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GB1450642A - Fire retardant thermoplastic interpolymer concentrate - Google Patents

Fire retardant thermoplastic interpolymer concentrate

Info

Publication number
GB1450642A
GB1450642A GB612174A GB612174A GB1450642A GB 1450642 A GB1450642 A GB 1450642A GB 612174 A GB612174 A GB 612174A GB 612174 A GB612174 A GB 612174A GB 1450642 A GB1450642 A GB 1450642A
Authority
GB
United Kingdom
Prior art keywords
grafted
rubber
weight
concentrate
polymer
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB612174A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Monsanto Co
Original Assignee
Monsanto Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Monsanto Co filed Critical Monsanto Co
Publication of GB1450642A publication Critical patent/GB1450642A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C08L51/04—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02—Homopolymers or copolymers of hydrocarbons
    • C08L25/04—Homopolymers or copolymers of styrene
    • C08L25/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/18—Homopolymers or copolymers of nitriles

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Graft Or Block Polymers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

1450642 Grafted chloroprene rubber concentrates MONSANTO CO 11 Feb 1974 [12 Feb 1973] 06121/74 Heading C3G A fire retardant interpolymer concentrate comprises (A) from 1 to 82% by weight of a polymer of at least one mono (alkyl- or halosubstituted or unsubstituted) aromatic monomer and from 0 to 90% by weight of the polymer of an ethylenically unsaturated nitrile and (B) from 99 to 18% of a grafted chloroprene rubber, the rubber being grafted with (1) at least one mono (alkyl- or halo-substituted or unsubstituted) aromatic monomer and (2) from 0 to 90% of the total monomers grafted of an ethylenically unsaturated nitrile, the chloroprene rubber being present in from 15% to 75% by weight of the interpolymer concentrate and polymer (A) and grafted rubber (B) being obtained as said concentrate by polymerization of the monomer or monomers in the presence of the chloroprene rubber. The grafted rubber may comprise a first component having a weight average grafted rubber particle size of from 0À01 to 0À35 micron and a "high" grafted monomer proportion of from 10 to 100% by weight of the rubber and a second component having a particle size of from 0À4 to 1À5 micron and a "low" grafted monomer proportion of 5 to 40% by weight of the rubber. The concentrates are dispersed in a polymer of a vinyl aromatic monomer and 0 to 90% of ethylenically unsaturated nitrile by blending in the melt phase. Examples are given in which (a) chloroprene rubber is grafted in aqueous emulsion with styrene and acrylonitrile, the resulting concentrate being co-coagulated with styreneacrylonitrile copolymer latex and melt colloided with Sb 2 O 3 ; (b) mixtures of "high" and "low" grafted chloroprene rubbers produced as in (a) are formed into blends as in (a); and (c) a blend produced as in (a) is mixed with a butadiene rubber grafted with styrene and acrylonitrile.
GB612174A 1973-02-12 1974-02-11 Fire retardant thermoplastic interpolymer concentrate Expired GB1450642A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US33194373A 1973-02-12 1973-02-12

Publications (1)

Publication Number Publication Date
GB1450642A true GB1450642A (en) 1976-09-22

Family

ID=23296023

Family Applications (1)

Application Number Title Priority Date Filing Date
GB612174A Expired GB1450642A (en) 1973-02-12 1974-02-11 Fire retardant thermoplastic interpolymer concentrate

Country Status (9)

Country Link
JP (1) JPS5029692A (en)
AR (1) AR197547A1 (en)
BR (1) BR7401010A (en)
CA (1) CA1027283A (en)
DE (1) DE2406334A1 (en)
FR (2) FR2219957B1 (en)
GB (1) GB1450642A (en)
IL (1) IL44184A (en)
IT (1) IT1007368B (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1505124A1 (en) * 2003-08-05 2005-02-09 HILTI Aktiengesellschaft Permanently plastic kneading mixture for fire proofing applications, method for its preparation and its use
CN108530789A (en) * 2018-03-21 2018-09-14 青岛海尔新材料研发有限公司 Environmental protection flame retardant injection grade ACS modified materials and preparation method thereof

Families Citing this family (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4130605A (en) * 1976-04-26 1978-12-19 Monsanto Company Method for reducing the dripping in flaming polystyrene compositions
JPS606266A (en) * 1983-06-27 1985-01-12 Toyota Motor Corp Production of metal-base composite material
US5055525A (en) * 1990-02-23 1991-10-08 The Dow Chemical Company Low temperature toughened thermoplastic polymer blend compositions

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR1213542A (en) * 1957-08-28 1960-04-01 Foster Grant Co Inc Styrene resin enhancements
DE1745098B2 (en) * 1966-03-21 1974-10-24 Monsanto Co., St. Louis, Mo. (V.St.A.) Polymer mixtures
FR1537704A (en) * 1966-03-21 1968-08-30 Monsanto Co New polyblend and manufacturing process

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP1505124A1 (en) * 2003-08-05 2005-02-09 HILTI Aktiengesellschaft Permanently plastic kneading mixture for fire proofing applications, method for its preparation and its use
CN100393804C (en) * 2003-08-05 2008-06-11 希尔蒂股份公司 Permanently plastic plasticine for fire-protection applications, methods for its preparation and its use
CN108530789A (en) * 2018-03-21 2018-09-14 青岛海尔新材料研发有限公司 Environmental protection flame retardant injection grade ACS modified materials and preparation method thereof
CN108530789B (en) * 2018-03-21 2021-02-02 青岛海纳新材料有限公司 Environment-friendly flame-retardant injection molding grade ACS modified material and preparation method thereof

Also Published As

Publication number Publication date
AR197547A1 (en) 1974-04-15
DE2406334A1 (en) 1974-08-15
BR7401010A (en) 1976-09-14
FR2219957B1 (en) 1979-02-09
JPS5029692A (en) 1975-03-25
FR2225463B1 (en) 1979-03-09
IL44184A (en) 1977-05-31
IT1007368B (en) 1976-10-30
CA1027283A (en) 1978-02-28
AU6544774A (en) 1975-08-14
FR2219957A1 (en) 1974-09-27
IL44184A0 (en) 1974-05-16
BR7401010D0 (en) 1974-09-10
FR2225463A1 (en) 1974-11-08

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Legal Events

Date Code Title Description
PS Patent sealed [section 19, patents act 1949]
PCNP Patent ceased through non-payment of renewal fee