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FR2324980A1 - Storing hydrogen in magnesium and other hydridable metal(s) - used as source for motive power; releasing hydrogen at near ambient temp. - Google Patents

Storing hydrogen in magnesium and other hydridable metal(s) - used as source for motive power; releasing hydrogen at near ambient temp.

Info

Publication number
FR2324980A1
FR2324980A1 FR7528646A FR7528646A FR2324980A1 FR 2324980 A1 FR2324980 A1 FR 2324980A1 FR 7528646 A FR7528646 A FR 7528646A FR 7528646 A FR7528646 A FR 7528646A FR 2324980 A1 FR2324980 A1 FR 2324980A1
Authority
FR
France
Prior art keywords
hydrogen
source
magnesium
metal
motive power
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR7528646A
Other languages
French (fr)
Other versions
FR2324980B1 (en
Inventor
Bernard Tanguy
Jean-Louis Soubeyroux
Michel Pezat
Josick Portier
Paul Hagenmuller
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bpifrance Financement SA
Original Assignee
Agence National de Valorisation de la Recherche ANVAR
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Agence National de Valorisation de la Recherche ANVAR filed Critical Agence National de Valorisation de la Recherche ANVAR
Priority to FR7528646A priority Critical patent/FR2324980A1/en
Publication of FR2324980A1 publication Critical patent/FR2324980A1/en
Application granted granted Critical
Publication of FR2324980B1 publication Critical patent/FR2324980B1/fr
Granted legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • C01B3/001—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes characterised by the uptaking medium; Treatment thereof
    • C01B3/0078—Composite solid storage mediums, i.e. coherent or loose mixtures of different solid constituents, chemically or structurally heterogeneous solid masses, coated solids or solids having a chemically modified surface region
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/0005—Reversible uptake of hydrogen by an appropriate medium, i.e. based on physical or chemical sorption phenomena or on reversible chemical reactions, e.g. for hydrogen storage purposes ; Reversible gettering of hydrogen; Reversible uptake of hydrogen by electrodes
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02B—INTERNAL-COMBUSTION PISTON ENGINES; COMBUSTION ENGINES IN GENERAL
    • F02B43/00—Engines characterised by operating on gaseous fuels; Plants including such engines
    • F02B43/10—Engines or plants characterised by use of other specific gases, e.g. acetylene, oxyhydrogen
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M21/00—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
    • F02M21/02—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
    • F02M21/0203—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels characterised by the type of gaseous fuel
    • F02M21/0206—Non-hydrocarbon fuels, e.g. hydrogen, ammonia or carbon monoxide
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M21/00—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
    • F02M21/02—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
    • F02M21/0218—Details on the gaseous fuel supply system, e.g. tanks, valves, pipes, pumps, rails, injectors or mixers
    • F02M21/0221—Fuel storage reservoirs, e.g. cryogenic tanks
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
    • F02M—SUPPLYING COMBUSTION ENGINES IN GENERAL WITH COMBUSTIBLE MIXTURES OR CONSTITUENTS THEREOF
    • F02M21/00—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form
    • F02M21/02—Apparatus for supplying engines with non-liquid fuels, e.g. gaseous fuels stored in liquid form for gaseous fuels
    • F02M21/0218—Details on the gaseous fuel supply system, e.g. tanks, valves, pipes, pumps, rails, injectors or mixers
    • F02M21/0296—Manufacturing or assembly; Materials, e.g. coatings
    • F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F17—STORING OR DISTRIBUTING GASES OR LIQUIDS
    • F17C—VESSELS FOR CONTAINING OR STORING COMPRESSED, LIQUEFIED OR SOLIDIFIED GASES; FIXED-CAPACITY GAS-HOLDERS; FILLING VESSELS WITH, OR DISCHARGING FROM VESSELS, COMPRESSED, LIQUEFIED, OR SOLIDIFIED GASES
    • F17C11/00—Use of gas-solvents or gas-sorbents in vessels
    • F17C11/005—Use of gas-solvents or gas-sorbents in vessels for hydrogen
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/30—Use of alternative fuels, e.g. biofuels

Landscapes

  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Combustion & Propulsion (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Mechanical Engineering (AREA)
  • General Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Hydrogen, Water And Hydrids (AREA)

Abstract

Method comprises absorbing the H2 in a complex mixture of Mg and >=1 other metal (alloy) in powder form, esp. La/Ni alloy, V, Ti and ferrotitanium. The metal is chosen so that at ambient temp. then is already a hydrogen pressure after absorption. The H2 fuel source is used in engines or other receivers or transformers of energy (e.g. fuel cells). MgH2 is cheap and provides high concn. of H2, the additive metals bring the H2 disengagement temp. to approx ambient and the metals are highly reactive with H2, so that the hydrides are readily regenerated.
FR7528646A 1975-09-18 1975-09-18 Storing hydrogen in magnesium and other hydridable metal(s) - used as source for motive power; releasing hydrogen at near ambient temp. Granted FR2324980A1 (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
FR7528646A FR2324980A1 (en) 1975-09-18 1975-09-18 Storing hydrogen in magnesium and other hydridable metal(s) - used as source for motive power; releasing hydrogen at near ambient temp.

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7528646A FR2324980A1 (en) 1975-09-18 1975-09-18 Storing hydrogen in magnesium and other hydridable metal(s) - used as source for motive power; releasing hydrogen at near ambient temp.

Publications (2)

Publication Number Publication Date
FR2324980A1 true FR2324980A1 (en) 1977-04-15
FR2324980B1 FR2324980B1 (en) 1979-03-30

Family

ID=9160151

Family Applications (1)

Application Number Title Priority Date Filing Date
FR7528646A Granted FR2324980A1 (en) 1975-09-18 1975-09-18 Storing hydrogen in magnesium and other hydridable metal(s) - used as source for motive power; releasing hydrogen at near ambient temp.

Country Status (1)

Country Link
FR (1) FR2324980A1 (en)

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2407169A1 (en) 1977-10-27 1979-05-25 Raffinage Cie Francaise PROCESS FOR PREPARING A HYDROGEN RESERVE AND APPLICATIONS OF THIS PROCESS.
FR2411626A1 (en) * 1977-12-19 1979-07-13 Billings Energy Corp FILTRATION PROCESS AND DEVICE, WITH SELF-REGENERATION, TO PURIFY HYDROGEN GAS AND REMOVE THEXYGEN AND WATER
FR2419458A2 (en) * 1978-03-08 1979-10-05 Anvar Storage of hydrogen in hydride form - using mixt. of magnesium and a component contg. cerium
JPS55149101A (en) * 1979-05-10 1980-11-20 Seijiro Suda Novel hydrogen absorbent
US4259110A (en) * 1978-07-07 1981-03-31 Agence Nationale De Valorisation De La Recherche (Anvar) Process for storing of hydrogen and the use thereof, particularly in engines
FR2525974A1 (en) * 1977-04-22 1983-11-04 Dornier System Gmbh Military vehicle, esp. armoured tank - driven by engine receiving hydrogen from metal hydride stored in separate reservoirs, giving power if some reservoirs are damaged

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
NEANT *

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2525974A1 (en) * 1977-04-22 1983-11-04 Dornier System Gmbh Military vehicle, esp. armoured tank - driven by engine receiving hydrogen from metal hydride stored in separate reservoirs, giving power if some reservoirs are damaged
FR2407169A1 (en) 1977-10-27 1979-05-25 Raffinage Cie Francaise PROCESS FOR PREPARING A HYDROGEN RESERVE AND APPLICATIONS OF THIS PROCESS.
FR2411626A1 (en) * 1977-12-19 1979-07-13 Billings Energy Corp FILTRATION PROCESS AND DEVICE, WITH SELF-REGENERATION, TO PURIFY HYDROGEN GAS AND REMOVE THEXYGEN AND WATER
FR2419458A2 (en) * 1978-03-08 1979-10-05 Anvar Storage of hydrogen in hydride form - using mixt. of magnesium and a component contg. cerium
US4259110A (en) * 1978-07-07 1981-03-31 Agence Nationale De Valorisation De La Recherche (Anvar) Process for storing of hydrogen and the use thereof, particularly in engines
JPS55149101A (en) * 1979-05-10 1980-11-20 Seijiro Suda Novel hydrogen absorbent
JPS5946881B2 (en) * 1979-05-10 1984-11-15 精二郎 須田 Novel hydrogen absorbent

Also Published As

Publication number Publication date
FR2324980B1 (en) 1979-03-30

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