GB1491851A - Process for recovering copper and zinc from hydrothermal ore sludges - Google Patents
Process for recovering copper and zinc from hydrothermal ore sludgesInfo
- Publication number
- GB1491851A GB1491851A GB1236676A GB1236676A GB1491851A GB 1491851 A GB1491851 A GB 1491851A GB 1236676 A GB1236676 A GB 1236676A GB 1236676 A GB1236676 A GB 1236676A GB 1491851 A GB1491851 A GB 1491851A
- Authority
- GB
- United Kingdom
- Prior art keywords
- suspension
- electrodeposition
- ions
- separating
- resulting
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- 239000010949 copper Substances 0.000 title abstract 6
- 239000011701 zinc Substances 0.000 title abstract 6
- 229910052802 copper Inorganic materials 0.000 title abstract 3
- 229910052725 zinc Inorganic materials 0.000 title abstract 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 title abstract 2
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 title abstract 2
- 239000000725 suspension Substances 0.000 abstract 5
- 238000004070 electrodeposition Methods 0.000 abstract 4
- 150000002500 ions Chemical class 0.000 abstract 4
- 239000012141 concentrate Substances 0.000 abstract 3
- 239000003153 chemical reaction reagent Substances 0.000 abstract 2
- 239000003792 electrolyte Substances 0.000 abstract 2
- 238000001704 evaporation Methods 0.000 abstract 2
- 230000008020 evaporation Effects 0.000 abstract 2
- 230000001376 precipitating effect Effects 0.000 abstract 2
- 239000000047 product Substances 0.000 abstract 2
- 239000010802 sludge Substances 0.000 abstract 2
- 239000007787 solid Substances 0.000 abstract 2
- 150000004325 8-hydroxyquinolines Chemical class 0.000 abstract 1
- 206010011416 Croup infectious Diseases 0.000 abstract 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 abstract 1
- 239000000920 calcium hydroxide Substances 0.000 abstract 1
- 235000011116 calcium hydroxide Nutrition 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000010908 decantation Methods 0.000 abstract 1
- 239000007788 liquid Substances 0.000 abstract 1
- 239000000203 mixture Substances 0.000 abstract 1
- 150000002923 oximes Chemical class 0.000 abstract 1
- 229910052760 oxygen Inorganic materials 0.000 abstract 1
- 239000001301 oxygen Substances 0.000 abstract 1
- 239000002244 precipitate Substances 0.000 abstract 1
- 238000011084 recovery Methods 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G3/00—Compounds of copper
- C01G3/003—Preparation involving a liquid-liquid extraction, an adsorption or an ion-exchange
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B15/00—Obtaining copper
- C22B15/0063—Hydrometallurgy
- C22B15/0065—Leaching or slurrying
- C22B15/0067—Leaching or slurrying with acids or salts thereof
- C22B15/0071—Leaching or slurrying with acids or salts thereof containing sulfur
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B19/00—Obtaining zinc or zinc oxide
- C22B19/20—Obtaining zinc otherwise than by distilling
- C22B19/22—Obtaining zinc otherwise than by distilling with leaching with acids
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/04—Extraction of metal compounds from ores or concentrates by wet processes by leaching
- C22B3/06—Extraction of metal compounds from ores or concentrates by wet processes by leaching in inorganic acid solutions, e.g. with acids generated in situ; in inorganic salt solutions other than ammonium salt solutions
- C22B3/08—Sulfuric acid, other sulfurated acids or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/30—Oximes
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22B—PRODUCTION AND REFINING OF METALS; PRETREATMENT OF RAW MATERIALS
- C22B3/00—Extraction of metal compounds from ores or concentrates by wet processes
- C22B3/20—Treatment or purification of solutions, e.g. obtained by leaching
- C22B3/26—Treatment or purification of solutions, e.g. obtained by leaching by liquid-liquid extraction using organic compounds
- C22B3/36—Heterocyclic compounds
- C22B3/362—Heterocyclic compounds of a single type
- C22B3/364—Quinoline
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P10/00—Technologies related to metal processing
- Y02P10/20—Recycling
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Mechanical Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Materials Engineering (AREA)
- Metallurgy (AREA)
- Geology (AREA)
- Geochemistry & Mineralogy (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Environmental & Geological Engineering (AREA)
- Inorganic Chemistry (AREA)
- Manufacture And Refinement Of Metals (AREA)
Abstract
1491851 Copper and zinc recovery FRIED KRUPP GmbH 26 March 1976 [27 March 1975] 12366/76 Heading ClA [Also in Division C7] Cu and Zn are recovered from concentrates of hydrothermal ore sludges by (a) treating a suspension consisting of a mixture of undried ore sludge concentrate having a solids content of 100 to 250 g/l and spent electrolyte from Zn electrode position, the suspension having 20 to 60 g free H 2 SO 4 /100 g. solids, in an autoclave at 80 to 120 C. under superatmospheric pressure in an atmosphere containing oxygen for ¢ to 3 hours, (b) subject the resulting suspension after cooling to multi-stage counterflow decantation in a wash concentrator preferably using vapour condensate produced by evaporation of Cu-free refined product (see below) to separate leach liquor and residue, (c) adding a reagent precipitating Cl ions, e.g. Cu 2 O and a gaseous reducing agent such as SO2, and separating the resulting precipitate, (d) extracting Cu from the resulting solution poor in Cl ions by a liquid ion exchanger (e.g. oximes or derivatives of 8-hydroxy quinoline) and after reextraction separating Cu by electrodeposition, (e) subjecting the Cu-free refined product to multistage evaporation and separating Zn by electrodeposition from the resulting concentrated solution after adding milk of lime, and (f) using the spent electrolyte containing H 2 SO 4 from the Zn electrodeposition to form the suspension in (a). Initially the undried ore sludge concentrate may be washed to a Cl content of less than 5 g/l; and a reagent precipitating Fe ions, e.g. Na 2 SO 4 may be added to the suspension.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE19752513689 DE2513689A1 (en) | 1975-03-27 | 1975-03-27 | PROCESS FOR THE RECOVERY OF VALUABLE SUBSTANCES FROM HYDROTHERMAL OINE SLURES |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1491851A true GB1491851A (en) | 1977-11-16 |
Family
ID=5942613
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB1236676A Expired GB1491851A (en) | 1975-03-27 | 1976-03-26 | Process for recovering copper and zinc from hydrothermal ore sludges |
Country Status (3)
| Country | Link |
|---|---|
| DE (1) | DE2513689A1 (en) |
| FR (1) | FR2305501A1 (en) |
| GB (1) | GB1491851A (en) |
Cited By (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4715939A (en) * | 1986-04-22 | 1987-12-29 | Cominco Ltd. | Method for removal of monovalent ions from ZnSO4 electrolyte by electrodialysis |
| US4979987A (en) | 1988-07-19 | 1990-12-25 | First Miss Gold, Inc. | Precious metals recovery from refractory carbonate ores |
| NL2003595C2 (en) * | 2009-10-06 | 2011-04-07 | Elemetal Holding B V | Process and apparatus for recovering metals. |
| US8029751B2 (en) | 2004-12-22 | 2011-10-04 | Placer Dome Technical Services Limited | Reduction of lime consumption when treating refractory gold ores or concentrates |
| US8061888B2 (en) | 2006-03-17 | 2011-11-22 | Barrick Gold Corporation | Autoclave with underflow dividers |
| US8252254B2 (en) | 2006-06-15 | 2012-08-28 | Barrick Gold Corporation | Process for reduced alkali consumption in the recovery of silver |
| US9827547B2 (en) | 2013-08-15 | 2017-11-28 | Hatch Ltd. | Multi-compartment reactor and method for controlling retention time in a multi-compartment reactor |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL1006340C2 (en) * | 1997-06-17 | 1998-12-21 | Rafael Technologie En Manageme | Method and device for recovering metals. |
Family Cites Families (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR611358A (en) * | 1925-09-24 | 1926-09-27 | Improvements in electrochemical processes and devices for extracting copper and zinc from ores | |
| US2898196A (en) * | 1953-10-22 | 1959-08-04 | Sherritt Gordon Mines Ltd | Method of treating pyrrhotitic mineral sulphides containing non-ferrous metal values for the recovery of said metal values and sulfur |
| US2898197A (en) * | 1958-11-05 | 1959-08-04 | Sherritt Gordon Mines Ltd | Method of treating pyrrhotitic mineral sulphides containing non-ferrous metal values |
| FR1233781A (en) * | 1959-01-22 | 1960-10-12 | Sherritt Gordon Mines Ltd | Process for the production of zinc |
| FR1492518A (en) * | 1965-09-11 | 1967-08-18 | Sherritt Gordon Mines Ltd | Hydrometallurgical process to recover zine and sulfur contained in mineral sulphides |
-
1975
- 1975-03-27 DE DE19752513689 patent/DE2513689A1/en not_active Withdrawn
-
1976
- 1976-03-26 GB GB1236676A patent/GB1491851A/en not_active Expired
- 1976-03-26 FR FR7608839A patent/FR2305501A1/en active Granted
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US4715939A (en) * | 1986-04-22 | 1987-12-29 | Cominco Ltd. | Method for removal of monovalent ions from ZnSO4 electrolyte by electrodialysis |
| US4979987A (en) | 1988-07-19 | 1990-12-25 | First Miss Gold, Inc. | Precious metals recovery from refractory carbonate ores |
| US8029751B2 (en) | 2004-12-22 | 2011-10-04 | Placer Dome Technical Services Limited | Reduction of lime consumption when treating refractory gold ores or concentrates |
| US8061888B2 (en) | 2006-03-17 | 2011-11-22 | Barrick Gold Corporation | Autoclave with underflow dividers |
| US8252254B2 (en) | 2006-06-15 | 2012-08-28 | Barrick Gold Corporation | Process for reduced alkali consumption in the recovery of silver |
| NL2003595C2 (en) * | 2009-10-06 | 2011-04-07 | Elemetal Holding B V | Process and apparatus for recovering metals. |
| WO2011074948A1 (en) * | 2009-10-06 | 2011-06-23 | Elemetal Holding B.V. | Hydrometalurgical process and apparatus for recovering metals from waste material |
| US9023129B2 (en) | 2009-10-06 | 2015-05-05 | Elemetal Holding B.V. | Hydrometalurgical process and apparatus for recovering metals from waste material |
| US9827547B2 (en) | 2013-08-15 | 2017-11-28 | Hatch Ltd. | Multi-compartment reactor and method for controlling retention time in a multi-compartment reactor |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2305501B1 (en) | 1980-04-04 |
| DE2513689A1 (en) | 1976-10-07 |
| FR2305501A1 (en) | 1976-10-22 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| PCNP | Patent ceased through non-payment of renewal fee |