GB1371889A - Carbon fibre reinforced nickel matrix composite having an intermediate layer of metal carbide - Google Patents
Carbon fibre reinforced nickel matrix composite having an intermediate layer of metal carbideInfo
- Publication number
- GB1371889A GB1371889A GB3270573A GB3270573A GB1371889A GB 1371889 A GB1371889 A GB 1371889A GB 3270573 A GB3270573 A GB 3270573A GB 3270573 A GB3270573 A GB 3270573A GB 1371889 A GB1371889 A GB 1371889A
- Authority
- GB
- United Kingdom
- Prior art keywords
- fibres
- metal
- deposition
- electrolyte containing
- coating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title abstract 5
- 229910052799 carbon Inorganic materials 0.000 title abstract 5
- 239000002184 metal Substances 0.000 title abstract 5
- 229910052751 metal Inorganic materials 0.000 title abstract 5
- 239000002131 composite material Substances 0.000 title abstract 3
- 239000011159 matrix material Substances 0.000 title abstract 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 title 2
- 239000000835 fiber Substances 0.000 title 1
- 229910052759 nickel Inorganic materials 0.000 title 1
- 239000011248 coating agent Substances 0.000 abstract 3
- 238000000576 coating method Methods 0.000 abstract 3
- 238000000151 deposition Methods 0.000 abstract 3
- 230000008021 deposition Effects 0.000 abstract 3
- 239000003792 electrolyte Substances 0.000 abstract 3
- 238000007731 hot pressing Methods 0.000 abstract 2
- 241000080590 Niso Species 0.000 abstract 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 abstract 1
- 229910052804 chromium Inorganic materials 0.000 abstract 1
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 238000005868 electrolysis reaction Methods 0.000 abstract 1
- 238000009713 electroplating Methods 0.000 abstract 1
- 229910052735 hafnium Inorganic materials 0.000 abstract 1
- 150000004820 halides Chemical class 0.000 abstract 1
- 229910052742 iron Inorganic materials 0.000 abstract 1
- 238000000034 method Methods 0.000 abstract 1
- 229910052750 molybdenum Inorganic materials 0.000 abstract 1
- 229910052758 niobium Inorganic materials 0.000 abstract 1
- 238000004544 sputter deposition Methods 0.000 abstract 1
- 229910052715 tantalum Inorganic materials 0.000 abstract 1
- 229910052719 titanium Inorganic materials 0.000 abstract 1
- 229910052721 tungsten Inorganic materials 0.000 abstract 1
- 229910052720 vanadium Inorganic materials 0.000 abstract 1
- 229910052726 zirconium Inorganic materials 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C22—METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
- C22C—ALLOYS
- C22C49/00—Alloys containing metallic or non-metallic fibres or filaments
- C22C49/14—Alloys containing metallic or non-metallic fibres or filaments characterised by the fibres or filaments
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
- Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
- Y10T29/00—Metal working
- Y10T29/49—Method of mechanical manufacture
- Y10T29/49801—Shaping fiber or fibered material
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Manufacture Of Alloys Or Alloy Compounds (AREA)
- Chemical Treatment Of Fibers During Manufacturing Processes (AREA)
- Electroplating Methods And Accessories (AREA)
- Solid-Phase Diffusion Into Metallic Material Surfaces (AREA)
Abstract
1371889 Hot pressed metal coated carbon fibres UNION CARBIDE CORP 9 July 1973 [10 July 1972] 32705/73 Headings C7B C7D and C7F A composite article comprising a Ni base matrix reinforced with carbon fibres is made by coating the fibres with a Ni layer and an outer layer of a metal which can diffuse through the Ni and react with the carbon to form a metal carbide and then hot pressing the coated fibres. The carbide forming metal may be Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W or Fe and it may be deposited up to a thickness of 5000 by electrolysis, electroless coating, by decomposition of the carbonyl or halide or by sputtering. The Ni coating of 5 micron maximum thickness may be deposited by the same methods. Hot pressing is effected at 700-1300C and 500-4500 p.s.i.a. in N 2 , A, Xe, He or a vacuum. The examples disclose electro-plating of carbon fibres by deposition of Ni from an electrolyte containing NiSO 4 , NiCl 2 and H 3 BO 3 and either deposition of Cr from an electrolyte containing H 2 CrO 4 , Cr 2 (SO 4 ) 3 and H 2 SO 4 or deposition of Fe from an electrolyte containing Fe(NH 4 ) SO 4 . The coated fibres can be hot pressed in aligned layers or wound on a mandrel. The composites are used in subsonic and supersonic aircraft, space system components and other propulsion devices.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US00270260A US3807996A (en) | 1972-07-10 | 1972-07-10 | Carbon fiber reinforced nickel matrix composite having an intermediate layer of metal carbide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1371889A true GB1371889A (en) | 1974-10-30 |
Family
ID=23030579
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB3270573A Expired GB1371889A (en) | 1972-07-10 | 1973-07-09 | Carbon fibre reinforced nickel matrix composite having an intermediate layer of metal carbide |
Country Status (5)
| Country | Link |
|---|---|
| US (1) | US3807996A (en) |
| JP (1) | JPS5224501B2 (en) |
| FR (1) | FR2192193B1 (en) |
| GB (1) | GB1371889A (en) |
| IT (1) | IT989794B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2219006A (en) * | 1988-05-26 | 1989-11-29 | Rolls Royce Plc | Coated fibre for use in a metal matrix |
Families Citing this family (36)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3888661A (en) * | 1972-08-04 | 1975-06-10 | Us Army | Production of graphite fiber reinforced metal matrix composites |
| US4252856A (en) * | 1973-03-12 | 1981-02-24 | Union Carbide Corporation | Chemically bonded aluminum coated carbon via monocarbides |
| US3918141A (en) * | 1974-04-12 | 1975-11-11 | Fiber Materials | Method of producing a graphite-fiber-reinforced metal composite |
| JPS5253720A (en) * | 1975-10-29 | 1977-04-30 | Hitachi Ltd | Non-orientated cu-carbon fiber compoite and its manufacturing method |
| US4440571A (en) * | 1981-07-10 | 1984-04-03 | Nippon Carbon Co., Ltd. | Process for the surface treatment of inorganic fibers for reinforcing titanium or nickel and product |
| US4661403A (en) * | 1982-03-16 | 1987-04-28 | American Cyanamid Company | Yarns and tows comprising high strength metal coated fibers, process for their production, and articles made therefrom |
| US4680100A (en) * | 1982-03-16 | 1987-07-14 | American Cyanamid Company | Electrochemical cells and electrodes therefor |
| US4904351A (en) * | 1982-03-16 | 1990-02-27 | American Cyanamid Company | Process for continuously plating fiber |
| US4609449A (en) * | 1982-03-16 | 1986-09-02 | American Cyanamid Company | Apparatus for the production of continuous yarns or tows comprising high strength metal coated fibers |
| US4909910A (en) * | 1982-03-16 | 1990-03-20 | American Cyanamid | Yarns and tows comprising high strength metal coated fibers, process for their production, and articles made therefrom |
| US4911797A (en) * | 1983-06-24 | 1990-03-27 | American Cyanamid Company | Contact roller mounting assembly and tensioning mechanism for electroplating fiber |
| US4624751A (en) * | 1983-06-24 | 1986-11-25 | American Cyanamid Company | Process for fiber plating and apparatus with special tensioning mechanism |
| JPH07818B2 (en) * | 1985-11-20 | 1995-01-11 | 株式会社日立製作所 | Method for producing metal matrix-fiber composite material |
| FR2685693B1 (en) * | 1991-12-30 | 1994-06-03 | Europ Propulsion | PROCESS FOR PRODUCING PROTECTION AGAINST OXIDATION OF COMPOSITE MATERIAL PRODUCTS, AND PRODUCTS THUS PROTECTED. |
| US20050181209A1 (en) * | 1999-08-20 | 2005-08-18 | Karandikar Prashant G. | Nanotube-containing composite bodies, and methods for making same |
| US7169465B1 (en) | 1999-08-20 | 2007-01-30 | Karandikar Prashant G | Low expansion metal-ceramic composite bodies, and methods for making same |
| US7244034B1 (en) | 1999-08-20 | 2007-07-17 | M Cubed Technologies, Inc. | Low CTE metal-ceramic composite articles, and methods for making same |
| US6355340B1 (en) | 1999-08-20 | 2002-03-12 | M Cubed Technologies, Inc. | Low expansion metal matrix composites |
| US20060062985A1 (en) * | 2004-04-26 | 2006-03-23 | Karandikar Prashant G | Nanotube-containing composite bodies, and methods for making same |
| DE102007004531A1 (en) * | 2007-01-24 | 2008-07-31 | Eads Deutschland Gmbh | Fiber composite with metallic matrix and process for its preparation |
| US20230339820A1 (en) * | 2011-04-12 | 2023-10-26 | Powdermet, Inc. | Low thermal stress engineered metal structures |
| US9963395B2 (en) | 2013-12-11 | 2018-05-08 | Baker Hughes, A Ge Company, Llc | Methods of making carbon composites |
| US9325012B1 (en) | 2014-09-17 | 2016-04-26 | Baker Hughes Incorporated | Carbon composites |
| US10315922B2 (en) | 2014-09-29 | 2019-06-11 | Baker Hughes, A Ge Company, Llc | Carbon composites and methods of manufacture |
| US10480288B2 (en) | 2014-10-15 | 2019-11-19 | Baker Hughes, A Ge Company, Llc | Articles containing carbon composites and methods of manufacture |
| GB2531522B (en) * | 2014-10-20 | 2018-05-09 | Bae Systems Plc | Strain sensing in composite materials |
| US9962903B2 (en) | 2014-11-13 | 2018-05-08 | Baker Hughes, A Ge Company, Llc | Reinforced composites, methods of manufacture, and articles therefrom |
| US9745451B2 (en) | 2014-11-17 | 2017-08-29 | Baker Hughes Incorporated | Swellable compositions, articles formed therefrom, and methods of manufacture thereof |
| US11097511B2 (en) | 2014-11-18 | 2021-08-24 | Baker Hughes, A Ge Company, Llc | Methods of forming polymer coatings on metallic substrates |
| US10300627B2 (en) | 2014-11-25 | 2019-05-28 | Baker Hughes, A Ge Company, Llc | Method of forming a flexible carbon composite self-lubricating seal |
| CN104674327B (en) * | 2015-03-03 | 2017-07-28 | 北京汽车股份有限公司 | The preparation method and composite deposite of composite deposite |
| US9840887B2 (en) | 2015-05-13 | 2017-12-12 | Baker Hughes Incorporated | Wear-resistant and self-lubricant bore receptacle packoff tool |
| US10125274B2 (en) | 2016-05-03 | 2018-11-13 | Baker Hughes, A Ge Company, Llc | Coatings containing carbon composite fillers and methods of manufacture |
| US10344559B2 (en) | 2016-05-26 | 2019-07-09 | Baker Hughes, A Ge Company, Llc | High temperature high pressure seal for downhole chemical injection applications |
| CN108796400B (en) * | 2018-07-11 | 2019-07-30 | 河北工业职业技术学院 | A kind of preparation method of continuous carbon fibre enhancing nickel-base composite material |
| CN111360269B (en) * | 2020-04-03 | 2022-05-06 | 浙江蓝天知识产权运营管理有限公司 | Multi-stage nanostructure reinforced laminated nickel-based composite material and preparation method thereof |
Family Cites Families (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US2093390A (en) * | 1934-12-19 | 1937-09-14 | Union Carbide & Carbon Corp | Means and method of making electrode joints |
| US2548897A (en) * | 1947-04-07 | 1951-04-17 | William J Kroll | Process for melting hafnium, zirconium, and titanium metals |
| US3047383A (en) * | 1955-12-27 | 1962-07-31 | Owens Corning Fiberglass Corp | Polyphase materials |
| US3098723A (en) * | 1960-01-18 | 1963-07-23 | Rand Corp | Novel structural composite material |
| DE1299056B (en) * | 1966-09-29 | 1969-07-10 | Rhein Westfael Elect Werk Ag | Method for the production of a porous Stromableitgeruestes consisting of metallized, in particular nickel-plated, finest-fiber carbon or graphite fleece by sintering |
| GB1215002A (en) * | 1967-02-02 | 1970-12-09 | Courtaulds Ltd | Coating carbon with metal |
| US3553820A (en) * | 1967-02-21 | 1971-01-12 | Union Carbide Corp | Method of producing aluminum-carbon fiber composites |
| US3443301A (en) * | 1967-02-24 | 1969-05-13 | United Aircraft Corp | Method of fabricating fiber-reinforced articles |
| US3622283A (en) * | 1967-05-17 | 1971-11-23 | Union Carbide Corp | Tin-carbon fiber composites |
| US3535093A (en) * | 1968-05-09 | 1970-10-20 | Union Carbide Corp | Aluminum composite containing carbon fibers coated with silver |
| US3571901A (en) * | 1969-06-13 | 1971-03-23 | Union Carbide Corp | Method of fabricating a carbon-fiber reinforced composite article |
| CH528596A (en) * | 1970-07-03 | 1972-09-30 | Bbc Brown Boveri & Cie | Process for the production of metal reinforced with carbon fibers |
| NL7010183A (en) * | 1970-07-09 | 1972-01-11 | Solderable metal coatings of carbon - surfaces | |
| DE2037901B2 (en) * | 1970-07-30 | 1974-05-30 | Battelle-Institut E.V., 6000 Frankfurt | Process for the production of a composite material from a metal or plastic matrix with coated embedding materials |
| CA953128A (en) * | 1971-01-06 | 1974-08-20 | British Railways Board | Methods of producing a metal and carbon fibre composite |
-
1972
- 1972-07-10 US US00270260A patent/US3807996A/en not_active Expired - Lifetime
-
1973
- 1973-07-09 FR FR7325063A patent/FR2192193B1/fr not_active Expired
- 1973-07-09 JP JP48076669A patent/JPS5224501B2/ja not_active Expired
- 1973-07-09 IT IT51319/73A patent/IT989794B/en active
- 1973-07-09 GB GB3270573A patent/GB1371889A/en not_active Expired
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB2219006A (en) * | 1988-05-26 | 1989-11-29 | Rolls Royce Plc | Coated fibre for use in a metal matrix |
Also Published As
| Publication number | Publication date |
|---|---|
| FR2192193B1 (en) | 1976-06-18 |
| IT989794B (en) | 1975-06-10 |
| DE2334218B2 (en) | 1976-04-08 |
| US3807996A (en) | 1974-04-30 |
| FR2192193A1 (en) | 1974-02-08 |
| DE2334218A1 (en) | 1974-01-31 |
| JPS5224501B2 (en) | 1977-07-01 |
| JPS4953119A (en) | 1974-05-23 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PS | Patent sealed [section 19, patents act 1949] | ||
| 732 | Registration of transactions, instruments or events in the register (sect. 32/1977) | ||
| PCNP | Patent ceased through non-payment of renewal fee |