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ES2388226A1 - Anoxic denitrifier of depressed wastewater (Machine-translation by Google Translate, not legally binding) - Google Patents

Anoxic denitrifier of depressed wastewater (Machine-translation by Google Translate, not legally binding) Download PDF

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Publication number
ES2388226A1
ES2388226A1 ES201031610A ES201031610A ES2388226A1 ES 2388226 A1 ES2388226 A1 ES 2388226A1 ES 201031610 A ES201031610 A ES 201031610A ES 201031610 A ES201031610 A ES 201031610A ES 2388226 A1 ES2388226 A1 ES 2388226A1
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Spain
Prior art keywords
wastewater
reactor
denitrifier
anoxic
purified
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Granted
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ES201031610A
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Spanish (es)
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ES2388226B1 (en
Inventor
Ángel Silla Gómez
José Luis Navarro Vigueras
José María Silla Gómez
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Tratamiento Aguas Del Sureste S L
TRATAMIENTO AGUAS DEL SURESTE SL
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Tratamiento Aguas Del Sureste S L
TRATAMIENTO AGUAS DEL SURESTE SL
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Priority to ES201031610A priority Critical patent/ES2388226B1/en
Publication of ES2388226A1 publication Critical patent/ES2388226A1/en
Application granted granted Critical
Publication of ES2388226B1 publication Critical patent/ES2388226B1/en
Expired - Fee Related legal-status Critical Current
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Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2806Anaerobic processes using solid supports for microorganisms
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/28Anaerobic digestion processes
    • C02F3/2833Anaerobic digestion processes using fluidized bed reactors

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  • Life Sciences & Earth Sciences (AREA)
  • Microbiology (AREA)
  • Biodiversity & Conservation Biology (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Purification Treatments By Anaerobic Or Anaerobic And Aerobic Bacteria Or Animals (AREA)
  • Biological Treatment Of Waste Water (AREA)

Abstract

Anoxic de-nitrifier of purified wastewater. It comprises: a reactor (1) fed in its lower part by a flow of purified wastewater, with nitrate charge, through a first conduit (3), where the reactor (1) is closed to prevent the entry of light and of oxygen, said reactor (1) provided with an inert bed (2) for receiving and retaining heterotrophic anaerobic bacteria to produce the denitrification of the treated wastewater, during its upward advance through the inert bed (2), avoiding the dragging of bacteria by wastewater; a second duct (4) located in the upper part of the reactor (1), to allow the exit of wastewater with reduced concentration of nitrates; a third conduit (5) for the exit of gaseous nitrogen obtained by denitrification; and a fourth conduit (6) for dislodging sludge from the bottom of the reactor (1). (Machine-translation by Google Translate, not legally binding)

Description

DESNITRIFICADOR ANÓXICO DE AGUAS RESIDUALES DEPURADAS ANOXY DENITRIFIER OF CLEAN WASTEWATER

5 5
OBJETO DE LA INVENCIÓN OBJECT OF THE INVENTION

1 o 1st
La presente invención se puede incluir dentro del campo técnico de la depuración de aguas residuales, más concretamente de la reducción del exceso de nitratos presentes en el agua residual una vez depurada. El objeto de la invención se refiere a un desnitrificador anóxico de aguas residuales depuradas. The present invention can be included within the technical field of wastewater purification, more specifically the reduction of excess nitrates present in the wastewater once purified. The object of the invention relates to an anoxic denitrifier of purified wastewater.

ANTECEDENTES DE LA INVENCIÓN BACKGROUND OF THE INVENTION

15 2 o 15 2nd
La desnitrificación anóxica consiste en un proceso de transformación biológica del nitrógeno por medio de la transformación de los nitratos (N03) y nitritos (N02), presentes en un medio acuático, a nitrógeno libre (N2), mediante la intervención de bacterias anaerobias facultativas, las cuales pueden realizar su función metabólica sin necesidad de encontrar oxígeno disuelto en su medio, pudiendo obtener dicho oxígeno de los nitratos presentes, mediante reacciones de desnitrificación. Como consecuencia de dichas reacciones se libera nitrógeno gaseoso hacia la atmósfera y se consume carbono orgánico biodegradable. The anoxic denitrification consists of a process of biological transformation of nitrogen by means of the transformation of nitrates (N03) and nitrites (N02), present in an aquatic environment, to free nitrogen (N2), through the intervention of facultative anaerobic bacteria, which can perform their metabolic function without the need to find dissolved oxygen in their environment, being able to obtain said oxygen from the nitrates present, through denitrification reactions. As a consequence of these reactions, nitrogen gas is released into the atmosphere and biodegradable organic carbon is consumed.

2 5 2 5
En síntesis, la secuencia de reacciones que se encadenan en el proceso, para conseguir la reducción de nitratos hasta nitrógeno gaseoso, ocurre en etapas seriadas efectuadas por diferentes organismos según el siguiente esquema. In synthesis, the sequence of reactions that are chained in the process, to achieve the reduction of nitrates to nitrogen gas, occurs in serial stages performed by different organisms according to the following scheme.

En la actualidad existen diversos sistemas de desnitrificación asociados a los procesos de depuración de aguas residuales, ya sean el embalsado anóxico, There are currently various denitrification systems associated with wastewater treatment processes, whether they are anoxic reservoir,

de ósmosis inversa, compactos, humedales, etc. No obstante, dichos sistemas reverse osmosis, compact, wetlands, etc. However, these systems

presentan una serie de inconvenientes, entre los que se mencionan los they present a series of drawbacks, among which the

siguientes: following:

-las bacterias anaeróbicas facultativas empleadas son arrastradas por el -the optional anaerobic bacteria used are carried away by the

5 5
flujo de agua tratada; treated water flow;

-se acompañan de una alta producción de fangos digeridos, lo que -They are accompanied by a high production of digested sludge, which

disminuye el rendimiento de los procedimientos de desnitrificación; decreases the performance of denitrification procedures;

-presentan rendimientos bajos. - they present low yields.

10 10
Los problemas técnicos mencionados se pueden resolver mediante el The mentioned technical problems can be solved by

uso de un "desnitrificador anóxico" para aguas residuales depuradas que use of an "anoxic denitrifier" for purified wastewater that

garantiza el mantenimiento de la población bacteriana, una menor producción de guarantees the maintenance of the bacterial population, a lower production of

fangos digeridos y un mayor rendimiento digested sludge and higher yield

15 fifteen
DESCRIPCIÓN DE LA INVENCIÓN DESCRIPTION OF THE INVENTION

La presente invención resuelve el problema técnico planteado por medio The present invention solves the technical problem posed by

de un desnitrificador anóxico y afótico de flujo vertical ascendente, para of an anoxic and afotic denitrifier of upward vertical flow, for

desnitrificar aguas residuales depuradas, tal como se describe seguidamente: denitrify purified wastewater, as described below:

20 twenty

El desnitrificador anóxico es un sistema afótico de flujo vertical The anoxic denitrifier is an afotic vertical flow system

ascendente, que permite la desnitrificación de aguas residuales depuradas. El ascending, which allows denitrification of purified wastewater. He

sistema se compone de un reactor cerrado provisto de un lecho inerte para system consists of a closed reactor provided with an inert bed for

soportar poblaciones de bacterias anaerobias heterótrofas. Las bacterias se withstand populations of heterotrophic anaerobic bacteria. Bacteria is

2 5 2 5
instalan en dicho lecho a consecuencia de un influente de aguas residuales installed in said bed as a result of a wastewater influent

depuradas, pero aún con carga de nitratos, que se introduce en el desnitrifiador a purified, but still loaded with nitrates, which is introduced into the denitrifier to

través de un conducto de entrada dispuesto en la parte inferior del reactor. through an inlet conduit disposed in the bottom of the reactor.

De manera preferente, el lecho inerte presenta una granulometría Preferably, the inert bed has a particle size

uniforme, para evitar la existencia, a lo largo del mismo, de zonas con diferente uniform, to avoid the existence, along the same, of areas with different

3 o 3rd
resistencia al paso de agua residual, siendo los materiales que lo constituyen: resistance to the passage of residual water, being the materials that constitute it:

grava, materiales cerámicos, arcillosos, plásticos, etc., lo cual permite que las gravel, ceramic, clay, plastics, etc., which allows the

bacterias arraiguen en el lecho y no sean arrastradas por el influente.    bacteria take root in the bed and are not dragged by the influent.

El funcionamiento del desnitrificador de la invención se produce tras la The operation of the denitrifier of the invention occurs after the

inyección de un flujo constante de caudal de agua residual depurada a través del injection of a constant flow of purified wastewater through the

conducto de entrada, que se distribuye uniformemente en sentido ascendente a inlet duct, which is distributed evenly upwards to

través del lecho inerte. through the inert bed.

5 5

Como consecuencia de tratarse de un reactor cerrado, se consigue un As a result of being a closed reactor, a

ambiente anóxico y afótico, lo cual evita el crecimiento de algas en el interior, así anoxic and afotic environment, which prevents the growth of algae inside, as well

como la entrada de oxígeno, evitando, por tanto, su absorción por parte del as the entry of oxygen, thus preventing its absorption by the

influente. influent

10 10

El desnitrificador de la invención es un sistema de gran versatilidad, en The denitrifier of the invention is a highly versatile system, in

cuanto al tipo de influentes de agua residual que puede tratar, ya que funciona as to the type of influents of wastewater that you can treat, since it works

tanto para aguas residuales inorgánicas como para aguas residuales con both for inorganic wastewater and for wastewater with

diferentes concentraciones orgánicas. En el caso de agua residual sin carga Different organic concentrations. In the case of unloaded wastewater

15 fifteen
orgánica, se emplea el aporte de una fuente de carbono para asegurar la organic, the contribution of a carbon source is used to ensure the

viabilidad de las bacterias, lo cual se consigue mediante el aporte controlado de viability of bacteria, which is achieved through the controlled contribution of

carbono necesario desde un medio externo. Carbon needed from an external medium.

Por la parte superior del desnitrificador se producen la salida tanto del From the top of the denitrifier both the output of the

2 o 2nd
agua residual desnitrificada, una vez reducidos los niveles de nitratos, como la denitrified wastewater, once nitrate levels have been reduced, such as

del nitrógeno gaseoso, mientras que los fangos producidos, (disminuida of gaseous nitrogen, while the sludge produced, (decreased

sensiblemente su cantidad, debido a la ausencia de algas y al aumento del substantially its quantity, due to the absence of algae and the increase in

rendimiento del desnitrificador), se van desalojando por la parte inferior. performance of the denitrifier), are evicted from the bottom.

25 25
Se puede incluir en la parte superior del desnitrificador una válvula de A valve can be included on the top of the denitrifier

venteo y un contador volumétrico para controlar el rendimiento del desnitrificador, venting and a volumetric counter to control the performance of the denitrifier,

expresado en volumen de nitrógeno obtenido en relación al volumen de influente expressed in volume of nitrogen obtained in relation to the volume of influent

tratado.    treaty.
DESCRIPCIÓN DE LOS DIBUJOS DESCRIPTION OF THE DRAWINGS

Para complementar la descripción que se está realizando y con objeto de ayudar a una mejor comprensión de las características de la invención, de acuerdo con un ejemplo preferente de realización práctica de la misma, se acompaña como parte integrante de dicha descripción, un juego de dibujos en donde con carácter ilustrativo y no limitativo, se ha representado lo siguiente: To complement the description that is being made and in order to help a better understanding of the characteristics of the invention, according to a preferred example of practical implementation thereof, a set of drawings is attached as an integral part of said description. where, for illustrative and non-limiting purposes, the following has been represented:

Figura 1.-Muestra un esquema del desnitrificador según la invención. Figure 1.- Shows a scheme of the denitrifier according to the invention.

REALIZACIÓN PREFERENTE DE LA INVENCIÓN PREFERRED EMBODIMENT OF THE INVENTION

El desnitrificador anóxico de influentes de aguas residuales de la invención comprende un reactor (1) cerrado opaco en el que se encuentra dispuesto un lecho (2) inerte de granulometría uniforme para soportar poblaciones de bacterias anaerobias heterótrofas. A través de un primer conducto (3) dispuesto en la parte inferior del reactor (1) se introduce el agua residual depurada que aún contiene cargas de nitratos. The anoxic wastewater denitrifier of the invention comprises an opaque closed reactor (1) in which an inert bed (2) of uniform granulometry is arranged to support populations of heterotrophic anaerobic bacteria. Through a first duct (3) disposed in the lower part of the reactor (1), the purified waste water that still contains nitrate charges is introduced.

El agua residual es repartida hacia el interior del reactor (1) mediante unos medios de reparto (7) según un caudal constante y se distribuye uniformemente desde la parte inferior del reactor (1) en sentido ascendente a través del lecho (2) inerte. The wastewater is distributed into the reactor (1) by means of distribution (7) according to a constant flow and is distributed uniformly from the bottom of the reactor (1) upwards through the inert bed (2).

El reactor (1) cerrado y opaco impide la entrada de luz y de oxígeno, con lo cual se evita el crecimiento de algas en el interior del reactor (1 ), elevándose consecuentemente el rendimiento del dispositivo. The closed and opaque reactor (1) prevents the entry of light and oxygen, thereby preventing the growth of algae inside the reactor (1), consequently raising the performance of the device.


En el caso de que el agua residual no contenga carga orgánica, se prevén 3 o unos medios de aporte (8) para proporcionar un el aporte controlado externo de una fuente de carbono para asegurar la viabilidad de las bacterias.

In the event that the wastewater does not contain an organic load, 3 or a contribution means (8) are provided to provide an external controlled supply of a carbon source to ensure the viability of the bacteria.

Se dispone en la parte superior del desnitrificador de un segundo conducto (4) para la salida del agua residual desnitrificada, una vez reducidos los niveles de nitratos, así como un tercer conducto (5) para la salida del nitrógeno gaseoso obtenido, mientras que los fangos producidos durante el proceso se van A second duct (4) for the outlet of the denitrified wastewater is disposed in the upper part of the denitrifier, once nitrate levels have been reduced, as well as a third duct (5) for the output of the obtained nitrogen gas, while the sludge produced during the process leaves

s desalojando por la parte inferior a través de cuartos conductos (6). s dislodging from the bottom through fourth ducts (6).


Se puede incluir en la parte superior del desnitrificador una válvula (9) de venteo y un contador (1 O) volumétrico para controlar el rendimiento del desnitrificador.

A vent valve (9) and a volumetric counter (1 O) can be included in the upper part of the denitrifier to control the performance of the denitrifier.

Claims (4)

REIVINDICACIONES
1.-Desnitrificador anóxico de aguas residuales depuradas, caracterizado 1.-Anoxic denitrifier of purified wastewater, characterized
porque comprende: because it includes:
5 5
-un reactor (1) alimentado en su parte inferior por un caudal de aguas -a reactor (1) fed in its lower part by a water flow
residuales depuradas, con carga de nitratos, a través de un primer conducto (3), purified waste, with nitrate loading, through a first duct (3),
donde el reactor (1) está cerrado para impedir la entrada de luz y de oxígeno, where the reactor (1) is closed to prevent the entry of light and oxygen,
dicho reactor (1) provisto de un lecho (2) inerte para alojar y retener bacterias said reactor (1) provided with an inert bed (2) to house and retain bacteria
anaerobias heterótrofas para producir la desnitrificación de las aguas residuales heterotrophic anaerobes to produce denitrification of wastewater
1 o 1st
depuradas, durante su avance ascendente a través del lecho (2) inerte, evitando purified, during its upward advance through the inert bed (2), avoiding
el arrastre de las bacterias por el agua residual; the entrainment of bacteria by wastewater;
-un segundo conducto (4) situado en la parte superior del reactor (1 ), -a second conduit (4) located at the top of the reactor (1),
para permitir la salida de las aguas residuales desnitrificadas, una vez reducida to allow the outflow of denitrified wastewater, once reduced
la concentración de nitratos; nitrate concentration;
15 fifteen
-un tercer conducto (5) para la salida de nitrógeno gaseoso obtenido -a third conduit (5) for the output of gaseous nitrogen obtained
mediante la desnitrificación; y by denitrification; Y
-un cuarto conducto (6) para desalojar por la parte inferior del reactor (1) -a fourth conduit (6) to dislodge from the bottom of the reactor (1)
fangos producidos durante el proceso. sludge produced during the process.
20 twenty
2.-Desnitrificador anóxico de aguas residuales depuradas, de acuerdo con 2.-Anoxic denitrifier of purified wastewater, in accordance with
la reivindicación 1, caracterizado porque comprende adicionalmente unos claim 1, characterized in that it further comprises
medios de reparto (7) para repartir el agua residual hacia el interior del reactor delivery means (7) for distributing waste water into the reactor
(1) según un caudal constante y para distribuir uniformemente dicha agua (1) according to a constant flow and to distribute said water evenly
residual desde la parte inferior del reactor (1) en sentido ascendente a través del residual from the bottom of the reactor (1) upwards through the
2 5 2 5
lecho (2) inerte. inert bed (2).
3.-Desnitrificador anóxico de aguas residuales depuradas, de acuerdo con la 3.-Anoxic denitrifier of purified wastewater, in accordance with the
reivindicación 1, caracterizado porque comprende adicionalmente unos medios claim 1, characterized in that it further comprises means
de aporte (8) para proporcionar un aporte controlado externo de una fuente de of contribution (8) to provide an external controlled contribution from a source of
3 o 3rd
carbono para asegurar la viabilidad de las bacterias en caso de que el agua carbon to ensure the viability of bacteria in case the water
residual no contenga carga orgánica. residual does not contain organic load.
4.-Desnitrificador anóxico de aguas residuales depuradas, de acuerdo con la reivindicación 1, caracterizado porque comprende adicionalmente en la parte superior del reactor (1) una válvula (9) de venteo y un contador (1 O) volumétrico para controlar el rendimiento del desnitrificador. 4.-Anoxic denitrifier of purified wastewater, according to claim 1, characterized in that it additionally comprises at the top of the reactor (1) a vent valve (9) and a volumetric counter (1 O) to control the performance of the denitrifier 5.-Desnitrificador anóxico de aguas residuales depuradas, de acuerdo con la reivindicación 1, caracterizado porque el lecho (2) inerte presenta una granulometría uniforme. 5.-Anoxic denitrifier of purified wastewater, according to claim 1, characterized in that the inert bed (2) has a uniform particle size. 1 o 6.-Desnitrificador anóxico de aguas residuales depuradas, de acuerdo con una cualquiera de las reivindicaciones 1 ó 5, caracterizado porque el lecho (2) inerte está compuesto de al menos un material seleccionado entre: -grava, -materiales cerámicos, 1 or 6.-Anoxic denitrifier of purified waste water, according to any one of claims 1 or 5, characterized in that the inert bed (2) is composed of at least one material selected from: -gravel,-ceramic materials, 15 -materiales arcillosos, y -materiales plásticos. 15 -clay materials, and -plastic materials.
ES201031610A 2010-11-02 2010-11-02 ANOXIC DENURRIFIER OF CLEAN WASTEWATER Expired - Fee Related ES2388226B1 (en)

Priority Applications (1)

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ES2388226A1 true ES2388226A1 (en) 2012-10-10
ES2388226B1 ES2388226B1 (en) 2013-09-13

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3846289A (en) * 1972-06-19 1974-11-05 Ecolotrol Waste treatment process
US4043936A (en) * 1976-02-24 1977-08-23 The United States Of America As Represented By United States Energy Research And Development Administration Biological denitrification of high concentration nitrate waste
US4322296A (en) * 1980-08-12 1982-03-30 Kansas State Univ. Research Foundation Method for wastewater treatment in fluidized bed biological reactors
EP0327184A1 (en) * 1988-02-05 1989-08-09 Gist-Brocades N.V. Anoxic ammonia oxidation
WO2003093180A1 (en) * 2002-05-02 2003-11-13 Korea Institute Of Science And Technology Biological denitrification apparatus and method using fluidized-bed reactor filled with elemental sulfur

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3846289A (en) * 1972-06-19 1974-11-05 Ecolotrol Waste treatment process
US4043936A (en) * 1976-02-24 1977-08-23 The United States Of America As Represented By United States Energy Research And Development Administration Biological denitrification of high concentration nitrate waste
US4322296A (en) * 1980-08-12 1982-03-30 Kansas State Univ. Research Foundation Method for wastewater treatment in fluidized bed biological reactors
EP0327184A1 (en) * 1988-02-05 1989-08-09 Gist-Brocades N.V. Anoxic ammonia oxidation
WO2003093180A1 (en) * 2002-05-02 2003-11-13 Korea Institute Of Science And Technology Biological denitrification apparatus and method using fluidized-bed reactor filled with elemental sulfur

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