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GB994789A - Process and apparatus for the continuous polymerisation of ethylenically unsaturatedpolymerisable compounds - Google Patents

Process and apparatus for the continuous polymerisation of ethylenically unsaturatedpolymerisable compounds

Info

Publication number
GB994789A
GB994789A GB35091/61A GB3509161A GB994789A GB 994789 A GB994789 A GB 994789A GB 35091/61 A GB35091/61 A GB 35091/61A GB 3509161 A GB3509161 A GB 3509161A GB 994789 A GB994789 A GB 994789A
Authority
GB
United Kingdom
Prior art keywords
styrene
water
emulsified
compounds
acrylic
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB35091/61A
Inventor
Hans-Werner Otto
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
BASF SE
Original Assignee
BASF SE
Badische Anilin and Sodafabrik AG
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from DEB59607A external-priority patent/DE1125175B/en
Application filed by BASF SE, Badische Anilin and Sodafabrik AG filed Critical BASF SE
Publication of GB994789A publication Critical patent/GB994789A/en
Expired legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J19/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J19/18—Stationary reactors having moving elements inside
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01F—MIXING, e.g. DISSOLVING, EMULSIFYING OR DISPERSING
    • B01F31/00—Mixers with shaking, oscillating, or vibrating mechanisms
    • B01F31/44—Mixers with shaking, oscillating, or vibrating mechanisms with stirrers performing an oscillatory, vibratory or shaking movement
    • B01F31/441—Mixers with shaking, oscillating, or vibrating mechanisms with stirrers performing an oscillatory, vibratory or shaking movement performing a rectilinear reciprocating movement
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00081—Tubes
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00076—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements inside the reactor
    • B01J2219/00085—Plates; Jackets; Cylinders
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00051—Controlling the temperature
    • B01J2219/00074—Controlling the temperature by indirect heating or cooling employing heat exchange fluids
    • B01J2219/00087—Controlling the temperature by indirect heating or cooling employing heat exchange fluids with heat exchange elements outside the reactor
    • B01J2219/00094—Jackets
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00049—Controlling or regulating processes
    • B01J2219/00168—Controlling or regulating processes controlling the viscosity
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00765—Baffles attached to the reactor wall
    • B01J2219/00777—Baffles attached to the reactor wall horizontal
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/00761—Details of the reactor
    • B01J2219/00763—Baffles
    • B01J2219/00779—Baffles attached to the stirring means
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
    • B01J2219/18—Details relating to the spatial orientation of the reactor
    • B01J2219/185—Details relating to the spatial orientation of the reactor vertical

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Ethylenically unsaturated polymerizable compounds are continuously polymerized in a cylindrical reaction vessel fitted with perforated plates mounted transversely on a reciprocating shaft (see Division B1). The inlet of the vessel may be up to 120 DEG C. lower than the outlet and block, solution and emulsion polymerization methods are used. Starting materials specified are styrene, a -methylstyrene and o-chlorostyrene; vinyl halides, vinylidene chloride and vinylidine fluoride; acrylic compounds, for example acrylic and methacrylic acids and their esters as well as acrylonitrile, methacrylonitrile, acrylamide and methacrylamide; vinyl esters as well as diolefines, for example butadiene, 2-chloro-butadiene and isoprene. The Examples describe the polymerization of (1) styrene emulsified in water with a sodium salt of a paraffin sulphonic acid in the presence of potassium persulphate; (2) butyl acrylate and acrylic acid emulsified in water with an aryl sulphonate and in the presence of potassium persulphate; (3) styrene in toluene in presence of azo-di-isobutyro-nitrile; and (4) butyl acrylate and acrylic acid emulsified in water with a sulphonated fatty alcohol-ethylene oxide condensate.
GB35091/61A 1960-10-01 1961-09-29 Process and apparatus for the continuous polymerisation of ethylenically unsaturatedpolymerisable compounds Expired GB994789A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DEB59607A DE1125175B (en) 1960-10-01 1960-10-01 Process and device for the continuous polymerization of ethylenically unsaturated polymerizable compounds
DEB0063868 1961-09-01

Publications (1)

Publication Number Publication Date
GB994789A true GB994789A (en) 1965-06-10

Family

ID=25965758

Family Applications (1)

Application Number Title Priority Date Filing Date
GB35091/61A Expired GB994789A (en) 1960-10-01 1961-09-29 Process and apparatus for the continuous polymerisation of ethylenically unsaturatedpolymerisable compounds

Country Status (2)

Country Link
BE (1) BE608707A (en)
GB (1) GB994789A (en)

Cited By (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2359848A1 (en) * 1976-07-27 1978-02-24 Ici Australia Ltd
EP0036896A1 (en) * 1980-03-27 1981-10-07 Toray Industries, Inc. Bulk polymerization reactor
JPH09173812A (en) * 1995-12-27 1997-07-08 Reika Kogyo Kk Mixer and agitating filter therewith
NL1009069C2 (en) * 1998-05-05 1999-11-09 Kees Van Der Manden B V Whipping machine for making whipped cream and chocolate foam
WO2003061819A1 (en) * 2002-01-26 2003-07-31 Forschungszentrum Jülich GmbH Reactor with sieve-like bodies and method for operating said reactor
EP1402939A2 (en) * 2002-09-25 2004-03-31 Reika Kogyo Kabushiki Kaisha Apparatus and method for mixing by agitation
EP1879691A2 (en) * 2005-05-13 2008-01-23 Fina Technology, Inc. Plug flow reactor and polymers prepared therewith
US7350961B2 (en) * 2003-08-13 2008-04-01 Reika Kogyo Kabushiki Kaisha Agitation mixer, pasteurizer, and cleaning device
JP2009515695A (en) * 2005-11-17 2009-04-16 フルーエンズ シンサシス エーエス Continuous flow reactor
EP4065266A4 (en) * 2019-11-28 2023-11-01 Council Of Scientific & Industrial Research A continuous flow reactor

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113856590A (en) * 2021-09-28 2021-12-31 芜湖优机环保科技有限公司 Reaction kettle for producing benzoyl peroxide

Cited By (16)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2359848A1 (en) * 1976-07-27 1978-02-24 Ici Australia Ltd
EP0036896A1 (en) * 1980-03-27 1981-10-07 Toray Industries, Inc. Bulk polymerization reactor
JPH09173812A (en) * 1995-12-27 1997-07-08 Reika Kogyo Kk Mixer and agitating filter therewith
NL1009069C2 (en) * 1998-05-05 1999-11-09 Kees Van Der Manden B V Whipping machine for making whipped cream and chocolate foam
WO2003061819A1 (en) * 2002-01-26 2003-07-31 Forschungszentrum Jülich GmbH Reactor with sieve-like bodies and method for operating said reactor
US7090391B2 (en) 2002-09-25 2006-08-15 Reika Kogyo Kabushiki Kaisha Apparatus and method for mixing by agitation in a multichambered mixing apparatus including a pre-agitation mixing chamber
EP1402939A3 (en) * 2002-09-25 2004-06-16 Reika Kogyo Kabushiki Kaisha Apparatus and method for mixing by agitation
EP1655067A1 (en) * 2002-09-25 2006-05-10 Reika Kogyo Kabushiki Kaisha Apparatus and method for mixing by agitation
EP1402939A2 (en) * 2002-09-25 2004-03-31 Reika Kogyo Kabushiki Kaisha Apparatus and method for mixing by agitation
US7293909B2 (en) 2002-09-25 2007-11-13 Reika Kogyo Kabushiki Kaisha Apparatus and method for mixing by agitation in a multichambered mixing apparatus including a pre-agitation mixing chamber
US7350961B2 (en) * 2003-08-13 2008-04-01 Reika Kogyo Kabushiki Kaisha Agitation mixer, pasteurizer, and cleaning device
EP1879691A2 (en) * 2005-05-13 2008-01-23 Fina Technology, Inc. Plug flow reactor and polymers prepared therewith
EP1879691A4 (en) * 2005-05-13 2010-11-24 Fina Technology Plug flow reactor and polymers prepared therewith
US8066954B2 (en) 2005-05-13 2011-11-29 Fina Technology, Inc. Plug flow reactor and polymers prepared therewith
JP2009515695A (en) * 2005-11-17 2009-04-16 フルーエンズ シンサシス エーエス Continuous flow reactor
EP4065266A4 (en) * 2019-11-28 2023-11-01 Council Of Scientific & Industrial Research A continuous flow reactor

Also Published As

Publication number Publication date
BE608707A (en) 1962-03-29

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