JP2000214638A - Color toner - Google Patents

Abstract

PROBLEM TO BE SOLVED: To obtain a color toner causing no filming on a photoreceptor, less liable to cause offsetting and excellent also in preservability, durability and color reproducibility. SOLUTION: The color toner has 56-75 deg.C glass transition temperature and 0.1-0.5 wt.% water content. A bonding resin in the color toner is based on a polyester obtained by condensation-polymerizing polyhydric alcohol components including >=5 mol% compound of the formula [where R1 is 2-4 alkylene, each of (x) and (y) is a positive number and x+y=1 to 16] and carboxylic acid components including a dicarboxylic acid compound and a polycarboxylic acid compound having >=3 COOH groups. The average dispersion diameter of a releasing agent in the color toner is 0.1-3 μm. The particle diameter of an additive used is 4-200 nm and the additive content of the toner is 1-5 pts.wt. based on 100 pts.wt. toner before treatment with the additive.

Description

DETAILED DESCRIPTION OF THE INVENTION

[0001]

BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a color toner used for developing an electrostatic latent image formed in an electrophotographic method, an electrostatic recording method, an electrostatic printing method or the like, and a non-magnetic toner using the color toner. It relates to a component development method.

[0002]

2. Description of the Related Art As a method for fixing a toner image, a heat roll fixing method is widely used. However, since a large amount of color toners having a low softening point is contained from the viewpoint of optical characteristics, offset printing is required. The phenomenon is easy to occur. Therefore, toners containing a release agent such as carnauba wax, montan wax, canderia wax, and rice wax have been proposed (JP-A-5-341577, JP-A-8-220808, etc.). Insufficient setting of the conditions causes problems such as lack of filming resistance to the photoreceptor, resistance to offset, and lack of transparency of the fixing toner. Further, no toner has been reported which satisfies all the characteristics required for color toners such as storability, durability and color reproducibility.

[0003]

SUMMARY OF THE INVENTION An object of the present invention is to prevent filming on a photoreceptor, to prevent an offset from occurring,
Another object of the present invention is to provide a color toner excellent in storability, durability and color reproducibility, and a non-magnetic one-component developing method using the color toner.

[0004]

According to the present invention, there is provided a resin composition comprising a binder resin, a release agent, a colorant and an external additive and having a glass transition point of 5%.
A color toner having a water content of 6 to 75 ° C. and a water content of 0.1 to 0.5% by weight, wherein the binder resin has the formula (I):

[0005]

Embedded image

Wherein R ¹ is an alkylene group having 2 to 4 carbon atoms, x and y are positive numbers, and the sum of x and y is 1 to 16 (polyhydric alcohol) A polyhydric alcohol component containing at least 5 mol% of the components, a dicarboxylic acid compound (at least 50 mol% of the carboxylic acid component) and a trivalent or higher polycarboxylic acid compound (at most 50 mol% of the carboxylic acid component). A polyester obtained by polycondensation with a carboxylic acid component contained as a main component, an average dispersion diameter of the release agent in the color toner is 0.1 to 3 μm, and a particle diameter of the external additive is 4 to The present invention relates to a color toner having a thickness of 200 nm and a content of 1 to 5 parts by weight based on 100 parts by weight of a toner before being treated with an external additive, and a non-magnetic one-component developing method using the color toner.

[0007]

DESCRIPTION OF THE PREFERRED EMBODIMENTS The binder resin used in the toner of the present invention contains polyester as a main component. The content of the polyester is from 50 to 100% by weight, preferably from 90 to 100% by weight in the binder resin, from the viewpoints of the dispersibility, fixability and chargeability of the colorant.
Desirably, it is 100% by weight, more preferably 100% by weight. In addition, as resins usable other than polyester, polyamide, acrylic resin, epoxy resin,
Polycarbonate, polyurethane, silicone resin,
Fluorinated resins, petroleum resins, natural and synthetic waxes, and the like.

The polyester has the formula (I):

[0009]

Embedded image

(Wherein R ¹ is an alkylene group having 2 to 4 carbon atoms, x and y are positive numbers, and the sum of x and y is 1 to 16). It is obtained by polycondensing a dihydric alcohol component with a carboxylic acid component containing a dicarboxylic acid compound and a trivalent or higher polycarboxylic acid compound.

In the present invention, the polyhydric alcohol component comprises
From the viewpoint of dispersibility and fixability of the colorant, the compound represented by the formula (I) is contained in an amount of 5 mol% or more, preferably 50 mol% or more.

The compounds represented by the formula (I) include polyoxypropylene (2.2) -2,2-bis (4-hydroxyphenyl) propane and polyoxyethylene (2.
2) Bisphenol A alkylene oxide (average addition mole number 1 to 16) adduct such as -2,2-bis (4-hydroxyphenyl) propane and the like. Further, as other polyhydric alcohol components, ethylene glycol,
Examples thereof include propylene glycol, glycerin, pentaerythritol, trimethylolpropane, hydrogenated bisphenol A, sorbitol, and alkylene oxide adducts thereof, and preferably contain at least one of these.

The carboxylic acid component contains a dicarboxylic acid compound in an amount of 50 mol% or more, preferably 50 to 95 mol%, and a trivalent or higher polycarboxylic acid compound in an amount of 50 to 95 mol% from the viewpoint of color reproducibility and fixability. Mol% or less, preferably 5 to
It is preferable to contain 50 mol%.

As the dicarboxylic acid compound, phthalic acid,
Isophthalic acid, terephthalic acid, fumaric acid, maleic acid,
Dodecenyl succinic acid, carbon number 1 such as octyl succinic acid
Examples include succinic acid substituted with 20 alkyl groups or alkenyl groups having 2 to 20 carbon atoms, anhydrides of these acids, and alkyl (1 to 8 carbon atoms) esters.

Examples of the trivalent or higher polycarboxylic acid compound include trimellitic acid, pyromellitic acid, anhydrides of these acids, and alkyl (C1-8) esters.

The polycondensation of the polyhydric alcohol component and the carboxylic acid component can be carried out, for example, by reacting at 180 to 250 ° C. in an inert gas atmosphere, if necessary, using an esterification catalyst. .

The release agent used in the toner of the present invention includes natural waxes such as carnauba wax and rice wax, synthetic waxes such as low-molecular-weight polypropylene, low-molecular-weight polyethylene and sasol wax, and coal-based waxes such as montan wax. Among them, carnauba wax is preferable from the viewpoint of compatibility with the polyester resin.

The melting point of the release agent is preferably from 65 to 110 ° C, more preferably from 70 to 100 ° C, from the viewpoint of storage stability and offset resistance.

The content of the release agent is preferably 1 to 10 parts by weight, more preferably 1.5 to 5 parts by weight, based on 100 parts by weight of the binder resin, from the viewpoint of offset resistance and fixing property. is there.

From the viewpoint of energy efficiency, the endothermic amount of the release agent in the toner is preferably 5 to 25 mj / mg of toner, more preferably 7 to 15 mj / mg of toner.
It is.

The average dispersion diameter of the release agent in the color toner of the present invention is such that an excellent effect of preventing offset can be obtained.
In addition, in order to prevent filming of the toner on the photosensitive member and obtain a stable image, 0.1 to 3 μm, preferably 0.1 to 3 μm is preferable.
It is 4-1.5 μm, more preferably 0.6-1.2 μm.

As the colorant used in the toner of the present invention, dyes and pigments which have been used as conventional full-color colorants can be used without particular limitation.
As the yellow pigment, C.I. I. Pigment Yellow (hereinafter referred to as "PY") 17, P.I. Y. 93,
P. Y. 128, p. Y. 151, p. Y. 155,
P. Y. 173, p. Y. 180, p. Y. 185 and Solvent Yellow (hereinafter referred to as “SY”) 16
One or more magenta pigments selected from the group consisting of I. Pigment Red (hereinafter, “PR”)
57), p. R. 122 and P.E. R. 184
And at least one cyan pigment selected from the group consisting of C.I. I. Pigment Blue (hereinafter referred to as “PB”) 15: 3, P.I. B. 15, p. B. 15: 4 and C.I. I. Pigment Green 7 (hereinafter referred to as "PG").
Each is preferable from the viewpoint of color reproducibility. The amount of the colorant used is preferably 0.5 to 10 parts by weight based on 100 parts by weight of the binder resin. The toner of the present invention can be used as a full-color toner by blending these colorants.

In the present invention, a relatively large amount of an external additive is used in order to impart fluidity to the toner and more effectively prevent filming on the photoreceptor.

The external additives used in the toner of the present invention include silicon dioxide (silica), titanium dioxide (titania), aluminum oxide, zinc oxide, magnesium oxide, cerium oxide, iron oxide, copper oxide, tin oxide and the like. Among these, silica is preferable from the viewpoint of imparting chargeability, and in the present invention, in particular, hydrophobic silica in which a hydrophobizing agent such as hexamethyldisilazane or silicone oil is adsorbed on the silica surface is used. preferable.

Commercially available hydrophobic silica that has been subjected to a hydrophobizing treatment includes “Aerosil R-972” (manufactured by Nippon Aerosil Co., Ltd., average particle size: about 16 nm), and “HDKH”.
2000 "(manufactured by Wacker Chemicals, average particle size: about 1
2 nm), "CABOSIL TS-530" (manufactured by Cabrack, average particle size: about 8 nm) and the like can be used. These external additives may be used alone or in combination of two or more.

The particle size of the external additive is 4 to 200 nm, preferably 8 to 30 nm. The particle size of the external additive can be determined from a photograph obtained using a scanning electron microscope or a transmission electron microscope.

The content of the external additive is 1 to 5 parts by weight, preferably 1.5 to 3.5 parts by weight, based on 100 parts by weight of the toner before the treatment with the external additive. However, when hydrophobic silica is used as the external additive, the desired effect as described above can be obtained by including 1 to 3 parts by weight of the hydrophobic silica with respect to 100 parts by weight of the toner before the treatment with the external additive. Is obtained.

The toner of the present invention is not particularly limited, and examples thereof include a pulverized toner, a polymerized toner, and a capsule toner. Examples of the toner include those obtained by a conventionally known method such as a kneading and pulverizing method, a spray drying method, and a polymerization method. It can be produced by adding an external additive to the powder. For example, after uniformly mixing a binder resin, a colorant, a release agent, and the like with a mixer such as a Henschel mixer, a kneader, an extruder, a continuous two-roll type kneader, and the like, preferably a continuous two-roll type The mixture is melt-kneaded using a kneader, cooled, pulverized and classified to obtain a powder. In the present invention, the conditions of the kneading machine used are adjusted so that the average dispersion diameter of the release agent in the obtained toner is 0.1 to 3 μm, for example, in the case of a continuous two-roll kneading machine, , 50 to 100 rotations / minute, the low-speed roll at a low rotation of 10 to 30 rotations / minute, and the roll temperature at 70 to 150 ° C. Thereafter, the obtained powder and the external additive are stirred and mixed by a high-speed stirrer such as a super mixer or a Henschel mixer, so that the external additive is adhered to the surface of the toner to obtain the toner of the present invention. it can.

The thus obtained toner of the present invention preferably has a weight average particle diameter of usually 3 to 10 μm.

The toner of the present invention further comprises a charge control agent,
Conductive filler, extender, reinforcing fillers such as fibrous substances,
Additives such as antioxidants and antioxidants may be added as appropriate.

The glass transition point of the thus obtained toner of the present invention is from 56 to 75 ° C., preferably from 60 to 65 ° C., from the viewpoints of storage stability, filming prevention and fixability.

The water content of the toner of the present invention is 0.1 to 0.5% by weight, preferably 0.15 to 0.3% by weight, in order to obtain good chargeability.

The color toner of the present invention is used alone as a developer when it contains a magnetic fine powder, as a non-magnetic one-component developer when it does not contain a magnetic fine powder, or as a mixture with a carrier. Although used as a two-component developer, it is preferably used as a non-magnetic one-component developer because of its excellent chargeability and offset property.

Further, the present invention provides a non-magnetic one-component developing method using the color toner of the present invention. As the developing method of the present invention, for example, a developing device having a non-magnetic developing roll and a blade that uniformly regulates the thickness of a toner layer formed on the developing roll and imparts a charge to the toner, A method using a color toner is exemplified.

Further, since the color toner of the present invention has extremely excellent offset resistance, it can be used in a fixing device without an oil supply device.

[0036]

[Example] [Glass transition point of resin and toner and melting point and endothermic amount of release agent] Differential scanning calorimeter "DSC210"
(Seiko Electronics Co., Ltd.) using a heating rate of 10 ° C.
/ Min.

[Moisture Content of Toner] 100 g of the toner is dried in a drier at 50 ° C. under a reduced pressure of about 1 kPa for 24 hours, and the rate of weight change before and after the drying is measured.

[Average Dispersion Diameter of Release Agent] (1) The toner embedded in the epoxy resin is cut into a thin section having a thickness of about 100 nm in a frozen state, and dispersed into the toner using a transmission electron microscope. Measure the major axis and minor axis of the mold. (2) The domain diameter of the release agent is determined from the values of the major axis and the minor axis. The domain diameter is obtained from the formula of (major axis + minor axis) / 2. (3) According to the methods (1) and (2), 50 domain diameters of the release agent dispersed in the toner are measured, and the value of the obtained domain diameter (D _p ) is calculated by the following formula:

[0039]

(Equation 1)

(Where n _p is the number of dispersed particles having a domain diameter of D _p ), and the obtained value is defined as the average dispersed diameter.

[Kneading Conditions A] Using a continuous two-roll kneader having a roll outer diameter of 0.12 m and an effective roll length of 0.8 m, the rotation speed of the high rotation roll was set to 75 rotations / minute, The number of rotations is 50 rotations / minute, and the roll gap is 0.0001.
m, the temperature of the heating medium on the material input side of the high speed roll is 100
℃, 80 ℃
Set to. The feed rate of the mixture is 4 kg / hour, and the average residence time is about 10 minutes.

[Kneading Conditions B] The conditions are the same as those of the kneading conditions A, except that the temperature of the heating medium on the material input side of the high-speed roll is set to 130 ° C.

[Kneading condition C] The total length of the kneading portion is 1560 m
A co-rotating twin-screw extruder with m, screw diameter of 42 mm and barrel inner diameter of 43 mm is used for kneading. The roll rotation speed is set to 200 rotations / minute, the heating temperature in the roll is set to 100 ° C., the feed rate of the mixture is 40 kg / hour, and the average residence time is about 21 seconds.

Resin Production Example 1 1 mol of polyoxyethylene (2.2) -2,2-bis (4-hydroxyphenyl) propane, polyoxypropylene (2.2) -2,2-bis (4-hydroxyphenyl) ) While stirring 3 mol of propane, 3.6 mol of terephthalic acid, 0.3 mol of trimellitic acid and 4 g of dibutyltin oxide at 230 ° C under a nitrogen atmosphere, until the softening point measured by ASTME 28-67 reaches 110 ° C. The reaction was performed to obtain resin A. The glass transition point of the resin A was 60 ° C.

Resin Production Example 2 1 mol of polyoxyethylene (2.2) -2,2-bis (4-hydroxyphenyl) propane, polyoxypropylene (2.2) -2,2-bis (4-hydroxyphenyl) ) 3 mol of propane, 1.8 mol of terephthalic acid, 2.7 mol of trimellitic acid and 4 g of dibutyltin oxide were stirred at 230 ° C under a nitrogen atmosphere until the softening point measured by ASTME 28-67 reached 138 ° C. The reaction was performed to obtain resin B. The glass transition point of the resin B was 66 ° C.

Resin Production Example 3 0.15 mol of polyoxyethylene (2.2) -2,2-bis (4-hydroxyphenyl) propane, polyoxypropylene (2.2) -2,2-bis (4- 2.85 mol of hydroxyphenyl) propane, terephthalic acid 1.1
Mol, 1.6 mol of adipic acid and 4 g of dibutyltin oxide were stirred under a nitrogen atmosphere at 230 ° C. while ASTM E2
The reaction was carried out until the softening point measured by 8-67 reached 99 ° C. to obtain a resin C. The glass transition point of resin C is 56
° C.

Examples 1 to 16 100 parts by weight of resin A as a binder resin, 5 parts by weight of "Carnauba Wax C1" (manufactured by Kato Yoko Co., Ltd., melting point: 81 ° C.) as a colorant and a release agent shown in Table 1 After 1 part by weight of "LR-147" (manufactured by Nippon Carlit Co., Ltd.) as a charge control agent was sufficiently mixed with a Henschel mixer, the mixture was melt-kneaded under kneading conditions A, cooled, and coarsely pulverized. Then, it is pulverized and classified by a jet mill, and has a weight average particle diameter of 7.5 μm.
m were obtained. To 100 parts by weight of the obtained powder, 2.0 parts by weight of "Aerosil R-972" (manufactured by Nippon Aerosil Co., Ltd.) as an external additive was added, and the mixture was mixed with a Henschel mixer to perform a surface treatment on the powder. To obtain toners Y1 to M9, toners M1 to M3, and toners C1 to C4.

[0048]

[Table 1]

Examples 17 and 18 In Example 16, "LR-14" was used as a charge control agent.
7 was replaced with 1 part by weight of "Bontron E-81" (manufactured by Orient Chemical Industries) and 1 part by weight of "Bontron E-84" (manufactured by Orient Chemical Industries), respectively, except that toner C5 was similarly used. Thus, toner C6 was obtained.

Example 19 Toner C was prepared in the same manner as in Example 16 except that the amount of “Carnauba wax C1” was changed to 10 parts by weight.
7 was obtained.

Example 20 and Comparative Example 1 Toner C8 and toner C9 were obtained in the same manner as in Example 19 except that the kneading conditions B and C were used instead of the kneading conditions A, respectively.

Examples 21 and 22 In Example 16, instead of "Carnauba wax C1", "SP-105" (manufactured by Sasol Co., Ltd.)
5 parts by weight of polyethylene wax, melting point: 90 ° C.)
P-056 "(manufactured by Mitsui Chemicals, Inc., polypropylene wax, melting point: 92 ° C.)
Similarly, toner C10 and toner C11 were obtained.

Examples 23 and 24 In Example 16, "Aerosil R-
"HDK H2000" (manufactured by Wacker Chemicals) 2.0 parts by weight instead of "972"
Toner C12 and toner C13 were obtained in the same manner except that 1.0 part by weight of "0" (manufactured by Cabrack) was used.

Comparative Example 2 A toner C14 was obtained in the same manner as in Example 16, except that the amount of “Aerosil R-972” was changed to 0.8 parts by weight.

Comparative Example 3 In Example 16, "Aerosil R-
"Aerosil R-9" instead of 2.0 parts by weight
72 "3.0 parts by weight and" STT-30A "(manufactured by Titanium Industry Co., Ltd., raw material: titanium dioxide, average particle diameter: about 40 n)
m) A toner C15 was obtained in the same manner except that 2.5 parts by weight of the mixture was used.

Comparative Examples 4 and 5 Toners C16 and C17 were obtained in the same manner as in Example 16, except that 100 parts by weight of the resin B and the resin C were used instead of the resin A.

The water content of all the toners obtained in the above Examples and Comparative Examples was 0.2% by weight. Further, the toner C16 (Comparative Example 4), the toner C17
The glass transition point of Comparative Example 5 was 66 ° C. and 54 ° C., respectively.
The glass transition point of all other toners was 58 ° C., except at ℃. Further, Table 2 shows the average dispersion diameter and the endothermic amount of the release agent in each toner.

[0058]

[Table 2]

Test Example 1 [Evaluation of Offset Resistance] 5 parts by weight of toner and 95 parts by weight of a ferrite carrier coated with a silicone resin and having a particle diameter of 50 μm were mixed in a ball mill, and each of yellow, magenta and cyan was mixed. A developer was used. Each of the obtained developers is referred to as “Pretail 5
50 "(manufactured by Ricoh Co., Ltd.), and evaluated according to the following evaluation criteria from the fixable temperature range. Table 2 shows the results.

[Evaluation Criteria] A: The fixable temperature range is 50 ° C. or more, which is particularly good for practical use. ○: The fixable temperature range is 30 ° C. or more and less than 50 ° C., and there is no problem in actual use. Δ: Fixable temperature range is 10 ° C. or more and less than 30 ° C. and there is no problem in actual use ×: Fixable temperature range is less than 10 ° C. and a problem occurs in actual use

Test Example 2 [Evaluation of Storage Property and Durability] A non-magnetic one-component developing apparatus equipped with a heat roll, “Page Presto N” was used in the combinations shown in Table 3 in the same amounts of yellow toner, magenta toner and cyan toner. -4 "(manufactured by Casio Computer) and" Tektronix Phaser 56 "
0 "(manufactured by Sony Tektronix, Inc.), and printing at a printing rate of 4% for each color was continuously performed on 10,000 sheets. The state of aggregation of each remaining toner and the image quality of the 10,000th sheet are visually determined,
The storage stability and durability in the developing device were evaluated according to the following evaluation criteria. The results are shown in Tables 2 and 3.

[Evaluation Criteria of Storage] 凝集: No aggregation is observed at all ○: Almost no aggregation is observed ×: Aggregation is observed

[Evaluation Criteria of Durability] A: Image is particularly clear O: Image is clear Δ: Image is slightly unclear X: Image is poor, (filming) indicates toner on photoreceptor Indicates the occurrence of fusion

Test Example 3 [Evaluation of Color Reproducibility] Equal amounts of yellow toner, magenta toner and cyan toner
In the combinations shown in Table 3 and provided with a heat roll.
Non-magnetic one-component developing device "Page Presto N-4"
O-Computer Co., Ltd.) and "Tektronix Phaser 56
0 ”(manufactured by Sony Tektronix, Inc.)
Adjust the assemblage and adjust the colors of yellow, magenta and cyan
0.6mg / cm^TwoAnd then a solid yellow picture
Image, magenta solid image, cyan solid image, process
Solid image, process green solid image, process
-Blue solid images were collected. A of each image^*Passing
And b ^*With "X-Rite 938" (manufactured by X-Rite)
Measure and a^*And b^*Are plotted on the chromaticity diagram. Got
By measuring the area of the hexagon, the following evaluation criteria
Therefore, it was evaluated. Table 3 shows the results.

[Evaluation Criteria] A: The area exceeds 6000 and is particularly good for practical use. A: The area is 3500 to 6000 and there is no problem in actual use. X: The area is less than 3500. There is a problem in practical use. (C) shows that the a ^* and b ^* values of the cyan toner have defects and the area is small.

Each image was output up to 6,000 sheets, and the same result was obtained.

[0067]

[Table 3]

From the above results, the toner of the comparative example is inferior in any of offset resistance, storage stability, durability and color reproducibility, whereas the toner of the example is excellent in all of these properties. You can see that it is.

[0069]

According to the present invention, it is possible to provide a color toner which does not cause filming on a photoreceptor, hardly causes an offset even during heat roll fixing, and has excellent storage stability, durability and color reproducibility. Became possible.

 ──────────────────────────────────────────────────続 き Continued on the front page (72) Inventor Toshihiro Hattori 1334 Minato, Wakayama, Kao Corporation Research Institute (72) Inventor Hironori Nagasaki 1334 Minato, Wakayama City Kao Corporation Research Institute (72) Inventor Yoshifumi Tokuhisa 1334 Minato, Wakayama City Kao Research Institute

Claims (5)

[Claims] 1. A color toner having a glass transition point of 56 to 75 ° C. and a water content of 0.1 to 0.5% by weight, containing a binder resin, a release agent, a colorant and an external additive. Wherein the binder resin has the formula (I): (Wherein, R ¹ is an alkylene group having 2 to 4 carbon atoms, x and y
Represents a positive number, and the sum of x and y is 1 to 16) (5 mol% or more of the polyhydric alcohol component), and a dicarboxylic acid compound (carboxylic acid). A polyester obtained by polycondensing a carboxylic acid component containing a polyvalent carboxylic acid compound having a valency of 3 or more (50 mol% or less in the carboxylic acid component) as a main component, The average dispersion diameter of the colorant in the color toner is 0.1 to 3 μm, the particle size of the external additive is 4 to 200 nm, and the content thereof is 1 to 100 parts by weight of the toner before the treatment with the external additive. 5 to 5 parts by weight of a color toner. 2. The color toner according to claim 1, wherein the release agent has a melting point of 65 to 110 ° C. 3. The color toner according to claim 1, wherein the heat release amount of the release agent is 5 to 25 mj / mg of toner. 4. The method according to claim 1, wherein the coloring agent is C.I. I. Pigment Yellow 17, C.I. I. Pigment Yellow 93, C.I. I. Pigment Yellow 128, C.I. I. Pigment Yellow 1
51, C.I. I. Pigment yellow 155, C.I. I. Pigment Yellow 173, C.I. I. Pigment yellow 180, C.I. I. One or more yellow pigments selected from the group consisting of CI Pigment Yellow 185 and Solvent Yellow 162; I. Pigment Red 57: 1,
C. I. Pigment Red 122 and C.I. I. Pigment Red 184, one or more magenta pigments selected from the group consisting of C.I. I. Pigment Blue 15: 3,
C. I. Pigment Blue 15, C.I. I. Pigment Blue 15: 4 and C.I. I. The color toner according to any one of claims 1 to 3, which is one or more cyan pigments selected from the group consisting of CI Pigment Green 7. 5. A non-magnetic one-component developing method using the color toner according to claim 1.