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GB1367238A - Complex polyelectrolytes - Google Patents

Complex polyelectrolytes

Info

Publication number
GB1367238A
GB1367238A GB3083372A GB3083372A GB1367238A GB 1367238 A GB1367238 A GB 1367238A GB 3083372 A GB3083372 A GB 3083372A GB 3083372 A GB3083372 A GB 3083372A GB 1367238 A GB1367238 A GB 1367238A
Authority
GB
United Kingdom
Prior art keywords
formula
symbol
quaternised
polymer
membranes
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB3083372A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhone Poulenc SA
Original Assignee
Rhone Poulenc SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from FR7124234A external-priority patent/FR2100165A5/en
Application filed by Rhone Poulenc SA filed Critical Rhone Poulenc SA
Publication of GB1367238A publication Critical patent/GB1367238A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G69/00—Macromolecular compounds obtained by reactions forming a carboxylic amide link in the main chain of the macromolecule
    • C08G69/02—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids
    • C08G69/26—Polyamides derived from amino-carboxylic acids or from polyamines and polycarboxylic acids derived from polyamines and polycarboxylic acids
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D71/00—Semi-permeable membranes for separation processes or apparatus characterised by the material; Manufacturing processes specially adapted therefor
    • B01D71/06—Organic material
    • B01D71/76—Macromolecular material not specifically provided for in a single one of groups B01D71/08 - B01D71/74
    • B01D71/80—Block polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0809—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups
    • C08G18/0814—Manufacture of polymers containing ionic or ionogenic groups containing cationic or cationogenic groups containing ammonium groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/42—Polycondensates having carboxylic or carbonic ester groups in the main chain
    • C08G18/46—Polycondensates having carboxylic or carbonic ester groups in the main chain having heteroatoms other than oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G65/00—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
    • C08G65/34—Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule from hydroxy compounds or their metallic derivatives
    • C08G65/48—Polymers modified by chemical after-treatment
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G75/00—Macromolecular compounds obtained by reactions forming a linkage containing sulfur with or without nitrogen, oxygen, or carbon in the main chain of the macromolecule
    • C08G75/20—Polysulfones
    • C08G75/23—Polyethersulfones
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C08J3/246—Intercrosslinking of at least two polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L101/00—Compositions of unspecified macromolecular compounds
    • C08L101/02—Compositions of unspecified macromolecular compounds characterised by the presence of specified groups, e.g. terminal or pendant functional groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L57/00—Compositions of unspecified polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G2340/00—Filter material

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • General Chemical & Material Sciences (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Macromolecular Compounds Obtained By Forming Nitrogen-Containing Linkages In General (AREA)

Abstract

1367238 Dialysis; ultra filtration RHONEPOULENC SA 30 June 1972 [2 July 1971] 30833/72 Heading B1X [Also in Division C3] Films and membranes useful for fractionating protein solutions and in applications such as artificial kidneys and lungs are formed from complex polyelectrolytes which comprise an ionically crosslinked, polymer which is soluble in a liquid organic medium and which corresponds to the general formula: in which the symbol N<SP>+</SP> represents a quaternary nitrogen-containing group; the symbol represents a first macromolecular chain to which the indicated -SO 3 <SP>-</SP> groups are linked via a divalent radical or a direct bond, the symbol represents a second macromolecular chain, the symbol indicates that the N<SP>+</SP> groups shown are linked to said second macromolecular chain via at least one divalent radical or direct bond, and said macromolecular chains, considered together, do not contain oppositely charged groups which are capable of forming inter chain covalent bonds; the ratio n/m is from 0.1 to 10; and the nature of the units forming the macromolecular chains and the values of n and m are such that the polymer of the formula: in which M represents a hydrogen ion or an alkali metal or alkaline earth metal ion and x is 1 or 2, and the polymer of the formula: in which A represents a hydroxyl radical or the anion of an inorganic or organic acid of formula AHy, y being 1, 2 or 3, are both insoluble in water but soluble in a common liquid organic medium. The films and membranes can be planar, tubular or spiral and may have isotropic (dense structure of uniform porosity) or anisotropic (having a porosity gradient from one face to the other) structure. In Examples the membranes are used to fractionate (e.g. by ultra filtration, inverse osmosis or dialysis) bovine albumen, ovalbumin, lysozyme and cytochrome C. In the Examples the polyelectrolytes are derived from (a) acrylonitrile-sodium methallyl sulphonate copolymer or sulphonated polyaryl ether/sulphone and (b) acrylonitrile/3-vinyl-6-methyl pyridine copolymer quaternised by methyl sulphate, a phenoxy resin quaternised by treatment with epichlorohydrin and then with trimethylamine, or a polyester-quaternised polyurethane.
GB3083372A 1971-07-02 1972-07-30 Complex polyelectrolytes Expired GB1367238A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR7124235A FR2144922A5 (en) 1971-07-02 1971-07-02
FR7124234A FR2100165A5 (en) 1970-07-03 1971-07-02 Film sleeve packaging - with roller feed, welding and sealing and metered filling for aseptic contents

Publications (1)

Publication Number Publication Date
GB1367238A true GB1367238A (en) 1974-09-18

Family

ID=26216496

Family Applications (1)

Application Number Title Priority Date Filing Date
GB3083372A Expired GB1367238A (en) 1971-07-02 1972-07-30 Complex polyelectrolytes

Country Status (8)

Country Link
JP (1) JPS6018698B2 (en)
BE (1) BE785741A (en)
CH (2) CH563419A5 (en)
DE (1) DE2232204A1 (en)
FR (1) FR2144922A5 (en)
GB (1) GB1367238A (en)
LU (1) LU65631A1 (en)
NL (1) NL170550C (en)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4842849A (en) * 1981-05-08 1989-06-27 L'oreal Composition intended for the treatment of keratin fibres, based on a cationic polymer and an anionic polymer containing vinylsulphonic groups
WO2024219965A1 (en) * 2023-04-17 2024-10-24 Stichting Wageningen Research Polyelectrolyte complex

Families Citing this family (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2252862B1 (en) * 1973-12-04 1978-10-27 Rhone Poulenc Ind
FR2295979A1 (en) * 1974-12-26 1976-07-23 Rhone Poulenc Ind SULPHONATED POLYARYLETHERSULFONES AND THEIR PREPARATION PROCESS
IL64967A0 (en) * 1981-03-17 1982-04-30 Aligena Ag Semipermeable membranes containing modified polysulfones,their manufacture and their use
DE3277458D1 (en) * 1981-11-05 1987-11-19 Takeo Saegusa Polymer compositions
JP3289055B2 (en) * 1990-11-29 2002-06-04 株式会社ヤトロン Polyelectrolyte complex antibacterial agent and antibacterial material
JP2016113499A (en) * 2014-12-12 2016-06-23 日本エクスラン工業株式会社 Resin molded body

Family Cites Families (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA838720A (en) * 1970-04-07 S. Michaels Alan Aqueous polyanionic polycationic electrolyte resin solutions
CA838717A (en) * 1970-04-07 S. Michaels Alan Making plasticised polyelectrolyte aqueous gels
CA838718A (en) * 1970-04-07 S. Michaels Alan Making shaped polyanion-polycation resin structures
CA838719A (en) * 1970-04-07 S. Michaels Alan Making shaped articles of polyelectrolyte resin gels
CA838721A (en) * 1970-04-07 S. Michaels Alan Shaping articles of poly anionic poly cationic resin gels
NL185232B (en) * 1953-02-18 Rhodes Walton Richard DEVICE FOR COMPRESSIBLE LONG-DIRECTIONAL CRUSHING OF A MOVING MATERIAL PATH.
US3546142A (en) * 1967-01-19 1970-12-08 Amicon Corp Polyelectrolyte structures

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4842849A (en) * 1981-05-08 1989-06-27 L'oreal Composition intended for the treatment of keratin fibres, based on a cationic polymer and an anionic polymer containing vinylsulphonic groups
WO2024219965A1 (en) * 2023-04-17 2024-10-24 Stichting Wageningen Research Polyelectrolyte complex

Also Published As

Publication number Publication date
DE2232204A1 (en) 1973-01-11
FR2144922A5 (en) 1973-02-16
NL170550B (en) 1982-06-16
LU65631A1 (en) 1973-01-22
NL170550C (en) 1982-11-16
JPS5334887A (en) 1978-03-31
JPS6018698B2 (en) 1985-05-11
NL7208686A (en) 1973-01-04
CH573953A5 (en) 1976-03-31
BE785741A (en) 1973-01-02
CH563419A5 (en) 1975-06-30

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Legal Events

Date Code Title Description
PS Patent sealed
PCNP Patent ceased through non-payment of renewal fee