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GB1128724A - Process for producing crystalline homopolymers or copolymers of olefin - Google Patents

Process for producing crystalline homopolymers or copolymers of olefin

Info

Publication number
GB1128724A
GB1128724A GB2471067A GB2471067A GB1128724A GB 1128724 A GB1128724 A GB 1128724A GB 2471067 A GB2471067 A GB 2471067A GB 2471067 A GB2471067 A GB 2471067A GB 1128724 A GB1128724 A GB 1128724A
Authority
GB
United Kingdom
Prior art keywords
propylene
phenyl
tolyl
aliphatic residue
pentene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2471067A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Petrochemical Co Ltd
Original Assignee
Mitsubishi Petrochemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Petrochemical Co Ltd filed Critical Mitsubishi Petrochemical Co Ltd
Publication of GB1128724A publication Critical patent/GB1128724A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

Abstract

1,128,724. Polymerization catalysts for olefins. MITSUBISHI PETROCHEMICAL CO. Ltd. 26 May, 1967 [30 May, 1966; 27 March, 1967], No. 24710/67. Heading C3P. A polymerization catalyst system comprises (1) an organometallic compound of a metal of Groups I, II and III of the Periodic Table of Elements; (2) a halide of a transition metal of Groups IV, V and VI of the Periodic Table; and (3) an aromatic compound of the general formula where X, Y and Z represent hydrogen, halegon, a C1 to 5 aliphatic residue, phenyl, tolyl, alkoxy, amino, nitro, and wherein R<SP>1</SP> represents hydrogen, a C 1-8 aliphatic residue, phenyl or tolyl, and R is a group selected from -OR<SP>2</SP>, -NR<SP>3</SP>R<SP>4</SP>, and -SR<SP>5</SP> (wherein R<SP>2</SP>, R<SP>3</SP> and R<SP>4</SP> represent hydrogen, a C 1-5 aliphatic residue, phenyl or tolyl, and R<SP>5</SP> represents a C 1-8 aliphatic residue, phenyl or tolyl), and aliphatic residues containing 1 to 8 carbon atoms. Compound (3) is selected from benzoates, substituted benzoates, alkyl and alkylene phenyl ketones, aromatic amides, and aromatic thiol esters. A large number of these compounds are specified and exemplified. The catalyst is used for polymerizing mono-olefins. Specified mono-olefins are ethylene, propylene, 1-butene, 1-pentene, 4 - methyl - 1 - pentene, 1 - hexene, styrene, and mixtures e.g. propylene/ethylene, propylene/butene, propylene/styrene, and propylene/4 - methyl - 1 - pentene. The polymerization is preferably effected in a hydrocarbon diluent. The polymers are recovered by conventional techniques and the product fractionated by solvent extraction.
GB2471067A 1966-05-30 1967-05-26 Process for producing crystalline homopolymers or copolymers of olefin Expired GB1128724A (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP3489766 1966-05-30
JP1896967 1967-03-27

Publications (1)

Publication Number Publication Date
GB1128724A true GB1128724A (en) 1968-10-02

Family

ID=26355746

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2471067A Expired GB1128724A (en) 1966-05-30 1967-05-26 Process for producing crystalline homopolymers or copolymers of olefin

Country Status (2)

Country Link
DE (1) DE1745117A1 (en)
GB (1) GB1128724A (en)

Cited By (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2230672A1 (en) * 1971-06-25 1972-12-28 Montedison Spa Process for the stereoregular polymerization of alpha-olefins
US3950268A (en) 1971-11-08 1976-04-13 Standard Oil Company Catalyst for the polymerization of olefins
US4064336A (en) * 1976-11-03 1977-12-20 Chemplex Company Catalyst and method
US4071673A (en) * 1976-11-03 1978-01-31 Chemplex Company Catalyst and method
US4107414A (en) 1971-06-25 1978-08-15 Montecatini Edison S.P.A. Process for the stereoregular polymerization of alpha olefins
US4156063A (en) 1971-06-25 1979-05-22 Montecanti Edison, S.p.A. Process for the stereoregular polymerization of alpha olefins
US4194075A (en) * 1976-05-14 1980-03-18 Phillips Petroleum Company Magnesium reducing agent-hydrocarbylaluminum halide cocatalyst for titanium tetrahalide
US4194076A (en) * 1976-05-14 1980-03-18 Phillips Petroleum Company Washing magnesium reducing agent prepared in absence of complexing diluent
US4234710A (en) 1976-07-08 1980-11-18 Phillips Petroleum Company Catalyst and a polymerization process employing the catalyst
US4255281A (en) 1979-07-03 1981-03-10 Standard Oil Company (Indiana) Alpha-olefin polymerization catalyst and process
US4258161A (en) * 1978-02-14 1981-03-24 Mitsubishi Chemical Industries Ltd. Process for polymerizing propylene
US4288579A (en) * 1978-04-11 1981-09-08 Nippon Oil Company, Limited Process for preparing polyolefins
US4296222A (en) * 1976-04-13 1981-10-20 Basf Aktiengesellschaft Manufacture of poly-α-olefins
US4297465A (en) * 1980-10-29 1981-10-27 Eastman Kodak Company Catalysts for polymerizing propylene in a high temperature solution process
EP0039442A2 (en) * 1980-05-02 1981-11-11 Mitsubishi Kasei Corporation Process for producing polyolefins
US4477639A (en) * 1983-05-27 1984-10-16 Shell Oil Company Olefin polymerization catalyst component and composition and method of preparation
US4490513A (en) * 1976-09-27 1984-12-25 Mitsui Petrochemical Industries, Ltd. Process for producing polymers or copolymers of olefins containing at least three carbon atoms and catalysts therefor
US4507450A (en) * 1976-08-18 1985-03-26 Mitsubishi Chemical Industries Limited Process for preparing polyolefin
US5026889A (en) * 1979-06-20 1991-06-25 Sumitomo Chemical Company, Limited Catalyst system for olefin polymerization and method for production of olefin polymers by using the same
JP2016047916A (en) * 2010-09-30 2016-04-07 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー Polymeric compositions with voltage stabilizer additive
CN105934449A (en) * 2013-12-20 2016-09-07 沙特基础工业公司 Catalyst system for polymerization of olefin
US9926391B2 (en) 2013-12-20 2018-03-27 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
US9944734B2 (en) 2013-12-20 2018-04-17 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
US10000591B2 (en) 2013-12-20 2018-06-19 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
US10640586B2 (en) 2013-12-20 2020-05-05 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2553104A1 (en) * 1975-11-26 1977-06-08 Mitsui Petrochemical Ind Supported catalyst prodn. - by contacting titanium cpd. with solid magnesium compone

Cited By (33)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2230672A1 (en) * 1971-06-25 1972-12-28 Montedison Spa Process for the stereoregular polymerization of alpha-olefins
US4336360A (en) 1971-06-25 1982-06-22 Montecatini Edison S.P.A. Process for the stereoregular polymerization of alpha-olefins
US4107414A (en) 1971-06-25 1978-08-15 Montecatini Edison S.P.A. Process for the stereoregular polymerization of alpha olefins
US4156063A (en) 1971-06-25 1979-05-22 Montecanti Edison, S.p.A. Process for the stereoregular polymerization of alpha olefins
US3950268A (en) 1971-11-08 1976-04-13 Standard Oil Company Catalyst for the polymerization of olefins
US4296222A (en) * 1976-04-13 1981-10-20 Basf Aktiengesellschaft Manufacture of poly-α-olefins
US4194075A (en) * 1976-05-14 1980-03-18 Phillips Petroleum Company Magnesium reducing agent-hydrocarbylaluminum halide cocatalyst for titanium tetrahalide
US4194076A (en) * 1976-05-14 1980-03-18 Phillips Petroleum Company Washing magnesium reducing agent prepared in absence of complexing diluent
US4234710A (en) 1976-07-08 1980-11-18 Phillips Petroleum Company Catalyst and a polymerization process employing the catalyst
US4507450A (en) * 1976-08-18 1985-03-26 Mitsubishi Chemical Industries Limited Process for preparing polyolefin
US4490513A (en) * 1976-09-27 1984-12-25 Mitsui Petrochemical Industries, Ltd. Process for producing polymers or copolymers of olefins containing at least three carbon atoms and catalysts therefor
US4071673A (en) * 1976-11-03 1978-01-31 Chemplex Company Catalyst and method
US4064336A (en) * 1976-11-03 1977-12-20 Chemplex Company Catalyst and method
US4258161A (en) * 1978-02-14 1981-03-24 Mitsubishi Chemical Industries Ltd. Process for polymerizing propylene
US4357452A (en) * 1978-02-14 1982-11-02 Mitsubishi Chemical Industries Limited Process for polymerizing propylene
US4288579A (en) * 1978-04-11 1981-09-08 Nippon Oil Company, Limited Process for preparing polyolefins
US5026889A (en) * 1979-06-20 1991-06-25 Sumitomo Chemical Company, Limited Catalyst system for olefin polymerization and method for production of olefin polymers by using the same
US4255281A (en) 1979-07-03 1981-03-10 Standard Oil Company (Indiana) Alpha-olefin polymerization catalyst and process
EP0039442A3 (en) * 1980-05-02 1982-01-13 Mitsubishi Chemical Industries Limited Process for producing polyolefins
US4381383A (en) * 1980-05-02 1983-04-26 Mitsubishi Chemical Industries Limited Process for producing polyolefins
EP0039442A2 (en) * 1980-05-02 1981-11-11 Mitsubishi Kasei Corporation Process for producing polyolefins
US4297465A (en) * 1980-10-29 1981-10-27 Eastman Kodak Company Catalysts for polymerizing propylene in a high temperature solution process
US4477639A (en) * 1983-05-27 1984-10-16 Shell Oil Company Olefin polymerization catalyst component and composition and method of preparation
US10163545B2 (en) 2010-09-30 2018-12-25 Union Carbide Chemical & Plastics Technology Llc Polymeric compositions with voltage stabilizer additive
JP2016047916A (en) * 2010-09-30 2016-04-07 ユニオン カーバイド ケミカルズ アンド プラスティックス テクノロジー エルエルシー Polymeric compositions with voltage stabilizer additive
US10622117B2 (en) 2010-09-30 2020-04-14 Union Carbide Chemicals & Plastics Technology Llc Polymeric compositions with voltage stabilizer additive
US9926391B2 (en) 2013-12-20 2018-03-27 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
US9944734B2 (en) 2013-12-20 2018-04-17 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
US10000591B2 (en) 2013-12-20 2018-06-19 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
CN105934449B (en) * 2013-12-20 2018-07-10 沙特基础工业公司 For the carbon monoxide-olefin polymeric of olefinic polymerization
US9944731B2 (en) 2013-12-20 2018-04-17 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin
CN105934449A (en) * 2013-12-20 2016-09-07 沙特基础工业公司 Catalyst system for polymerization of olefin
US10640586B2 (en) 2013-12-20 2020-05-05 Saudi Basic Industries Corporation Catalyst system for polymerization of an olefin

Also Published As

Publication number Publication date
DE1745117A1 (en) 1970-02-19

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