JP2000153229A5 - - Google Patents
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- Publication number
- JP2000153229A5 JP2000153229A5 JP1999322544A JP32254499A JP2000153229A5 JP 2000153229 A5 JP2000153229 A5 JP 2000153229A5 JP 1999322544 A JP1999322544 A JP 1999322544A JP 32254499 A JP32254499 A JP 32254499A JP 2000153229 A5 JP2000153229 A5 JP 2000153229A5
- Authority
- JP
- Japan
- Prior art keywords
- layer
- compound
- polythiophene
- dielectric constant
- allowed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000203 mixture Substances 0.000 description 4
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Natural products NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- 229920001940 conductive polymer Polymers 0.000 description 2
- 229920000447 polyanionic polymer Polymers 0.000 description 2
- 229920000123 polythiophene Polymers 0.000 description 2
- ABLZXFCXXLZCGV-UHFFFAOYSA-L CHEBI:8154 Chemical class [O-]P([O-])=O ABLZXFCXXLZCGV-UHFFFAOYSA-L 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 150000003462 sulfoxides Chemical class 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
Description
【特許請求の範囲】
【請求項１】
−ポリチオフェン、
ポリアニオン化合物及び
ε≧１５の誘電率を有する非プロトン性化合物
を含有する水性組成物を準備し；
−該組成物を物体上に適用して層を形成せしめ；
−該層を乾燥して該物体上に導電性ポリマー層を形成せしめる
段階を含んでなり、該物体及び該層を１００℃未満の温度に保ち、該導電性ポリ
マー層が最高で２ｋΩ／平方の抵抗率を有することを特徴とする物体上にポリマ
ー性導電層を形成するための方法。
【請求項２】
ディスプレー及びエレクトロルミネセンス装置における透明電極としての請求項１に記載のパターン形成された導電層の使用。
【請求項３】
−ポリチオフェン、
−ポリアニオン化合物及び
−スルホン、スルホキシド、有機リン酸エステル、有機ホスホネート、有機ホスファミド、尿素、尿素の誘導体及びそれらの混合物から成る群より選ばれるε≧１５の誘電率を有する非プロトン性化合物
を含有する水性組成物。
[Claims]
(1)
-Polythiophene,
Providing an aqueous composition comprising a polyanion compound and an aprotic compound having a dielectric constant of ε ≧ 15;
- allowed a layer by applying the composition onto an object;
- drying the said layer comprises the step of Ru allowed forming a conductive polymer layer on said object, maintaining said object and said layer to a temperature below 100 ° C., 2 k.OMEGA / square conductive polymer layer is the highest A method for forming a polymeric conductive layer on an object, characterized by having a resistivity of:
(2)
Use of the patterned conductive layer according to claim 1 as a transparent electrode in displays and electroluminescent devices.
(3)
-Polythiophene,
Containing a polyanion compound and an aprotic compound having a dielectric constant of ε ≧ 15 selected from the group consisting of sulfones, sulfoxides, organophosphates, organic phosphonates, organic phosphamides, ureas, urea derivatives and mixtures thereof. Aqueous composition.
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP98203951 | 1998-11-17 | ||
| EP98204382A EP1013413B1 (en) | 1998-12-21 | 1998-12-21 | Electroconductive glass laminate |
| EP98204382.0 | 1998-12-21 | ||
| EP98203951.3 | 1998-12-21 |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| JP2000153229A JP2000153229A (en) | 2000-06-06 |
| JP2000153229A5 true JP2000153229A5 (en) | 2007-01-11 |
| JP4491098B2 JP4491098B2 (en) | 2010-06-30 |
Family
ID=26150906
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP32254499A Expired - Fee Related JP4491098B2 (en) | 1998-11-17 | 1999-11-12 | Method for forming a conductive polythiophene layer at low temperature |
Country Status (2)
| Country | Link |
|---|---|
| JP (1) | JP4491098B2 (en) |
| DE (1) | DE69919661T2 (en) |
Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2003000765A2 (en) * | 2001-06-22 | 2003-01-03 | Agfa-Gevaert | Flexographic ink containing a polymer or copolymer of a 3,4-dialkoxythiophene |
| JP4208720B2 (en) * | 2001-12-04 | 2009-01-14 | アグフア−ゲヴエルト，ナームローゼ・フエンノートシヤツプ | Composition comprising a polymer or copolymer of 3,4-dialkoxythiophene and a non-aqueous solvent |
| JP3940625B2 (en) * | 2002-03-29 | 2007-07-04 | 株式会社東芝 | Ink for organic EL hole injection layer and manufacturing method thereof, manufacturing method of organic EL display device, and organic EL display device |
| KR100498577B1 (en) * | 2002-07-26 | 2005-07-01 | 이찬우 | EMI paint and the method for making it |
| AU2003262551A1 (en) * | 2002-08-23 | 2004-03-11 | Agfa-Gevaert | Layer configuration with improved stability to sunlight exposure |
| CN100594560C (en) * | 2003-06-20 | 2010-03-17 | 爱克发-格法特公司 | Process for preparing electroconductive coatings |
| JP2006028214A (en) * | 2004-07-12 | 2006-02-02 | Nagase Chemtex Corp | Method for producing aqueous dispersion of complex of poly(3,4-dialkoxythiophene) with polyanion |
| US7387856B2 (en) * | 2005-06-20 | 2008-06-17 | Industrial Technology Research Institute | Display comprising liquid crystal droplets in a hydrophobic binder |
| EP1953178B1 (en) | 2005-11-17 | 2018-06-13 | Heraeus Deutschland GmbH & Co. KG | Process for producing aqueous dispersion of composite of poly(3,4-dialkoxythiophene) with polyanion |
| JP2009255546A (en) * | 2008-03-28 | 2009-11-05 | Nagaoka Sangyo Kk | Method for manufacturing resin laminate, and laminated body |
| JP2010090397A (en) * | 2010-01-29 | 2010-04-22 | Nagase Chemtex Corp | Method for manufacturing water dispersion of composite of poly(3,4-dialkoxy-thiophene) and poly-anions |
| JP5952551B2 (en) | 2011-12-12 | 2016-07-13 | Ｎｅｃトーキン株式会社 | Conductive polymer composition and method for producing the same, method for producing conductive polymer material, method for producing conductive substrate, method for producing electrode, method for producing electronic device, and method for producing solid electrolytic capacitor |
| JP5872872B2 (en) | 2011-12-12 | 2016-03-01 | Ｎｅｃトーキン株式会社 | Method for producing conductive polymer composition, method for producing conductive polymer material, method for producing conductive substrate, method for producing electrode, and method for producing solid electrolytic capacitor |
Family Cites Families (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4211461A1 (en) * | 1992-04-06 | 1993-10-07 | Agfa Gevaert Ag | Antistatic plastic parts |
| TW247319B (en) * | 1992-06-17 | 1995-05-11 | Japat Ltd | |
| ATE228545T1 (en) * | 1994-05-06 | 2002-12-15 | Bayer Ag | CONDUCTIVE COATINGS |
-
1999
- 1999-10-27 DE DE69919661T patent/DE69919661T2/en not_active Expired - Lifetime
- 1999-11-12 JP JP32254499A patent/JP4491098B2/en not_active Expired - Fee Related
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