GB1603062A - Ink composition - Google Patents
Ink composition Download PDFInfo
- Publication number
- GB1603062A GB1603062A GB11803/78A GB1180378A GB1603062A GB 1603062 A GB1603062 A GB 1603062A GB 11803/78 A GB11803/78 A GB 11803/78A GB 1180378 A GB1180378 A GB 1180378A GB 1603062 A GB1603062 A GB 1603062A
- Authority
- GB
- United Kingdom
- Prior art keywords
- composition according
- resin
- blend
- resins
- resins comprises
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000000203 mixture Substances 0.000 title claims abstract description 160
- 229920005989 resin Polymers 0.000 claims abstract description 136
- 239000011347 resin Substances 0.000 claims abstract description 136
- 239000002904 solvent Substances 0.000 claims abstract description 52
- 238000007639 printing Methods 0.000 claims abstract description 28
- 239000000758 substrate Substances 0.000 claims abstract description 18
- 239000003792 electrolyte Substances 0.000 claims abstract description 15
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 claims description 33
- 239000000463 material Substances 0.000 claims description 32
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 27
- 238000004040 coloring Methods 0.000 claims description 16
- 229920000180 alkyd Polymers 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 12
- JOXIMZWYDAKGHI-UHFFFAOYSA-N toluene-4-sulfonic acid Chemical compound CC1=CC=C(S(O)(=O)=O)C=C1 JOXIMZWYDAKGHI-UHFFFAOYSA-N 0.000 claims description 12
- 239000000975 dye Substances 0.000 claims description 10
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 claims description 8
- TWRXJAOTZQYOKJ-UHFFFAOYSA-L Magnesium chloride Chemical compound [Mg+2].[Cl-].[Cl-] TWRXJAOTZQYOKJ-UHFFFAOYSA-L 0.000 claims description 8
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 claims description 8
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 claims description 8
- 150000003839 salts Chemical class 0.000 claims description 7
- -1 isopropvl Chemical class 0.000 claims description 6
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 6
- 239000000126 substance Substances 0.000 claims description 6
- 150000003505 terpenes Chemical class 0.000 claims description 6
- 235000007586 terpenes Nutrition 0.000 claims description 6
- 229920000728 polyester Polymers 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229910001629 magnesium chloride Inorganic materials 0.000 claims description 4
- 229920000642 polymer Polymers 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 3
- 150000001299 aldehydes Chemical class 0.000 claims description 3
- 150000001875 compounds Chemical class 0.000 claims description 3
- 229920001971 elastomer Polymers 0.000 claims description 3
- 239000004615 ingredient Substances 0.000 claims description 3
- 150000002576 ketones Chemical class 0.000 claims description 3
- 239000000049 pigment Substances 0.000 claims description 3
- 229920000915 polyvinyl chloride Polymers 0.000 claims description 3
- 239000005060 rubber Substances 0.000 claims description 3
- JYEUMXHLPRZUAT-UHFFFAOYSA-N 1,2,3-triazine Chemical compound C1=CN=NN=C1 JYEUMXHLPRZUAT-UHFFFAOYSA-N 0.000 claims description 2
- PYSRRFNXTXNWCD-UHFFFAOYSA-N 3-(2-phenylethenyl)furan-2,5-dione Chemical compound O=C1OC(=O)C(C=CC=2C=CC=CC=2)=C1 PYSRRFNXTXNWCD-UHFFFAOYSA-N 0.000 claims description 2
- 239000004925 Acrylic resin Substances 0.000 claims description 2
- 229920000178 Acrylic resin Polymers 0.000 claims description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 claims description 2
- 239000013032 Hydrocarbon resin Substances 0.000 claims description 2
- 229920000877 Melamine resin Polymers 0.000 claims description 2
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 2
- 229920001328 Polyvinylidene chloride Polymers 0.000 claims description 2
- 229920001800 Shellac Polymers 0.000 claims description 2
- 229920000147 Styrene maleic anhydride Polymers 0.000 claims description 2
- 229920001807 Urea-formaldehyde Polymers 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 claims description 2
- 229930195733 hydrocarbon Natural products 0.000 claims description 2
- 229920006270 hydrocarbon resin Polymers 0.000 claims description 2
- 150000002430 hydrocarbons Chemical class 0.000 claims description 2
- 150000002825 nitriles Chemical class 0.000 claims description 2
- 238000009928 pasteurization Methods 0.000 claims description 2
- 229920006122 polyamide resin Polymers 0.000 claims description 2
- 229920005668 polycarbonate resin Polymers 0.000 claims description 2
- 239000004431 polycarbonate resin Substances 0.000 claims description 2
- 229920000647 polyepoxide Polymers 0.000 claims description 2
- 229920000570 polyether Polymers 0.000 claims description 2
- 229920000098 polyolefin Polymers 0.000 claims description 2
- 150000007519 polyprotic acids Polymers 0.000 claims description 2
- 239000005033 polyvinylidene chloride Substances 0.000 claims description 2
- 230000005855 radiation Effects 0.000 claims description 2
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 claims description 2
- 239000004208 shellac Substances 0.000 claims description 2
- ZLGIYFNHBLSMPS-ATJNOEHPSA-N shellac Chemical compound OCCCCCC(O)C(O)CCCCCCCC(O)=O.C1C23[C@H](C(O)=O)CCC2[C@](C)(CO)[C@@H]1C(C(O)=O)=C[C@@H]3O ZLGIYFNHBLSMPS-ATJNOEHPSA-N 0.000 claims description 2
- 229940113147 shellac Drugs 0.000 claims description 2
- 235000013874 shellac Nutrition 0.000 claims description 2
- 229920002050 silicone resin Polymers 0.000 claims description 2
- 159000000000 sodium salts Chemical class 0.000 claims description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 claims description 2
- 239000008158 vegetable oil Substances 0.000 claims description 2
- JEVGKYBUANQAKG-UHFFFAOYSA-N victoria blue R Chemical compound [Cl-].C12=CC=CC=C2C(=[NH+]CC)C=CC1=C(C=1C=CC(=CC=1)N(C)C)C1=CC=C(N(C)C)C=C1 JEVGKYBUANQAKG-UHFFFAOYSA-N 0.000 claims description 2
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims 2
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 claims 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical class [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims 1
- 239000004215 Carbon black (E152) Substances 0.000 claims 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 claims 1
- GZCGUPFRVQAUEE-SLPGGIOYSA-N aldehydo-D-glucose Chemical compound OC[C@@H](O)[C@@H](O)[C@H](O)[C@@H](O)C=O GZCGUPFRVQAUEE-SLPGGIOYSA-N 0.000 claims 1
- QGZKDVFQNNGYKY-UHFFFAOYSA-O ammonium group Chemical group [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims 1
- 239000003822 epoxy resin Substances 0.000 claims 1
- 239000007850 fluorescent dye Substances 0.000 claims 1
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 claims 1
- 229920001470 polyketone Polymers 0.000 claims 1
- 229920002803 thermoplastic polyurethane Polymers 0.000 claims 1
- 229910052751 metal Inorganic materials 0.000 abstract description 8
- 239000002184 metal Substances 0.000 abstract description 8
- 239000007787 solid Substances 0.000 abstract description 2
- 239000003086 colorant Substances 0.000 abstract 1
- 239000011521 glass Substances 0.000 abstract 1
- 239000004033 plastic Substances 0.000 abstract 1
- 239000011877 solvent mixture Substances 0.000 abstract 1
- 239000000976 ink Substances 0.000 description 87
- 239000002585 base Substances 0.000 description 8
- 238000007641 inkjet printing Methods 0.000 description 7
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 6
- 238000001704 evaporation Methods 0.000 description 5
- 230000008020 evaporation Effects 0.000 description 4
- 230000001747 exhibiting effect Effects 0.000 description 4
- 238000000034 method Methods 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 235000019198 oils Nutrition 0.000 description 4
- 150000007513 acids Chemical class 0.000 description 3
- JPIYZTWMUGTEHX-UHFFFAOYSA-N auramine O free base Chemical compound C1=CC(N(C)C)=CC=C1C(=N)C1=CC=C(N(C)C)C=C1 JPIYZTWMUGTEHX-UHFFFAOYSA-N 0.000 description 3
- 229920002678 cellulose Polymers 0.000 description 3
- 238000002844 melting Methods 0.000 description 3
- 230000008018 melting Effects 0.000 description 3
- 230000001590 oxidative effect Effects 0.000 description 3
- 239000002966 varnish Substances 0.000 description 3
- 239000003981 vehicle Substances 0.000 description 3
- YBYIRNPNPLQARY-UHFFFAOYSA-N 1H-indene Chemical compound C1=CC=C2CC=CC2=C1 YBYIRNPNPLQARY-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- 239000011230 binding agent Substances 0.000 description 2
- 239000004359 castor oil Substances 0.000 description 2
- 235000019438 castor oil Nutrition 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 238000013329 compounding Methods 0.000 description 2
- 238000001035 drying Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000010685 fatty oil Substances 0.000 description 2
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 2
- 239000004922 lacquer Substances 0.000 description 2
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 2
- 239000011976 maleic acid Substances 0.000 description 2
- 150000007522 mineralic acids Chemical class 0.000 description 2
- CKIGNOCMDJFFES-UHFFFAOYSA-N n-naphthalen-2-yl-1-phenylmethanimine Chemical compound C=1C=C2C=CC=CC2=CC=1N=CC1=CC=CC=C1 CKIGNOCMDJFFES-UHFFFAOYSA-N 0.000 description 2
- 150000007530 organic bases Chemical class 0.000 description 2
- 230000035515 penetration Effects 0.000 description 2
- VLTOSDJJTWPWLS-UHFFFAOYSA-N pent-2-ynal Chemical compound CCC#CC=O VLTOSDJJTWPWLS-UHFFFAOYSA-N 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical compound OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000057 synthetic resin Substances 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 229920002554 vinyl polymer Polymers 0.000 description 2
- SQAINHDHICKHLX-UHFFFAOYSA-N 1-naphthaldehyde Chemical compound C1=CC=C2C(C=O)=CC=CC2=C1 SQAINHDHICKHLX-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000001856 Ethyl cellulose Substances 0.000 description 1
- ZZSNKZQZMQGXPY-UHFFFAOYSA-N Ethyl cellulose Chemical compound CCOCC1OC(OC)C(OCC)C(OCC)C1OC1C(O)C(O)C(OC)C(CO)O1 ZZSNKZQZMQGXPY-UHFFFAOYSA-N 0.000 description 1
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 1
- 239000004606 Fillers/Extenders Substances 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N Furan Chemical compound C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 229920000663 Hydroxyethyl cellulose Polymers 0.000 description 1
- 239000004354 Hydroxyethyl cellulose Substances 0.000 description 1
- 229920002153 Hydroxypropyl cellulose Polymers 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- SJEYSFABYSGQBG-UHFFFAOYSA-M Patent blue Chemical compound [Na+].C1=CC(N(CC)CC)=CC=C1C(C=1C(=CC(=CC=1)S([O-])(=O)=O)S([O-])(=O)=O)=C1C=CC(=[N+](CC)CC)C=C1 SJEYSFABYSGQBG-UHFFFAOYSA-M 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 229920002367 Polyisobutene Polymers 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 150000001241 acetals Chemical class 0.000 description 1
- 239000000980 acid dye Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- VZTDIZULWFCMLS-UHFFFAOYSA-N ammonium formate Chemical compound [NH4+].[O-]C=O VZTDIZULWFCMLS-UHFFFAOYSA-N 0.000 description 1
- 239000012752 auxiliary agent Substances 0.000 description 1
- 239000000981 basic dye Substances 0.000 description 1
- WRUAHXANJKHFIL-UHFFFAOYSA-N benzene-1,3-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC(S(O)(=O)=O)=C1 WRUAHXANJKHFIL-UHFFFAOYSA-N 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- 229910052791 calcium Inorganic materials 0.000 description 1
- 239000011575 calcium Substances 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 229920003086 cellulose ether Polymers 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003240 coconut oil Substances 0.000 description 1
- 235000019864 coconut oil Nutrition 0.000 description 1
- 238000002508 contact lithography Methods 0.000 description 1
- 229920001577 copolymer Polymers 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000986 disperse dye Substances 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 229920001249 ethyl cellulose Polymers 0.000 description 1
- 235000019325 ethyl cellulose Nutrition 0.000 description 1
- JVICFMRAVNKDOE-UHFFFAOYSA-M ethyl violet Chemical compound [Cl-].C1=CC(N(CC)CC)=CC=C1C(C=1C=CC(=CC=1)N(CC)CC)=C1C=CC(=[N+](CC)CC)C=C1 JVICFMRAVNKDOE-UHFFFAOYSA-M 0.000 description 1
- 230000003203 everyday effect Effects 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 235000021323 fish oil Nutrition 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 150000004676 glycans Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229920000578 graft copolymer Polymers 0.000 description 1
- 235000019447 hydroxyethyl cellulose Nutrition 0.000 description 1
- 239000001863 hydroxypropyl cellulose Substances 0.000 description 1
- 235000010977 hydroxypropyl cellulose Nutrition 0.000 description 1
- 235000021388 linseed oil Nutrition 0.000 description 1
- 239000000944 linseed oil Substances 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- HZULAIWBSUOQGY-UHFFFAOYSA-N methanol;pentan-3-one Chemical compound OC.CCC(=O)CC HZULAIWBSUOQGY-UHFFFAOYSA-N 0.000 description 1
- 229920000609 methyl cellulose Polymers 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- 239000001923 methylcellulose Substances 0.000 description 1
- 235000010981 methylcellulose Nutrition 0.000 description 1
- 238000003801 milling Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000000025 natural resin Substances 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920001225 polyester resin Polymers 0.000 description 1
- 239000004645 polyester resin Substances 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920001282 polysaccharide Polymers 0.000 description 1
- 239000005017 polysaccharide Substances 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002689 polyvinyl acetate Polymers 0.000 description 1
- 239000011118 polyvinyl acetate Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 229920001289 polyvinyl ether Polymers 0.000 description 1
- 238000002360 preparation method Methods 0.000 description 1
- HJWLCRVIBGQPNF-UHFFFAOYSA-N prop-2-enylbenzene Chemical compound C=CCC1=CC=CC=C1 HJWLCRVIBGQPNF-UHFFFAOYSA-N 0.000 description 1
- FVSKHRXBFJPNKK-UHFFFAOYSA-N propionitrile Chemical compound CCC#N FVSKHRXBFJPNKK-UHFFFAOYSA-N 0.000 description 1
- 239000000985 reactive dye Substances 0.000 description 1
- 230000003134 recirculating effect Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- JXKPEJDQGNYQSM-UHFFFAOYSA-M sodium propionate Chemical compound [Na+].CCC([O-])=O JXKPEJDQGNYQSM-UHFFFAOYSA-M 0.000 description 1
- 239000004324 sodium propionate Substances 0.000 description 1
- 229960003212 sodium propionate Drugs 0.000 description 1
- 235000010334 sodium propionate Nutrition 0.000 description 1
- 239000007858 starting material Substances 0.000 description 1
- FDDDEECHVMSUSB-UHFFFAOYSA-N sulfanilamide Chemical compound NC1=CC=C(S(N)(=O)=O)C=C1 FDDDEECHVMSUSB-UHFFFAOYSA-N 0.000 description 1
- 229940124530 sulfonamide Drugs 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-N sulfonic acid Chemical compound OS(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-N 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000003784 tall oil Substances 0.000 description 1
- 229920005992 thermoplastic resin Polymers 0.000 description 1
- 229920006337 unsaturated polyester resin Polymers 0.000 description 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 150000003751 zinc Chemical class 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
- Developing Agents For Electrophotography (AREA)
- Inspection Of Paper Currency And Valuable Securities (AREA)
Abstract
A high solids printing ink suitable for jet (inkjet) printing onto coated, untreated, stiff or flexible metal, glass, plastic and most other substrates contains in each case up to 10 per cent by weight of colorant and of an electrolyte, up to 80 per cent by weight of a resin or resin mixture, and a solvent or solvent mixture.
Description
(54) AN INK COMPOSITION
(71) We, WHITTAKER CORPORATION. a corporation organised and existing under the laws of the State of California. United States of America, of 10880 Wilshire
Boulevard. Los Angeles. California 91)024. United States of America, do hereby declare the invention. for which we pray that a patent may be granted to us, and the method by which it is to be performed, to be particularly described in and by the following statement:
The present invention relates to an ink composition suitable for use in jet printing operations.
Although the concept of recording an experimental event using jet of ink dates back to
Lord Kelvin in the 1800's, it has only been within the past 20 years that commercial devices using '*Ink Jet Printing" principle have been available. A number of different electronically controlled ink jet approaches have been taken in the effort to develop commercial devices.
With both economic and environmental pressures affecting the cost of printing systems using high speed, relatively noisy mechanical mechanisms and other problems associated with them. because of these problems, printers based on "ink jet principle" are becoming more and more acceptable everyday.
There are basicallv three ink droplet generating approaches:
(1) high frequency. pressurized and electrostatically deflected systems;
(2) low frequency, pressurized, electrostatically gated and deflected systems, and
(3) low to medium frequency, non-pressurized impulse or ink on demand systems.
Inks suitable for use in the ink jet printing system, or ink jets as they will be referred to hereinafter, have been developed which work satisfactorily on a limited number of substrates. The main reason for this limitation is lack of sufficient amount of binder in an ink to give suitable printing. adhesion and other end use properties.
In order to operate satisfactorily in an ink jet printing system, an ink must display a consistent drop break-up length. drop velocity and drop charge under set machine operating conditions. To achieve these ends the ink must meet strict requirements with regards to viscosity, resistivity. solubility. and compatibility of components, stability and anti-skinning properties and must redissolve in a suitable solvent for rapid clean-up of the machine components with a minimum of effort.
It has been determined that on an ink jet printer, described in U.S. Patent Specifications
Nos. 3,465,350 and 3.465.351. inks with viscosity of 20 cps. will perform satisfactorily depending upon the type of nozzle used. However, inks with lower viscosities perform much better. The resistivity of the ink may be as high as 10,000 ohm cm. for satisfactory operations.
It is also important that, in an ink jet printing system where ink is recirculated, before ink is reused. it must be brought to its original form by adding exact amounts of solvents and ingredients lost while recirculating.
Also, printing inks must possess satisfactory printability for intended utility, to meet the requirements which may vary for each specific type of substrate and printing apparatus.
Particularly the printing inks for non-contact printing are subject to a number of limitations incurred by the printing machine.
It is an object of this invention to provide an ink with film-forming resin for use in ink jet printing on a wide variety of substrates which combines properties necessary for satisfactory operation of the ink in the printing apparatus with the properties necessary for obtaining and preserving a satisfactory printed image on the particular substrate in question.
In this Specification the term "resin" as applied to the present invention means a resinous andlor polymeric material capable of forming a film.
In presently available commercial inks, for ink jet printing, the printability characteristics are generally determined by their solvent composition. However, in general, printing characteristics of any type of printing ink are determined by its resin composition. In ink compositions of the present invention, printing characteristics and end use properties are determined by their vehicle components and solvents which may play a supporting role of penetration of inks into substrates.
According to the present invention there is provided an ink composition suitable for use in jet printing operations comprising a solution of the following components:
(a) a resin as hereinbefore defined or blend of resins in a total amount between 10 and
80 weight percent of the ink composition;
(b) a colouring material in an amount below 10 weight percent of the ink composition;
(c) an electrolyte in an amount of up to 10 weight percent of the ink composition;
(d) a solvent or blend of solvents to give a desired viscosity, of 1.50 cp to 25.0 cp at 77"F.
It is to be understood that the ink composition of the invention must contain finite amounts of Components (a). (b), (c) and (d). Preferably the total amount of resin or blend of resins is between 15 and 50 weight percent of the ink composition and the ink composition preferably has a viscosity of 1.75 cp. to 25.0 cp. at 770F.
Although jet printing inks contain a colourant, a solvent and a binding agent in common with conventional inks, certain functions are required of these components in jet printing inks in addition to those required in conventional inks and, in particular, the ink jet printing of coated or virgin metal substrates such as aluminium, steel and tinned steel can imposes particular functional requirements on these components. The achievement of a satisfactory balance of the functional requirements of the ink by appropriate compounding is, in essence, the subject matter of this invention and it is for this reason that the special functions required of the various ink components in metal printing jet inks are discussed herein in some detail.
The properties of the resins and the characteristics which are imparted to the ink by the resin are of paramount importance in the present invention. It has been previously pointed out that the overall ink composition must be of very low viscosity. Satisfactory results are readily obtainable with inks having a viscosity as high as 20 cps. at 77"F., and it is possible to operate with ink having a viscosity approaching 25 cps. at 770F, although the jet printing process becomes increasingly difficult to control as the ink viscosity increases. A viscosity of 2-5 cps. is considered to give optimum results. Since the resin component tends to increase the viscosity of the solvent medium, it is therefore necessary to have resin which in solvents at high weight percent having very low viscosity to prevent an undesirable viscosity build-up as a result of compounding.
The resin component of a jet printing ink suitable for printing on coated or virgin metal must also meet a variety of requirements. Of primary importance is the ability of the resin to adhere to the coated or virgin metal surface on which the ink is printed and to maintain this strong adhesion under widely varying conditions of humidity and temperature. When the ink is applied to the metal surface. it must "wet" or adhere to-a coated or virgin metal surface, even in the presence of some moisture, and must exhibit a high degree of moistureproofness, not only to maintain adhesion to the metal but also to protect the dye or other colouring material, which may be water-sensitive, from the effects of moisture which may make the dye bleed into surrounding areas.
The resin component must also be very readily soluble in the solvent medium to form a stable, low viscosity solution that effective amounts can be dissolved in the solvent without unduly increasing the viscosity of the composition. Similarly, the electrolytic component
must also be effective at concentrations well below its solubility limit in order to achieve the desired drop deflection characteristics without danger of precipitation and plugging of the system.
A further requirement of the resin is that it should have sufficient solvent-release so that a desired rate of drying is obtained on a given substrate. In order to be effective in a formulation of a jet printing ink for a given substrate, the solvent medium must readily dissolve sufficient amounts of the resin component, the dye or other colouring material and electrolyte to achieve the desired level of adhesiveness, conductivity and visual impact of the ink composition. Further, since some degree of evaporation of solvent will occur in the ink supply and ink return systems, thereby, increasing the solids concentration in ink the solvent should have sufficient power to prevent precipitation in this situation.
Although evaporation of the solvent from the ink supply and return systems is generally undesirable, it is important that the solvent evaporate at the desired rate from the printed image area in order to leave the printed image smearproof and moistureproof in the required time after the printing operation is carried out. The solvent must achieve a satisfactory balance in evaporative properties between these opposed objectives.
Depending upon the type of substrate on which the ink is to be printed, it is advantageous to use a solvent which will penetrate the wax or other coating on substrates to enhance adhesion and rub resistance of the ink.
This invention relates to ink compositions which have excellent adhesion on various substrates. The ink composition may be prepared by adding a suitable electrolyte to an ink vehicle which comprises, as the essential component, a resin or blend of resins dissolved in a solvent or blend of solvents to give a viscosity preferably in a range of 1.5 cp. to 12 cp., and which is compatible with fatty oils; and various oils, resins, resinous varnishes solvents, etc., conventionally used as printing ink materials and further, if necessary, by milling with and dispersing pigments, extenders and/or auxiliary agents in the resulting components.
Furthermore. the preparation of the ink composition of this invention is subject to no critical limitation as to the starting materials and blending method, other than that the vehicle component should contain a suitable electrolyte. Conventional raw materials employed in liquid printing inks such as fatty oils, resin, resin varnishes, solvents, etc., can be freely incorporated at optimal quantities depending upon intended end use of the ink composition.
Colouring Components - There are no significant limitations in use of any colouring matter. only limitation being that it must be compatible with the resin and electrolyte and solvent(s) used. Some of the dyes which are suitable for colouring are basic dyes, acid dyes, reactive dyes dye bases, disperse dyes, pigments and fluorescent compounds visible under
UV radiation. There is the limit that the amount of colouring material must be below 10 weight percent of the ink composition.
Solo eft Component - There is no significant limitation on the type of solvent which is used in the ink composition. the only limit being the effect on machine components, that is the solvent material chosen will be one having the desired viscosity. Some solvents which are suitable for these ink compositions comprise one or more alcohols, ketones, ethers, esters, hydrocarbons. glycols or glycolethers. The solvent material may comprise water. Further examples of solvents are: halogenated compounds, aldehydes, ether alcohols, acids and nitriles. Of course solvent selection will depend upon type of resin or blend of resins selected and the rate of evaporation required and type of substrate being printed and if penetration in the substrate is desired or not.
Variables which determine the rate at which a non-contact ink of the present invention will dry will depend upon evaporation rate of solvent material present and solvent release characteristics of the resin material present in an ink composition. Thus, it is possible to formulate an ink composition with a very fast drying rate by using very fast evaporating solvents.
In order that droplets of ink injected from the printer may receive and hold an appropriate electrical charge. the ink composition must be conductive. Conductivity of the ink composition is checked by its low resistance to electric current; ink compositions with resistivity of up to 10,000 ohm cm. are suitable.
It has been found that some of the ink compositions of this invention will have a resistivity within operable range without the necessity of adding an electrolyte (c). In general, however. it has been found that optimum results are obtained if an electrolyte is added to the ink. Preferred electrolvtes for the ink composition of this invention are acids, preferably organic acids, bases, preferably organic bases, salts of (preferably organic) acids and (preferably inorganic) bases, salts of organic bases and inorganic acids; e.g. inorganic acids, salts, alkali bases which are soluble in solvents. Some examples of electrolytes (c) are paratoluene sulphonic acid, the sodium salt of paratoluene sulphonic acid, sodiumpropionate, dimethylamine hydrochloride triethanolamine, magnesium chloride and ammonium formate.
Resin Component - The resin component is of paramount importance in ink compositions of this invention. depending upon the type of substrate and end use properties required of the printing substrate. A suitable resin or blend of resins is selected from the following type of resins:
Synthetic, semi-synthetic and natural resins, that is both polymerization as well as polycondensation and polyaddition products, are suitable. In principle, all resins customary in the printing ink and paint industry, such as are, for example, described in the lacquer raw material tables of Karstne (4th edition. Hanover, 1967) and in Wagner and Sarx's work on lacquer resins (4th edition, Munich, 1959) may be used.
The following, for example, are suitable resins: shellac resins, colophony and derivatives thereof, hydrogenated colophony, di- or polymerized colophony, as calcium or zinc salt, with colophony esterified with mono-or polyvalent alcohols; with resinifiers such as acrylic acid and butane diol or maleic acid and pentaerythritol modified colophony resin; the soluble phenol resins modified with colophony, rosin modified phenolic resins and resins based on acrylic compounds, phenolic polymers, maleinate resins, alkyd resins, oil-free alkyd resins, rosin modified maleic resins, rosin modified fumaric resins, styrene maleic anhydride resins, styrolated alkyd resins, vinyl toluene modified alkyd resins, alkyd resins with synthetic fatty acids, linseed oil alkyd resins, ricinene alkyd resins, castor oil alkyd resins, soy oil alkyd resins, coconut oil alkyd resins, rosin, tall oil and fish oil alkyd resins, acrylic resins, acrylated alkyd resins, also oils, e.g. vegetable oils, and oil varnishes. Also suitable are terpene resins, e.g. phenol modified terpene resins, polyvinyl resins, e.g.
polyvinyl acetate, polyvinyl chloride, polyvinylidene chloride, polyvinyl acetals, polyvinyl alcohol, polyvinyl ether, copolymers and graft polymers with various vinyl monomers, polyacrylic resins, acrylate resins, acrylonitrile resins' polystyrenes, polyisobutylenes, polyesters, e.g. those based on phthalic acid. maleic acid, adipic acid, sebacic acid, etc.; urea formaldehyde resins, melamine formaldehyde resins, naphthalene formaldehyde resins furane resins, ketone resins. aldehyde resins, polurethanes (especially urethane primary-products that cure only at elevated temperature), epoxide resins (especially resin-curer mixtures that cure only at elevated temperature) and precondensates thereof.
Suitable too are primary products of unsaturated polyester resins, dialkylphthalateprepolymers, hydrocarbon resins, polyolefins such as polyethylene wax or polypropylene wax, indene and cumaronindene resins, carbamide and sulphonamide resins, polyether resins. polyamide and polyester resins, triazine resins, silicone resins, polycarbonate resins, rubber and derivatives thereof, for example, cyclorubber and chlorinated rubber; chiefly, however. cellulose derivatives such as cellulose esters (nitrocellulose, cellulose acetate and the like), and especially cellulose ethers. for example, methylcellulose, hydroxyethylcellulose, hydroxypropylcellulose. propionitrile cellulose, ethyl cellulose and benzylcellulose.
The corresponding derivatives of other polysaccharides can also be used.
There are disclosed below by way of example only a limited number of embodiments of the invention herein presented it is possible to produce still other embodiments without departing from the inventive concepts herein disclosed.
The following compositions illustrating the invention are expressed in parts by weight and were prepared by conventional procedures:
Example 1.
poly ketone-base synthetic resin
exhibiting a viscosity of V on
the Gardner-Holdt scale and a
softening point of 117"C sold as
"Krumbhar Resin K -1717 HMP" by
Lawter Chemicals Inc., Chicago,
Illinois 50.00
methyl ethyl ketone 50.00
methanol 40.00 pamtoluene sulphonic acid 2.00
methyl violet base 2.00
144.00.
Example 2.
non-oxidizing polyester exhibiting a
viscosity of S-X on the Gardner
Holdt scale and a melting point
of 75 - 85"C sold as "Arochem 650"
by Ashland Chemical Company,
Columbus, Ohio 41.40
methanol 41.40
methyl ethyl ketone 16.00
paratoluene sulphonic acid 1.00
auramine base 0.20
100.00.
Example 3.
non-oxidizing polyester exhibiting a
viscosity of S-X on the Gardner
Holdt scale and a melting point
of 75 - 85"C sold as "Arochem 650"
by Ashland Chemical Company,
Columbus, Ohio 24.00
methanol 24.00
methyl ethyl ketone 40.00
paratoluene sulphonic acid 5.00
auramine base 7.00
100.00
Example 4.
non-oxidizing polyester exhibiting a
viscosity of S-X on the Gardner
Holdt scale and a melting point of
75 - 85"C sold as "Arochem 650" by
Ashland Chemical Company. Columbus,
Ohio 30.50
methanol 30.50
methyl ethyl ketone 25.00
paratoluene sulphonic acid 0.80
auramine base 0.20
raw castor oil 13.00
100.00.
Example 5.
"Krumbhar 1717 HMP" 59.40
paratoluene sulphonic acid 5.40 methyl ethyl ketone 40.50
methanol 76.50
isopropyl alcohol 130.50
312.30.
Example 6.
"Krumbhar 1717 HMP" 21.87
paratoluene sulphonic acid 1.99
methyl ethyl ketone 14.91
methanol 2X.l5 isopropyl alcohol 20.00 135.()().
Example 7.
"Krumbhar 1717 HMP" 50.00 methyl | ethyl ketone methanol 40.00 paratoluene sulphonic acid 2.00 ethyl violet base 144.00.
Example 8.
"Pentalyn 856" 35.00
methyl ethyl ketone 35.()()
methanol 70.00
m-benzen-di sulphonic acid 0.5() methyl violet base 1.00
141.50.
"Pentalyn 856" is an aqueous alkali soluble
high wetting thermoplastic resin sold by Hercules
Incorporated. Wilmington. Delaware, U.S.A.
Example 9.
"Krumbhar 1717 HMP" 15.00 isopropvl alcohol 36.00
methanol 25.70
methyl ethyl ketone 14.00 MgCl2 2.00
rhodamine base FB 0.80 Petrex acid SS 70 A" 2.50
96.00.
Petrex acid SS 7()A" is a synthetic, resinous polybasic acid of terpene origin sold by Hercules Incorporated. Wilmington, Delware, U.S.A.
Example 10.
Triazine-ftrmaldehyde resin sold as Uformite-336' by Rohm & Haas
Chemical Corp.. Philadelphia.
Pennsylvania 41.00
methyl ethyl ketone 86.00
heptanone 13.00
paratoluene sulphonic acid 2.00
victoria blue base 1.00
143.00.
Although the actual individual viscosity values of the specific examples of jet ink compositions recited above are not stated they all have viscosity values of 1.50 to 25.0 cp. at 77 F by virtue of the specified proportions of the ingredients used.
The foregoing jet ink compositions provide excellent adhesion to virtually any substrate as demonstrated in more than 500 hours of life tests, excellent rub resistance. excellent thermotropic properties under steam processing and pasteurization, and excellent resistance to water.
Pentalvn'', "Petrex", iUformite". "Krumbhar" and "Arochem" are Trade Marks.
WHAT WE CLAIM IS:
1. An ink composition suitable for use in jet printing operations comprising a solution of the following components:
(a) a resin as hereinbefore defined or blend of resins in a total amount between 10 and
80 weight percent of the ink composition;
(b) a colouring material in an amount below 10 weight percent of the ink composition;
(c) an electrolyte in an amount of up to 10 weight percent of the ink composition;
(d) a solvent or blend of solvents to give a desired viscosity of 1.50 cp. to 25.0 cp. at 77"F.
2. An ink composition according to Claim 1, wherein the total amount of resin or blend of resins is between 15 and 50 weight percent of the ink composition.
3. An ink composition according to Claim 1 or Claim 2. wherein the ink composition has a viscosity of 1.75 cp. to 25.0 cp. at 77 F.
4. The composition according to any preceding claim, wherein the resin or blend of resins comprises phenolic polymer.
5. The composition according to any one of Claims 1 to 3, wherein the resin or blend of
**WARNING** end of DESC field may overlap start of CLMS **.
Claims (62)
1. An ink composition suitable for use in jet printing operations comprising a solution of the following components:
(a) a resin as hereinbefore defined or blend of resins in a total amount between 10 and
80 weight percent of the ink composition;
(b) a colouring material in an amount below 10 weight percent of the ink composition;
(c) an electrolyte in an amount of up to 10 weight percent of the ink composition;
(d) a solvent or blend of solvents to give a desired viscosity of 1.50 cp. to 25.0 cp. at 77"F.
2. An ink composition according to Claim 1, wherein the total amount of resin or blend of resins is between 15 and 50 weight percent of the ink composition.
3. An ink composition according to Claim 1 or Claim 2. wherein the ink composition has a viscosity of 1.75 cp. to 25.0 cp. at 77 F.
4. The composition according to any preceding claim, wherein the resin or blend of resins comprises phenolic polymer.
5. The composition according to any one of Claims 1 to 3, wherein the resin or blend of
resins comprises rosin modified phenolic resin.
6. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises rosin modified maleic resin.
7. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises rosin modified fumaric resin.
S. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises polyester.
The The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises rosin.
1(). The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises urea formaldehyde resin.
11. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises melamine formaldehyde resin.
12. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises rubber resin.
13. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins compiiscs polyketone.
14. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises silicone resin.
15. The composition according to any one of Claims 1 to 3, wherein the resin or blend ot resins comprises acrylic resin.
16. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises cellulosic polymer.
17. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises triazine resin.
18. The composition according to 'iny one of Claims 1 to 3, wherein the resin or blend of resins comprises polyvinyl resin.
19. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises polyvinylidene chloride.
20. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises epoxy resin.
21. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises terpene resin.
2. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises phenol modified terpene resin.
23. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises alkyd resin.
24. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises polyamide resin.
25. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises urethane resin.
26. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises hydrocarbon resin.
27. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises shellac resin.
8. The composition according to any one of Claims 1 to 3, wherein the resin or blend of resins comprises vegetable oil.
'9. The composition according to any preceding Claim, wherein an acid electrolyte is present.
30. The composition according to Claim 29, wherein the acid electrolyte is paratoluene sulphonic acid.
31. The composition according to any one of Claims 1 to 28. wherein an alkaline electrolete is present.
2. The composition according to any one of Claims 1 to 28, wherein triethanolamine is present as electrolyte.
33. The composition according to any one of Claims 1 to 28. wherein a salt of an acid and a base is present as electrolyte.
34. The composition according to Claim 33, wherein the salt is the sodium salt of paratoluene sulphonic acid.
35. The composition according to Claim 33, wherein the salt is magnesium chloride.
36. The composition according to Claim 33. wherein the salt is ammonium fomlate.
37. The composition according to any preceding claim, wherein the colouring material
Is an acid dyestuff.
38. The composition according to any one of Claims 1 to 36, wherein the colouring material is a reactive dyestuff.
39. The composition according to any one of Claims 1 to 36, wherein the colouring material is a disperse dyestuff.
40. The composition according to any one of Claims 1 to 36, wherein the colouring material is a basic dyestuff.
41. The composition according to any one of Claims 1 to 36, wherein the colouring material is a dye base.
42. The composition according to any one of Claims 1 to 36, wherein the colouring material is a pigment.
43. The composition according to any one of Claims 1 to 36, wherein the colouring material is a fluorescent compound visible under UV radiation.
44. The composition according to any preceding claim, wherein the solvent material comprises at least one alcohol.
45. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises at least one ether.
46. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises at least one ketone.
47. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises at least one hydrocarbon.
48. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises at least one ester.
49. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises at least one glycol.
50. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises at least one glycol ether.
51. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises water.
52. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises at least one halogenated compound.
53. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises at least one aldehyde.
54. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises at least one ether alcohol.
55. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises at least one acid.
56. The composition according to any one of Claims 1 to 43, wherein the solvent material comprises at least one nitrile.
57. The composition according to any one of Claims 1 to 3 or any one of Claims 29 to 56, wherein the resin or blend of resins comprises acrylonitrile resin.
58. The composition according to any one of Claims 1 to 3 or to any one of Claims 29 to 56, wherein the resin or blend of resins comprises polyether resin.
59. The composition according to any one of Claims 1 to 3 or to any one of Claims 29 to 56, wherein the resin or blend of resins comprises chlorinated polyolefine.
60. The composition according to any one of Claims 1 to 3 or to any one of Claims 29 to 56, wherein the resin or blend of resins comprises polycarbonate resin.
61. The composition according to any one of Claims 1 to 3 or to any one of Claims 29 to 56, wherein the resin or blend of resins comprises styrene maleic anhydride
62. The composition according to Claim 1 substantially as herein described and exemplified.
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US78157577A | 1977-03-28 | 1977-03-28 |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1603062A true GB1603062A (en) | 1981-11-18 |
Family
ID=25123208
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB11803/78A Expired GB1603062A (en) | 1977-03-28 | 1978-03-23 | Ink composition |
Country Status (15)
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JP (1) | JPS53123210A (en) |
AU (1) | AU515542B2 (en) |
BE (1) | BE865206A (en) |
CH (1) | CH639413A5 (en) |
DE (1) | DE2812364A1 (en) |
DK (1) | DK133078A (en) |
ES (1) | ES468239A1 (en) |
FR (1) | FR2385782A1 (en) |
GB (1) | GB1603062A (en) |
IT (1) | IT1103082B (en) |
NL (1) | NL7803273A (en) |
NO (1) | NO781044L (en) |
NZ (1) | NZ186690A (en) |
PL (1) | PL205552A1 (en) |
SE (1) | SE437997B (en) |
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DE3306786A1 (en) * | 1983-02-26 | 1984-08-30 | Fa. J.S. Staedtler, 8500 Nürnberg | WRITING FLUID |
GB2137219A (en) * | 1983-03-10 | 1984-10-03 | Dick Co Ab | Ink composition for ink jet printing |
US5510415A (en) * | 1994-04-25 | 1996-04-23 | Videojet Systems, Inc. | Ink jet composition for printing on textiles |
US5663217A (en) * | 1991-01-11 | 1997-09-02 | Xaar Limited | Ink composition |
US5936027A (en) * | 1994-04-25 | 1999-08-10 | Videojet Systems International, Inc. | Textile jet ink |
US6010564A (en) * | 1997-10-16 | 2000-01-04 | Videojet Systems International, Inc. | Jet ink composition |
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EP1231243A1 (en) * | 2001-01-30 | 2002-08-14 | J.S. STAEDTLER GmbH & Co | Ink-jet ink for for ink-jet printing and use thereof |
US6726756B1 (en) | 2000-05-26 | 2004-04-27 | Videojet Technologies Inc. | Continuous ink jet printing ink composition |
EP1930384A1 (en) * | 2005-09-30 | 2008-06-11 | Dainippon Ink and Chemicals, Incorporated | Ink for jet printer |
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JPS5550073A (en) * | 1978-10-05 | 1980-04-11 | Dainippon Toryo Co Ltd | Jet printing ink |
US4260531A (en) * | 1979-07-02 | 1981-04-07 | A. B. Dick Company | Ink composition for printing on polyolefin |
DE2966788D1 (en) * | 1979-08-15 | 1984-04-19 | American Can Co | Contactless jet printing method, printing ink composition therefor, and articles including containers bearing indicia, printed using said composition |
US4290072A (en) * | 1980-01-28 | 1981-09-15 | American Can Company | Opaque jet ink printing method and composition |
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JPS6076574A (en) * | 1983-10-03 | 1985-05-01 | Tokyo Ohka Kogyo Co Ltd | Ink composition for ink-jet recording |
JPS60118767A (en) * | 1983-11-30 | 1985-06-26 | Tokyo Ohka Kogyo Co Ltd | White ink composition for jet printing |
DE3545625A1 (en) * | 1985-12-21 | 1987-06-25 | Dataprint Datendrucksysteme R | Water-free, liquid recording material |
DE4013456A1 (en) * | 1990-04-27 | 1991-10-31 | Beck & Co Ag Dr | TEMPERATURE AND SOLVENT RESISTANT INK FOR THE JET PRINTING PROCESS |
US5478383A (en) * | 1993-10-14 | 1995-12-26 | Canon Kabushiki Kaisha | Ink, and ink-jet recording method and instrument using the same |
JP4984800B2 (en) * | 2005-09-30 | 2012-07-25 | Dic株式会社 | Ink for jet printer |
JP5463130B2 (en) * | 2009-12-10 | 2014-04-09 | 株式会社ミマキエンジニアリング | ink |
CN104946012B (en) * | 2014-03-27 | 2018-05-01 | 佛山市高明绿色德化工有限公司 | Color crystal glass ink and its production method |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3903034A (en) * | 1970-12-07 | 1975-09-02 | Dick Co Ab | Offset jet printing ink |
US4021252A (en) * | 1973-10-31 | 1977-05-03 | American Can Company | Jet printing ink composition |
JPS5214644B2 (en) * | 1974-09-03 | 1977-04-23 | ||
US4045397A (en) * | 1975-04-24 | 1977-08-30 | Dean Burton Parkinson | Printing ink compositions for jet printing on glazed ceramic surfaces |
US4024096A (en) * | 1975-07-07 | 1977-05-17 | A. B. Dick Company | Jet printing ink composition for glass |
JPS5315905A (en) * | 1976-07-28 | 1978-02-14 | Tokyo Ouka Kougiyou Kk | Method of making offset plate material |
-
1978
- 1978-03-14 NZ NZ186690A patent/NZ186690A/en unknown
- 1978-03-20 CH CH301778A patent/CH639413A5/en not_active IP Right Cessation
- 1978-03-21 DE DE19782812364 patent/DE2812364A1/en active Granted
- 1978-03-21 FR FR7808134A patent/FR2385782A1/en active Granted
- 1978-03-22 NO NO781044A patent/NO781044L/en unknown
- 1978-03-22 SE SE7803316A patent/SE437997B/en not_active IP Right Cessation
- 1978-03-22 DK DK133078A patent/DK133078A/en not_active Application Discontinuation
- 1978-03-22 BE BE186197A patent/BE865206A/en not_active IP Right Cessation
- 1978-03-23 GB GB11803/78A patent/GB1603062A/en not_active Expired
- 1978-03-23 AU AU34468/78A patent/AU515542B2/en not_active Expired
- 1978-03-24 IT IT09390/78A patent/IT1103082B/en active
- 1978-03-24 PL PL20555278A patent/PL205552A1/en unknown
- 1978-03-27 ES ES468239A patent/ES468239A1/en not_active Expired
- 1978-03-28 JP JP3491878A patent/JPS53123210A/en active Granted
- 1978-03-28 NL NL7803273A patent/NL7803273A/en not_active Application Discontinuation
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
DE3306786A1 (en) * | 1983-02-26 | 1984-08-30 | Fa. J.S. Staedtler, 8500 Nürnberg | WRITING FLUID |
GB2135686A (en) * | 1983-02-26 | 1984-09-05 | Staedtler J S | Writing or drawing fluid |
GB2137219A (en) * | 1983-03-10 | 1984-10-03 | Dick Co Ab | Ink composition for ink jet printing |
US5663217A (en) * | 1991-01-11 | 1997-09-02 | Xaar Limited | Ink composition |
US5510415A (en) * | 1994-04-25 | 1996-04-23 | Videojet Systems, Inc. | Ink jet composition for printing on textiles |
US5936027A (en) * | 1994-04-25 | 1999-08-10 | Videojet Systems International, Inc. | Textile jet ink |
US6010564A (en) * | 1997-10-16 | 2000-01-04 | Videojet Systems International, Inc. | Jet ink composition |
WO2000027935A1 (en) * | 1998-11-06 | 2000-05-18 | Marconi Data Systems Inc. | Jet ink composition |
US6444019B1 (en) | 1998-11-06 | 2002-09-03 | Videojet Technologies Inc. | Ink jet ink composition |
AU770978B2 (en) * | 1998-11-06 | 2004-03-11 | Videojet Technologies Inc. | Jet ink composition |
US6726756B1 (en) | 2000-05-26 | 2004-04-27 | Videojet Technologies Inc. | Continuous ink jet printing ink composition |
EP1231243A1 (en) * | 2001-01-30 | 2002-08-14 | J.S. STAEDTLER GmbH & Co | Ink-jet ink for for ink-jet printing and use thereof |
EP1930384A1 (en) * | 2005-09-30 | 2008-06-11 | Dainippon Ink and Chemicals, Incorporated | Ink for jet printer |
EP1930384A4 (en) * | 2005-09-30 | 2011-01-26 | Dainippon Ink & Chemicals | Ink for jet printer |
Also Published As
Publication number | Publication date |
---|---|
FR2385782B1 (en) | 1984-10-19 |
CH639413A5 (en) | 1983-11-15 |
NO781044L (en) | 1978-09-29 |
NL7803273A (en) | 1978-10-02 |
IT7809390A0 (en) | 1978-03-24 |
FR2385782A1 (en) | 1978-10-27 |
DE2812364A1 (en) | 1978-10-05 |
DE2812364C2 (en) | 1988-12-01 |
JPS53123210A (en) | 1978-10-27 |
BE865206A (en) | 1978-07-17 |
AU3446878A (en) | 1979-09-27 |
JPS6221032B2 (en) | 1987-05-11 |
ES468239A1 (en) | 1979-09-16 |
PL205552A1 (en) | 1978-12-04 |
AU515542B2 (en) | 1981-04-09 |
SE437997B (en) | 1985-03-25 |
IT1103082B (en) | 1985-10-14 |
DK133078A (en) | 1978-09-29 |
SE7803316L (en) | 1978-09-29 |
NZ186690A (en) | 1979-10-25 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed [section 19, patents act 1949] | ||
732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
PCNP | Patent ceased through non-payment of renewal fee |
Effective date: 19960323 |