EP1935280A1 - Method for dispensing a product sprayed by a piezoelectric spraying system and spraying system for implementing such a method - Google Patents
Method for dispensing a product sprayed by a piezoelectric spraying system and spraying system for implementing such a method Download PDFInfo
- Publication number
- EP1935280A1 EP1935280A1 EP07123781A EP07123781A EP1935280A1 EP 1935280 A1 EP1935280 A1 EP 1935280A1 EP 07123781 A EP07123781 A EP 07123781A EP 07123781 A EP07123781 A EP 07123781A EP 1935280 A1 EP1935280 A1 EP 1935280A1
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- EP
- European Patent Office
- Prior art keywords
- product
- chamber
- spraying
- piezoelectric
- pump
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000000034 method Methods 0.000 title claims abstract description 29
- 238000005507 spraying Methods 0.000 title claims description 63
- 239000012528 membrane Substances 0.000 claims abstract description 13
- 239000000203 mixture Substances 0.000 claims abstract description 8
- 230000000007 visual effect Effects 0.000 claims abstract description 5
- 238000004891 communication Methods 0.000 claims abstract description 4
- 239000002537 cosmetic Substances 0.000 claims abstract description 4
- 230000008878 coupling Effects 0.000 claims description 16
- 238000010168 coupling process Methods 0.000 claims description 16
- 238000005859 coupling reaction Methods 0.000 claims description 16
- 239000007921 spray Substances 0.000 claims description 10
- 230000000977 initiatory effect Effects 0.000 claims 1
- 238000004544 sputter deposition Methods 0.000 claims 1
- 238000010298 pulverizing process Methods 0.000 abstract 11
- 238000007599 discharging Methods 0.000 abstract 2
- 210000000056 organ Anatomy 0.000 abstract 1
- 239000000919 ceramic Substances 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 2
- 239000004020 conductor Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000005684 electric field Effects 0.000 description 2
- 238000005868 electrolysis reaction Methods 0.000 description 2
- 230000005284 excitation Effects 0.000 description 2
- 238000009472 formulation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000002245 particle Substances 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 1
- 239000000443 aerosol Substances 0.000 description 1
- JRPBQTZRNDNNOP-UHFFFAOYSA-N barium titanate Chemical compound [Ba+2].[Ba+2].[O-][Ti]([O-])([O-])[O-] JRPBQTZRNDNNOP-UHFFFAOYSA-N 0.000 description 1
- 229910002113 barium titanate Inorganic materials 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000003792 electrolyte Substances 0.000 description 1
- 238000007590 electrostatic spraying Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 238000002955 isolation Methods 0.000 description 1
- 230000002572 peristaltic effect Effects 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000000518 rheometry Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000005236 sound signal Effects 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B9/00—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour
- B05B9/03—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material
- B05B9/04—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material with pressurised or compressible container; with pump
- B05B9/08—Apparatus to be carried on or by a person, e.g. of knapsack type
- B05B9/085—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump
- B05B9/0855—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump the pump being motor-driven
- B05B9/0861—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump the pump being motor-driven the motor being electric
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B15/00—Details of spraying plant or spraying apparatus not otherwise provided for; Accessories
- B05B15/50—Arrangements for cleaning; Arrangements for preventing deposits, drying-out or blockage; Arrangements for detecting improper discharge caused by the presence of foreign matter
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B17/00—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups
- B05B17/04—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods
- B05B17/06—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods using ultrasonic or other kinds of vibrations
- B05B17/0607—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods using ultrasonic or other kinds of vibrations generated by electrical means, e.g. piezoelectric transducers
- B05B17/0638—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods using ultrasonic or other kinds of vibrations generated by electrical means, e.g. piezoelectric transducers spray being produced by discharging the liquid or other fluent material through a plate comprising a plurality of orifices
- B05B17/0646—Vibrating plates, i.e. plates being directly subjected to the vibrations, e.g. having a piezoelectric transducer attached thereto
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B17/00—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups
- B05B17/04—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods
- B05B17/06—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods using ultrasonic or other kinds of vibrations
- B05B17/0607—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods using ultrasonic or other kinds of vibrations generated by electrical means, e.g. piezoelectric transducers
- B05B17/0653—Details
- B05B17/0676—Feeding means
-
- A—HUMAN NECESSITIES
- A45—HAND OR TRAVELLING ARTICLES
- A45D—HAIRDRESSING OR SHAVING EQUIPMENT; EQUIPMENT FOR COSMETICS OR COSMETIC TREATMENTS, e.g. FOR MANICURING OR PEDICURING
- A45D2200/00—Details not otherwise provided for in A45D
- A45D2200/20—Additional enhancing means
- A45D2200/207—Vibration, e.g. ultrasound
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B12/00—Arrangements for controlling delivery; Arrangements for controlling the spray area
- B05B12/02—Arrangements for controlling delivery; Arrangements for controlling the spray area for controlling time, or sequence, of delivery
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B17/00—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups
- B05B17/04—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods
- B05B17/06—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods using ultrasonic or other kinds of vibrations
- B05B17/0607—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods using ultrasonic or other kinds of vibrations generated by electrical means, e.g. piezoelectric transducers
- B05B17/0653—Details
- B05B17/0661—Transducer materials
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B9/00—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour
- B05B9/03—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material
- B05B9/04—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material with pressurised or compressible container; with pump
- B05B9/08—Apparatus to be carried on or by a person, e.g. of knapsack type
- B05B9/085—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump
- B05B9/0866—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump the pump being a gear, centrifugal or screw-type pump
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B9/00—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour
- B05B9/03—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material
- B05B9/04—Spraying apparatus for discharge of liquids or other fluent material, without essentially mixing with gas or vapour characterised by means for supplying liquid or other fluent material with pressurised or compressible container; with pump
- B05B9/08—Apparatus to be carried on or by a person, e.g. of knapsack type
- B05B9/085—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump
- B05B9/0872—Apparatus to be carried on or by a person, e.g. of knapsack type with a liquid pump the pump being a peristaltic pump
Definitions
- the present invention relates to a piezoelectric spraying system and a method of dispensing at least one pulverized product using such a system.
- Piezoelectric spraying devices are widely used for spraying low viscosity liquids, for example room fragrances.
- a wick allows to supply, by capillarity, a membrane vibrated by a ceramic.
- the patent application European EP 0 656 230 describes an aerosol comprising a piezoelectric system and a membrane provided with an orifice. The liquid particles are sprayed with a jet of gas disposed at the outlet of the orifice. A method of cleaning the orifice in the event of capping is provided.
- the patent application European EP 1 533 041 discloses a spraying device comprising a water reservoir comprising an electrolyte, a pump and an electrolysis bath provided with an anode and a cathode for producing acidic water on the side of the anode and the alkaline water on the side of the cathode, the first being sprayed with the piezoelectric device and the second being directed to a second reservoir of lost liquids.
- a control circuit including a microprocessor for controlling the electrolysis, the pump and the piezoelectric device is also included.
- the invention aims in particular to provide a system and a spraying method for spraying products having various rheologies and formulations, polarizable or not.
- the present invention thus relates, in one of its aspects, to a method of dispensing a product, in which a product supply chamber of a piezoelectric spraying device receives, during a spraying cycle, of product flowing in a direction from at least one tank, the flow direction of the product being reversed at the end of the spraying cycle to evacuate the product contained in the feed chamber.
- the feed chamber is delimited at least partially by a vibrating membrane of the piezoelectric device.
- piezoelectric device may make it possible to spray with a relatively large spray if necessary.
- the circulation of the product can be effected for example by a pump driven in one direction to supply the chamber and in the opposite direction to empty the chamber.
- This pump may comprise for example two rotary members, for example ovoid or other shape, may or may not include a toothing.
- the two rotating members can rotate in contact with each other.
- means may be provided to prevent slippage of one member relative to the other, for example a friction or a suitable mechanical connection.
- the pump can be configured to close, when stopped, any communication between the chamber and the tank, which can help improve the conservation of the product, especially when it comprises one or more volatile solvents.
- the operation of the piezoelectric spraying device can be interrupted only after the direction of circulation of the product has been reversed.
- the operation of the piezoelectric device is for example maintained for a duration greater than or equal to 0.5 seconds from the reversal of the direction of flow of the product. This duration can be for example between 0.5 and 2 seconds. This can further improve the emptying of the chamber by spraying a residual amount of product.
- the piezoelectric device can be operated before the product is circulated at the beginning of a spraying cycle. This can improve the particle size distribution of the sprayed product by allowing the device piezoelectric to reach a relatively stable operating regime before the actual spraying.
- Feeding at least one product from the chamber may be through a channel at a lower end of the chamber when the spraying system is in a normal position of use.
- An inclination of the chamber is detected in an exemplary implementation of the method. This may indicate to the user that the spraying system is not in an orientation suitable for complete emptying of the chamber. An audible and / or visual signal can then be emitted if the chamber is inclined unfavorable to the emptying thereof.
- the duration of circulation of the product to the chamber can be counted.
- An audible and / or visual signal may be emitted depending on the duration of circulation of the product, to inform the user on the degree of emptying of the tank.
- the chamber can receive sprays from at least two tanks, for example two products having different hues.
- the product or products may be taken from the reservoir (s) without air intake.
- the chamber may have a volume of less than or equal to 1 ml, for example a volume of between 0.25 and 0.75 ml.
- the product flow to the chamber during spraying is, for example, between 0.1 g / min and 5 g / min, for example from 0.7 to 0.9 g / min.
- the sprayed product may be any cosmetic or care product, for example a makeup composition, especially a foundation or a self-tanning composition.
- the circulation system may comprise a pump integral with the reservoir, and the pump and reservoir assembly may belong for example to a refill.
- the spraying system may comprise a switch, for example a push button, to trigger a spraying cycle.
- the spraying system may comprise an electric motor for driving a first coupling member, the aforementioned pump comprising a second coupling member arranged to cooperate with the first coupling member, so that a rotation of the first coupling member Coupling caused by the motor is accompanied by a rotation of the second coupling member and the actuation of the pump.
- the piezoelectric spraying device may be normally separable from the tank or alternatively may be permanently attached to the tank.
- the spraying system 1 shown in FIG. figure 1 comprises a housing 2 housing a piezoelectric spraying device 3 for spraying a product through an opening 4 of the housing 2.
- the opening 4 is for example a front opening, of axis oriented perpendicular to the longitudinal axis X of the housing 2, as illustrated in FIG. figure 1 , but other configurations of the housing 2 are possible without departing from the scope of the present invention.
- the opening 4 is formed on a removable cover 5, which can be separated from the base of the housing by acting on unlocking tabs 6 which are for example diametrically opposed.
- the spraying system 1 comprises, as illustrated schematically in FIG. figure 7 , an electrical source 11 which is for example accessible under the hood 5 and / or after removal of a hatch, not shown, so as to be replaced.
- the electric source 11 can be integrated into the refill 10.
- the spraying system 1 also comprises a control circuit 12 which makes it possible to control the operation of an electric motor 13 and that of the piezoelectric device 3 during a spraying cycle, as will be detailed below.
- the spraying system 1 comprises, in the illustrated example, a push-button 15 located in the upper part of the housing 2. This push-button 15 can pass through a corresponding opening formed on the cover 5.
- the spraying system 1 may also comprise at least one audible and / or luminous warning device 17, for example a light-emitting diode, and possibly at least one inclinometer 19 represented diagrammatically in FIG. figure 7 whose role will be explained later.
- the refill 10 comprises, as shown figure 2 , a reservoir 20, which is for example in the form of a flexible bag containing at least one product to be dispensed.
- the product can be taken from the tank 20 without air intake, if necessary.
- the refill 10 further comprises the piezoelectric device 3, which is contained in a housing 22 integral with the reservoir 20.
- the piezoelectric device 3 may comprise a not shown ring, made of a piezoelectric material, and a perforated membrane, still sometimes called a grid, mechanically vibrated by the ring.
- the latter may have a circular or non-circular shape, comprising for example a ceramic, in particular zirconate (PZT), metaniobate (PN), barium titanate or zinc oxide.
- PZT zirconate
- PN metaniobate
- FR 2,886,174 discloses an example of a piezoelectric device.
- the perforated membrane has for example a diameter greater than or equal to 6 mm, for example equal to 7 mm.
- the membrane comprises, for example, more than 100 holes, for example 150 holes.
- the holes have for example a diameter of between 20 microns and 40 microns, for example equal to 30 microns.
- the holes are for example located in the central region of the membrane.
- the membrane is for example glued on a ceramic having a thickness of between 0.5 and 0.7 mm, for example equal to 0.6 mm, for example with an outer diameter of 20 mm, and an internal diameter equal to 5 mm. .
- the ceramic is for example excited by a sinusoidal voltage 100 kHz 100 peak to peak.
- the control circuit 12 can supply the excitation current of the piezoelectric material ring and comprise the electronic components making it possible to keep the excitation frequency at the resonance value.
- the reservoir 20 can be connected to the housing 22 detachably, if necessary, for example to allow its replacement while maintaining the piezoelectric device 3.
- the reservoir 20, in particular when it is permanently fixed on the housing 2, may optionally be made to allow it to be reloaded with product and may include an opening for this purpose.
- the housing 22 houses, in the example considered, in addition to the piezoelectric device 3, a pump 26 which allows the circulation of the product from the reservoir 20 to a feed chamber 27 of the piezoelectric device 3.
- the chamber 27 is delimited by one side by the vibrating membrane of the piezoelectric device.
- the pump 26 comprises for example two rotary members 28 and 29 which rotate in contact with one another, which makes it possible to close the communication between the chamber 27 and the reservoir 20 when the pump is at a standstill.
- the pump 26 can be rotated by means of a first coupling member 30 accessible on one face of the casing 22, arranged to cooperate with a second coupling member 31 which is only shown schematically in FIG. figure 7 driven by the motor 13.
- a first coupling member 30 accessible on one face of the casing 22, arranged to cooperate with a second coupling member 31 which is only shown schematically in FIG. figure 7 driven by the motor 13.
- the rotation of the motor can be transmitted, via the first and second coupling members 30 and 31, to the rotary members 28 and 29.
- the spraying system may comprise, where appropriate, a gearbox between the motor 13 and the second coupling member 31.
- the housing 22 also comprises, in the example considered, electrical conductors 32 intended for the electrical supply of the piezoelectric device 3, the housing 2 housing corresponding electrical contacts connected to the control circuit 12.
- the first and second coupling members 30 and 31 cooperate and the conductors 32 can be supplied by the control circuit 12.
- the operation of the spraying system 1 during the spraying cycle can be as follows, as illustrated in FIG. figure 11 .
- pressing the push-button 15 is detected by the control circuit 12 in step 40.
- the circuit 12 can then control the operation of the piezoelectric device 3 in step 41, then that of the motor 13 so as to cause in step 42 the circulation of the product to the chamber 27.
- the spraying can take place, for example, as long as the user holds down the pushbutton 15.
- step 43 When the release thereof is detected in step 43, the operation of the piezoelectric device 3 can be maintained while the direction of rotation of the motor 13 is reversed, so that the pump 26 empties the chamber 27. After a predefined duration, the piezoelectric device 3 can be stopped in step 45.
- the chamber 27 may be powered by a channel 48 located in the lower part thereof.
- This channel 48 preferably has a small section.
- the control circuit 12 may be arranged to signal to the user by means of the inclinometer 19, for example by emitting a light and / or sound signal, that the spraying system 1 is not in the most suitable orientation. the complete emptying of the chamber 27, in this case head up in the example of the figure 6 .
- the control circuit 12 can also, if necessary, record the operating time of the motor 13 when it drives the pump 26 so as to supply the product to the chamber 27. This operating time thus counted can be compared to a preset value and the control circuit 12 may be arranged to warn the user of the imminent emptying of the tank 20 by emitting for example a sound and / or light signal.
- the alarm 17 is for example an LED which changes color or which flashes when the reservoir 20 is empty or practically empty. This LED can also light to indicate that the device is working properly.
- the invention is not limited to a particular drive means for circulating the product to the chamber 27 from the tank 20 or vice versa, and one can use various types of pumps, for example using a peristaltic pump, to gears or screw.
- the reservoir 20 may be further defined at least partially by a piston 65, as illustrated in FIG. figure 8 and the motor 13 can drive a pusher 50 which moves the piston 20 in one direction or another, depending on whether it is desired to supply the chamber 27 or empty it.
- the invention is not limited to the spraying of a single product and the housing 2 may for example receive at least two refills which are for example each associated with a spraying device 3, the housing 2 may comprise in this case two openings 4a and 4b for respectively spraying each of the products, as illustrated in FIG. figure 9 .
- the spraying system 1 may then comprise a selector 52 which allows the user to choose one or the other of the products, or even to allow the simultaneous spraying of the two products with a user-determined ratio, the control can for example in this case control the respective drive motors of the corresponding pumps with different speeds of rotation depending on the relative proportion of the products to be sprayed.
- Products can also be sprayed together through a single opening, as shown in figure 10 .
- the spraying system may comprise two tanks respectively containing the two products to be sprayed and corresponding pumps for feeding a single chamber associated with the spraying device.
- the piezoelectric device can be made in various ways and comprise for example any form of vibrating membrane.
- the invention is not limited either to a feed chamber of the piezoelectric device of particular shape.
- the shape of the feed chamber of the piezoelectric device may in particular depend on the shape of the vibrating membrane.
- the refill also includes the drive motor of the pump.
- additional electrical contacts can be made on the recharge to allow the supply of the current corresponding to the engine.
- the spraying system comprises a refill which is limited to the single tank.
- the spray system may still not have a removable refill.
- the tank may for example be permanently present in the housing of the spray system and can be reloaded or not in product.
- the pump for supplying the product to the feed chamber of the piezoelectric device may, where appropriate, serve to fill the tank, a selector being for example provided to allow the pump to suck in a source of product for filling the reservoir and not in the feed chamber of the piezoelectric device.
- the recharging may comprise means for informing the housing on the nature of the product contained therein, for example reliefs cooperating with contactors of the housing and whose state is analyzed by the control circuit.
- the refill can also comprise an electronic memory or a barcode containing information representative of the product contained inside, and possibly also additional characteristics, such as, for example, information relating to the spraying conditions of the product, for example the flow rate. supply of the piezoelectric device.
- the piezoelectric device may for example have a shape as disclosed in the application WO 9116997 .
Landscapes
- Containers And Packaging Bodies Having A Special Means To Remove Contents (AREA)
- Special Spraying Apparatus (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
- Nozzles (AREA)
- Coating By Spraying Or Casting (AREA)
Abstract
Description
La présente invention concerne un système de pulvérisation piézoélectrique et un procédé de distribution d'au moins un produit pulvérisé au moyen d'un tel système.The present invention relates to a piezoelectric spraying system and a method of dispensing at least one pulverized product using such a system.
Des dispositifs de pulvérisation piézoélectriques sont largement utilisés pour pulvériser des liquides faiblement visqueux, par exemple des parfums d'ambiance.Piezoelectric spraying devices are widely used for spraying low viscosity liquids, for example room fragrances.
Une mèche permet d'alimenter, par capillarité, une membrane mise en vibration par une céramique.A wick allows to supply, by capillarity, a membrane vibrated by a ceramic.
Ces dispositifs ne conviennent pas pour pulvériser un produit plus visqueux, tel qu'un fond de teint par exemple.These devices are not suitable for spraying a more viscous product, such as a foundation for example.
La demande internationale
La demande de brevet
La demande de brevet
L'invention vise notamment à proposer un système et un procédé de pulvérisation permettant de pulvériser des produits ayant des rhéologies et formulations diverses, polarisables ou non.The invention aims in particular to provide a system and a spraying method for spraying products having various rheologies and formulations, polarizable or not.
La présente invention concerne ainsi, selon l'un de ses aspects, un procédé de distribution d'un produit, dans lequel une chambre d'alimentation en produit d'un dispositif de pulvérisation piézoélectrique reçoit, au cours d'un cycle de pulvérisation, du produit circulant dans un sens en provenance d'au moins un réservoir, le sens de circulation du produit étant inversé à la fin du cycle de pulvérisation pour évacuer le produit contenu dans la chambre d'alimentation.The present invention thus relates, in one of its aspects, to a method of dispensing a product, in which a product supply chamber of a piezoelectric spraying device receives, during a spraying cycle, of product flowing in a direction from at least one tank, the flow direction of the product being reversed at the end of the spraying cycle to evacuate the product contained in the feed chamber.
Grâce à l'invention, un produit même relativement visqueux peut être pulvérisé à plusieurs reprises par le dispositif de pulvérisation piézoélectrique, car le séchage et la formation d'un important dépôt solide de produit dans la chambre d'alimentation, entre deux utilisations espacées dans le temps, est évité.Thanks to the invention, even a relatively viscous product can be sprayed several times by the piezoelectric spraying device, because the drying and the formation of a large solid deposit of product in the feed chamber, between two uses spaced apart in time, is avoided.
La chambre d'alimentation est délimitée au moins partiellement par une membrane vibrante du dispositif piézoélectrique.The feed chamber is delimited at least partially by a vibrating membrane of the piezoelectric device.
L'utilisation d'un dispositif piézoélectrique peut permettre de pulvériser avec un spray relativement large si nécessaire.The use of a piezoelectric device may make it possible to spray with a relatively large spray if necessary.
La circulation du produit peut s'effectuer par exemple grâce à une pompe entrainée dans un sens pour alimenter la chambre et dans le sens opposé pour vider la chambre.The circulation of the product can be effected for example by a pump driven in one direction to supply the chamber and in the opposite direction to empty the chamber.
Cette pompe peut comporter par exemple deux organes rotatifs, par exemple de forme ovoïde ou autre, pouvant ou non comporter une denture.This pump may comprise for example two rotary members, for example ovoid or other shape, may or may not include a toothing.
Les deux organes rotatifs peuvent tourner au contact l'un de l'autre. En l'absence de dents, des moyens peuvent être prévus pour éviter le glissement d'un organe par rapport à l'autre, par exemple une friction ou une liaison mécanique adaptée.The two rotating members can rotate in contact with each other. In the absence of teeth, means may be provided to prevent slippage of one member relative to the other, for example a friction or a suitable mechanical connection.
La pompe peut être configurée pour fermer, à l'arrêt, toute communication entre la chambre et le réservoir, ce qui peut contribuer à améliorer la conservation du produit, notamment lorsque celui-ci comporte un ou plusieurs solvants volatils.The pump can be configured to close, when stopped, any communication between the chamber and the tank, which can help improve the conservation of the product, especially when it comprises one or more volatile solvents.
Le fonctionnement du dispositif de pulvérisation piézoélectrique peut être interrompu seulement après que le sens de circulation du produit ait été inversé. Le fonctionnement du dispositif piézoélectrique est par exemple maintenu pendant une durée supérieure ou égale à 0.5 secondes à compter de l'inversion du sens de circulation du produit. Cette durée peut être comprise par exemple entre 0.5 et 2 secondes. Cela peut améliorer encore le vidage de la chambre en pulvérisant une quantité résiduelle de produit.The operation of the piezoelectric spraying device can be interrupted only after the direction of circulation of the product has been reversed. The operation of the piezoelectric device is for example maintained for a duration greater than or equal to 0.5 seconds from the reversal of the direction of flow of the product. This duration can be for example between 0.5 and 2 seconds. This can further improve the emptying of the chamber by spraying a residual amount of product.
Le dispositif piézoélectrique peut être mis en fonctionnement avant la mise en circulation du produit, au début d'un cycle de pulvérisation. Cela peut améliorer la distribution granulométrique du produit pulvérisé en permettant au dispositif piézoélectrique d'atteindre un régime de fonctionnement relativement stable avant la pulvérisation effective.The piezoelectric device can be operated before the product is circulated at the beginning of a spraying cycle. This can improve the particle size distribution of the sprayed product by allowing the device piezoelectric to reach a relatively stable operating regime before the actual spraying.
L'alimentation en au moins un produit de la chambre peut s'effectuer par un canal situé à une extrémité inférieure de la chambre, lorsque le système de pulvérisation est dans une position normale d'utilisation.Feeding at least one product from the chamber may be through a channel at a lower end of the chamber when the spraying system is in a normal position of use.
Une inclinaison de la chambre est détectée, dans un exemple de mise en oeuvre du procédé. Cela peut permettre de signaler à l'utilisateur que le système de pulvérisation n'est pas dans une orientation adaptée à un vidage complet de la chambre. Un signal audible et/ou visuel peut alors être émis en cas d'inclinaison de la chambre défavorable au vidage de celle-ci.An inclination of the chamber is detected in an exemplary implementation of the method. This may indicate to the user that the spraying system is not in an orientation suitable for complete emptying of the chamber. An audible and / or visual signal can then be emitted if the chamber is inclined unfavorable to the emptying thereof.
La durée de circulation du produit vers la chambre peut être comptabilisée. Un signal audible et/ou visuel peut être émis en fonction de la durée de circulation du produit, pour renseigner l'utilisateur sur le degré de vidage du réservoir.The duration of circulation of the product to the chamber can be counted. An audible and / or visual signal may be emitted depending on the duration of circulation of the product, to inform the user on the degree of emptying of the tank.
La chambre peut recevoir des produits à pulvériser d'au moins deux réservoirs, par exemple deux produits ayant des teintes différentes.The chamber can receive sprays from at least two tanks, for example two products having different hues.
Le ou les produits peuvent être prélevés dans le ou les réservoirs sans reprise d'air.The product or products may be taken from the reservoir (s) without air intake.
La chambre peut présenter un volume inférieur ou égal à 1 ml, par exemple un volume compris entre 0,25 et 0,75 ml.The chamber may have a volume of less than or equal to 1 ml, for example a volume of between 0.25 and 0.75 ml.
Le débit de produit vers la chambre lors de la pulvérisation est compris par exemple entre 0,1 g/mn et 5 g/mn, allant par exemple de 0,7 à 0,9 g/mn.The product flow to the chamber during spraying is, for example, between 0.1 g / min and 5 g / min, for example from 0.7 to 0.9 g / min.
Le produit pulvérisé peut être tout produit cosmétique ou de soin, par exemple une composition de maquillage, notamment un fond de teint ou une composition auto-bronzante.The sprayed product may be any cosmetic or care product, for example a makeup composition, especially a foundation or a self-tanning composition.
L'invention concerne également, selon un autre de ses aspects, un système de pulvérisation d'au moins un produit, comportant :
- un réservoir contenant au moins un produit à pulvériser,
- une chambre d'alimentation d'un dispositif piézoélectrique,
- un système de mise en circulation du produit du réservoir vers la chambre,
- un circuit de contrôle du système de mise en circulation pour inverser le sens de circulation du produit à la fin d'un cycle de pulvérisation, afin de vider la chambre.
- a tank containing at least one product to be sprayed,
- a feed chamber of a piezoelectric device,
- a system for circulating the product of the reservoir to the chamber,
- a control circuit of the circulation system to reverse the flow direction of the product at the end of a spraying cycle, in order to empty the chamber.
Le système de mise en circulation peut comporter une pompe solidaire du réservoir, et l'ensemble pompe et réservoir peut appartenir par exemple à une recharge.The circulation system may comprise a pump integral with the reservoir, and the pump and reservoir assembly may belong for example to a refill.
Le système de pulvérisation peut comporter un interrupteur, par exemple un bouton-poussoir, pour déclencher un cycle de pulvérisation.The spraying system may comprise a switch, for example a push button, to trigger a spraying cycle.
Le système de pulvérisation peut comporter un moteur électrique pour entraîner un premier organe d'accouplement, la pompe précitée comportant un deuxième organe d'accouplement agencé pour coopérer avec le premier organe d'accouplement, de telle sorte qu'une rotation du premier organe d'accouplement provoquée par le moteur s'accompagne d'une rotation du deuxième organe d'accouplement et de l'actionnement de la pompe.The spraying system may comprise an electric motor for driving a first coupling member, the aforementioned pump comprising a second coupling member arranged to cooperate with the first coupling member, so that a rotation of the first coupling member Coupling caused by the motor is accompanied by a rotation of the second coupling member and the actuation of the pump.
Le dispositif de pulvérisation piézoélectrique peut être normalement séparable du réservoir ou en variante être solidaire en permanence du réservoir.The piezoelectric spraying device may be normally separable from the tank or alternatively may be permanently attached to the tank.
L'invention pourra être mieux comprise à la lecture de la description détaillée qui va suivre, d'exemples de mise en oeuvre non limitatifs de celle-ci, et à l'examen du dessin annexé, sur lequel :
- la
figure 1 représente, en perspective, un exemple de système de pulvérisation réalisé conformément à l'invention, - la
figure 2 représente isolément une recharge pour le système de pulvérisation de lafigure 1 , - la
figure 3 est une vue de côté selon III de lafigure 2 , - la
figure 4 est une vue partielle arrière selon IV de lafigure 3 , - la
figure 5 représente schématiquement un exemple de pompe pouvant être utilisée, - la
figure 6 représente de manière schématique la chambre d'alimentation du dispositif piézoélectrique et la pompe associée, - la
figure 7 est un schéma en blocs représentant différents composants du système de pulvérisation, - la
figure 8 illustre une variante de réalisation du système de mise en circulation du produit, - les
figures 9 et 10 représentent partiellement, en perspective, des variantes du système de pulvérisation, et - la
figure 11 est un schéma en blocs illustrant un exemple de déroulement d'un cycle de pulvérisation.
- the
figure 1 represents, in perspective, an example of a spraying system produced according to the invention, - the
figure 2 represents in isolation a refill for the spray system of thefigure 1 , - the
figure 3 is a side view according to III of thefigure 2 , - the
figure 4 is a partial rear view according to IV of thefigure 3 , - the
figure 5 schematically represents an example of a pump that can be used, - the
figure 6 schematically represents the feed chamber of the piezoelectric device and the associated pump, - the
figure 7 is a block diagram showing different components of the spray system, - the
figure 8 illustrates an alternative embodiment of the system for circulating the product, - the
Figures 9 and 10 partially represent, in perspective, variants of the spraying system, and - the
figure 11 is a block diagram illustrating an example of a spraying cycle.
Le système de pulvérisation 1 représenté à la
L'ouverture 4 est par exemple une ouverture frontale, d'axe orienté perpendiculairement à l'axe longitudinal X du boîtier 2, comme illustré à la
Dans l'exemple considéré, l'ouverture 4 est formée sur un capot 5 amovible, lequel peut être séparé de la base du boîtier en agissant sur des pattes de déverrouillage 6 qui sont par exemple diamétralement opposées.In the example, the
L'enlèvement du capot 5 libère l'accès à une recharge 10 que l'on a représentée isolément aux
Le système de pulvérisation 1 comporte, comme illustré schématiquement à la
Le système de pulvérisation 1 comporte également un circuit de contrôle 12 qui permet de commander le fonctionnement d'un moteur électrique 13 et celui du dispositif piézoélectrique 3 lors d'un cycle de pulvérisation, comme cela sera détaillé plus loin.The spraying system 1 also comprises a
Le système de pulvérisation 1 comporte, dans l'exemple illustré, un bouton-poussoir 15 situé en partie supérieure du boitier 2. Ce bouton-poussoir 15 peut traverser une ouverture correspondante ménagée sur le capot 5.The spraying system 1 comprises, in the illustrated example, a push-
Le système de pulvérisation 1 peut encore comporter au moins un avertisseur 17 sonore et/ou lumineux, par exemple une diode électroluminescente, et éventuellement au moins un inclinomètre 19 représenté schématiquement à la
La recharge 10 comporte, comme représenté
Dans l'exemple illustré, la recharge 10 comporte en outre le dispositif piézoélectrique 3, lequel est contenu dans un boitier 22 solidaire du réservoir 20.In the example illustrated, the
Le dispositif piézoélectrique 3 peut comporter un anneau non représenté, réalisé en un matériau piézoélectrique, et une membrane perforée, encore parfois appelée grille, sollicitée mécaniquement en vibration par l'anneau. Ce dernier peut présenter une forme circulaire ou non circulaire, comportant par exemple une céramique, notamment du zirconate (PZT), du métaniobate (PN), du titanate de baryum ou de l'oxyde de zinc. La demande
La membrane perforée présente par exemple un diamètre supérieur ou égal à 6 mm, par exemple égal à 7 mm. La membrane comporte par exemple plus de 100 trous, par exemple 150 trous.The perforated membrane has for example a diameter greater than or equal to 6 mm, for example equal to 7 mm. The membrane comprises, for example, more than 100 holes, for example 150 holes.
Les trous ont par exemple un diamètre compris entre 20 µm et 40 µm, par exemple égal à 30 µm.The holes have for example a diameter of between 20 microns and 40 microns, for example equal to 30 microns.
Les trous sont par exemple situés dans la région centrale de la membrane.The holes are for example located in the central region of the membrane.
La membrane est par exemple collée sur une céramique d'épaisseur comprise entre 0,5 et 0,7 mm, par exemple égale à 0,6 mm, par exemple de diamètre extérieur égal à 20 mm, et de diamètre intérieur égal à 5 mm.The membrane is for example glued on a ceramic having a thickness of between 0.5 and 0.7 mm, for example equal to 0.6 mm, for example with an outer diameter of 20 mm, and an internal diameter equal to 5 mm. .
La céramique est par exemple excitée par une tension sinusoïdale à 100 kHz de 100 crête à crête.The ceramic is for example excited by a sinusoidal voltage 100 kHz 100 peak to peak.
Le circuit de contrôle 12 peut fournir le courant d'excitation de l'anneau en matériau piézoélectrique et comporter les composants électroniques permettant de maintenir la fréquence d'excitation à la valeur de résonnance.The
Le réservoir 20 peut être lié au boitier 22 de manière détachable, le cas échéant, afin par exemple de permettre son remplacement tout en conservant le dispositif piézoélectrique 3.The
Le réservoir 20, notamment lorsqu'il est fixé à demeure sur le boîtier 2, peut éventuellement être réalisé de manière à permettre son rechargement en produit et peut comporter une ouverture à cet effet.The
Le boîtier 22 loge, dans l'exemple considéré, outre le dispositif piézoélectrique 3, une pompe 26 qui permet la mise en circulation du produit depuis le réservoir 20 vers une chambre d'alimentation 27 du dispositif piézoélectrique 3. La chambre 27 est délimitée d'un côté par la membrane vibrante du dispositif piézoélectrique.The
La pompe 26 comporte par exemple deux organes rotatifs 28 et 29 qui tournent au contact l'un de l'autre, ce qui permet d'obturer la communication entre la chambre 27 et le réservoir 20 lorsque la pompe est à l'arrêt.The
La pompe 26 peut être mise en rotation grâce à un premier organe d'accouplement 30 accessible sur une face du boîtier 22, agencé pour coopérer avec un deuxième organe d'accouplement 31 qui n'est représenté que schématiquement à la
Le système de pulvérisation peut comporter, le cas échéant, un réducteur entre le moteur 13 et le deuxième organe d'accouplement 31.The spraying system may comprise, where appropriate, a gearbox between the
Le boîtier 22 comporte également, dans l'exemple considéré, des conducteurs électriques 32 destinés à l'alimentation électrique du dispositif piézoélectrique 3, le boitier 2 logeant des contacts électriques correspondants reliés au circuit de contrôle 12.The
Lors de la mise en place de la recharge 30 dans le boîtier 2, les premier et deuxième organes d'accouplement 30 et 31 coopèrent et les conducteurs 32 peuvent être alimentés par le circuit de contrôle 12.During the introduction of the
Le fonctionnement du système de pulvérisation 1 au cours du cycle de pulvérisation peut être le suivant, comme illustré à la
Tout d'abord, une pression sur le bouton-poussoir 15 est détectée par le circuit de contrôle 12, à l'étape 40.First, pressing the push-
Le circuit 12 peut commander alors le fonctionnement du dispositif piézoélectrique 3 à l'étape 41, puis celui du moteur 13 afin de provoquer à l'étape 42 la mise en circulation du produit vers la chambre 27.The
La pulvérisation peut avoir lieu, par exemple, tant que l'utilisateur maintient enfoncé le bouton-poussoir 15.The spraying can take place, for example, as long as the user holds down the
Lorsque le relâchement de celui-ci est détecté à l'étape 43, le fonctionnement du dispositif piézoélectrique 3 peut être maintenu tandis que le sens de rotation du moteur 13 est inversé, de manière à ce que la pompe 26 vide la chambre 27. Après une durée prédéfinie, le dispositif piézoélectrique 3 peut être arrêté, à l'étape 45.When the release thereof is detected in
La chambre 27 peut être alimentée par un canal 48 situé en partie inférieure de celle-ci. Ce canal 48 présente de préférence une faible section.The
Le circuit de contrôle 12 peut être agencé pour signaler à l'utilisateur grâce à l'inclinomètre 19, par exemple en émettant un signal lumineux et/ou sonore, que le système de pulvérisation 1 n'est pas dans l'orientation convenant le mieux au vidage complet de la chambre 27, en l'espèce tête en haut dans l'exemple de la
Le circuit de contrôle 12 peut encore, le cas échéant, comptabiliser le temps de fonctionnement du moteur 13 lorsque celui-ci entraine la pompe 26 de manière à fournir du produit à la chambre 27. Ce temps de fonctionnement ainsi comptabilisé peut être comparé à une valeur prédéfinie et le circuit de contrôle 12 peut être agencé pour avertir l'utilisateur du vidage imminent du réservoir 20 en émettant par exemple un signal sonore et/ou lumineux.The
L'avertisseur 17 est par exemple une LED qui change de couleur ou qui clignote lorsque le réservoir 20 est vide ou pratiquement vide. Cette LED peut également s'allumer pour signaler le bon fonctionnement du dispositif.The
L'invention n'est pas limitée à un moyen d'entraînement particulier pour faire circuler le produit vers la chambre 27 depuis le réservoir 20 ou inversement, et l'on peut utiliser divers types de pompes, par exemple utiliser une pompe péristaltique, à engrenages ou à vis.The invention is not limited to a particular drive means for circulating the product to the
Le réservoir 20 peut encore être délimité au moins partiellement par un piston 65, comme illustré à la
L'invention n'est pas limitée à la pulvérisation d'un produit unique et le boitier 2 peut par exemple recevoir au moins deux recharges qui sont par exemple associées chacune à un dispositif de pulvérisation 3, le boîtier 2 pouvant comporter dans ce cas deux ouvertures 4a et 4b pour la pulvérisation respectivement de chacun des produits, comme illustré à la
Le système de pulvérisation 1 peut alors comporter un sélecteur 52 qui permet à l'utilisateur de choisir l'un ou l'autre des produits, voire de permettre la pulvérisation simultanée des deux produits avec un rapport déterminé par l'utilisateur, le circuit de contrôle pouvant par exemple dans ce cas commander les moteurs respectifs d'entraînement des pompes correspondantes avec des vitesses de rotation différentes en fonction de la proportion relative des produits à pulvériser.The spraying system 1 may then comprise a
Les produits peuvent également être pulvérisés ensemble à travers une ouverture unique, comme illustré à la
Dans ce cas, le système de pulvérisation peut comporter deux réservoirs contenant respectivement les deux produits à pulvériser et des pompes correspondantes permettant d'alimenter une chambre unique associée au dispositif de pulvérisation.In this case, the spraying system may comprise two tanks respectively containing the two products to be sprayed and corresponding pumps for feeding a single chamber associated with the spraying device.
Le dispositif piézoélectrique peut être réalisé de diverses manières et comporter par exemple toute forme de membrane vibrante. L'invention n'est pas limitée non plus à une chambre d'alimentation du dispositif piézoélectrique de forme particulière. La forme de la chambre d'alimentation du dispositif piézoélectrique pourra notamment dépendre de la forme de la membrane vibrante.The piezoelectric device can be made in various ways and comprise for example any form of vibrating membrane. The invention is not limited either to a feed chamber of the piezoelectric device of particular shape. The shape of the feed chamber of the piezoelectric device may in particular depend on the shape of the vibrating membrane.
Dans une variante, la recharge comporte également le moteur d'entraînement de la pompe. Dans ce cas, des contacts électriques supplémentaires peuvent être réalisés sur la recharge afin de permettre la fourniture du courant correspondant au moteur.In a variant, the refill also includes the drive motor of the pump. In this case, additional electrical contacts can be made on the recharge to allow the supply of the current corresponding to the engine.
Dans une autre variante, le système de pulvérisation comporte une recharge qui est limitée au seul réservoir.In another variant, the spraying system comprises a refill which is limited to the single tank.
Le système de pulvérisation peut encore ne pas comporter de recharge amovible. Dans ce cas, le réservoir peut par exemple être présent à demeure dans le boîtier du système de pulvérisation et peut être rechargé ou non en produit.The spray system may still not have a removable refill. In this case, the tank may for example be permanently present in the housing of the spray system and can be reloaded or not in product.
La pompe servant à fournir le produit à la chambre d'alimentation du dispositif piézoélectrique peut, le cas échéant, servir au remplissage du réservoir, un sélecteur étant par exemple prévu afin de permettre à la pompe d'aspirer dans une source de produit servant au remplissage du réservoir et non dans la chambre d'alimentation du dispositif piézoélectrique.The pump for supplying the product to the feed chamber of the piezoelectric device may, where appropriate, serve to fill the tank, a selector being for example provided to allow the pump to suck in a source of product for filling the reservoir and not in the feed chamber of the piezoelectric device.
Le cas échéant, la recharge peut comporter des moyens pour renseigner le boîtier sur la nature du produit contenu à l'intérieur, par exemple des reliefs coopérant avec des contacteurs du boîtier et dont l'état est analysé par le circuit de contrôle.Where appropriate, the recharging may comprise means for informing the housing on the nature of the product contained therein, for example reliefs cooperating with contactors of the housing and whose state is analyzed by the control circuit.
La recharge peut aussi comporter une mémoire électronique ou un code à barres contenant une information représentative du produit contenu à l'intérieur ainsi éventuellement que des caractéristiques additionnelles, telles que par exemple une information relative à des conditions de pulvérisation du produit, par exemple le débit d'alimentation du dispositif piézoélectrique.The refill can also comprise an electronic memory or a barcode containing information representative of the product contained inside, and possibly also additional characteristics, such as, for example, information relating to the spraying conditions of the product, for example the flow rate. supply of the piezoelectric device.
Le dispositif piézoélectrique peut par exemple présenter une forme telle que divulguée dans la demande
L'expression « comportant un » doit être comprise comme étant synonyme de « comportant au moins un », sauf si le contraire est spécifié.The expression "having one" shall be understood as being synonymous with "having at least one", unless the opposite is specified.
Claims (28)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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FR0655745A FR2910253B1 (en) | 2006-12-20 | 2006-12-20 | METHOD FOR DISPENSING A PRODUCT SPRAYED BY A PIEZOELECTRIC SPRAY SYSTEM AND A SPRAY SYSTEM FOR IMPLEMENTING SUCH A METHOD |
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EP1935280A1 true EP1935280A1 (en) | 2008-06-25 |
EP1935280B1 EP1935280B1 (en) | 2009-10-21 |
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EP07123781A Not-in-force EP1935280B1 (en) | 2006-12-20 | 2007-12-20 | Method for dispensing a product sprayed by a piezoelectric spraying system and spraying system for implementing such a method |
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US (1) | US20080290185A1 (en) |
EP (1) | EP1935280B1 (en) |
JP (1) | JP2008246468A (en) |
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DE (1) | DE602007002870D1 (en) |
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2007
- 2007-12-20 EP EP07123781A patent/EP1935280B1/en not_active Not-in-force
- 2007-12-20 AT AT07123781T patent/ATE446031T1/en not_active IP Right Cessation
- 2007-12-20 DE DE602007002870T patent/DE602007002870D1/en active Active
- 2007-12-20 US US12/004,058 patent/US20080290185A1/en not_active Abandoned
- 2007-12-20 JP JP2007328463A patent/JP2008246468A/en active Pending
- 2007-12-20 ES ES07123781T patent/ES2334276T3/en active Active
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US10625031B2 (en) | 2016-12-27 | 2020-04-21 | L'oreal | Orientation independent topical applicator |
Also Published As
Publication number | Publication date |
---|---|
ATE446031T1 (en) | 2009-11-15 |
ES2334276T3 (en) | 2010-03-08 |
EP1935280B1 (en) | 2009-10-21 |
DE602007002870D1 (en) | 2009-12-03 |
FR2910253A1 (en) | 2008-06-27 |
JP2008246468A (en) | 2008-10-16 |
FR2910253B1 (en) | 2010-03-12 |
US20080290185A1 (en) | 2008-11-27 |
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