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JP2002234066A - Method for manufacturing resin tube having three-layer structure - Google Patents

Method for manufacturing resin tube having three-layer structure

Info

Publication number
JP2002234066A
JP2002234066A JP2001034068A JP2001034068A JP2002234066A JP 2002234066 A JP2002234066 A JP 2002234066A JP 2001034068 A JP2001034068 A JP 2001034068A JP 2001034068 A JP2001034068 A JP 2001034068A JP 2002234066 A JP2002234066 A JP 2002234066A
Authority
JP
Japan
Prior art keywords
tube
resin
forming
thermoplastic resin
layer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
JP2001034068A
Other languages
Japanese (ja)
Inventor
Hiroyoshi Sen
裕喜 撰
Hideshi Matsumoto
英志 松本
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sekisui Chemical Co Ltd
Original Assignee
Sekisui Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sekisui Chemical Co Ltd filed Critical Sekisui Chemical Co Ltd
Priority to JP2001034068A priority Critical patent/JP2002234066A/en
Publication of JP2002234066A publication Critical patent/JP2002234066A/en
Pending legal-status Critical Current

Links

Classifications

    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/30Extrusion nozzles or dies
    • B29C48/32Extrusion nozzles or dies with annular openings, e.g. for forming tubular articles
    • B29C48/335Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles
    • B29C48/336Multiple annular extrusion nozzles in coaxial arrangement, e.g. for making multi-layered tubular articles the components merging one by one down streams in the die
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/09Articles with cross-sections having partially or fully enclosed cavities, e.g. pipes or channels
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/16Articles comprising two or more components, e.g. co-extruded layers
    • B29C48/18Articles comprising two or more components, e.g. co-extruded layers the components being layers
    • B29C48/21Articles comprising two or more components, e.g. co-extruded layers the components being layers the layers being joined at their surfaces

Landscapes

  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Extrusion Moulding Of Plastics Or The Like (AREA)
  • Molding Of Porous Articles (AREA)

Abstract

PROBLEM TO BE SOLVED: To manufacture a resin tube having an inner layer and an outer layer formed of a non-foamed foam thermoplastic resin composition and an intermediate layer formed of a foamed thermoplastic resin composition so that a thickness of the tube at its product finishing time always becomes uniform. SOLUTION: A method for manufacturing the resin tube having a three-layer structure comprises the step of forming the resin tube by setting an adding amount of a foaming agent to be added to a thermoplastic resin for forming the intermediate layer to that of a theoretically adding amount for obtaining an expansion ratio of a predetermined product dimension when the tube is formed without specifying a radial spread of the tube and sizing in a predetermined finishing dimension against a foaming pressure by using a tube outer surface forming tube and a tube inner surface forming core.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、内層および外層と
なる非発泡熱可塑性樹脂組成物との間に中間層となる発
泡熱可塑性樹脂組成物を介在された状態の三層構造の未
固化管状体を金型から共押出し、共押出された未固化管
状体中の発泡熱可塑性樹脂組成物を発泡させるととも
に、熱可塑性樹脂を冷却固化する三層構造の樹脂管の製
造方法に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an unsolidified tubular three-layer structure in which a foamed thermoplastic resin composition serving as an intermediate layer is interposed between a non-foamed thermoplastic resin composition serving as an inner layer and an outer layer. The present invention relates to a method for producing a three-layer resin tube for coextruding a body from a mold, foaming a foamed thermoplastic resin composition in a co-extruded unsolidified tubular body, and cooling and solidifying the thermoplastic resin.

【0002】[0002]

【従来の技術】合成樹脂で形成される樹脂管は、剛性と
耐衝撃破壊強度を保ちながら軽量であることが望まれて
おり、その目的を達成するため、管壁を波形にする方法
やリブを設けた管や硬質の発泡性熱可塑性樹脂を使用し
た管など様々な方法が提案されている。特に内層および
外層が非発泡熱可塑性樹脂組成物で形成され、中間層が
発泡熱可塑性樹脂組成物で形成される樹脂管が、剛性と
耐衝撃破壊強度を保ちながら軽量化が図れる樹脂管とし
て注目されている。この三層構造の樹脂管を製造する製
造装置として、例えば特公平7−51308号公報に記
載されているものがある。
2. Description of the Related Art It is desired that a resin tube made of a synthetic resin be lightweight while maintaining rigidity and impact resistance to fracture. Various methods have been proposed, such as a tube provided with a resin and a tube using a hard foamable thermoplastic resin. In particular, a resin tube in which the inner layer and the outer layer are formed of a non-foamed thermoplastic resin composition and the intermediate layer is formed of a foamed thermoplastic resin composition has attracted attention as a resin tube capable of achieving weight reduction while maintaining rigidity and impact fracture strength. Have been. As a manufacturing apparatus for manufacturing this three-layer resin tube, there is, for example, one described in Japanese Patent Publication No. 7-51308.

【0003】特公平7−51308号公報に記載の製造
装置では、内層、外層、さらに中間層を形成するため
に、内径及び外径の異なる複数の筒状金型部材をコート
ハンガー状態に重ね合わせて組み付けることにより、ス
パイダーの無い金型を提案している。この装置を用いて
樹脂管を製造することにより、樹脂管の表面の外観を良
好にでき、かつ、金型から吐出されるときの管の肉厚も
ほぼ均一なものとすることができる。
In the manufacturing apparatus described in Japanese Patent Publication No. 7-51308, in order to form an inner layer, an outer layer, and an intermediate layer, a plurality of cylindrical mold members having different inner and outer diameters are superimposed on a coat hanger. By assembling it, we propose a mold without a spider. By manufacturing a resin tube using this apparatus, the appearance of the surface of the resin tube can be improved, and the thickness of the tube when discharged from the mold can be made substantially uniform.

【0004】[0004]

【発明が解決しようとする課題】しかしながら外層およ
び内層を形成する熱可塑性樹脂組成物や、中間層を形成
する発泡性の熱可塑性樹脂組成物の組成または配合比率
を変更した場合や、仕上がり外径寸法の異なる製品を得
るため押出条件を変更したりした場合などに、樹脂粘度
が変化する場合がある。このように樹脂粘度が変化する
と、金型からの樹脂の吐出量に変動が生じることとな
り、吐出流速分布が大きくなって均一肉厚の成形品を得
ることが困難となる。特に中間層の発泡樹脂に回収樹脂
(廃棄された樹脂製品から回収したリサイクル樹脂)を
用いる際は、樹脂粘度の変化に追従できなくなる場合が
多く、発泡樹脂層の肉厚の変動が大きくなることが多
い。
However, when the composition or the mixing ratio of the thermoplastic resin composition for forming the outer layer and the inner layer and the foamable thermoplastic resin composition for forming the intermediate layer are changed, or when the finished outer diameter is changed. The resin viscosity may change when the extrusion conditions are changed in order to obtain products having different dimensions. If the resin viscosity changes in this way, the amount of resin discharged from the mold will fluctuate, and the discharge flow velocity distribution will increase, making it difficult to obtain a molded product having a uniform thickness. In particular, when using recovered resin (recycled resin recovered from discarded resin products) as the foamed resin in the intermediate layer, it often becomes impossible to follow the change in resin viscosity, and the thickness of the foamed resin layer varies greatly. There are many.

【0005】また、発泡剤として化学発泡剤を使用する
場合には、使用する樹脂や添加剤の種類、添加量等の諸
条件を変更することによってガス発生量が変化すること
となって、発泡倍率分布が大きくなり金型吐出後に均一
肉厚製品を得ることが困難となる問題もある。
When a chemical foaming agent is used as a foaming agent, the amount of gas generated varies by changing various conditions such as the type and amount of the resin used and the additive. There is also a problem that the magnification distribution becomes large and it becomes difficult to obtain a uniform thick product after discharging the mold.

【0006】本発明は、上記した従来の三層構造の樹脂
管の製造方法における問題点に鑑み、非発泡の発泡熱可
塑性樹脂組成物で形成される内層および外層と、発泡熱
可塑性樹脂組成物で形成される中間層とで構成される樹
脂管の製品仕上がり時での肉厚が常に均一となるように
樹脂管を製造することができる三層構造の樹脂管の製造
方法を提供することを目的とする。
The present invention has been made in view of the above-mentioned problems in the conventional method of manufacturing a three-layer resin tube, and has been made in consideration of the problems described above. To provide a method of manufacturing a resin pipe having a three-layer structure capable of manufacturing a resin pipe so that the thickness of the resin pipe formed by the intermediate layer formed at the time of finished product is always uniform. Aim.

【0007】[0007]

【課題を解決するための手段】上記目的を達成するた
め、請求項1に記載の発明は、内層および外層となる非
発泡熱可塑性樹脂組成物との間に中間層となる発泡熱可
塑性樹脂組成物を介在させた状態の三層構造の未固化管
状体を金型から共押出し、共押出された未固化管状体中
の発泡熱可塑性樹脂組成物を発泡させるとともに、熱可
塑性樹脂を冷却固化する三層構造の樹脂管の製造方法に
おいて、中間層を形成する熱可塑性樹脂に添加する発泡
剤の添加量を、樹脂管の径方向への広がりを規制せずに
成形した場合における所定製品寸法の発泡倍率を得るた
めの理論添加量以上の添加量とするとともに、管外面成
形用チューブと管内面成形用コアを用いて発泡圧に抗し
て所定の仕上がり寸法にサイジングを行って樹脂管を形
成するようにした。
In order to achieve the above object, the invention according to claim 1 is directed to a foamed thermoplastic resin composition which forms an intermediate layer between a non-foamed thermoplastic resin composition which forms an inner layer and an outer layer. The co-extruded unsolidified tubular body having a three-layer structure with a material interposed therebetween is extruded from a mold, and the foamed thermoplastic resin composition in the co-extruded unsolidified tubular body is foamed, and the thermoplastic resin is cooled and solidified. In the method of manufacturing a three-layer resin tube, the amount of the foaming agent to be added to the thermoplastic resin forming the intermediate layer is adjusted to a predetermined product size when the resin tube is molded without restricting the radial expansion of the resin tube. A resin tube is formed by sizing to a predetermined finished size against the foaming pressure using a tube for forming the outer surface of the tube and a core for forming the inner surface of the tube, in addition to the theoretical amount for obtaining the expansion ratio. I did it.

【0008】本発明の製造方法によれば、発泡熱可塑性
樹脂層が発泡により径方向内外方に向けて広がろうとし
ても、管外面成形用チューブと管内面成形用コアによ
り、発泡熱可塑性樹脂層が膨らもうとするのが抑制され
るとともに発泡熱可塑性樹脂層が加圧された状態になっ
て、仕上がり寸法通りの一定肉厚が得られる。また、廃
棄樹脂製品から回収された回収樹脂を使用する場合に粘
度変化を起こして、金型からの吐出量に変動が生じて
も、樹脂管を管外面成形用チューブと管内面成形用コア
により圧縮状態でサイジングを行って表面を平滑にでき
るので、粘度変化に対応させた流路調整を行う必要がな
くなる。なお、サイジングを行う際の冷却固化する方法
としては、水冷などの強制冷却方法や自然放置による自
然冷却などがある。
According to the production method of the present invention, even if the foamed thermoplastic resin layer tries to expand radially inward and outward by foaming, the foamed thermoplastic resin is formed by the tube for forming the tube outer surface and the core for forming the tube inner surface. Attempts to expand the layer are suppressed, and the foamed thermoplastic resin layer is in a pressurized state, so that a constant thickness according to the finished dimensions is obtained. In addition, when using the recovered resin recovered from waste resin products, viscosity changes occur, and even if the discharge amount from the mold fluctuates, the resin tube is formed by the tube for forming the outer surface of the tube and the core for forming the inner surface of the tube. Since the surface can be smoothed by sizing in a compressed state, it is not necessary to adjust the flow path in accordance with the change in viscosity. In addition, as a method of cooling and solidifying at the time of performing sizing, there are a forced cooling method such as water cooling and a natural cooling by natural leaving.

【0009】本発明の製造方法で用いられる熱可塑性樹
脂としては、塩化ビニル、ポリスチレン、ポリプロピレ
ン、ポリブテン、塩素化ポリエチレン、エチレン−プロ
ピレン共重合体、エチレン−エチルアクリレート共重合
体、ポリエチレンテレフタレート、ABS樹脂、アクリ
ル樹脂などの押出可能な熱可塑性樹脂があげられ、これ
らは単独で用いても良く、二種以上を併用しても良い。
As the thermoplastic resin used in the production method of the present invention, vinyl chloride, polystyrene, polypropylene, polybutene, chlorinated polyethylene, ethylene-propylene copolymer, ethylene-ethyl acrylate copolymer, polyethylene terephthalate, ABS resin And extrudable thermoplastic resins such as acrylic resins. These may be used alone or in combination of two or more.

【0010】本発明において用いられる発泡剤として
は、上記熱可塑性樹脂を劣化させないものならば特に限
定されず、たとえばアゾジカルボンアミド、ベンゼンス
ルホニルヒドラジド、トルエンスルホニルヒドラジド等
の熱分解型発泡剤やジクロロテトラフルオロエタン、モ
ノクロロジフロロエタン、ブタン、ペンタン、炭酸ガ
ス、窒素、空気、アルゴン等の物理型発泡剤があげられ
る。これらは単独で使用しても良いし、2種類以上併用
しても良い。
The blowing agent used in the present invention is not particularly limited as long as it does not deteriorate the above-mentioned thermoplastic resin. For example, pyrolytic blowing agents such as azodicarbonamide, benzenesulfonylhydrazide and toluenesulfonylhydrazide, and dichlorotetrafluoroethylene Physical foaming agents such as fluoroethane, monochlorodifluoroethane, butane, pentane, carbon dioxide, nitrogen, air, and argon. These may be used alone or in combination of two or more.

【0011】発泡剤の添加量は、通常用いられる量を逸
脱するものではないが、樹脂管の径方向への広がりを規
制せずに成形した場合における所定製品寸法の発泡倍率
を得るための理論添加量以上の添加量を添加する必要が
ある。但し多く入れすぎるとコスト上の問題もあり、理
論添加量の1.5〜3倍程度が好ましい。
The addition amount of the foaming agent does not deviate from the amount usually used, but it is a theoretical value for obtaining a foaming ratio of a predetermined product size when the resin tube is molded without restricting the radial expansion of the resin tube. It is necessary to add more than the addition amount. However, if too much is added, there is a problem in cost, and it is preferable that the amount is 1.5 to 3 times the theoretical addition amount.

【0012】本発明の樹脂組成物中には、必要に応じて
安定剤、抗酸化剤、加工助剤、滑剤、発泡助剤、充填
剤、顔料、難燃剤等を添加することができる。
[0012] In the resin composition of the present invention, a stabilizer, an antioxidant, a processing aid, a lubricant, a foaming aid, a filler, a pigment, a flame retardant and the like can be added as required.

【0013】請求項2に記載の発明は、請求項1に記載
の三層構造の樹脂管の製造方法において、中間層に用い
られる熱可塑性樹脂を回収樹脂とした。回収樹脂とは、
廃棄された樹脂製品を回収し、樹脂部分を粉砕したもの
や、工場内での成形品の端材や、成形スタート時、スト
ップ時、あるいはトラブル時に発生するスクラップを粉
砕したものなど再生利用する樹脂のことをいう。
According to a second aspect of the present invention, in the method for manufacturing a three-layer resin tube according to the first aspect, the thermoplastic resin used for the intermediate layer is a recovered resin. What is recovered resin?
Resin that collects discarded resin products and crushes the resin part, scraps of molded products in factories, and crushed scrap generated at the start, stop, or trouble of molding, etc. Means

【0014】請求項3に記載の発明は、請求項1または
請求項2に記載の三層構造の樹脂管の製造方法におい
て、熱可塑性樹脂を塩化ビニル系樹脂とした。塩化ビニ
ル系樹脂は、熱分解型発泡剤を使用する際に安定剤など
の種類によってガス発生量が変化し発泡倍率の変動が発
生するといった問題や、滑剤の添加量の変化による粘度
変化による押出変動や吐出分布を発生させるという不具
合が生じやすいが本発明の製造方法によれば、そのよう
な問題が生じても仕上がり寸法の安定した樹脂管が得ら
れる。
According to a third aspect of the present invention, in the method for producing a three-layered resin tube according to the first or second aspect, the thermoplastic resin is a vinyl chloride resin. In the case of vinyl chloride resin, when using a pyrolysis type foaming agent, the amount of gas generated varies depending on the type of stabilizer and the like, and the foaming ratio fluctuates. Although problems such as fluctuation and discharge distribution are likely to occur, according to the manufacturing method of the present invention, a resin tube having stable finished dimensions can be obtained even if such a problem occurs.

【0015】なお、本発明の製造方法を実施するための
製造装置としては、中間層が発泡熱可塑性樹脂層よりな
る三層構造を有する樹脂管を共押出する金型と外層冷却
用の管外面成形用チューブを備えるとともに、金型に設
けるマンドレルから一部を管外面成形用チューブに向け
て突出させて内部コア(管内面成形用コア)とし、この
内部コアの少なくとも一部を管外面成形用チューブ内に
設けるようにすることにより構成できる。
The production apparatus for carrying out the production method of the present invention includes a mold for co-extruding a resin tube having a three-layer structure in which an intermediate layer is formed of a foamed thermoplastic resin layer, and a tube outer surface for cooling the outer layer. A molding tube is provided, and a part of the mandrel provided in the mold is projected toward the tube for forming the outer surface of the tube to form an inner core (core for forming the inner surface of the tube), and at least a part of the inner core is formed for forming the outer surface of the tube. It can be configured by providing it in a tube.

【0016】[0016]

【発明の実施の形態】本発明の三層構造の樹脂管の製造
方法について図面に基づいて説明する。図1及び図2
は、本発明の三層構造の樹脂管を製造するための製造装
置の全体構成図であって、非発泡性熱可塑性樹脂組成物
21が溶融混練される内外層押出機11と、発泡性熱可
塑性樹脂組成物22が溶融混練される中間層押出機12
と、内外層押出機11の非発泡性熱可塑性樹脂組成物2
1と中間層押出機12の発泡性熱可塑性樹脂組成物22
が注入される金型3と、三層構造の樹脂管2の外面を成
形するための管外面成形用チューブ5が取り付けられた
冷却水槽4と、冷却水槽4から送られてきた樹脂管2を
受け取る引き取り機6と、引き取り機6から送られてき
た樹脂管2を所定の長さに切断する切断機7とから構成
されている。
DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS A method for manufacturing a three-layer resin tube according to the present invention will be described with reference to the drawings. 1 and 2
FIG. 1 is an overall configuration diagram of a manufacturing apparatus for manufacturing a three-layer resin tube of the present invention, wherein an inner / outer layer extruder 11 in which a non-foamable thermoplastic resin composition 21 is melt-kneaded; Intermediate layer extruder 12 in which plastic resin composition 22 is melt-kneaded
And the non-foamable thermoplastic resin composition 2 of the inner and outer layer extruder 11
1 and foamable thermoplastic resin composition 22 of intermediate layer extruder 12
A cooling water tank 4 to which a tube 5 for forming the outer surface of the resin tube 2 for forming the outer surface of the resin tube 2 having a three-layer structure, and a resin tube 2 sent from the cooling water tank 4 are formed. It comprises a receiving machine 6 for receiving and a cutting machine 7 for cutting the resin tube 2 sent from the machine 6 into a predetermined length.

【0017】また、図3に示すように、金型3における
マンドレル31の先端には、管外面成形用チューブ5に
向けて突出される支持棒32が設けられており、この支
持棒32の突出側端部に、管外面成形用チューブ5の内
径より小径で、三層構造の樹脂管2の内面を成形するた
めの管内面成形用コア8が設けられている。この管内面
成形用コア8は、少なくとも一部を管外面成形用チュー
ブ5内に位置させるように配設されている。
As shown in FIG. 3, a support rod 32 projecting toward the tube forming tube outer surface 5 is provided at the tip of the mandrel 31 in the mold 3. At the side end, a tube inner surface forming core 8 for forming the inner surface of the resin tube 2 having a smaller diameter than the inner diameter of the tube outer surface forming tube 5 and having a three-layer structure is provided. The tube inner surface forming core 8 is disposed so that at least a part thereof is located in the tube outer surface forming tube 5.

【0018】まず、図1および図2に示すように内外層
押出機11により溶融混練された非発泡性熱可塑性樹脂
組成物21と中間層押出機12により溶融混練された発
泡性熱可塑性樹脂組成物22が、金型3に注入され金型
3内部で合流される。そして三層構造の未固化管状体が
金型3より吐出されると発泡し、そのまま管外面成形用
チューブ5と管内面成形用コア8との間に挿入され、発
泡圧に抗して所定寸法に型成形されながら、冷却水槽4
内で樹脂管2が冷却される。さらに、冷却された樹脂管
2は引き取り機6に引き渡されて切断機7に送られ、切
断機7において所定の長さに切断される。
First, as shown in FIGS. 1 and 2, a non-foamable thermoplastic resin composition 21 melt-kneaded by an inner and outer layer extruder 11 and a foamable thermoplastic resin composition melt-kneaded by an intermediate layer extruder 12 The object 22 is injected into the mold 3 and merges inside the mold 3. When the unsolidified tubular body having the three-layer structure is discharged from the mold 3, it foams and is inserted as it is between the tube 5 for forming the outer surface of the tube and the core 8 for forming the inner surface of the tube. Cooling water tank 4
The resin tube 2 is cooled inside. Further, the cooled resin pipe 2 is delivered to a take-off machine 6 and sent to a cutting machine 7, where it is cut into a predetermined length.

【0019】本実施の形態では、図3に示すように、金
型3の樹脂出口と管外面成形用チューブ5の入口との間
に所定の間隔を設ける構造としたが、金型3の樹脂出口
と管外面成形用チューブ5の入口を接触させるようにし
てもよい。図3に示すように間隔を設ける場合は、樹脂
詰まりを起こさず安定して成形することができ、その間
隔は、50mmから100mmとするのが好ましい。
In this embodiment, as shown in FIG. 3, a predetermined space is provided between the resin outlet of the mold 3 and the inlet of the tube 5 for forming the tube outer surface. The outlet and the inlet of the tube outer surface forming tube 5 may be brought into contact with each other. When an interval is provided as shown in FIG. 3, molding can be performed stably without causing resin clogging, and the interval is preferably set to 50 mm to 100 mm.

【0020】また、本実施の形態の製造装置は、図3お
よび図4に示すように、管内面成形用コア8が一つ設け
られており、さらに、管内面成形用コア8の形状は、図
3または図4に示すように、未固化の樹脂管2の送りを
円滑にするために押出機側にテーパー面を形成するか、
もしくは曲面に形成することが好ましい。また、外面成
形用チューブ5の入口側も、未固化の樹脂管2の送りを
円滑に行うべく、テーパー面が形成されている。
Further, as shown in FIGS. 3 and 4, the manufacturing apparatus of this embodiment is provided with one core 8 for forming the inner surface of the tube, and the shape of the core 8 for forming the inner surface of the tube is as follows. As shown in FIG. 3 or FIG. 4, a taper surface is formed on the side of the extruder in order to smoothly feed the unsolidified resin tube 2 or
Alternatively, it is preferably formed on a curved surface. In addition, the inlet side of the outer surface forming tube 5 is also formed with a tapered surface in order to smoothly feed the unsolidified resin tube 2.

【0021】さらに、本実施の形態では、管内面成形用
コア8を冷却するために、管内面成形用コア8内に冷却
媒体を送るようにしている。具体的には、図3および図
4に示すように、金型3内に、支持棒32内部に形成す
る冷却媒体送り通路33に連通させる冷却媒体流入通路
34が形成されており、また、支持棒32内部には、図
4に示すように、前記した冷却媒体送り通路33と平行
して延びる冷却媒体戻り通路35が形成されている。
Further, in this embodiment, in order to cool the core 8 for forming the inner surface of the tube, a cooling medium is sent into the core 8 for forming the inner surface of the tube. Specifically, as shown in FIGS. 3 and 4, a cooling medium inflow passage 34 communicating with a cooling medium sending passage 33 formed inside the support rod 32 is formed in the mold 3. As shown in FIG. 4, a cooling medium return passage 35 extending parallel to the cooling medium feed passage 33 is formed inside the rod 32.

【0022】そして、管内面成形用コア8の内部には、
図3および図4に示すように、冷却媒体送り通路33と
冷却媒体戻り通路35とに連通する中心から径方向外方
に向けて延びる冷却用通路81が複数本形成されてい
る。なお、図示していないが、金型3には冷却媒体流入
通路34と平行して形成される冷却後の冷却媒体が回収
される冷却媒体回収通路が形成されている。
Then, inside the core 8 for forming the inner surface of the tube,
As shown in FIGS. 3 and 4, a plurality of cooling passages 81 extending radially outward from the center communicating with the cooling medium feed passage 33 and the cooling medium return passage 35 are formed. Although not shown, the mold 3 is provided with a cooling medium recovery passage formed in parallel with the cooling medium inflow passage 34 for collecting the cooled cooling medium.

【0023】図4に示す管内面成形用コア8では、金型
3の冷却媒体流入通路34から支持棒32の冷却媒体送
り通路33に送られた冷却媒体は、管内面成形用コア8
内の冷却用通路81に送られ、管内面成形用コア8が冷
却される。そして、冷却後の冷却媒体は、支持棒32の
冷却媒体戻り通路35に送られ、金型3に設ける冷却媒
体回収通路へと回収される。
In the tube inner surface forming core 8 shown in FIG. 4, the cooling medium sent from the cooling medium inflow passage 34 of the mold 3 to the cooling medium feed passage 33 of the support rod 32 is supplied to the tube inner surface forming core 8.
It is sent to the cooling passage 81 in the inside, and the pipe inner surface forming core 8 is cooled. Then, the cooled cooling medium is sent to the cooling medium return passage 35 of the support rod 32 and collected in the cooling medium collection passage provided in the mold 3.

【0024】冷却媒体としては、空気、水、油、ポリエ
チレングリコール等の金型3を腐食させず、通路内を流
動し熱交換の良いものを用いる。なかでも冷媒洗浄や回
収の必要のない空気や水が好ましい。
As the cooling medium, a material such as air, water, oil, polyethylene glycol or the like which does not corrode the mold 3 and flows in the passage and has good heat exchange is used. Of these, air and water that do not require cleaning and recovery of the refrigerant are preferred.

【0025】また、管内面成形用コア8内に形成する冷
却用通路81は、図5に示すようにその一端をコア表面
に開口させて噴出口82を形成し、この噴出口82から
冷却媒体を管外面成形用チューブ5内部に噴出させるよ
うにしても良い。
As shown in FIG. 5, one end of the cooling passage 81 formed in the core 8 for forming the inner surface of the pipe is opened to the surface of the core to form a jet port 82. May be ejected into the tube 5 for forming the outer surface of the tube.

【0026】図4および図5に示す実施形態では、管内
面成形用コア8を1つ設けるようにしたが、図6及び図
7に示す他の実施形態のように支持棒32上に断続的に
複数枚(図6及び図7においては3枚)設置させるよう
にしてもよい。
In the embodiment shown in FIGS. 4 and 5, one core 8 for forming the inner surface of the tube is provided. However, as in the other embodiments shown in FIGS. May be set to a plurality (three in FIGS. 6 and 7).

【0027】図6および図7に示す管内面成形用コア8
とする場合は、金型3内に、支持棒32内部に形成する
冷却媒体送り通路33に連通させる冷却媒体流入通路3
4のみを形成し、支持棒32内部にも、冷却媒体送り通
路33のみを形成し、各々隣り合った管内面成形用コア
8の間に露出されている支持棒32外面に冷却媒体送り
通路33に連通する吐出口36を形成している。これら
吐出口36から冷却媒体が製品に向かって噴出される。
この場合、管内面成形用コア8には冷却用通路は形成し
ない。
The core 8 for forming a pipe inner surface shown in FIGS.
In this case, the cooling medium inflow passage 3 communicated with the cooling medium feed passage 33 formed inside the support rod 32 in the mold 3.
4, only the cooling medium feed passage 33 is formed inside the support rod 32, and the cooling medium feed passage 33 is formed on the outer surface of the support rod 32 exposed between the adjacent pipe inner surface forming cores 8 respectively. Is formed with a discharge port 36 that communicates with the nozzle. The cooling medium is ejected from these discharge ports 36 toward the product.
In this case, no cooling passage is formed in the core 8 for forming the inner surface of the pipe.

【0028】以下、本発明の作用について詳述する。中
間層押出機12内にて樹脂管2の径方向への広がりを規
制せずに成形した場合における所定製品寸法の発泡倍率
を得るための理論添加量以上の添加量で発泡剤が溶融樹
脂に溶解する。
Hereinafter, the operation of the present invention will be described in detail. The foaming agent is added to the molten resin at an amount not less than the theoretical amount to obtain a foaming ratio of a predetermined product size when the resin tube 2 is molded without restricting the radial expansion of the resin tube 2 in the intermediate layer extruder 12. Dissolve.

【0029】この中間層の樹脂は金型から吐出すると同
時に発泡を始める。そして、管外面成形用チューブ5と
管内面成形用コア8との間隙に発泡状態の樹脂管2が入
り、樹脂管2の中間層となる発泡性熱可塑性樹脂組成物
22が径方向外方に広がろうとしても、管外面成形用チ
ューブ5と管内面成形用コア8とにより発泡圧に抗して
径方向への広がりが抑制され、加圧された状態となり、
樹脂管2は所定製品寸法となる肉厚を得ることができ
る。
The resin of the intermediate layer starts foaming as soon as it is discharged from the mold. The foamed resin tube 2 enters the gap between the tube outer surface forming tube 5 and the tube inner surface forming core 8, and the expandable thermoplastic resin composition 22 serving as an intermediate layer of the resin tube 2 moves radially outward. Even if it tries to spread, the tube 5 for forming the outer surface of the tube and the core 8 for forming the inner surface of the tube suppress the expansion in the radial direction against the foaming pressure, and become a pressurized state.
The resin tube 2 can have a wall thickness having a predetermined product size.

【0030】この結果、吐出流速の低い部分では管外面
成形用チューブ5と管内面成形用コア8との間に入った
ときに発泡が十分行われて流量不足による肉厚低下が補
われて一定肉厚が得られるし、吐出流速の早い部分は管
外面成形用チューブ5と管内面成形用コア8とにより発
泡が抑制されて一定肉厚が得られることから、最終製品
の全体の肉厚が一定となる。
As a result, in the portion where the discharge flow rate is low, when the tube enters between the tube 5 for forming the outer surface of the tube and the core 8 for forming the inner surface of the tube, the foaming is sufficiently performed, and the reduction in wall thickness due to insufficient flow is compensated for. The wall thickness is obtained, and foaming is suppressed by the tube 5 for forming the outer surface of the tube and the core 8 for forming the inner surface of the tube, so that a constant thickness is obtained. It will be constant.

【0031】以上のことから、本発明の製造方法によれ
ば、中間層を形成する発泡性熱可塑性樹脂組成物22
に、樹脂管2の径方向への広がりを規制せずに成形した
場合における所定製品寸法の発泡倍率を得るための理論
添加量以上の添加量となる発泡剤を添加しているので、
金型吐出後に所定製品寸法の肉厚以上に発泡しようとす
るが、管外面成形用チューブ5と管内面成形用コア8と
により発泡圧に抗して発泡が抑制されるため、常に均一
の肉厚を有する樹脂管2が得られる。
As described above, according to the production method of the present invention, the expandable thermoplastic resin composition 22
In addition, since a foaming agent having an addition amount equal to or more than a theoretical addition amount for obtaining a foaming ratio of a predetermined product size when the resin tube 2 is formed without restricting the radial expansion of the resin tube 2 is added,
After the mold is ejected, the foam tends to foam to a thickness greater than the predetermined product size. However, the foaming is suppressed by the tube 5 for forming the outer surface of the tube and the core 8 for forming the inner surface of the tube against the foaming pressure. The resin tube 2 having a thickness is obtained.

【0032】そして、中間層の流速を厳密に均一にせず
とも強制的に肉厚均一の樹脂管を成形することができる
ようになる。特に吐出流速分布の大きい回収樹脂の場合
でも、肉厚が均一な最終製品が得られる。また、中間層
の吐出流速を厳密に調整する必要が無いため、中間層の
樹脂変更が容易に行えるようになる。
Further, it is possible to forcibly mold a resin pipe having a uniform thickness without making the flow rate of the intermediate layer strictly uniform. In particular, even in the case of a recovered resin having a large discharge flow rate distribution, a final product having a uniform wall thickness can be obtained. Further, since it is not necessary to strictly adjust the discharge flow rate of the intermediate layer, the resin of the intermediate layer can be easily changed.

【0033】さらに、管外面成形用チューブ5と管内面
成形用コア8とにより樹脂管2の外面および内面をサイ
ジングにより型成形しているので、樹脂管2の内外面の
平滑性が上がり転写性を向上させることができるととも
に、表面外観が良好な三層構造の樹脂管2が容易に得ら
れる。特に、管内面成形用コア8により内層の表面状態
も良好な製品を得ることができる。
Further, since the outer and inner surfaces of the resin tube 2 are molded by sizing with the tube 5 for forming the outer surface of the tube and the core 8 for forming the inner surface of the tube, the smoothness of the inner and outer surfaces of the resin tube 2 is improved and the transferability is improved. And the resin tube 2 having a three-layer structure having a good surface appearance can be easily obtained. In particular, a product having a good surface condition of the inner layer can be obtained by the core 8 for forming the inner surface of the tube.

【0034】[0034]

【実施例】次に、実施例、比較例を挙げて本発明を詳し
く説明するが、本発明はこれらの実施例にのみ限定され
るものではない。以下の実施例、比較例で用いた原材料
について説明する。
Next, the present invention will be described in detail with reference to examples and comparative examples, but the present invention is not limited to these examples. Raw materials used in the following Examples and Comparative Examples will be described.

【0035】〔用いた原料〕内外層を形成するための熱
可塑性樹脂としてJIS K 6741に規定する硬質
塩化ビニル管用の塩化ビニル樹脂を用いた。
[Raw Materials Used] As a thermoplastic resin for forming the inner and outer layers, a vinyl chloride resin for a rigid vinyl chloride pipe specified in JIS K 6741 was used.

【0036】また、中間層を形成する熱可塑性樹脂に
は、 A:鉛系安定剤が混入された下水用塩化ビニル管に使用
された回収塩化ビニル樹脂 B:錫系安定剤が混入された水道用塩化ビニル管に使用
された回収塩化ビニル樹脂 C:重合度800の塩化ビニル樹脂(徳山積水工業製の
TS800E) を用い、表1および下記に示す配合1から配合3に示す
ものを用意した。
The thermoplastic resin forming the intermediate layer includes: A: a recovered vinyl chloride resin used in a sewage vinyl chloride pipe mixed with a lead-based stabilizer B: a tap water mixed with a tin-based stabilizer Recovered vinyl chloride resin used in a vinyl chloride pipe for use C: A vinyl chloride resin having a degree of polymerization of 800 (TS800E manufactured by Tokuyama Sekisui Kogyo Co., Ltd.) was used, and those shown in Table 1 and the following Formulations 1 to 3 were prepared.

【0037】配合1、配合2、配合3の配合比率を以下
の3通りの配合とした。 配合1:A原料50重量部、C原料50重量部 配合2:B原料50重量部、C原料50重量部 配合3:A原料25重量部、B原料25重量部、C原料
50重量部
The following three compounding ratios were used for Compounds 1, 2, and 3. Formulation 1: 50 parts by weight of raw material A, 50 parts by weight of raw material C Formulation 2: 50 parts by weight of raw material B, 50 parts by weight of raw material C Formulation 3: 25 parts by weight of raw material A, 25 parts by weight of raw material B, 50 parts by weight of raw material C

【0038】さらに、表1に示すように、上記配合1か
ら配合3に鉛安定剤2重量部、アクリル系加工助剤5重
量部、滑剤0.6重量部を添加した。
Further, as shown in Table 1, 2 parts by weight of a lead stabilizer, 5 parts by weight of an acrylic processing aid, and 0.6 parts by weight of a lubricant were added to the above-mentioned Formulations 1 to 3.

【表1】 [Table 1]

【0039】〔実施例1〕実施例1は、表1および上記
に示す配合1に、ADCA(アゾジカルボンアミド)発
泡剤を0.3部添加した発泡性熱可塑性樹脂組成物を用
い、図1および図2に示す樹脂管製造装置で、しかも、
金型3と管外面成形用チューブ5そして管内面成形用コ
ア8を図6および図7に示すものを用いて樹脂管を成形
した。そして、非発泡性熱可塑性樹脂組成物は190℃
で内外層押出機11にて混練し、押出量40kg/hで金型
3に注入させ、また発泡性熱可塑性樹脂組成物は、19
0℃で混練し60kg/hにて金型3に注入させた。金型3
は製品外径89mm、内径77mmの金型を用いた。
Example 1 In Example 1, a foamable thermoplastic resin composition obtained by adding 0.3 parts of an ADCA (azodicarbonamide) foaming agent to Table 1 and Formulation 1 shown above was used. And the resin pipe manufacturing apparatus shown in FIG.
A resin tube was formed by using the mold 3, the tube 5 for forming the outer surface of the tube, and the core 8 for forming the inner surface of the tube, as shown in FIGS. Then, the non-foamable thermoplastic resin composition has a temperature of 190 ° C.
And the mixture is kneaded with the inner and outer layer extruder 11 and injected into the mold 3 at an extrusion rate of 40 kg / h.
The mixture was kneaded at 0 ° C. and injected into the mold 3 at 60 kg / h. Mold 3
Used a mold having an outer diameter of 89 mm and an inner diameter of 77 mm.

【0040】〔実施例2〕実施例2は、表1および上記
に示す配合2に、ADCA(アゾジカルボンアミド)発
泡剤を0.3部添加した発泡性熱可塑性樹脂組成物を用
いたことを除いては、実施例1と同じ製造装置を用い、
同じ条件で樹脂管を成形した。
Example 2 Example 2 shows that a foamable thermoplastic resin composition obtained by adding 0.3 parts of an ADCA (azodicarbonamide) foaming agent to Table 1 and Formulation 2 shown above was used. Except for using the same manufacturing apparatus as in Example 1,
A resin tube was molded under the same conditions.

【0041】〔実施例3〕実施例3は、表1および上記
に示す配合3に、ADCA(アゾジカルボンアミド)発
泡剤を0.3部添加した発泡性熱可塑性樹脂組成物を用
いたことを除いては、実施例1と同じ製造措置を用い、
同じ条件で樹脂管を成形した。
Example 3 Example 3 shows that a foamable thermoplastic resin composition obtained by adding 0.3 parts of an ADCA (azodicarbonamide) foaming agent to Table 1 and the composition 3 shown above was used. Except for using the same manufacturing measures as in Example 1,
A resin tube was molded under the same conditions.

【0042】〔比較例1〕比較例1は、実施例1と同じ
配合1に、ADCA(アゾジカルボンアミド)発泡剤を
0.1部添加した発泡性熱可塑性樹脂組成物を用いて樹
脂管を成形したものであって、各実施例1から実施例3
に用いた製造装置において、管内面成形用コア8を取り
除いた状態で、即ち、管外面成形用チューブ5のみでサ
イジングを行って樹脂管を成形した。
[Comparative Example 1] In Comparative Example 1, a resin tube was formed using a foamable thermoplastic resin composition obtained by adding 0.1 part of ADCA (azodicarbonamide) foaming agent to the same formulation 1 as in Example 1. Each of Examples 1 to 3 was molded.
In the manufacturing apparatus used in (1), sizing was performed with the tube inner surface forming core 8 removed, that is, only with the tube outer surface forming tube 5 to form a resin tube.

【0043】なお、樹脂管の径方向への広がりを規制せ
ずに成形した場合における中間層の仕上製品寸法を得る
ための発泡倍率を2倍程度にするためには、通常ADC
Aを0.1部程度添加している。
When the expansion ratio for obtaining the finished product size of the intermediate layer in the case where the resin tube is formed without restricting the radial expansion of the resin tube is set to about 2 times, usually an ADC is used.
About 0.1 part of A is added.

【0044】〔比較例2〕比較例2は、実施例2と同じ
配合2に、ADCA(アゾジカルボンアミド)発泡剤を
0.1部添加した発泡性熱可塑性樹脂組成物を用いたこ
とを除いては、比較例1と同じ製造措置を用い、同じ条
件で樹脂管を成形した。
Comparative Example 2 Comparative Example 2 was the same as Example 2 except that a foamable thermoplastic resin composition was used in which 0.1 part of an ADCA (azodicarbonamide) blowing agent was added. Then, a resin tube was molded under the same manufacturing conditions as in Comparative Example 1 under the same manufacturing conditions.

【0045】〔比較例3〕比較例3は、実施例3と同じ
配合3に、ADCA(アゾジカルボンアミド)発泡剤を
0.1部添加した発泡性熱可塑性樹脂組成物を用いたこ
とを除いては、比較例1と同じ製造措置を用い、同じ条
件で樹脂管を成形した。
Comparative Example 3 Comparative Example 3 was the same as Example 3 except that a foamable thermoplastic resin composition was used in which 0.1 part of an ADCA (azodicarbonamide) blowing agent was added. Then, a resin tube was molded under the same manufacturing conditions as in Comparative Example 1 under the same manufacturing conditions.

【0046】〔サンプル評価法〕サンプル評価は樹脂管
の肉厚変動により評価した。押出成形品を1分ごとに切
断し、断面上下左右の4力所の肉厚を測定した。40の
データをとり、それらの標準偏差を算出した。表2に、
実施例および比較例にて行った三層構造の樹脂管の肉厚
変動の評価結果を示す。
[Sample Evaluation Method] The sample evaluation was made based on the thickness variation of the resin tube. The extruded product was cut every one minute, and the thickness at four places at the top, bottom, left and right of the cross section was measured. Forty data were taken and their standard deviation was calculated. In Table 2,
The evaluation result of the thickness fluctuation | variation of the resin pipe of a three-layer structure performed in the Example and the comparative example is shown.

【表2】 [Table 2]

【0047】〔結果〕実施例1〜3に示すように、本発
明の製造方法によれば、安定剤の種類や原料重合度に違
いがあっても、安定した肉厚が得られ、且つ、内面の平
滑性が向上した三層構造の樹脂管を得ることができた。
比較例の方法によれば、重合度の変化や安定剤の変化に
よって、肉厚変動が大きくなった。
[Results] As shown in Examples 1 to 3, according to the production method of the present invention, even if the type of stabilizer and the degree of polymerization of the raw materials are different, a stable thickness can be obtained. A three-layer resin tube with improved smoothness on the inner surface was obtained.
According to the method of the comparative example, the change in wall thickness was increased due to the change in the degree of polymerization and the change in the stabilizer.

【0048】[0048]

【発明の効果】本発明の三層構造の樹脂管の製造方法に
よれば、内層および外層となる非発泡熱可塑性樹脂組成
物との間に中間層となる発泡熱可塑性樹脂組成物を介在
された状態の三層構造の未固化管状体を金型から共押出
し、共押出された未固化管状体中の発泡熱可塑性樹脂組
成物を発泡させるとともに、熱可塑性樹脂を冷却固化す
る三層構造の樹脂管の製造方法において、中間層を形成
する熱可塑性樹脂に添加する発泡剤の添加量を、樹脂管
の径方向への広がりを規制せずに成形した場合における
所定製品寸法の発泡倍率を得るための理論添加量以上の
添加量とするとともに、管外面成形用チューブと管内面
成形用コアを用いて発泡圧に抗して所定の仕上がり寸法
にサイジングを行って樹脂管を形成したので、金型吐出
後に所定製品寸法の肉厚以上に発泡しようとした中間層
は、管外面成形用チューブと管内面成形用コアにより発
泡が抑制されるため所定の肉厚寸法で、かつ、均一の肉
厚の樹脂管を製造することができる。
According to the method for producing a three-layer resin tube of the present invention, a foamed thermoplastic resin composition as an intermediate layer is interposed between a non-foamed thermoplastic resin composition as an inner layer and an outer layer. Co-extruded the unsolidified tubular body of the three-layered structure from the mold, foams the foamed thermoplastic resin composition in the co-extruded unsolidified tubular body, and cools and solidifies the thermoplastic resin. In the method for manufacturing a resin tube, the amount of the foaming agent to be added to the thermoplastic resin forming the intermediate layer is obtained to obtain a foaming ratio of a predetermined product size when the resin tube is molded without restricting the radial expansion of the resin tube. In addition to the addition amount that is greater than the theoretical addition amount, a resin tube was formed by sizing to a predetermined finished size against foaming pressure using a tube for forming the outer surface of the tube and a core for forming the inner surface of the tube. Predetermined product dimensions after mold discharge Since the foaming is suppressed by the tube for forming the outer surface of the tube and the core for forming the inner surface of the tube, it is necessary to manufacture a resin tube having a predetermined thickness and a uniform thickness. Can be.

【0049】その結果、中間層の吐出流速を厳密に調整
する必要が無くなり、中間層の樹脂変更が容易行うこと
ができる。さらに、添加剤の種類の多いリサイクル樹脂
を中間層に用いても、安定した肉厚の三層構造の樹脂管
が容易に成形できる。
As a result, it is not necessary to strictly adjust the discharge flow rate of the intermediate layer, and the resin of the intermediate layer can be easily changed. Further, even if a recycled resin containing many kinds of additives is used for the intermediate layer, a resin pipe having a stable thickness and a three-layer structure can be easily formed.

【0050】さらに、管外面成形用チューブと管内面成
形用コアを用いるサイジングにより樹脂管の内外面を型
成形するようにしているので、樹脂管の内外面の平滑性
が上がり、内外面の転写性を向上できるとともに、内面
外観も良好な三層構造の樹脂管が容易に得られる。
Further, since the inner and outer surfaces of the resin tube are molded by sizing using the tube for forming the outer surface of the tube and the core for forming the inner surface of the tube, the smoothness of the inner and outer surfaces of the resin tube is improved, and the transfer of the inner and outer surfaces is performed. A resin tube having a three-layer structure that can improve the properties and also has a good inner surface appearance can be easily obtained.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の三層構造の樹脂管を製造するための製
造装置の上方から見た全体構成図を示す。
FIG. 1 is an overall configuration diagram of a manufacturing apparatus for manufacturing a resin tube having a three-layer structure according to the present invention as viewed from above.

【図2】図1に示す製造装置の側面から見た全体構成図
を示す。
FIG. 2 shows an overall configuration diagram of the manufacturing apparatus shown in FIG. 1 as viewed from a side.

【図3】本発明の三層構造の樹脂管を製造するために用
いる金型と管外面成形用チューブと管内面成形用コアを
示す1実施形態の断面図である。
FIG. 3 is a cross-sectional view of one embodiment showing a mold, a tube for forming an outer surface of a tube, and a core for forming an inner surface of a tube used for manufacturing a resin tube having a three-layer structure of the present invention.

【図4】本発明に用いる管内面成形用コアの1実施形態
における一部断面図である。
FIG. 4 is a partial cross-sectional view of one embodiment of a tube inner surface forming core used in the present invention.

【図5】本発明に用いる管内面成形用コアの他の実施形
態における一部断面図である。
FIG. 5 is a partial cross-sectional view of another embodiment of the core for forming a pipe inner surface used in the present invention.

【図6】本発明の三層構造の樹脂管を製造するために用
いる金型と管外面成形用チューブと管内面成形用コアを
示す他の実施形態の断面図である。
FIG. 6 is a cross-sectional view of another embodiment showing a mold, a tube for forming an outer surface of a tube, and a core for forming an inner surface of a tube used for manufacturing a resin tube having a three-layer structure of the present invention.

【図7】図6に示した管内面成形用コアの断面図であ
る。
FIG. 7 is a sectional view of the core for forming a tube inner surface shown in FIG. 6;

【符号の説明】[Explanation of symbols]

11 内外層押出機 12 中間層押出機 2 樹脂管 21 非発泡性熱可塑性樹脂組成物 22 発泡性熱可塑性樹脂組成物 3 金型 5 管外面成形用チューブ 8 管内面成形用コア DESCRIPTION OF SYMBOLS 11 Inner and outer layer extruder 12 Intermediate layer extruder 2 Resin tube 21 Non-foamable thermoplastic resin composition 22 Foamable thermoplastic resin composition 3 Die 5 Tube outer surface forming tube 8 Tube inner surface forming core

───────────────────────────────────────────────────── フロントページの続き (51)Int.Cl.7 識別記号 FI テーマコート゛(参考) B29L 9:00 B29L 9:00 23:00 23:00 ──────────────────────────────────────────────────続 き Continued on the front page (51) Int.Cl. 7 Identification symbol FI theme coat ゛ (Reference) B29L 9:00 B29L 9:00 23:00 23:00

Claims (3)

【特許請求の範囲】[Claims] 【請求項1】内層および外層となる非発泡熱可塑性樹脂
組成物との間に中間層となる発泡熱可塑性樹脂組成物を
介在させた状態の三層構造の未固化管状体を金型から共
押出し、共押出された未固化管状体中の発泡熱可塑性樹
脂組成物を発泡させるとともに、熱可塑性樹脂を冷却固
化する三層構造の樹脂管の製造方法において、中間層を
形成する熱可塑性樹脂に添加する発泡剤の添加量を、樹
脂管の径方向への広がりを規制せずに成形した場合にお
ける所定製品寸法の発泡倍率を得るための理論添加量以
上の添加量とするとともに、管外面成形用チューブと管
内面成形用コアを用いて発泡圧に抗して所定の仕上がり
寸法にサイジングを行って樹脂管を形成したことを特徴
とする三層構造の樹脂管の製造方法。
1. An unsolidified tubular body having a three-layer structure in which a foamed thermoplastic resin composition serving as an intermediate layer is interposed between a non-foamed thermoplastic resin composition serving as an inner layer and an outer layer, is formed from a mold. Extrusion, while foaming the foamed thermoplastic resin composition in the co-extruded unsolidified tubular body, in the method of manufacturing a three-layer resin tube cooling and solidifying the thermoplastic resin, the thermoplastic resin forming the intermediate layer The amount of the foaming agent to be added should be not less than the theoretical amount for obtaining a foaming ratio of a predetermined product size when the resin tube is molded without restricting the radial expansion of the resin tube, and the outer surface of the tube is formed. A method for producing a resin tube having a three-layer structure, wherein a resin tube is formed by sizing to a predetermined finished size against foaming pressure using a tube for forming a tube and a core for forming an inner surface of the tube.
【請求項2】中間層に用いられる熱可塑性樹脂が回収樹
脂である請求項1に記載の三層構造の樹脂管の製造方
法。
2. The method according to claim 1, wherein the thermoplastic resin used for the intermediate layer is a recovered resin.
【請求項3】熱可塑性樹脂が塩化ビニル系樹脂である請
求項1または請求項2に記載の三層構造の樹脂管の製造
方法。
3. The method according to claim 1, wherein the thermoplastic resin is a vinyl chloride resin.
JP2001034068A 2001-02-09 2001-02-09 Method for manufacturing resin tube having three-layer structure Pending JP2002234066A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
JP2001034068A JP2002234066A (en) 2001-02-09 2001-02-09 Method for manufacturing resin tube having three-layer structure

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP2001034068A JP2002234066A (en) 2001-02-09 2001-02-09 Method for manufacturing resin tube having three-layer structure

Publications (1)

Publication Number Publication Date
JP2002234066A true JP2002234066A (en) 2002-08-20

Family

ID=18897732

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2001034068A Pending JP2002234066A (en) 2001-02-09 2001-02-09 Method for manufacturing resin tube having three-layer structure

Country Status (1)

Country Link
JP (1) JP2002234066A (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2019161821A1 (en) * 2018-02-22 2019-08-29 Reifenhäuser GmbH & Co. KG Maschinenfabrik Method for producing a multi-layer plastic web, installation, multi-layer plastic web, and packaging tray
US10478150B2 (en) 2001-08-24 2019-11-19 The Cooper Companies Global Holdings Lp Medico—surgical devices
US10639002B2 (en) 2003-03-29 2020-05-05 The Cooper Companies Global Holdings Lp Medical devices

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US10478150B2 (en) 2001-08-24 2019-11-19 The Cooper Companies Global Holdings Lp Medico—surgical devices
US10639002B2 (en) 2003-03-29 2020-05-05 The Cooper Companies Global Holdings Lp Medical devices
WO2019161821A1 (en) * 2018-02-22 2019-08-29 Reifenhäuser GmbH & Co. KG Maschinenfabrik Method for producing a multi-layer plastic web, installation, multi-layer plastic web, and packaging tray

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