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ES482759A1 - Un procedimiento de preparacion de acidos ciclopropano-car- boxilicos - Google Patents

Un procedimiento de preparacion de acidos ciclopropano-car- boxilicos

Info

Publication number
ES482759A1
ES482759A1 ES482759A ES482759A ES482759A1 ES 482759 A1 ES482759 A1 ES 482759A1 ES 482759 A ES482759 A ES 482759A ES 482759 A ES482759 A ES 482759A ES 482759 A1 ES482759 A1 ES 482759A1
Authority
ES
Spain
Prior art keywords
formula
preparation
compound
image
propane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired
Application number
ES482759A
Other languages
English (en)
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sanofi Aventis France
Original Assignee
Roussel Uclaf SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Roussel Uclaf SA filed Critical Roussel Uclaf SA
Publication of ES482759A1 publication Critical patent/ES482759A1/es
Expired legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D305/00—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
    • C07D305/02—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings
    • C07D305/10—Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms not condensed with other rings having one or more double bonds between ring members or between ring members and non-ring members
    • C07D305/12—Beta-lactones
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D307/00—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
    • C07D307/02—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings
    • C07D307/34—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
    • C07D307/56—Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D307/58—One oxygen atom, e.g. butenolide
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D309/00—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings
    • C07D309/32—Heterocyclic compounds containing six-membered rings having one oxygen atom as the only ring hetero atom, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D331/00—Heterocyclic compounds containing rings of less than five members, having one sulfur atom as the only ring hetero atom
    • C07D331/04—Four-membered rings
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D333/00—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
    • C07D333/02—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings
    • C07D333/04—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom
    • C07D333/26—Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings not substituted on the ring sulphur atom with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D333/30—Hetero atoms other than halogen
    • C07D333/32—Oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07D—HETEROCYCLIC COMPOUNDS
    • C07D335/00—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom
    • C07D335/02—Heterocyclic compounds containing six-membered rings having one sulfur atom as the only ring hetero atom not condensed with other rings

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Heterocyclic Compounds Containing Sulfur Atoms (AREA)
  • Furan Compounds (AREA)
  • Pyrane Compounds (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Plural Heterocyclic Compounds (AREA)

Abstract

1. Un procedimiento de preparación de ácidos ciclopropano- carboxílicos de fórmula general-01 (I) de configuración (1R,3S): **(Fórmula-01)** en la que X representa un átomo de azufre o de oxígeno y n representa un número entero igual a 1, 2 o 3, caracterizado porque se hace reaccionar, en el seno de un disolvente orgánico, y en presencia de un agente básico fuerte, lactona de ácido cis 2,2-dimetil-3S(dihidroximetil)ciclopropano-1R- carboxílico , fórmula-02 (II): **(Fórmula-02)** con un compuesto de fórmula general-03 (III): **(Fórmula-03)** en la que X y n son como se han definido anteriormente, se somete el compuesto resultante, de fórmula general-04 (IV): **(Fórmula-04)** a la acción de un agente ácido, en el seno de un disolvente orgánico apolar, y después se somete el compuesto resultante, de fórmula general-05 (V): **(Fórmula-05)** a la acción de un agente básico en el seno de un disolvente orgánico apolar, para obtener el compuesto (I) correspondiente deseado.
ES482759A 1978-07-24 1979-07-23 Un procedimiento de preparacion de acidos ciclopropano-car- boxilicos Expired ES482759A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR7821813A FR2450830A1 (fr) 1978-07-24 1978-07-24 Nouveau procede de preparation d'acides cyclopropane-1-carboxyliques 3-substitues

Publications (1)

Publication Number Publication Date
ES482759A1 true ES482759A1 (es) 1980-09-01

Family

ID=9211069

Family Applications (1)

Application Number Title Priority Date Filing Date
ES482759A Expired ES482759A1 (es) 1978-07-24 1979-07-23 Un procedimiento de preparacion de acidos ciclopropano-car- boxilicos

Country Status (8)

Country Link
US (1) US4412069A (es)
EP (1) EP0007839B1 (es)
JP (1) JPS5519262A (es)
AT (1) ATE182T1 (es)
DE (1) DE2960733D1 (es)
ES (1) ES482759A1 (es)
FR (1) FR2450830A1 (es)
HU (1) HU178717B (es)

Family Cites Families (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4014918A (en) * 1968-07-12 1977-03-29 Roussel-Uclaf Process for the preparation of cyclopropane derivatives and compounds produced therein
SE371821B (es) * 1968-07-12 1974-12-02 Roussel Uclaf
US3714153A (en) * 1970-06-22 1973-01-30 Roussel Uclaf Novel cyclopropanecarboxylic acids
GB1448586A (en) * 1973-06-07 1976-09-08 Nat Res Dev 3-substituted-2,2,dimethyl cyclopropane carboxylic acid esters and their use as insecticides
JPS5111173B2 (es) * 1974-04-25 1976-04-09
FR2396006A1 (fr) * 1977-06-27 1979-01-26 Roussel Uclaf Nouveaux composes a noyau cyclopropanique, procede de preparation et application a la preparation de derives cyclopropaniques a chaine dihalovinyliques

Also Published As

Publication number Publication date
US4412069A (en) 1983-10-25
DE2960733D1 (en) 1981-11-26
JPS5519262A (en) 1980-02-09
EP0007839A1 (fr) 1980-02-06
ATE182T1 (de) 1981-09-15
HU178717B (en) 1982-06-28
JPH0118075B2 (es) 1989-04-03
EP0007839B1 (fr) 1981-09-02
FR2450830A1 (fr) 1980-10-03
FR2450830B1 (es) 1982-02-26

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Legal Events

Date Code Title Description
FD1A Patent lapsed

Effective date: 19981201