalmitate − − 0.05 − Ascorbyl palmitate − − 0.05 Same as left Riboflavin butyrate 0.001 Same as left Same as left Same as left Pyridoxy dilaurate 0.001 Same as left Same as left Same as left Rice Haiga Oil 0.1 − − − Evening primrose oil − − 0.05 − Camellia oil --- 0.05 Same as left Raspberry extract 0.1-0.1 Blueberry extract-0.1-0.1 Wild Berry Extract --- 0.1- Raspberry extract --- 0.1 Mushroom extract 0.1 0.1 − − Korean ginseng extract-0.1 0.1- Brown sugar extract --- 0.1 Same as left Fragrance 0.3 Same as left Same as left Same as left Disodium edetate 0.02 Same as left Same as left Same as left Water 5.0 Same as left Same as left Same as left -------------------------------------------------- ----------------- Example 3: 105.402, Example 4: 105.452                   Example 5: 105.447, Example 6: 105.647

The results of the questionnaire are shown in Table 6. (Table 6)                       Example 2 Example 3 Example 4 Example 5 Example 6 -------------------------------------------------- ---------------- Good foaming 4.2 4.4 4.4 4.0 3.8 4.5 Detergency (makeup removal) 3.4 3.5 3.2 3.5 3.5 3.2 No stickiness after use 3.3 3.0 3.2 3.7 3.2 Moisture 3.5 3.7 2.9 3.0 3.2 Reduction of dullness 3.6 3.9 4.0 3.3 3.5 Skin gloss 3.6 3.7 3.7 3.3 4.1 Elasticity 3.4 3.2 3.4 3.0 3.0 3.7 Comprehensive evaluation 4.0 4.0 4.0 3.4 3.8 3.7

Example 7, Comparative Example 4 A cleaning sheet having the composition of the dried detergent shown in Table 7 below was prepared. In preparing the sheet, the components having the composition shown in Table 7 were dissolved in 3.5 times the amount of water, and this solution was mixed with rayon 7
Porous non-woven fabric (1.0 mm × 1.5 mm pores, manufactured by Sansho Paper Co., Ltd.) having a weight of 80 g / m ² consisting of 0% and 30% pulp was impregnated and dried in a dryer at 100 ° C. for 11 minutes. It was dried to obtain 100 g / m ² of the product of Example 7. Similarly, as Comparative Example 4, 8% composed of 70% rayon and 30% pulp 8
A similar cleaning agent was applied to a non-woven fabric having a plane type of 0 g / m ² which does not transmit light through the pores and does not allow water to permeate freely, and the weight loss on drying was 7% by mass. The thing was produced. These are cut into 50 cm × 16 cm (about 7.8 g: non-woven fabric 6.3 g, cleaning agent 1.5 g),
With the cooperation of 10 in-house panelists,
It was applied to the whole face, hair, and body, and the evaluation after use was evaluated by a questionnaire survey with 5 points for each item. The results are shown in Table 1.
It shows in 0.

[0040] (Table 7) Raw material ingredients Amount (parts by mass) -------------------------------------------------- -------------- 2-alkyl-N-carboxy   Methyl-N-hydroxyethyl   Imidazolinium betaine 20.0 Lauroylmethyl-α-alanine   Sodium 15.0 Lauryl dimethylaminoacetic acid betaine 10.0 β-laurylaminopropionate sodium 5.0 Lauryl sulfosuccinate disodium 5.0 Lauroyl sarcosine sodium 5.0 Polyethylene glycol 400 10.0 Polyethylene glycol 1500 10.0 Polyethylene glycol 6000 10.0 Propylene glycol 4.0 Polyoxyethylene   Glyceryl (26EO) 10.0 Chlorohexidine gluconate solution 0.02 Citric acid 0.3 Sodium citrate 0.02 Paraben 0.2 Acetic acid-dl-α-tocopherol 0.1 L-ascorbic acid sulfate 0.02   Disodium Vitamin A oil gelatin capsule 0.05 Raspberry extract 0.1 Blueberry extract 0.1 Coix germination extract 0.1 Korean ginseng extract 0.1 Coix extract 0.1 Fragrance 0.3 Edetate disodium 0.02 Water 5.0 -------------------------------------------------- ---------------- 110.53 in total

Example 8 A cleaning sheet having the composition of the dried cleaning agent shown in Table 8 below was prepared. The manufacturing method was carried out according to the above-mentioned Example 7 except that the composition having the composition of the cleaning agent shown in Table 8 was used.
The obtained product was applied to the whole body of the face, hair and body, and the evaluation after use was evaluated by a questionnaire survey with 5 points for each item. The results are shown in Table 10.

[0042] (Table 8) Raw material ingredients Amount (parts by mass) -------------------------------------------------- -------------- Lauric acid amidopropyl betaine 37.5 Disodium lauryl sulfosuccinate 27.2 Coconut oil fatty acid amide propyl betaine 14.6 Polyoxyethylene (5) lauric acid mono   Ethanolamide 10.0 Polyethylene glycol (1500) 5.0 Acetic acid-dl-α-tocopherol 0.1 L-ascorbic acid sulfate disodium 0.1 Peppermint extract 0.1 Peach fruit extract 0.1 Fragrance 0.2 Isopropyl methylphenol 0.02 Water 5.0 -------------------------------------------------- ------------- 99.92 in total

Example 9 A cleaning sheet having the composition of the dried cleaning agent shown in Table 9 below was prepared. The manufacturing method was the same as in Example 7 except that the composition shown in Table 9 was used as the cleaning agent.
The obtained product was applied to the whole body of the face, hair and body, and the evaluation after use was evaluated by a questionnaire survey with 5 points for each item. The results are shown in Table 10.

[0044] (Table 9) Raw material ingredients Amount (parts by mass) -------------------------------------------------- -------------- Lauric acid amidopropyl betaine 18.5 Coconut oil fatty acid amide propyl betaine 11.0 Polyglyceryl monomyristate 15.0 Lauryl dimethylamino acetic acid betaine 6.0 Coconut oil fatty acid methyl taurine sodium 7.5 N-stearoyl-N-methyltaurine sodium 7.5 Acetic acid-dl-α-tocopherol 0.15 Riboflavin 0.015 Polyglyceryl monolaurate 7.5 Polyethylene glycol (6000) 7.5 Polyethylene glycol (1500) 7.5 Polyethylene glycol (400) 7.5 Perfume 0.15 Soap extract 0.3 Sage (salvia) extract 0.3 Sorbitol 4.0 Dipropylene glycol 1.5 Water 8.0 -------------------------------------------------- -------------- Total 109.915

[0045] (Table 10) Evaluation items Example 7 Comparative example 4 Example 8 Example 9 -------------------------------------------------- --------------- Good foaming 4.0 3.4 3.7 3.7 3.6 Detergency (body) 4.2 2.5 4.0 3.2 No stickiness after use 3.6 2.5 3.5 3.5 3.3 Moisture (body) 3.2 2.6 3.4 3.5 Tsuya (body) 3.3 3.1 3.2 3.4 Elasticity (body) 3.8 3.2 3.3 3.7 Comprehensive evaluation 4.1 3.0 3.8 3.9

As is clear from the results shown in Table 10, Examples 7 to 9 are clearly superior to Comparative Example 4 in all respects. It is also an excellent cleaning agent for cleaning hair, face and whole body.

Example 10 A cleaning sheet having the composition of the cleaning composition after drying shown in Table 10 below was prepared. In preparing the sheet, the components having the composition shown in Table 10 were dissolved in 3.0 times the amount of water, and this solution was made of 70% rayon and 30% pulp and had a weight of 80 g / m ² and was a porous nonwoven fabric (1.0 mm × 1 0.5 mm pores, manufactured by Sansho Paper Co., Ltd.) and dried in a dryer at 80 ° C. for 15 minutes to give a weight of 110 g / m ² and a loss on drying of 15.0% by mass.
Got a semi-finished product. Then, a product obtained by dissolving a fragrance in ethanol was sprayed onto the above dried product and a predetermined amount was applied to produce a product of Example 10. 16 cm x 16 cm
The resulting product was continuously applied to face washing with the cooperation of 10 in-house panelists, and the evaluation after use was evaluated by a questionnaire survey, and each item was evaluated by 5 points. The results are shown in Table 11.

[0048] (Table 10) Raw material ingredients Amount (parts by mass) -------------------------------------------------- -------------- Lauric acid amidopropyl dimethylamine oxide 11.2 Lauric acid dimethylaminoacetic acid betaine 10.0 Coconut oil fatty acid amide propyl betaine 4.9 Lauric acid amidopropyl betaine 5.1 Polyglyceryl monolaurate 8.6 Polyoxyethylene sorbitan monolaurate (20EO) 2.9 Polyoxyethylene glyceryl (26EO) 9.8 Polyethylene glycol (400) 9.8 Glycerin 16.3 Disodium edetate 0.2 Citric acid 1.0 Isopropyl methylphenol 1.6 Salicylic acid 0.5 Fragrance 0.6 Acetic acid-dl-α-tocopherol 0.16 Ascorbic acid glucoside 0.2 Seaweed extract (brown algae) 0.2 Sage extract 0.1 Water 15.0 -------------------------------------------------- --------------- 98.16 in total

(Table 11) Evaluation item Example 10 -------------------------------------- Good foaming 4.2 Good fragrance 3.8 Detergency (makeup removal) 3.7 No feeling of tightness after washing 3.5 Moisture 4.0 Smooth feeling 4.0 Reduction of dullness 3.8 Skin gloss 3.8 Comprehensive evaluation 4.0

As is clear from the results shown in Table 11, Example 10 is clearly superior in all aspects.

[0051]

As described above, according to the present invention, the initial foaming is good, the detergency is excellent, there is no tension or irritation during use, the moist feeling is excellent after use, and the dullness of skin is reduced. It is obvious that a cleaning sheet can be provided that enhances the gloss and elasticity of the skin.

   ─────────────────────────────────────────────────── ─── Continued front page    F-term (reference) 4C083 AA111 AA112 AC122 AC181                       AC302 AC422 AC472 AC482                       AC532 AC561 AC641 AC662                       AC692 AC712 AC852 AC861                       AC862 AD042 AD221 AD222                       AD621 AD622 AD631 AD641                       AD642 AD651 AD652 AD661                       AD662 AD671 AD672 BB01                       BB41 BB60 CC23 DD12 EE06                       EE07

Claims (7)

[Claims] 1. (a) 40% by mass or more of a surfactant,
(B) Acetic acid-dl-α-tocopherol, nicotinic acid-
dl-α-tocopherol, dl-α-tocopherol, dl-σ-tocopherol, retinol, retinol acetate, retinol palmitate, vitamin A oil, β-
Carotene, ascorbic acid, sodium ascorbate, ascorbic acid glycoside, L-ascorbyl stearate, L-ascorbyl sulfate disodium salt, ascorbyl dipalmitate, ascorbyl palmitate, cyanocobalamin, ergocalciferol, cholecalciferol , Biotin, thiamine hydrochloride, thiamine nitrate, riboflavin, riboflavin butyrate, dicaprylic acid pyridoxine, dipalmitic acid pyridoxine, dilauric acid pyridoxine, orotic acid, menadione, at least one compound selected from the group consisting of (c) prune , Orange, rosehip, pearl barley, pearl barley germination, safflower, hops, wheat haiga, rice haiga, evening primrose, camellia, raspberry, blueberry, wild A cleaning agent containing at least one of an extract of a substance selected from the group consisting of lee, raspberry, ginseng, peach fruit, peppermint, soapless, sage, jellyfish, seaweed, brown sugar, compressed oil, and distilled oil. (D) is applied to or impregnated into a porous non-woven fabric, Japanese paper, a porous film, a foam sheet having continuous pores, or a sheet base material having pores of a woven fabric, and water when used. Or a cleaning sheet that is used by adding hot water and foaming. 2. A detergent comprising (a) an amphoteric surfactant as a surfactant and / or a higher fatty acid amide propylamine oxide having 8 to 22 carbon atoms in an amount of 30 to 70% by mass. The cleaning sheet according to 1. 3. The cleaning agent according to claim 1, which is a cleaning agent containing 1 to 15% by mass of polyoxyalkylene glyceryl ether (wherein the alkylene has 2 and / or 3 carbon atoms). Sheet. 4. The cleaning material according to any one of claims 1 to 3, wherein (d) a porous non-woven fabric, Japanese paper, a porous film, a foam having continuous pores, or a sheet having fine pores of a woven fabric. The cleaning sheet according to any one of claims 1 to 3, which is impregnated in an amount of ² to 50 g / m ^{2 with} respect to an area of the base material and is in a dry state with a loss on drying of 2 to 30% by mass. . 5. (d) Porous non-woven fabric, Japanese paper, porous fibrous
Sheets of rum, foam with open pores, or woven fabric
The size of each pore formed on the substrate surface is 0.1 to 9 mm²
And porous non-woven fabric, Japanese paper, porous film, continuous
Foam with open pores, or mesh with woven fabric pores
The mass of the base material is 20 to 120 g / m ²Specially
The cleaning sea according to any one of claims 1 to 4,
To. 6. The cleaning agent further contains 3 at 70 to 125 ° C.
The cleaning sheet according to any one of claims 1 to 5, further comprising a fragrance having a fragrance retaining property even under a dry condition of 0 to 250 seconds. 7. The mass of water or hot water added to the cleaning sheet at the time of use is 2 to 20 times the final mass of the cleaning sheet, and is used while massaging the skin with the foamed cleaning sheet. The method of using the cleaning sheet according to any one of claims 1 to 6, characterized in that: