JP2001004235A - Steam compression refrigeration cycle - Google Patents
Steam compression refrigeration cycleInfo
- Publication number
- JP2001004235A JP2001004235A JP11175598A JP17559899A JP2001004235A JP 2001004235 A JP2001004235 A JP 2001004235A JP 11175598 A JP11175598 A JP 11175598A JP 17559899 A JP17559899 A JP 17559899A JP 2001004235 A JP2001004235 A JP 2001004235A
- Authority
- JP
- Japan
- Prior art keywords
- refrigerant
- state
- heat exchanger
- internal heat
- temperature
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B40/00—Subcoolers, desuperheaters or superheaters
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B1/00—Compression machines, plants or systems with non-reversible cycle
- F25B1/10—Compression machines, plants or systems with non-reversible cycle with multi-stage compression
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B9/00—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point
- F25B9/002—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant
- F25B9/008—Compression machines, plants or systems, in which the refrigerant is air or other gas of low boiling point characterised by the refrigerant the refrigerant being carbon dioxide
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2309/00—Gas cycle refrigeration machines
- F25B2309/06—Compression machines, plants or systems characterised by the refrigerant being carbon dioxide
- F25B2309/061—Compression machines, plants or systems characterised by the refrigerant being carbon dioxide with cycle highest pressure above the supercritical pressure
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/13—Economisers
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2400/00—General features or devices for refrigeration machines, plants or systems, combined heating and refrigeration systems or heat-pump systems, i.e. not limited to a particular subgroup of F25B
- F25B2400/23—Separators
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B2600/00—Control issues
- F25B2600/17—Control issues by controlling the pressure of the condenser
Landscapes
- Engineering & Computer Science (AREA)
- Physics & Mathematics (AREA)
- Mechanical Engineering (AREA)
- Thermal Sciences (AREA)
- General Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Air-Conditioning For Vehicles (AREA)
Abstract
Description
【0001】[0001]
【発明の属する技術分野】本発明は、自動車用、業務用
あるいは家庭用の空調システムに好適に用いられる、超
臨界状態における冷凍サイクル、およびそれを利用した
空調装置に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a refrigeration cycle in a supercritical state suitably used for an air conditioning system for automobiles, business use or home use, and an air conditioner using the same.
【0002】[0002]
【従来の技術】現在は広くフロンガス(炭素C、フッ素
F、塩素Clの化合物の総称で、頭文字をとってCFC
とよぶこともある)が用いられている。ところが、今
日、オゾン層の破壊防止や地球温暖化防止が、世界的に
求められるようになってきている。フロンも大気環境を
破壊する物質として、その使用の見直しが叫ばれてい
る。その一つとして、蒸気圧縮式冷凍装置の技術分野で
は冷媒の脱フロン対策の一つとして、たとえば二酸化炭
素(CO2)を使用した蒸気圧縮式冷凍サイクル(以
下、“CO2サイクル”と記述)が提案されている。冷
凍機として一般に広く用いられているのが蒸気圧縮式冷
凍装置である。この装置の構造を図1に、この装置を用
いた超臨界での冷凍サイクルを図2に示す。図1のアル
ファベットAは圧縮機101の吸入側(蒸発器105の
出口側)、Bは圧縮機101の吐出側(ガス冷却器10
2の入口側)、Cはガス冷却器102の出口側、Dは蒸
発器の入口側(膨張弁の出口側)を表し、図2はp−h
線図(モリエル蒸気圧線、略してモリエル線図)を表
し、図2のA、B、C、Dは図1のそれぞれの点に対応
した冷媒の状態を表している。2. Description of the Related Art At present, Freon gas is a general term for compounds of carbon C, fluorine F, and chlorine Cl.
Is sometimes used). However, today, prevention of ozone layer destruction and prevention of global warming are required worldwide. The use of CFCs as a substance that destroys the atmospheric environment has been called for to be reviewed. As one of the measures, in the technical field of a vapor compression refrigeration system, as one of measures against de-fluorocarbon refrigerant, for example, a vapor compression refrigeration cycle using carbon dioxide (CO 2 ) (hereinafter referred to as “CO 2 cycle”) Has been proposed. A vapor compression refrigeration system is widely used as a refrigerator. FIG. 1 shows the structure of this device, and FIG. 2 shows a supercritical refrigeration cycle using this device. 1, the letter A is the suction side of the compressor 101 (the outlet side of the evaporator 105), and the letter B is the discharge side of the compressor 101 (the gas cooler 10).
2, C represents the outlet side of the gas cooler 102, D represents the inlet side of the evaporator (the outlet side of the expansion valve), and FIG.
FIG. 2 shows a diagram (Mollier vapor pressure line, abbreviated Mollier diagram), and A, B, C, and D in FIG. 2 represent states of the refrigerant corresponding to respective points in FIG.
【0003】なお、ガス冷却器は凝縮器ともよぶ。ま
た、従来フロンガスを使用した冷凍サイクルでは飽和蒸
気圧以下の温度に冷却されるために、ガス状の冷媒は液
相化するので、凝縮器とよばれる。しかし、超臨界状態
では冷媒は液化しないために、この装置を凝縮器とよば
ずにガス冷却器(ガスクーラー)または放熱器とよぶ。
超臨界状態とは、物質が液相と気相との間の相移転がな
く、密度が液密度と略同等でありながら、物質の分子が
気相状態のように運動する状態をいう。物質は臨界温度
以上の気体の時には、圧力を加えても液化しない。また
受液器は2相化(液体と気体の混合状態化)した冷媒を
液体とガス(気体)に分けることから、気液分離器とも
よばれる。ここでは、受液器で統一して使用する。[0003] The gas cooler is also called a condenser. In a conventional refrigeration cycle using CFCs, the gaseous refrigerant is cooled to a temperature lower than the saturated vapor pressure, so that the gaseous refrigerant is in a liquid phase, and is therefore called a condenser. However, since the refrigerant does not liquefy in the supercritical state, this device is not called a condenser but a gas cooler (gas cooler) or a radiator.
The supercritical state refers to a state in which molecules of a substance move like a gas phase while the substance has no phase transition between a liquid phase and a gas phase, and has a density substantially equal to the liquid density. When a substance is a gas at or above the critical temperature, it does not liquefy even when pressure is applied. The liquid receiver is also called a gas-liquid separator because it separates the two-phase (mixed state of liquid and gas) refrigerant into liquid and gas (gas). Here, the same is used for the receiver.
【0004】図2において、縦軸は圧力p(kg/cm2 ab
s)、横軸はエンタルピh(kcal/kg)を表し、その他の
記号は、 Tk:臨界を通る等温線(Tkは絶対温度abs<゜K>) Tx:温度Txの等温線(Txは絶対温度abs<゜K>) K :臨界点 Sl:飽和液線 Sv:飽和蒸気線 S :飽和線(SlとSvを合わせた曲線の総称、記号は
図示せず) h1:A点のエンタルピhAからD点のエンタルピhVを
引いた値 p1:A点およびD点の圧力 h2:B点のエンタルピhBからC点のエンタルピhCを
引いた値 p2:B点およびC点の圧力 を表している。すなわち、図2は以下のことを表してい
る。 (1)臨界点を通る等温線Tkは飽和線S(SlとSvで
表される曲線)と臨界点Kで接する。 (2)飽和線Sにおいて、臨界点Kの左は左下がりの曲
線(Sl)となり、右は右下がりの曲線(Sv)となる。 (3)等温線Tkの左および飽和液線Slの左は冷媒が液
状態になる領域(斜線部)である。 (4)飽和線Sより下の部分は2相状態、すなわち液体
と気体が混合した状態である。 (5)等温線Tkの右または飽和蒸気線Svの右は冷媒が
気体状態(過熱蒸気)になる領域である。 (6)等温線Txは温度Txのときの蒸気圧を示しいる。In FIG. 2, the vertical axis represents the pressure p (kg / cm 2 ab).
s), the horizontal axis represents enthalpy h (kcal / kg), and other symbols are: T k : isotherm passing through criticality (T k is absolute temperature abs <゜ K>) T x : isotherm of temperature T x (T x is the absolute temperature abs <° K>) K: critical point S l: saturated liquid line S v: saturated vapor line S: generic curve combined saturation line (S l and S v, symbols not shown ) H 1 : Value obtained by subtracting enthalpy h V at point D from enthalpy h A at point A p 1 : Pressure at points A and D h 2 : Enthalpy h C at point C is subtracted from enthalpy h B at point B Value p 2 : represents the pressure at point B and point C. That is, FIG. 2 shows the following. (1) isotherm T k through the critical point it is in contact with saturation line S (S l and S v curve expressed by) the critical point K. (2) In the saturation line S, the left of the critical point K is a curve (S l ) falling left, and the right is a curve (S v ) falling right. (3) Left of the left and the saturated liquid line S l isotherms T k is the area (hatched portion) in which the refrigerant in a liquid state. (4) The portion below the saturation line S is a two-phase state, that is, a state in which a liquid and a gas are mixed. (5) the right of the right or saturated vapor line S v isotherms T k is the region in which the refrigerant in the gaseous state (superheated steam). (6) isotherms T x is shown a vapor pressure at the temperature T x.
【0005】例えば、二酸化炭素においては、Tx>Tk
すなわち等温線Tkの右側では、温度Txが一定の状態で
は冷媒は液化も2相化も起こりえないことを表してい
る。臨界温度(31.1℃)等温線Tkの右側であって飽
和蒸気線の臨界圧PK(75.28kg/cm2)以上の蒸気
圧の右側の領域を特に超臨界状態といい、この領域を含
む冷凍サイクルを超臨界冷凍サイクルという(正しくは
臨界温度以上の蒸気圧領域を含む冷凍サイクル。一般に
ガス冷却器だけでは液化できない領域のサイクル)。 (7)B→Cの冷媒の状態変化は、ガス冷却器102を
モータファン(図示せず)にて冷却する。等圧状態で熱
量h2を放熱し、従来のフロンガス冷媒が液化(凝縮)
していることを表している(凝縮過程)。しかし、ここ
では超臨界領域の冷媒のため密度の高いガス状態を示
す。 (8)D→Aの冷媒の状態変化は等圧状態で熱量h1を
吸熱し、液化した冷媒が蒸発器105にて蒸発している
ことを表している(蒸発過程)。 (9)A→Bの冷媒の状態変化は、断熱状態で圧縮機1
01により冷媒を圧縮して圧力をp1からp2に高めてい
ることを表している(圧縮過程)。 (10)C→Dの冷媒の状態変化は、断熱状態で膨張弁
104を開放することによって冷媒を膨張させ、圧力を
p2からp1に減圧していることを表している(膨張過
程)。For example, in carbon dioxide, T x > T k
That is, in the right side of the isotherm T k, it indicates that the temperature T x is the refrigerant can not occur nor 2 phased liquefied in certain conditions. The region on the right side of the critical temperature (31.1 ° C.) isotherm T k and above the critical pressure P K (75.28 kg / cm 2 ) of the saturated vapor line is particularly called a supercritical state. A refrigeration cycle including a region is called a supercritical refrigeration cycle (correctly, a refrigeration cycle including a vapor pressure region above a critical temperature. Generally, a cycle in a region that cannot be liquefied by a gas cooler alone). (7) When the state of the refrigerant changes from B to C, the gas cooler 102 is cooled by a motor fan (not shown). Radiates heat h 2 isobaric conditions, conventional chlorofluorocarbon refrigerant is liquefied (condensed)
(Condensation process). However, here, a gas state with a high density is shown because of the refrigerant in the supercritical region. (8) The change in the state of the refrigerant D → A indicates that the refrigerant absorbs the heat quantity h 1 at an equal pressure and the liquefied refrigerant evaporates in the evaporator 105 (evaporation process). (9) The state change of the refrigerant from A to B is caused by the compressor 1 in the adiabatic state.
It represents that increasing the pressure p 2 from p 1 to compress the refrigerant by 01 (compression process). (10) C → state change of the refrigerant D inflates the refrigerant by opening the expansion valve 104 adiabatically, indicating that that the pressure was reduced from p 2 to p 1 (expansion process) .
【0006】凝縮過程(B→C)および蒸発過程(D→
A)では熱交換が行われる。例えば、カーエアコンでの
冷房モードの場合、凝縮過程では、ガス冷却器102を
モータファンにより外気で冷却して冷媒の熱を外部に放
出し、蒸発過程では、蒸発器105でモーターファンに
より車内の空気から冷媒が熱を奪って車内空気を冷や
し、蒸気圧縮冷凍サイクル100中の冷媒を温める。た
だし、ガス冷却器用および蒸発器用のモーターファンは
図示していない。The condensation process (B → C) and the evaporation process (D →
In A), heat exchange is performed. For example, in the case of a cooling mode in a car air conditioner, in a condensing process, the gas cooler 102 is cooled by the outside air by a motor fan to release the heat of the refrigerant to the outside. The refrigerant takes heat from the air to cool the air inside the vehicle, and warms the refrigerant in the vapor compression refrigeration cycle 100. However, motor fans for the gas cooler and the evaporator are not shown.
【0007】圧縮過程(A→B)および膨張過程(C→
D)は断熱変化であるから、冷凍システム外からの熱の
流入はない。しかし、圧縮過程では圧縮機の冷媒圧縮が
行われるために、圧縮機の行った仕事量が冷媒の熱量
(モリエル線図のエンタルピ)を増加させ、図2に示す
ように右上がりのグラフとなる。したがって、熱量h1
とh2を比較すると、h2>h1の関係が成り立つ。ここ
で、冷凍機の性能を示す尺度として、一般に成績係数C
OPが用いられる。すなわち、成績係数COPは、 COP=冷凍熱量/圧縮仕事 =h1/(h2−h1) で表される。成績係数COPを上げるには、圧縮仕事
(h2−h1)を減らすか、冷凍熱量h1を上げればよい
ことになる。The compression process (A → B) and the expansion process (C →
Since D) is an adiabatic change, there is no heat inflow from outside the refrigeration system. However, in the compression process, since the refrigerant is compressed by the compressor, the work performed by the compressor increases the calorific value of the refrigerant (enthalpy in the Mollier diagram), and the graph rises to the right as shown in FIG. . Therefore, the heat quantity h 1
And h 2 , the relationship h 2 > h 1 holds. Here, a coefficient of performance C is generally used as a scale indicating the performance of a refrigerator.
OP is used. In other words, the COP is, COP = represented by the refrigeration heat / compression work = h 1 / (h 2 -h 1). In order to increase the coefficient of performance COP, the compression work (h 2 −h 1 ) may be reduced or the amount of frozen heat h 1 may be increased.
【0008】熱量h1を高めるための一つの方法とし
て、内部熱交換方式がある(この例として特公平7−1
8602公報)。この方法は図3に示すように、凝縮過
程および蒸発過程を終えた冷媒を接触させることによっ
て、双方で熱交換を行い、h1の熱量を増加させるもの
である。図3において、各記号は以下の意味を持ってい
る。 A´ :圧縮機101吸入前の冷媒状態 B´ :圧縮機101吐出後の冷媒状態 C´ :膨張弁104吸入前(入口側)の冷媒状態 D´ :膨張弁104吐出後(出口側)の冷媒状態 △h :熱交換によって出入りする熱量 △h´:内部熱交換のない場合に比べて、圧縮機101
により圧力p1まで圧縮されたときの冷媒の増加熱量 矢印 :冷媒の流れの向きを表している。As one method for increasing the heat quantity h 1 , there is an internal heat exchange method (for example, Japanese Patent Publication No. 7-1
8602). The method as shown in FIG. 3, by contacting the refrigerant which has been condensed process and evaporation process, subjected to heat exchange in both, but to increase the amount of heat h 1. In FIG. 3, each symbol has the following meaning. A ′: state of refrigerant before suction of compressor 101 B ′: state of refrigerant after discharge of compressor 101 C ′: state of refrigerant before suction of expansion valve 104 (inlet side) D ′: state of refrigerant after discharge of expansion valve 104 (outlet side) Refrigerant state Δh: amount of heat entering and exiting through heat exchange Δh ′: compressor 101 as compared to the case without internal heat exchange
Refrigerant increases heat arrow when compressed to a pressure p 1 by: represents the direction of the coolant flow.
【0009】図4は、図3の冷凍装置に対する冷凍サイ
クルを表している。図4における実線で示した冷凍サイ
クルABCDは、内部熱交換器106のない場合であ
り、破線で示したサイクルA´B´C´D´(一部AB
CDと重複)は、図4のように内部熱交換器を取り付け
た場合である。CがC´にずれているのは、内部熱交換
器106によって凝縮(冷却)ずみの冷媒が熱量を失っ
たためであり、その熱量△hは △h=hC−hC´ である。一方、AからA´の変化は、凝縮ずみ冷媒が放
熱した熱量を蒸発ずみ冷媒が吸収したものであるから、
hA´−hAは△hに等しい。ところが、圧縮機101で
気圧をp1からp2に上げたとき、AではT1に温度上昇
しても、A´ではT1にならず、それより高い温度T2に
なる。しかも通常、 △h´=hB´−hB>△h である。内部熱交換によって得た熱量△hは冷却に寄与
しないから、必ずしも成績係数がアップするとは限らな
い。しかし、冷凍効果は増加している。(線分AD=h
1+線分DD´=△h)分の蒸発潜熱を外部流体から奪
って外部流体を冷却する。FIG. 4 shows a refrigeration cycle for the refrigeration apparatus of FIG. The refrigeration cycle ABCD shown by the solid line in FIG. 4 is a case without the internal heat exchanger 106, and the cycle A'B'C'D '(partly AB) shown by the broken line
CD) is a case where the internal heat exchanger is attached as shown in FIG. The reason why C is shifted to C ′ is that the refrigerant condensed (cooled) by the internal heat exchanger 106 has lost its heat, and the heat Δh is Δh = h C −h C ′. On the other hand, the change from A to A 'is due to the heat absorbed by the condensed refrigerant being absorbed by the evaporated refrigerant.
h A ′ −h A is equal to Δh. However, when the pressure in the compressor 101 is raised from p 1 to p 2, even if the temperature rises in the A T 1, not to A'In T 1, consisting of a higher temperature T 2 it. And usually, a △ h'= h B '-h B> △ h. Since the heat quantity Δh obtained by the internal heat exchange does not contribute to the cooling, the coefficient of performance does not always increase. However, the freezing effect is increasing. (Line segment AD = h
The latent heat of evaporation corresponding to 1 + line segment DD '= △ h) is taken from the external fluid to cool the external fluid.
【0010】内部熱交換器を有する臨界領域での冷凍サ
イクルにおいての一つの問題点は、図4においてA点
(圧力p1)からB点(圧力p2)に気圧を上げるとき
と、A´点からB´点に気圧を上げるときとでは、同じ
p1からp2への気圧の変化ではあるが、温度が後者の場
合の方が高くなる。図の例ではT2−T1(T2>T1)だ
け高くなっている。すなわち、圧縮機に吸入される冷媒
は高温状態となり、潤滑油の劣化や圧縮機各部品の破損
の原因となる。One problem in a refrigeration cycle in a critical region having an internal heat exchanger is that when the pressure is increased from point A (pressure p 1 ) to point B (pressure p 2 ) in FIG. in the case of increasing the air pressure in the B'point from the point, albeit a change in air pressure from the same p 1 to p 2, who when the temperature is in the latter is higher. In the example of FIG becomes higher by T 2 -T 1 (T 2> T 1). That is, the refrigerant sucked into the compressor is in a high temperature state, which causes deterioration of the lubricating oil and damage of each component of the compressor.
【0011】一方、高熱化を防ぐために過熱度を低く
し、図5に示すA点の状態で運転すると、圧縮機に液相
冷媒が流れ込み、圧縮機の破損につながる。したがっ
て、一般にはわずかに飽和蒸気線Svより右の状態(図
5のA´)の状態で運転する。どの程度の状態にするか
は、成績係数との兼ね合いになる。On the other hand, if the degree of superheat is reduced to prevent the heating, and the apparatus is operated in the state of point A shown in FIG. 5, the liquid-phase refrigerant flows into the compressor, leading to damage to the compressor. Therefore, operating in a state of general slightly saturated vapor line S v in from the right state (A'in Fig. 5). The degree to which the state is set depends on the coefficient of performance.
【0012】この問題を解決する方法として、従来技術
である『蒸気圧縮式冷凍サイクル』(特開平10-11547
0)では、センサーと膨張弁を2個設けた、超臨界状態
でのCO2冷凍サイクルが提唱されている。図6は、上
記冷凍サイクルの構造を示している。第1膨張弁104
1によって減圧をし、2相状態を作り出す。このとき、
温度センサー1081および圧力センサー104で放熱
器102(ガス冷却器)からの吐出ガスの温度と圧力を
測定し、制御装置110で第1膨張弁1041の開度を
決定し、最適制御線を算出している。これによって、冷
凍効率(成績係数)が最適値になるように工夫されてい
る。一方、第2膨張弁1042は、圧縮機101のCO
2の過熱度が所定値になるように調整する働きを持って
いる。圧縮機の吸入側のCO2を温度筒1082で取り
込み、温度変化を感知して第2膨張弁1042に伝え、
第2膨張弁の開度を調整している。これによって、液相
状態のCO2が圧縮機に流入しないように制御してい
る。As a method for solving this problem, there is a prior art “vapor compression refrigeration cycle” (Japanese Patent Laid-Open No. 10-11547).
0) proposes a supercritical CO 2 refrigeration cycle in which two sensors and an expansion valve are provided. FIG. 6 shows the structure of the refrigeration cycle. First expansion valve 104
Reduce pressure by 1 to create a two-phase state. At this time,
The temperature and pressure of the gas discharged from the radiator 102 (gas cooler) are measured by the temperature sensor 1081 and the pressure sensor 104, the opening degree of the first expansion valve 1041 is determined by the control device 110, and the optimal control line is calculated. ing. Thereby, the refrigerating efficiency (coefficient of performance) is devised so as to be an optimum value. On the other hand, the second expansion valve 1042
It has the function of adjusting the degree of superheat to a predetermined value. CO 2 on the suction side of the compressor is taken in by the temperature cylinder 1082, and the temperature change is sensed and transmitted to the second expansion valve 1042,
The opening of the second expansion valve is adjusted. Thus, CO 2 in the liquid phase state is controlled not to flow into the compressor.
【0013】上記冷凍サイクルでは、圧縮機を2個持っ
た図7で示すような装置も、実施例として挙げられてい
る。図6で示すように、センサーや制御装置を備えたシ
ステムは冷凍機の構造が大型化し、コストも高くなるな
るために、このシステムでは、第1膨張弁を制御する装
置を取り付けずに、開閉は機械式になっている。第1膨
張弁1041で減圧されたCO2の気相部分は受液器1
03から直接第1圧縮機1011に導かれている。第2
膨張弁1042は図6と同じ働きをするが、第2膨張弁
で気化され、蒸発器105で温められたCO2は第2圧
縮機1012で第1段階の圧縮が行われ、さらに第1圧
縮機で受液器から直接導かれたガスとともに第2段階の
圧縮が行われる。この例でも、受液器103に溜まる中
間圧のガスを第1圧縮機の加入側に導く導入配管や、圧
縮機が2個も設け、大型化し、コスト高でもある。In the refrigerating cycle, an apparatus having two compressors as shown in FIG. 7 is also mentioned as an embodiment. As shown in FIG. 6, the system including the sensor and the control device has a large refrigerator structure and increases the cost. Therefore, in this system, the system that opens and closes without installing the device for controlling the first expansion valve is used. Is mechanical. The gaseous phase portion of CO 2 decompressed by the first expansion valve 1041 is supplied to the receiver 1
03 is directly led to the first compressor 1011. Second
The expansion valve 1042 operates in the same manner as in FIG. 6, but CO 2 vaporized by the second expansion valve and warmed by the evaporator 105 is subjected to the first stage compression by the second compressor 1012 and further to the first compression. A second stage of compression takes place with the gas introduced directly from the receiver in the machine. Also in this example, the introduction pipe for guiding the intermediate-pressure gas accumulated in the liquid receiver 103 to the joining side of the first compressor and the two compressors are provided, so that the size is increased and the cost is increased.
【0014】これまでフロンが広く用いられてきたこと
には、それなりの理由がある。その一つが、臨界温度が
高いことである。たとえば、フロンR12の臨界温度は約
112℃であり、フロンR134aでは約80℃である。こ
れに対して、CO2の臨界温度は31.1℃と低い。この
ことは、CO2サイクルでは液相が作りにくいことを意
味している。とくに家庭用空調装置やカーエアコンのよ
うな場合に、夏場、外気温が30℃以上になる日本にお
いては、ガス冷却器を外気温で冷やすとき、等温線Tk
(図2参照)以下の温度にCO2を冷却できずに、凝縮
を伴う冷凍サイクルが成立しない。かりに外気温度が3
1℃としても、カーエアコンの場合には圧縮機がエンジ
ンとベルトでつながれて固定されている装置において
は、冷却空気温度がゆうに臨界温度(31.1℃)を超
えてしまい、冷房効果が低くなるとともに、それに伴う
成績係数の低下を招いてしまう。There has been a good reason why CFCs have been widely used so far. One of them is that the critical temperature is high. For example, the critical temperature of Freon R12 is about 112 ° C., and that of Freon R134a is about 80 ° C. On the other hand, the critical temperature of CO 2 is as low as 31.1 ° C. This means that it is difficult to form a liquid phase in the CO 2 cycle. Especially in the case of home air conditioners and car air conditioners, where the outside air temperature is 30 ° C. or higher in summer, when the gas cooler is cooled at the outside air temperature, the isothermal line T k
(Refer to FIG. 2) Since the CO 2 cannot be cooled to the following temperature, a refrigeration cycle involving condensation cannot be established. The outside air temperature is 3
Even in the case of 1 ° C, in the case of a car air conditioner, in a device in which the compressor is connected to the engine and a belt and fixed, the cooling air temperature will soon exceed the critical temperature (31.1 ° C), and the cooling effect will be reduced. As a result, the coefficient of performance is reduced.
【0015】内部熱交換器を有しない単圧縮単膨張冷凍
サイクルで冷凍効果を維持するには、より一層、高圧に
ガス圧縮し、ガス冷却器で多くの放熱を必要とする。図
8を用いて具体的に説明しよう。図において、まず外気
温が臨界温度Tkよりも低く、ABCDの冷凍サイクル
は臨界温度近辺の温度T1(≦Tk)まで温度を下げられ
るものとする。このときの成績係数COPは、 COP=h1/hw となる。ここでh1はD→A間の蒸発器の吸熱による冷
凍効果、hwは圧縮機の圧縮仕事である。いま外気温が
上昇して温度がT2(>T1)までしか下げられなかった
とすれば、そのままの運転では冷凍サイクルはABC´
D´となる。すなわち、成績係数は COP=(h1−△h1)/hw となり、冷凍能力、冷凍性能ともに低下する。ここで、
△h1は蒸発器の吸熱の減少量である。そのABCDと
同じ冷房効果を維持させるためには、蒸発器での吸熱を
h1に保たせなければならない。すなわち、圧縮機から
吐出するガスのガス圧力を上げ、AB´C″Dの冷凍サ
イクルにする必要がある。この場合の成績係数は、 COP=h1/(hw+△hw) となり、やはり冷凍性能は低下する。ここで、△hwは
圧縮機の圧縮仕事の増加を表す。In order to maintain the refrigerating effect in a single-compression single-expansion refrigeration cycle having no internal heat exchanger, the gas is further compressed to a high pressure and a large amount of heat is required by a gas cooler. This will be specifically described with reference to FIG. In the figure, first, the outside air temperature is lower than the critical temperature T k, refrigeration cycle ABCD is assumed to be the temperature is lowered to the temperature T 1 of the near critical temperature (≦ T k). The coefficient of performance COP at this time is COP = h 1 / h w . Here, h 1 is the refrigerating effect due to heat absorption of the evaporator between D → A, and h w is the compression work of the compressor. Assuming now that the outside air temperature rises and the temperature can be reduced only to T 2 (> T 1 ), the refrigeration cycle is ABC '
D '. That is, the coefficient of performance is COP = (h 1 − △ h 1 ) / h w , and both the refrigerating capacity and the refrigerating performance decrease. here,
Δh 1 is the amount of decrease in the heat absorption of the evaporator. To maintain the same cooling effect and its ABCD must not keep the heat absorption of the evaporator to h 1. That is, it is necessary to increase the gas pressure of the gas discharged from the compressor to make a refrigeration cycle of AB′C ″ D. In this case, the coefficient of performance is COP = h 1 / (h w + △ h w ) Again, the refrigeration performance is reduced, where Δh w represents an increase in the compression work of the compressor.
【0016】このように、CO2冷媒では外気温が臨界
温度(31.1℃)以上になると、単段冷凍サイクル
(たとえば、図1の構造の蒸気圧縮冷凍機)においては
ガス冷却器で冷媒を臨界温度以下に下げることができな
いために、いっきに冷凍性能を悪化させる。なぜなら、
ガス冷却器で冷媒をTkの温度に下げることができず、
液化できないからである。As described above, when the outside air temperature of the CO 2 refrigerant exceeds the critical temperature (31.1 ° C.), in the single-stage refrigeration cycle (for example, the vapor compression refrigerator having the structure shown in FIG. 1), the refrigerant is cooled by the gas cooler. Cannot be lowered below the critical temperature, so that the refrigerating performance deteriorates at once. Because
The gas cooler cannot reduce the refrigerant to the temperature of T k ,
This is because it cannot be liquefied.
【0017】[0017]
【発明が解決しようとする課題】従来の技術でいくつか
の冷凍サイクルの形態を見てきた。しかし、それぞれに
おいて一長一短がある。冷凍(あるいは冷房)しようと
する対象によっても、また使用する冷媒によっても、ど
の冷凍サイクルがよいかの判断基準が異なってくる。た
とえば−20℃、−30℃といった業務用冷凍機のよう
な場合と、家庭用冷蔵庫、空調機、あるいはカーエアコ
ンのような場合とでは、冷凍機の装置の構造やそのサイ
クルは違ってくる。The prior art has seen several refrigeration cycle configurations. However, each has its advantages and disadvantages. The criteria for determining which refrigeration cycle is better depends on the object to be frozen (or cooled) and the refrigerant to be used. For example, the structure of the refrigerator and the cycle thereof differ between a case of a commercial refrigerator such as -20 ° C and -30 ° C and a case of a home refrigerator, an air conditioner, or a car air conditioner.
【0018】冷媒の問題も今後の課題として残されてい
る。現在、広く利用されているフロンは、地球温暖化な
どの地球環境破壊化学物資の一つとして挙げられてい
る。この代替物質としてCO2が注目されている。しか
し、従来技術でも述べたように、CO2は臨界温度が低
いために、カーエアコンなどの冷媒として使用するとき
には、内部熱交換器を有しない単圧縮単膨張冷凍サイク
ルでは冷凍効率が悪く、また冷凍サイクルが作りにくい
という弱点を持っている。[0018] The problem of the refrigerant remains as a future subject. At present, CFCs widely used are listed as one of chemicals for destruction of the global environment such as global warming. CO 2 has attracted attention as an alternative material. However, as described in the prior art, because CO 2 has a low critical temperature, when used as a refrigerant for a car air conditioner or the like, the refrigeration efficiency is poor in a single compression single expansion refrigeration cycle having no internal heat exchanger, and The weak point is that it is difficult to make a refrigeration cycle.
【0019】さらに問題になる点は、モリエル線図でも
示されるように等温線の特徴から、急激な圧力上昇が必
要となる。この圧力を確保するために、圧縮機では圧力
をp 2からp3まで上昇させる必要がある。このとき、冷
媒の温度もTmからTn(>Tm)に急上昇する。すなわ
ち、CO2のように臨界温度が低い冷媒の場合には、液
溜めができず、また封入冷媒量、圧縮機の回転数の変化
によって高圧側圧力の変動が著しくなる。A further problem is that even in the Mollier diagram,
As shown, the characteristic of the isotherm requires a sharp pressure rise.
It becomes important. In order to secure this pressure, the compressor
To p TwoTo pThreeNeed to be raised up. At this time,
The temperature of the medium is also TmTo Tn(> Tm). Sand
C, COTwoIn the case of a refrigerant with a low critical temperature as in
Inability to accumulate, and change in the amount of charged refrigerant and the number of revolutions of the compressor
As a result, the fluctuation of the high pressure side becomes remarkable.
【0020】従来例でも述べたように、冷凍効果や成績
係数の向上のために内部熱交換を行う方法もある(図
3、図4参照)。しかし、この図3の内部熱交換を有す
る冷凍機では、図8で示すように冷凍サイクルA´B″
CDとなる。C´→C、A→A´の変化は内部熱交換に
よって生じる状態変換を示している。すなわち、高圧側
で放熱した熱量△h1は、低圧側で吸熱される。このた
め、圧縮過程で圧縮された冷媒の温度はTo変化する。
図においてTo>Tmであるから、内部熱交換のない場合
に比べて改善が認められる。しかし同じ冷凍能力を維持
しようとすると、外気温が上がるに従って内部熱交換器
で熱交換する熱量を単純増加させなければならない。そ
の場合、A→A´での吸熱過熱度が過大になり、さらに
温度が上昇する。したがって、ABCDと同じ冷凍効果
が得られるからといって、超臨界状態では図3の構造を
そのまま利用することができない。As described in the conventional example, there is a method of performing internal heat exchange in order to improve the refrigerating effect and the coefficient of performance (see FIGS. 3 and 4). However, in the refrigerator having the internal heat exchange shown in FIG. 3, the refrigeration cycle A′B ″ as shown in FIG.
Become a CD. The changes C ′ → C and A → A ′ indicate a state change caused by internal heat exchange. That is, the heat amount Δh 1 radiated on the high pressure side is absorbed on the low pressure side. Therefore, the temperature of the refrigerant compressed in the compression process varies T o.
In the figure, since T o > T m , an improvement is recognized as compared with the case without internal heat exchange. However, in order to maintain the same refrigeration capacity, the amount of heat exchanged in the internal heat exchanger must be simply increased as the outside air temperature increases. In that case, the degree of endothermic superheat at A → A ′ becomes excessive, and the temperature further rises. Therefore, the structure shown in FIG. 3 cannot be used in the supercritical state as it is because the same refrigeration effect as that of ABCD is obtained.
【0021】一方、従来技術で挙げた『蒸気圧縮式冷凍
サイクル』は基本的に冷凍効率を最適化する冷凍サイク
ルであって、本発明が扱おうとしている問題とは別物で
ある。 同特開平10−115470公報では、2段圧
縮2段膨張冷凍サイクルも実施例として載せてある。し
かし、この方法は、構成が大型化し、コスト高でもある
ため、根本的に本発明が扱おうとしている問題を解決す
るものではない。On the other hand, the "vapor compression refrigeration cycle" mentioned in the prior art is basically a refrigeration cycle for optimizing the refrigeration efficiency, and is different from the problem to be addressed by the present invention. In Japanese Patent Application Laid-Open No. H10-115470, a two-stage compression / two-stage expansion refrigeration cycle is described as an embodiment. However, this method does not fundamentally solve the problem to be addressed by the present invention because the configuration is large and the cost is high.
【0022】また、中間冷却器(内部熱交換器とは別
物)を有する2段圧縮2段膨張冷凍サイクルなども現実
に存在するが、中間冷却器と受液器で低圧側の冷媒温度
を下げる方法は、カーエアコンのような場合に中間冷却
器を高い温度の外気で過冷却する範囲では十分な効果は
期待できない。それに単に圧縮途中の冷媒温度を下げる
目的の中間冷却器と、2台の圧縮機を備えることは、蒸
気圧縮冷凍装置そのものの構造を大きくし、しかもコス
ト高となるために、一般ユーザー用のエアコンでは有効
な対策とはならない。とくに圧縮機の動力をエンジンか
ら得るようなカーエアコンの場合には、『蒸気圧縮式冷
凍サイクル』と同様に、2台の圧縮機を有することは、
エンジンルーム内の占有空間を少しでも小さくし、かつ
重量を少しでも少なくするためには、現実的でない。Although a two-stage compression / two-stage expansion refrigeration cycle having an intercooler (different from the internal heat exchanger) actually exists, the temperature of the low-pressure refrigerant is reduced by the intercooler and the receiver. This method cannot be expected to have a sufficient effect in the range where the intercooler is supercooled with high-temperature outside air in the case of a car air conditioner or the like. In addition, the provision of an intercooler for the purpose of simply lowering the refrigerant temperature during compression and two compressors increases the structure of the vapor compression refrigeration system itself and increases the cost. This is not an effective measure. In particular, in the case of a car air conditioner in which the power of the compressor is obtained from the engine, having two compressors, like the “vapor compression refrigeration cycle,”
It is not realistic to reduce the space occupied in the engine room as much as possible and to reduce the weight as much as possible.
【0023】以上の点に鑑み、本発明が解決しようとす
る課題は、超臨界状態における冷凍サイクルにおいて、
従来の冷凍サイクルと同様に冷凍能力を実現し、なおか
つ複雑な構造を持たない簡単な装置で効率的な冷凍サイ
クルを実現することである。In view of the above, an object to be solved by the present invention is to provide a refrigeration cycle in a supercritical state,
It is an object of the present invention to realize a refrigerating capacity similar to a conventional refrigerating cycle, and to realize an efficient refrigerating cycle with a simple device having no complicated structure.
【0024】[0024]
【課題を解決するための手段】本発明は、上記課題を解
決するため、内部熱交換器と2個の膨張弁を設ける。そ
の構造は以下の通りである。超臨界冷凍サイクルを利用
した蒸気圧縮式空気調和装置において、その構成要素は
圧縮機、ガス冷却器、内部熱交換器、受液器、蒸発器お
よび第1膨張弁と第2膨張弁の2個の膨張弁からなる。
内部熱交換器においては外部との熱交換はなく(すなわ
ち断熱処理)、状態の違う冷媒同士の熱交換を行う(こ
こでいう状態とは液相、気相を意味するだけでなく、圧
力、温度、エンタルピなども含む冷媒状態をさす)。冷
凍装置は断熱的であるが、ガス冷却器、蒸発器では外部
との熱交換が行われる。したがって、広い意味での表現
を使うなら、ガス冷却器、蒸発器は“外部システムとの
熱交換器”である。カーエアコンの場合には、ファンで
外気をガス冷却器に当てて熱を奪い、奪った熱は外部に
捨てる。一方、蒸発器には車内の空気をファンで当て、
冷媒の潜熱を奪って車内空気を冷やして、車内を冷房す
る。冷房と逆の操作を行えば、暖房が行えることにな
る。すなわち、ガス冷却器は放熱器であり、蒸発器は吸
熱器の働きを持っている。なお、ガス冷却器と蒸発器の
作用を逆にすれば、ヒートポンプ(暖房機)として利用
できる。According to the present invention, an internal heat exchanger and two expansion valves are provided to solve the above-mentioned problems. The structure is as follows. In a vapor compression type air conditioner using a supercritical refrigeration cycle, its components are a compressor, a gas cooler, an internal heat exchanger, a liquid receiver, an evaporator, and a first expansion valve and a second expansion valve. Consisting of an expansion valve.
In the internal heat exchanger, there is no heat exchange with the outside (that is, adiabatic treatment), and heat exchange between refrigerants in different states is performed (the state here means not only liquid phase and gas phase, but also pressure, Refrigerant state including temperature, enthalpy, etc.). Although the refrigerating device is adiabatic, the gas cooler and the evaporator exchange heat with the outside. Therefore, in a broad sense, gas coolers and evaporators are "heat exchangers with external systems." In the case of a car air conditioner, the outside air is applied to a gas cooler with a fan to take heat, and the heat taken away is discarded outside. On the other hand, the air in the car is blown to the evaporator with a fan,
The inside of the vehicle is cooled by removing the latent heat of the refrigerant to cool the air in the vehicle. By performing the reverse operation of cooling, heating can be performed. That is, the gas cooler is a radiator, and the evaporator has a function of a heat absorber. In addition, if the functions of the gas cooler and the evaporator are reversed, it can be used as a heat pump (heating machine).
【0025】以上の装置で、以下のような冷凍サイクル
を行う。 (1)蒸発器および内部熱交換器を通過した乾いた状態
Aの気相冷媒を圧縮機で吸入し圧縮して、高圧高温の超
臨界状態Bのガスを吐出し、(2)状態Bのガスをガス
冷却器で冷却して状態C´のガスを作り出し、(3)状
態C´のガスを第1膨張弁で減圧して臨界蒸気圧温度ま
で下げて、冷媒を状態C2にし、(4)状態C2の冷媒
を内部熱交換器内で、蒸発器を通過した状態Dの冷媒と
で熱交換させることによって状態C3の冷媒を作り出し
て、受液器で液相と気相を分離し、(5)状態C3の液
相冷媒を第2膨張弁で減圧して2相状態Dを作り、
(6)状態Dの冷媒を蒸発器で蒸発するとともに、外気
温度を冷却するとともに、状態A´の気相冷媒にし、
(7)状態A´の冷媒を、内部熱交換器内で状態C2の
冷媒とで熱交換させることによって状態Aの気相冷媒を
作り出すことによって、 A→B→C´→C2→C3→D→A´→A の冷凍サイクルを可能にする。The following refrigeration cycle is performed by the above apparatus. (1) The gaseous phase refrigerant in the dry state A that has passed through the evaporator and the internal heat exchanger is sucked and compressed by the compressor, and the high-pressure and high-temperature supercritical state B gas is discharged. The gas is cooled by a gas cooler to produce a gas in state C ′, and (3) the gas in state C ′ is reduced in pressure by the first expansion valve to a critical vapor pressure temperature, and the refrigerant is brought into state C2. A) producing a refrigerant in state C3 by exchanging heat in the internal heat exchanger with the refrigerant in state D passing through the evaporator in the internal heat exchanger, separating the liquid phase and the gaseous phase in the receiver, (5) The liquid-phase refrigerant in state C3 is decompressed by the second expansion valve to create a two-phase state D,
(6) evaporating the refrigerant in the state D with the evaporator, cooling the outside air temperature, and converting the refrigerant into the gaseous refrigerant in the state A ′;
(7) The refrigerant in state A 'is heat-exchanged with the refrigerant in state C2 in the internal heat exchanger to produce a gaseous state refrigerant in state A, whereby A → B → C ′ → C2 → C3 → D → A '→ A refrigeration cycle is enabled.
【0026】すなわち本発明の冷凍サイクルは、ガス冷
却器では液相状態にできない超臨界状態冷媒に対して、
ガス冷却器で冷却されたガスを第1膨張弁で減圧して等
温臨界蒸気圧線の温度まで下げ、さらに内部熱交換によ
って冷媒の温度を下げて液相状態を作ることができる。
しかも、内部熱交換によって圧縮機の冷媒吸入側で高い
温度(高温高圧のエンタルピの高い状態)にならないよ
うに抑えることができる。この点の詳細は、実施の形態
で、実施例とともに詳細に説明する。That is, the refrigeration cycle of the present invention is applied to a supercritical refrigerant which cannot be brought into a liquid phase by a gas cooler.
The gas cooled by the gas cooler is depressurized by the first expansion valve to lower the temperature to the temperature of the isothermal critical vapor pressure line, and further, the temperature of the refrigerant is lowered by internal heat exchange to form a liquid phase state.
In addition, it is possible to prevent the internal temperature of the compressor from reaching a high temperature (high enthalpy of high temperature and high pressure) on the refrigerant suction side of the compressor. Details of this point will be described in detail in the embodiments and examples.
【0027】また、本発明の冷凍装置では、ガス冷却器
では液相状態にできない超臨界状態冷媒に対して、ガス
冷却器で冷却されたガスを第1膨張弁で減圧して温度を
下げ、さらに内部熱交換によって冷媒の温度を下げて液
相状態を作ることができ、簡便にして保守が容易な装置
が得られる。Further, in the refrigeration apparatus of the present invention, the temperature of the gas cooled by the gas cooler is reduced by the first expansion valve to reduce the temperature of the supercritical refrigerant which cannot be brought into the liquid state by the gas cooler. Furthermore, a liquid phase state can be created by lowering the temperature of the refrigerant by internal heat exchange, and a device that is simple and easy to maintain can be obtained.
【0028】[0028]
【発明の実施の形態】以下、本発明の実施の形態を図面
と具体的数値を用いて説明する。本発明の実施例の一つ
として図9の回路構成図を挙げる。図10は図9に対応
した冷凍サイクルである。なお、本発明の冷凍サイクル
は破線(一部、実線と重複)で示す A→B→C´→C2→C3→D→A´→A である。Embodiments of the present invention will be described below with reference to the drawings and specific numerical values. FIG. 9 is a circuit diagram showing one embodiment of the present invention. FIG. 10 shows a refrigeration cycle corresponding to FIG. Note that the refrigeration cycle of the present invention is A → B → C ′ → C2 → C3 → D → A ′ → A indicated by a broken line (partly overlapping with the solid line).
【0029】図10において、図1および図2に相当す
る、ベースとなるCO2冷凍サイクルでは、蒸発温度を
例えば0℃とし、等エントロピ圧縮、等エンタルピ膨張
としている。凝縮側については臨界点Kr(臨界圧力7
5.28kg/cm2、臨界温度31.1℃)を越えた領域で
ある超臨界領域になっており、冷却に伴いB1点Tn、例
えば80℃からC’点T2、例えば40℃に温度低下
し、凝縮器出口C´点に冷媒は流れ、C´点から冷媒は
膨張弁により圧力P2を106kg/cm2からD´点の3
5.5kg/cm2に下げられ、蒸発器入口に導入される(こ
の間に余剰冷媒は受液器にストックできるようにしてあ
る。しかしこの場合、受液器での相分離はない。すなわ
ち、冷媒は液化しない)。蒸発温度0℃で冷媒は、蒸発
器から圧縮機へ流れる。これらを図10では、実線で示
す内部熱交換器を有しない単圧縮単膨張冷凍サイクル A´→B´→C´→D´→A´ として示してある。In FIG. 10, in a CO 2 refrigeration cycle serving as a base corresponding to FIGS. 1 and 2, the evaporation temperature is set to, for example, 0 ° C., and isentropic compression and isenthalpy expansion are performed. For the condensation side, the critical point Kr (critical pressure 7
5.28 kg / cm 2 , a critical temperature of 31.1 ° C.), which is a supercritical region. The temperature changes from B 1 point T n , for example, 80 ° C. to C ′ point T 2 , for example, 40 ° C., upon cooling. temperature drops, the condenser outlet C'refrigerant flows in point 3 the pressure P 2 from 106 kg / cm 2 of D'point refrigerant from C'point by the expansion valve
It is reduced to 5.5 kg / cm 2 and introduced into the evaporator inlet (during which the excess refrigerant can be stocked in the receiver, but in this case there is no phase separation in the receiver, ie The refrigerant does not liquefy). At an evaporation temperature of 0 ° C., the refrigerant flows from the evaporator to the compressor. These are shown in FIG. 10 as a single compression single expansion refrigeration cycle A ′ → B ′ → C ′ → D ′ → A ′ without an internal heat exchanger indicated by a solid line.
【0030】このベースとなるCO2サイクルに内部熱
交換器106のみを加えたCO2サイクルでは、凝縮器
102を通過した冷媒は、内部熱交換器106により、
ベースのCO2サイクルC´点のT2例えば40℃から
C″点のT1例えば30℃にまで温度が下げられる。こ
れを熱量(エンタルピ)に換算すると、圧力P2例えば
106kg/cm2のまま、C´からC″点までの減少熱量
△h´は、例えば9.6kcal/kgである。この減じた熱
量△h´分が、内部熱交換器106でそのまま蒸発器1
05を出た冷媒の熱量増加分となり、圧縮機101中の
冷媒はA´からA″の△h´増加した熱量のガスとなる
ために、圧縮後はB″点に達する。B″点(温度To例
えば108℃、圧力P2例えば105kg/cm2)の状態で
圧縮機から吐出された冷媒は、再び凝縮器102へ導入
されることになる。これを図10で示せば、一点破線
(一部、実線および破線と重複)で示す内部熱交換器の
みを有する冷凍サイクル A″→B″→C″→D″→A´→A″ となる。このように内部熱交換器のみを設けて蒸発器能
力を向上させようとすると、すなわち成績係数COP=
D´A´/C´B´−(D´A´)を向上させようとす
ると、圧縮機の吸入温度がTo例えば103℃と高温に
なってしまう。これにより、潤滑油の劣化や、シール部
や軸受部等の不具合が生じて圧縮機破損というような事
故原因となる恐れがある。In the CO 2 cycle in which only the internal heat exchanger 106 is added to the base CO 2 cycle, the refrigerant that has passed through the condenser 102 is removed by the internal heat exchanger 106.
The temperature of the base CO 2 cycle is reduced from T 2 at point C ′, for example, 40 ° C., to T 1 at point C ″, for example, 30 ° C. When this is converted into a calorie (enthalpy), the pressure P 2 becomes, for example, 106 kg / cm 2 . As it is, the reduced heat quantity Δh ′ from the point C ′ to the point C ″ is, for example, 9.6 kcal / kg. The reduced amount of heat △ h 'is directly supplied to the evaporator 1 by the internal heat exchanger 106.
Since the amount of heat of the refrigerant that has exited 05 has increased, the refrigerant in the compressor 101 becomes a gas having an amount of heat increased from A 'to A "by A", and reaches the point B "after compression. B "point (the temperature T o for example 108 ° C., the pressure P 2 for example 105 kg / cm 2) with refrigerant discharged from the compressor is the state of, will be reintroduced into the condenser 102. Shimese this in Figure 10 For example, a refrigeration cycle having only an internal heat exchanger indicated by a one-dot broken line (partly overlapping with the solid line and the broken line) is given as A "→ B" → C "→ D" → A '→ A ". In this way, when only the internal heat exchanger is provided to improve the evaporator capacity, that is, the coefficient of performance COP =
D'A' / C'B'- if an attempt to improve the (D'A'), the suction temperature of the compressor becomes T o for example 103 ° C. and a high temperature. As a result, deterioration of the lubricating oil, defects of the seal portion and the bearing portion, and the like may occur, which may cause an accident such as breakage of the compressor.
【0031】そこで本発明では、図9に示すように冷凍
サイクル中に膨張弁を2個所と内部熱交換器とを併せ設
けたものとする。すなわち、ガス冷却器102の出口C
´と内部熱交換器106の入口C2との間に第1膨張弁
1041を、内部熱交換器106の出口C3を経て、受
液器103と蒸発器105の入口D点との間に第2膨張
弁1042を設ける。したがって、第2膨張弁1042
で減圧された冷媒は、蒸発器105の出口A´および内
部熱交換器106の出口Aを経たのち、圧縮機101で
圧縮されて吐出されることになる。Therefore, in the present invention, as shown in FIG. 9, two expansion valves and an internal heat exchanger are provided in the refrigeration cycle. That is, the outlet C of the gas cooler 102
′ And the inlet C2 of the internal heat exchanger 106, and a second expansion valve 1041 between the receiver 103 and the inlet D of the evaporator 105 via the outlet C3 of the internal heat exchanger 106. An expansion valve 1042 is provided. Therefore, the second expansion valve 1042
After passing through the outlet A ′ of the evaporator 105 and the outlet A of the internal heat exchanger 106, the refrigerant decompressed by the above is compressed by the compressor 101 and discharged.
【0032】本発明では、ガス冷却器102でファンモ
ーター1071で放熱された冷媒に対して、C´点で第
1膨張弁1041で圧力をP2106kg/cm2から、C2
点のP3例えば80kg/cm2まで低下させたのち、内部熱
交換器106でC3点のT1例えば30℃まで温度を低下
させる。次にC3点で第2膨張弁1042で圧力をP3
例えば80kg/cm2からP1例えば35.5kg/cm2まで低
下させ、蒸発器105の入口D点に冷媒を導く。このと
きの内部熱交換器106での熱量の交換量(エンタル
ピ)は△h線分C2C3例えば5.2Kcal/kgである。こ
れによって、圧縮機に吸入される冷媒は、図10に示す
ようにA点かB点に圧縮され、吐出される。すなわち、
B点の冷媒は温度Tn例えば90℃、圧力P2例えば10
6kg/cm2である。これにより、圧縮機101の温度
は、Tn例えば90℃と低く抑えることが可能となる。
この間に、受液器103に余剰冷媒をためておくことが
できる。上記の冷凍サイクルにおいては、受液器での気
液分離はない状態であると考えられる。すなわち、すべ
てが液化された状態であると考えられる。According to the present invention, the pressure of the refrigerant radiated by the fan motor 1071 by the gas cooler 102 at the point C ′ by the first expansion valve 1041 from P 2 106 kg / cm 2 to C2
After the temperature is lowered to the point P 3, for example, 80 kg / cm 2 , the temperature is lowered in the internal heat exchanger 106 to the C 3 point, T 1, for example, 30 ° C. Next, at the point C3, the pressure is increased to P 3 by the second expansion valve 1042.
For example reduced from 80 kg / cm 2 to P 1 for example 35.5 kg / cm 2, it guides the refrigerant to the inlet point D in the evaporator 105. At this time, the heat exchange amount (enthalpy) in the internal heat exchanger 106 is Δh line segment C 2 C 3, for example, 5.2 Kcal / kg. Thereby, the refrigerant sucked into the compressor is compressed to the point A or the point B as shown in FIG. 10, and is discharged. That is,
Refrigerant at the point B the temperature T n for example 90 ° C., the pressure P 2 for example 10
6 kg / cm 2 . Thereby, the temperature of the compressor 101 can be kept low, for example, Tn, for example, 90 ° C.
During this time, the excess refrigerant can be stored in the liquid receiver 103. In the above refrigeration cycle, it is considered that there is no gas-liquid separation in the receiver. That is, it is considered that everything is in a liquefied state.
【0033】蒸発器105を通過した冷媒は、内部熱交
換器106を通過するために、C2→C3の状態変化で
放熱された熱量△hを吸熱してA´→Aに状態変化し、
圧縮機101に吸入されることになる。さきに述べたよ
うに △h<△h´ であるから、単に内部熱交換器のみを有する冷凍サイク
ルA´B´C´D´に比べて、圧縮機で圧力p2に圧縮
した場合の温度は、本発明の冷凍サイクルABC´C2
C3DA´の方が低い(図10のTn、To参照)。すな
わち、圧縮機の高圧側の温度を抑えられるために、冷媒
の温度上昇に伴う潤滑油の劣化や圧縮機破損といった故
障を防げる。Since the refrigerant having passed through the evaporator 105 passes through the internal heat exchanger 106, the refrigerant absorbs the heat amount Δh radiated by the state change of C2 → C3 and changes its state to A ′ → A.
It will be sucked into the compressor 101. Since Δh <Δh ′ as described above, the temperature when the compressor is compressed to the pressure p 2 by the compressor as compared with the refrigeration cycle A′B′C′D ′ having only the internal heat exchanger. Is the refrigeration cycle ABC'C2 of the present invention.
C3DA' is lower (see T n, T o in FIG. 10). That is, since the temperature on the high pressure side of the compressor can be suppressed, failures such as deterioration of lubricating oil and damage to the compressor due to an increase in the temperature of the refrigerant can be prevented.
【0034】なお、内部熱交換器の概念的構造は図11
のようになっている。一般に高圧側の冷媒tHを中の管
に流し、低圧側の冷媒tLをそれを取り巻くように外の
管に流す(図9の矢印は冷媒の流れを表し、tLは低圧
側の冷媒の流れ<蒸発器105を通過した冷媒の流れ
>、tHは高圧側の冷媒<第1膨張弁1041を通過し
た冷媒の流れ>をそれぞれ表している)。このような構
造をとるのも、高圧ガスで管が破損しにくくしているた
めである。The conceptual structure of the internal heat exchanger is shown in FIG.
It is like. Generally, the high-pressure side refrigerant t H flows through the middle pipe, and the low-pressure side refrigerant t L flows through the outer pipe so as to surround it (the arrows in FIG. 9 indicate the flow of the refrigerant, and t L denotes the low-pressure side refrigerant). <Flow of refrigerant passing through the evaporator 105>, and t H represents the high-pressure side refrigerant <flow of refrigerant passing through the first expansion valve 1041>, respectively). The reason why such a structure is adopted is that the pipe is hardly damaged by the high-pressure gas.
【0035】以上、本発明はフロンに代わる超臨界冷凍
サイクルを余儀なくされる冷媒に対して、将来的に有効
な手法になる。As described above, the present invention will be an effective method in the future for a refrigerant which requires a supercritical refrigeration cycle instead of CFC.
【0036】[0036]
【発明の効果】現在使用されているフロンは、オゾン層
の破壊や地球温暖化の原因となるということで、世界的
に使用基準が見直されようとしている。そこで現在、フ
ロンに代わる冷媒の一つとして、例えば、二酸化炭素C
O2が冷媒として研究されるようになってきているが、
CO2サイクルは、フロンに比べて臨界温度が低いこと
である。CO2の臨界温度は31.1℃。夏場の日本の気
温はゆうに30℃を超える。カーエアコン(家庭用エア
コンも同様)の冷媒としてCO2を使用するとなると、
30℃以上の外気でガス冷却器を冷やさなけらばならな
い。ところが、カーエアコンの場合、圧縮機の動力はエ
ンジンから得るために、圧縮機とエンジンが一体型の構
造となり、ガス冷却の大気温度は臨界温度以上になって
しまう。すなわち、ガス冷却器だけでは受液器に液溜め
を作ることができず、安定した冷凍効果(冷房効果)が
得られない。The use of chlorofluorocarbon, which causes destruction of the ozone layer and global warming, is being reviewed for use standards worldwide. Therefore, at present, as one of the refrigerants replacing Freon, for example, carbon dioxide C
O 2 has been studied as a refrigerant,
The CO 2 cycle has a lower critical temperature than CFCs. The critical temperature of CO 2 is 31.1 ° C. Summer temperatures in Japan can easily exceed 30 degrees Celsius. When CO 2 is used as a refrigerant for car air conditioners (as well as home air conditioners),
The gas cooler must be cooled with outside air above 30 ° C. However, in the case of a car air conditioner, since the power of the compressor is obtained from the engine, the compressor and the engine have an integrated structure, and the atmospheric temperature of gas cooling becomes higher than the critical temperature. That is, a liquid reservoir cannot be formed in the liquid receiver only with the gas cooler, and a stable freezing effect (cooling effect) cannot be obtained.
【0037】この解決方法として、内部熱交換器によっ
て膨張弁前の冷媒温度(ガス冷却器より吐出ガス温度)
を下げて液相化することも考えられるが、この場合、低
圧側(圧縮機吸入側)の過熱度温度が上昇し、圧縮機の
吐出温度が高くなってしまうというジレンマが生じてい
た。As a solution to this problem, the temperature of the refrigerant before the expansion valve (the temperature of the gas discharged from the gas cooler) is controlled by the internal heat exchanger.
However, in this case, there is a dilemma that the superheat temperature on the low pressure side (compressor suction side) increases and the discharge temperature of the compressor increases.
【0038】本発明ではガス冷却器出口側と内部熱交換
器の吸入側との間に膨張弁を新たに設けて、いったんガ
ス圧を臨界圧近傍まで下げ、そのあとで内部熱交換する
ことによって、小さな熱量の内部熱交換で凝縮温度まで
冷却可能として、液相化しており、吐出温度の上昇を防
ぎ、従って、本発明は割合簡単な構造で、しかも受液器
を設けることにより高圧側の熱量変動、圧力変動を抑え
ることを可能にしているので、下記の通りの効果を奏す
る。In the present invention, a new expansion valve is provided between the outlet side of the gas cooler and the suction side of the internal heat exchanger, the gas pressure is reduced to near the critical pressure, and then the internal heat exchange is performed. It can be cooled to the condensing temperature by internal heat exchange with a small amount of heat and is in the liquid phase, preventing the discharge temperature from rising. Therefore, the present invention has a relatively simple structure, and furthermore, by providing a receiver, the high pressure side is provided. Since it is possible to suppress fluctuations in calorific value and pressure, the following effects can be obtained.
【0039】圧縮機吸入側の冷媒温度を低く抑えられ、
高圧変動を小さくすることが可能となり、これによっ
て、圧縮ガスの過熱化を防ぎ、潤滑油の劣化や圧縮機の
高熱化による破損を防止できる。The refrigerant temperature on the compressor suction side can be kept low,
High-pressure fluctuations can be reduced, thereby preventing overheating of the compressed gas and preventing deterioration of the lubricating oil and damage to the compressor due to high heat.
【0040】内部熱交換器を有しない単圧縮単膨張冷凍
機に比べて、高い冷却効果を得られる。また、内部熱交
換器のみを有する単圧縮単膨張冷凍機に比べて、圧縮機
吸入側の冷媒の温度を低くすることができ、高圧変動を
小さくするとともに、冷媒の過熱化を防止できること。A higher cooling effect can be obtained as compared with a single compression single expansion refrigerator having no internal heat exchanger. Further, compared with a single compression single expansion refrigerator having only an internal heat exchanger, the temperature of the refrigerant on the compressor suction side can be reduced, the high pressure fluctuation can be reduced, and the refrigerant can be prevented from being overheated.
【0041】多段圧縮冷凍サイクルの装置に比べて構造
が単純なために冷凍機の小型化、製造時の低コスト化が
可能である。Since the structure is simpler than that of the multi-stage compression refrigeration cycle apparatus, it is possible to reduce the size of the refrigerator and to reduce the production cost.
【図1】従来技術における内部熱交換器を有しない単圧
縮単膨張冷凍サイクルの回路構成図(模式図)である。FIG. 1 is a circuit configuration diagram (schematic diagram) of a single-compression single-expansion refrigeration cycle having no internal heat exchanger according to the related art.
【図2】従来技術における図1に対する冷凍サイクルを
説明するためのモリエル線図である。FIG. 2 is a Mollier diagram for explaining a refrigeration cycle for FIG. 1 in the prior art.
【図3】従来技術における内部熱交換器を有する単圧縮
単膨張冷凍サイクルの回路構成図(模式図)である。FIG. 3 is a circuit configuration diagram (schematic diagram) of a single-compression single-expansion refrigeration cycle having an internal heat exchanger according to a conventional technique.
【図4】従来技術における図3に対する冷凍サイクルを
説明するためのモリエル線図である。FIG. 4 is a Mollier diagram for describing a refrigeration cycle for FIG. 3 in the related art.
【図5】従来技術において、圧縮機に液が流れ込まない
冷凍サイクルを説明するための図である。FIG. 5 is a view for explaining a refrigeration cycle in which liquid does not flow into a compressor in the related art.
【図6】従来技術における各種センサーと単圧縮2段膨
張冷凍サイクルの回路構成図(模式図、『蒸気圧縮式冷
凍サイクル』(特開平10-115470)より抜粋)である。FIG. 6 is a circuit diagram of various sensors and a single-compression two-stage expansion refrigeration cycle in the prior art (schematic diagram, excerpted from “vapor-compression refrigeration cycle” (JP-A-10-115470)).
【図7】従来技術における2段圧縮2段膨張冷凍サイク
ルの回路構成図(模式図、『蒸気圧縮式冷凍サイクル』
(特開平10-115470)より抜粋)である。FIG. 7 is a circuit diagram of a conventional two-stage compression two-stage expansion refrigeration cycle (schematic diagram, “vapor compression refrigeration cycle”).
(Excerpted from JP-A-10-115470).
【図8】従来技術において、内部熱交換の有無により単
圧縮単膨張冷凍サイクルによる外気温上昇に伴う冷凍効
果、冷凍性能の変動を説明するための図である。FIG. 8 is a diagram for explaining a refrigeration effect and a change in refrigeration performance due to an increase in outside air temperature by a single-compression single-expansion refrigeration cycle depending on the presence or absence of internal heat exchange in the related art.
【図9】発明の実施の形態における内部熱交換器を有す
る2段膨張式冷凍機の回路構成図(模式図)の一例であ
る。FIG. 9 is an example of a circuit configuration diagram (schematic diagram) of a two-stage expansion refrigerator having an internal heat exchanger according to an embodiment of the invention.
【図10】発明の実施の形態における図9の冷凍機の超
臨界状態での冷凍サイクルを説明するための図である。10 is a diagram illustrating a refrigeration cycle in a supercritical state of the refrigerator of FIG. 9 in the embodiment of the present invention.
【図11】発明の実施の形態において、内部熱交換器の
構造を概念的に説明するための図である。FIG. 11 is a diagram conceptually illustrating the structure of an internal heat exchanger in the embodiment of the present invention.
100 蒸気圧縮冷凍サイクル(単に“冷凍サイク
ル”とも記述) 101 圧縮機(コンプレッサー) 1011 第1圧縮機 1012 第2圧縮機 102 ガス冷却器(放熱器、凝縮器、ガスクーラ
ー) 103 受液器(気液分離器、レシーバー) 104 膨張弁(減圧弁、エクスパンションバルブ) 1041 第1膨張弁 1042 第2膨張弁 105 蒸発器(エバポレーター、吸熱器) 106 内部熱交換器 1071 ファン(ガス冷却器用) 1072 ファン(蒸発器用) 1081 温度センサー 1082 温度筒 109 圧力センサー 110 制御装置REFERENCE SIGNS LIST 100 vapor compression refrigeration cycle (also simply referred to as “refrigeration cycle”) 101 compressor (compressor) 1011 first compressor 1012 second compressor 102 gas cooler (radiator, condenser, gas cooler) 103 liquid receiver (gas) Liquid separator, receiver) 104 Expansion valve (pressure reducing valve, expansion valve) 1041 First expansion valve 1042 Second expansion valve 105 Evaporator (evaporator, heat absorber) 106 Internal heat exchanger 1071 Fan (for gas cooler) 1072 Fan ( 1081 Temperature sensor 1082 Temperature tube 109 Pressure sensor 110 Control device
Claims (2)
気調和装置において、(1)圧縮機、ガス冷却器、内部
熱交換器、受液器、蒸発器および第1膨張弁と第2膨張
弁の2個の膨張弁を有する蒸気圧縮式装置構造をもち、
(2)蒸発器および内部熱交換器を通過した乾いた状態
Aの加熱蒸気冷媒を圧縮機で吸入し圧縮して、高圧高温
の超臨界状態Bのガスを吐出し、(3)状態Bのガスを
ガス冷却器で冷却して状態C´のガスを作り出し、
(4)状態C´のガスを第1膨張弁で減圧して臨界蒸気
圧近傍まで下げて、冷媒を状態C2にし、(5)状態C
2の冷媒を、内部熱交換器内で蒸発器を通過した状態
A’の冷媒とで熱交換させることによって状態C3の液
相冷媒を作り出して、(6)状態C3の液相冷媒を第2
膨張弁で減圧して2相状態Dを作り、(7)状態Dの冷
媒を蒸発器で蒸発するとともに、外気を冷却するととも
に、状態A´の加熱蒸気冷媒にし、(8)状態A´の冷
媒を、内部熱交換器内で状態C2の冷媒とで熱交換させ
ることによって状態Aの加熱蒸気冷媒を作り出すことに
よって、 A→B→C´→C2→C3→D→A´→A の冷凍サイクルを可能にする、2個の膨張弁と内部熱交
換器を有することを特徴とする蒸気圧縮式冷凍サイク
ル。1. A vapor compression type air conditioner using a supercritical cycle, wherein (1) a compressor, a gas cooler, an internal heat exchanger, a liquid receiver, an evaporator, a first expansion valve and a second expansion valve. Having a vapor compression type device structure having two expansion valves of
(2) The heated steam refrigerant in the dry state A that has passed through the evaporator and the internal heat exchanger is sucked and compressed by the compressor, and the gas in the supercritical state B at high pressure and high temperature is discharged. The gas is cooled by a gas cooler to produce a gas in state C ′,
(4) The gas in the state C ′ is decompressed by the first expansion valve and reduced to near the critical vapor pressure, and the refrigerant is changed to the state C2.
The refrigerant in the state C3 is produced by exchanging heat with the refrigerant in the state A ′ that has passed through the evaporator in the internal heat exchanger to produce the liquid-phase refrigerant in the state C3.
The pressure in the expansion valve is reduced to create a two-phase state D. (7) The refrigerant in the state D is evaporated by the evaporator, the outside air is cooled, and the heated vapor refrigerant in the state A 'is obtained. A-B->C->C2->C3->D->A-> A refrigeration by creating a heated steam refrigerant in state A by exchanging heat with the refrigerant in state C2 in the internal heat exchanger. A vapor compression refrigeration cycle having two expansion valves and an internal heat exchanger enabling the cycle.
気調和装置において、圧縮機、ガス冷却器、内部熱交換
器、受液器、蒸発器および第1膨張弁と第2膨張弁の2
個の膨張弁を有する蒸気圧縮式装置構造を備えたことを
特徴とする蒸気圧縮式空気調和装置。2. A vapor compression air conditioner utilizing a supercritical cycle, comprising: a compressor, a gas cooler, an internal heat exchanger, a receiver, an evaporator, and a first expansion valve and a second expansion valve.
A vapor compression type air conditioner comprising a vapor compression type device structure having a plurality of expansion valves.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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JP11175598A JP2001004235A (en) | 1999-06-22 | 1999-06-22 | Steam compression refrigeration cycle |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP11175598A JP2001004235A (en) | 1999-06-22 | 1999-06-22 | Steam compression refrigeration cycle |
Publications (1)
Publication Number | Publication Date |
---|---|
JP2001004235A true JP2001004235A (en) | 2001-01-12 |
Family
ID=15998899
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP11175598A Pending JP2001004235A (en) | 1999-06-22 | 1999-06-22 | Steam compression refrigeration cycle |
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Country | Link |
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JP (1) | JP2001004235A (en) |
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