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GB1380819A - Glass-cermic laminated articles - Google Patents

Glass-cermic laminated articles

Info

Publication number
GB1380819A
GB1380819A GB5120672A GB5120672A GB1380819A GB 1380819 A GB1380819 A GB 1380819A GB 5120672 A GB5120672 A GB 5120672A GB 5120672 A GB5120672 A GB 5120672A GB 1380819 A GB1380819 A GB 1380819A
Authority
GB
United Kingdom
Prior art keywords
glass
surface layer
core
density
crystallization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB5120672A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Corning Glass Works
Original Assignee
Corning Glass Works
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Corning Glass Works filed Critical Corning Glass Works
Publication of GB1380819A publication Critical patent/GB1380819A/en
Expired legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • C03C10/0018Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and monovalent metal oxide as main constituents
    • C03C10/0027Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition containing SiO2, Al2O3 and monovalent metal oxide as main constituents containing SiO2, Al2O3, Li2O as main constituents
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/02Forming molten glass coated with coloured layers; Forming molten glass of different compositions or layers; Forming molten glass comprising reinforcements or inserts
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B27/00Tempering or quenching glass products
    • C03B27/012Tempering or quenching glass products by heat treatment, e.g. for crystallisation; Heat treatment of glass products before tempering by cooling
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B32/00Thermal after-treatment of glass products not provided for in groups C03B19/00, C03B25/00 - C03B31/00 or C03B37/00, e.g. crystallisation, eliminating gas inclusions or other impurities; Hot-pressing vitrified, non-porous, shaped glass products
    • C03B32/02Thermal crystallisation, e.g. for crystallising glass bodies into glass-ceramic articles
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C10/00Devitrified glass ceramics, i.e. glass ceramics having a crystalline phase dispersed in a glassy phase and constituting at least 50% by weight of the total composition
    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03CCHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C17/00Surface treatment of glass, not in the form of fibres or filaments, by coating
    • C03C17/02Surface treatment of glass, not in the form of fibres or filaments, by coating with glass

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Ceramic Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Dispersion Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Glass Compositions (AREA)
  • Re-Forming, After-Treatment, Cutting And Transporting Of Glass Products (AREA)
  • Surface Treatment Of Glass (AREA)

Abstract

1380819 Glass-ceramic laminates CORNING GLASS WORKS 7 Nov 1972 [8 Nov 1971] 51206/72 Heading C1M A strengthened glass-ceramic laminated article comprises a glass-ceramic core of density D ef and a compressively-stressed glass or glassceramic surface layer of density D sf fused to and substantially enveloping the core, the core being formed by crystallization in situ of a crystallizable glass of density D ci and the surface layer by crystallization of a glass of density D si , the core and surface materials being chosen such that the value of the expression is positive. The article is formed by laminating a thermally-crystallizable glass core portion and a glass or crystallizable glass surface layer at a temperature above the softening point of one of the glasses, and heat treating the laminated glass article at a temperature and for a time sufficient to crystallize the crystallizable glass portions, but insufficient to allow complete stress relaxation in the surface. The strengthening is primarily caused by differential densification on crystallization, but some strengthening may result from thermal expansion mismatch, as the core material preferably has an expansion coefficient at least equal to that of the surface layer before and after crystallization. Preferably the surface layer crystallizes at a lower temperature and higher viscosity than the core. Preferably the percent densification differential (D), defined by is at least 0À5%, more preferably 1-5%. Where the surface layer is of non-crystallizable glass or certain glass-ceramics D sf = D si (i.e. there is no density change in the surface layer).
GB5120672A 1971-11-08 1972-11-07 Glass-cermic laminated articles Expired GB1380819A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US19659371A 1971-11-08 1971-11-08

Publications (1)

Publication Number Publication Date
GB1380819A true GB1380819A (en) 1975-01-15

Family

ID=22726021

Family Applications (1)

Application Number Title Priority Date Filing Date
GB5120672A Expired GB1380819A (en) 1971-11-08 1972-11-07 Glass-cermic laminated articles

Country Status (9)

Country Link
JP (1) JPS553300B2 (en)
AU (1) AU465939B2 (en)
BE (1) BE791041A (en)
CA (1) CA981022A (en)
DE (1) DE2254118C3 (en)
FR (1) FR2159300B1 (en)
GB (1) GB1380819A (en)
IT (1) IT970215B (en)
NL (1) NL7215029A (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2212800A (en) * 1987-10-06 1989-08-02 Univ Sheffield Method of coating articles
EP2903821B1 (en) * 2012-10-04 2019-08-28 Corning Incorporated Laminated glass article with ceramic phase and method of making the article

Families Citing this family (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110698059B (en) * 2012-10-04 2022-07-29 康宁股份有限公司 Compressive stressed laminated glass articles made from photosensitive glass and methods of making the same
JP6026926B2 (en) * 2012-11-16 2016-11-16 株式会社オハラ Crystallized glass and crystallized glass substrate for information recording medium
US20160114564A1 (en) * 2013-06-14 2016-04-28 Corning Incorporated Laminated glass article with scratch resistant surface
WO2016028625A1 (en) * 2014-08-21 2016-02-25 Corning Incorporated Methods for preventing blisters in laminated glass articles and laminated glass articles formed therefrom

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB2212800A (en) * 1987-10-06 1989-08-02 Univ Sheffield Method of coating articles
EP2903821B1 (en) * 2012-10-04 2019-08-28 Corning Incorporated Laminated glass article with ceramic phase and method of making the article

Also Published As

Publication number Publication date
FR2159300B1 (en) 1980-04-04
AU4829872A (en) 1974-05-02
JPS553300B2 (en) 1980-01-24
BE791041A (en) 1973-05-07
NL7215029A (en) 1973-05-10
CA981022A (en) 1976-01-06
AU465939B2 (en) 1975-10-09
DE2254118B2 (en) 1980-11-13
DE2254118A1 (en) 1973-05-10
DE2254118C3 (en) 1981-10-01
JPS4855211A (en) 1973-08-03
IT970215B (en) 1974-04-10
FR2159300A1 (en) 1973-06-22

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee