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FR2734823B1 - NOVEL OPTICALLY ACTIVE METAL COMPLEXES AND THEIR USE IN ASYMMETRICAL CATALYSIS - Google Patents

NOVEL OPTICALLY ACTIVE METAL COMPLEXES AND THEIR USE IN ASYMMETRICAL CATALYSIS

Info

Publication number
FR2734823B1
FR2734823B1 FR9506286A FR9506286A FR2734823B1 FR 2734823 B1 FR2734823 B1 FR 2734823B1 FR 9506286 A FR9506286 A FR 9506286A FR 9506286 A FR9506286 A FR 9506286A FR 2734823 B1 FR2734823 B1 FR 2734823B1
Authority
FR
France
Prior art keywords
optically active
metal complexes
active metal
novel optically
asymmetrical
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR9506286A
Other languages
French (fr)
Other versions
FR2734823A1 (en
Inventor
Francois Mathey
Frederic Robin
Francois Mercier
Michel Spagnol
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Chimie SAS
Original Assignee
Rhone Poulenc Chimie SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR9506286A priority Critical patent/FR2734823B1/en
Application filed by Rhone Poulenc Chimie SA filed Critical Rhone Poulenc Chimie SA
Priority to PT95943260T priority patent/PT748326E/en
Priority to PCT/FR1995/001716 priority patent/WO1996020202A1/en
Priority to US08/696,824 priority patent/US5783738A/en
Priority to ES95943260T priority patent/ES2158147T3/en
Priority to DE69521605T priority patent/DE69521605T2/en
Priority to AT95943260T priority patent/ATE202783T1/en
Priority to DK95943260T priority patent/DK0748326T3/en
Priority to JP8520253A priority patent/JPH09510233A/en
Priority to EP95943260A priority patent/EP0748326B1/en
Priority to AU44513/96A priority patent/AU4451396A/en
Publication of FR2734823A1 publication Critical patent/FR2734823A1/en
Application granted granted Critical
Publication of FR2734823B1 publication Critical patent/FR2734823B1/en
Priority to US09/025,441 priority patent/US6037493A/en
Priority to US09/498,466 priority patent/US6380412B1/en
Priority to US10/076,560 priority patent/US6683208B2/en
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0033—Iridium compounds
    • C07F15/004—Iridium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B53/00—Asymmetric syntheses
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C51/00—Preparation of carboxylic acids or their salts, halides or anhydrides
    • C07C51/347—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups
    • C07C51/36—Preparation of carboxylic acids or their salts, halides or anhydrides by reactions not involving formation of carboxyl groups by hydrogenation of carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0046—Ruthenium compounds
    • C07F15/0053—Ruthenium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/006—Palladium compounds
    • C07F15/0066—Palladium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0073—Rhodium compounds
    • C07F15/008—Rhodium compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
    • C07F15/0006—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table compounds of the platinum group
    • C07F15/0086—Platinum compounds
    • C07F15/0093—Platinum compounds without a metal-carbon linkage
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
    • C07F9/00—Compounds containing elements of Groups 5 or 15 of the Periodic Table
    • C07F9/02—Phosphorus compounds
    • C07F9/547—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom
    • C07F9/6564—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms
    • C07F9/6568—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms
    • C07F9/65683—Heterocyclic compounds, e.g. containing phosphorus as a ring hetero atom having phosphorus atoms, with or without nitrogen, oxygen, sulfur, selenium or tellurium atoms, as ring hetero atoms having phosphorus atoms as the only ring hetero atoms the ring phosphorus atom being part of a phosphine

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Biochemistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Molecular Biology (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
FR9506286A 1994-12-28 1995-05-29 NOVEL OPTICALLY ACTIVE METAL COMPLEXES AND THEIR USE IN ASYMMETRICAL CATALYSIS Expired - Fee Related FR2734823B1 (en)

Priority Applications (14)

Application Number Priority Date Filing Date Title
FR9506286A FR2734823B1 (en) 1995-05-29 1995-05-29 NOVEL OPTICALLY ACTIVE METAL COMPLEXES AND THEIR USE IN ASYMMETRICAL CATALYSIS
AU44513/96A AU4451396A (en) 1994-12-28 1995-12-22 Optically active diphosphines and method for preparing same by resolution of the racemic mixture
US08/696,824 US5783738A (en) 1994-12-28 1995-12-22 Optically active diphosphines, preparation thereof according to a process for the resolution of the racemic mixture and use thereof
ES95943260T ES2158147T3 (en) 1994-12-28 1995-12-22 OPTICALLY ACTIVE DYPHOSPHINES, AND THEIR PREPARATION FOR DEVELOPMENT OF RACEMIC BLENDS.
DE69521605T DE69521605T2 (en) 1994-12-28 1995-12-22 OPTICALLY ACTIVE DIPHOSPHINS AND PRODUCTION METHOD BY SEPARATING THE RACEMAT MIXTURE
AT95943260T ATE202783T1 (en) 1994-12-28 1995-12-22 OPTICALLY ACTIVE DIPHOSPHINS AND PRODUCTION PROCESS BY SEPARATION OF THE RACEMAT MIXTURE
DK95943260T DK0748326T3 (en) 1994-12-28 1995-12-22 Optically active diphosphines and their preparation by cleavage of the racemic mixture
JP8520253A JPH09510233A (en) 1994-12-28 1995-12-22 Production of optically active diphosphine, said diphosphine by a method of resolving a racemic mixture, and use of said diphosphine
PT95943260T PT748326E (en) 1994-12-28 1995-12-22 OPTICALLY ACTIVE DIFFOSPHINS AND PROCESS FOR THEIR PREPARATION BY LAYING THE RACEMIC MIX
PCT/FR1995/001716 WO1996020202A1 (en) 1994-12-28 1995-12-22 Optically active diphosphines and method for preparing same by resolution of the racemic mixture
EP95943260A EP0748326B1 (en) 1994-12-28 1995-12-22 Optically active diphosphines and method for preparing same by resolution of the racemic mixture
US09/025,441 US6037493A (en) 1994-12-28 1998-02-17 Optically active diphosphines, preparation thereof according to a process for the resolution of the racemic mixture and use thereof
US09/498,466 US6380412B1 (en) 1994-12-28 2000-02-04 Optically active diphosphines, preparation thereof according to a process for the resolution of the racemic mixture and use thereof
US10/076,560 US6683208B2 (en) 1994-12-28 2002-02-19 Optically active diphosphines, preparation thereof according to a process for the resolution of the racemic mixture and use thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR9506286A FR2734823B1 (en) 1995-05-29 1995-05-29 NOVEL OPTICALLY ACTIVE METAL COMPLEXES AND THEIR USE IN ASYMMETRICAL CATALYSIS

Publications (2)

Publication Number Publication Date
FR2734823A1 FR2734823A1 (en) 1996-12-06
FR2734823B1 true FR2734823B1 (en) 1997-07-18

Family

ID=9479411

Family Applications (1)

Application Number Title Priority Date Filing Date
FR9506286A Expired - Fee Related FR2734823B1 (en) 1994-12-28 1995-05-29 NOVEL OPTICALLY ACTIVE METAL COMPLEXES AND THEIR USE IN ASYMMETRICAL CATALYSIS

Country Status (1)

Country Link
FR (1) FR2734823B1 (en)

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5202474A (en) * 1989-06-22 1993-04-13 Monsanto Company Asymmetric catalytic hydrogenation of α-arylpropenoic acids
EP0530015A1 (en) * 1991-08-30 1993-03-03 MITSUI TOATSU CHEMICALS, Inc. Optically active diphosphines, intermediates thereof, and processes for production thereof

Also Published As

Publication number Publication date
FR2734823A1 (en) 1996-12-06

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Legal Events

Date Code Title Description
ST Notification of lapse