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JP2001288548A - Method for removing dross in hot dip metal coating bath and hot dip metal coating apparatus - Google Patents

Method for removing dross in hot dip metal coating bath and hot dip metal coating apparatus

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Publication number
JP2001288548A
JP2001288548A JP2000098663A JP2000098663A JP2001288548A JP 2001288548 A JP2001288548 A JP 2001288548A JP 2000098663 A JP2000098663 A JP 2000098663A JP 2000098663 A JP2000098663 A JP 2000098663A JP 2001288548 A JP2001288548 A JP 2001288548A
Authority
JP
Japan
Prior art keywords
dross
plating
tank
bath
plating solution
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
JP2000098663A
Other languages
Japanese (ja)
Other versions
JP4238457B2 (en
Inventor
Makoto Yamaguchi
誠 山口
Takefumi Kametani
岳文 亀谷
Kazunari Adachi
一成 安達
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
JFE Steel Corp
Original Assignee
Kawasaki Steel Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Kawasaki Steel Corp filed Critical Kawasaki Steel Corp
Priority to JP2000098663A priority Critical patent/JP4238457B2/en
Publication of JP2001288548A publication Critical patent/JP2001288548A/en
Application granted granted Critical
Publication of JP4238457B2 publication Critical patent/JP4238457B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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Abstract

PROBLEM TO BE SOLVED: To provide a method of removing dross in a hot dip metal coating bath by which the dross in the hot dip metal coating bath is effectively removed with a simple device and the recovering work of the dross and the maintenance of this device are easily performed, and a hot dip metal coating apparatus. SOLUTION: In the method of removing the dross in the hot dip metal coating bath in the case of continuously applying a hot dip metal coating, as a dross removing vessel 10, the dross removing vessel 10 having coating metal liquid inflow port 11, plural baffles 13, 14 for separating the dross with the specific gravity and a coating metal liquid outflow port 15, is used. Then, the dross removing vessel 10 is dipped into the hot dip metal coating bath 1, and the coating metal liquid is introduced into the dross removing vessel 10 from the coating metal liquid inflow port 11 by using the flow F of the coating metal liquid developed with the rotation of a sink roll 3 in the bath as the driving force, and is made to pass through the lower part or the upper part of plural baffles 13, 14, and after separating the dross with the specific gravity, the coating metal liquid is recirculated from the coating metal liquid outflow port 15 into the hot dip metal coating bath 1 to remove the dross in the hot dip metal coating bath.

Description

【発明の詳細な説明】DETAILED DESCRIPTION OF THE INVENTION

【0001】[0001]

【発明の属する技術分野】本発明は、鋼帯の連続溶融金
属めっきにおいて、簡易な装置で、めっき浴中のドロス
を効果的に除去し、かつ、ドロスの回収作業が容易で装
置の保守性に優れた溶融金属めっき浴中のドロス除去方
法および溶融金属めっき装置に関する。
BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a continuous apparatus for continuous hot-dip metal plating of steel strips, which effectively removes dross from a plating bath with a simple apparatus, facilitates the dross recovery operation, and facilitates maintenance of the apparatus. TECHNICAL FIELD The present invention relates to a method for removing dross from a hot-dip metal plating bath and a hot-dip metal plating apparatus having excellent heat resistance.

【0002】[0002]

【従来の技術】図8に、従来の鋼帯の連続溶融金属めっ
き装置を縦断面図によって示す。なお、図8において、
1は溶融金属であるめっき浴、2はめっき用ポット、3
はめっき浴1中に配設されたシンクロール(以下、浴中
シンクロールまたはシンクロールと記す)、4は鋼帯、
5はスナウト、f1は鋼帯の搬送方向(通板方向)、f2
シンクロールの回転方向を示す。
2. Description of the Related Art FIG. 8 is a longitudinal sectional view of a conventional continuous strip metal plating apparatus for a steel strip. In FIG. 8,
1 is a plating bath which is a molten metal, 2 is a plating pot, 3
Is a sink roll disposed in the plating bath 1 (hereinafter referred to as a sink roll or sink roll in the bath), 4 is a steel strip,
5 snout, f 1 is the transport direction of the steel strip (sheet passing direction), f 2 represents the rotation direction of the sink roll.

【0003】すなわち、鋼帯の連続溶融金属めっき装置
においては、鋼帯を溶融金属であるめっき浴1中に連続
的に侵入させ、シンクロール3を周回後、方向転換し、
めっき浴1液面より上方へ引き上げて連続的にめっきを
施す。以下、溶融金属めっきにおける従来技術を、鋼帯
の連続溶融金属めっきの代表例である溶融亜鉛めっきを
例として説明する。
That is, in a continuous strip metal plating apparatus for a steel strip, the steel strip is continuously penetrated into a plating bath 1 which is a molten metal, and after turning around a sink roll 3, the direction is changed.
The plating bath 1 is pulled up from the liquid level to perform plating continuously. Hereinafter, a conventional technique in hot-dip metal plating will be described by taking hot-dip galvanizing, which is a typical example of continuous hot-dip metal plating of a steel strip, as an example.

【0004】現在、溶融亜鉛めっきラインにおいては、
一般的に、めっきしたままの通常の溶融亜鉛めっき鋼板
と、溶融亜鉛めっき後、合金化処理を施す合金化溶融亜
鉛めっき鋼板を、同一ラインで適宜処理を切り替えるこ
とにより製造している。この内、合金化溶融亜鉛めっき
鋼板は、耐食性、溶接性および加工性に優れた特性を有
するため、主に自動車用鋼板として広く使用されている
が、特に外装用鋼板として使用される場合には、塗装後
の高鮮映性も要求されるなど、品質に対する要求が益々
厳しくなっている。
At present, in a hot-dip galvanizing line,
Generally, a normal hot-dip galvanized steel sheet as-plated and an alloyed hot-dip galvanized steel sheet which is subjected to an alloying process after hot-dip galvanizing are manufactured by appropriately switching the processing on the same line. Among them, alloyed hot-dip galvanized steel sheet is widely used mainly as a steel sheet for automobiles because it has excellent properties of corrosion resistance, weldability and workability, but especially when used as an exterior steel sheet. Demands for quality are becoming more and more severe, such as the requirement for high definition after painting.

【0005】かかる状況下において、溶融亜鉛めっきポ
ット内では、鋼帯(以下ストリップとも記す)から溶出
するFeとZnが反応して、FeZn7 を主成分とするボトムド
ロスが生成し、めっきポット内の底部に堆積する。ま
た、めっき液中のAlとFeが反応しFe2Al5を主成分とする
浮上ドロスが生成し、めっき浴上に浮上する。
[0005] Under these circumstances, in the hot-dip galvanizing pot, Fe and Zn eluted from a steel strip (hereinafter also referred to as a strip) react with each other to form bottom dross containing FeZn 7 as a main component. Deposits on the bottom. Further, Al and Fe in the plating solution react with each other to generate floating dross mainly composed of Fe 2 Al 5 and float on the plating bath.

【0006】この場合、ボトムドロスは、めっき浴中の
シンクロールを周回して搬送されるストリップの随伴流
であるめっき液に巻き上げられてストリップに付着す
る。また、浮上ドロスは再度めっき液中に一部巻き込ま
れ、上記と同様にストリップに付着する。この結果、製
造されためっき鋼板のプレス時に、プレスブツと称する
表面不均一部分が生じ、鮮映性が損なわれるばかりでな
く、付着ドロスが金型に損傷を与えるという問題があ
る。
In this case, the bottom dross is wound up by the plating solution, which is an accompanying flow of the strip conveyed around the sink roll in the plating bath, and adheres to the strip. Further, the floating dross is partially involved in the plating solution again and adheres to the strip in the same manner as described above. As a result, when the manufactured plated steel sheet is pressed, a non-uniform surface portion called a press spot occurs, which not only impairs the sharpness but also causes a problem that the attached dross damages the mold.

【0007】上記した問題を解決するため、特開平6−
248405号公報において、溶融亜鉛めっき浴中に、取り外
し可能な槽からなるドロス除去装置を設置し、ポンプに
よって浴内の溶融亜鉛を吸い上げ、槽の上部側壁に設け
た流入口から槽内に流入せしめ、槽内に配設した複数枚
の邪魔板によってドロスを沈降させた後、溶融亜鉛を槽
の上部側壁に接続した返送管から浴内に返送することに
よってめっき浴中のドロスを除去するドロスの除去方法
および装置が開示されている。
In order to solve the above-mentioned problem, Japanese Patent Laid-Open No.
In Japanese Patent No. 248405, a dross removing device comprising a removable tank is installed in a hot-dip galvanizing bath, and the molten zinc in the bath is sucked up by a pump, and the molten zinc is introduced into the bath from an inlet provided in an upper side wall of the bath. After the dross is settled by a plurality of baffles arranged in the tank, the dross in the plating bath is removed by returning the molten zinc into the bath from a return pipe connected to the upper side wall of the tank. A removal method and apparatus are disclosed.

【0008】しかしながら、上記した方法は、下記、
の問題を有している。 ポンプの交換および配管の閉塞:浴内の溶融亜鉛を吸
い上げ、ドロス除去装置の槽内に流入せしめるために、
回転翼などを用いたポンプが必要となる。この結果、ポ
ンプおよび配管が亜鉛もしくはドロスによって閉塞もし
くは破損することが避けられず、ポンプの交換および配
管中の閉塞物の除去など装置の保守が必要となる。
[0008] However, the above method is as follows:
Problem. Replacement of pump and blockage of piping: In order to suck up molten zinc in the bath and allow it to flow into the tank of the dross removing device,
A pump using a rotary wing or the like is required. As a result, it is inevitable that the pump and the piping are clogged or damaged by zinc or dross, and maintenance of the device such as replacement of the pump and removal of the clogging material in the piping is required.

【0009】めっき鋼板への比重の軽いドロスの付
着:前記したように、めっき鋼板の付着ドロスとして
は、溶融亜鉛より比重の重いFe-Zn 系のドロスと溶融亜
鉛より比重の軽いFe-Al 系のドロスの両者が生成する。
これに対して、上記したドロスの除去方法、除去装置の
場合、その構成上、除去装置の槽が密閉式の構造とな
り、比重の軽いFe-Al 系のドロスの分離が不可能であ
り、Fe-Al 系のドロスが浴中に再循環され、前記しため
っき鋼板へのドロス付着による問題を解決することがで
きない。
Attachment of dross having a low specific gravity to a plated steel sheet: As described above, the dross adhered to a plated steel sheet includes Fe-Zn-based dross having a higher specific gravity than molten zinc and Fe-Al-based dross having a specific gravity lower than molten zinc. Both of the dross are generated.
On the other hand, in the case of the dross removing method and the removing device described above, the tank of the removing device has a hermetic structure due to its configuration, and it is impossible to separate Fe-Al dross having a low specific gravity. -Al-based dross is recirculated in the bath, making it impossible to solve the above-mentioned problem caused by the dross adhering to the plated steel sheet.

【0010】特開平4−52257 号公報では、めっきポッ
ト底部の一部にドロス溜まりを設け、該ドロス溜まりが
設けられた空間とシンクロールが設けられた空間とを遮
断する開閉自在な開口を有する遮断部材を設け、該遮断
部材の作用により、ドロス溜まりに堆積したボトムドロ
スがめっき浴中を浮遊してストリップ表面に付着するこ
とを防止する方法が提案されている。
In Japanese Patent Application Laid-Open No. 4-52257, a dross reservoir is provided at a part of the bottom of a plating pot, and an opening which can be opened and closed to shut off a space in which the dross reservoir is provided and a space in which a sink roll is provided. A method has been proposed in which a blocking member is provided to prevent bottom dross accumulated in the dross pool from floating in the plating bath and adhering to the strip surface by the action of the blocking member.

【0011】また、特開昭55−128569号公報では、めっ
きポット内を、上部に開閉可能な開口を有し下部が解放
された隔壁によりめっき用槽と反応用槽とに2分割し、
前記めっき用槽の底部を反応用槽に向かうにつれて下降
する傾斜面とすることで、反応用槽内にボトムドロスを
導き入れ、反応用槽内の撹拌機を運転することでボトム
ドロスを浮上させてトップドロスとして回収する方法が
提案されている。
In Japanese Patent Application Laid-Open No. 55-128569, the inside of a plating pot is divided into a plating tank and a reaction tank by a partition having an openable upper opening and a lower opening.
By making the bottom of the plating tank an inclined surface that descends toward the reaction tank, the bottom dross is introduced into the reaction tank, and the bottom dross is lifted up by operating the stirrer in the reaction tank. A method of recovering as a dross has been proposed.

【0012】しかしながら、特開平4−52257 号公報で
提案された方法の場合、シンクロールが設けられた空間
を開閉自在な遮断部材で囲むことは、現実的にはスナウ
トが障害となって設置スペースを確保するのが困難であ
り、また浴面に浮遊しているトップドロスを掻き寄せて
除去・回収する作業を著しく困難にするなどの問題があ
り現実的でない。
However, in the case of the method proposed in Japanese Patent Application Laid-Open No. 4-52257, enclosing the space in which the sink rolls are provided with an openable and closable blocking member is not practical because the snout becomes an obstacle and the installation space is reduced. It is difficult to secure the top dross floating on the bath surface, and it is extremely difficult to remove and collect the top dross.

【0013】また、特開昭55−128569号公報で提案され
た方法の場合、めっき用槽の傾斜底面によりボトムドロ
スを反応用槽内に導き入れることは可能だが、解放され
たままの隔壁下部の開口および隔壁上部の開口から反応
用槽内で撹拌されたボトムドロスがめっき用槽内へ入り
込むため、ドロス付着防止効果が不十分であるという問
題があった。
In the case of the method proposed in Japanese Patent Application Laid-Open No. 55-128569, the bottom dross can be guided into the reaction tank by the inclined bottom surface of the plating tank, but the bottom dross at the bottom of the partition wall which is open remains. Since the bottom dross stirred in the reaction tank enters the plating tank through the opening and the opening above the partition wall, there is a problem that the dross adhesion preventing effect is insufficient.

【0014】[0014]

【発明が解決しようとする課題】本発明は、前記した従
来技術の問題点を解決し、連続溶融金属めっきにおい
て、簡易な装置で、めっき浴中のドロスを効果的に除去
し、かつ、ドロスの回収作業が容易で装置の保守性に優
れた溶融金属めっき浴中のドロス除去方法および溶融金
属めっき装置を提供することを目的とする。
SUMMARY OF THE INVENTION The present invention solves the above-mentioned problems of the prior art, and in a continuous hot-dip metal plating, dross in a plating bath is effectively removed by a simple apparatus, and dross is removed. It is an object of the present invention to provide a method for removing dross in a hot-dip metal plating bath and a hot-dip metal plating apparatus, which can easily recover the molten metal and have excellent maintainability of the apparatus.

【0015】[0015]

【課題を解決するための手段】第1の発明は、鋼帯を溶
融金属であるめっき浴1中に連続的に侵入させ、浴中シ
ンクロール3を周回後、方向転換し、めっき浴1液面よ
り上方へ引き上げて連続的にめっきを施す溶融金属めっ
きにおけるドロス除去槽10を用いた溶融金属めっき浴中
のドロス除去方法であって、前記ドロス除去槽10とし
て、槽内へのめっき液流入口11と、槽内に設けられかつ
板面が上下方向に配設されたドロス比重分離用の複数枚
の邪魔板13、14と、槽内からのめっき液流出口15を有す
るドロス除去槽10を用いると共に、該ドロス除去槽10を
めっき浴1に浸漬し、めっき液を、浴中シンクロール3
の回転によって生じるめっき液の流れFを駆動力として
前記めっき液流入口11から前記ドロス除去槽10内に導入
し、前記複数枚の邪魔板13、14のそれぞれの下方または
上方を通過せしめ、めっき液中のドロスを比重分離した
後、前記めっき液流出口15からめっき浴1中に再循環す
ることを特徴とする溶融金属めっき浴中のドロス除去方
法である。
According to a first aspect of the present invention, a steel strip is continuously intruded into a plating bath 1 which is a molten metal, and after turning around a sink roll 3 in the bath, the direction is changed and a plating bath 1 solution is formed. A dross removing method in a molten metal plating bath using a dross removing tank 10 in a molten metal plating in which plating is continuously performed by being pulled up from a surface, wherein the dross removing tank 10 includes a plating solution flowing into the tank. A dross removal tank 10 having an inlet 11, a plurality of baffles 13 and 14 for dross specific gravity separation provided in the tank and having a plate surface arranged vertically, and a plating solution outlet 15 from the inside of the tank. The dross removing tank 10 is immersed in the plating bath 1 and the plating solution is applied to the sink roll 3 in the bath.
The flow F of the plating solution generated by the rotation of the plating solution is introduced into the dross removing tank 10 from the plating solution inlet 11 as a driving force, and passes below or above each of the plurality of baffle plates 13 and 14 to form a plating solution. A dross removal method for a molten metal plating bath, comprising dross in a solution is separated into specific gravity and then recirculated through the plating solution outlet 15 into the plating bath 1.

【0016】前記した第1の発明においては、前記ドロ
ス除去槽10の前記めっき液流入口11に、ドロス除去槽10
内へのめっき液流入量調整用の可動整流板12を取り付
け、該可動整流板12によってドロス除去槽10内へのめっ
き液流入量を調整することが好ましい(第1の発明の好
適態様)。第2の発明は、鋼帯を溶融金属であるめっき
浴1中に連続的に侵入させ溶融金属めっきを施すめっき
用ポット2と、鋼帯を方向転換させめっき浴1液面より
上方へ引き上げるための浴中シンクロール3と、溶融金
属めっき浴中のドロスを除去するためのドロス除去槽10
を有する溶融金属めっき装置であって、前記ドロス除去
槽10として、槽内へのめっき液流入口11と、該めっき液
流入口11に設けられた槽内へのめっき液流入量調整用の
可動整流板12と、槽内に設けられかつ板面が上下方向に
配設されたドロス比重分離用の複数枚の邪魔板13、14
と、槽内からのめっき液流出口15を有するドロス除去槽
10を用い、該ドロス除去槽10をめっき浴1に浸漬配置す
ると共に、前記めっき液流入口11を、前記めっき液流出
口15に対して浴中シンクロール3の回転によって生じる
めっき液の流れの上流側に配置したことを特徴とする溶
融金属めっき装置である。
In the first aspect, the dross removing tank 10 is connected to the plating solution inlet 11 of the dross removing tank 10.
It is preferable to attach a movable rectifying plate 12 for adjusting the amount of plating solution flowing into the inside, and adjust the amount of plating solution flowing into the dross removing tank 10 by the movable rectifying plate 12 (a preferred embodiment of the first invention). A second invention is to provide a plating pot 2 for continuously intruding a steel strip into a plating bath 1 which is a molten metal to apply a molten metal plating, and to change the direction of the steel strip and pull it upward from a liquid level of the plating bath 1. Bath roll 3 and a dross removing tank 10 for removing dross from the hot-dip metal plating bath.
A dipping removal tank 10, a plating solution inflow port 11 into the tank, and a movable for adjusting a plating solution inflow amount into a tank provided at the plating solution inflow port 11. Rectifying plate 12, and a plurality of baffle plates 13 and 14 for dross specific gravity separation provided in the tank and having plate surfaces arranged in the vertical direction.
And a dross removing tank having a plating solution outlet 15 from inside the tank
10, the dross removing tank 10 is immersed in the plating bath 1, and the plating solution inlet 11 is connected to the plating solution outlet 15 by the rotation of the sink roll 3 in the bath. This is a hot-dip metal plating apparatus that is arranged on the upstream side.

【0017】前記した第2の発明においては、前記めっ
き液流出口15を、該めっき液流出口15の開口部最下端の
位置が、ドロス除去槽10内の槽底から100mm 以上の高さ
の位置となるように配置することが好ましい。また、前
記した第2の発明においては、前記めっき液流出口15
を、該めっき液流出口15の開口部最下端の位置が、ドロ
ス除去槽10内の槽底から100mm 以上の高さの位置で、か
つ、ドロス除去槽10内のめっき液液面の高さおよびドロ
ス除去槽10槽外のめっき浴1浴面の高さの両者よりも低
い高さの位置となるように配置することが好ましい。
In the second aspect of the present invention, the plating solution outlet 15 is positioned such that the lowermost position of the opening of the plating solution outlet 15 is at least 100 mm above the bottom of the dross removing tank 10. It is preferable to arrange them so as to be located at positions. In the second invention, the plating solution outlet 15 is provided.
The position of the lowermost end of the opening of the plating solution outlet 15 is at a position of 100 mm or more from the bottom of the dross removing tank 10, and the height of the plating solution level in the dross removing tank 10. It is preferable that the height is lower than both of the plating bath 1 and the bath surface outside the dross removing tank 10.

【0018】また、前記した第2の発明においては、前
記複数枚の邪魔板13、14の少なくとも一枚を取り外し可
能な構造とすることが好ましい。さらに、前記した第2
の発明においては、前記ドロス除去槽10を一体としてめ
っき浴1から引き上げ可能な構造とすることが好まし
い。なお、前記した第1の発明の好適態様、第2の発明
における前記可動整流板12としては、前記ドロス除去槽
10のめっき液流入口11に設けられ、めっき液の流れに対
して抵抗を与える面を有し、めっき浴1内のめっき液を
ドロス除去槽10内に導入すると共に、上記した面が傾動
および/または移動することが可能な可動部材であれば
その形状、構造は特に制限を受けるものではない。
In the second aspect of the present invention, it is preferable that at least one of the plurality of baffle plates 13 and 14 has a removable structure. Further, the second
In the present invention, it is preferable that the dross removing tank 10 is integrated with the plating bath 1 so as to be able to be pulled up from the plating bath 1. In the preferred embodiment of the first invention and the movable baffle 12 in the second invention, the dross removing tank is used.
10 is provided at the plating solution inflow port 11 and has a surface that gives resistance to the flow of the plating solution. The plating solution in the plating bath 1 is introduced into the dross removing tank 10, and the surface tilts and The shape and structure of the movable member are not particularly limited as long as it is movable.

【0019】[0019]

【発明の実施の形態】以下、本発明をさらに詳細に説明
する。本発明者らは前記した課題を解決するために、図
6に示す槽内に複数枚の邪魔板32、33を各々上下方向に
取り付けたドロス除去槽30を用い、ドロス除去槽内の溶
融亜鉛31の流量を変化させ、ドロスの比重分離実験を行
った。
BEST MODE FOR CARRYING OUT THE INVENTION Hereinafter, the present invention will be described in more detail. In order to solve the above-mentioned problem, the present inventors used a dross removing tank 30 in which a plurality of baffle plates 32 and 33 were vertically mounted in a tank shown in FIG. The specific gravity separation experiment of dross was performed by changing the flow rate of 31.

【0020】図7に、得られた結果を示す。なお、図7
に示す溶融亜鉛の流量は、溶融亜鉛中の粒子の移動速
度、溶融亜鉛の流れと直交する槽内断面の面積および溶
融亜鉛の密度から求め、ドロス除去効率:ηは下記式
(1) から求めた。 ドロス除去効率:η=〔(A−B)/A〕×100 %………(1) なお、上記式(1) 中、 A:ドロス除去槽入口の溶融亜鉛中の粒子径≧20μm の
粒子の個数 B:ドロス除去槽出口の溶融亜鉛中の粒子径≧20μm の
粒子の個数 を示し、上記した個数は、ドロス除去槽入口、出口の溶
融亜鉛をサンプリングし、凝固後の亜鉛の断面の観察に
よって測定した。
FIG. 7 shows the obtained results. FIG.
Is determined from the moving speed of particles in the molten zinc, the area of the cross section inside the tank orthogonal to the flow of the molten zinc, and the density of the molten zinc.
Determined from (1). Dross removal efficiency: η = [(AB) / A] × 100% (1) In the above formula (1), A: particles having a particle diameter of ≧ 20 μm in the molten zinc at the entrance of the dross removal tank. B: The number of particles having a particle diameter of ≧ 20 μm in the molten zinc at the outlet of the dross removing tank. The above number is obtained by sampling the molten zinc at the inlet and the outlet of the dross removing tank and observing the cross section of the solidified zinc. Was measured by

【0021】図7に示されるように、上記した実験によ
って、一定値以下の溶融亜鉛流量、すなわち上記した実
験装置においては、0.5t/min以下の溶融亜鉛流量でほぼ
100%に近いドロス除去効率ηが得られることが分かっ
た。本発明者らは、上記で得られた実験結果および
回転する浴中シンクロールを用いた鋼帯の連続溶融金属
めっきのめっき浴におけるめっき液の循環流に着目し
た。
As shown in FIG. 7, according to the above experiment, the molten zinc flow rate of not more than a certain value, that is, in the experimental apparatus described above, the molten zinc flow rate of 0.5 t / min or less was substantially obtained.
It was found that dross removal efficiency η close to 100% was obtained. The present inventors paid attention to the experimental results obtained above and the circulating flow of a plating solution in a plating bath for continuous molten metal plating of a steel strip using a sink roll in a rotating bath.

【0022】すなわち、回転する浴中シンクロールを用
いた鋼帯の連続溶融金属めっきのめっき浴においては、
浴中シンクロールの回転方向に沿ってめっき液が流れ、
めっき浴内に循環流が形成される。本発明者らは、ドロ
ス除去槽をめっき浴に浸漬配置すると共に、上記した循
環流を有効に活用し、ドロス除去槽内に溶融金属を導入
することによって、ポンプを用いずにめっき浴中のドロ
スを比重分離できるのではないかと考えた。
That is, in a plating bath for continuous hot-dip metal plating of a steel strip using a sink roll in a rotating bath,
The plating solution flows along the rotation direction of the sink roll in the bath,
A circulating flow is formed in the plating bath. The present inventors have arranged the dross removing tank in the plating bath while immersing the dross removing tank in the plating bath, and effectively utilizing the circulating flow described above, and introducing the molten metal into the dross removing tank so that the dross removing tank is not used in the plating bath without using a pump. We thought that dross could be separated by specific gravity.

【0023】このため、めっき浴内にめっき浴の循環流
を利用したドロス除去槽を配設して実験を行った。その
結果、後記する実施例で示すように、めっき浴中のドロ
スが効率的に比重分離され、溶融金属めっき鋼板へのド
ロス付着を極めて効果的に防止することが可能であるこ
とが分かり本発明に至った。
For this reason, an experiment was conducted by disposing a dross removing tank utilizing a circulating flow of the plating bath in the plating bath. As a result, as shown in Examples described later, it was found that dross in the plating bath was efficiently separated by specific gravity, and it was possible to extremely effectively prevent dross from adhering to the hot-dip coated steel sheet. Reached.

【0024】図1に、本発明の溶融金属めっき装置およ
びドロス除去槽の1例を平面図(a)、A−A部矢視図
(縦側面図)(b) およびB−B部断面図(縦断面図)
(c) によって示す。なお、図1において、1は溶融金属
であるめっき浴、2はめっき用ポット、3は浴中シンク
ロール(:シンクロール)、4は鋼帯、5はスナウト、
10はドロス除去槽、11はドロス除去槽10内へのめっき液
流入口、12はめっき液流入口11に設けられたドロス除去
槽10内へのめっき液流入量調整用の可動整流板、12S は
可動整流板12の回転軸、13、14は板面が上下方向に配設
されためっき液中のドロス比重分離用の邪魔板、15はド
ロス除去槽10内からのめっき液流出口、Fはめっき液の
流れ、fはめっき液の流れ方向、f1は鋼帯の搬送方向
(通板方向)、f3は可動整流板12の回転方向、hはめっ
き液流出口15の開口部最下端部のドロス除去槽10内槽底
に対する高さ、θはめっき液流入口11に対する可動整流
板12の水平方向の角度(以下、整流板角度とも記す)を
示す。
FIG. 1 is a plan view showing one example of a hot-dip metal plating apparatus and a dross removing tank according to the present invention, FIG. 1B is a sectional view taken along arrow AA (vertical side view), and FIG. (Vertical cross section)
Indicated by (c). In FIG. 1, 1 is a molten metal plating bath, 2 is a plating pot, 3 is a sink roll in the bath (: sink roll), 4 is a steel strip, 5 is a snout,
10 is a dross removing tank, 11 is a plating solution inlet into the dross removing tank 10, 12 is a movable rectifying plate for adjusting the amount of plating solution flowing into the dross removing tank 10 provided at the plating solution inlet 11, 12S Is a rotating shaft of the movable rectifying plate 12, 13 and 14 are baffles for separating dross specific gravity in the plating solution whose plate surfaces are arranged vertically, 15 is a plating solution outlet from the dross removing tank 10, and F plating solution flow, f is the flow direction of the plating solution, f 1 is the transport direction of the steel strip (sheet passing direction), f 3 is the uppermost opening in the rotational direction, h is the plating solution outlet 15 of the movable current plate 12 The height of the lower end portion with respect to the bottom of the dross removing tank 10 and the angle θ indicate the horizontal angle of the movable rectifying plate 12 with respect to the plating solution inlet 11 (hereinafter also referred to as rectifying plate angle).

【0025】図1に示す溶融金属めっき装置において
は、溶融金属めっき浴中のドロスを除去するためのドロ
ス除去槽10がめっき浴1に浸漬されている。また、上記
ドロス除去槽10として、槽内へのめっき液流入口11と、
めっき液流入口11に設けられた槽内へのめっき液流入量
調整用の可動整流板12と、槽内に設けられかつ板面が上
下方向に配設されためっき液中のドロス比重分離用の複
数枚の邪魔板13、14と、槽内からのめっき液流出口15を
有するドロス除去槽10を配設した。
In the molten metal plating apparatus shown in FIG. 1, a dross removing tank 10 for removing dross in the molten metal plating bath is immersed in the plating bath 1. Further, as the dross removal tank 10, a plating solution inflow port 11 into the tank,
A movable rectifying plate 12 for adjusting the inflow amount of a plating solution into a tank provided at a plating solution inlet 11 and a dross specific gravity separation in a plating solution provided in a tank and having a plate surface arranged vertically. And a dross removing tank 10 having a plating solution outlet 15 from the inside of the tank.

【0026】なお、図1に示すドロス除去槽10は、槽全
体をめっき浴に浸漬することなく、ドロス除去槽10の槽
壁がめっき浴浴面(めっき浴液面)より上方に突き出
し、またドロス比重分離用の邪魔板13および邪魔板14が
下記に示すように配置されている。すなわち、図1に示
す溶融金属めっき装置においては、ドロス比重分離用の
邪魔板13は、板面上方端部がめっき液液面より上方に突
き出すと共に、板面下方端部とドロス除去槽10内の槽底
との間にめっき液流通用の流路を形成するように配置さ
れている。
In the dross removing tank 10 shown in FIG. 1, the tank wall of the dross removing tank 10 protrudes above the plating bath surface (plating bath liquid surface) without immersing the entire tank in the plating bath. A baffle plate 13 and a baffle plate 14 for dross specific gravity separation are arranged as shown below. That is, in the molten metal plating apparatus shown in FIG. 1, the baffle plate 13 for dross specific gravity separation has an upper end of the plate surface projecting above the liquid surface of the plating solution, and a lower end of the plate surface and the dross removing tank 10. It is arranged so as to form a flow path for plating solution distribution between the bottom of the tank and the bottom of the tank.

【0027】また、ドロス比重分離用の邪魔板14は、板
面上方端部がめっき液中に浸漬され、板面上方端部上方
にめっき液流通用の流路を形成し、板面下方端部がドロ
ス除去槽10内の槽底に至るように配置されている。ま
た、ドロス比重分離用の邪魔板13と邪魔板14の両者は、
邪魔板13の板面下方端部が邪魔板14の板面上方端部より
低い位置となるように配置されている。
The baffle plate 14 for dross specific gravity separation has an upper end portion of the plate surface immersed in the plating solution to form a flow path for plating solution distribution above the upper end portion of the plate surface. The portion is arranged so as to reach the bottom of the dross removing tank 10. Also, both the baffle 13 and baffle 14 for dross specific gravity separation are:
The lower end of the baffle plate 13 is disposed at a position lower than the upper end of the baffle plate 14.

【0028】この結果、めっき液がドロス除去槽10内に
配設された邪魔板13、14のそれぞれの下方または上方を
通過することによって、ドロス除去槽10内にめっき液の
下降流および上昇流の両者が形成され、めっき液中の比
重の軽いドロスは、ドロス除去槽10内のめっき液液面に
浮上し、めっき液中の比重の重いドロスは、ドロス除去
槽10内の槽底に沈積し、めっき液中のドロスが比重分離
される。
As a result, when the plating solution passes below or above each of the baffles 13 and 14 disposed in the dross removing tank 10, the plating solution flows downward and upward in the dross removing tank 10. The dross having a low specific gravity in the plating solution floats on the surface of the plating solution in the dross removing tank 10, and the dross having a high specific gravity in the plating solution deposits on the bottom of the dross removing tank 10. Then, dross in the plating solution is separated by specific gravity.

【0029】また、図1に示す溶融金属めっき装置にお
いては、ドロス除去槽10内へのめっき液流入量調整用の
可動整流板12が、板面が上下方向となるように配設され
ると共に、整流板が、可動整流板12の回転軸12S を中心
として水平方向(f3の方向)に回転可能な構成となって
いる。この結果、めっき液の流れが可動整流板12によっ
て抵抗を受け、めっき液流入口11に対する可動整流板12
の水平方向の角度(:整流板角度)θを調整することに
よって、ドロス除去槽10内へのめっき液流入口11の開口
部の開度を調整し、ドロス除去槽10内へのめっき液の流
入量を調整することができる。
In the molten metal plating apparatus shown in FIG. 1, a movable rectifying plate 12 for adjusting the flow rate of a plating solution into a dross removing tank 10 is arranged so that the plate surface is vertically oriented. , current plate, and has a rotatable structure in a horizontal direction (direction f 3) around the rotation axis 12S of the movable current plate 12. As a result, the flow of the plating solution is subjected to resistance by the movable rectifying plate 12, and the movable rectifying plate 12
The opening angle of the plating solution inlet 11 into the dross removing tank 10 is adjusted by adjusting the horizontal angle θ of the The inflow can be adjusted.

【0030】なお、本発明における前記可動整流板12と
しては、上記した目的からドロス除去槽10のめっき液流
入口11に設けられ、めっき液の流れに対して抵抗を与え
る面を有し、めっき浴1内のめっき液をドロス除去槽10
内に導入すると共に、上記した面が傾動および/または
移動することが可能な可動部材であればその形状、構造
は特に制限を受けるものではない。
The movable rectifying plate 12 in the present invention has a surface which is provided at the plating solution inlet 11 of the dross removing tank 10 for the above-mentioned purpose and gives resistance to the flow of the plating solution. The plating solution in bath 1 is removed from dross removal tank 10
The shape and structure of the movable member are not particularly limited as long as the movable member is capable of being tilted and / or moved while being introduced into the inside.

【0031】次に、図2に、上記した図1に示す溶融金
属めっき装置を斜視図によって示す。なお、図2におい
て、16はドロス除去槽10の保守時に、ドロス除去槽10を
一体(全体)としてめっき浴から引き上げるためにドロ
ス除去槽10に取り付けられた懸架用部材を示し、その他
の符号は図1と同一の内容を示す。
Next, FIG. 2 is a perspective view showing the hot-dip metal plating apparatus shown in FIG. In FIG. 2, reference numeral 16 denotes a suspension member attached to the dross removing tank 10 so that the dross removing tank 10 can be lifted out of the plating bath as a whole (at the time of maintenance) during maintenance of the dross removing tank 10. It shows the same contents as FIG.

【0032】以上述べた図1、図2に示す本発明の溶融
金属めっき装置によれば、めっき液を、浴中シンクロー
ル3の回転によって生じるめっき液の流れFを駆動力と
してドロス除去槽10のめっき液流入口11からドロス除去
槽10内に導入し、複数枚の邪魔板13、14のそれぞれの下
方または上方を通過せしめ、めっき液中のドロスを比重
分離した後、めっき液流出口15からめっき浴1中に再循
環することが可能となった。
According to the molten metal plating apparatus of the present invention shown in FIGS. 1 and 2 described above, the plating solution is supplied to the dross removing tank 10 by using the plating solution flow F generated by the rotation of the sink roll 3 in the bath as a driving force. The dross in the plating solution is introduced into the dross removing tank 10 from the plating solution inflow port 11 and passed under or above each of the plurality of baffle plates 13 and 14, and the dross in the plating solution is separated by specific gravity. From the plating bath 1.

【0033】なお、図3に示すように、本発明において
は、上記しためっき液の流れFをさらに効果的に利用す
るために、めっき用ポット2内にめっき液流れに対する
抵抗板20を設けてもよい。これは、上記した抵抗板20に
よって抵抗板20の配設箇所におけるめっき液の流通抵抗
が大となり、ドロス除去槽10内へのめっき液の流入量
(流入速度)が増加するためである。
As shown in FIG. 3, in the present invention, in order to more effectively use the flow F of the plating solution, a resistance plate 20 for the plating solution flow is provided in the plating pot 2. Is also good. This is because the resistance plate 20 described above increases the flow resistance of the plating solution at the location where the resistance plate 20 is provided, and increases the inflow amount (flow speed) of the plating solution into the dross removing tank 10.

【0034】なお、上記した抵抗板20は、図3に示すめ
っき用ポットの側壁に取り付けた抵抗板20に限定はされ
ず、めっき用ポット2内に配設され、ドロス除去槽10内
へのめっき液の流入量(流入速度)を増加できる位置に
取り付けた抵抗板20であればよい。本発明の溶融金属め
っき装置によれば、比重の重いドロスがドロス除去槽10
の槽内底部に沈降し分離されるばかりでなく、ドロス除
去槽10内のめっき液液面の上方を大気開放とするか空間
を形成することが可能であるため、比重の軽いドロスは
ドロス除去槽10の槽内のめっき液液面に浮上、滞留し、
浮上ドロスが再度めっき液中に巻き込まれることが防止
される。
The above-described resistance plate 20 is not limited to the resistance plate 20 attached to the side wall of the plating pot shown in FIG. It is sufficient that the resistance plate 20 is mounted at a position where the inflow amount (inflow speed) of the plating solution can be increased. According to the molten metal plating apparatus of the present invention, dross having a high specific gravity
Not only does the sediment settle down at the bottom of the dross tank, but also the dross with a low specific gravity can be removed from the dross removal tank 10 because the dross with a low specific gravity can be opened to the atmosphere or a space can be formed above it. Floats and stays on the plating solution level in the tank of tank 10,
The floating dross is prevented from being caught in the plating solution again.

【0035】この結果、本発明によれば、連続溶融金属
めっきにおいて、めっき浴中のドロスを効果的に除去す
ることが可能となった。さらに、本発明によれば、ポン
プおよび配管が不要であり、ポンプおよび配管の亜鉛も
しくはドロスによる閉塞もしくは破損に対する保守が不
要となり、保守性に優れた連続溶融金属めっき装置を達
成できた。
As a result, according to the present invention, dross in a plating bath can be effectively removed in continuous hot-dip metal plating. Further, according to the present invention, a pump and a piping are unnecessary, and maintenance for clogging or breakage of the pump and the piping by zinc or dross is not required, and a continuous hot-dip metal plating apparatus excellent in maintainability can be achieved.

【0036】また、本発明においては、ドロス除去槽10
のめっき液流出口15を、めっき液流出口15の開口部最下
端の位置がドロス除去槽10内の槽底から100mm 以上の高
さの位置となるよう配置することが好ましい。これは、
めっき液流出口15を、上記した条件を満足するように配
置することによって、ドロス除去槽10出口側の槽底に沈
降したドロスの槽外めっき浴への流出を防止できるため
である。
In the present invention, the dross removing tank 10
It is preferable that the plating solution outlet 15 is arranged such that the position of the lowermost end of the opening of the plating solution outlet 15 is at a height of 100 mm or more from the bottom of the dross removing tank 10. this is,
By arranging the plating solution outlet 15 so as to satisfy the above conditions, it is possible to prevent dross settled at the bottom of the dross removing tank 10 from flowing out to the plating bath outside the tank.

【0037】また、本発明においては、ドロス除去槽10
のめっき液流出口15から槽外のめっき浴1へのめっき液
の流出が阻害されないように、めっき液流出口15を、め
っき液流出口15の開口部最下端の位置が、ドロス除去槽
10内の槽底から100mm 以上の高さの位置で、かつ、ドロ
ス除去槽10内のめっき液液面の高さおよびドロス除去槽
10槽外のめっき浴1浴面の高さの両者よりも低い高さの
位置となるよう配置することが好ましい。
In the present invention, the dross removing tank 10
So that the outflow of the plating solution from the plating solution outlet 15 into the plating bath 1 outside the tank is not hindered, the plating solution outlet 15 is positioned at the lowermost position of the opening of the plating solution outlet 15 in the dross removing tank.
10 at a height of 100 mm or more from the bottom of the tank, and the height of the plating solution level in the dross removal tank 10 and the dross removal tank
It is preferable to arrange so as to be at a position lower than both of the heights of the plating bath 1 and the bath surface outside the 10 tanks.

【0038】さらに、本発明においては、前記した複数
枚の邪魔板13、14の少なくとも一枚を取り外し可能な構
造とすることが好ましい。図4に、上記した溶融金属め
っき装置の一例を、図1のB−B部縦断面図によって示
す。なお、図4において、17a 、18a は邪魔板13、邪魔
板14のそれぞれを両面側から挟持する支持部材、17b 、
18b は邪魔板13、邪魔板14のそれぞれを邪魔板の下端で
支持する支持部材を示し、その他の符号は図1、図2と
同一の内容を示す。
Further, in the present invention, it is preferable that at least one of the plurality of baffle plates 13 and 14 is configured to be removable. FIG. 4 shows an example of the above-described hot-dip metal plating apparatus in a longitudinal sectional view taken along the line BB in FIG. In FIG. 4, reference numerals 17a and 18a denote support members for holding the baffle plate 13 and the baffle plate 14 from both sides, respectively.
Reference numeral 18b denotes a support member for supporting each of the baffle plates 13 and 14 at the lower end of the baffle plate, and the other reference numerals indicate the same contents as in FIGS.

【0039】すなわち、図4に示す溶融金属めっき装置
においては、装置稼働時においても、邪魔板13、邪魔板
14を上方に引き上げ取り外すことができる。本発明にお
いては、図4に例示するように、複数枚の邪魔板13、14
の少なくとも一枚を取り外し可能な構造とすることによ
って、溶融金属めっき装置の稼働中においても、邪魔板
を取り外し、ドロス除去槽10内の槽底に沈積した槽底ド
ロスを容易に掻き出し、回収することが可能となる。
That is, in the hot-dip metal plating apparatus shown in FIG. 4, the baffle plate 13 and the baffle plate
14 can be pulled up and removed. In the present invention, as illustrated in FIG. 4, a plurality of baffle plates 13 and 14 are provided.
By making at least one of them removable, even during operation of the hot-dip metal plating apparatus, the baffle plate is removed, and the tank bottom dross deposited on the tank bottom in the dross removing tank 10 is easily scraped and collected. It becomes possible.

【0040】なお、上記した溶融金属めっき装置の稼働
中に槽底ドロスを掻き出し、回収する際には、前記した
ドロス除去槽10のめっき液流入口11に対する可動整流板
12の水平方向の角度(:整流板角度)θを0度としめっ
き液流入口11を閉鎖し、ドロス除去槽10内におけるめっ
き液の流れを停止することによって、ドロス除去槽10内
の槽底ドロスおよびドロス除去槽10内の浮遊ドロスの槽
外めっき浴中への流出を防止できる。
When the dross at the bottom of the tank is scraped out and collected during the operation of the molten metal plating apparatus, the movable rectifying plate with respect to the plating solution inlet 11 of the dross removing tank 10 is used.
The plating solution inlet 11 is closed by setting the horizontal angle θ of the 12 (: rectifying plate angle) to 0 degree, and the flow of the plating solution in the dross removing tank 10 is stopped. The dross and floating dross in the dross removing tank 10 can be prevented from flowing into the plating bath outside the tank.

【0041】さらに、本発明においては、図2、図4に
例示するようにドロス除去槽10に懸架用部材16などを取
り付け、ドロス除去槽10を一体(全体)としてめっき浴
1から引き上げ可能な構造とすることが好ましい。これ
は、ドロス除去槽10を上記した構造とし、ドロス除去槽
10を一体(全体)としてめっき浴1から引き上げること
によって、ドロス除去槽10の保守、補修を容易に行うこ
とができ、また保守、補修の時間を短縮することができ
るためである。
Further, in the present invention, as shown in FIGS. 2 and 4, a suspension member 16 and the like are attached to the dross removing tank 10, and the dross removing tank 10 can be lifted up from the plating bath 1 as a whole (entirely). It is preferable to have a structure. This is because the dross removing tank 10 has the above-described structure,
This is because the dross removing tank 10 can be easily maintained and repaired by pulling up the plating bath 1 from the plating bath 1 as a whole (as a whole), and the maintenance and repairing time can be shortened.

【0042】また、ドロス除去槽10を上記した構造とす
ることによって、軽微な保守、補修の場合は、溶融金属
めっき装置の稼働中においても、ドロス除去槽10を一体
(全体)としてめっき浴1から引き上げ、保守、補修を
行うことができる。さらに、本発明によれば、ドロス除
去槽10をめっき浴1内に浸漬配置するため、めっき浴外
にドロス除去槽を設ける場合の放散熱量が大幅に低減で
き、省エネルギーを達成できるという効果も有する。
Further, by making the dross removing tank 10 having the above-described structure, in the case of minor maintenance and repair, the dross removing tank 10 is integrated (total) even during operation of the molten metal plating apparatus. , And can perform maintenance and repair. Furthermore, according to the present invention, since the dross removing tank 10 is immersed in the plating bath 1, the amount of heat dissipated when the dross removing tank is provided outside the plating bath can be greatly reduced, and there is an effect that energy saving can be achieved. .

【0043】また、本発明によれば、ドロス除去槽10を
めっき浴1内に浸漬配置するため、ドロス除去槽からの
めっき液の漏洩の問題が無く、安全上の問題も無い。以
上本発明について述べたが、本発明における溶融金属め
っきの溶融金属としては、溶融亜鉛に限定されることは
なく、亜鉛を主成分とする溶融(亜鉛−アルミ:Zn-Al
)、アルミを主成分とする溶融(アルミ−亜鉛:Al-Zn
)など、溶融亜鉛以外の溶融金属を用いることもでき
る。
Further, according to the present invention, since the dross removing tank 10 is immersed in the plating bath 1, there is no problem of leakage of the plating solution from the dross removing tank and no safety problem. Although the present invention has been described above, the molten metal of the hot-dip metal plating in the present invention is not limited to molten zinc, and the molten metal containing zinc as a main component (zinc-aluminum: Zn-Al
), Aluminum-based melting (aluminium-zinc: Al-Zn)
) Can be used.

【0044】すなわち、本発明は、前記した本発明の作
用、効果に基づき、溶融亜鉛以外の溶融金属を用いた溶
融金属めっきにおける溶融金属めっき浴中のドロスの除
去方法および溶融金属めっき装置としても好適に用いる
ことができる。
That is, the present invention also provides a method for removing dross from a molten metal plating bath and a molten metal plating apparatus in molten metal plating using a molten metal other than molten zinc, based on the functions and effects of the present invention. It can be suitably used.

【0045】[0045]

【実施例】以下、実施例に基づき本発明および本発明に
より得られる効果をさらに具体的に説明する。図1、図
2に示す本発明の溶融金属めっき装置を用いて鋼帯への
連続溶融亜鉛めっきを行い、鋼板へのドロス付着状況を
調べた。
EXAMPLES Hereinafter, the present invention and the effects obtained by the present invention will be described more specifically based on examples. Continuous hot-dip galvanizing was performed on a steel strip using the hot-dip metal plating apparatus of the present invention shown in FIGS. 1 and 2, and the state of dross adhesion to the steel sheet was examined.

【0046】また、図8に示す従来の溶融金属めっき装
置を用いて鋼帯への連続溶融亜鉛めっきを行い、本発明
の溶融金属めっき装置で得られた鋼板のドロス付着状況
と従来の溶融金属めっき装置で得られた鋼板のドロス付
着状況との比較を行った。なお、図1、図2に示す溶融
金属めっき装置において、めっき液流出口15の開口部最
下端の位置は、ドロス除去槽10内の槽底から 500mmの高
さとした。
Further, continuous hot-dip galvanizing is performed on a steel strip using the conventional hot-dip metal plating apparatus shown in FIG. 8, and the state of dross adhesion of the steel sheet obtained by the hot-dip metal plating apparatus of the present invention and the conventional hot-dip Comparison with the dross adhesion state of the steel sheet obtained by the plating apparatus was performed. In the molten metal plating apparatus shown in FIGS. 1 and 2, the position of the lowermost end of the opening of the plating solution outlet 15 was set at a height of 500 mm from the bottom of the dross removing tank 10.

【0047】すなわち、図1(b) 、図2においてh= 5
00mmとした。 (実施例1)図1、図2に示す本発明の溶融金属めっき
装置を用い、予め、ドロス除去槽10のめっき液流入口11
に対する可動整流板12の水平方向の角度(:整流板角
度)θと、ドロス除去槽10内の循環溶融亜鉛流量との関
係を、前記した図7と同様の方法で調査した。
That is, in FIG. 1B and FIG.
00 mm. (Embodiment 1) Using the molten metal plating apparatus of the present invention shown in FIGS.
The relationship between the horizontal angle θ of the movable straightening plate 12 (: straightening plate angle) and the flow rate of the circulating molten zinc in the dross removing tank 10 was investigated in the same manner as in FIG.

【0048】図5に、得られた結果を示す。なお、図5
に示す循環溶融亜鉛流量は、可動整流板12を取り付ける
前のドロス除去槽10内の循環溶融亜鉛流量を1とし、相
対値で示した。図5に示されるように、整流板角度:θ
=90度の時に最大の循環溶融亜鉛流量が得られ、以下の
実験では整流板角度:θ=90度と設定した。
FIG. 5 shows the obtained results. FIG.
The circulating molten zinc flow rate shown in (1) is shown as a relative value, with the circulating molten zinc flow rate in the dross removing tank 10 before the movable rectifying plate 12 is attached as 1. As shown in FIG. 5, the current plate angle: θ
= 90 degrees, the maximum circulating molten zinc flow rate was obtained. In the following experiments, the rectifying plate angle: θ was set to 90 degrees.

【0049】次に、下記条件下で鋼帯の連続溶融亜鉛め
っきを行い、得られた溶融亜鉛めっき鋼板の品質を下記
試験方法で評価した。 (溶融亜鉛めっきの条件:) 鋼帯:冷延鋼板、板厚0.4 〜1.6mm ×板幅750 〜1850mm 溶融亜鉛めっき浴侵入板温:470 〜480 ℃ 溶融亜鉛めっき浴Al濃度 :0.13〜0.15% 通板速度 :30〜150m/min (溶融亜鉛めっき鋼板の試験方法:)得られた鋼帯50コ
イルについて下記試験を行い、品質を評価した。
Next, the steel strip was subjected to continuous hot-dip galvanizing under the following conditions, and the quality of the obtained hot-dip galvanized steel sheet was evaluated by the following test method. (Conditions of hot-dip galvanizing :) Steel strip: cold-rolled steel sheet, sheet thickness 0.4 to 1.6 mm × sheet width 750 to 1850 mm Hot-dip galvanizing bath temperature: 470 to 480 ° C Hot-dip galvanizing bath Al concentration: 0.13 to 0.15% Passing speed: 30 to 150 m / min (Test method for hot-dip galvanized steel sheet :) The following test was performed on the obtained 50 coils of the steel strip to evaluate the quality.

【0050】溶融亜鉛めっき鋼板のドロス付着による
不良率:溶融亜鉛めっき鋼板をプレス加工し、プレス加
工後の鋼板のドロス付着個数が2個/m2以上の製品を不
良とし、全製品中における不良製品の発生率を不良率と
定義した。 付着ドロスの最大粒径:溶融亜鉛めっき鋼板表面の付
着ドロスを顕微鏡で観察し、各コイルの付着ドロスの最
大粒径を求め、全コイルについての付着ドロスの平均最
大粒径を求めた。
Defect rate due to dross adhesion of hot-dip galvanized steel sheet: A hot-dip galvanized steel sheet is pressed, and a product in which the number of dross adhering to the steel sheet after press working is 2 pieces / m 2 or more is defective, and is defective in all products. The product incidence was defined as the defect rate. Maximum particle size of attached dross: The attached dross on the surface of the hot-dip galvanized steel sheet was observed with a microscope, the maximum particle size of the attached dross of each coil was determined, and the average maximum particle size of the attached dross for all the coils was determined.

【0051】表1に、得られた試験結果を示す。 (比較例)図8に示す従来の溶融金属めっき装置を用い
た以外は前記した実施例1と同様の条件で鋼帯への連続
溶融亜鉛めっきを行い、得られた溶融亜鉛めっき鋼板の
品質を前記した実施例1と同様の方法で評価した。
Table 1 shows the test results obtained. (Comparative Example) Continuous hot-dip galvanizing of a steel strip was performed under the same conditions as in Example 1 except that the conventional hot-dip galvanizing apparatus shown in FIG. 8 was used. Evaluation was performed in the same manner as in Example 1 described above.

【0052】表1に、得られた試験結果を示す。表1の
前記した実施例1と比較例との対比で示されるように、
本発明によれば、本発明に係わるドロス除去槽および浴
中シンクロールによるめっき液の循環流の作用・効果に
よって、めっき浴中のドロスが効率的に比重分離され、
溶融金属めっき鋼板へのドロス付着を極めて効果的に防
止することが可能であることが分かった。
Table 1 shows the test results obtained. As shown in Table 1 by comparison between Example 1 and Comparative Example,
According to the present invention, the dross in the plating bath is efficiently separated by specific gravity by the action and effect of the circulating flow of the plating solution by the dross removing tank and the sink roll in the bath according to the present invention,
It has been found that dross adhesion to the hot-dip metal-plated steel sheet can be extremely effectively prevented.

【0053】(実施例2)前記した実施例1で用いた図
1、図2に示す溶融金属めっき装置において、前記した
図4に示す邪魔板13、邪魔板14を両面側から挟持する支
持部材17a 、18bおよび邪魔板13、邪魔板14を邪魔板の
下端で支持する支持部材17b 、18b を取り付けた。
(Embodiment 2) In the hot-dip metal plating apparatus shown in FIGS. 1 and 2 used in Embodiment 1 described above, a support member for holding the baffle plates 13 and 14 shown in FIG. 4 from both sides. Support members 17b and 18b for supporting the baffles 13a and 14 and the baffle plates 13 and 14 at the lower ends of the baffle plates were attached.

【0054】本実施例においては、前記した実施例1と
同様の方法および条件で鋼帯への連続溶融亜鉛めっきを
行うと共に、下記(1) 、(2) の方法で本発明の溶融金属
めっき装置の保守の難易度を評価した。 (1) ドロス除去槽内の蓄積ドロスの回収:ドロス除去槽
10内に槽底ドロスおよび浮遊ドロスが蓄積した時点で、
装置を稼働した状態でドロスの掻き上げ、回収を行っ
た。
In this embodiment, the continuous hot-dip galvanizing of the steel strip is carried out in the same manner and under the same conditions as in the first embodiment, and the hot-dip galvanizing of the present invention is carried out by the following methods (1) and (2). The difficulty of maintenance of the equipment was evaluated. (1) Collection of accumulated dross in the dross removal tank: dross removal tank
When the bottom dross and floating dross accumulate in 10,
The dross was scraped up and collected while the device was operating.

【0055】すなわち、ドロス除去槽10内にドロスが蓄
積した時点で、可動整流板12の整流板角度:θを0度と
し、めっき液流入口11を閉鎖した。次に、邪魔板13、邪
魔板14を上方に引き上げ取り外し、槽底ドロスおよび浮
遊ドロスを掻き上げ、回収した。この結果、ドロス除去
槽10内の槽底ドロスおよび浮遊ドロスの両者を容易に回
収することができ、また回収時に製造された鋼板へのド
ロス付着量が回収前後のドロス付着量と同様に少ないこ
とが分かった。
That is, when the dross accumulated in the dross removing tank 10, the rectifying plate angle: θ of the movable rectifying plate 12 was set to 0 degree, and the plating solution inlet 11 was closed. Next, the baffle plate 13 and the baffle plate 14 were lifted up and removed, and the tank bottom dross and the floating dross were scraped up and collected. As a result, both the dross at the bottom of the tank and the floating dross in the dross removing tank 10 can be easily collected, and the amount of dross adhered to the steel plate manufactured at the time of collection is as small as the amount of dross before and after the collection. I understood.

【0056】(2) ドロス除去槽の保守、補修:ドロス除
去槽10内の邪魔板13、14の支持部材17b 、18b の凹部に
ドロスが沈積し、邪魔板13、14の取り外し、取り付けに
支障が生じた時点で、ドロス除去槽10の懸架用部材16に
チェーンを掛け、巻上機を用いてドロス除去槽10を一体
(全体)としてめっき浴1から引き上げた。
(2) Maintenance and repair of the dross removing tank: Dross deposits in the recesses of the support members 17b and 18b of the baffle plates 13 and 14 in the dross removing tank 10, which hinders removal and attachment of the baffle plates 13 and 14. When this occurred, a chain was hung on the suspension member 16 of the dross removing tank 10, and the dross removing tank 10 was pulled up from the plating bath 1 as a whole (entire) using a hoisting machine.

【0057】次に、支持部材17b 、18b の凹部に沈積し
たドロスを除去した。また、上記したドロス除去後、ド
ロス除去槽10をめっき浴1中に浸漬した。この結果、溶
融金属めっき装置の稼働中においても、短時間かつ容易
にドロス除去槽10の保守、補修を行うことができること
が分かった。
Next, dross deposited in the recesses of the support members 17b and 18b was removed. After the dross removal, the dross removal tank 10 was immersed in the plating bath 1. As a result, it was found that the dross removing tank 10 can be maintained and repaired in a short time and easily even during the operation of the molten metal plating apparatus.

【0058】[0058]

【表1】 [Table 1]

【0059】[0059]

【発明の効果】本発明によれば、連続溶融金属めっきに
おいて、極めて簡易な装置で、めっき浴中のドロスを効
果的に除去し、かつ、ドロスの回収作業が容易で装置の
保守性に優れた溶融金属めっき浴中のドロス除去方法お
よび溶融金属めっき装置を提供することが可能となっ
た。
According to the present invention, in continuous hot metal plating, dross in a plating bath can be effectively removed with an extremely simple apparatus, dross recovery operation is easy, and the maintainability of the apparatus is excellent. It has become possible to provide a method for removing dross from a molten metal plating bath and a molten metal plating apparatus.

【図面の簡単な説明】[Brief description of the drawings]

【図1】本発明の溶融金属めっき装置およびドロス除去
槽の1例を示す平面図(a) 、A−A部矢視図(縦側面
図)(b) およびB−B部断面図(縦断面図)(c) であ
る。
BRIEF DESCRIPTION OF THE DRAWINGS FIG. 1 is a plan view showing one example of a hot-dip metal plating apparatus and a dross removing tank according to the present invention, FIG. 1B is a sectional view taken along arrow AA (vertical side view), FIG. (C).

【図2】本発明の溶融金属めっき装置の1例を示す斜視
図である。
FIG. 2 is a perspective view showing one example of a hot-dip metal plating apparatus of the present invention.

【図3】本発明の溶融金属めっき装置およびドロス除去
槽の1例を示す平面図である。
FIG. 3 is a plan view showing one example of a hot-dip metal plating apparatus and a dross removing tank according to the present invention.

【図4】本発明の溶融金属めっき装置の1例を示す図1
のB−B部縦断面図である。
FIG. 4 is a view showing one example of a hot-dip metal plating apparatus of the present invention.
It is a BB section longitudinal cross-sectional view.

【図5】整流板角度θとドロス除去槽内の循環溶融亜鉛
流量との関係を示すグラフである。
FIG. 5 is a graph showing a relationship between a flow straightening plate angle θ and a flow rate of circulating molten zinc in a dross removing tank.

【図6】ドロス除去槽を示す縦断面図である。FIG. 6 is a vertical sectional view showing a dross removing tank.

【図7】ドロス除去槽内の溶融亜鉛流量とドロス除去効
率ηとの関係を示すグラフである。
FIG. 7 is a graph showing a relationship between a flow rate of molten zinc in a dross removing tank and a dross removing efficiency η.

【図8】従来の溶融金属めっき装置を示す縦断面図であ
る。
FIG. 8 is a longitudinal sectional view showing a conventional hot-dip metal plating apparatus.

【符号の説明】[Explanation of symbols]

1 めっき浴(溶融金属) 2 めっき用ポット 3 浴中シンクロール(:シンクロール) 4 鋼帯 5 スナウト 10 ドロス除去槽 11 ドロス除去槽内へのめっき液流入口 12 ドロス除去槽内へのめっき液流入量調整用の可動整
流板 12S 可動整流板の回転軸 13、14 めっき液中のドロス比重分離用の邪魔板 15 ドロス除去槽内からのめっき液流出口 16 ドロス除去槽懸架用部材 17a 、17b 、18a 、18b 邪魔板の支持部材 20 抵抗板 F めっき液の流れ f めっき液の流れ方向 f1 鋼帯の搬送方向(通板方向) f2 浴中シンクロールの回転方向 f3 可動整流板の回転方向 h めっき液流出口の開口部最下端部のドロス除去槽内
槽底に対する高さ θ 整流板角度
DESCRIPTION OF SYMBOLS 1 Plating bath (molten metal) 2 Pot for plating 3 Sink roll in bath (: sink roll) 4 Steel strip 5 Snout 10 Dross removal tank 11 Plating solution inlet into dross removal tank 12 Plating solution into dross removal tank Movable baffle plate for adjusting inflow amount 12S Rotating shaft of movable baffle plate 13, 14 Baffle plate for separating dross specific gravity in plating solution 15 Plating solution outlet from inside dross removal tank 16 Dross removal tank suspension members 17a, 17b , 18a, 18b Support member for baffle plate 20 Resistance plate F Flow of plating solution f Flow direction of plating solution f 1 Transport direction of steel strip (passing direction) f 2 Rotation direction of sink roll in bath f 3 Moving rectifying plate Rotation direction h Height of the lowermost end of the opening of the plating solution outlet relative to the bottom of the dross removal tank θ Rectifier plate angle

フロントページの続き (72)発明者 安達 一成 岡山県倉敷市水島川崎通1丁目(番地な し) 川崎製鉄株式会社水島製鉄所内 Fターム(参考) 4K027 AA02 AA22 AB42 AD08 AE04 AE08 Continued on the front page (72) Inventor Kazunari Adachi 1-chome, Mizushima-Kawasaki-dori, Kurashiki-shi, Okayama Pref.

Claims (6)

【特許請求の範囲】[Claims] 【請求項1】 鋼帯を溶融金属であるめっき浴(1) 中に
連続的に侵入させ、浴中シンクロール(3) を周回後、方
向転換し、めっき浴(1) 液面より上方へ引き上げて連続
的にめっきを施す溶融金属めっきにおけるドロス除去槽
(10)を用いた溶融金属めっき浴中のドロス除去方法であ
って、前記ドロス除去槽(10)として、槽内へのめっき液
流入口(11)と、槽内に設けられかつ板面が上下方向に配
設されたドロス比重分離用の複数枚の邪魔板(13 、14)
と、槽内からのめっき液流出口(15)を有するドロス除去
槽(10)を用いると共に、該ドロス除去槽(10)をめっき浴
(1) に浸漬し、めっき液を、浴中シンクロール(3) の回
転によって生じるめっき液の流れFを駆動力として前記
めっき液流入口(11)から前記ドロス除去槽(10)内に導入
し、前記複数枚の邪魔板(13 、14) のそれぞれの下方ま
たは上方を通過せしめ、めっき液中のドロスを比重分離
した後、前記めっき液流出口(15)からめっき浴(1) 中に
再循環することを特徴とする溶融金属めっき浴中のドロ
ス除去方法。
1. A steel strip is continuously intruded into a plating bath (1) which is a molten metal, and after turning around a sink roll (3) in the bath, the direction is changed and the plating bath (1) rises above the liquid level. Dross removal tank in hot-dip metal plating for continuous plating by lifting
A method for removing dross in a molten metal plating bath using (10), wherein as the dross removing tank (10), a plating solution inlet (11) into the tank, and a plate surface provided in the tank and having a plate surface is provided. Multiple baffles (13, 14) for vertical dross separation for specific gravity separation
And a dross removing tank (10) having a plating solution outlet (15) from inside the tank, and using the dross removing tank (10) as a plating bath.
(1), and the plating solution is introduced into the dross removing tank (10) from the plating solution inlet (11) with the flow F of the plating solution generated by the rotation of the sink roll (3) in the bath as a driving force. After passing through the lower or upper part of each of the plurality of baffle plates (13, 14) and separating dross in the plating solution by specific gravity, the dross in the plating solution is introduced into the plating bath (1) from the plating solution outlet (15). A method for removing dross from a molten metal plating bath, wherein the dross is recycled.
【請求項2】 前記ドロス除去槽(10)の前記めっき液流
入口(11)に、ドロス除去槽(10)内へのめっき液流入量調
整用の可動整流板(12)を取り付け、該可動整流板(12)に
よってドロス除去槽(10)内へのめっき液流入量を調整す
ることを特徴とする請求項1記載の溶融金属めっき浴中
のドロス除去方法。
2. A movable rectifying plate (12) for adjusting the amount of plating solution flowing into the dross removing tank (10) is attached to the plating solution inlet (11) of the dross removing tank (10). 2. The method for removing dross in a molten metal plating bath according to claim 1, wherein the flow rate of the plating solution into the dross removing tank (10) is adjusted by the current plate (12).
【請求項3】 鋼帯を溶融金属であるめっき浴(1) 中に
連続的に侵入させ溶融金属めっきを施すめっき用ポット
(2) と、鋼帯を方向転換させめっき浴(1) 液面より上方
へ引き上げるための浴中シンクロール(3) と、溶融金属
めっき浴中のドロスを除去するためのドロス除去槽(10)
を有する溶融金属めっき装置であって、前記ドロス除去
槽(10)として、槽内へのめっき液流入口(11)と、該めっ
き液流入口(11)に設けられた槽内へのめっき液流入量調
整用の可動整流板(12)と、槽内に設けられかつ板面が上
下方向に配設されたドロス比重分離用の複数枚の邪魔板
(13 、14) と、槽内からのめっき液流出口(15)を有する
ドロス除去槽(10)を用い、該ドロス除去槽(10)をめっき
浴(1) に浸漬配置すると共に、前記めっき液流入口(11)
を、前記めっき液流出口(15)に対して浴中シンクロール
(3) の回転によって生じるめっき液の流れの上流側に配
置したことを特徴とする溶融金属めっき装置。
3. A plating pot for continuously intruding a steel strip into a plating bath (1), which is a molten metal, to apply a molten metal plating.
(2), a plating bath (1) a sink roll in the bath for turning the steel strip up above the liquid level (3), and a dross removal tank (10) for removing dross in the molten metal plating bath. )
Wherein the dross removing tank (10) includes a plating solution inlet (11) into the tank, and a plating solution into a tank provided at the plating solution inlet (11). A movable rectifying plate (12) for adjusting the inflow amount, and a plurality of baffle plates for dross specific gravity separation provided in the tank and having the plate surface arranged vertically
(13, 14) and a dross removing tank (10) having a plating solution outlet (15) from the tank, the dross removing tank (10) is immersed in a plating bath (1), and the plating is performed. Liquid inlet (11)
The sink roll in the bath with respect to the plating solution outlet (15)
(3) A hot-dip metal plating apparatus, which is disposed upstream of a flow of a plating solution generated by the rotation of (3).
【請求項4】 前記めっき液流出口(15)を、該めっき液
流出口(15)の開口部最下端の位置が、ドロス除去槽(10)
内の槽底から100mm 以上の高さの位置となるように配置
したことを特徴とする請求項3記載の溶融金属めっき装
置。
4. A dross removing tank (10), wherein the plating solution outlet (15) is positioned at the lowermost position of the opening of the plating solution outlet (15).
4. The hot-dip metal plating apparatus according to claim 3, wherein the apparatus is arranged so as to be at a height of 100 mm or more from the bottom of the tank.
【請求項5】 前記複数枚の邪魔板(13 、14) の少なく
とも一枚を取り外し可能な構造としたことを特徴とする
請求項3または4記載の溶融金属めっき装置。
5. The hot-dip metal plating apparatus according to claim 3, wherein at least one of the plurality of baffle plates (13, 14) has a removable structure.
【請求項6】 前記ドロス除去槽(10)を一体としてめっ
き浴(1) から引き上げ可能な構造としたことを特徴とす
る請求項3〜5いずれかに記載の溶融金属めっき装置。
6. The molten metal plating apparatus according to claim 3, wherein said dross removing tank (10) is integrated with said dross removing tank (10) so as to be able to be lifted from said plating bath (1).
JP2000098663A 2000-03-31 2000-03-31 Method for removing dross in molten metal plating bath and molten metal plating apparatus Expired - Fee Related JP4238457B2 (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITPI20090011A1 (en) * 2009-02-09 2010-08-10 Siderprogetti Sa Llc METHOD FOR METALLIC COATING OF CONTINUOUS PRODUCTS AND STRUCTURE THAT IMPLEMENTS THIS METHOD
KR101415651B1 (en) 2012-08-21 2014-07-04 (주)엠솔루션 Dross gathering member of zinc pot
CN107761031A (en) * 2017-12-06 2018-03-06 馆陶县鑫江电热设备有限公司 Hot-dip galvanizing device
JP2018119188A (en) * 2017-01-26 2018-08-02 新日鐵住金株式会社 Apparatus for hot-dip galvanizing steel strip
JP2021063241A (en) * 2019-10-10 2021-04-22 日本製鉄株式会社 Hot-dip metal coating apparatus

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
ITPI20090011A1 (en) * 2009-02-09 2010-08-10 Siderprogetti Sa Llc METHOD FOR METALLIC COATING OF CONTINUOUS PRODUCTS AND STRUCTURE THAT IMPLEMENTS THIS METHOD
WO2010089666A1 (en) * 2009-02-09 2010-08-12 Siderprogetti Sa Llc Method for metal coating a continuous metal product and apparatus therefor
KR101415651B1 (en) 2012-08-21 2014-07-04 (주)엠솔루션 Dross gathering member of zinc pot
JP2018119188A (en) * 2017-01-26 2018-08-02 新日鐵住金株式会社 Apparatus for hot-dip galvanizing steel strip
CN107761031A (en) * 2017-12-06 2018-03-06 馆陶县鑫江电热设备有限公司 Hot-dip galvanizing device
CN107761031B (en) * 2017-12-06 2023-11-03 唐山东冶实业有限公司 Hot dip galvanization apparatus
JP2021063241A (en) * 2019-10-10 2021-04-22 日本製鉄株式会社 Hot-dip metal coating apparatus
JP7252465B2 (en) 2019-10-10 2023-04-05 日本製鉄株式会社 Hot-dip metal plating equipment

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