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ES2065130T3 - Un catalizador para induccion asimetrica. - Google Patents

Un catalizador para induccion asimetrica.

Info

Publication number
ES2065130T3
ES2065130T3 ES92302120T ES92302120T ES2065130T3 ES 2065130 T3 ES2065130 T3 ES 2065130T3 ES 92302120 T ES92302120 T ES 92302120T ES 92302120 T ES92302120 T ES 92302120T ES 2065130 T3 ES2065130 T3 ES 2065130T3
Authority
ES
Spain
Prior art keywords
hydrogen
catalyst
bencil
phenyl
asymmetric induction
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Lifetime
Application number
ES92302120T
Other languages
English (en)
Inventor
Atsunori Mori
Shohei Inoue
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Sumitomo Chemical Co Ltd
Original Assignee
Sumitomo Chemical Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sumitomo Chemical Co Ltd filed Critical Sumitomo Chemical Co Ltd
Application granted granted Critical
Publication of ES2065130T3 publication Critical patent/ES2065130T3/es
Anticipated expiration legal-status Critical
Expired - Lifetime legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C253/00—Preparation of carboxylic acid nitriles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0201—Oxygen-containing compounds
    • B01J31/0211—Oxygen-containing compounds with a metal-oxygen link
    • B01J31/0212—Alkoxylates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0241—Imines or enamines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/0234—Nitrogen-, phosphorus-, arsenic- or antimony-containing compounds
    • B01J31/0235—Nitrogen containing compounds
    • B01J31/0245—Nitrogen containing compounds being derivatives of carboxylic or carbonic acids
    • B01J31/0247—Imides, amides or imidates (R-C=NR(OR))
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/30—Addition reactions at carbon centres, i.e. to either C-C or C-X multiple bonds
    • B01J2231/34—Other additions, e.g. Monsanto-type carbonylations, addition to 1,2-C=X or 1,2-C-X triplebonds, additions to 1,4-C=C-C=X or 1,4-C=-C-X triple bonds with X, e.g. O, S, NH/N
    • B01J2231/341—1,2-additions, e.g. aldol or Knoevenagel condensations
    • B01J2231/342—Aldol type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues, to aldehydes or ketones
    • B01J2231/343—Aldol type reactions, i.e. nucleophilic addition of C-H acidic compounds, their R3Si- or metal complex analogues, to aldehydes or ketones to prepare cyanhydrines, e.g. by adding HCN or TMSCN
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07B—GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
    • C07B2200/00—Indexing scheme relating to specific properties of organic compounds
    • C07B2200/07—Optical isomers

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)

Abstract

CATALIZADORES PARA LA PRODUCCION DE CIANHIDRINAS OPTICAMENTE ACTIVAS MEDIANTE LA ADICION DE CIANURO DE HIDROGENO A ALDEHIDOS QUE SE COMPONEN DE UN ALCOXIDO DE TITANIO (IV) Y UN DERIVADO DE DIPEPTIDO DE FORMULA (I) DONDE R1 ES ISOPROPILO, ISOBUTILO, SEC-BUTILO, TERC-BUTILO, METILO, BENCILO O FENILO, R3 ES UN ALKOXI INFERIOR, HIDROXILO O MONOR, Y ADEMAS R4 ES HIDROGENO Y R2 ES BENCILO, INDOL-3-ILMETILO, ISOPROPILO, ISOBUTILO O FENILO, O R2 Y R4 JUNTOS FORMAN -CH2-CH=CH Y CADA UNO ES HIDROGENO, HALOGENO, ALKILO INFERIOR O ALCOHOXILO INFERIOR, O R5 Y R6 O R6 Y R7, O R7 Y R8 JUNTOS FORMAN -CH=CH-CH=CH TIENE UNA CONFIGURACION ABSOLUTA DE S O R.
ES92302120T 1991-03-12 1992-03-12 Un catalizador para induccion asimetrica. Expired - Lifetime ES2065130T3 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
JP4648291 1991-03-12

Publications (1)

Publication Number Publication Date
ES2065130T3 true ES2065130T3 (es) 1995-02-01

Family

ID=12748425

Family Applications (1)

Application Number Title Priority Date Filing Date
ES92302120T Expired - Lifetime ES2065130T3 (es) 1991-03-12 1992-03-12 Un catalizador para induccion asimetrica.

Country Status (6)

Country Link
US (1) US5288682A (es)
EP (1) EP0505089B1 (es)
CA (1) CA2062233A1 (es)
DE (1) DE69200875T2 (es)
ES (1) ES2065130T3 (es)
HU (1) HU212630B (es)

Family Cites Families (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
NZ206106A (en) * 1982-11-22 1987-10-30 Shell Oil Co Processes for the preparation of optically active cyanomethyl esters of alpha-chiral carboxylic acids and optionally substituted s-alpha-cyano-3-phenoxybenzyl alcohol
JPH064578B2 (ja) * 1986-12-15 1994-01-19 鐘淵化学工業株式会社 光学活性シアノ化合物の製造方法
US5118665A (en) * 1990-02-09 1992-06-02 Procyte Corporation Anti-oxidative and anti-inflammatory metal:peptide complexes and uses thereof

Also Published As

Publication number Publication date
DE69200875T2 (de) 1995-04-20
DE69200875D1 (de) 1995-01-26
EP0505089A1 (en) 1992-09-23
HU212630B (en) 1996-09-30
EP0505089B1 (en) 1994-12-14
HU9200835D0 (en) 1992-05-28
US5288682A (en) 1994-02-22
CA2062233A1 (en) 1992-09-13
HUT61257A (en) 1992-12-28

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