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GB1092884A - Copolymers - Google Patents

Copolymers

Info

Publication number
GB1092884A
GB1092884A GB23/65A GB2365A GB1092884A GB 1092884 A GB1092884 A GB 1092884A GB 23/65 A GB23/65 A GB 23/65A GB 2365 A GB2365 A GB 2365A GB 1092884 A GB1092884 A GB 1092884A
Authority
GB
United Kingdom
Prior art keywords
copolymers
methacrylate
trimethyl
vinyl
methacrylic acid
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB23/65A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Eastman Kodak Co
Original Assignee
Eastman Kodak Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Eastman Kodak Co filed Critical Eastman Kodak Co
Publication of GB1092884A publication Critical patent/GB1092884A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/20—Esters of polyhydric alcohols or phenols, e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Abstract

Novel copolymers are derived from 2,2,4-trimethyl - 3 - hydroxypentyl methacrylate as essential component. The methacrylate is copolymerized with one or more other monomers such as styrene and its halogen and alkyl derivatives, vinylnaphthalene and halogen derivatives thereof, acrylonitrile, methacrylonitrile, vinyl esters, vinyl ethers, olefins, dienes, alkyl maleates and fumarates, vinyl and vinylidene halides, and aliphatic, alicyclic, aromatic and heterocyclic esters of acrylic or methacrylic acid. The copolymers may be obtained by dispersion, emulsion or solution polymerization methods using catalysts such as benzoyl, acetyl or hydrogen peroxide, cumene hydroperoxide, sodium, potassium or ammonium persulphate, possibly in a redox system, in some cases in the presence of dodecyl mercaptan. The copolymers are generally thermosetting and form hard films, for which purpose they may be admixed with, for example, melamine-formaldehyde resins.ALSO:2,2,4 - Trimethyl - 3 - hydroxypentyl methacrylate may be prepared by heating 2,2,4-trimethyl - 1,3 - pentanediol with methyl methacrylate in the presence of acidic or basic catalysts, e.g. sodium methoxide, optionally at reduced pressure and/or in the presence of excess methyl methacrylate or of an inert diluent, or by esterifying the aforementioned diol with methacrylic acid using an acidic catalyst. In either method an inhibitor such as hydroquinone is added to prevent polymerization. An example of the former method is given, the monomethacrylate ester being separated from dimethacrylate formed by distillation.
GB23/65A 1964-01-03 1965-01-01 Copolymers Expired GB1092884A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US33566864A 1964-01-03 1964-01-03

Publications (1)

Publication Number Publication Date
GB1092884A true GB1092884A (en) 1967-11-29

Family

ID=23312766

Family Applications (1)

Application Number Title Priority Date Filing Date
GB23/65A Expired GB1092884A (en) 1964-01-03 1965-01-01 Copolymers

Country Status (2)

Country Link
FR (1) FR1432588A (en)
GB (1) GB1092884A (en)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5290602A (en) * 1992-10-19 1994-03-01 Union Carbide Chemicals & Plastics Technology Corporation Hindered-hydroxyl functional (meth) acrylate-containing copolymers particularly suitable for use in coating compositions which are sprayed with compressed fluids as viscosity reducing diluents
EP0594109A1 (en) * 1992-10-19 1994-04-27 Union Carbide Chemicals & Plastics Technology Corporation Hindered-hydroxyl functional (meth)acrylate esters, copolymers containing them and compositions including same
EP0646047A1 (en) * 1991-04-19 1995-04-05 Basf Corporation Etch-resistant coating
US5420341A (en) * 1992-10-19 1995-05-30 Union Carbide Chemicals & Plastics Hindered-hydroxyl functional (meth)acrylate compounds and processes for the preparation thereof
US5442023A (en) * 1994-06-30 1995-08-15 Union Carbide Chemicals & Plastics Technology Corporation Hindered-hydroxyl functional (meth)acrylate monomers containing di(meth)acrylates and compositions including same
WO2003000434A1 (en) * 2001-06-21 2003-01-03 Basf Corporation Basecoat composition comprising a poly(meth)acrylate binder
WO2003027198A1 (en) * 2001-09-27 2003-04-03 Basf Corporation Acryl clearcoat refinish composition

Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0646047A1 (en) * 1991-04-19 1995-04-05 Basf Corporation Etch-resistant coating
EP0646047A4 (en) * 1991-04-19 1995-05-17 Basf Corp Etch-resistant coating.
US5290602A (en) * 1992-10-19 1994-03-01 Union Carbide Chemicals & Plastics Technology Corporation Hindered-hydroxyl functional (meth) acrylate-containing copolymers particularly suitable for use in coating compositions which are sprayed with compressed fluids as viscosity reducing diluents
EP0594109A1 (en) * 1992-10-19 1994-04-27 Union Carbide Chemicals & Plastics Technology Corporation Hindered-hydroxyl functional (meth)acrylate esters, copolymers containing them and compositions including same
JPH06199953A (en) * 1992-10-19 1994-07-19 Union Carbide Chem & Plast Technol Corp Copolymer containing hindered-hydroxyl-functional (meth)acrylate and composition containing same
US5420341A (en) * 1992-10-19 1995-05-30 Union Carbide Chemicals & Plastics Hindered-hydroxyl functional (meth)acrylate compounds and processes for the preparation thereof
US5442023A (en) * 1994-06-30 1995-08-15 Union Carbide Chemicals & Plastics Technology Corporation Hindered-hydroxyl functional (meth)acrylate monomers containing di(meth)acrylates and compositions including same
WO2003000434A1 (en) * 2001-06-21 2003-01-03 Basf Corporation Basecoat composition comprising a poly(meth)acrylate binder
US6794442B2 (en) 2001-06-21 2004-09-21 Basf Corporation Fast drying basecoat refinish composition
WO2003027198A1 (en) * 2001-09-27 2003-04-03 Basf Corporation Acryl clearcoat refinish composition
US7446149B2 (en) 2001-09-27 2008-11-04 Basf Corporation Fast drying clearcoat refinish composition

Also Published As

Publication number Publication date
FR1432588A (en) 1966-03-25

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