JP2000073087A - Liquid detergent composition for house - Google Patents
Liquid detergent composition for houseInfo
- Publication number
- JP2000073087A JP2000073087A JP10243161A JP24316198A JP2000073087A JP 2000073087 A JP2000073087 A JP 2000073087A JP 10243161 A JP10243161 A JP 10243161A JP 24316198 A JP24316198 A JP 24316198A JP 2000073087 A JP2000073087 A JP 2000073087A
- Authority
- JP
- Japan
- Prior art keywords
- detergent composition
- liquid detergent
- weight
- alkyl group
- component
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003599 detergent Substances 0.000 title claims abstract description 18
- 239000007788 liquid Substances 0.000 title claims abstract description 15
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 12
- -1 diethylene glycol monoalkyl ether Chemical class 0.000 claims abstract description 11
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 claims abstract description 8
- MTHSVFCYNBDYFN-UHFFFAOYSA-N anhydrous diethylene glycol Natural products OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims abstract description 8
- 125000004432 carbon atom Chemical group C* 0.000 claims description 11
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 150000008051 alkyl sulfates Chemical class 0.000 claims description 4
- IVSZLXZYQVIEFR-UHFFFAOYSA-N 1,3-Dimethylbenzene Natural products CC1=CC=CC(C)=C1 IVSZLXZYQVIEFR-UHFFFAOYSA-N 0.000 claims description 3
- 229940071104 xylenesulfonate Drugs 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 abstract description 10
- 239000004800 polyvinyl chloride Substances 0.000 abstract description 10
- 239000011347 resin Substances 0.000 abstract description 9
- 229920005989 resin Polymers 0.000 abstract description 9
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 abstract 4
- 125000005907 alkyl ester group Chemical group 0.000 abstract 2
- DSYVTLPHGJLVKD-UHFFFAOYSA-M sodium 1,5-dimethylcyclohexa-2,4-diene-1-sulfonate Chemical compound [Na+].C1(CC(=CC=C1)C)(C)S(=O)(=O)[O-] DSYVTLPHGJLVKD-UHFFFAOYSA-M 0.000 abstract 1
- 238000004140 cleaning Methods 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- HZAXFHJVJLSVMW-UHFFFAOYSA-N 2-Aminoethan-1-ol Chemical compound NCCO HZAXFHJVJLSVMW-UHFFFAOYSA-N 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 238000005406 washing Methods 0.000 description 4
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- XXJWXESWEXIICW-UHFFFAOYSA-N diethylene glycol monoethyl ether Chemical compound CCOCCOCCO XXJWXESWEXIICW-UHFFFAOYSA-N 0.000 description 2
- 229940075557 diethylene glycol monoethyl ether Drugs 0.000 description 2
- 230000000149 penetrating effect Effects 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- DJCYDDALXPHSHR-UHFFFAOYSA-N 2-(2-propoxyethoxy)ethanol Chemical compound CCCOCCOCCO DJCYDDALXPHSHR-UHFFFAOYSA-N 0.000 description 1
- YJTIFIMHZHDNQZ-UHFFFAOYSA-N 2-[2-(2-methylpropoxy)ethoxy]ethanol Chemical compound CC(C)COCCOCCO YJTIFIMHZHDNQZ-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000003242 anti bacterial agent Substances 0.000 description 1
- 239000002216 antistatic agent Substances 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 238000011109 contamination Methods 0.000 description 1
- 239000002781 deodorant agent Substances 0.000 description 1
- 229940028356 diethylene glycol monobutyl ether Drugs 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 230000001771 impaired effect Effects 0.000 description 1
- 239000000077 insect repellent Substances 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- JCGNDDUYTRNOFT-UHFFFAOYSA-N oxolane-2,4-dione Chemical compound O=C1COC(=O)C1 JCGNDDUYTRNOFT-UHFFFAOYSA-N 0.000 description 1
- 238000005498 polishing Methods 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 239000005871 repellent Substances 0.000 description 1
- 230000002940 repellent Effects 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Detergent Compositions (AREA)
Abstract
Description
【０００１】[0001]
【発明の属する技術分野】本発明は、住居用液体洗浄剤
組成物に関し、更に詳しくはポリ塩化ビニル等の樹脂を
使用した床や壁紙の表面の汚れを洗浄するのに適した液
体洗浄剤組成物に関する。BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a liquid detergent composition for dwelling, and more particularly to a liquid detergent composition suitable for cleaning floor and wallpaper surfaces using a resin such as polyvinyl chloride. About.
【０００２】[0002]
【従来の技術】従来の住居用洗浄剤には、ポリオキシエ
チレンアルキルエーテル等のノニオン系界面活性剤やア
ルキルフェノキシフェニルジスルホン酸ナトリウム、α
−オレフィンスルホン酸塩等のアニオン系界面活性剤と
溶剤を配合した洗浄剤が使用されている（例えば、特開
平３−１８２５９６号公報）。2. Description of the Related Art Conventional household detergents include nonionic surfactants such as polyoxyethylene alkyl ether, sodium alkylphenoxyphenyldisulfonate, α
-A detergent containing an anionic surfactant such as an olefin sulfonate and a solvent is used (for example, JP-A-3-182596).
【０００３】一方、最近の住宅では、ポリ塩化ビニル等
の樹脂を使用した床や壁紙が多く用いられているが、ポ
リ塩化ビニル製の床や壁紙は汚れが固着しやすい。更
に、樹脂製の床や壁紙には、デザイン性や、滑り止め機
能のため表面に凹凸を付けたものが多く、付着した汚れ
が洗浄されにくく、これらの樹脂製の床や壁紙に適し
た、強力な洗浄力を持つ洗浄剤が望まれていた。On the other hand, in recent homes, floors and wallpapers using resin such as polyvinyl chloride are often used, but dirt is likely to adhere to floors and wallpapers made of polyvinyl chloride. In addition, many resin floors and wallpapers have irregularities on the surface for design and anti-slip function. A cleaning agent having detergency has been desired.
【０００４】[0004]
【発明が解決しようとする課題】本発明は上記問題に鑑
み、ポリ塩化ビニル等の樹脂を使用した床や壁紙の表面
の汚れに対して、高い洗浄力を有する住居用液体洗浄剤
組成物を提供する。DISCLOSURE OF THE INVENTION In view of the above problems, the present invention provides a liquid detergent composition for residential use which uses a resin such as polyvinyl chloride and has a high detergency against stains on the floor and wallpaper surfaces. I do.
【０００５】[0005]
【課題を解決するための手段】本発明の住居用液体洗浄
剤組成物は、下記（ａ）、（ｂ）、（ｃ）、（ｄ）を含
有してなり、（ａ）と（ｂ）の合計で０．５〜７重量
部、（ｃ）１〜１０重量部、（ｄ）１〜１０重量部、か
つ、（ａ）と（ｂ）の重量比が（ａ）／（ｂ）＝１／９
〜９／１となされていることを特徴とする。 （ａ）アルキル基の炭素数が１０〜１６であり、エチレ
ンオキサイドが１〜５モル付加されたアルキル硫酸エス
テル塩 （ｂ）アルキル基の炭素数が８であり、エチレンオキサ
イドが１〜５モル付加されたアルキル硫酸エステル塩 （ｃ）メタキシレンスルホン酸ナトリウム （ｄ）アルキル基の炭素数が１〜４であるジエチレング
リコールモノアルキルエーテルThe liquid detergent composition for dwelling of the present invention comprises the following (a), (b), (c) and (d), and (a) and (b): 0.5 to 7 parts by weight, (c) 1 to 10 parts by weight, (d) 1 to 10 parts by weight, and the weight ratio of (a) and (b) is (a) / (b) = 1/9
９9/1. (A) an alkyl sulfate having 10 to 16 carbon atoms in an alkyl group and 1 to 5 moles of ethylene oxide added thereto (b) an alkyl sulfate having 8 carbon atoms and 1 to 5 moles of ethylene oxide added thereto (C) sodium meta-xylene sulfonate (d) diethylene glycol monoalkyl ether having 1 to 4 carbon atoms in the alkyl group
【０００６】本発明の住居用液体洗浄剤組成物は、成分
（ａ）、（ｂ）および（ｃ）の組み合わせにより汚れに
強力に浸透し、成分（ｄ）の作用により、汚れを可溶化
するため、床や壁紙表面の頑固な汚れに対しても、高い
洗浄力を有する。[0006] The liquid detergent composition for residential use of the present invention penetrates strongly into soil by the combination of the components (a), (b) and (c), and solubilizes the soil by the action of the component (d). Therefore, it has a high detergency against stubborn dirt on the floor and wallpaper surface.
【０００７】本発明に用いられる（ａ）成分は、アルキ
ル基の炭素数が１０〜１６でエチレンオキサイドが１〜
５モル付加されたアルキル硫酸エステル塩であり、好ま
しくはアルキル基の炭素数が１２〜１４である。また、
中和塩はナトリウム、カリウム、エタノールアミン類が
好ましい。The component (a) used in the present invention comprises an alkyl group having 10 to 16 carbon atoms and an ethylene oxide having 1 to 10 carbon atoms.
It is an alkyl sulfate salt having 5 moles added, and preferably has 12 to 14 carbon atoms in the alkyl group. Also,
The neutralized salt is preferably sodium, potassium or ethanolamine.
【０００８】本発明に用いられる（ｂ）成分は、アルキ
ル基の炭素数が８でエチレンオキサイドが１〜５モル付
加されたアルキル硫酸エステル塩であり、好ましくはア
ルキル基が２−エチルヘキシルである。また、中和塩は
ナトリウム 、カリウム、エタノールアミン類が好まし
い。The component (b) used in the present invention is an alkyl sulfate salt in which the alkyl group has 8 carbon atoms and 1 to 5 mol of ethylene oxide is added, and the alkyl group is preferably 2-ethylhexyl. The neutralized salt is preferably sodium, potassium or ethanolamine.
【０００９】本発明に用いられる（ｃ）成分は、メタキ
シレンスルホン酸ナトリウムである。The component (c) used in the present invention is sodium meta-xylene sulfonate.
【００１０】本発明に用いられる（ｄ）成分は、アルキ
ル基の炭素数が１〜４であるジエチレングリコールモノ
アルキルエーテルである。（ｄ）成分の例としては、ジ
エチレングリコールモノエチルエーテル、ジエチレング
リコールモノプロピルエーテル、ジエチレングリコール
モノブチルエーテル、ジエチレングリコールイソブチル
エーテル等が挙げられる。ジエチレングリコールモノエ
チルエーテルが好適に用いられる。The component (d) used in the present invention is a diethylene glycol monoalkyl ether having an alkyl group having 1 to 4 carbon atoms. Examples of the component (d) include diethylene glycol monoethyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, diethylene glycol isobutyl ether, and the like. Diethylene glycol monoethyl ether is preferably used.
【００１１】本発明の洗浄剤組成物においては、（ａ）
成分と（ｂ）成分の合計で０．５〜７重量部、（ｃ）成
分は１〜１０重量部、（ｄ）成分は１〜１０重量部とな
るように配合される。In the cleaning composition of the present invention, (a)
The component and the component (b) are blended so that the total amount is 0.5 to 7 parts by weight, the component (c) is 1 to 10 parts by weight, and the component (d) is 1 to 10 parts by weight.
【００１２】（ａ）成分と（ｂ）成分の合計が０．５重
量部未満である場合は、汚れに対する洗浄効果が充分で
なく、７重量部を超える場合は、洗浄剤使用時に激しく
起泡するため、ふき取ることが困難になる。When the total of the components (a) and (b) is less than 0.5 parts by weight, the effect of cleaning dirt is not sufficient. Therefore, it becomes difficult to wipe off.
【００１３】（ｃ）成分が１重量部未満である場合は、
汚れに対する洗浄効果が充分でなく、１０重量部を超え
る場合は、溶液が不安定になる。When the component (c) is less than 1 part by weight,
If the cleaning effect on dirt is not sufficient and exceeds 10 parts by weight, the solution becomes unstable.
【００１４】（ｄ）成分が１重量部未満である場合は、
汚れに対する洗浄効果が充分でなく、１０重量部を超え
る場合は、増量による効果の向上が認められない。When the component (d) is less than 1 part by weight,
If the cleaning effect on dirt is not sufficient and exceeds 10 parts by weight, no improvement in the effect by increasing the amount is observed.
【００１５】（ａ）成分と（ｂ）成分の重量比は、
（ａ）／（ｂ）＝１／９〜９／１となされ、好ましくは
（ａ）／（ｂ）＝３／７〜７／３である。（ａ）／
（ｂ）が１／９未満である場合および９／１を超える場
合は、汚れに対する洗浄効果が充分でない。The weight ratio of component (a) to component (b) is
(A) / (b) = 1/9 to 9/1, and preferably (a) / (b) = 3/7 to 7/3. (A) /
When (b) is less than 1/9 or more than 9/1, the effect of cleaning dirt is not sufficient.
【００１６】本発明の洗浄剤組成物は、（ａ）、
（ｂ）、（ｃ）、（ｄ）を必須成分として含有し、これ
以外に水、アルコール等を配合して用いられる。水、ア
ルコール等を加えた溶液において（ａ）と（ｂ）の合計
が０．５〜７重量％、（ｃ）１〜１０重量％、（ｄ）１
〜１０重量％となされていることが好ましい。The cleaning composition of the present invention comprises (a)
(B), (c), and (d) are contained as essential components, and water, alcohol, and the like are blended and used in addition thereto. In a solution to which water, alcohol, or the like is added, the total of (a) and (b) is 0.5 to 7% by weight, (c) 1 to 10% by weight, (d) 1
Preferably, the amount is from 10 to 10% by weight.
【００１７】本発明の洗浄剤組成物におけるｐＨ値は、
特に限定されないが、７．０〜１２．０の範囲であるこ
とが望ましい。The pH value of the cleaning composition of the present invention is as follows:
Although it is not particularly limited, it is desirable to be in the range of 7.0 to 12.0.
【００１８】また、本発明では、上記の必須成分以外
に、通常の住居用液体洗浄剤において使用されている公
知の成分、すなわち、香料、抗菌剤、つや出し剤、撥水
剤、帯電防止剤等や、消臭剤、防虫剤等の添加剤を、こ
の発明の効果を損なわない範囲で配合できる。Further, in the present invention, in addition to the above essential components, known components used in ordinary household liquid detergents, such as fragrances, antibacterial agents, polishing agents, water repellent agents, antistatic agents, etc. Additives such as deodorants and insect repellents can be blended as long as the effects of the present invention are not impaired.
【００１９】本発明の洗浄剤組成物は樹脂製の床や壁紙
の洗浄に特に高い効果を発揮する。樹脂としては、ポリ
塩化ビニル、ポリエチレン、ポリプロピレン、ポリウレ
タン、ポリカーボネート等が例示されるが、特に、ポリ
塩化ビニルに適している。なお、本発明の住居用液体洗
浄剤組成物は、強力な浸透力を持つので、木質や畳など
に浸透してしまうため、ポリ塩化ビニル等の樹脂製品に
対する使用が適している。The cleaning composition of the present invention is particularly effective for cleaning resin floors and wallpaper. Examples of the resin include polyvinyl chloride, polyethylene, polypropylene, polyurethane, polycarbonate and the like, and are particularly suitable for polyvinyl chloride. In addition, since the liquid cleaner composition for residential use of the present invention has a strong penetrating power and penetrates into wood or tatami mats, it is suitable for use in resin products such as polyvinyl chloride.
【００２０】[0020]
【実施の形態】（実施例１、２及び比較例１、２）表１
に示す配合で液体洗浄剤組成物を調整し、以下の評価を
行った。(Examples 1 and 2 and Comparative Examples 1 and 2) Table 1
The liquid detergent composition was prepared according to the formula shown below, and the following evaluation was performed.
【００２１】＜洗浄力評価１＞調整した液体洗浄剤組成
物を用いて、洗浄水温度２５℃、洗浄剤組成物使用量１
０ｇ／水１Ｌの条件下で、人工湿式汚染布（日本洗濯化
学協会市販品）を攪拌式洗浄力試験機Terg-O-Tometerに
より洗浄し、洗浄前と洗浄後の汚染布の表面反射率の差
より洗浄率を算出した。。 洗浄率（％）＝（Ｒw −Ｒs ）／（Ｒo −Ｒs ）×１０
０ Ｒw ；洗浄後の汚染布の表面反射率 Ｒs ；洗浄前の汚染布の表面反射率 Ｒo ；汚染前の原白布の表面反射率<Evaluation of Detergency 1> Using the prepared liquid detergent composition, the temperature of the washing water was 25 ° C., and the amount of the detergent composition used was 1
Under a condition of 0 g / water 1 L, the artificial wet-stained cloth (commercially available from the Japan Laundry Chemistry Association) is washed with a stirring-type detergency tester Terg-O-Tometer. The washing rate was calculated from the difference. . Washing rate (%) = (Rw−Rs) / (Ro−Rs) × 10
0 Rw: Surface reflectance of the contaminated cloth after cleaning Rs: Surface reflectance of the contaminated cloth before cleaning Ro: Surface reflectance of the original white cloth before the contamination
【００２２】＜洗浄力評価２＞家庭での使用により汚れ
ているポリ塩化ビニル製のクッションフロアに、調整し
た液体洗浄剤組成物を自動スプレーを用いて噴霧した。
この状態で１分間放置した後、水洗した雑巾を堅く絞っ
て水拭きした。洗浄の度合いを目視によって判定した。
判定結果を表１に示す。判定基準は以下の通りである。 ○ 完全に汚れが洗浄できた。 △ 一部残っている汚れが認められた。 × 洗浄作用が認められなかった。<Evaluation of Detergency 2> The adjusted liquid detergent composition was sprayed on a cushion floor made of polyvinyl chloride which had been stained by use at home using an automatic sprayer.
After leaving for 1 minute in this state, the rag washed with water was squeezed tightly and wiped with water. The degree of washing was visually determined.
Table 1 shows the determination results. The criteria are as follows. ○ Dirt was completely cleaned. △ Some remaining stains were observed. × No cleaning action was observed.
【表１】 [Table 1]
【００２３】[0023]
【発明の効果】本発明の住居用液体洗浄剤組成物は、強
い浸透力と汚れを可溶化する性能を有するため、従来の
洗浄剤では汚れが落ちにくかったポリ塩化ビニル等の樹
脂を使用した床や壁紙の表面の汚れに対して、優れた洗
浄力を発揮する。The liquid detergent composition for residential use according to the present invention has a strong penetrative power and a property of solubilizing dirt. Therefore, a resin such as polyvinyl chloride, which is difficult to remove dirt with a conventional detergent, is used. Demonstrates excellent detergency against dirt on the floor and wallpaper surfaces.
───────────────────────────────────────────────────── フロントページの続き Ｆターム(参考） 4H003 AB31 BA12 DA04 DA07 EB22 ED02 ED29 FA06 ──────────────────────────────────────────────────続 き Continued on the front page F-term (reference) 4H003 AB31 BA12 DA04 DA07 EB22 ED02 ED29 FA06
Claims (1)
含有してなり、（ａ）と（ｂ）の合計で０．５〜７重量
部、（ｃ）１〜１０重量部、（ｄ）１〜１０重量部、か
つ、（ａ）と（ｂ）の重量比が（ａ）／（ｂ）＝１／９
〜９／１となされていることを特徴とする住居用液体洗
浄剤組成物。 （ａ）アルキル基の炭素数が１０〜１６であり、エチレ
ンオキサイドが１〜５モル付加されたアルキル硫酸エス
テル塩 （ｂ）アルキル基の炭素数が８であり、エチレンオキサ
イドが１〜５モル付加されたアルキル硫酸エステル塩 （ｃ）メタキシレンスルホン酸ナトリウム （ｄ）アルキル基の炭素数が１〜４であるジエチレング
リコールモノアルキルエーテル1. It comprises the following (a), (b), (c), and (d), and a total of 0.5 to 7 parts by weight of (a) and (b); 10 parts by weight, (d) 1 to 10 parts by weight, and the weight ratio between (a) and (b) is (a) / (b) = 1/9
Liquid detergent composition for residential use, characterized in that the composition is set to 9/1. (A) an alkyl sulfate having 10 to 16 carbon atoms in an alkyl group and 1 to 5 moles of ethylene oxide added thereto (b) an alkyl sulfate having 8 carbon atoms and 1 to 5 moles of ethylene oxide added thereto (C) Sodium meta-xylene sulfonate (d) Diethylene glycol monoalkyl ether having 1 to 4 carbon atoms in the alkyl group
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10243161A JP2000073087A (en) | 1998-08-28 | 1998-08-28 | Liquid detergent composition for house |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP10243161A JP2000073087A (en) | 1998-08-28 | 1998-08-28 | Liquid detergent composition for house |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| JP2000073087A true JP2000073087A (en) | 2000-03-07 |
Family
ID=17099723
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP10243161A Pending JP2000073087A (en) | 1998-08-28 | 1998-08-28 | Liquid detergent composition for house |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JP2000073087A (en) |
-
1998
- 1998-08-28 JP JP10243161A patent/JP2000073087A/en active Pending
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