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EP3425005A4 - Composition de résine époxy, matériau de moulage et matériau composite renforcé par des fibres - Google Patents

Composition de résine époxy, matériau de moulage et matériau composite renforcé par des fibres Download PDF

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Publication number
EP3425005A4
EP3425005A4 EP17759987.5A EP17759987A EP3425005A4 EP 3425005 A4 EP3425005 A4 EP 3425005A4 EP 17759987 A EP17759987 A EP 17759987A EP 3425005 A4 EP3425005 A4 EP 3425005A4
Authority
EP
European Patent Office
Prior art keywords
fiber
resin composition
epoxy resin
reinforced composite
composite material
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
EP17759987.5A
Other languages
German (de)
English (en)
Other versions
EP3425005B1 (fr
EP3425005A1 (fr
Inventor
Akira Oota
Masahiro Ichino
Takuya Teranishi
Mitsuru Kutsuwada
Yusuke Watanabe
Natsumi Mukouzaka
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Mitsubishi Chemical Corp
Original Assignee
Mitsubishi Chemical Corp
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Mitsubishi Chemical Corp filed Critical Mitsubishi Chemical Corp
Publication of EP3425005A1 publication Critical patent/EP3425005A1/fr
Publication of EP3425005A4 publication Critical patent/EP3425005A4/fr
Application granted granted Critical
Publication of EP3425005B1 publication Critical patent/EP3425005B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

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Classifications

    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/22Di-epoxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32Epoxy compounds containing three or more epoxy groups
    • C08G59/3227Compounds containing acyclic nitrogen atoms
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/10Reinforcing macromolecular compounds with loose or coherent fibrous material characterised by the additives used in the polymer mixture
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/20Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the epoxy compounds used
    • C08G59/32Epoxy compounds containing three or more epoxy groups
    • C08G59/38Epoxy compounds containing three or more epoxy groups together with di-epoxy compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/5026Amines cycloaliphatic
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/50Amines
    • C08G59/56Amines together with other curing agents
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/04Reinforcing macromolecular compounds with loose or coherent fibrous material
    • C08J5/0405Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres
    • C08J5/042Reinforcing macromolecular compounds with loose or coherent fibrous material with inorganic fibres with carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/241Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres
    • C08J5/243Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs using inorganic fibres using carbon fibres
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/24Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs
    • C08J5/249Impregnating materials with prepolymers which can be polymerised in situ, e.g. manufacture of prepregs characterised by the additives used in the prepolymer mixture
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L63/00Compositions of epoxy resins; Compositions of derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G59/00Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
    • C08G59/18Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing
    • C08G59/40Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups ; e.g. general methods of curing characterised by the curing agents used
    • C08G59/4007Curing agents not provided for by the groups C08G59/42 - C08G59/66
    • C08G59/4014Nitrogen containing compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2363/00Characterised by the use of epoxy resins; Derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/02Elements
    • C08K3/04Carbon
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/16Nitrogen-containing compounds
    • C08K5/17Amines; Quaternary ammonium compounds
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00Use of ingredients characterised by shape
    • C08K7/02Fibres or whiskers

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  • Chemical & Material Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Organic Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Inorganic Chemistry (AREA)
  • Reinforced Plastic Materials (AREA)
  • Epoxy Resins (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
EP17759987.5A 2016-02-29 2017-02-28 Composition de résine époxy, matériau de moulage et matériau composite renforcé par des fibres Active EP3425005B1 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
JP2016038205 2016-02-29
PCT/JP2017/007755 WO2017150521A1 (fr) 2016-02-29 2017-02-28 Composition de résine époxy, matériau de moulage et matériau composite renforcé par des fibres

Publications (3)

Publication Number Publication Date
EP3425005A1 EP3425005A1 (fr) 2019-01-09
EP3425005A4 true EP3425005A4 (fr) 2019-03-13
EP3425005B1 EP3425005B1 (fr) 2020-08-12

Family

ID=59742915

Family Applications (1)

Application Number Title Priority Date Filing Date
EP17759987.5A Active EP3425005B1 (fr) 2016-02-29 2017-02-28 Composition de résine époxy, matériau de moulage et matériau composite renforcé par des fibres

Country Status (5)

Country Link
US (1) US10920027B2 (fr)
EP (1) EP3425005B1 (fr)
JP (2) JP6292345B2 (fr)
CN (1) CN108603009B (fr)
WO (1) WO2017150521A1 (fr)

Families Citing this family (18)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP6708256B2 (ja) * 2017-04-12 2020-06-10 三菱ケミカル株式会社 シートモールディングコンパウンド、および繊維強化複合材料
WO2018236455A1 (fr) * 2017-06-20 2018-12-27 Dow Global Technologies Llc Système de résine époxy pour produire des composites renforcés de fibres
EP3663338A4 (fr) * 2017-07-31 2021-07-07 Toray Industries, Inc. Mélange pour le moulage en feuille, préimprégné et matériau composite renforcé par des fibres
CN109206646A (zh) * 2018-08-14 2019-01-15 艾达索高新材料芜湖有限公司 一种可降解环氧短切碳纤维毡预浸料及其生产工艺
ES2971016T3 (es) * 2018-09-05 2024-06-03 Mitsubishi Chem Corp Compuesto para el moldeo de láminas y material compuesto reforzado con fibra
WO2020054340A1 (fr) * 2018-09-10 2020-03-19 東レ株式会社 Composition de résine époxy, matériau de moulage destiné à un matériau composite renforcé par des fibres et matériau composite renforcé par des fibres
JP6835253B2 (ja) * 2018-10-05 2021-02-24 三菱ケミカル株式会社 シートモールディングコンパウンド、シートモールディングコンパウンドの製造方法、繊維強化複合材料、繊維強化複合材料の製造方法
EP3868815A4 (fr) * 2018-10-16 2021-12-15 Mitsubishi Chemical Corporation Composé de moulage de feuille et article moulé
CN110079049B (zh) * 2018-10-25 2022-01-07 比亚迪股份有限公司 一种片状模塑料树脂组合物、片状模塑料及其制备方法
JP7230433B2 (ja) * 2018-10-30 2023-03-01 三菱ケミカル株式会社 エポキシ樹脂組成物、成形材料の製造方法、成形材料、繊維強化複合材料及び繊維強化複合材料の製造方法
EP3978572A4 (fr) * 2019-05-28 2023-05-24 DIC Corporation Matériau de moulage, composé de moulage en feuille et article moulé
US20230016883A1 (en) * 2019-11-25 2023-01-19 Dic Corporation Methods for producing sheet molding compound and for producing molded product
CN112048156A (zh) * 2020-07-28 2020-12-08 艾达索高新材料芜湖有限公司 一种环氧smc树脂
CN112048154A (zh) * 2020-07-28 2020-12-08 艾达索高新材料芜湖有限公司 一种环氧玻纤smc片料及其制备方法
JP7040683B1 (ja) 2020-09-15 2022-03-23 三菱瓦斯化学株式会社 エポキシ樹脂硬化剤、エポキシ樹脂組成物、及びアミン組成物の使用
CN116348518A (zh) * 2020-10-22 2023-06-27 三菱化学株式会社 电沉积涂装品的制造方法、预浸料和环氧树脂组合物
CN112358633B (zh) * 2020-10-23 2022-05-10 广州市聚欣盈复合材料科技股份有限公司 一种碳布-环氧树脂复合材料及其制备方法与应用
EP4410876A4 (fr) * 2021-09-29 2025-01-15 Mitsubishi Chem Corp Procédé de production de préimprégné et préimprégné

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DE3827626A1 (de) 1988-08-10 1990-03-08 Teroson Gmbh Reaktiver schmelzklebstoff
JPH0288684A (ja) 1988-09-27 1990-03-28 Nitto Denko Corp 接着方法及びそれに使用する液状接着剤
JPH02286722A (ja) 1989-04-28 1990-11-26 Dainippon Ink & Chem Inc 含浸用樹脂組成物、プリプレグ、及び積層板の製法
JPH0488011A (ja) 1990-07-31 1992-03-19 Sumitomo Chem Co Ltd エポキシ樹脂組成物
US5350779A (en) * 1991-12-19 1994-09-27 Hughes Aircraft Company Low exotherm, low temperature curing, epoxy impregnants
CN101735570A (zh) * 2009-11-19 2010-06-16 东方电气集团东方汽轮机有限公司 风力发电机叶片用的环氧树脂体系及其改性方法
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CN102040805A (zh) * 2010-12-23 2011-05-04 东方电气集团东方汽轮机有限公司 一种用于制造风力发电机叶片模具的环氧树脂体系及其制备方法
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Publication number Priority date Publication date Assignee Title
JPH06166742A (ja) * 1992-12-02 1994-06-14 Sumitomo Chem Co Ltd エポキシ樹脂組成物

Also Published As

Publication number Publication date
WO2017150521A1 (fr) 2017-09-08
US10920027B2 (en) 2021-02-16
JPWO2017150521A1 (ja) 2018-03-08
EP3425005B1 (fr) 2020-08-12
EP3425005A1 (fr) 2019-01-09
JP6292345B2 (ja) 2018-03-14
JP2018066026A (ja) 2018-04-26
US20200140633A1 (en) 2020-05-07
CN108603009A (zh) 2018-09-28
CN108603009B (zh) 2020-10-20

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