GB1242980A - A PROCESS OF PREPARING CARBALKOXYALKYL ESTERS OF alpha,beta-UNSATURATED ACIDS - Google Patents
A PROCESS OF PREPARING CARBALKOXYALKYL ESTERS OF alpha,beta-UNSATURATED ACIDSInfo
- Publication number
- GB1242980A GB1242980A GB6073469A GB6073469A GB1242980A GB 1242980 A GB1242980 A GB 1242980A GB 6073469 A GB6073469 A GB 6073469A GB 6073469 A GB6073469 A GB 6073469A GB 1242980 A GB1242980 A GB 1242980A
- Authority
- GB
- United Kingdom
- Prior art keywords
- methacrylate
- carbalkoxyalkyl
- esters
- carbmethoxybutyl
- acrylate
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C69/00—Esters of carboxylic acids; Esters of carbonic or haloformic acids
- C07C69/52—Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
- C07C69/533—Monocarboxylic acid esters having only one carbon-to-carbon double bond
- C07C69/54—Acrylic acid esters; Methacrylic acid esters
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
1,242,980. Preparation of carbalkoxyalkyl esters of α,#-unsaturated acids. NAUCHNOISSLEDOVATELSKY INSTITUT MONOMEROV DLYA SINTETICHESKOGO KAUCHJKA. 12 Dec., 1969, No. 60734/69. Heading C2C. Carbalkoxyalkyl esters of α,#-unsaturated carboxylic acids are prepared by heating an ester of a halogen-substituted carboxylic acid with an alkali metal salt of an α,#-unsaturated carboxylic acid in the presence of a catalyst comprising a tertiary amine or a quaternary ammonium salt. The reactants are preferably XACOOR<SP>1</SP> and CH 2 = C(R)COOM in which X is Cl, Br or I, A is a C 1-6 divalent hydrocarbon radical, R<SP>1</SP> is a C 1-6 alkyl radical, R is H or CH 3 and M is alkali metal. The ester to salt molar ratio is advantageously 1: 1 to 4: 1 and the reaction may be performed in an inert solvent such as acetonitrile, toluene, dimethylformamide or dimethylsulphoxide in the presence of a radical polymerization inhibitor. Suitable catalysts are triethylamine, tetramethylammonium chloride, pyridine, benzyltrimethylammonium chloride and tetraethylammonium bromide. In the examples the novel compounds carbethoxymethylacrylate, carbisopropoxymethyl methacrylate, 4 - carbmethoxybutyl methacrylate, 4 - carbethoxybutyl methacrylate, 6 - carbmethoxyhexyl methacrylate, 4- carbmethoxybutyl acrylate and 6-carbmethoxy acrylate are prepared.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB6073469A GB1242980A (en) | 1969-12-12 | 1969-12-12 | A PROCESS OF PREPARING CARBALKOXYALKYL ESTERS OF alpha,beta-UNSATURATED ACIDS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB6073469A GB1242980A (en) | 1969-12-12 | 1969-12-12 | A PROCESS OF PREPARING CARBALKOXYALKYL ESTERS OF alpha,beta-UNSATURATED ACIDS |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| GB1242980A true GB1242980A (en) | 1971-08-18 |
Family
ID=10485993
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| GB6073469A Expired GB1242980A (en) | 1969-12-12 | 1969-12-12 | A PROCESS OF PREPARING CARBALKOXYALKYL ESTERS OF alpha,beta-UNSATURATED ACIDS |
Country Status (1)
| Country | Link |
|---|---|
| GB (1) | GB1242980A (en) |
Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0020000A1 (en) * | 1979-05-29 | 1980-12-10 | American Cyanamid Company | Activated ester monomers, polymers formed therefrom and coating compositions containing said polymers |
| US4587055A (en) * | 1982-05-26 | 1986-05-06 | Research Corporation | Polymerized vesicles and compounds for their preparation |
| US4608400A (en) * | 1984-07-23 | 1986-08-26 | Nippon Kayaku Kabushiki Kaisha | Novel (meth)acrylate and resin composition comprising the same |
| US4656308A (en) * | 1979-05-29 | 1987-04-07 | American Cyanamid Company | Ethers of acrylamidoglycolic acid and esters |
| US4668433A (en) * | 1984-08-06 | 1987-05-26 | Givaudan Corporation | Novel derivatives of 6-hydroxyhexanoates as fragrance ingredients |
| CN103217523A (en) * | 2006-08-09 | 2013-07-24 | 住友电木株式会社 | Sugar chain-capturing substance and use thereof |
| US9334428B2 (en) | 2012-12-19 | 2016-05-10 | 3M Innovative Properties Company | Pressure-sensitive adhesives prepared from degradable monomers and polymers |
| JP2017110154A (en) * | 2015-12-18 | 2017-06-22 | 株式会社リコー | Active energy ray-curable composition, active energy ray-curable ink composition, active energy ray-curable inkjet ink composition, composition container, 2- or 3-dimensional image formation device, and 2- or 3-dimensional image formation method |
-
1969
- 1969-12-12 GB GB6073469A patent/GB1242980A/en not_active Expired
Cited By (15)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0020000A1 (en) * | 1979-05-29 | 1980-12-10 | American Cyanamid Company | Activated ester monomers, polymers formed therefrom and coating compositions containing said polymers |
| EP0049910A2 (en) * | 1979-05-29 | 1982-04-21 | American Cyanamid Company | Copolymers formed from activated ester monomers, and coating compositions containing said copolymers |
| EP0049910A3 (en) * | 1979-05-29 | 1982-08-11 | American Cyanamid Company | Copolymers formed from activated ester monomers, and coating compositions containing said copolymers |
| US4656308A (en) * | 1979-05-29 | 1987-04-07 | American Cyanamid Company | Ethers of acrylamidoglycolic acid and esters |
| US4587055A (en) * | 1982-05-26 | 1986-05-06 | Research Corporation | Polymerized vesicles and compounds for their preparation |
| US4608400A (en) * | 1984-07-23 | 1986-08-26 | Nippon Kayaku Kabushiki Kaisha | Novel (meth)acrylate and resin composition comprising the same |
| US4668433A (en) * | 1984-08-06 | 1987-05-26 | Givaudan Corporation | Novel derivatives of 6-hydroxyhexanoates as fragrance ingredients |
| CN103217523A (en) * | 2006-08-09 | 2013-07-24 | 住友电木株式会社 | Sugar chain-capturing substance and use thereof |
| CN103257223A (en) * | 2006-08-09 | 2013-08-21 | 住友电木株式会社 | Sugar chain-capturing substance and use thereof |
| EP2503332A3 (en) * | 2006-08-09 | 2013-11-13 | Sumitomo Bakelite Company, Ltd. | Sugar chain-capturing substance and use thereof |
| CN103217523B (en) * | 2006-08-09 | 2015-05-06 | 住友电木株式会社 | Sugar chain-capturing substance and use thereof |
| US9340651B2 (en) | 2006-08-09 | 2016-05-17 | Sumitomo Bakelite Company Limited | Sugar chain-capturing substance and use thereof |
| US9714328B2 (en) | 2006-08-09 | 2017-07-25 | Sumitomo Bakelite Company, Ltd. | Sugar chain-capturing substance and use thereof |
| US9334428B2 (en) | 2012-12-19 | 2016-05-10 | 3M Innovative Properties Company | Pressure-sensitive adhesives prepared from degradable monomers and polymers |
| JP2017110154A (en) * | 2015-12-18 | 2017-06-22 | 株式会社リコー | Active energy ray-curable composition, active energy ray-curable ink composition, active energy ray-curable inkjet ink composition, composition container, 2- or 3-dimensional image formation device, and 2- or 3-dimensional image formation method |
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