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GB2006260A - Process for preparing aromatic hydrocarbons - Google Patents

Process for preparing aromatic hydrocarbons

Info

Publication number
GB2006260A
GB2006260A GB7840721A GB7840721A GB2006260A GB 2006260 A GB2006260 A GB 2006260A GB 7840721 A GB7840721 A GB 7840721A GB 7840721 A GB7840721 A GB 7840721A GB 2006260 A GB2006260 A GB 2006260A
Authority
GB
United Kingdom
Prior art keywords
molar ratio
hydrocarbons
aromatic hydrocarbons
constraint index
mixture
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
GB7840721A
Other versions
GB2006260B (en
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of GB2006260A publication Critical patent/GB2006260A/en
Application granted granted Critical
Publication of GB2006260B publication Critical patent/GB2006260B/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/02—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon
    • C07C1/04—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon from oxides of a carbon from carbon monoxide with hydrogen
    • C07C1/0425—Catalysts; their physical properties
    • C07C1/043—Catalysts; their physical properties characterised by the composition
    • C07C1/0435—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof
    • C07C1/044—Catalysts; their physical properties characterised by the composition containing a metal of group 8 or a compound thereof containing iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/745—Iron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2523/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
    • C07C2523/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00 of the iron group metals or copper
    • C07C2523/74—Iron group metals
    • C07C2523/75—Cobalt
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Catalysts (AREA)

Abstract

Process for preparing aromatics from carbon monoxide and hydrogen. A mixture whose H2/CO molar ratio is less than 1.0, is contacted with a trifunctional catalyst containing at least one metal catalyzing the conversion of a H2/CO mixture into hydrocarbons and/or oxygen- containing hydrocarbons, at least one metal catalyzing the water gas shift reaction and a crystalline aluminosilicate zeolite having an SiO2/Al2O3 molar ratio of at least 12 and a constraint index between 1 and 12. The "constraint index" is an empirical value based on the relative sorption by the zeolite of n-hexane and 3-methylpentane in a defined experimental procedure.
GB7840721A 1977-10-17 1978-10-16 Process for preparing aromatic hydrocarbons Expired GB2006260B (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
NL7711350A NL7711350A (en) 1977-10-17 1977-10-17 PROCESS FOR THE PREPARATION OF HYDROCARBONS.

Publications (2)

Publication Number Publication Date
GB2006260A true GB2006260A (en) 1979-05-02
GB2006260B GB2006260B (en) 1982-03-03

Family

ID=19829349

Family Applications (1)

Application Number Title Priority Date Filing Date
GB7840721A Expired GB2006260B (en) 1977-10-17 1978-10-16 Process for preparing aromatic hydrocarbons

Country Status (8)

Country Link
AU (1) AU520964B2 (en)
BE (1) BE871122A (en)
CA (1) CA1111073A (en)
FR (1) FR2405912A1 (en)
GB (1) GB2006260B (en)
IT (1) IT1099979B (en)
NL (1) NL7711350A (en)
ZA (1) ZA785799B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4350772A (en) * 1978-11-30 1982-09-21 Shell Oil Company Process for the preparation of hydrocarbons from synthesis gas
US4507404A (en) * 1983-03-10 1985-03-26 Shell Oil Company Preparation of hydrocarbon mixtures from syngas
US5344849A (en) * 1990-10-31 1994-09-06 Canada Chemical Corporation Catalytic process for the production of hydrocarbons

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2496095B1 (en) 1980-12-15 1985-11-15 Shell Int Research PROCESS FOR THE PREPARATION OF A HYDROCARBON MIXTURE FROM A H2 / CO MIXTURE
US6703429B2 (en) 2001-08-23 2004-03-09 Chevron U.S.A. Inc. Process for converting synthesis gas into hydrocarbonaceous products

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2815357A (en) * 1954-03-12 1957-12-03 Standard Oil Co Synthesis of aromatic hydrocarbons
CA1062285A (en) * 1974-04-24 1979-09-11 Mobil Oil Corporation Conversion of synthesis gas to hydrocarbon mixtures
CA1081196A (en) * 1975-08-14 1980-07-08 Charles M. Bartish Process for producing hydrocarbons and the catalyst used therein
CA1117883A (en) * 1977-05-13 1982-02-09 Bernardus J. Runderkamp Process for preparing liquid hydrocarbons

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4350772A (en) * 1978-11-30 1982-09-21 Shell Oil Company Process for the preparation of hydrocarbons from synthesis gas
US4507404A (en) * 1983-03-10 1985-03-26 Shell Oil Company Preparation of hydrocarbon mixtures from syngas
AU568338B2 (en) * 1983-03-10 1987-12-24 Shell Internationale Research Maatschappij B.V. Isomerisation of paraffins
US5344849A (en) * 1990-10-31 1994-09-06 Canada Chemical Corporation Catalytic process for the production of hydrocarbons

Also Published As

Publication number Publication date
IT1099979B (en) 1985-09-28
BE871122A (en) 1979-04-10
FR2405912A1 (en) 1979-05-11
IT7828803A0 (en) 1978-10-16
AU4073578A (en) 1980-04-24
GB2006260B (en) 1982-03-03
ZA785799B (en) 1979-09-26
FR2405912B1 (en) 1983-12-16
CA1111073A (en) 1981-10-20
NL7711350A (en) 1979-04-19
AU520964B2 (en) 1982-03-11

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Legal Events

Date Code Title Description
PCNP Patent ceased through non-payment of renewal fee