JP2001220332A - Composition for formulating hair treatment preparation and hair treatment preparation - Google Patents

Abstract

PROBLEM TO BE SOLVED: To provide the subject composition capable of easily and inexpensively preparing hair treatment preparations including hair conditioners, waving preparations, finishers and thickening agent to be prepared in time of use, and to provide hair treatment preparations excellent in feeling when applied such as light oily feeling, slipperiness, softness, dampishness, glossiness and hair touch, and also in characteristics such as adherability/spreadability/ humectancy/sag resistance, applicability, retouch workability, uneven and firm wave formability, low irritant odor (e.g. ammonia odor), wave formation quickness, slight residual odor after waving operation, good appearance (e.g. sophisticated silky touch appearance) and low skin irritancy. SOLUTION: This composition for formulating hair treatment preparations is characterized by containing (I) alcohol(s) and (II) at least one ingredient selected from the group consisting of anionic surfactants, inorganic acids and inorganic alkali agents.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

TECHNICAL FIELD The present invention relates to a composition for blending a hair treatment agent and a hair treatment agent. In particular, the present invention is a composition for blending a hair treatment agent for preparing a hair treatment agent, and a treatment obtained therefrom, a hair conditioner such as a rinse, a hair dye, a waving agent, a finishing agent, a feel improving agent, and The present invention relates to a hair treatment agent such as a hair remover.

[0002]

2. Description of the Related Art In recent years, the aesthetic sense of hair has increased, and accordingly, the demand for hair treatment agents has also increased. Specifically, it has a light oiliness, smoothness, softness, softness, shine, and a feeling of use such as touch to hair, and is easy to apply, spread, wet, drip, and easy to apply. (Applicability), Ease of retouching work (Retouching workability), Formability of solid wave without spots, Low irritating odor (for example, ammonia odor), Quickness of wave formation, After wave treatment There is a strong need for a hair treatment agent having excellent properties such as low residual odor, excellent appearance of the treatment agent (for example, a luxurious pearl touch appearance), and low skin irritation.

[0003] Conventionally, in order to satisfy such demands of consumers, hair conditioners containing various compounding components,
Hair treatment agents such as hair dyes, waving agents, finishing agents, feel improvers, and hair removers have been proposed.

[0004] However, in the conventional preparation of a hair treatment agent, since each compounding component is weighed, added and mixed one by one, there is a problem that the process is very complicated and time and cost are required. there were.

[0005] Further, in conventional hair treatment agents, specific components such as specific fatty acid esters, surfactants, silicones, etc. are added to the hair treatment agent in order to exhibit various hair treatment effects. .

[0006] However, these compounds are often uncommon because they have a special structure. Therefore, there is a problem that it is difficult to obtain or expensive. There is also a problem that the hair treatment effect is not sufficient.

[0007]

DISCLOSURE OF THE INVENTION The present invention relates to a hair conditioner, a hair dye, a waving agent, a finishing agent, a feel improving agent, and a hair treating agent which can be easily and inexpensively prepared. Composition, and light oiliness, smoothness, softness, softness, luster, excellent feeling of use such as touch to hair, and adhesion, elongation, wettability,
Hard to sag, easy to apply (applicability), easy to retouch (easy to retouch), formable with no spots, firm wave, less irritating odor (eg ammonia odor), wave formation The above-mentioned hair treatment agent which has excellent properties such as quickness of the treatment, low residual odor after the wave treatment, excellent appearance of the treatment agent (for example, high-quality silky touch appearance), and low skin irritation. The purpose is to provide.

[0008]

Means for Solving the Problems In order to solve the above problems, the present inventors have conducted intensive studies and found that (I) alcohols and (II) anionic surfactants, inorganic acids and inorganic alkali agents. It has been found that a hair treating agent having an excellent hair treatment effect (that is, an excellent feeling in use and excellent properties) can be easily and inexpensively prepared by using a composition containing the one selected from the group consisting of: Thus, the present invention has been completed.

That is, the present invention relates to (I) an alcohol,
(II) A composition for blending a hair treatment agent, comprising a composition selected from the group consisting of anionic surfactants, inorganic acids, and inorganic alkali agents.

According to the present invention, the alcohols are selected from the group consisting of ethanol, isopropanol, lauryl alcohol, cetanol, stearyl alcohol, oleyl alcohol, behenyl alcohol, cetostearyl alcohol, benzyl alcohol, propylene glycol, 1,3-butylene glycol and glycerin. One to four compounds selected, wherein the anionic surfactant is sodium lauryl sulfate, triethanolamine lauryl sulfate,
One or two compounds selected from the group consisting of sodium cetyl sulfate, sodium myristoylmethyltaurine, polyethanoloxylauryl ether triethanolamine sulfate, and polyoxyethylene oleyl ether phosphoric acid, wherein the inorganic acids are phosphoric acid or phosphorus. The composition for blending a hair treatment agent, wherein the composition is sodium monohydrogen oxyacid and the inorganic alkali agent is sodium hydroxide.

The present invention provides the composition for blending a hair treatment agent according to any one of the above, wherein the alcohol is one or two compounds selected from the group consisting of lauryl alcohol, cetanol, and glycerin.

[0012] The present invention provides the composition for blending a hair treatment agent according to any of the above, wherein the anionic surfactant is sodium lauryl sulfate.

[0013] The present invention provides a composition for blending a hair treatment agent, which further comprises a nonionic surfactant, an oil or fat, a hydrocarbon, a polymer, an organic acid, an organic base, an amphoteric surfactant, a sequestering agent, Any of the above-mentioned compositions for compounding a hair treatment agent, comprising one to six kinds selected from the group consisting of hydrolyzed collagen, fragrances, parabens, nitrogen-containing solvents, and water.

According to the present invention, the nonionic surfactant is polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether,
Polyoxyethylene oleyl ether, polyoxyethylene nonyl phenyl ether, polyoxyethylene castor oil, polyoxyethylene hardened castor oil, polyoxyethylene lanolin, polyoxyethylene coconut oil alkylamine, polyoxyethylene / polyoxypropylene cetyl ether, poly Oxyethylene polyoxypropylene lanolin, diethanolamide oleate, diethanolamide stearate, polyoxyethylene sorbite tetraoleate, and one selected from the group consisting of coconut oil alkyldimethylamine oxide, two, three, four, Or six kinds of compounds, wherein the fats and oils are one or two kinds of compounds selected from the group consisting of meadowfoam oil, olive oil, shea butter, and mink wax, and the hydrocarbons are liquid paraffins. A fin, polymers such is dimethyldiallylammonium chloride-acrylamide copolymer,
Hydroxyethyl cellulose, polypropylene glycol, carboxyvinyl polymer, or polyoxypropylene methyl glucoside; the organic acid is glycolic acid or tartaric acid; the organic bases are triethanolamine; and the amphoteric surfactant is 2-alkyl-N-. Carboxymethyl-N-hydroxyethylimidazolinium betaine or coconut oil fatty acid amidopropyl betaine, the sequestering agent is hydroxyethanediphosphonic acid or disodium edetate, the flavor is orange oil,
The above hair treatment composition, wherein the parabens are one or two compounds selected from the group consisting of propyl paraoxybenzoate, isopropyl paraoxybenzoate, and methyl paraoxybenzoate, and the nitrogen-containing solvent is N-methylpyrrolidone. A composition for use is provided.

[0015] The present invention provides a composition for a hair treatment composition, wherein the content of the alcohol (I) is A% by weight, and the composition comprises a group consisting of an anionic surfactant, an inorganic acid, and an inorganic alkali agent. Assuming that the content of at least one type (II) selected is B wt%, A and B are represented by the following formula: 0.1 ≦
A ≦ 90, 0.05 ≦ B ≦ 65 and A + B ≦ 100
The composition for blending a hair treatment agent according to any of the above, which satisfies the following.

The present invention relates to a composition for blending a hair treatment agent, a composition for blending a hair conditioner, a composition for blending a hair dye,
Any of the above compositions for blending a hair treatment agent, which is a composition for blending a waving agent, a composition for blending a finishing agent, a composition for blending a feel improving agent, or a composition for blending a hair remover, is provided.

The present invention provides a hair treatment composition containing any of the above compositions for compounding a hair treatment composition.

The present invention provides the above hair treatment composition, wherein the hair treatment composition is a hair conditioner, a hair dye, a waving agent, a finishing agent, a feel improving agent, or a hair remover.

[0019]

BEST MODE FOR CARRYING OUT THE INVENTION The composition for blending a hair treatment composition of the present invention contains an alcohol as the component (I). Examples of the alcohols include lower / higher alcohols, natural alcohols, aromatic alcohols, and polyhydric alcohols (glycols, glycerins, etc.).

Specifically, the alcohols include ethanol, isopropanol, lauryl alcohol, cetanol, stearyl alcohol, oleyl alcohol,
One to four compounds selected from the group consisting of behenyl alcohol, cetostearyl alcohol, benzyl alcohol, propylene glycol, 1,3-butylene glycol, and glycerin (for example, concentrated glycerin).

For example, the composition for mixing a waving agent and the composition for mixing a hair dye may contain lauryl alcohol and / or cetanol. Hair conditioner composition, hair dye composition, waving composition,
And glycerin may be contained in the composition for blending a finish.

The composition for compounding a hair treatment composition of the present invention contains, as the component (II), an anionic surfactant, an inorganic acid, or an inorganic alkali agent.

For example, the composition for blending the hair dye, the composition for blending the waving agent, the composition for blending the finish, and the composition for blending the hair remover may contain an anionic surfactant. The composition for blending a hair dye, the composition for blending a waving agent, the composition for blending a finish, and the composition for blending a feel improver may contain, for example, inorganic acids. The composition for formulating a hair conditioner and the composition for formulating a hair dye may contain, for example, an inorganic alkali agent.

Examples of the anionic surfactant include higher alkyl sulfates, sulfonates of higher fatty acid amides, higher alkyl ether sulfates and phosphates, and salts thereof.

Specifically, it is selected from the group consisting of sodium lauryl sulfate, triethanolamine lauryl sulfate, sodium cetyl sulfate, sodium myristoylmethyltaurine, triethanolamine polyoxyethylene lauryl ether sulfate, and polyoxyethylene oleyl ether phosphoric acid. Or two or more compounds. The degree of polymerization of ethylene oxide (EO) in "polyoxyethylene" is, for example, 2 to 5.

Examples of the inorganic acids include phosphoric acid and salts thereof. Specific examples include phosphoric acid and sodium monohydrogen phosphate.

Examples of the inorganic alkali agent include an alkali metal hydroxide (specifically, sodium hydroxide and the like).

Further, various additives may be appropriately added to the composition for compounding a hair treatment agent of the present invention according to the type and purpose of the hair treatment agent. For example, the composition for compounding a hair treatment agent of the present invention includes, as additives, nonionic surfactants, oils and fats, hydrocarbons, polymers, organic acids, organic bases, amphoteric surfactants, sequestering agents , Hydrolyzed collagen, perfume, parabens, nitrogen-containing solvents, and water.

For example, a nonionic surfactant is added to a composition for blending a hair dye, a composition for blending a waving agent, a composition for blending a finish, a composition for blending a feel improving agent, and a composition for blending a hair remover. May be contained. The composition for compounding a waving agent may contain, for example, one or two selected from the group consisting of fats and oils, organic bases, amphoteric surfactants, and fragrances.

The depilatory composition may contain, for example, hydrocarbons. A composition for blending a hair conditioner,
For example, polymers may be contained in the composition for blending a hair dye, the composition for blending a waving agent, the composition for blending a finish, and the composition for blending a feel improver. The composition for blending a hair conditioner, the composition for blending a hair dye, and the composition for blending a waving agent may contain, for example, organic acids. The composition for mixing a wave agent and the composition for mixing a feel-enhancing agent may contain, for example, a sequestering agent.

The composition for formulating a hair conditioner may contain, for example, hydrolyzed collagen. For example, parabens may be contained in the composition for blending the hair conditioner, the composition for blending the waving agent, the composition for blending the finish, and the composition for blending the feel improving agent. The hair dye may contain, for example, a nitrogen-containing solvent. Hair conditioner composition, hair dye composition, waving composition, finish composition, feel improver composition,
The composition for blending a hair remover may contain, for example, water.

Examples of the nonionic surfactant include polyoxyethylene alkyl, alkenyl, and alkyl.
Examples include aryl ethers, polyoxyethylene derivatives of natural fats and oils, ethylene oxide / propylene oxide block copolymers, fatty acid alkylolamides, and higher fatty acid esters (for example, tetraesters) of polyhydric alcohols (such as sorbitans).

The degree of polymerization of ethylene oxide (EO) in "polyoxyethylene" is, for example, 2 to 70.
And so on. The degree of polymerization of propylene oxide (PO) in “polyoxypropylene” may be, for example, 4 to 25 or the like.

Specific examples of the nonionic surfactant include polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene nonylphenyl ether, and polyoxyethylene castor oil. , Polyoxyethylene hydrogenated castor oil, polyoxyethylene lanolin, polyoxyethylene coconut oil alkylamine, polyoxyethylene / polyoxypropylene cetyl ether, polyoxyethylene / polyoxypropylene lanolin, diethanolamide oleate,
One, two, three, four, or six compounds selected from the group consisting of stearic acid diethanolamide, polyoxyethylene sorbite tetraoleate, and coconut oil alkyldimethylamine oxide.

The fats and oils include vegetable fats and oils and fats. Specifically, examples of the fats and oils include one or two kinds of compounds selected from the group consisting of meadowfoam oil, olive oil, shea butter, and mink wax. Specific examples of the hydrocarbons include liquid paraffin.

As the polymers, specifically, dimethyldiallylammonium chloride / acrylamide copolymer (molecular weight, for example, 100,000 to 1,000,000), hydroxyethyl cellulose (viscosity, for example, 500 to 5
000 cps, etc.), polypropylene glycol (PO polymerization degree, for example, 10 to 50, etc.), carboxyvinyl polymer (molecular weight, for example, 2,000,000 to 500, for example)
And polyoxypropylene methyl glucoside (PO polymerization degree is, for example, 10 to 50).

Specific examples of the organic acid include glycolic acid and tartaric acid. Specific examples of organic bases include triethanolamine. Specific examples of the amphoteric surfactant include 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine and coconut oil fatty acid amidopropyl betaine. Specific examples of the sequestering agent include hydroxyethanediphosphonic acid and disodium edetate.

Specific examples of the flavor include orange oil and the like. Specific examples of the parabens include one or two compounds selected from the group consisting of propyl paraoxybenzoate, isopropyl paraoxybenzoate, and methyl paraoxybenzoate. Specific examples of the nitrogen-containing solvent include N-methylpyrrolidone.

In the composition of the composition for compounding a hair treatment composition of the present invention, the content of the component (I) is defined as A weight%, and the component (I)
Assuming that the content of I) is B wt%, A and B are represented by the following formulas:
0.1 ≦ A ≦ 90, 0.05 ≦ B ≦ 65 and A + B
≦ 100 may be satisfied.

For example, in the composition for formulating a hair conditioner, A and B are represented by the following formula: 1 ≦ A ≦ 30, 0.1
≦ B ≦ 10 may be satisfied.

In the hair dye composition, for example, A
And B are represented by the following formula: 10 ≦ A ≦ 65, 0.1 ≦ B ≦ 10
May be satisfied.

In the composition for mixing the wave agent, for example, A and B are represented by the following formulas: 0.1 ≦ A ≦ 90, 0.05 ≦
B ≦ 65 and A + B ≦ 100 may be satisfied.

In the composition for finish compounding, for example, A and B are represented by the following formula: 15 ≦ A ≦ 50, 0.05 ≦ B ≦
20 may be satisfied.

In the composition for blending the feel improver, for example, A and B are represented by the following formulas: 1 ≦ A ≦ 10, 0.1 ≦ B ≦ 10
May be satisfied.

In the composition for blending a hair remover, for example, A
And B may satisfy the following formula: 20 ≦ A ≦ 60, 1 ≦ B ≦ 10

In the preparation method of the composition for compounding a hair treatment composition of the present invention, for example, compounding components such as component (I), component (II) and, if necessary, various additives are mixed, and if necessary, The stirring is performed under reduced pressure and / or heating until complete dissolution. The reduced pressure may be, for example, 400 to 600 mmHg. The heating temperature may be lower than the temperature at which the mixture does not decompose, for example, lower than 95 ° C. The order of addition of the components is not particularly limited. For example, each of the components may be added at once, or may be added sequentially while confirming that the components are dissolved one by one.

As another method for preparing the composition for blending a hair treatment composition of the present invention, for example, alcohols and various other oily components (for example, nonionic surfactants, parabens, etc.) are mixed, and the mixture is heated and uniformly dissolved. I do. This homogeneous solution is added to heated water while stirring to form an emulsion, which is then cooled.

Thereafter, the component (II) may be added to the cooled emulsion while stirring and uniformly mixed to prepare the emulsion. The heating temperature is preferably lower than the temperature at which the mixture does not decompose, for example, 95 ° C or lower.

The hair treatment composition of the present invention contains the composition for compounding the hair treatment composition of the present invention. Hereinafter, a hair conditioner, a hair dye, a waving agent, a finishing agent, a feel improving agent, a hair remover, and the like will be described as examples of hair treatment agents.

The hair conditioner of the present invention includes:
Two-part treatments are included. A two-part treatment consists of a first part and a second part.

The first part of the two-part treatment of the present invention contains the composition for blending the hair conditioner of the present invention, and may further contain, for example, alcohols, preservatives, water and the like. The two-part treatment first agent alone is also included in the hair conditioner of the present invention.) Examples of alcohols include ethanol and 1,3-butylene glycol. Preservatives include parabens and the like.

In the composition of the first part of the two-part treatment of the present invention, the composition for blending a hair conditioner of the present invention contains 10 to 50% by weight.

As a method for preparing the first part of the two-part treatment of the present invention, for example, a composition for blending a hair conditioner and water are uniformly mixed to obtain an aqueous composition. On the other hand, an alcoholic composition is obtained by uniformly mixing alcohols and preservatives.
Thereafter, the oily composition may be added to the aqueous composition while stirring, and may be uniformly dissolved to prepare the composition.

The two-part treatment second part includes, for example, alcohols, cationic surfactants, nonionic surfactants, preservatives, organic acids, silicons (Si-containing compounds),
It may contain water and the like.

Examples of the alcohols include higher alcohols (eg, behenyl alcohol) and glycols (eg, 1,3-butylene glycol). Examples of the cationic surfactant include stearyltrimethylammonium chloride. Examples of the nonionic surfactant include polyoxyethylene sorbitan monooleate (for example, a polymer of 10 to 30 EO).

Examples of preservatives include parabens (eg, methyl paraoxybenzoate, propyl paraoxybenzoate, etc.). Examples of the organic acid include lactic acid. Examples of silicons include amino-modified silicone and methylpolysiloxane (for example, those having 10 to 30 cs).

In the composition of the two-part treatment second part, alcohols are 5 to 30% by weight, cationic surfactants are 1 to 5% by weight, nonionic surfactants are 0.1 to 1% by weight, preservatives 0.05 to 1% by weight of an agent and 0.01% of an organic acid
To 1% by weight and silicons to 10 to 30% by weight, respectively.

As a method for preparing the two-part treatment second part, for example, an alcohol, a cationic surfactant, a nonionic surfactant, a preservative, and the like are mixed and then heated and uniformly dissolved. A heated organic acid aqueous solution is added thereto, and the mixture is emulsified and then cooled. Thereafter, silicones may be added to the cooled emulsion and uniformly mixed to prepare.

The hair dye of the present invention includes an acidic hair dye. The acidic hair dye may contain an alcohol, a dye, an acid, water, etc., in addition to the hair dye composition of the present invention.
Examples of alcohols include ethanol, benzyl alcohol, glycerin and the like. Examples of the dye include tar dyes (for example, Red No. 2, Orange No. 205, Yellow No. 4, Green No. 3 and No. 204, Purple No. 401, Black No. 401, etc.).
Is mentioned. Examples of the acid include organic acids (eg, lactic acid, glycolic acid, tartaric acid, citric acid, etc.) and inorganic acids (eg, hydrochloric acid, etc.).

In the composition of the acidic hair dye, the hair dye composition may contain, for example, 20 to 90% by weight.

As a method for preparing an acidic hair dye, for example, an alcohol, a dye, an organic acid, and the like may be sequentially added to a composition for blending a hair dye, and the mixture may be uniformly stirred and mixed.

Another hair dye of the present invention includes an oxidative hair dye. The oxidative hair dye comprises a first agent and a second agent (in the present invention, the oxidative hair dye first agent alone and the oxidative hair dye second agent alone also include the hair dye of the present invention). include.). The first oxidative hair dye of the present invention may contain a dye intermediate, an alkali agent, an antioxidant, a sequestering agent, water, etc., in addition to the composition for blending a hair dye of the present invention.

Examples of the dye intermediate pair include phenylenediamines (such as ortho-meta-para-phenylenediamine), phenols (such as ortho-meta-para-aminophenol and nitrophenol), and aminocresols. Ammonia water as the alkaline agent,
Monoethanolamine (MEA) and the like. Examples of the antioxidant include those commonly used in oxidative hair dyes, such as sodium sulfite, ammonium thioglycolate, ascorbic acid, and cysteine. Examples of sequestering agents include edetates.

In the composition of the first oxidative hair dye, the composition for blending the hair dye may contain, for example, 10 to 35% by weight.

As a method for preparing the first agent for oxidative hair dye, for example, a dye intermediate and an antioxidant are added to heated water to form an aqueous solution, and the composition is then heated and uniformly dissolved to mix the hair dye. Add, mix and cool, then, with stirring, an alkaline agent,
This may be performed by adding a sequestering agent or the like. The heating temperature of the composition for mixing water and the hair dye is preferably a temperature at which the components are not decomposed, for example, 95 ° C. or lower.

The second agent for oxidative hair coloring of the present invention comprises, in addition to the composition for compounding hair coloring of the present invention, an oxidizing agent, a sequestering agent,
It may contain a pH adjuster, water and the like. Examples of the oxidizing agent include hydrogen peroxide. As sequestering agents,
And hydroxyethanediphosphonic acid. Examples of the pH adjuster include phosphates (for example, sodium monohydrogen phosphate) and the like.

In the composition of the oxidative hair dye second agent, the composition for compounding the hair dye may contain, for example, 1 to 15% by weight.

As a method of preparing the oxidative hair dye second agent, for example, a hair dye composition for heating and uniformly dissolved in heated water is added, stirred and emulsified, cooled with stirring, and then sequestered with metal ions. An agent, a pH adjuster, an oxidizing agent and the like may be added.
The heating temperature of the composition for mixing water and the hair dye is preferably a temperature at which the components are not decomposed, for example, 95 ° C. or lower.

The oxidative hair dye of the present invention uses at least one of the first oxidative hair dye of the present invention and the second oxidative hair dye of the present invention. For example, the oxidative hair dye of the present invention includes the oxidative hair dye first agent of the present invention and the oxidative hair dye second agent of the present invention, and the oxidative hair dye first agent of the present invention. And an oxidized hair dye second agent other than the above, and an oxidized hair dye second agent other than the above and an oxidized hair dye second agent of the present invention.

Examples of the “first agent for oxidative hair dyes other than those described above” and the “second agent for oxidative hair dyes other than those described above” include, for example, a first agent and a second agent which are respectively commonly used for hair dyes. No.

Another hair treatment agent of the present invention includes a hair bleaching agent. The hair bleaching agent comprises a first agent and a second agent. (In the present invention, the hair bleaching agent, the hair bleaching agent first agent alone, and the hair bleaching agent second agent alone are also used in the present invention. Agent).

The hair bleaching agent first agent of the present invention may contain an antioxidant, an alkali agent, a sequestering agent, water and the like in addition to the composition for blending a hair dye of the present invention.

Examples of the antioxidant include those commonly used in oxidative hair dyes, for example, sodium sulfite, ammonium thioglycolate, ascorbic acid, cysteine and the like. Examples of the alkaline agent include MEA and ammonia. As sequestering agents, edetate,
And hydroxyethanediphosphonic acid.

In the composition of the first hair bleaching agent of the present invention, the composition for blending a hair dye may contain, for example, 10 to 35% by weight.

As a method for preparing the first agent for the hair bleaching agent of the present invention, for example, an antioxidant, a sequestering agent and the like are added to heated water to form an aqueous solution, and then the hair dye is heated and uniformly dissolved. The composition may be added and mixed, and after cooling, an additive such as an alkali agent may be added with stirring. The heating temperature of the composition for mixing water and the hair dye is preferably a temperature at which the components are not decomposed, for example, 90 ° C. or lower.

The hair bleaching agent second agent of the present invention may contain a sequestering agent, a pH adjuster, an oxidizing agent, water and the like in addition to the composition for blending a hair dye of the present invention. Examples of the sequestering agent include hydroxyethanediphosphonic acid. Examples of the pH adjuster include a phosphate (eg, sodium monohydrogen phosphate) and the like. Examples of the oxidizing agent include hydrogen peroxide.

In the composition of the hair bleaching agent second agent of the present invention, the composition for blending a hair dye may contain, for example, 1 to 15% by weight.

As a method for preparing the second agent for the hair bleaching agent of the present invention, for example, a hair dye composition for heating and uniformly dissolved in heated water is added, stirred and emulsified, and cooled with stirring.
This may be performed by adding additives such as a sequestering agent, a pH adjuster, and an oxidizing agent. The heating temperature of the composition for mixing water and the hair dye is preferably a temperature at which the components are not decomposed, for example, 90 ° C. or lower.

The hair bleaching agent of the present invention uses at least one of the hair bleaching agent first agent of the present invention and the hair bleaching agent second agent of the present invention. For example, as the hair bleaching agent of the present invention, those comprising the above-described hair bleaching agent first agent of the present invention and the above-mentioned hair bleaching agent second agent, the above-mentioned hair bleaching agent first agent of the present invention and other than the above A hair bleaching agent second agent, and a hair bleaching agent first agent other than those described above and a hair bleaching agent second agent of the present invention are included.

Examples of the "first agent other than the above-mentioned hair bleaching agent" and the "second agent other than the above-mentioned hair bleaching agent" include, for example, a first agent and a second agent each of which are usually used for a hair bleaching agent. .

Examples of the waving agent of the present invention include those comprising a first agent and a second agent. (In the present invention, the first waving agent alone and the second waving agent alone are also used. , Included in the hair treatment composition of the present invention). The first waving agent of the present invention may contain a reducing agent, an alkali agent, an antibacterial agent, water and the like in addition to the waving agent blending composition of the present invention.

As the composition for compounding the waving agent, one or more kinds may be used. As the reducing agent, thioglycolic acid, cysteine and the like, or salts thereof [ammonium salt,
Monoethanolamine (MEA) salt, hydrochloride, etc.]. Examples of the alkaline agent include ammonia, amines (such as MEA and isopropanolamine), ammonium salts (such as ammonium bicarbonate), and basic amino acids. Examples of the antibacterial agent include sodium dehydroacetate.

In the composition of the first part of the waving agent of the present invention, the composition for blending the waving agent may contain, for example, 0.1 to 35% by weight.

As a method for preparing the first agent of the waving agent of the present invention, for example, a composition for mixing a waving agent, which is heated and uniformly dissolved in heated water, is stirred and emulsified, and then cooled to prepare a viscous liquid. . Thereafter, a reducing agent, an alkali agent and the like may be added at room temperature, and the mixture may be uniformly stirred and mixed. In addition, the concentration of the composition for compounding a wave agent contained in the viscous liquid may be, for example, 1 to 20% by weight.

As another method for preparing the first waving agent of the present invention, for example, a waving agent blending composition, a reducing agent, an alkali agent, water and the like are added, and if necessary, the mixture is stirred and mixed under heating. May be.

The second waving agent of the present invention includes, in addition to the waving composition of the present invention, an oxidizing agent, a surfactant,
It may contain water and the like. As the composition for blending a waving agent, one or more types may be used. Examples of the oxidizing agent include bromates (eg, sodium bromate) and hydrogen peroxide, and examples of the surfactant include lauryl trimethyl ammonium halide (lauryl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide).

In the composition of the second waving agent of the present invention, the waving agent blending composition may contain, for example, 1 to 50% by weight.

As the second waving agent, those usually used for the second waving agent can be used in place of the second waving agent of the present invention. Examples of such a wave agent second agent include an oxidizing agent (eg, sodium bromate) and a surfactant (lauryl trimethyl ammonium chloride, lauryl trimethyl ammonium bromide, etc.).
Prepared by uniformly dissolving in water.

As a method for preparing the second waving agent of the present invention, for example, water and an oxidizing agent are mixed and heated to obtain an aqueous solution. Next, the composition for mixing a wave agent, which is heated and uniformly dissolved, is added to the heated aqueous solution, and the mixture is emulsified with stirring, followed by cooling to prepare.

As another method for preparing the second agent of the waving agent of the present invention, for example, a waving agent blending composition, an oxidizing agent, water and the like may be added and, if necessary, may be prepared by stirring and mixing under heating.

The waving agent of the present invention uses at least one of the first waving agent of the present invention and the second waving agent of the present invention. For example, as the waving agent of the present invention, those comprising the above-mentioned waving agent first agent of the present invention and the above waving agent second agent, the above-mentioned waving agent first agent of the present invention and other waving agents other than the above And the second wave agent of the present invention other than the above.

Examples of the “first agent other than the above-mentioned agents” and the “second agent other than the above-mentioned agents” include, for example, the first agent and the second agent each of which is usually used for a waving agent. Specifically, "the second wave agent other than the above"
Examples thereof include those prepared by uniformly dissolving an oxidizing agent and a surfactant in water.

The finish of the present invention contains a composition for blending a finish, and usually further contains water. In addition, esters, alcohols, sequestering agents, bases, preservatives, and the like may be appropriately added as additional components.

The esters include higher fatty acid esters (eg, isopropyl myristate), and the alcohols include isopropyl alcohol (IPA), propylene glycol, glycerin and the like. Examples of the sequestering agent include disodium edetate. As the bases, sodium hydroxide, MEA
And the like. Preservatives include parabens.

In the finish composition of the present invention, the finish compounding composition may contain, for example, 20 to 60% by weight.

As a method of preparing the finishing agent of the present invention, each of the components may be added sequentially under heating, if necessary. In this case, the order of addition of the respective components is preferably such that the respective components are uniformly dissolved. Specifically, the composition may be prepared by uniformly mixing the composition for blending the finishing agent, the esters, the alcohols, the bases, the preservative, the water, and the like while stirring them sequentially.

The feel-improving agent of the present invention imparts luster to the treated hair by adding it to a hair treatment agent such as a waving agent, and further improves the feel of the hair. As the feel improving agent of the present invention, the composition for blending the feel improving agent of the present invention itself can be used.

The blending amount of the feel-improving agent of the present invention may be, for example, 10 to 25% by weight based on the total weight of the waving agent after blending when it is incorporated into the waving agent.

The hair remover of the present invention contains the composition for blending a hair remover of the present invention, and may further contain a hair remover, a reducing agent, an alkali agent, water and the like. Examples of the hair removal aid include urea and the like. Examples of the reducing agent include calcium thioglycolate. Examples of the alkali agent include sodium hydroxide.

In the composition of the hair remover of the present invention, the composition for blending the hair remover may be contained in an amount of 1 to 20% by weight. In addition, as pH of a hair remover, for example, 12-13, especially 12.2-1.
2.8 is preferred.

As a method for preparing the hair remover of the present invention, for example, a hair remover blending composition heated and uniformly dissolved in heated water is added with stirring and emulsified. Next, after cooling this emulsion, a hair removal aid, a reducing agent, an alkali agent, and the like may be added, and the mixture may be uniformly mixed to prepare.

[0102]

EXAMPLES The present invention will be described more specifically with reference to the following examples. (Preparation of Hair Treatment Agent Composition) Example 1 After dispersing the components 43, 1, 57, and 12 in the component 59 at room temperature, the components 21, 47, and 5 were dispersed.
4 were successively added to prepare a composition for blending a hair treatment agent of the present invention. In addition, after confirming that the previously added components were uniformly dissolved, the latter components were added. Tables 1 and 2 show the compounding component numbers, the corresponding compounding components, and the compounding amount (kg).
Is shown.

Example 2 At the heating temperature shown in Table 1, each of the components 4, 13, 59,
25 and 22 were successively added to prepare a composition for blending a hair treatment composition of the present invention. After confirming that the above-mentioned additional components were dissolved, the following components were added. Tables 1 and 2 show the component numbers, the corresponding components, and the amounts (kg).

Example 3 In the same manner as in Example 2, each of the components 4, 13, 59, 2
5, 22, and 3 were sequentially added to prepare a composition for blending a hair treatment agent of the present invention.

Example 4 In the same manner as in Example 2, each of the components 4, 3, 13, 5
9 and 23 were sequentially added to prepare a composition for blending a hair treatment agent of the present invention.

Example 5 In the same manner as in Example 2, the components 4, 13, and 59 were added.
Were sequentially added to prepare a composition for blending a hair treatment agent of the present invention.

Example 6 In the same manner as in Example 2, each of the components 4, 23, 26, 1
5, 59, 29, and 32 were sequentially added to prepare a composition for blending a hair treatment agent of the present invention.

Example 7 In the same manner as in Example 2, each of the components 4, 23, 29, 1
5 and 59 were successively added to prepare a composition for blending a hair treatment agent of the present invention.

Example 8 In the same manner as in Example 2, the components 4, 3, 33, 3
2, 25, 23, 22, 35, 40, 13, and 59 were sequentially added to prepare a composition for blending a hair treatment agent of the present invention.

Example 9 In the same manner as in Example 2, the components 4, 3, 33, 3
2, 25, 23, 22, 35, 37, 39, 16, and 59 were sequentially added to prepare a composition for blending a hair treatment composition of the present invention.

Example 10 In the same manner as in Example 2, each of the components 4, 5, 13, 5
9, 25, and 22 were sequentially added to prepare a composition for blending a hair treatment agent of the present invention.

Example 11 In the same manner as in Example 2, the components 8, 4, 13, 1
4, 25, 22, 3, 38, and 6 are sequentially added,
A composition for blending a hair treatment agent of the present invention was prepared.

Example 12 In the same manner as in Example 2, each of the components 5, 4, 7, 13,
59, 25, 44, 22, and 3 were sequentially added to prepare a composition for blending a hair treatment composition of the present invention.

Example 13 In the same manner as in Example 2, the components 34, 4, 3, 1
3, 23, and 10 were sequentially added to prepare a composition for blending a hair treatment agent of the present invention.

Example 14 In the same manner as in Example 2, each of the components 8, 3, 41, 1
6, 59, 23, 25, and 24 were sequentially added to prepare a composition for blending a hair treatment composition of the present invention.

Example 15 The blending component 59 was heated to 80 ° C., and the blending components 22 and 29 were heated.
, And dissolved by stirring.
Was added and mixed uniformly. Then, with stirring, 45 ° C
Then, the components 52 and 49 were sequentially added and uniformly mixed to prepare a composition for mixing a hair treatment agent of the present invention.

Example 16 Each of the components 25, 57, 12, and 55 was heated to the temperature shown in Table 5 to obtain a homogeneous solution. On the other hand, component 5
3 and 59 (45.9 kg) were heated to the temperatures shown in Table 5 to form aqueous solutions. The heated homogeneous solution is added to the heated aqueous solution with stirring, mixed, and then
Cooled to 45 ° C or less.

Thereafter, the components 36, 51, and 19 were sequentially added to the cooled mixture while confirming that the components were dissolved, and finally, water (replacement water) was added to add a total weight of 1%.
The composition was adjusted to 00 kg and uniformly mixed to prepare a composition for blending a hair treatment agent of the present invention. In Tables 5 and 6,
The compounding component number, the corresponding compounding component, and the compounding weight (kg) are shown.

Example 17 Compounding ingredients 59 (48.78 kg) and 42 were added in an amount of 40 to 50.
The mixture was stirred and mixed at 0 ° C. to prepare a homogeneous solution I. The components 53, 20, and 59 (2.44 kg) were stirred and mixed at 85 ° C. to prepare a homogeneous dissolution II. Ingredient 1
1, 27, 56, 57 and 59 (3.66 kg) to 8
The mixture was stirred and mixed at 5 ° C. to prepare a homogeneous solution III.

[0120] II and III were sequentially added to the homogeneous solution I, and the mixture was stirred and dissolved.
The composition was adjusted to 00 kg and uniformly mixed to prepare a composition for blending a hair treatment agent of the present invention. After confirming that the previously added dissolved substance was uniformly dissolved, the following dissolved substance was added. Tables 5 and 6 show the compounding component numbers, the corresponding compounding components, and the compounding weight (kg).

Example 18 Each of the components 4, 23, 13, and 59 (0.22 kg)
Was heated to the temperature shown in Table 5 to obtain a homogeneous solution. On the other hand, compounding component 59 (88.58 L) was heated to the temperature shown in Table 5. The heated homogeneous solution is added to the heated water with stirring, mixed and emulsified.
Cooled to below 9 ° C.

Thereafter, the components 56 and 57 were sequentially added to the cooled mixture while confirming that the components were dissolved, and finally water (supplemented water) was added to add a total weight of 100 kg.
And the mixture was uniformly mixed to prepare a composition for blending a hair treatment agent of the present invention. Tables 5 and 6 show the compounding component numbers, the corresponding compounding components, and the compounding weights (k
g).

Example 19 After blending component 29 was heated to the temperature shown in Table 5 and uniformly dissolved, blending component 58 (13.33 kg) was added little by little to obtain a melt. On the other hand, after adding the homogeneous mixture of the components 1, 9, and 58 to the above-mentioned melt, the components 48 and 59 are further added, and finally, the component 19 is added and uniformly mixed. A formulation composition was prepared. Table 5
And Table 6 shows the compounding component numbers, the corresponding compounding components, and the compounding weight (kg).

Example 20 In the same manner as in Example 2, the components 59, 48, 19,
46, 9, and 58 were sequentially added to prepare a composition for blending a hair treatment composition of the present invention.

Example 21 Each of the components 43, 1, 12, and 59 (59.43 k
g) was uniformly stirred and mixed at room temperature, and then ingredients 21 and 59 (5.14 kg) were added. Next, this mixture was stirred and mixed at room temperature at 400 mmHg. Then, the ingredients 47 and 59 (2.86 kg) were added, and 4
The composition for mixing a hair treatment agent of the present invention was prepared by stirring and mixing at 00 mmHg. Tables 5 and 6 show the compounding component numbers, the corresponding compounding components, and the compounding weight (kg).

Example 22 The ingredients 59, 19, and 48 were stirred and mixed at room temperature to prepare a homogeneous solution I. Ingredients 9, 1, and 5
8 was stirred and mixed at room temperature to prepare a homogeneous solution II. II was added to the homogeneous solution I, and the mixture was uniformly stirred and mixed. After that, 500mmH
g. The mixture was stirred at room temperature and uniformly mixed to prepare a composition for blending a hair treatment agent of the present invention. Tables 7 and 8 show the compounding component numbers, the corresponding compounding components, and the compounding weights (k
g).

Example 23 Ingredients 19 (47.62 kg) in each of the ingredients 19,
57, 2, 11, and 45 were added sequentially, confirming dissolution. Next, the mixture was stirred at 500 mmHg, and then the blending component 59 (10.95 kg) and the blending component 12 were added.
The composition was adjusted to 0 kg and uniformly mixed to prepare a composition for blending a hair treatment agent of the present invention. Tables 7 and 8 show the compounding component numbers, the corresponding compounding components, and the compounding weight (kg).

Example 24 Melt of Blend Components 43 and 12, Melt of Blend Components 1 and 57, Blend Component 59 (73 kg), Blend Components 21 and 5
9 (4.045 kg), blended ingredients 47 and 59
(3.05 kg) and ingredients 54 and 59
(1.48 kg) was sequentially added while confirming dissolution to prepare a composition for blending a hair treatment agent of the present invention. Tables 7 and 8 show the compounding component numbers, the corresponding compounding components, and the compounding weight (kg).

Example 25 All the ingredients were stirred and mixed to prepare a composition for compounding a hair treatment composition of the present invention. Tables 7 and 8 show the compounding component numbers, the corresponding compounding components, and the compounding weight (kg).

[0130]

[Table 1]

[0131]

[Table 2]

In Table 2, 1) to 11) represent the following. 1) 23EO, 2) 5.87 kg (30EO) +28.
63 kg (40 EO), 3) 5.76 kg (30 EO)
+ 28.74 kg (40 EO), 4) 2.74 kg (2
EO) +72.29 kg (5EO) +1.17 kg (2
0EO), 5) 8.72kg (2EO) + 42.21k
g (6EO) + 2.29kg, 6) 50EO, 7) 50
EO, 8) 8EO, 9) 20EO, 10) 20EO, 1
1) 50EO, 12PO.

[0133]

[Table 3]

In Table 3, 1) and 2) represent the following. 1) Content concentration 43% by weight, 2) Content concentration 40% by weight.

[0135]

[Table 4]

In Table 4, 1) to 8) represent the following. 1) 3EO, 2) 6EO, 3) 1.55kg (30E
O) + 12.45k (40EO), 4) 20.91kg
(20EO) + 9.09kg (40EO), 5) 6E
O, 6) 50EO, 7) 50EO, 12PO, 8) 60
EO.

[0137]

[Table 5]

In Table 5, 1) and 2) represent the following. 1) 3EO, content concentration 43% by weight, 2) content concentration 85% by weight.

[0139]

[Table 6]

In Table 6, 1) to 11) represent the following. 1) 23EO, 2) 0.3kg (30EO) + 1.3k
g (40 EO), 3) 2.2 kg (10 EO) + 2.8
kg (20EO), 4) 40EO, 5) 70EO, 6)
30% by weight, 7) 70% by weight, 8) 50% by weight, 9) 30% by weight, 10) isopropyl paraoxybenzoate, 11) 60% by weight.

[0141]

[Table 7]

In Table 7, 1) and 2) represent the following. 1) Content concentration 85% by weight, 2) 3EO.

[0143]

[Table 8]

In Table 8, 1) to 4) represent the following. 1) 40EO, 2) 4EO, 3) 20EO, 4PO,
4) Content concentration 70% by weight.

(Preparation of Two-Part Treatment) Example 26 Preparation of First Part of Two-Part Treatment A composition for blending a hair conditioner (Example 24) 30
kg of water and 58.85 kg of water were uniformly mixed to prepare Composition I. Further, 7 kg of 1,3-butylene glycol,
A composition II was prepared by uniformly mixing 4 kg of ethanol and 0.15 kg of parabens. The composition II was added to the composition I and uniformly mixed to prepare a first agent.

Preparation of Two-Part Treatment Second Part 9.5 kg of behenyl alcohol, 2.8 kg of stearyltrimethylammonium chloride (60% by weight), 0.2 kg of polyoxyethylene sorbitan monooleate (20EO polymer), 1,3- 2 kg of butylene glycol,
And 0.15 kg of parabens were uniformly stirred and mixed to prepare composition IV.

An aqueous lactic acid solution was prepared from 0.1 kg of 90% lactic acid and 4.9 kg of water. Furthermore, Composition V was prepared by uniformly mixing 3 kg of amino-modified silicone, 2.5 kg of highly polymerized methylpolysiloxane, and 14.5 kg of methylpolysiloxane (20 cs). The composition IV and the aqueous lactic acid solution were heated to 80 to 85 ° C. and stirred and mixed to obtain an emulsion. Thereafter, the mixture was cooled to 45 ° C., the composition V was added, water (water supplement) was added to adjust the total weight to 100 kg, and the mixture was uniformly mixed to prepare a second agent.

(Preparation of Acid Hair Dye) Examples 27 to 35 and 37 A benzyl alcohol-ethanol mixture was added to the hair dye composition (Example 22) at room temperature to make it uniform.
Thereafter, glycolic acid and a fragrance were added as needed.
Next, an aqueous dye solution prepared by dissolving the dye (each of A to I) in an appropriate amount of water at 80 ° C. or higher is added to make the mixture uniform, and finally, water (refilling water) is added to adjust the total weight to 100 kg. Acid hair dye of the present invention (Examples 27 to 3)
5, and 37) were prepared. Tables 9 and 10 show the components and amounts (kg) of the acidic hair dye. Tables 12 and 13 show the composition of the dyes (A to I) used.

Example 36 An acidic hair dye was prepared in the same manner as in Examples 27 to 35 or 37, except that ethanol and benzyl alcohol were not used. Table 10 shows the components and amounts (k
g).

[0150]

[Table 9]

[0151]

[Table 10]

Example 38 Each of the ingredients II to V was added sequentially to the ingredient I uniformly dissolved, and finally water (refilling water) was added to make the total weight 100 k.
g, to prepare an acidic hair dye of the present invention. After confirming that the above blended components were dissolved, the following blended components were added. Ingredient V was prepared by dissolving Dye J in water at 80 ° C or higher. Table 11 shows the composition of each of the components I to V. Table 13 shows the composition of the dye J used.

Example 39 Each of the components II to VI was added to the component I uniformly dissolved.
And water (refilling) is added at the end to make the total weight 100
The acid hair dye of the present invention was prepared by adjusting the amount to be 0.5 kg. After confirming that the above blended components were dissolved, the following blended components were added. The compounding component VI was prepared by dissolving the dye K in water at 80 ° C. or higher. Table 11 shows each of the components I to
The composition of VI is shown. Table 13 shows the composition of the dye K used.

[0154]

[Table 11]

[0155]

[Table 12]

[0156]

[Table 13]

(Preparation of oxidative hair dye) Example 40 Preparation of oxidative hair dye first agent In 60 kg of initial water heated to 80 to 85 ° C., dye intermediates (resorcin, p-phenylenediamine, m-amino) were added. A mixture of phenol and p-aminophenol)
An appropriate amount of an antioxidant was added and stirred to obtain an aqueous solution.

On the other hand, a composition for compounding a hair dye (Example 13)
20 kg was uniformly dissolved at 80 to 85 ° C., added to the heated aqueous solution, and stirred and emulsified. After cooling this emulsion to 45 ° C. while stirring, an appropriate amount of monoethanolamine and 0.17 kg of 60% hydroxyethanediphosphonic acid
Was added thereto, and water (supplemented water) was further added to adjust the total weight to 100 kg to prepare a first agent.

Preparation of Second Agent for Oxidative Hair Coloring Agent 10 kg of a composition for blending a hair coloring agent (Example 13)
The mixture was uniformly dissolved at 5 ° C, added to initial water heated to 80 to 85 ° C, and stirred and emulsified. Next, this emulsion was cooled with stirring to 45 ° C., and 0.17 kg of 60% hydroxyethanediphosphonic acid, 0.26 kg of sodium monohydrogen phosphate (decahydrate), and aqueous hydrogen peroxide (3%) were added.
(5%) 16.9 kg was added, and finally water (refilling water) was added to adjust the total weight to 100 kg to prepare a second agent.

(Preparation of Hair Decoloring Agent) Example 41 Preparation of Hair Decoloring Agent First Agent An appropriate amount of an antioxidant was added to 60 kg of initial water heated to 80 to 85 ° C. and stirred to obtain an aqueous solution.

On the other hand, a composition for compounding a hair dye (Example 13)
20 kg was uniformly dissolved at 80 to 85 ° C., added to the heated aqueous solution, and stirred and emulsified. After cooling this emulsion to 45 ° C. while stirring, an appropriate amount of monoethanolamine and 0.17 kg of 60% hydroxyethanediphosphonic acid
Was added thereto, and water (supplemented water) was further added to adjust the total weight to 100 kg to prepare a first agent.

Preparation of Second Agent for Hair Decoloring Agent A second agent was prepared in exactly the same manner as in Example 40.

(Preparation of Wave Agents) Examples 42 to 48 Preparation of Viscous Liquids (AG) The compositions for mixing the wave agents (Examples 2 to 4, 6, 8, or 9) were prepared at the temperatures shown in Table 14. Until homogeneously dissolved. On the other hand, the initial water (and to which sodium dehydroacetate was added if necessary) was heated to the temperature shown in Table 14.
The heated uniform solution was added to the heated initial water (or aqueous solution) with stirring, and mixed uniformly.

After cooling the homogeneous mixture to the temperature shown in Table 14 while stirring, water (water supplement) was added to make the total weight
, And uniformly mixed to prepare viscous liquids of each concentration. Table 14 shows the heating / cooling temperature, blending components, blending amount (kg), and viscous liquid concentration (% by weight).

[0165]

[Table 14]

Preparation of the first part of the waving agent To the viscous liquids (A to G) obtained above, 50% ammonium thioglycolate (ATG) or cysteine, strong aqueous ammonia and, if necessary, monoethanolamine were added at room temperature. And add water (refilling) to make the total weight 100k
g, and uniformly mixed to prepare a first agent for a wave agent (Examples 42 to 48). Table 15 shows the components and the amount (kg).

[0167]

[Table 15]

In Table 15, 1) represents a 28% by weight aqueous solution. Preparation of second agent for waving agent 1 kg of lauryltrimethylammonium chloride, 8 kg of sodium bromate and water are added, and the total weight is 100 kg.
Aqueous solution. This aqueous solution was used as the second agent of the wave agent of each of Examples 42 to 48.

Examples 49 and 50 Preparation of first agent for waving agent The composition for mixing a waving agent (Example 11 or 12), which was heated to the temperature shown in Table 16 and uniformly dissolved, was heated to the temperature shown in Table 16. The mixture was added to the heated initial water and stirred and emulsified. The emulsion was cooled to the temperature shown in Table 16 and 50% ATG,
MEA and, if necessary, a composition for blending a wave agent (Example 17) were added, and water (rehydration) was further added to make the total weight 1
The first preparation was prepared by adjusting the weight to 00 kg. Table 16 shows the components and amounts (kg).

Preparation of Second Agent for Waving Agent The composition for mixing the waving agent (Example 11 or 12) is shown in Table 1.
The mixture was heated to the temperature shown in FIG. On the other hand, sodium bromate was added to the initial water and heated to the temperature shown in Table 16 to obtain an aqueous solution. Next, the homogeneous solution was added to the aqueous solution, and the mixture was stirred and emulsified.

This emulsion was cooled to the temperature shown in Table 16 and, if necessary, a composition for compounding a waving agent (Example 17).
And water (refilling) is added to make the total weight 100 kg
To prepare a second agent. In Table 16,
Shows the ingredients and amount (kg).

Example 51 Preparation of first agent for waving agent Composition for blending waving agent (Example 15), 50% AT
G, strong ammonia water, and the total weight of the waving agent to 100
kg of water, stirred at room temperature and homogeneously mixed,
A first waving agent was prepared. Table 16 shows the components and amounts (kg).

Preparation of the second agent for the waving agent The composition for mixing the waving agent (Example 17), sodium bromate, lauryltrimethylammonium chloride, and water in an amount to make the total weight of the waving agent 100 kg were stirred at room temperature. The resulting mixture was uniformly mixed to prepare a second agent for the waving agent.
Table 16 shows the components and amounts (kg).

Example 52 Preparation of first agent for waving agent Same as Example 51 except that the composition for waving agent mixing (Example 16) was used instead of the composition for waving agent mixing (Example 15) To prepare a first wave agent.
Table 16 shows the components and amounts (kg).

Preparation of second agent for waving agent 1 kg of lauryltrimethylammonium chloride, 8 kg of sodium bromate and water were added, and the total weight was 100 kg.
As an aqueous solution of the above, a second agent for the wave agent was prepared.

[0176]

[Table 16]

(Preparation of Finishing Agent) Example 53 The ingredients I to IV were added to the ingredients I uniformly dissolved.
Were successively added to prepare a finish of the present invention. After confirming that the above blended components were dissolved, the following blended components were added. Table 17 shows the composition of each of the components I to IV.

Example 54 III was added to the blending component II, and the mixture was stirred and mixed at 90 ° C., and then the blending component I heated to 90 ° C. was added and uniformly stirred and mixed. Then, it is cooled down to 70 ° C, and finally water
Was added to adjust the total weight to 100 kg to prepare a finish of the present invention. After confirming that the above blended components were dissolved, the following blended components were added. Table 17 shows the composition of each of the components I to III.

[0179]

[Table 17]

(Preparation of feel improving agent) Example 55 The composition for blending a feel improving agent (Example 17) was used as it was as a feel improving agent. That is, 10 kg of this feel enhancer (Example 17) was added to 90 kg of the wave agent (Example 50).
, And stirred uniformly to prepare a new waving agent.

Next, using this new waving agent, 50 test subjects were subjected to hair treatment in accordance with the following waving agent hair treatment method, and were subjected to a sensory evaluation.
Table 19 shows the results of the sensory evaluation.

(Preparation of Hair Removal Agent) Example 56 80-85 ° C. was added to 45 kg of initial water heated to 80-85 ° C.
10 kg of a composition for blending a hair remover (Example 14), which was heated and uniformly dissolved at a temperature of 10 ° C., was added with stirring to obtain an emulsion.
After cooling this emulsion to 55 ° C., 3 kg of urea, 6 kg of calcium thioglycolate and 20 kg of water were added. Further, after cooling to 45 ° C., 10 kg of a 10% aqueous sodium hydroxide solution was added, and finally, water (rehydration) was added to adjust the total weight to 100 kg, thereby preparing a hair remover of the present invention.

(Sensory Evaluation on Hair Treatment Effect of Hair Treatment Agent) Hair treatment was carried out on 50 test subjects by the following method, and the hair treatment effect (feel of use and characteristics) of the hair treatment agent was used. I had a sensory evaluation. Table 1 shows the evaluation results.
8 and Table 19.

Hair treatment method for hair conditioner After normal shampooing, two-part treatment (Example 2)
The first agent of 6) was applied to the hair, and then the second agent was applied, and then rinsed and dried with a dryer.

Hair treatment method of hair dye In the case of using an acidic hair dye, apply an acidic hair dye (Examples 27 to 39) to the hair,
After heating at 5 ° C. for 15 minutes, it was rinsed and dried with a dryer.

When an oxidative hair dye or a hair bleaching agent is used The first agent and the second agent of the hair dye (Example 40 or 41) are mixed at a ratio of 1: 1 (weight ratio), and this is mixed with the hair. Was applied. Then, after leaving at room temperature for 30 minutes, it was rinsed and dried with a dryer.

Hair treatment method of waving agent In the case of permanent giving wave Waving agent (Examples 42 to 48, 52) The first agent is applied to hair, combed and spread, hair is wound on a rod, and room temperature is maintained for 7 minutes. Left at Next, the second agent was applied with an applicator and allowed to stand for 7 minutes, and then the second agent was applied again with an applicator and allowed to stand for 7 minutes. Thereafter, the rod was removed, rinsed and dried with a dryer.

In the case of straight perm The first agent was applied to the hair and combed to spread the hair, so that the hair was straightened. Then, it was left for 10 minutes. Next, the second agent was applied to the hair, combed, allowed to spread, and left for 10 minutes. Finally, it was rinsed and dryer dried.

Hair treatment method of finishing agent The finishing agent (Examples 53 and 54) was applied to the hair and allowed to spread.

Hair treatment method of hair remover A hair remover (Example 56) was applied to the skin, left for 15 minutes, wiped off with absorbent cotton, and then washed with water.

[0191]

[Table 18]

[0192]

[Table 19]

In Tables 18 and 19, ◎ is very good;
Is good and △ is normal. As is clear from the results in Tables 18 and 19, the hair treatment composition of the present invention is excellent in light oiliness, slipperiness, softness, crispness, luster, and feeling of use for hair, and is excellent in use feeling. Adhesion, elongation,
Wettability, resistance to dripping, ease of application (applicability), ease of retouching (operability of retouching), formation of firm waves without spots, and low irritating odor (for example, ammonia odor) It shows that it has excellent properties such as rapid wave formation, low residual odor after wave treatment, excellent appearance of the treatment agent (for example, high-quality silky touch appearance), and low skin irritation. .

[0194]

The composition for compounding a hair treating agent of the present invention is prepared by appropriately selecting and combining inexpensive and easily available compounding ingredients so as to exert an excellent hair treating effect. Therefore, the composition for compounding a hair treatment agent of the present invention can be easily produced at low cost. Since the hair treatment composition of the present invention is prepared from the above composition, it is inexpensive, and is excellent in feeling of use such as light oiliness, slipperiness, softness, crispness, gloss, feel to hair, and treatment. Adhesiveness, elongation, wettability, resistance to dripping, ease of application (applicability), ease of retouching (operability of retouching), firm wave formation without stinging, strong odor ( Low ammonia smell), rapid wave formation, low residual odor after wave treatment, excellent appearance of treatment agent (eg high-quality silky touch appearance), low skin irritation, etc. Excellent characteristics. Further, in the production process of the hair treatment agent, (I) alcohols and (II)
One selected from the group consisting of an anionic surfactant, an inorganic acid, and an inorganic alkali agent can be compounded together, and the process can be greatly simplified.

Claims (10)

[Claims] 1. A hair treatment agent compounding composition comprising (I) an alcohol and (II) at least one selected from the group consisting of an anionic surfactant, an inorganic acid, and an inorganic alkali agent. Composition. 2. The method according to claim 1, wherein the alcohol is ethanol, isopropanol, lauryl alcohol, cetanol, stearyl alcohol, oleyl alcohol, behenyl alcohol, cetostearyl alcohol, benzyl alcohol,
Propylene glycol, 1,3-butylene glycol,
And at least one compound selected from the group consisting of glycerin, wherein the anionic surfactant is sodium lauryl sulfate, triethanolamine lauryl sulfate, sodium cetyl sulfate,
At least one compound selected from the group consisting of sodium myristoylmethyltaurate, triethanolamine polyoxyethylene lauryl ether sulfate, and polyoxyethylene oleyl ether phosphoric acid, wherein the inorganic acids are phosphoric acid and / or sodium monohydrogen phosphate The composition according to claim 1, wherein the inorganic alkali agent is sodium hydroxide. 3. The method according to claim 1, wherein the alcohol is at least one compound selected from the group consisting of lauryl alcohol, cetanol, and glycerin.
Or the composition for compounding a hair treatment agent according to claim 2. 4. The composition according to claim 1, wherein the anionic surfactant is sodium lauryl sulfate. 5. The composition for blending a hair treatment agent, further comprising a nonionic surfactant, an oil or fat, a hydrocarbon, a polymer, an organic acid, an organic base, an amphoteric surfactant, a sequestering agent,
The hair treatment composition according to any one of claims 1 to 4, further comprising at least one selected from the group consisting of hydrolyzed collagen, fragrance, parabens, nitrogen-containing solvent, and water. Composition. 6. The nonionic surfactant is polyoxyethylene lauryl ether, polyoxyethylene cetyl ether, polyoxyethylene stearyl ether, polyoxyethylene oleyl ether, polyoxyethylene nonyl phenyl ether, polyoxyethylene castor oil, polyoxyethylene. Hardened castor oil, polyoxyethylene lanolin, polyoxyethylene coconut oil alkylamine, polyoxyethylene / polyoxypropylene cetyl ether, polyoxyethylene / polyoxypropylene lanolin, oleic acid diethanolamide, stearic acid diethanolamide, polytetraoleic acid At least one compound selected from the group consisting of oxyethylene sorbit and coconut oil alkyldimethylamine oxide, wherein the fats and oils are Foam oil, olive oil, shea butter,
And mink wax, wherein the hydrocarbons are liquid paraffin, and the polymers are dimethyldiallylammonium chloride.
Acrylamide copolymer, hydroxyethyl cellulose, polypropylene glycol, carboxyvinyl polymer, and at least one compound selected from the group consisting of polyoxypropylene methyl glucoside,
The organic acid is glycolic acid and / or tartaric acid, the organic base is triethanolamine, and the amphoteric surfactant is 2-alkyl-N-carboxymethyl-N-hydroxyethylimidazolinium betaine and / or coconut oil fatty acid. Amidopropyl betaine, the sequestering agent is hydroxyethanediphosphonic acid and / or disodium edetate, the fragrance is orange oil, and the parabens are propyl paraoxybenzoate, isopropyl paraoxybenzoate, and paraoxybenzoic acid. The hair treating composition according to claim 5, which is at least one compound selected from the group consisting of methyl, and the nitrogen-containing solvent is N-methylpyrrolidone. 7. The composition of the composition for formulating a hair treatment composition, wherein the content of the alcohol (I) is A% by weight and is selected from the group consisting of an anionic surfactant, an inorganic acid, and an inorganic alkali agent. Assuming that the content of at least one (II) is B wt%, A and B are represented by the following formula: 0.1 ≦ A ≦ 9
The composition according to any one of claims 1 to 6, wherein the composition satisfies 0, 0.05 ≤ B ≤ 65, and A + B ≤ 100. 8. A composition for blending a hair treatment agent, a composition for blending a hair conditioner, a composition for blending a hair dye, a composition for blending a waving agent, a composition for blending a finishing agent, a composition for blending a feel improving agent, 8. The composition for blending a hair treatment agent according to claim 1, which is a composition for blending a hair remover. 9. A hair treatment agent comprising the composition for compounding a hair treatment agent according to claim 1. 10. A hair conditioner comprising: a hair conditioner;
The hair treatment agent according to claim 9, which is a hair dye, a waving agent, a finishing agent, a feel improving agent, or a hair remover.