IT1164100B - CATALYST AND PROCESS TO PRODUCE METHACRYLIC ACID - Google Patents

CATALYST AND PROCESS TO PRODUCE METHACRYLIC ACID

Info

Publication number: IT1164100B
Authority: IT; Italy
Prior art keywords: catalyst; methacrylic acid; produce methacrylic; produce; acid
Prior art date: 1978-12-26

Application number

IT51168/79A

Other languages

Italian (it)

Other versions

IT7951168A0 (en

Inventor

Sargis Khoobiar

Original Assignee

Halcon Res & Dev

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1978-12-26

Filing date

1979-12-21

Publication date

1987-04-08

1978-12-26 Priority claimed from US05/973,495 external-priority patent/US4252683A/en

1978-12-26 Priority claimed from US05/973,354 external-priority patent/US4374757A/en

1978-12-26 Priority claimed from US05/972,745 external-priority patent/US4252682A/en

1978-12-26 Priority claimed from US05/972,743 external-priority patent/US4252681A/en

1979-04-06 Priority claimed from US06/027,635 external-priority patent/US4261860A/en

1979-04-06 Priority claimed from US06/027,634 external-priority patent/US4261859A/en

1979-04-06 Priority claimed from US06/027,632 external-priority patent/US4240930A/en

1979-04-06 Priority claimed from US06/027,633 external-priority patent/US4261858A/en

1979-06-12 Priority claimed from US06/047,860 external-priority patent/US4377501A/en

1979-10-03 Priority claimed from US06/081,406 external-priority patent/US4271040A/en

1979-12-21 Publication of IT7951168A0 publication Critical patent/IT7951168A0/en

1979-12-21 Application filed by Halcon Res & Dev filed Critical Halcon Res & Dev

1987-04-08 Publication of IT1164100B publication Critical patent/IT1164100B/en

1987-04-08 Application granted granted Critical

Classifications

- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8878—Chromium
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/885—Molybdenum and copper
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8871—Rare earth metals or actinides
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8872—Alkali or alkaline earth metals
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/85—Chromium, molybdenum or tungsten
- B01J23/88—Molybdenum
- B01J23/887—Molybdenum containing in addition other metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8876—Arsenic, antimony or bismuth
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/89—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals
- B01J23/8933—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/8993—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with noble metals also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with chromium, molybdenum or tungsten
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/14—Phosphorus; Compounds thereof
- B01J27/186—Phosphorus; Compounds thereof with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
- C07C51/16—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation
- C07C51/21—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen
- C07C51/25—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring
- C07C51/252—Preparation of carboxylic acids or their salts, halides or anhydrides by oxidation with molecular oxygen of unsaturated compounds containing no six-membered aromatic ring of propene, butenes, acrolein or methacrolein
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Catalysts (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

IT51168/79A 1978-12-26 1979-12-21 CATALYST AND PROCESS TO PRODUCE METHACRYLIC ACID IT1164100B (en)

Applications Claiming Priority (10)

Application Number	Priority Date	Filing Date	Title
US05/973,495 US4252683A (en)	1978-12-26	1978-12-26	Catalyst for producing methacrylic acid
US05/972,743 US4252681A (en)	1978-12-26	1978-12-26	Catalyst for producing methacrylic acid
US05/972,745 US4252682A (en)	1978-12-26	1978-12-26	Catalyst for producing methacrylic acid
US05/973,354 US4374757A (en)	1978-12-26	1978-12-26	Catalyst and process for producing methacrylic acid
US06/027,634 US4261859A (en)	1979-04-06	1979-04-06	Catalyst for producing methacrylic acid
US06/027,635 US4261860A (en)	1979-04-06	1979-04-06	Catalyst for producing methacrylic acid
US06/027,632 US4240930A (en)	1979-04-06	1979-04-06	Catalyst and process for producing methacrylic acid
US06/027,633 US4261858A (en)	1979-04-06	1979-04-06	Catalyst for producing methacrylic acid
US06/047,860 US4377501A (en)	1978-12-26	1979-06-12	Catalyst and process for producing methacrylic acid
US06/081,406 US4271040A (en)	1978-12-26	1979-10-03	Catalyst and process for producing methacrylic acid

Publications (2)

Publication Number	Publication Date
IT7951168A0 IT7951168A0 (en)	1979-12-21
IT1164100B true IT1164100B (en)	1987-04-08

Family

ID=27580733

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
IT51168/79A IT1164100B (en)	1978-12-26	1979-12-21	CATALYST AND PROCESS TO PRODUCE METHACRYLIC ACID

Country Status (7)

Country	Link
BR (1)	BR7908476A (en)
DE (1)	DE2952455C2 (en)
FR (1)	FR2445310A1 (en)
GB (3)	GB2040717B (en)
IT (1)	IT1164100B (en)
MX (1)	MX154396A (en)
NL (1)	NL7909142A (en)

Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3030243A1 (en) *	1980-08-09	1982-03-18	Basf Ag, 6700 Ludwigshafen	OXIDATION CATALYST, IN PARTICULAR FOR THE PRODUCTION OF METHACRYLIC ACID BY GAS PHASE OXIDATION OF METHACROLEIN
NL8202791A (en) *	1981-07-17	1983-02-16	Halcon Sd Group Inc	METHOD FOR PREPARING METHACRYLIC ACID.
US4511548A (en) *	1981-12-18	1985-04-16	The Standard Oil Company	Ammoxidation of methanol to produce hydrogen cyanide
DE3208572A1 (en) *	1982-03-10	1983-09-22	Basf Ag, 6700 Ludwigshafen	METHOD AND CATALYST FOR PRODUCING METHACRYLIC ACID
DE3208571A1 (en) *	1982-03-10	1983-09-22	Basf Ag, 6700 Ludwigshafen	OXIDATION CATALYST, ESPECIALLY FOR THE PRODUCTION OF METHACRYLIC ACID BY GAS PHASE OXIDATION OF METHACROLEIN
JPS59115750A (en) *	1982-12-22	1984-07-04	Nippon Shokubai Kagaku Kogyo Co Ltd	Catalyst for synthesis of methacrylic acid
DE19630832A1 (en) *	1996-07-31	1998-02-05	Hoechst Ag	Process for the selective production of acetic acid

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE2460541C3 (en) *	1973-12-29	1979-10-18	Nippon Shokubai Kagaku Kogyo Co. Ltd., Osaka (Japan)	Oxide catalyst containing phosphorus, molybdenum and vanadium and optionally copper, cobalt, zirconium, bismuth, antimony and / or arsenic and its use for the production of methacrylic acid
JPS5827255B2 (en) *	1974-05-31	1983-06-08	三菱レイヨン株式会社	Method for producing unsaturated fatty acids
US4000088A (en) *	1974-06-03	1976-12-28	Nippon Kayaku Co., Ltd.	Oxidation catalyst for the manufacture of methacrylic acid
FR2273586A1 (en) *	1974-06-07	1976-01-02	Nippon Kayaku Kk	Oxidn. catalyst for methacrolein conversion - to methacrylic acid, contg. molybdenum, phosphorus, antimony, copper and chromium
IN145044B (en) *	1975-01-13	1978-08-19	Standard Oil Co Ohio
GB1489559A (en) *	1975-03-03	1977-10-19	Mitsubishi Rayon Co	Catalytic process for the preparation of acrylic acid or methacrylic acid
JPS51115414A (en) *	1975-04-03	1976-10-12	Mitsubishi Rayon Co Ltd	Process for preparation of unsaturated fatty acids
US4118419A (en) *	1975-12-03	1978-10-03	Mitsubishi Rayon Company, Ltd.	Catalytic process for the preparation of an unsaturated carboxylic acid

1979
- 1979-12-19 NL NL7909142A patent/NL7909142A/en not_active Application Discontinuation
- 1979-12-21 BR BR7908476A patent/BR7908476A/en unknown
- 1979-12-21 IT IT51168/79A patent/IT1164100B/en active
- 1979-12-24 FR FR7931595A patent/FR2445310A1/en active Granted
- 1979-12-24 GB GB7944392A patent/GB2040717B/en not_active Expired
- 1979-12-27 DE DE2952455A patent/DE2952455C2/en not_active Expired
1980
- 1980-01-02 MX MX180602A patent/MX154396A/en unknown
1983
- 1983-03-15 GB GB08307118A patent/GB2116063B/en not_active Expired
- 1983-03-15 GB GB08307119A patent/GB2121309B/en not_active Expired

Also Published As

Publication number	Publication date
NL7909142A (en)	1980-06-30
DE2952455A1 (en)	1980-07-17
BR7908476A (en)	1980-09-23
GB8307118D0 (en)	1983-04-20
GB2040717A (en)	1980-09-03
FR2445310A1 (en)	1980-07-25
GB2121309B (en)	1984-06-06
GB2116063B (en)	1984-02-01
MX154396A (en)	1987-08-07
FR2445310B1 (en)	1984-05-25
GB2040717B (en)	1983-09-14
DE2952455C2 (en)	1988-07-28
GB2116063A (en)	1983-09-21
GB8307119D0 (en)	1983-04-20
IT7951168A0 (en)	1979-12-21
GB2121309A (en)	1983-12-21

Publication	Publication Date	Title
IT1195265B (en)	1988-10-12	PROCESS TO PRODUCE METHACRYLIC ACID
BR7906733A (en)	1980-07-15	PROCESS TO PREPARE TEREFTALLIC ACID
IT1148235B (en)	1986-11-26	PROCESS AND MEANS TO ELIMINATE TURBIDATIONS
BR7503800A (en)	1976-07-06	IMPROVEMENT IN PROCESS FOR OBERENCE OF ACRYLIC ACID OR METHACRYLIC ACID
BR7802316A (en)	1978-11-28	CONTINUOUS PROCESS OF DIRECT STEREIFICATION OF TEREFTALLIC ACID AND POLYMERIZATION
BR7602788A (en)	1976-11-09	PROCESS TO PRODUCE SULFURIC ACID
BR7605401A (en)	1977-08-16	CATALYST AND PROCESSING IN PROCESS FOR THE PRODUCTION OF ACRYLIC ACID AND METHACRYLIC ACID
BR7805060A (en)	1979-03-13	PROCESS TO PREPARE 1R-CIS-CARONALDEIDIC ACID
BR7703021A (en)	1977-12-20	PROCESS OF OBTAINING TEREFTALLIC ACID THROUGH REACTION OF DIPOTASSIC TEREFTALATE AND BENZOIC ACID
BR7908473A (en)	1980-08-26	ACID GAS PURIFICATION PROCESS
IT1101260B (en)	1985-09-28	PROCESS FOR ISOLATING AND PURIFYING ACRYLIC ACID
IT1081296B (en)	1985-05-16	PROCESS FOR REGENERATING SULFURIC ACID
BR7904345A (en)	1980-04-08	PROCESS TO PRODUCE ACETANILIDES
IT1164100B (en)	1987-04-08	CATALYST AND PROCESS TO PRODUCE METHACRYLIC ACID
MX144528A (en)	1981-10-23	IMPROVED PROCESS AND APPARATUS TO PREPARE ALCOHOLIC SOLUTIONS OF PHOSPHORIC ACID
IT1076234B (en)	1985-04-27	PHENYLACETIC ACID PREPARATION PROCESS
BR8101515A (en)	1981-09-15	PROCESS TO PREPARE A BENZENE-MONOCARBOXYLIC ACID
IT1092168B (en)	1985-07-06	PROCESS AND PLANT FOR PURIFYING WET PROCESS PHOSPHORIC ACID
IT1090568B (en)	1985-06-26	PROCESS AND PLANT FOR PURIFYING WET PROCESS PHOSPHORIC ACID
IT8048160A0 (en)	1980-03-14	PROCESS TO RECOVER METHACRYLIC ACID
IT1125600B (en)	1986-05-14	PROCESS FOR THE PRODUCTION OF NITRIC ACID
IT8521530A0 (en)	1985-07-11	PROCESS TO PRODUCE CINNAMIC ACID.
IT1157222B (en)	1987-02-11	PROCESS TO PRODUCE METHACRYLIC ACID
BR7903476A (en)	1980-01-15	PROCESS TO PREPARE MICRORFIBROSO DICTATED TRICALCIO SILICATE
BR7903291A (en)	1979-12-11	PROCESS TO PRODUCE WIRE