EP3077603A1 - A thermally-insulating composite elevation panel, a method of its preparation and a use of the thermally-insulating composite elevation panel - Google Patents
A thermally-insulating composite elevation panel, a method of its preparation and a use of the thermally-insulating composite elevation panelInfo
- Publication number
- EP3077603A1 EP3077603A1 EP14827539.9A EP14827539A EP3077603A1 EP 3077603 A1 EP3077603 A1 EP 3077603A1 EP 14827539 A EP14827539 A EP 14827539A EP 3077603 A1 EP3077603 A1 EP 3077603A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- elevation
- thermally
- board
- mould
- foam
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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Classifications
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/0875—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements having a basic insulating layer and at least one covering layer
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/02—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials
- E04C2/26—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups
- E04C2/284—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating
- E04C2/296—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by specified materials composed of materials covered by two or more of groups E04C2/04, E04C2/08, E04C2/10 or of materials covered by one of these groups with a material not specified in one of the groups at least one of the materials being insulating composed of insulating material and non-metallic or unspecified sheet-material
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04C—STRUCTURAL ELEMENTS; BUILDING MATERIALS
- E04C2/00—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels
- E04C2/30—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure
- E04C2/38—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure with attached ribs, flanges, or the like, e.g. framed panels
- E04C2/384—Building elements of relatively thin form for the construction of parts of buildings, e.g. sheet materials, slabs, or panels characterised by the shape or structure with attached ribs, flanges, or the like, e.g. framed panels with a metal frame
-
- E—FIXED CONSTRUCTIONS
- E04—BUILDING
- E04F—FINISHING WORK ON BUILDINGS, e.g. STAIRS, FLOORS
- E04F13/00—Coverings or linings, e.g. for walls or ceilings
- E04F13/07—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor
- E04F13/08—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements
- E04F13/14—Coverings or linings, e.g. for walls or ceilings composed of covering or lining elements; Sub-structures therefor; Fastening means therefor composed of a plurality of similar covering or lining elements stone or stone-like materials, e.g. ceramics concrete; of glass or with an outer layer of stone or stone-like materials or glass
Definitions
- thermally-insulating composite elevation panel A thermally-insulating composite elevation panel, a method of its preparation and a use of the thermally-insulating composite elevation panel
- the object of the present invention is a ready-to-use thermally-insulating composite elevation panel, a method of its preparation and the use of the thermally-insulating composite elevation panel for simultaneous mounting of the elevation and the thermal insulation of buildings.
- Elevation boards made of these materials have a thickness of 12 to 40 mm.
- the huge weight of these boards requires a system of grillages and mechanical slings capable of supporting the weight of up to 400 kg per 1 m 2 of elevation surface.
- a thermal insulation made of mineral wool or expanded polystyrene is shoved under the boards. It must, however, be steered clear of a fixing frame and of panel fixing hooks.
- thermal bridges are formed, which dramatically deteriorate insulation properties of building elevations.
- further improvements of the technology have been developed, which allows production of boards having a thickness of 2 mm. These boards can be dyed arbitrarily in sintering phase, and therefore highest aesthetic values can be obtained.
- the low thickness of this type of boards allowed further decrease in the weight and simplification of the system of mechanical slings.
- Ceramic boards having a thickness of 3 mm to 10 mm are currently attached on metal slings without integration with the thermally insulating material, in the ventilated system, where boards are mounted on a complex supporting substructure connected to a thermally insulating layer, by means of a permanent elastic adhesive. Elevation boards are bonded after mounting thermally insulating elements connected to the supporting substructure on building walls, by qualified personnel, according to recommendations and instructions of the supplier of adhesive system. Consequently, the effectiveness of mounting of panels by means of an adhesive depends mainly on atmospheric conditions during their mounting. Moisture, low temperature and dustiness may have a negative effect on bond strength of the adhesive.
- any effective method of connecting to either the supporting substructure or directly to the thermally insulating layer has not been developed so far. This is due to the fact that boards of such a thickness are too fragile and susceptible to damage so that they cannot be mounted on the supporting substructure by means of an adhesive system.
- all attempts to develop a technology of bonding directly to the layer of thermally insulating material were unsuccessful because the so thin boards, especially in the case of large-surface boards, after bonding, were subject to deformation in many different ways, due to the difference in thermal expansions of the materials connected, which resulted in a drastic decrease in the adhesion of the board to the thermally insulating material, and as a consequence in its falling off.
- the aim of the present invention was to develop a ready-to-use, thermally-insulating composite panel which simultaneously combines three elements:
- Another aim of the present invention was to develop a method for permanent connection of elevation boards with the layer of thermal insulation and with the system for attaching the panel, the method allowing to manufacture of ready-to-use, thermally-insulating composite elevation panels.
- the object of the present invention is a thermally-insulating composite elevation panel, characterised in that it comprises an elevation board and a frame, preferably a metal one, which are permanently connected to each other through an insulating layer, the insulating layer being constituted by a plastic foam which, during its foaming process, permanently connects the elevation panel with the frame.
- the elevation board is selected from the group comprising ceramic board, board of natural or artificial stone, glass board, board of metal or metal alloys, board of wood, board of wood or wood-iike veneer, fibre cement board, plasterboard and the like.
- the elevation board is constituted by a ceramic board.
- the elevation board has a thickness of 0.1 mm to 10 cm.
- the plastic foam is selected from the group comprising polyurethane foam, polyester foam, polystyrene foam or mixtures and composites of these foams, such as polystyrene polyurethane foam, PSUR.
- the plastic foam is constituted by polystyrene polyurethane foam, PSUR.
- the thickness of the insulating layer is of 4 to 25 cm, more preferably of 8 to 16 cm, and most preferably of 10 to 14 cm.
- Another object of the invention is a method of preparing a thermally-insulating composite elevation panel, characterised in that it comprises steps in which:
- the mould is closed with a board of high strength, to the surface of which a pre-made frame is mounted,
- a foam is dispensed to the mould, then the foam, while expanding, fills the interior of the mould and is left in the mould until the process of polymerisation and curing is completed,
- the mould is opened by lifting the cover and moving apart the side walls of the mould.
- a mould whose side walls are covered with a material which does not adhere to the polymerising foam such as Teflon, Tarflen, is used.
- opening of the mould is supported by an air pulse of a high pressure getting between the walls of the panel and the mould by means of channels formed in the walls of the mould.
- the prepared panels are then subjected to conditioning at a temperature of 10 to 30Ā°C for a period of 2 to 30 hours.
- the object of the invention is also a thermally-insulating composite elevation panel performed by the above-defined method.
- the invention relates also to the use of the thermally-insulating composite elevation panel according to the present invention for simultaneous mounting of elevations and thermal insulation of buildings, especially high buildings.
- thermally-insulating composite elevation panel according to the present invention is shown in the figure of the drawing, where:
- a thermally-insulating composite elevation panel according to the invention is illustrated in a perspective view
- thermally-insulating composite elevation panel according to the invention is illustrated in a sectional view taken along line A-A shown in Fig. 1 ;
- a thermally-insulating composite elevation panel according to the invention is prepared by a known process of low-pressure pouring, into the mould, of a mixture of raw materials for the formation of plastic foams, preferably of polyurethane, polyester, polystyrene foam or mixtures and composites of these foams, for example polystyrene polyurethane foam.
- plastic foams preferably of polyurethane, polyester, polystyrene foam or mixtures and composites of these foams, for example polystyrene polyurethane foam.
- an elevation board is placed at the bottom of the open mould made of known materials of high strength and rigidity, e.g. of steel or of cast iron, having a shape reflecting the target panel shape.
- the elevation board can be made of any known elevation materials.
- They can comprise ceramic boards, boards of natural or artificial stone, of glass, of metals or of wood, and wood or wood-like veneer, fibre cement boards, plasterboards and the like.
- the thickness and type of board needs to be chosen so that its weight per unit area does not cause stresses exceeding the strength of the thermally insulating foam used, the said strength being obtained upon completing the production process, which could, otherwise, cause damage to the foam, detachment of the elevation board, and its falling off from the panel. Calculation of the maximum thickness of the foam, meeting this condition, is made using known engineering methods.
- the minimum thickness of the elevation boards used is limited by aesthetic considerations associated with possible showing of the foam through the board layer.
- Thicknesses of the boards range from 0.1 mm for metal sheets up to 10 mm for fibre cement boards and other lightweight materials.
- the side walls of the mould are covered with a material not adhering to the polymerising foam, e.g. with Teflon, Tarflen etc.
- the mould is closed with a board of a high strength, selected, using known design principles, so that it could withstand the pressure of the expanding and polymerising foam.
- a pre-made metal frame is attached to the surface of the cover. The attaching is made by means of permanent magnets attached in the cover of the mould, or by other known methods.
- the foam is dispensed from the head of mixing and dispensing machines commonly available on the market.
- the interior of the mould is pre-heated to a temperature of 10 to 100 degrees Celsius.
- the thermally insulating foam while expanding, fills the interior of the mould, and adheres strongly to the elevation board, as well as to the frame thanks to adhesion forces.
- the foam remains in the mould until the process of polymerisation and curing is completed.
- the process of polymerisation and curing having been completed, the mould is opened by lifting the cover and moving apart the side walls of the mould. This process is supported by an air pulse of a high pressure getting between the walls of the panel and the mould by means of small channels pre-formed in the walls of the mould. After removing from the mould and cooling down to ambient temperature, the thermally- insulating composite elevation panel is ready for use.
- the solution proposed by the present inventors is a thermally-insulating composite elevation panel consisting of three elements which fulfil three separate functions.
- the first element is a metal framework, preferably lightweight and of steel, which is a supporting structure and, at the same time, an element of the system for attaching the panel on the building wall.
- the second element is elevation boards, such as ceramic boards, boards of natural or artificial stone, of glass, of metals or of wood, and of wood or woodlike veneer, fibre cement boards, plasterboards and the like, preferably ceramic boards, for example such as the boards produced by Italian company Laminam S.P.A.
- the choice of ceramic boards, as those preferred ones, results from the specific characteristics of this material.
- the surface of these boards is very hard and resistant to mechanical scratches, and completely chemically passive.
- the ceramic boards make them resistant to atmospheric conditions and allow for easy cleaning (resistance to graffiti).
- the ceramic boards of this type are characterised by a close to zero absorbability and thereby by a complete frost resistance. At the same time, they are a great decorative material, with exceptional aesthetic value.
- the element that unites the metal frame and the elevation boards is the third component - a layer of insulating material, such as polyurethane foam, polyester foam, polystyrene foam or mixtures and composites of these foams, for example polystyrene polyurethane foam, PSUR.
- insulating material such as polyurethane foam, polyester foam, polystyrene foam or mixtures and composites of these foams, for example polystyrene polyurethane foam, PSUR.
- a particularly preferred insulation material is polystyrene polyurethane foam, hereinafter referred to as PSUR.
- PSUR polystyrene polyurethane foam
- This material is a composite consisting of two plastic materials: rigid polyurethane foam (PUR) and expanded polystyrene (EPS). It is their physical mixture.
- these three components are connected in a single process: as a result of pressing, bonding and simultaneous cross-linking of polyurethane foam and expansion of polystyrene, there is a very durable connection of the elevation board with the system of mechanical slings and with the thermally insulating material, PSUR.
- Construction of a prototype for the thermally insulating panel by the present inventors confirmed the possibility of integration, in a single process (in a single step), of three different materials, such as steel, ceramic board and insulation material.
- a key element was the choice of PSUR composite as a material connecting ceramic boards with the system of mechanical slings.
- This composite is one of very few polymeric materials, which is also a thermally insulating material, a construction material, with very good mechanical properties, and has, at the moment of formation, excellent adhesion properties allowing connection of the composite material into a single whole.
- PSUR composite created the possibility to permanently connect a steel supporting framework with a ceramic board in a single process - during the synthesis of polyurethane foam and the expansion of polystyrene granulate.
- PSUR composite is a much cheaper material than rigid polyurethane foams, which is an equally important fact and very significant for the building materials market.
- the proposed solution is therefore unique, so far unheard of among other manufacturers of construction materials.
- This is a solution thanks to which it will be possible to introduce, for the first time, on the global market of construction materials, a panel simultaneously consisting of a attaching system, an insulating layer and a ceramic board of a small thickness, for example 2 and 3 mm, allowing the creation of everlasting elevations of buildings, with a very attractive appearance and excellent utility parameters.
- EPS expanded polystyrene
- the coefficient of thermal conductivity of EPS depends on density and technology of its production, and varies between 0.032-0.042 W/mK, (Elzbieta Radziszewska-Zielina: Przeglad Budowlany, 4/2009).
- Rigid polyurethane foam does not have all of the disadvantages mentioned for EPS boards. It is an excellent thermal insulation material, also characterized by very good mechanical properties. Its density is similar to EPS, while the thermal conductivity coefficient of PUR is comprised in the range of 0.023 W/mK (closed cells) to 0.035 W/mK (open cell foam). Despite all of these advantages, the use of this material in the construction industry is limited by its price. The cost of boards made of rigid polyurethane foam is several times higher than for analogous boards of expanded polystyrene. It is the cost of this type of insulation that greatly limits its use in housing construction, (Elzbieta Radziszewska-Zielina: Przeglad Budowlany, 4/2009).
- PSUR Composite polymeric material
- PSUR is a combination of two plastic materials, the characteristics of which are described above. It is a new material with special characteristics, which in the future, will be widely used in technologies of insulation and construction materials. This material was developed by Polish company HIT Konsulting, and the process for the preparation of the composite has been applied for patent protection in a series of patent applications (PL387535, PL395886, PL396151 , PL396152).
- Preparation of PSUR consists in simultaneous synthesis and cross-linking of rigid polyurethane foam (two component process) and co-foaming (co-expansion) of polystyrene granulate, used for the production of expanded polystyrene.
- the thus obtained material is therefore a mixture of two plastic materials, and a composite exhibiting emergent characteristics not present separately in each of the components which constitute the target product.
- the composite of polyurethane and polystyrene, obtained in the process of simultaneous cross-linking and co-foaming, is an excellent adhesive material, closely adjacent to porous coatings (brick, concrete, natural and artificial stone, ceramics) but also to the metal supporting framework. It is this property of the material, combined with the process of simultaneous pressing at an elevated temperature in the preparation of the composite thermally insulating panel according to the invention, which allows its use as a material bonding the steel system of slings and the ceramic board to each other. In this way, gaps are not formed, which could otherwise be penetrated by rain water or water condensing in conditions of high humidity. Furthermore, the phenomenon of water approaching the gaps, which poses a risk of loosening of elevation tiles, as a result of freezing during the winter season, is not observed.
- rigid polyurethane foam is the matrix of PSUR, this material generally retains its excellent properties: it is mechanically stable, does not crack and does not crumble. At the same time, it has appropriate structural properties allowing the mounting of ceramic elevation boards, not as ventilated fagades, but as boards which are bonded and mounted directly on the exterior walls of insulated buildings.
- PSUR composite is characterised by a low coefficient of moisture absorption. Consequently, any significant diffusion of moisture to the outer insulation layers does not occur. In the winter period, freezing out of water in the closed cells of insulating foam does not occur. As a result, the proposed structure of elevation panel integrated with thermal insulation of PSUR material is not exposed to destructive effects of water being frozen out. Therefore, deterioration of thermal insulation due to water absorption in the insulating layer and possibility of loosening of the outer ceramic layer does not occur.
- PSUR composite material is based on cross-linked polyurethane plastic material, it is also very resistant chemically. This makes it possible to use a variety of very strongly binding industrial adhesives, e.g. at the time of bonding of this material to the building wall or bonding of individual panels to each other during mounting of the elevation.
- the composite structure of PSUR material results in the material having good parameters for acoustic attenuation. It attenuates sounds much better than single-phase materials, i.e. expanded polystyrene and polyurethane foam. Only mineral wool is better in this area.
- thermally insulating material PSUR is a flammable material in class:
- fire retardant panels of this type are of high fire resistance class because their mounting ensures the absence of oxygen reaching the insulating material.
- the polyurethane matrix annealing at a temperature above 140Ā°C, does not disintegrate, but forms specific slag which continues to be able to maintain the outer ceramic layer due to its low thickness and therefore also its low weight. This in turn continues to cut off the thermal insulation from oxygen supply and ensures safety during a possible rescue or fire fighting operation.
- PSUR composite due to its mechanical and chemical properties, is resistant to various kinds of microorganisms, fungus and rodents.
- Fire resistance class fire Low weight of the ceramic boards ensures that El 60 (for high
- the present inventors have produced a prototype of the thermally-insulating composite elevation panel. Construction of a suitable mould and production of such a panel was a significant construction and technological challenge, but by doing so it was demonstrated that it is possible to produce, in a single step, a thermally-insulating composite elevation panel, consisting of a system of mechanical slings, an elevation board and a layer of composite thermally insulating material which is, at the same time, a construction and thermally insulating material which bonds individual elements.
- thermally-insulating elevation panels are attached to building walls by means of expansion bolts. Structure of the system of mechanical slings allows position adjustments of individual panels relative to the wall and relative to consecutive elements of the elevation.
- the individual elements of the fagade - thermally-insulating elevation panels are not bonded to each other but only connected by scarf joint - successive panels overlap one another. Between the building wall and the rear wall of the panel, a gap of 1 cm is maintained, which can be filled with a light polyurethane foam.
- Such a solution allows arranging the thermally-insulating elevation panels on the building with an uneven wall surface and prevents formation of thermal bridges at the joints of individual boards.
- welds between individual boards of the elevation panels are grouted and sealed with suitable adhesive masses.
- a layer of PSUR thermally insulating material of 10-14 cm, and especially of 12 cm corresponds to a layer of expanded polystyrene of about 15-20 cm used in energy-efficient houses;
- Very low moisture absorption increase in the durability of the building by avoiding of insulation degradation and spalling or detachment of elevation boards due to freezing and freezing out of water condensing in the dew zone and longer period of exploitation.
- the thermally-insulating composite elevation panel according to the present invention is shown in Fig. 1 and in Fig. 2.
- the panel consists of a ceramic elevation board 1 having a thickness of 3 mm, a width of 50 cm and a height of 150 cm, a steel frame 3 having a structure shown in Fig. 1 and in Fig. 2, which are connected to each other by means a bonding layer of foamed PSUR material 3 having a thickness of 12 cm.
- This panel was prepared as follows:
- Laminam ceramic board 1 of the above dimensions was placed at the bottom of the open steel mould. Side walls of the mould were coated with Teflon.
- the mould was closed with a cover having a high strength, to the surface of which a pre-formed steel frame, shown in Fig. 2, was mounted by means of permanent magnets.
- the foam was dispensed from the head of a mixing and dispensing machine.
- the interior of the mould was pre-heated to a temperature of about 50 degrees Celsius.
- the foam was left in the mould until the process of polymerisation and curing was completed.
- the mould was opened by lifting the cover and moving apart the side walls of the mould. This process was supported by an air pulse of a high pressure getting between the walls of the panel and the mould by means of small channels pre-formed in the walls of the mould. After removing from the mould and cooling down to ambient temperature, the thermally-insulating composite elevation panel was ready for use.
- thermally-insulating composite elevation panel was subjected to flammability tests according to standard procedure of Building Research Institute, Warsaw.
- the object of the test was an elevation panel made of Laminam board integrated with an insulation made of PSUR material.
- Laminam board 1500 x 500 x 3 mm
- PSUR insulation 1510 x 510 x 120 mm
- the test stand imitated a window with the test panel placed above the window.
- the flammability test imitated a natural fire inside a building, near the window. It was assumed that burning time will be 30 minutes which is sufficient to obtain a certificate allowing for use in the construction industry.
- the fire was produced by burning a measured amount of wood so as to obtain an energy pulse, provided for by the procedure, and a predetermined amount of heat. Dry birch wood was used for burning. During burning, it turned out that this amount of wood was not sufficient to sustain the fire throughout the testing period. For this reason, an additional portion of wood was added after 15 minutes, and then yet another portion after 30 minutes of the test.
- Rear wall and side walls of the panel were insulated with mineral wool to prevent direct burning of PSUR insulating material. The outside temperature was about 10Ā°C.
- Conbest pyrometer testo 845 model
- Thermographic cameras, V20 and V50 models, used for low and high temperature measurements were used to study the temperature distribution. Course of the process was documented with photographic images and filmed.
- thermograms reflected temperature distribution on the surface of the panel tested.
- the rear side of the panel did not show any significant increase in temperature which reached a maximum of about 20Ā°C.
- the maximum temperature was obtained at the lower edge of the board and it reached 485.2Ā°C.
- Fig. 3 a photograph of the panel cut along its centre line is shown, on which it is clear that the fire did not spread to the inside of the panel, only an outer layer of PSUR material charred, which however did not lead to destruction of the panel, loosening of the metal frame and separation of the outer layer of the elevation. Though a high temperature gradient caused rupture of the surface of the ceramic board, falling off of any fragments thereof from the panel was not observed, due to its strong adhesion to the insulating material.
- Fig. 4 a cross-section of the panel with an indication of its individual components is shown.
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- Architecture (AREA)
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Abstract
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Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
PL406346A PL230119B1 (en) | 2013-12-03 | 2013-12-03 | Composite facade insulating cladding, method for producing it and application of the composite facade insulating cladding |
PCT/IB2014/066528 WO2015083084A1 (en) | 2013-12-03 | 2014-12-02 | A thermally-insulating composite elevation panel, a method of its preparation and a use of the thermally-insulating composite elevation panel |
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EP3077603A1 true EP3077603A1 (en) | 2016-10-12 |
EP3077603B1 EP3077603B1 (en) | 2020-02-05 |
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EP14827539.9A Active EP3077603B1 (en) | 2013-12-03 | 2014-12-02 | A thermally-insulating composite elevation panel, a method of its preparation and a use of the thermally-insulating composite elevation panel |
Country Status (4)
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EP (1) | EP3077603B1 (en) |
PL (1) | PL230119B1 (en) |
RU (1) | RU2651850C1 (en) |
WO (1) | WO2015083084A1 (en) |
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- 2014-12-02 EP EP14827539.9A patent/EP3077603B1/en active Active
- 2014-12-02 RU RU2016125015A patent/RU2651850C1/en active
- 2014-12-02 WO PCT/IB2014/066528 patent/WO2015083084A1/en active Application Filing
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Also Published As
Publication number | Publication date |
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EP3077603B1 (en) | 2020-02-05 |
PL406346A1 (en) | 2015-06-08 |
WO2015083084A1 (en) | 2015-06-11 |
PL230119B1 (en) | 2018-09-28 |
RU2651850C1 (en) | 2018-04-24 |
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