GB699455A - Improvements in and relating to the desulphurisation of hydrocarbons containing sulphur compounds - Google Patents
Improvements in and relating to the desulphurisation of hydrocarbons containing sulphur compoundsInfo
- Publication number
- GB699455A GB699455A GB12629/50A GB1262950A GB699455A GB 699455 A GB699455 A GB 699455A GB 12629/50 A GB12629/50 A GB 12629/50A GB 1262950 A GB1262950 A GB 1262950A GB 699455 A GB699455 A GB 699455A
- Authority
- GB
- United Kingdom
- Prior art keywords
- per cent
- hydrogen
- gas
- hydrocarbons
- sulphur
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G49/00—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00
- C10G49/007—Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58 or C10G47/00 in the presence of hydrogen from a special source or of a special composition or having been purified by a special treatment
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Catalysts (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Abstract
Hydrocarbons containing sulphur compounds are desulphurized by treatment with a gas containing 20 to 60 per cent by volume of hydrogen while they are passed in a liquid film at a temperature above 200 DEG C and pressure above 10 atmospheres over a stationary fragmentary catalyst comprising an oxygen-or sulphur-containing compound of a metal of Group VI of the Periodic System and an oxygen- or sulphur-containing compound of a metal of Group VIII of the Periodic System. The feed gas may contain nitrogen and hydrocarbons, and may suitably be gases produced by catalytic cracking, with or without additional hydrogen, or by re-forming of normally liquid or gas hydrocarbons or by the dry distillation of hydrocarbonaceous substances such as gas coal. The gases leaving the reaction zone, which have a comparatively low hydrogen content, may be discharged from the system The amount of gas leaving the system, measured at normal temperature and pressure after removal of hydrogen sulphide, should be less than 500 litres per kilogramme of hydrocarbons treated. Any carbon monoxide and unsaturated hydrocarbons in the gas should preferably be eliminated. Cobalt and molybdenum oxides or sulphides, or a cobalt salt of molybdic acid or molybdenum sulpho-acid on aluminium oxide as a carrier form suitable catalysts. The results of tests describing the desulphurization of a gas oil (boiling range 260-350 DEG C) containing 1.33 per cent sulphur using a feed gas of pure hydrogen, 40 per cent hydrogen and 60 per cent methane, 40 per cent hydrogen and 60 per cent nitrogen and 50 per cent hydrogen and 50 per cent carbon monoxide are reported. Specifications 657,400 and 665,575 are referred to.
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| NL657521X | 1948-01-06 | ||
| NL699455X | 1949-05-20 |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB699455A true GB699455A (en) | 1953-11-11 |
Family
ID=26643978
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB31066/48A Expired GB657521A (en) | 1948-01-06 | 1948-11-30 | A process for desulphurising hydrocarbon oils |
| GB12629/50A Expired GB699455A (en) | 1948-01-06 | 1950-05-19 | Improvements in and relating to the desulphurisation of hydrocarbons containing sulphur compounds |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB31066/48A Expired GB657521A (en) | 1948-01-06 | 1948-11-30 | A process for desulphurising hydrocarbon oils |
Country Status (4)
| Country | Link |
|---|---|
| BE (1) | BE495784A (en) |
| FR (1) | FR1017684A (en) |
| GB (2) | GB657521A (en) |
| NL (1) | NL71604C (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1120048B (en) * | 1956-09-18 | 1961-12-21 | Exxon Research Engineering Co | Process for the elimination of unpleasant smells from hydrocarbon fractions with narrow boiling ranges |
| DE1161373B (en) * | 1958-10-16 | 1964-01-16 | Inst Francais Du Petrol | Process for the continuous selective hydrorefining of crude petroleum |
Families Citing this family (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| BE528503A (en) * | 1953-04-29 | |||
| DE977260C (en) * | 1953-08-19 | 1965-08-12 | Exxon Research Engineering Co | Process for the production of a high quality gasoline and a stable mixture heating oil from crude oil |
| DE972924C (en) * | 1954-06-29 | 1959-11-19 | Metallgesellschaft Ag | Process for refining hydrocarbons that are liquid at normal temperature from the carbonization or gasification of lignite or oil shale or of petroleum distillates by catalytic treatment with hydrogen or hydrogen-containing gases |
| DE977579C (en) * | 1954-12-12 | 1967-05-03 | Exxon Research Engineering Co | Process for improving the coking test of untreated and / or split heating oils |
| US2987467A (en) * | 1958-05-26 | 1961-06-06 | Hydrocarbon Research Inc | Removal of sulfur and metals from heavy oils by hydro-catalytic treatment |
-
0
- NL NL71604D patent/NL71604C/xx active
- BE BE495784D patent/BE495784A/xx unknown
-
1948
- 1948-11-30 GB GB31066/48A patent/GB657521A/en not_active Expired
-
1950
- 1950-05-12 FR FR1017684D patent/FR1017684A/en not_active Expired
- 1950-05-19 GB GB12629/50A patent/GB699455A/en not_active Expired
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE1120048B (en) * | 1956-09-18 | 1961-12-21 | Exxon Research Engineering Co | Process for the elimination of unpleasant smells from hydrocarbon fractions with narrow boiling ranges |
| DE1161373B (en) * | 1958-10-16 | 1964-01-16 | Inst Francais Du Petrol | Process for the continuous selective hydrorefining of crude petroleum |
Also Published As
| Publication number | Publication date |
|---|---|
| NL71604C (en) | |
| BE495784A (en) | |
| GB657521A (en) | 1951-09-19 |
| FR1017684A (en) | 1952-12-17 |
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