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FR2012552A1 - Tertiary olefins prodn and purification - using an ion-exchange catalyst - Google Patents

Tertiary olefins prodn and purification - using an ion-exchange catalyst

Info

Publication number
FR2012552A1
FR2012552A1 FR6922961A FR6922961A FR2012552A1 FR 2012552 A1 FR2012552 A1 FR 2012552A1 FR 6922961 A FR6922961 A FR 6922961A FR 6922961 A FR6922961 A FR 6922961A FR 2012552 A1 FR2012552 A1 FR 2012552A1
Authority
FR
France
Prior art keywords
tert
ether
primary
alcohol
prodn
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
FR6922961A
Other languages
French (fr)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shell Internationale Research Maatschappij BV
Original Assignee
Shell Internationale Research Maatschappij BV
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from GB3261268A external-priority patent/GB1176620A/en
Priority claimed from GB3261568A external-priority patent/GB1272585A/en
Priority claimed from GB3261368A external-priority patent/GB1165479A/en
Priority claimed from GB4474968A external-priority patent/GB1173128A/en
Application filed by Shell Internationale Research Maatschappij BV filed Critical Shell Internationale Research Maatschappij BV
Publication of FR2012552A1 publication Critical patent/FR2012552A1/en
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C41/00—Preparation of ethers; Preparation of compounds having groups, groups or groups
    • C07C41/01—Preparation of ethers
    • C07C41/05—Preparation of ethers by addition of compounds to unsaturated compounds
    • C07C41/06—Preparation of ethers by addition of compounds to unsaturated compounds by addition of organic compounds only
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C1/00—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
    • C07C1/20—Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon starting from organic compounds containing only oxygen atoms as heteroatoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C7/00—Purification; Separation; Use of additives
    • C07C7/148—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound
    • C07C7/14875—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with organic compounds
    • C07C7/14891—Purification; Separation; Use of additives by treatment giving rise to a chemical modification of at least one compound with organic compounds alcohols
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2521/00—Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
    • C07C2521/02—Boron or aluminium; Oxides or hydroxides thereof
    • C07C2521/04—Alumina
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2527/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
    • C07C2527/02—Sulfur, selenium or tellurium; Compounds thereof
    • C07C2527/053—Sulfates or other compounds comprising the anion (SnO3n+1)2-

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

(1) Primary-tert. ether is obtd. by reacting (a) 4-7C tert. mono-olefin, with (b) 1-6C primary alcohol, in presence of (c) SO3H-containing cation exchange resin catalyst having specific surface area above 1 m2./g. and pore vol. above 0.05 ml./ml. before the reaction. (2) Continuous isolation of 4-7C tert. mono-olefins from a hydrocarbon mixt. is effected by (i) reacting the mixt. with a primary alcohol using a SO3H-containing cross-linked polystyrene ion exchange catalyst of above properties; (ii) separating corresponding primary-tert. ether; (iii) decomposing ether at raised temp. using steam and high surface area Al2O3; and (iv) recovering tert. olefin and primary alcohol for resulting decomposition products and recycling alcohol to ether formation.
FR6922961A 1968-07-09 1969-07-07 Tertiary olefins prodn and purification - using an ion-exchange catalyst Withdrawn FR2012552A1 (en)

Applications Claiming Priority (4)

Application Number Priority Date Filing Date Title
GB3261268A GB1176620A (en) 1968-07-09 1968-07-09 Recovery of Tertiary Olefins
GB3261568A GB1272585A (en) 1968-07-09 1968-07-09 Process for carrying ot exothermic catalytic reactions and an apparatus therefor
GB3261368A GB1165479A (en) 1968-07-09 1968-07-09 Process for the Preparation of Tertiary Monoolefins
GB4474968A GB1173128A (en) 1968-09-20 1968-09-20 Process for the preparation of Olefins

Publications (1)

Publication Number Publication Date
FR2012552A1 true FR2012552A1 (en) 1970-03-20

Family

ID=27448825

Family Applications (1)

Application Number Title Priority Date Filing Date
FR6922961A Withdrawn FR2012552A1 (en) 1968-07-09 1969-07-07 Tertiary olefins prodn and purification - using an ion-exchange catalyst

Country Status (6)

Country Link
BE (1) BE735740A (en)
CA (1) CA929537A (en)
DE (1) DE1934422C3 (en)
FR (1) FR2012552A1 (en)
NL (1) NL160234C (en)
SE (1) SE349559B (en)

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0008860A1 (en) * 1978-07-27 1980-03-19 CHEMICAL RESEARCH & LICENSING COMPANY Catalyst system
FR2440931A1 (en) * 1978-11-08 1980-06-06 Inst Francais Du Petrole PROCESS FOR PRODUCING ETHERS BY REACTION OF OLEFINS WITH ALCOHOLS
FR2520356A1 (en) * 1982-01-26 1983-07-29 Inst Francais Du Petrole Methyl tert.-butyl ether prodn. from mixed butene feed - by reacting isobutene with methanol and isomerising n-butene(s)

Families Citing this family (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS5168512A (en) * 1974-12-02 1976-06-14 Texaco Development Corp
DE2802199C3 (en) * 1978-01-19 1987-12-03 Basf Ag, 6700 Ludwigshafen Process for the recovery of isobutene from C↓4↓ hydrocarbon mixtures containing isobutene
FR2449074A1 (en) * 1979-02-14 1980-09-12 Inst Francais Du Petrole PROCESS FOR PRODUCING AND ISOLATING METHYL TERTIOBUTYL ETHER
DE2928510A1 (en) * 1979-07-14 1981-01-29 Basf Ag METHOD FOR PRODUCING ISOBUTEN FROM ISOBUTEN CONTAINING C TIEF 4-HYDROCARBON MIXTURES
DE2928509A1 (en) * 1979-07-14 1981-01-29 Basf Ag METHOD FOR THE SIMULTANEOUS PRODUCTION OF METHYL-TERT.-BUTYL ETHER AND PRODUCTION OF ISOBUTEN
FR2481269A1 (en) * 1980-04-28 1981-10-30 Inst Francais Du Petrole PROCESS FOR PRODUCING ETHERS BY REACTING OLEFINS WITH ALCOHOLS
JPS57209233A (en) * 1981-06-19 1982-12-22 Sumitomo Chem Co Ltd Decomposing method of methyl-tert-butyl ether
US4950803A (en) * 1982-11-17 1990-08-21 Chemical Research & Licensing Company Etherification process
DE3509292A1 (en) * 1985-03-15 1985-12-05 Ulrich 3300 Braunschweig Haupt METHOD FOR PRODUCING PURE TERTIAL OLEFINS
US5118873A (en) * 1990-11-19 1992-06-02 Chemical Research & Licensing Company Process for the preparation of mtbe
US7320745B2 (en) 2005-01-19 2008-01-22 Catalytic Distillation Technologies Energy efficient method for exothermic reactions
DE102009027404A1 (en) 2009-07-01 2011-01-05 Evonik Oxeno Gmbh Preparation of isobutene by cleavage of MTBE
CN108409517B (en) * 2018-02-24 2020-10-20 安徽海德化工科技有限公司 Method for preparing isobutene by catalytic cracking of methyl tert-butyl ether

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE733750C (en) * 1940-08-30 1943-04-01 Wacker Chemie Gmbh Process for the production of tetrachloroethane
DE908247C (en) * 1942-08-11 1954-04-05 Gaeneral Electric Company Process for removing cations from liquid media
US2480940A (en) * 1946-09-20 1949-09-06 Atlantic Refining Co Production of aliphatic ethers
DE1113570B (en) * 1957-04-20 1961-09-07 Bayer Ag Process for the production of cation exchangers based on non-shoot polymerized crosslinked polymers
BE590370A (en) * 1959-04-29 1900-01-01
DE1168081B (en) * 1960-01-21 1964-04-16 Bayer Ag Process for increasing the capacity of cation exchangers containing a maximum of one sulfonic acid group per aryl nucleus
FR1256388A (en) * 1960-05-04 1961-03-17 Sinclair Refining Co Process for the preparation of tertiary olefins
DE1224294B (en) * 1961-01-09 1966-09-08 Bayer Ag Process for the production of tertiary butyl alkyl ethers

Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0008860A1 (en) * 1978-07-27 1980-03-19 CHEMICAL RESEARCH & LICENSING COMPANY Catalyst system
FR2440931A1 (en) * 1978-11-08 1980-06-06 Inst Francais Du Petrole PROCESS FOR PRODUCING ETHERS BY REACTION OF OLEFINS WITH ALCOHOLS
FR2520356A1 (en) * 1982-01-26 1983-07-29 Inst Francais Du Petrole Methyl tert.-butyl ether prodn. from mixed butene feed - by reacting isobutene with methanol and isomerising n-butene(s)

Also Published As

Publication number Publication date
NL160234B (en) 1979-05-15
NL160234C (en) 1979-10-15
NL6910382A (en) 1970-01-13
SE349559B (en) 1972-10-02
DE1934422A1 (en) 1970-01-15
CA929537A (en) 1973-07-03
BE735740A (en) 1970-01-07
DE1934422C3 (en) 1984-04-26
DE1934422B2 (en) 1978-08-31

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Legal Events

Date Code Title Description
ST Notification of lapse