GB1162665A - Cationic and Basic Benzothiazolylazo Dyes, their preparation and use - Google Patents
Cationic and Basic Benzothiazolylazo Dyes, their preparation and useInfo
- Publication number
- GB1162665A GB1162665A GB4310366A GB4310366A GB1162665A GB 1162665 A GB1162665 A GB 1162665A GB 4310366 A GB4310366 A GB 4310366A GB 4310366 A GB4310366 A GB 4310366A GB 1162665 A GB1162665 A GB 1162665A
- Authority
- GB
- United Kingdom
- Prior art keywords
- alkyl
- alkoxy
- hydroxyethyl
- dyes
- proviso
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B44/00—Azo dyes containing onium groups
- C09B44/02—Azo dyes containing onium groups containing ammonium groups not directly attached to an azo group
- C09B44/04—Azo dyes containing onium groups containing ammonium groups not directly attached to an azo group from coupling components containing amino as the only directing group
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B62/00—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves
- C09B62/44—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring
- C09B62/443—Reactive dyes, i.e. dyes which form covalent bonds with the substrates or which polymerise with themselves with the reactive group not directly attached to a heterocyclic ring the reactive group being alternatively specified
- C09B62/447—Azo dyes
- C09B62/45—Monoazo dyes
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
1,162,665. Benzthiazole dyes. E. I. DU PONT DE NEMOURS & CO. 27 Sept., 1966, No. 43103/66. Heading C4P. The invention comprises monoazo dyes of the general formula wherein A is H, CH 3 , C 1 -C 4 alkoxy, Cl, Br, NO 2 , CN, CF 3 , R-CO-, R-SO 2 -, R 1 R 2 NSO 2 - or C 1 -C 4 alkyl-O-CO- with the proviso that when B is H, CH 3 or C 1 -C 4 alkoxy, then A is Cl, Br, NO 2 , CN, CF 3 , R-CO-, R-SO 2 -, R 1 R 2 NSO 2 - or C 1 -C 4 alkyl-O-CO-, R is C 1 -C 4 alkyl, CF 3 , cyclohexyl, 2-hydroxyethyl, or phenyl optionally substituted by Cl, Br, NO 2 or C 1 -C 4 alkyl; R 1 is H, C 1 -C 4 alkyl, or 2- hydroxyethyl; R 2 is C 1 -C 4 alkyl, 2-hydroxyethyl, benzyl or phenyl; B is H, CH 3 , C 1 -C 4 alkoxy, Cl, Br, NO 2 or CN with the proviso that when A is H, CH 3 or C 1 -C 4 alkoxy then B is Cl, Br, NO 2 or CN; X is H Cl, Br, CH 3 , C 2 H 5 or C 1 -C 4 alkoxy with the proviso that when Y is NH 2 then X is Cl, Br, CH 3 , C 2 H 5 or C 1 -C 4 alkoxy; Y is NH 2 , H, Cl, Br, CH 3 , C 2 H 5 , C 1 -C 4 alkoxy, QCONH- or QSO 2 NH-, wherein Q is C 1 -C 4 alkyl, 2-hydroxyethyl, or phenyl optionally substituted by Cl, Br, NO 2 or C 1 -C 4 alkyl; R 3 is H, C 1 -C 4 alkyl, 2-hydroxyethyl, 2-cyanoethyl or C 1 -C 4 alkoxyalkyl, R 4 is C 2 -C 4 alkylene; NR 5 is #NR 6 R 7 or NR 6 R 7 R 8 Z- wherein R 6 , R 7 and R 8 are C 1 -C 4 alkyl, 2-hydroxyethyl or benzyl and Z- is an anion. They are prepared by diazotization and coupling. They are used to dye acid modified acrylic fibres in orange, red-orange, red, and bluish-red shades.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4310366A GB1162665A (en) | 1966-09-27 | 1966-09-27 | Cationic and Basic Benzothiazolylazo Dyes, their preparation and use |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
GB4310366A GB1162665A (en) | 1966-09-27 | 1966-09-27 | Cationic and Basic Benzothiazolylazo Dyes, their preparation and use |
Publications (1)
Publication Number | Publication Date |
---|---|
GB1162665A true GB1162665A (en) | 1969-08-27 |
Family
ID=10427334
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
GB4310366A Expired GB1162665A (en) | 1966-09-27 | 1966-09-27 | Cationic and Basic Benzothiazolylazo Dyes, their preparation and use |
Country Status (1)
Country | Link |
---|---|
GB (1) | GB1162665A (en) |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4233214A (en) * | 1973-02-26 | 1980-11-11 | Bayer Aktiengesellschaft | Cationic azo dyestuffs with a hydroxyalkylated ammonium group |
US4247457A (en) * | 1972-07-31 | 1981-01-27 | Sandoz Ltd. | Cationic dyes containing an aryloxy group linked through a bridging radical to a quaternized nitrogen atom |
US4432899A (en) * | 1981-01-16 | 1984-02-21 | Bayer Aktiengesellschaft | Preparing concentrated azo dye solutions using nitrite salt as both coupling component and diazotizing agent |
EP1820537A1 (en) * | 2006-02-18 | 2007-08-22 | Wella Aktiengesellschaft | Agents for coloring keratin fibers |
EP1820536A1 (en) * | 2006-02-18 | 2007-08-22 | Wella Aktiengesellschaft | Coloring agents for keratin fibers |
-
1966
- 1966-09-27 GB GB4310366A patent/GB1162665A/en not_active Expired
Cited By (13)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4247457A (en) * | 1972-07-31 | 1981-01-27 | Sandoz Ltd. | Cationic dyes containing an aryloxy group linked through a bridging radical to a quaternized nitrogen atom |
US4233214A (en) * | 1973-02-26 | 1980-11-11 | Bayer Aktiengesellschaft | Cationic azo dyestuffs with a hydroxyalkylated ammonium group |
US4432899A (en) * | 1981-01-16 | 1984-02-21 | Bayer Aktiengesellschaft | Preparing concentrated azo dye solutions using nitrite salt as both coupling component and diazotizing agent |
WO2007097930A1 (en) * | 2006-02-18 | 2007-08-30 | The Procter & Gamble Company | Agents for coloring keratin fibers |
EP1820536A1 (en) * | 2006-02-18 | 2007-08-22 | Wella Aktiengesellschaft | Coloring agents for keratin fibers |
WO2007093943A1 (en) * | 2006-02-18 | 2007-08-23 | The Procter & Gamble Company | Coloring agents for keratin fibers |
EP1820537A1 (en) * | 2006-02-18 | 2007-08-22 | Wella Aktiengesellschaft | Agents for coloring keratin fibers |
US7513917B2 (en) | 2006-02-18 | 2009-04-07 | The Procter & Gamble Company | Coloring agents for keratin fibers |
US7513916B2 (en) | 2006-02-18 | 2009-04-07 | The Procter & Gamble Company | Agents for coloring keratin fibers |
JP2009531279A (en) * | 2006-02-18 | 2009-09-03 | ザ プロクター アンド ギャンブル カンパニー | Colorant for keratin fibers |
US7658770B2 (en) | 2006-02-18 | 2010-02-09 | The Procter & Gamble Company | Agents for coloring keratin fibers |
US7658771B2 (en) | 2006-02-18 | 2010-02-09 | The Procter & Gable Company | Coloring agents for keratin fibers |
CN101384303B (en) * | 2006-02-18 | 2012-07-04 | 宝洁公司 | Coloring agent for coloring keratin fibers |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
GB1285045A (en) | Disazo dyestuffs and a process for their manufacture and use | |
GB1224413A (en) | Water-insoluble monoazo dyestuffs | |
GB1379233A (en) | Disperse monoazo dyestuffs | |
GB1162665A (en) | Cationic and Basic Benzothiazolylazo Dyes, their preparation and use | |
GB1157834A (en) | Monoazo Basic Dyes | |
GB1186753A (en) | New Basic Disazo Dyes and a process for their preparation | |
GB1361250A (en) | Azo dyes containing sulphoalkyl-hydroxy pyridone residues their manufacture and use | |
GB1516717A (en) | Disperse azo dyes | |
GB1444749A (en) | Azo dyestuffs process for their preparation and their use for dyeing synthetic fibre materials | |
GB1521122A (en) | Disperse azo dyestuffs | |
GB1294978A (en) | ||
GB1338883A (en) | Disazo dyestuffs their preparation and use | |
GB1408672A (en) | Azo-pyrazolium dyestuffs | |
GB1349112A (en) | Green-yellow monoazo acid dyes | |
GB1351375A (en) | Monoazo disperse dyes | |
GB1250115A (en) | ||
GB1326171A (en) | Monoazoy dyestuffs | |
GB1392051A (en) | Mono azo disperse dyes | |
GB1445726A (en) | Water soluble disazo dyes | |
GB1254789A (en) | Disperse disazo dyes | |
GB1319087A (en) | Compounds of the azobenzene series their production and use as disperse dyes | |
GB1332899A (en) | Monoazo disperse dyes | |
GB1231593A (en) | ||
GB1522737A (en) | Monoazo dyes based on 4-hydroxphenylpropionic acids particularly suitet to the levelled dyeing of synthetic polymide fibres | |
GB1405799A (en) | Disperse mono- and dis-azy dyestuffs their manufacture and use |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PS | Patent sealed | ||
PLNP | Patent lapsed through nonpayment of renewal fees |