ES2263522T3 - WORK MEDIA EXEMPT PVC AND PLASTIFICANTS. - Google Patents
WORK MEDIA EXEMPT PVC AND PLASTIFICANTS.Info
- Publication number
- ES2263522T3 ES2263522T3 ES01104970T ES01104970T ES2263522T3 ES 2263522 T3 ES2263522 T3 ES 2263522T3 ES 01104970 T ES01104970 T ES 01104970T ES 01104970 T ES01104970 T ES 01104970T ES 2263522 T3 ES2263522 T3 ES 2263522T3
- Authority
- ES
- Spain
- Prior art keywords
- layer
- inner layer
- work
- medical
- outer layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
Classifications
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L29/00—Materials for catheters, medical tubing, cannulae, or endoscopes or for coating catheters
- A61L29/04—Macromolecular materials
- A61L29/041—Macromolecular materials obtained by reactions only involving carbon-to-carbon unsaturated bonds
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61L—METHODS OR APPARATUS FOR STERILISING MATERIALS OR OBJECTS IN GENERAL; DISINFECTION, STERILISATION OR DEODORISATION OF AIR; CHEMICAL ASPECTS OF BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES; MATERIALS FOR BANDAGES, DRESSINGS, ABSORBENT PADS OR SURGICAL ARTICLES
- A61L29/00—Materials for catheters, medical tubing, cannulae, or endoscopes or for coating catheters
- A61L29/08—Materials for coatings
- A61L29/085—Macromolecular materials
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0807—Copolymers of ethene with unsaturated hydrocarbons only containing more than three carbon atoms
- C08L23/0815—Copolymers of ethene with aliphatic 1-olefins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0853—Vinylacetate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/04—Homopolymers or copolymers of ethene
- C08L23/08—Copolymers of ethene
- C08L23/0846—Copolymers of ethene with unsaturated hydrocarbons containing other atoms than carbon or hydrogen atoms
- C08L23/0869—Acids or derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L75/00—Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
- C08L75/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L9/00—Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
- C08L9/06—Copolymers with styrene
Landscapes
- Health & Medical Sciences (AREA)
- Epidemiology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials For Medical Uses (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Medios de trabajo médicos exentos de PVC y plastificantes.PVC-free medical work media and plasticizers
La invención se refiere a medios de trabajo médicos, que pueden fabricarse en un procedimiento de extrusión, como tubos flexibles, tubos, catéteres y similares, formados por al menos una capa interior y una capa exterior que la envuelve de materiales polímeros.The invention relates to working means doctors, which can be manufactured in an extrusion procedure, as flexible tubes, tubes, catheters and the like, formed by minus an inner layer and an outer layer that wraps it polymeric materials.
En el estado de la técnica conocido, para medios de trabajo médicos de este tipo se usan sobre todo materiales polímeros basados en PVC, puesto que estos suponen una buena relación entre precio y prestaciones, gracias a los bajos costes de material y la técnica de confección basada en el pegado para elementos de conexión como, por ejemplo, cámaras de goteo, conectores, almohadillas de depresión y otros.In the state of the known art, for media Medical work of this type is used mostly materials PVC based polymers, since these are a good relationship between price and benefits, thanks to the low costs of material and manufacturing technique based on gluing for connection elements such as drip chambers, connectors, depression pads and others.
También se usan medios de trabajo médicos hechos de materiales de poliuretano. Aunque con estos sea posible usar las técnicas de confección existentes, los medios de trabajo médicos de este tipo conllevan la desventaja de una relación negativa entre precio y prestaciones debido al precio de material muy elevado, en particular en aplicaciones en el área de la diálisis y de las transfusiones. Otra posibilidad del estado de la técnica conocido es el uso de medios de trabajo médicos hechos de poliolefinas. Aunque estos tienen un precio de material aceptable, no pueden ser procesados con la técnica de confección convencional como, por ejemplo, el pegado, para obtener instrumentos para diálisis corrientes en el mercado para la hemodiálisis. Los materiales y sistemas que resultan del estado de la técnica conocido presentan, por un lado, una relación desfavorable entre precio y prestaciones y conllevan, por otro lado, asociaciones negativas por la actual discusión del PVC con los temas centrales de la migración de plastificantes, la eliminación de los desechos, como por ejemplo la formación de ácido clorhídrico en la combustión, o la formación de dioxinas y furanos.Medical means of work done are also used of polyurethane materials. Although with these it is possible to use the existing clothing techniques, medical means of work of this type entails the disadvantage of a negative relationship between price and performance due to the very high price of material, in particularly in applications in the area of dialysis and transfusions Another possibility of the known state of the art is the use of medical means of work made of polyolefins. Though these have an acceptable material price, they cannot be processed with the conventional clothing technique as, by example, gluing, to obtain instruments for dialysis current in the market for hemodialysis. The materials and systems that result from the known state of the art present, on the one hand, an unfavorable relationship between price and benefits and entail, on the other hand, negative associations for the current PVC discussion with the central issues of migration of plasticizers, waste disposal, such as formation of hydrochloric acid in combustion, or the formation of Dioxins and furans.
En el documento US5.562.127A están descritos tubos flexibles para el uso médico. Estos están formados por un material compuesto de capas de materiales polímeros, estando descritos tubos flexibles de dos y tres capas. La elección de materiales se hace de tal forma que se evite el uso de PVC. Los materiales preferibles para la formación de los tubos flexibles médicos del documento US5.562.127A no contienen plastificantes. Para la capa interior se indica, por ejemplo, copolímero de etileno y acetato de vinilo con un contenido de un 28% en peso de acetato de vinilo. También se habla de polimetacrilato como material posible para una de las capas. Asimismo se menciona el uso de un copolímero con una poliolefina. Como materiales para la capa interior se indican, por ejemplo, polietileno y polipropileno. Para la capa exterior se indica, por ejemplo, poliuretano.In document US5.562.127A are described flexible tubes for medical use. These are formed by a composite material of layers of polymeric materials, being described two and three layer flexible tubes. The choice of Materials are made in such a way that the use of PVC is avoided. The preferable materials for the formation of flexible tubes Doctors of US5,562,127A do not contain plasticizers. For the inner layer is indicated, for example, ethylene copolymer and vinyl acetate with a content of 28% by weight of acetate vinyl. There is also talk of polymethacrylate as a possible material for one of the layers. The use of a copolymer is also mentioned. with a polyolefin. As materials for the inner layer is indicate, for example, polyethylene and polypropylene. For the cape exterior is indicated, for example, polyurethane.
En el documento WO00/76564A1 está descrito un tubo flexible multicapa para fines médicos.A document WO00 / 76564A1 describes a Multilayer flexible tube for medical purposes.
La invención tiene el objetivo de eliminar las desventajas conocidas del estado de la técnica e indicar medios de trabajo médicos que puedan fabricarse de forma económica, que reduzcan el riesgo para el paciente por la migración de plastificantes y que puedan eliminarse los desechos sin problemas después del uso.The invention aims to eliminate the known disadvantages of the prior art and indicate means of medical work that can be manufactured economically, which reduce the risk to the patient by the migration of plasticizers and waste can be eliminated without problems after use
Por lo tanto, se considera otro objetivo especificar como pueden seguir usándose las técnicas de confección conocidas por el estado de la técnica.Therefore, another objective is considered specify how sewing techniques can continue to be used known by the state of the art.
Según la invención, esto se consigue mediante las propiedades caracterizadoras de la reivindicación 1. En las reivindicaciones subordinadas están definidas otras configuraciones ventajosas.According to the invention, this is achieved by the characterizing properties of claim 1. In the subordinate claims other configurations are defined advantageous
Los medios de trabajo médicos según la invención están caracterizados porque están hechos de materiales exentos de halógenos, porque la capa exterior puede pegarse mediante disolvente, porque la capa interior y la capa exterior que la envuelve están unidos fijamente una a otra y porque el grosor de pared de la capa exterior corresponde como máximo a la mitad del grosor de pared de la capa interior.The medical work means according to the invention they are characterized because they are made of materials free of halogens, because the outer layer can be glued by solvent, because the inner layer and the outer layer that the wraps are fixedly attached to each other and because the thickness of wall of the outer layer corresponds to a maximum of half of the wall thickness of the inner layer.
Gracias al uso de materiales exentos de halógenos y de plastificantes queda garantizado que durante el uso de los medios de trabajo médicos no surgen problemas debido a la migración de plastificantes. Con ello queda garantizada de forma ventajosa una seguridad para el paciente, en particular, en el caso de personas que sufren fácilmente reacciones alérgicas. Otra ventaja se considera que la capa exterior usada según la invención puede pegarse mediante disolvente, de modo que puedan usarse todas las técnicas de confección conocidas también por el uso de materiales que contienen halógenos, así como las piezas de empalme, elementos de conexión, etc. usados.Thanks to the use of materials exempt from Halogens and plasticizers are guaranteed that during use Medical problems do not arise due to the plasticizer migration. This is guaranteed so advantageous for patient safety, in particular, in the case of people who easily suffer allergic reactions. Another advantage it is considered that the outer layer used according to the invention can glued by solvent, so that all clothing techniques also known for the use of materials containing halogens, as well as splices, elements connection, etc. used.
Según los requisitos de los medios de trabajo médicos, tanto los grosores de pared de la capa exterior como de la capa interior pueden dimensionarse de tal forma que, por un lado, quede garantizada una unión fija entre los catéteres que se usan, por ejemplo, y los elementos de empalme o de conexión fijados en los mismos, además de la resistencia mecánica y la resistencia a la dobladura correspondientemente requeridas en el uso en zonas sensibles.According to the requirements of the means of work medical, both the wall thicknesses of the outer layer and the inner layer can be sized so that, on the one hand, a fixed connection between the catheters used is guaranteed, for example, and the connection or connection elements fixed in the themselves, in addition to mechanical strength and resistance to bending correspondingly required in zone use sensitive
En los medios de trabajo médicos según la invención se considera otra ventaja que la capa interior es al mismo tiempo la capa adhesiva, de modo que quede garantizada en cualquier momento la unión fija entre la capa interior y las capas exteriores correspondientes.In the medical work environment according to the invention is considered another advantage that the inner layer is the same time the adhesive layer, so that it is guaranteed in any moment the fixed connection between the inner layer and the outer layers corresponding.
Para la capa interior de los medios de trabajo médicos según la invención puede usarse un copolímero de etileno y acetato de vinilo con al menos un 10% de acetato de vinilo. Además, es ventajoso el uso de un etileno acrilato de metilo con al menos un 10% de acrilato de metilo. Gracias al uso de materiales polímeros de este tipo puede conseguirse de forma ventajosa que no queden perjudicados los líquidos a transportar por el lumen de los medios de trabajo médicos impidiéndose, además, interacciones como, por ejemplo, una difusión en las dos direcciones.For the inner layer of work media according to the invention, an ethylene copolymer and vinyl acetate with at least 10% vinyl acetate. Further, It is advantageous to use an ethylene methyl acrylate with at least one 10% methyl acrylate. Thanks to the use of polymeric materials this type can be obtained advantageously so that they are not left damaged liquids to be transported through the lumen of the media of medical work preventing, in addition, interactions such as example, a diffusion in the two directions.
En otra configuración ventajosa de los medios de trabajo sobre todo médicos según la invención se usa una poliolefina para la capa interior. Esto tiene la ventaja de que resulta una relación positiva entre precio y prestaciones para los medios de trabajo médicos a fabricar gracias a los precios del material.In another advantageous configuration of the means of work especially doctors according to the invention a polyolefin is used for the inner layer. This has the advantage that it results in a positive relationship between price and benefits for the media medical work to be manufactured thanks to the material prices.
En otra forma de realización ventajosa puede usarse un elastómero termoplástico para los medios de trabajo médicos, que puede ser, por ejemplo, del grupo de los polipropilenos modificados con elastómeros.In another advantageous embodiment it can use a thermoplastic elastomer for work media doctors, which may be, for example, from the group of polypropylenes modified with elastomers.
Este garantiza, a su vez, al igual que un elastómero termoplástico del grupo de los polietilenos modificados con elastómeros, que los medios de trabajo médicos tengan una elevada flexibilidad y al mismo tiempo una rigidez a la flexión suficiente y la resistencia a la dobladura necesaria. Gracias a distintas modificaciones de los elastómeros termoplásticos, los medios de trabajo médicos pueden adaptarse de forma óptima al caso de aplicación correspondiente, de modo que no quede cerrado, por ejemplo, el lumen de tubos flexibles, catéteres y similares en el caso de aplicación por una dobladura.This guarantees, in turn, like a thermoplastic elastomer of the group of modified polyethylenes with elastomers, that medical means of work have a high flexibility and at the same time a flexural rigidity sufficient and the necessary bending resistance. Thanks to different modifications of thermoplastic elastomers, Medical work means can be optimally adapted to the case corresponding application, so that it is not closed, by example, the lumen of flexible tubes, catheters and the like in the application case by a bend.
Debido a las posibilidades de combinación de las capas interiores y exteriores aquí es posible, a su vez, conseguir con los medios de trabajo médicos según la invención un ajuste de las propiedades adaptado a los requisitos específicos.Due to the combination possibilities of inner and outer layers here it is possible, in turn, to get with the medical work means according to the invention an adjustment of The properties adapted to the specific requirements.
Gracias al uso de copolímeros de estireno y
butadieno con al menos un 10% de estireno para la capa exterior de
los medios de trabajo médicos según la invención, pueden seguir
usándose las técnicas de confección y herramientas conocidas por el
estado de la técnica. La relación entre el precio y las
prestaciones de los medios de trabajo médicos fabricados de esta
manera destaca positivamente en comparación con los fabricados según
el estado de la técnica
conocido.Thanks to the use of styrene and butadiene copolymers with at least 10% styrene for the outer layer of the medical work media according to the invention, the manufacturing techniques and tools known in the state of the art can still be used. The relationship between the price and the benefits of medical work means manufactured in this way stands out positively compared to those manufactured according to the state of the art
known.
Gracias a la renuncia a materiales que contienen halógenos en la fabricación de los medios de trabajo médicos según la invención pueden resolverse, por un lado, los problemas conocidos de la eliminación de los desechos de los medios de trabajo médicos de este tipo, que es relevante después del primer uso, quedando excluidos, además, una posible migración de plastificantes y el riesgo para el paciente que va unido a ésta.Thanks to the resignation of materials that contain halogens in the manufacture of medical means of work according to the invention can solve, on the one hand, known problems of the disposal of waste from medical work facilities of this type, which is relevant after the first use, remaining excluded, in addition, a possible migration of plasticizers and the risk for the patient that is attached to it.
El marco de los medios de trabajo médicos según la invención comprende, además, que la capa interior y la capa exterior pueden fabricarse mediante el procedimiento de la coextrusión, pudiendo realizarse también procedimientos como barnizado, colada o inmersión para la fabricación de medios de trabajo médicos de este tipo.The framework of medical means of work according to the invention further comprises that the inner layer and the layer exterior can be manufactured by the procedure of the coextrusion, and procedures such as varnishing, casting or immersion for the manufacture of media I work doctors of this kind.
A continuación, se dará una explicación más detallada con ayuda de ejemplos de realización que no limitan la invención.Next, an explanation will be given. detailed with the help of embodiments that do not limit the invention.
Muestran:They show:
la figura 1, vista en corte a través de un tubo flexible de 2 capasFigure 1, sectional view through a tube flexible 2 layers
la figura 2, vista en corte a través de un tubo flexible de 3 capas.Figure 2, sectional view through a tube flexible 3 layers.
En la figura 1 está representado un corte transversal a través de un tubo flexible 2.A cut is shown in figure 1 transverse through a flexible tube 2.
Este tubo flexible, que puede usarse para catéteres, instrumentos para diálisis, drenajes, instrumentos para infusiones, etc., presenta una estructura tal que el lumen 4 del tubo flexible 1 está envuelto por una capa interior 3 de un copolímero de etileno y acetato de vinilo. Todo el contorno de la capa interior 3 está envuelto por una capa exterior 2, estando unidas la capa interior 3 y la capa exterior 2 en una pieza una con otra. En este ejemplo de realización, el grosor de pared de la capa exterior presenta aproximadamente 1/3 del grosor de pared de la capa interior 3.This flexible tube, which can be used for catheters, dialysis instruments, drains, instruments for infusions, etc., has a structure such that lumen 4 of the flexible tube 1 is wrapped by an inner layer 3 of a copolymer of ethylene and vinyl acetate. All the contour of the inner layer 3 is wrapped by an outer layer 2, being joined the inner layer 3 and the outer layer 2 in one piece with other. In this exemplary embodiment, the wall thickness of the layer exterior presents approximately 1/3 of the wall thickness of the layer interior 3.
En la figura 2 está representada la vista en corte a través de un tubo 1 de los medios de trabajo médicos según la invención. El lumen 4 está envuelto por una capa interior 3 de un polietileno estando aplicada en todo el contorno de la capa interior 3 una capa intermedia 5 de un copolímero de etileno y acetato de vinilo. Esta capa intermedia 5 presenta aproximadamente un grosor de pared de ¼ de la capa interior 3 y sirve, además, como capa adhesiva respecto a la capa exterior 2. La capa exterior 2 también está aplicada en todo el contorno de la capa intermedia 5, estando unidas la capa interior 3, la capa intermedia 5 y la capa exterior 2 de forma fija e inseparable entre sí.Figure 2 shows the view in cut through a tube 1 of the medical means of work according to the invention. Lumen 4 is wrapped by an inner layer 3 of a polyethylene being applied throughout the contour of the inner layer 3 an intermediate layer 5 of an ethylene acetate copolymer of vinyl. This intermediate layer 5 has approximately a thickness of ¼ wall of inner layer 3 and also serves as an adhesive layer with respect to the outer layer 2. The outer layer 2 is also applied throughout the contour of intermediate layer 5, being joined the inner layer 3, the intermediate layer 5 and the outer layer 2 of fixed and inseparable form each other.
Claims (2)
po:1. Catheters, flexible tubes or tubes for use in medicine, formed by a material composed of layers of halogen-free polymeric materials, free of plasticizers, serving the inner layer at the same time as an adhesive layer and selecting the inner layer of the gru -
po:
- --
- copolímeros de etileno y acetato de vinilo con un contenido de al menos 10% de acetato de vinilo,copolymers of ethylene acetate vinyl with a content of at least 10% acetate vinyl,
- --
- copolímeros de etileno y acrilato de metilo con un contenido de al menos 10% de acrilato de metilo,copolymers of ethylene and acrylate methyl with a content of at least 10% acrylate of methyl,
- --
- polipropileno modificado con elastómeros,modified polypropylene with elastomers,
- --
- polietileno modificado con elastómeros,modified polyethylene with elastomers,
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE10014248 | 2000-03-22 | ||
| DE10014248A DE10014248A1 (en) | 2000-03-22 | 2000-03-22 | Medical tools |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| ES2263522T3 true ES2263522T3 (en) | 2006-12-16 |
Family
ID=7635926
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| ES01104970T Expired - Lifetime ES2263522T3 (en) | 2000-03-22 | 2001-03-01 | WORK MEDIA EXEMPT PVC AND PLASTIFICANTS. |
Country Status (5)
| Country | Link |
|---|---|
| EP (1) | EP1136086B1 (en) |
| AT (1) | ATE327784T1 (en) |
| DE (2) | DE10014248A1 (en) |
| DK (1) | DK1136086T3 (en) |
| ES (1) | ES2263522T3 (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP4386738B2 (en) * | 2002-03-20 | 2009-12-16 | ガンブロ・ルンディア・エービー | Medical tubes and circuits incorporating these tubes |
| US20130190714A1 (en) | 2012-01-19 | 2013-07-25 | Tekni-Plex, Inc | Multi-layered tubing |
| CN105088806A (en) * | 2015-09-05 | 2015-11-25 | 四川大学 | Artificial leather manufacturing method adopting TPU (thermoplastic urethane) to plasticize PVC (polyvinyl chloride) and reducing use of plasticizer |
| KR102137709B1 (en) * | 2018-06-26 | 2020-07-24 | (의료)길의료재단 | Endotracheal intubation tube with flexible in region of body temperature |
Family Cites Families (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2480167A1 (en) * | 1980-04-15 | 1981-10-16 | Framatome Sa | DEVICE FOR SUPPORTING AND MOVING A TOOL WITHIN A FITTING |
| DE3204762C2 (en) * | 1982-02-11 | 1986-02-06 | REHAU AG + Co, 8673 Rehau | Technical accessories for medical equipment |
| EP0420488B1 (en) * | 1989-09-25 | 1993-07-21 | Schneider (Usa) Inc. | Multilayer extrusion as process for making angioplasty balloons |
| US5356709A (en) * | 1992-05-14 | 1994-10-18 | Baxter International, Inc. | Non-PVC coextruded medical grade port tubing |
| DE4216516A1 (en) * | 1992-05-19 | 1993-11-25 | Karl Haaga | Catheter tube with good transparency - comprising inner layer of HDPE, outer layer of thermoplastic pref. LDPE and opt. intermediate layer of thermoplastic of specified densities |
| EP0712354B1 (en) * | 1993-08-06 | 1999-01-13 | Minnesota Mining And Manufacturing Company | Multilayered tubing |
| DE19504414C2 (en) * | 1995-02-10 | 1996-12-05 | Pharmacia Gmbh | Hose for a medical container |
| DE19534455C1 (en) * | 1995-09-16 | 1996-12-12 | Fresenius Ag | Multilayer plastics tube free from PVC, for medical purposes |
| DE19534413C1 (en) * | 1995-09-16 | 1997-05-28 | Fresenius Ag | Connection arrangement and method for connecting two individual parts of a medical system |
-
2000
- 2000-03-22 DE DE10014248A patent/DE10014248A1/en not_active Ceased
-
2001
- 2001-03-01 EP EP01104970A patent/EP1136086B1/en not_active Expired - Lifetime
- 2001-03-01 AT AT01104970T patent/ATE327784T1/en active
- 2001-03-01 ES ES01104970T patent/ES2263522T3/en not_active Expired - Lifetime
- 2001-03-01 DE DE50109912T patent/DE50109912D1/en not_active Expired - Lifetime
- 2001-03-01 DK DK01104970T patent/DK1136086T3/en active
Also Published As
| Publication number | Publication date |
|---|---|
| EP1136086B1 (en) | 2006-05-31 |
| EP1136086A2 (en) | 2001-09-26 |
| ATE327784T1 (en) | 2006-06-15 |
| EP1136086A3 (en) | 2003-07-16 |
| DE50109912D1 (en) | 2006-07-06 |
| DE10014248A1 (en) | 2001-10-18 |
| DK1136086T3 (en) | 2006-10-02 |
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