GB963631A - Phosphorylated urethanes - Google Patents
Phosphorylated urethanesInfo
- Publication number
- GB963631A GB963631A GB19306/63A GB1930663A GB963631A GB 963631 A GB963631 A GB 963631A GB 19306/63 A GB19306/63 A GB 19306/63A GB 1930663 A GB1930663 A GB 1930663A GB 963631 A GB963631 A GB 963631A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- formula
- phosphorylated
- urethanes
- interrupted
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 150000003673 urethanes Chemical class 0.000 title abstract 3
- 125000004178 (C1-C4) alkyl group Chemical group 0.000 abstract 3
- 125000000217 alkyl group Chemical group 0.000 abstract 3
- 229910052757 nitrogen Inorganic materials 0.000 abstract 3
- 125000005842 heteroatom Chemical group 0.000 abstract 2
- 229910052739 hydrogen Inorganic materials 0.000 abstract 2
- 239000001257 hydrogen Substances 0.000 abstract 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 abstract 2
- 125000004433 nitrogen atom Chemical group N* 0.000 abstract 2
- 229910052760 oxygen Inorganic materials 0.000 abstract 2
- 229920006395 saturated elastomer Polymers 0.000 abstract 2
- 229910052717 sulfur Inorganic materials 0.000 abstract 2
- XXVRAGNROZKHBX-UHFFFAOYSA-N (2,2,2-trichloro-1-hydroxyethyl)phosphonic acid Chemical compound ClC(Cl)(Cl)C(O)P(O)(O)=O XXVRAGNROZKHBX-UHFFFAOYSA-N 0.000 abstract 1
- YGYAWVDWMABLBF-UHFFFAOYSA-N Phosgene Chemical compound ClC(Cl)=O YGYAWVDWMABLBF-UHFFFAOYSA-N 0.000 abstract 1
- 150000001412 amines Chemical class 0.000 abstract 1
- 150000001875 compounds Chemical class 0.000 abstract 1
- 239000000839 emulsion Substances 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 239000003337 fertilizer Substances 0.000 abstract 1
- 239000002917 insecticide Substances 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 230000000361 pesticidal effect Effects 0.000 abstract 1
- 239000007787 solid Substances 0.000 abstract 1
- 239000007858 starting material Substances 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/6527—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having nitrogen and oxygen atoms as the only ring hetero atoms
- C07F9/6533—Six-membered rings
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/28—Phosphorus compounds with one or more P—C bonds
- C07F9/38—Phosphonic acids [RP(=O)(OH)2]; Thiophosphonic acids ; [RP(=X1)(X2H)2(X1, X2 are each independently O, S or Se)]
- C07F9/40—Esters thereof
- C07F9/4003—Esters thereof the acid moiety containing a substituent or a structure which is considered as characteristic
- C07F9/4006—Esters of acyclic acids which can have further substituents on alkyl
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/572—Five-membered rings
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
- C07F9/02—Phosphorus compounds
- C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
- C07F9/553—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having one nitrogen atom as the only ring hetero atom
- C07F9/576—Six-membered rings
- C07F9/59—Hydrogenated pyridine rings
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Biochemistry (AREA)
- Molecular Biology (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
Abstract
The invention comprises phosphorylated urethanes of formula: <FORM:0963631/C1/1> where R1 and R2 are each C1- 4 alkyl, R3 is hydrogen or C1- 4 alkyl and R4 is C1- 4 alkyl, or R3 and R4 may, together with the nitrogen atom, form a saturated ring which may be interrupted by further hetero atoms, e.g. O, S or N. They are prepared by reacting a dialkyl 1-hydroxy-2,2, 2-trichloroethyl-phosphonate with phosgene, preferably in the presence of a tertiary base, to give a chloroformic ester of formula: <FORM:0963631/C1/2> and reacting this with an amine R3R4NH. Compounds of formula II in which R1=R2=CH3 or C2H5 are prepared as starting materials in examples.ALSO:Pesticidal compositions comprise, together with a solid or liquid carrier, a phosphorylated urethane of formula <FORM:0963631/A5-A6/1> where R1 and R2 are each C1-4 alkyl, R3 is hydrogen or C1-4 alkyl and R4 is C1-4 alkyl, or R3 and R4 together with the nitrogen atom form a saturated ring which may be interrupted by further hetero atoms, e.g. O, S or N (for preparation see Division C2). Solutions and emulsions are mentioned. Other insecticides and/or fertilizers may be present.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DEF0036817 | 1962-05-16 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB963631A true GB963631A (en) | 1964-07-15 |
Family
ID=7096623
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB19306/63A Expired GB963631A (en) | 1962-05-16 | 1963-05-15 | Phosphorylated urethanes |
Country Status (3)
| Country | Link |
|---|---|
| BE (1) | BE632366A (en) |
| GB (1) | GB963631A (en) |
| NL (1) | NL292791A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3758554A (en) * | 1971-06-18 | 1973-09-11 | Stevens & Co Inc J P | Phosphorus-containing carbamates |
| WO1997039756A1 (en) * | 1996-04-25 | 1997-10-30 | Troponwerke Gmbh & Co. Kg | Use of phosphonic acid esters for the treatment of functional disorders of the brain and depression |
-
0
- NL NL292791D patent/NL292791A/xx unknown
- BE BE632366D patent/BE632366A/xx unknown
-
1963
- 1963-05-15 GB GB19306/63A patent/GB963631A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3758554A (en) * | 1971-06-18 | 1973-09-11 | Stevens & Co Inc J P | Phosphorus-containing carbamates |
| WO1997039756A1 (en) * | 1996-04-25 | 1997-10-30 | Troponwerke Gmbh & Co. Kg | Use of phosphonic acid esters for the treatment of functional disorders of the brain and depression |
Also Published As
| Publication number | Publication date |
|---|---|
| NL292791A (en) | 1900-01-01 |
| BE632366A (en) | 1900-01-01 |
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