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GB1049046A - Synthesis of olefins - Google Patents

Synthesis of olefins

Info

Publication number
GB1049046A
GB1049046A GB2371464A GB2371464A GB1049046A GB 1049046 A GB1049046 A GB 1049046A GB 2371464 A GB2371464 A GB 2371464A GB 2371464 A GB2371464 A GB 2371464A GB 1049046 A GB1049046 A GB 1049046A
Authority
GB
United Kingdom
Prior art keywords
benzene
methyl
carbon
beta
pentene
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
GB2371464A
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Goodyear Tire and Rubber Co
Original Assignee
Goodyear Tire and Rubber Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Goodyear Tire and Rubber Co filed Critical Goodyear Tire and Rubber Co
Priority to GB2371464A priority Critical patent/GB1049046A/en
Publication of GB1049046A publication Critical patent/GB1049046A/en
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C4/00—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
    • C07C4/02—Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms by cracking a single hydrocarbon or a mixture of individually defined hydrocarbons or a normally gaseous hydrocarbon fraction
    • C07C4/04—Thermal processes

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Thermal Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

A process for cracking at least one paraffin containing at least 2 and not more than 15 carbon atoms, conducted in the presence of at least one homogeneous initiator which is an olefinic hydrocarbon having in the molecule a carbon to carbon single bond in a position beta to the double bond or an alkyl-substituted aromatic hydrocarbon having in the molecule a carbon to carbon single bond in a position beta to the aromatic ring, said beta position being between the alpha and beta carbon atoms away from the double bond or aromatic nucleus, the cracking operation being conducted under conditions such that said single bond is cleaved, to generate a free methyl or ethyl radical serving as initiator for the cracking process, said paraffin cracking process producing lower molecular weight hydrocarbons. The paraffin is preferably ethane, propane, n or iso-butane or n or iso-pentane and homogeneous initiators include 1-butene; 2-pentene; 4-methyl-2-pentene; 2-methyl - 2 - pentene 3 - methyl - 2 pentane ethyl-benzene; cumene; o, m and p-cymene; diisopropyl benzene; diethyl benzene; methyl-ethyl benzene; n-propyl benzene, n-propyl-toluene, sec.-butyl benzene and di-n-propyl benzene; other initiators are also specified. In a preferred process, propane is cracked to produce ethylene and propylene is presence of an initiator and steam in amounts varying from 5:1 to 2:1 moles of steam per mole of propane, at 600 DEG to 1000 DEG C. for a time of 0.005 to 0.5 seconds.
GB2371464A 1964-06-08 1964-06-08 Synthesis of olefins Expired GB1049046A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
GB2371464A GB1049046A (en) 1964-06-08 1964-06-08 Synthesis of olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
GB2371464A GB1049046A (en) 1964-06-08 1964-06-08 Synthesis of olefins

Publications (1)

Publication Number Publication Date
GB1049046A true GB1049046A (en) 1966-11-23

Family

ID=10200116

Family Applications (1)

Application Number Title Priority Date Filing Date
GB2371464A Expired GB1049046A (en) 1964-06-08 1964-06-08 Synthesis of olefins

Country Status (1)

Country Link
GB (1) GB1049046A (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3396208A (en) * 1966-09-16 1968-08-06 Mobil Oil Corp High temperature methylation of olefins
DE2140294A1 (en) * 1970-08-11 1972-02-17 Übe Industries Ltd , Übe, Yamaguchi (Japan) Process and apparatus for the manufacture of olefins from saturated coals hydrogen
WO1984001310A1 (en) * 1982-09-30 1984-04-12 Stone & Webster Eng Corp Process and apparatus for the production of olefins from both heavy and light hydrocarbons
JPS59501953A (en) * 1982-09-30 1984-11-22 スト−ン・アンド・ウェブスタ−・エンジニアリング・コ−ポレ−ション Olefin production method and equipment from both heavy and light hydrocarbons
US4906442A (en) * 1982-09-30 1990-03-06 Stone & Webster Engineering Corporation Process and apparatus for the production of olefins from both heavy and light hydrocarbons
BE1022626B1 (en) * 2012-10-29 2016-06-20 China Petroleum & Chemical Corporation STEAM CRACKAGE PROCESS

Cited By (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3396208A (en) * 1966-09-16 1968-08-06 Mobil Oil Corp High temperature methylation of olefins
DE2140294A1 (en) * 1970-08-11 1972-02-17 Übe Industries Ltd , Übe, Yamaguchi (Japan) Process and apparatus for the manufacture of olefins from saturated coals hydrogen
WO1984001310A1 (en) * 1982-09-30 1984-04-12 Stone & Webster Eng Corp Process and apparatus for the production of olefins from both heavy and light hydrocarbons
JPS59501953A (en) * 1982-09-30 1984-11-22 スト−ン・アンド・ウェブスタ−・エンジニアリング・コ−ポレ−ション Olefin production method and equipment from both heavy and light hydrocarbons
US4492624A (en) * 1982-09-30 1985-01-08 Stone & Webster Engineering Corp. Duocracking process for the production of olefins from both heavy and light hydrocarbons
US4906442A (en) * 1982-09-30 1990-03-06 Stone & Webster Engineering Corporation Process and apparatus for the production of olefins from both heavy and light hydrocarbons
JPS6360078B2 (en) * 1983-09-27 1988-11-22
BE1022626B1 (en) * 2012-10-29 2016-06-20 China Petroleum & Chemical Corporation STEAM CRACKAGE PROCESS
US9505677B2 (en) 2012-10-29 2016-11-29 China Petroleum & Chemical Corporation Steam cracking processes

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