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FR2931708B1 - Catalyseur a base d'un materiau cristallise a porosite hierarchisee et organisee et son utilisation en oligomerisation des olefines legeres - Google Patents

Catalyseur a base d'un materiau cristallise a porosite hierarchisee et organisee et son utilisation en oligomerisation des olefines legeres

Info

Publication number
FR2931708B1
FR2931708B1 FR0802951A FR0802951A FR2931708B1 FR 2931708 B1 FR2931708 B1 FR 2931708B1 FR 0802951 A FR0802951 A FR 0802951A FR 0802951 A FR0802951 A FR 0802951A FR 2931708 B1 FR2931708 B1 FR 2931708B1
Authority
FR
France
Prior art keywords
hierarchised
oligomerization
catalyst based
light olefins
crystallized material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0802951A
Other languages
English (en)
Other versions
FR2931708A1 (fr
Inventor
Amandine Cabiac
Alexandra Chaumonnot
Laurent Simon
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
IFP Energies Nouvelles IFPEN
Original Assignee
IFP Energies Nouvelles IFPEN
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN
Priority to FR0802951A priority Critical patent/FR2931708B1/fr
Priority to PCT/FR2009/000501 priority patent/WO2009153421A1/fr
Priority to US12/994,194 priority patent/US8785707B2/en
Publication of FR2931708A1 publication Critical patent/FR2931708A1/fr
Application granted granted Critical
Publication of FR2931708B1 publication Critical patent/FR2931708B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/12—Catalytic processes with crystalline alumino-silicates or with catalysts comprising molecular sieves
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/041—Mesoporous materials having base exchange properties, e.g. Si/Al-MCM-41
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11, as exemplified by patent documents US3702886, GB1334243 and US3709979, respectively
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J29/00—Catalysts comprising molecular sieves
    • B01J29/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites
    • B01J29/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • B01J29/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
    • B01J29/7007—Zeolite Beta
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/40—Catalysts, in general, characterised by their form or physical properties characterised by dimensions, e.g. grain size
    • B01J35/45—Nanoparticles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • B01J37/0027—Powdering
    • B01J37/0045—Drying a slurry, e.g. spray drying
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G50/00—Production of liquid hydrocarbon mixtures from lower carbon number hydrocarbons, e.g. by oligomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2229/00—Aspects of molecular sieve catalysts not covered by B01J29/00
    • B01J2229/30—After treatment, characterised by the means used
    • B01J2229/42—Addition of matrix or binder particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/0009—Use of binding agents; Moulding; Pressing; Powdering; Granulating; Addition of materials ameliorating the mechanical properties of the product catalyst
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/40—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2529/00—Catalysts comprising molecular sieves
    • C07C2529/04—Catalysts comprising molecular sieves having base-exchange properties, e.g. crystalline zeolites, pillared clays
    • C07C2529/06—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
    • C07C2529/70—Crystalline aluminosilicate zeolites; Isomorphous compounds thereof of types characterised by their specific structure not provided for in groups C07C2529/08 - C07C2529/65

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Dispersion Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Catalysts (AREA)
FR0802951A 2008-05-28 2008-05-28 Catalyseur a base d'un materiau cristallise a porosite hierarchisee et organisee et son utilisation en oligomerisation des olefines legeres Expired - Fee Related FR2931708B1 (fr)

Priority Applications (3)

Application Number Priority Date Filing Date Title
FR0802951A FR2931708B1 (fr) 2008-05-28 2008-05-28 Catalyseur a base d'un materiau cristallise a porosite hierarchisee et organisee et son utilisation en oligomerisation des olefines legeres
PCT/FR2009/000501 WO2009153421A1 (fr) 2008-05-28 2009-04-28 Catalyseur a base d1un materiau cristallise à porosité hiérarchisée et organisee et son utilisation en oligomerisat1on des olefines legeres
US12/994,194 US8785707B2 (en) 2008-05-28 2009-04-28 Catalyst based on a crystallized material with hierarchized and organized porosity and its use in oligomerization of light olefins

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0802951A FR2931708B1 (fr) 2008-05-28 2008-05-28 Catalyseur a base d'un materiau cristallise a porosite hierarchisee et organisee et son utilisation en oligomerisation des olefines legeres

Publications (2)

Publication Number Publication Date
FR2931708A1 FR2931708A1 (fr) 2009-12-04
FR2931708B1 true FR2931708B1 (fr) 2014-03-14

Family

ID=40377238

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0802951A Expired - Fee Related FR2931708B1 (fr) 2008-05-28 2008-05-28 Catalyseur a base d'un materiau cristallise a porosite hierarchisee et organisee et son utilisation en oligomerisation des olefines legeres

Country Status (3)

Country Link
US (1) US8785707B2 (fr)
FR (1) FR2931708B1 (fr)
WO (1) WO2009153421A1 (fr)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2958297B1 (fr) * 2010-03-30 2013-11-29 Total Raffinage Marketing Procede de valorisation d'essence
WO2012033562A1 (fr) * 2010-09-07 2012-03-15 Exxonmobil Chemical Patents Inc. Extrudats comprenant des catalyseurs zéolites et leur utilisation dans des procédés d'oligomérisation
SG11201400308SA (en) * 2011-10-31 2014-03-28 Exxonmobil Chem Patents Inc Olefin oligomerization process
CN102515195B (zh) * 2011-11-21 2013-05-22 浙江大学 一步法合成整体型多级孔道分子筛的方法
WO2013123297A2 (fr) 2012-02-17 2013-08-22 Kior, Inc. Composition de catalyseur ayant une accessibilité accrue de site actif en volume pour la thermoconversion catalytique de biomasse en carburants liquides et produits chimiques et pour la valorisation de biohuiles
US9732285B2 (en) 2013-12-17 2017-08-15 Uop Llc Process for oligomerization of gasoline to make diesel
US9670425B2 (en) 2013-12-17 2017-06-06 Uop Llc Process for oligomerizing and cracking to make propylene and aromatics
KR101679515B1 (ko) * 2015-02-12 2016-11-24 주식회사 엘지화학 올리고머화 촉매계의 제조방법 및 이에 의해 제조된 올리고머화 촉매계
RU2722157C1 (ru) 2015-07-22 2020-05-27 Басф Корпорейшн Катализаторы с высокой геометрической площадью поверхности для получения винилацетатного мономера
KR101818180B1 (ko) * 2016-05-13 2018-02-21 한국화학연구원 에틸렌 올리고머화 방법
RU2635110C1 (ru) * 2016-09-16 2017-11-09 Публичное акционерное общество "Нефтяная компания "Роснефть" Способ получения бензиновых фракций из олефинсодержащих газов
JP2019195803A (ja) * 2018-03-14 2019-11-14 エボニック デグサ ゲーエムベーハーＥｖｏｎｉｋ Ｄｅｇｕｓｓａ ＧｍｂＨ 沈殿による長期安定性の構造選択的オリゴマー化触媒の調製方法
FR3084267B1 (fr) * 2018-07-25 2021-10-08 Axens Alumine a acidite et structure de porosite optimales

Family Cites Families (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5134243A (en) * 1991-06-21 1992-07-28 Mobil Oil Corporation Catalytic oligomerization process using synthetic mesoporous crystalline material
US5849258A (en) * 1996-06-06 1998-12-15 Intevep, S.A. Material with microporous crystalline walls defining a narrow size distribution of mesopores, and process for preparing same
DE19939416A1 (de) * 1999-08-20 2001-02-22 Basf Ag Verfahren zur Herstellung eines kristallinen, zeolithischen Feststoffs
FR2800300B1 (fr) * 1999-11-02 2002-12-20 Rhodia Chimie Sa Materiau mesostructure integrant des particules de dimension nanometrique
CA2392296C (fr) * 1999-11-23 2008-03-11 Universite Laval Materiau zeolitique mesoporeux ayant des parois de mesopore cristallines microporeuses
FR2802120B1 (fr) * 1999-12-14 2002-02-01 Inst Francais Du Petrole Solide silicoaluminate micro et mesoporeux, procede de preparation, utilisation comme catalyseur et en conversion d'hydrocarbures
US20050063901A1 (en) * 2003-09-24 2005-03-24 Miller Stephen J. Preparation of molecular sieves involving spray drying
US7589041B2 (en) * 2004-04-23 2009-09-15 Massachusetts Institute Of Technology Mesostructured zeolitic materials, and methods of making and using the same
FR2872152B1 (fr) 2004-06-24 2006-08-11 Inst Francais Du Petrole Materiau a porosite hierarchisee comprenant du silicium
FR2872151B1 (fr) * 2004-06-24 2007-06-29 Inst Francais Du Petrole Materiau aluminosilicate mesostructure
FR2886637B1 (fr) * 2005-06-02 2007-08-03 Inst Francais Du Petrole Materiau mesostructure a forte teneur en aluminium

Also Published As

Publication number Publication date
FR2931708A1 (fr) 2009-12-04
WO2009153421A1 (fr) 2009-12-23
US20110172482A1 (en) 2011-07-14
US8785707B2 (en) 2014-07-22

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Effective date: 20160129