GB727790A - Process for the production of high molecular weight linear polyesters from diol esters of terephthalic acid - Google Patents
Process for the production of high molecular weight linear polyesters from diol esters of terephthalic acidInfo
- Publication number
- GB727790A GB727790A GB3134354A GB3134354A GB727790A GB 727790 A GB727790 A GB 727790A GB 3134354 A GB3134354 A GB 3134354A GB 3134354 A GB3134354 A GB 3134354A GB 727790 A GB727790 A GB 727790A
- Authority
- GB
- United Kingdom
- Prior art keywords
- molecular weight
- high molecular
- terephthalic acid
- weight linear
- production
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 title abstract 4
- 229920000728 polyester Polymers 0.000 title abstract 2
- -1 diol esters Chemical class 0.000 title 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 abstract 3
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 abstract 2
- 229940046892 lead acetate Drugs 0.000 abstract 2
- 239000004246 zinc acetate Substances 0.000 abstract 2
- 239000003054 catalyst Substances 0.000 abstract 1
- 230000005494 condensation Effects 0.000 abstract 1
- 238000009833 condensation Methods 0.000 abstract 1
- 150000002148 esters Chemical class 0.000 abstract 1
- 125000002887 hydroxy group Chemical group [H]O* 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/85—Germanium, tin, lead, arsenic, antimony, bismuth, titanium, zirconium, hafnium, vanadium, niobium, tantalum, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/83—Alkali metals, alkaline earth metals, beryllium, magnesium, copper, silver, gold, zinc, cadmium, mercury, manganese, or compounds thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
- C08G63/78—Preparation processes
- C08G63/82—Preparation processes characterised by the catalyst used
- C08G63/84—Boron, aluminium, gallium, indium, thallium, rare-earth metals, or compounds thereof
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyesters Or Polycarbonates (AREA)
Abstract
Hydroxyl terminated esters from terephthalic acid and ethylene glycol are converted to high molecular weight linear polyesters by condensation in the presence, as catalyst, of zinc acetate, and/or lead acetate. Two examples are given, one employing zinc acetate and the other lead acetate.
Priority Applications (4)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
NL198358D NL198358A (en) | 1954-05-21 | ||
NL81197D NL81197C (en) | 1954-05-21 | ||
NL89114D NL89114C (en) | 1954-05-21 | ||
GB3134354A GB727790A (en) | 1954-05-21 | 1954-05-21 | Process for the production of high molecular weight linear polyesters from diol esters of terephthalic acid |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB3134354A GB727790A (en) | 1954-05-21 | 1954-05-21 | Process for the production of high molecular weight linear polyesters from diol esters of terephthalic acid |
Publications (1)
Publication Number | Publication Date |
---|---|
GB727790A true GB727790A (en) | 1955-04-06 |
Family
ID=10321711
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB3134354A Expired GB727790A (en) | 1954-05-21 | 1954-05-21 | Process for the production of high molecular weight linear polyesters from diol esters of terephthalic acid |
Country Status (2)
Country | Link |
---|---|
GB (1) | GB727790A (en) |
NL (3) | NL198358A (en) |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2961430A (en) * | 1955-11-01 | 1960-11-22 | Celanese Corp | Unsaturated polyester preparation under reduced pressure |
US3185668A (en) * | 1959-08-31 | 1965-05-25 | Standard Oil Co | Direct esterification |
-
0
- NL NL89114D patent/NL89114C/xx active
- NL NL81197D patent/NL81197C/xx active
- NL NL198358D patent/NL198358A/xx unknown
-
1954
- 1954-05-21 GB GB3134354A patent/GB727790A/en not_active Expired
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2961430A (en) * | 1955-11-01 | 1960-11-22 | Celanese Corp | Unsaturated polyester preparation under reduced pressure |
US3185668A (en) * | 1959-08-31 | 1965-05-25 | Standard Oil Co | Direct esterification |
US3185670A (en) * | 1959-08-31 | 1965-05-25 | Standard Oil Co | Pressure esterification |
US3185669A (en) * | 1959-08-31 | 1965-05-25 | Standard Oil Co | Total liquid phase esterification |
Also Published As
Publication number | Publication date |
---|---|
NL198358A (en) | |
NL89114C (en) | |
NL81197C (en) |
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