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FR3057867B1 - Preparation d'emulsion polymerique - Google Patents

Preparation d'emulsion polymerique Download PDF

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Publication number
FR3057867B1
FR3057867B1 FR1660345A FR1660345A FR3057867B1 FR 3057867 B1 FR3057867 B1 FR 3057867B1 FR 1660345 A FR1660345 A FR 1660345A FR 1660345 A FR1660345 A FR 1660345A FR 3057867 B1 FR3057867 B1 FR 3057867B1
Authority
FR
France
Prior art keywords
preparation
polymeric emulsion
relates
monomer
emulsion
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR1660345A
Other languages
English (en)
Other versions
FR3057867A1 (fr
Inventor
Clementine CHAMPAGNE
Jean-Marc Suau
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Coatex SAS
Original Assignee
Coatex SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1660345A priority Critical patent/FR3057867B1/fr
Application filed by Coatex SAS filed Critical Coatex SAS
Priority to PCT/FR2017/052883 priority patent/WO2018078247A1/fr
Priority to KR1020197015012A priority patent/KR20190076002A/ko
Priority to MX2019004719A priority patent/MX2019004719A/es
Priority to US16/340,849 priority patent/US20190264019A1/en
Priority to EP17794391.7A priority patent/EP3532508A1/fr
Priority to BR112019006297A priority patent/BR112019006297A2/pt
Priority to CN201780065824.9A priority patent/CN109863177A/zh
Publication of FR3057867A1 publication Critical patent/FR3057867A1/fr
Application granted granted Critical
Publication of FR3057867B1 publication Critical patent/FR3057867B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/22—Emulsion polymerisation
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2/00—Processes of polymerisation
    • C08F2/12—Polymerisation in non-solvents
    • C08F2/16—Aqueous medium
    • C08F2/20—Aqueous medium with the aid of macromolecular dispersing agents
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
    • C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/02—Homopolymers or copolymers of acids; Metal or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/52—Aqueous emulsion or latex, e.g. containing polymers of a glass transition temperature (Tg) below 20°C

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Polymerisation Methods In General (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

L'invention concerne un procédé de préparation dans l'eau d'un polymère comprenant la préparation d'une émulsion comprenant un copolymère de type HASE et un mélange d'un monomère comprenant au moins une insaturation oléfinique polymérisable et d'un composé générateur de radicaux, puis la polymérisation du monomère émulsionné par chauffage à une température supérieure à la température requise pour la réaction de polymérisation. L'invention concerne également le polymère préparé ainsi que son utilisation.
FR1660345A 2016-10-25 2016-10-25 Preparation d'emulsion polymerique Expired - Fee Related FR3057867B1 (fr)

Priority Applications (8)

Application Number Priority Date Filing Date Title
FR1660345A FR3057867B1 (fr) 2016-10-25 2016-10-25 Preparation d'emulsion polymerique
KR1020197015012A KR20190076002A (ko) 2016-10-25 2017-10-20 중합체 에멀젼의 제조
MX2019004719A MX2019004719A (es) 2016-10-25 2017-10-20 Produccion de una emulsion polimerica.
US16/340,849 US20190264019A1 (en) 2016-10-25 2017-10-20 Production of a polymer emulsion
PCT/FR2017/052883 WO2018078247A1 (fr) 2016-10-25 2017-10-20 Préparation d'émulsion polymérique
EP17794391.7A EP3532508A1 (fr) 2016-10-25 2017-10-20 Préparation d'émulsion polymérique
BR112019006297A BR112019006297A2 (pt) 2016-10-25 2017-10-20 método para a preparação em água de um polímero (p1), polímero (p1) capaz de ser preparado e compósito
CN201780065824.9A CN109863177A (zh) 2016-10-25 2017-10-20 聚合物乳液的生产

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1660345A FR3057867B1 (fr) 2016-10-25 2016-10-25 Preparation d'emulsion polymerique
FR1660345 2016-10-25

Publications (2)

Publication Number Publication Date
FR3057867A1 FR3057867A1 (fr) 2018-04-27
FR3057867B1 true FR3057867B1 (fr) 2018-11-02

Family

ID=57583340

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1660345A Expired - Fee Related FR3057867B1 (fr) 2016-10-25 2016-10-25 Preparation d'emulsion polymerique

Country Status (8)

Country Link
US (1) US20190264019A1 (fr)
EP (1) EP3532508A1 (fr)
KR (1) KR20190076002A (fr)
CN (1) CN109863177A (fr)
BR (1) BR112019006297A2 (fr)
FR (1) FR3057867B1 (fr)
MX (1) MX2019004719A (fr)
WO (1) WO2018078247A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3104594B1 (fr) * 2019-12-16 2022-06-24 Coatex Sas Composition aqueuse thermo-stabilisée

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
MX200986B (en) * 1997-07-29 2001-03-07 Rohm & Haas Solubilized hydrophobically-modified alkali-soluble emulsion polymers
US20040151886A1 (en) * 2000-03-06 2004-08-05 Bobsein Barrett Richard Binder composition
EP1428867B1 (fr) * 2002-12-09 2007-08-01 Rohm And Haas Company Compositions de polymère fabriqué en plusieurs étapes à effet déclenché
JP5122215B2 (ja) * 2006-08-31 2013-01-16 ローム アンド ハース カンパニー 調整された粘度を有する水性両親媒性コポリマーエマルジョンおよびその製造方法
EP2113004B1 (fr) * 2007-02-22 2014-12-17 DSM IP Assets B.V. Compositions aqueuses durcissables par radiation pour revêtements à faible brillance
JP2009001776A (ja) * 2007-06-11 2009-01-08 Rohm & Haas Co 水性エマルジョンポリマー会合性増粘剤
FR2956862B1 (fr) * 2010-02-26 2013-03-15 Coatex Sas Monomere associatif a base d'alcools oxo, polymere acrylique contenant ce monomere, utilisation dudit polymere comme epaississant dans une formulation aqueuse, formulation obtenue.
WO2015143050A1 (fr) * 2014-03-18 2015-09-24 Rhodia Operations Tensioactifs et additifs trisubstitués contenant des aromatiques et procédés d'utilisation associés

Also Published As

Publication number Publication date
MX2019004719A (es) 2019-08-05
EP3532508A1 (fr) 2019-09-04
KR20190076002A (ko) 2019-07-01
BR112019006297A2 (pt) 2019-07-02
CN109863177A (zh) 2019-06-07
US20190264019A1 (en) 2019-08-29
FR3057867A1 (fr) 2018-04-27
WO2018078247A1 (fr) 2018-05-03

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