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GB2136577A - Corrosion control monitoring device - Google Patents

Corrosion control monitoring device Download PDF

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Publication number
GB2136577A
GB2136577A GB08401768A GB8401768A GB2136577A GB 2136577 A GB2136577 A GB 2136577A GB 08401768 A GB08401768 A GB 08401768A GB 8401768 A GB8401768 A GB 8401768A GB 2136577 A GB2136577 A GB 2136577A
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United Kingdom
Prior art keywords
corrosion
metal
electrical
electrolyte
current
Prior art date
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Withdrawn
Application number
GB08401768A
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GB8401768D0 (en
Inventor
Roger Alexander
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Individual
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Individual
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Publication date
Priority claimed from GB838304458A external-priority patent/GB8304458D0/en
Application filed by Individual filed Critical Individual
Priority to GB08401768A priority Critical patent/GB2136577A/en
Publication of GB8401768D0 publication Critical patent/GB8401768D0/en
Publication of GB2136577A publication Critical patent/GB2136577A/en
Priority to AU40682/85A priority patent/AU4068285A/en
Priority to PCT/EP1985/000049 priority patent/WO1985003311A1/en
Priority to EP19850901396 priority patent/EP0169901A1/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C23COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23FNON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/02Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
    • C23F13/04Controlling or regulating desired parameters
    • GPHYSICS
    • G01MEASURING; TESTING
    • G01NINVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
    • G01N17/00Investigating resistance of materials to the weather, to corrosion, or to light
    • G01N17/02Electrochemical measuring systems for weathering, corrosion or corrosion-protection measurement

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Environmental Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Health & Medical Sciences (AREA)
  • Ecology (AREA)
  • Analytical Chemistry (AREA)
  • Biochemistry (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Environmental & Geological Engineering (AREA)
  • Immunology (AREA)
  • Pathology (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Testing Resistance To Weather, Investigating Materials By Mechanical Methods (AREA)

Abstract

This device simulates corrosion taking place on a structure which is subjected to a corrosion control system, The electrical behaviour of that corrosion can be observed while the device, which is submerged in the same electrolyte, is connected to and disconnected from the structure. The corrosion control current may pass into the structure through metal 2 and conductor 4 or through metal 1 to conductor 3, through a meter, connected to conductor 3, to conductor 5 and metal 8 against the corrosion current in the electrolyte contained by metal 8 to metal 2 and then via conductor 4 to the structure. If the corrosion prevention current overcomes the corrosive activity the meter reading is reduced to zero or reversed in direction. <IMAGE>

Description

SPECIFICATION Cathodic protection monitoring device 1. This invention relates to a corrosion control monitoring device. It enables the user to ascertain the adequacy of a corrosion control system installed to protect a buried or submerged structure.
Corrosion can be caused by impurities introduced into the metal during manufacture. The impurities and the metal have different electrical properties.
When both are immersed in an electrolyte, a corrosion cell is formed between the pure and the impure metals. Figure 1. The electrical circuit that is formed, causes a current to flow from the metallic anode into the electrolyte. Where this occurs, metal is lost into solution and the structure is damaged. At another location, the current passes from the electrolyte to the metal and no corrosion damage occurs at this (cathode) point. A corrosion control system is designed to stop the metal loss at the anode. In a system, called cathodic protection, a D.C. current is caused to flow into the enviromental electrolyte and from there, onto the surface of the structure.
At present the effectiveness of the corrosion control system is assessed using a voltmeter to measure electrical potential differences and a theoretical level of protection exists at which sufficient current is thought to pass onto each part of the structure to prevent corrosive activity. The system of using electrical potential differences is not satisfactory in many ways and consequently no criteria for protection has proved infallible.
The corrosion control monitoring device is inovative in that it simulates the corrosion process taking place on the structure, while this corrosion can be electrically measured. The design of the device allows the observation of the electrical behaviour of the corrosion cell while it is being connected and disconnected from the structure, and thus with and without the influence of the corrosion control system. It can therefore be seen if the system is capable of stopping corrosion. This is achieved by the inovation of encapsulating a sample of electrolyte to form a corrosion cell within the device.
The wiring circuit allows the corrosion prevention system to act upon the simulated corrosion cell in the same way as it would act upon a natural corrosion cell on the surface of structure.
The circuit of the device is completed when the corrosion current passes through the environment in which the device is placed. Ideally, the metals of which the device is partly made, should be the same as the metals to be found on the structure to be monitored. For general use concerning steel structures, it is sufficient that a mild steel anode, and a copper cathode be used to produce an electromotive-force of about 0.600 V.
A specific embodiment of the invention will now be described by way of example with reference to the accompanying drawings in which Figure 3 shows in perspective a view of the base and end of the device.
Figure 4 shows in perspective a view of the top and end of the device.
Figure 5 shows a secrion through the device.
Referrring to the drawing, the device comprises three pieces of metal 1, 2, and 8. They are set in an electrically insulating material 7, and connected to separate electrical conductors 3,4 and 5 passing out of the device through lead 6.
Current passes from steel plate 2 into a sample electrolyte which has been placed into the cavity formed by the copper 8, and the inulating material 7.
The current then pases through the conductor 5, and through an electrical current measuring and/or direction indicating device to conductor 3. The current then passes to the steel plate 1 and from the device into the environment on which the device has been placed.
From the environment the current passes onto the other steel plate 2 to complete the circuit. The magnitude and direction of the current is noted by the operator observing the electrical current measuring and/or direction indication device.
Electrical conductor4 is then connected to the metal of the structure.
The magnitude and direction of the indication given by the electrical current measuring and/or direction indicating device, are again noted.
1. A method to determin the effect of a corrosion control system upon a structure which is at least partly immersed in an electrolyte and in which it is liable to corrode, the method being a corrosion cell constructed in such a way that the electrical current resulting from the electrolytic action at the anodic metal to electrolyte, interface, passes through that electrolyte which is contained out of contact with the environmental electrolyte, into a metalic cathode contact which is connected to an electrical current measurement and/or direction indicating device, and which allows the current to pass through an electrical conductor to metal which is placed in contact with the environment in which the aforementioned structure is at least partly immersed being the same environmental electrolyte in which the outer surface of the said anodic metal is immersed or the outer surface of a metal which is in electrical connection with the said anodic metal, is immersed.A method wherein an electrical contact is made between the anodic metal of the said internal corrosion cell, to the structure which is underthe influence of the corrosion control system, thus providing a conductive path from the environmental electrolyte from the outer surface of the metal of which the inner surface forms the anode of the internal corrosion cell within the device or providing a conductive path from the environmental electrolyte from the outer surface of the metal which is in electrical contact with the anodic metal of the internal corrosion cell, which electrical contact may or may not include an electrical current measuring and/or direction indicating device, to the said structure which is under the influence of the corrosion control system.
2. A method according to claim 1 wherein a sample of the environmental electrolyte is contained in electrical separation from the external environ
**WARNING** end of DESC field may overlap start of CLMS **.

Claims (6)

**WARNING** start of CLMS field may overlap end of DESC **. SPECIFICATION Cathodic protection monitoring device 1. This invention relates to a corrosion control monitoring device. It enables the user to ascertain the adequacy of a corrosion control system installed to protect a buried or submerged structure. Corrosion can be caused by impurities introduced into the metal during manufacture. The impurities and the metal have different electrical properties. When both are immersed in an electrolyte, a corrosion cell is formed between the pure and the impure metals. Figure 1. The electrical circuit that is formed, causes a current to flow from the metallic anode into the electrolyte. Where this occurs, metal is lost into solution and the structure is damaged. At another location, the current passes from the electrolyte to the metal and no corrosion damage occurs at this (cathode) point. A corrosion control system is designed to stop the metal loss at the anode. In a system, called cathodic protection, a D.C. current is caused to flow into the enviromental electrolyte and from there, onto the surface of the structure. At present the effectiveness of the corrosion control system is assessed using a voltmeter to measure electrical potential differences and a theoretical level of protection exists at which sufficient current is thought to pass onto each part of the structure to prevent corrosive activity. The system of using electrical potential differences is not satisfactory in many ways and consequently no criteria for protection has proved infallible. The corrosion control monitoring device is inovative in that it simulates the corrosion process taking place on the structure, while this corrosion can be electrically measured. The design of the device allows the observation of the electrical behaviour of the corrosion cell while it is being connected and disconnected from the structure, and thus with and without the influence of the corrosion control system. It can therefore be seen if the system is capable of stopping corrosion. This is achieved by the inovation of encapsulating a sample of electrolyte to form a corrosion cell within the device. The wiring circuit allows the corrosion prevention system to act upon the simulated corrosion cell in the same way as it would act upon a natural corrosion cell on the surface of structure. The circuit of the device is completed when the corrosion current passes through the environment in which the device is placed. Ideally, the metals of which the device is partly made, should be the same as the metals to be found on the structure to be monitored. For general use concerning steel structures, it is sufficient that a mild steel anode, and a copper cathode be used to produce an electromotive-force of about 0.600 V. A specific embodiment of the invention will now be described by way of example with reference to the accompanying drawings in which Figure 3 shows in perspective a view of the base and end of the device. Figure 4 shows in perspective a view of the top and end of the device. Figure 5 shows a secrion through the device. Referrring to the drawing, the device comprises three pieces of metal 1, 2, and 8. They are set in an electrically insulating material 7, and connected to separate electrical conductors 3,4 and 5 passing out of the device through lead 6. Current passes from steel plate 2 into a sample electrolyte which has been placed into the cavity formed by the copper 8, and the inulating material 7. The current then pases through the conductor 5, and through an electrical current measuring and/or direction indicating device to conductor 3. The current then passes to the steel plate 1 and from the device into the environment on which the device has been placed. From the environment the current passes onto the other steel plate 2 to complete the circuit. The magnitude and direction of the current is noted by the operator observing the electrical current measuring and/or direction indication device. Electrical conductor4 is then connected to the metal of the structure. The magnitude and direction of the indication given by the electrical current measuring and/or direction indicating device, are again noted. CLAIMS
1. A method to determin the effect of a corrosion control system upon a structure which is at least partly immersed in an electrolyte and in which it is liable to corrode, the method being a corrosion cell constructed in such a way that the electrical current resulting from the electrolytic action at the anodic metal to electrolyte, interface, passes through that electrolyte which is contained out of contact with the environmental electrolyte, into a metalic cathode contact which is connected to an electrical current measurement and/or direction indicating device, and which allows the current to pass through an electrical conductor to metal which is placed in contact with the environment in which the aforementioned structure is at least partly immersed being the same environmental electrolyte in which the outer surface of the said anodic metal is immersed or the outer surface of a metal which is in electrical connection with the said anodic metal, is immersed.A method wherein an electrical contact is made between the anodic metal of the said internal corrosion cell, to the structure which is underthe influence of the corrosion control system, thus providing a conductive path from the environmental electrolyte from the outer surface of the metal of which the inner surface forms the anode of the internal corrosion cell within the device or providing a conductive path from the environmental electrolyte from the outer surface of the metal which is in electrical contact with the anodic metal of the internal corrosion cell, which electrical contact may or may not include an electrical current measuring and/or direction indicating device, to the said structure which is under the influence of the corrosion control system.
2. A method according to claim 1 wherein a sample of the environmental electrolyte is contained in electrical separation from the external environ ment, except that the electrical current developed at the corroding anodic interface is electrically conducted through an electrical measuring and/or direction indicating device, and through a metalic contact to the external environment from where it re-enters the device via a second metalic contact with the external environmental electrolyte in the same manner as a natural corrosion cell would if it was in the same location.
3. A method according to claims 1 & 2 wherein the external surfaces of two pieces of metal of identical chemical composition, are put into contact the environmental electrolyte thus completing the electrical circuit allowing corrosion to take place on the inner surface of the first piece of metal and the resulting electrical current to pass through an encapsulated electrolyte to a dissimilar third piece of metal being cathodic to the first piece of metal, and from the cathodic metal to pass through an electrical current measuring and/or direction indicating device, returning to the second piece of metal which is in contact with the environmental electrolyte.
4. A method according to claims 1,2, & 3, wherein the corrosion current passes from the anodic surface of the encapsulated corrosion cell through the cathodic metal of the said cell and through an electrical conductor available for the operator of the device to connect into circuit, a means of measuring and/or indicating the direction of an electrical current which is generated by the electrolytic reaction within the device, or that such a means of measuring and/or indicating the direction of the said current, be madetemporarilly or permanently part of the device.
5. A method according to claims 1,2,3 & 4 wherein the device is divided into two units connected by electrical conductors to achieve the same circuit as described in claim 1, and by which means, one unit contains metalic environmental contact and the other unit contains encapsulated electrolyte by means ofwhich an electrical current is caused to pass through an electrical current measuring and/or direction indicating device and from there to the other unit which on contact with the environmental electrolyte allows the current to pass through that environmental electrolyte to the external surface of the metal of the other unit, which metal forms the anodic surface of the corrosion cell contained within that unit.
6. A corrosion monitoring device substantially as described herein with reference to Figures 3 to 5 of the accompanying drawings.
GB08401768A 1983-02-17 1984-01-24 Corrosion control monitoring device Withdrawn GB2136577A (en)

Priority Applications (4)

Application Number Priority Date Filing Date Title
GB08401768A GB2136577A (en) 1983-02-17 1984-01-24 Corrosion control monitoring device
AU40682/85A AU4068285A (en) 1984-01-24 1985-01-24 Cathodic protection monitoring method and device
PCT/EP1985/000049 WO1985003311A1 (en) 1984-01-24 1985-01-24 Cathodic protection monitoring method and device
EP19850901396 EP0169901A1 (en) 1984-01-24 1985-01-24 Cathodic protection monitoring method and device

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
GB838304458A GB8304458D0 (en) 1983-02-17 1983-02-17 Cathodic protection monitoring device
GB08401768A GB2136577A (en) 1983-02-17 1984-01-24 Corrosion control monitoring device

Publications (2)

Publication Number Publication Date
GB8401768D0 GB8401768D0 (en) 1984-02-29
GB2136577A true GB2136577A (en) 1984-09-19

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GB08401768A Withdrawn GB2136577A (en) 1983-02-17 1984-01-24 Corrosion control monitoring device

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5681160A (en) * 1994-07-26 1997-10-28 Hamworthy Combustion Eng Ltd Flare tip structure and a method of disposal of gas ulilizing such a structure

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1184484A (en) * 1966-04-04 1970-03-18 Wallace & Tiernan Inc Methods and Systems for Protecting Metal Structures from Corrosion.
GB1466782A (en) * 1973-03-12 1977-03-09 Sanyo Electric Co Estimation of electrolytic corrosion
GB1516011A (en) * 1975-04-28 1978-06-28 Chemoprojekt Projektova Inzeny Measurement of the polarization potential of metal structures
GB1589243A (en) * 1976-10-21 1981-05-07 Chemoprojekt Projektova Inzeny Test sensor for measuring corrosion and cathodic protection of metal structures

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB1184484A (en) * 1966-04-04 1970-03-18 Wallace & Tiernan Inc Methods and Systems for Protecting Metal Structures from Corrosion.
GB1466782A (en) * 1973-03-12 1977-03-09 Sanyo Electric Co Estimation of electrolytic corrosion
GB1516011A (en) * 1975-04-28 1978-06-28 Chemoprojekt Projektova Inzeny Measurement of the polarization potential of metal structures
GB1589243A (en) * 1976-10-21 1981-05-07 Chemoprojekt Projektova Inzeny Test sensor for measuring corrosion and cathodic protection of metal structures

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5681160A (en) * 1994-07-26 1997-10-28 Hamworthy Combustion Eng Ltd Flare tip structure and a method of disposal of gas ulilizing such a structure

Also Published As

Publication number Publication date
GB8401768D0 (en) 1984-02-29

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