Nothing Special   »   [go: up one dir, main page]

EP1722860B1 - Konditionierungsshampoo-zusammensetzungen - Google Patents

Konditionierungsshampoo-zusammensetzungen Download PDF

Info

Publication number
EP1722860B1
EP1722860B1 EP05711564A EP05711564A EP1722860B1 EP 1722860 B1 EP1722860 B1 EP 1722860B1 EP 05711564 A EP05711564 A EP 05711564A EP 05711564 A EP05711564 A EP 05711564A EP 1722860 B1 EP1722860 B1 EP 1722860B1
Authority
EP
European Patent Office
Prior art keywords
composition
surfactant
silicone oil
composition according
shampoo
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
EP05711564A
Other languages
English (en)
French (fr)
Other versions
EP1722860A1 (de
Inventor
Marjorie Mossman Peffly
Jennifer Elaine Hilvert
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Procter and Gamble Co
Original Assignee
Procter and Gamble Co
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Family has litigation
First worldwide family litigation filed litigation Critical https://patents.darts-ip.com/?family=34825915&utm_source=google_patent&utm_medium=platform_link&utm_campaign=public_patent_search&patent=EP1722860(B1) "Global patent litigation dataset” by Darts-ip is licensed under a Creative Commons Attribution 4.0 International License.
Application filed by Procter and Gamble Co filed Critical Procter and Gamble Co
Publication of EP1722860A1 publication Critical patent/EP1722860A1/de
Application granted granted Critical
Publication of EP1722860B1 publication Critical patent/EP1722860B1/de
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
    • A61K8/89—Polysiloxanes
    • A61K8/891—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone
    • A61K8/892—Polysiloxanes saturated, e.g. dimethicone, phenyl trimethicone, C24-C28 methicone or stearyl dimethicone modified by a hydroxy group, e.g. dimethiconol
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/02—Cosmetics or similar toiletry preparations characterised by special physical form
    • A61K8/04—Dispersions; Emulsions
    • A61K8/06—Emulsions
    • A61K8/068—Microemulsions
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/40—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing nitrogen
    • A61K8/44—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof
    • A61K8/442—Aminocarboxylic acids or derivatives thereof, e.g. aminocarboxylic acids containing sulfur; Salts; Esters or N-acylated derivatives thereof substituted by amido group(s)
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
    • A61K8/46—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur
    • A61K8/463—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing sulfur containing sulfuric acid derivatives, e.g. sodium lauryl sulfate
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/731—Cellulose; Quaternized cellulose derivatives
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K8/00—Cosmetics or similar toiletry preparations
    • A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
    • A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
    • A61K8/73—Polysaccharides
    • A61K8/737—Galactomannans, e.g. guar; Derivatives thereof
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/02—Preparations for cleaning the hair
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
    • A61Q5/00—Preparations for care of the hair
    • A61Q5/12—Preparations containing hair conditioners
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y5/00—Nanobiotechnology or nanomedicine, e.g. protein engineering or drug delivery
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/41—Particular ingredients further characterized by their size
    • A61K2800/413—Nanosized, i.e. having sizes below 100 nm
    • A—HUMAN NECESSITIES
    • A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
    • A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
    • A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
    • A61K2800/40—Chemical, physico-chemical or functional or structural properties of particular ingredients
    • A61K2800/54—Polymers characterized by specific structures/properties
    • A61K2800/542—Polymers characterized by specific structures/properties characterized by the charge
    • A61K2800/5426—Polymers characterized by specific structures/properties characterized by the charge cationic

Definitions

  • This invention relates to shampoo compositions, particularly to shampoo compositions which include an anionic surfactant system, a microemulsion of silicone and a cationic cellulose deposition polymer.
  • Shampoo compositions comprising various combinations of detersive surfactant and conditioning agents are known. These products typically comprise an anionic detersive surfactant in combination with a conditioning agent such as silicone, hydrocarbon oil, fatty esters, or combinations thereof. These products have become more popular among consumers as a means of conveniently obtaining hair and skin conditioning and cleansing performance all from a single personal care product.
  • a conditioning agent such as silicone, hydrocarbon oil, fatty esters, or combinations thereof.
  • Obtaining good deposition of a conditioning agent is further complicated by the action of detersive surfactants in the shampoo composition.
  • Detersive surfactants are designed to carry away or remove oil, grease, dirt, and particulate matter from the hair and skin. In doing so, the detersive surfactants can also interfere with deposition of the conditioning agent, and both deposited and non deposited conditioning agent can be removed during rinsing. This further reduces deposition of the conditioning agent onto the hair and skin after rinsing, thus further reducing conditioning performance.
  • One known method for improving deposition of a conditioning agent involves the use of certain cationic deposition polymers. These polymers may be natural cellulosic or guar polymers that have been modified with cationic substituents. Selecting a polymer with sufficient charge density and molecular weight in combination with an optimized surfactant system results in sufficient deposition of conditioning agents. When the silicone in these higher deposition systems has a high internal phase viscosity some consumers notice performance tradeoffs in terms of reduced shampoo cleaning, conditioner buildup, and a reduction in volume of the hair style.
  • a high internal phase viscosity refers to viscosities greater than 50,000 m 2 /s (cst), and especially those greater than 100,000 m 2 /s (cst.) Reduction in the deposition of the silicone will reduce these negatives, but will also reduce desirable hair conditioning benefits. Thus, a need still exists for improved conditioning performance in shampoo compositions that does not result in buildup leading to reduced volume and dissatisfaction with the cleansing properties of the shampoo.
  • a recently identified unmet consumer need is the ability to deliver sufficient conditioning performance from a shampoo that is optically clear or at least transparent and does not result in a cleaning tradeoff, buildup, or reduced volume of the intended hair style, and is storage stable.
  • Attempts have been made previously to use dispersed droplets of silicone oil deposited on the hair shaft to provide this conditioning.
  • these attempts have resulted in either insufficient conditioning, buildup of conditioning agents, reduction of style volume, or product instability in the form of reduced product clarity and/or an unacceptable reduction in shampoo viscosity over time.
  • oily cosmetic agents such as silicones can be incorporated into cosmetic compositions by means of microemulsification, whereby the silicone is present as stably emulsified droplets of a particle size of about 0.15 microns or less.
  • EP0529 883 (1) relates to cosmetic compositions which have good mechanical stability, high optical translucency and conditioning by using a microemulsified conditioning oil in combination with a deposition aid.
  • the deposition aid is preferably a Cationic deposition polymer especially cationic derivatives of guar gum or cationic cellulose ether derivatives.
  • D1 lists a large number of suitable guar gum materials from the Jaguar range and mentions the polymer JR series as suitable cellulosic polymers, preferably Polymer JR 400.
  • the need remains for a substantially clear shampoo composition, which delivers superior conditioning benefits to hair.
  • the need also remains for a substantially clear shampoo composition, which remains stable/substantially clear after prolonged storage.
  • the present invention meets the aforementioned needs by providing a shampoo composition, which provides superior conditioning to hair while also providing excellent storage stability and optionally high optical transparency or translucency. These benefits can be obtained by combining a low viscosity microemulsified silicone oil with a cationic deposition polymer.
  • a shampoo composition comprising:
  • the shampoo compositions of the present invention include at least one detersive surfactant, a silicone oil microemulsion, a cationic deposition polymer and an aqueous carrier.
  • detersive surfactant e.g., a silicone oil microemulsion
  • a cationic deposition polymer e.g., a quaternary ammonium salt
  • charge density refers to the ratio of the number of positive charges on a monomeric unit of which a polymer is comprised to the molecular weight of said monomeric unit. Charge density is typically expressed in miliequivalents per gram. The charge density multiplied by the polymer molecular weight determines the number of positively charged sites on a given polymer chain.
  • compositions and methods/processes of the present invention can comprise, consist of, and consist essentially of the essential elements and limitations of the invention described herein, as well as any of the additional or optional ingredients, components, steps, or limitations described herein.
  • polymer as used herein shall include materials whether made by polymerization of one type of monomer or made by two (i.e., copolymers) or more types of monomers.
  • compositions or components thereof so described are suitable for use in contact with human hair and the scalp and skin without undue toxicity, incompatibility, instability, allergic response, and the like.
  • compositions have a percent transparency of at least about 75% transmittance at 600nm when measured in the absence of dyes and colorants using any standard UV spectrophotometer.
  • storage stable means the compositions maintain a level of transparency of at least about 70% transmittance at 600nm when measured in the absence of dyes and colorants for at least 6 months when stored at one (1) atmosphere of pressure, 50% relative humidity, and 25°C, or to approximate rapid aging for 2 weeks at a temperature of 45 °C.
  • storage stable may also refer to the shampoo viscosity stability wherein the viscosity of the finished shampoo composition drops no more than 40% of the shampoo compositions initial viscosity for at least 6 months when stored at (1) atmosphere of pressure, 50% relative humidity, and 25°C or to approximate rapid aging for 2 weeks at a temperature of 45 °C.
  • the internal phase viscosity of the silicone being measured is the viscosity of the silicone oil itself and not that of the emulsion or the final shampoo composition.
  • the emulsion In order to measure the internal phase viscosity of the silicone the emulsion must first be broken to phase separate the silcone oil from the carrier (i.e. water) and surfactants in the microemulsion. Breaking the silicone emulsion is typically accomplished by addition of a sufficient amount of solvent, for example isopropanol, which is not substantially soluble in the silicone, or a stepwise procedure wherein isopropanol addition is followed by acetone addition. After physical separation of the silicone oil from the carrier and surfactants standard viscosity measurement techniques may be used. The preferred viscosity measurement technique involves use of a Brookfield Cone and Plate viscometer and is measured at 25 °C.
  • the shampoo compositions of the present invention include an anionic surfactant system.
  • the surfactant component is included to impart cleaning performance to the composition.
  • the surfactant component in turn comprises an ethoxylated surfactant and a sulfate, and optionally a zwitterionic or amphoteric surfactant, an additional surfactant, or a combination thereof.
  • Such surfactants should be physically and chemically compatible with the essential components described herein, or should not otherwise unduly impair product stability, aesthetics or performance.
  • Suitable anionic surfactant components for use in the shampoo compositions herein include those that are known for use in hair care or other personal care compositions.
  • the concentration of the anionic surfactant component in the shampoo compositions should be sufficient to provide the desired cleaning and lather performance, and generally range from 2% to 35%, preferably from 5% to about 25%, by weight of the shampoo composition.
  • Preferred anionic surfactants suitable for use in the shampoo compositions are the alkyl sulfates and alkyl ether sulfates. These materials have the respective formulae ROSO 3 M and RO(C 2 H 4 O) x SO 3 M, wherein R is alkyl or alkenyl of from a 8 to 18 carbon atoms, x is an integer having a value of from a 1 to 10, and M is a cation such as ammonium, alkanolamines, such as triethanolamine, monovalent metals, such as sodium and potassium, and polyvalent metal cations, such as magnesium, and calcium. Solubility of the surfactant will depend upon the particular anionic surfactants and cations chosen.
  • R has from a 8 to 18 carbon atoms, more preferably from about 10 to about 16 carbon atoms, even more preferably from 12 to 14 carbon atoms, in both the alkyl sulfates and alkyl ether sulfates.
  • the alkyl ether sulfates are typically made as condensation products of ethylene oxide and monohydric alcohols having from 8 to 24 carbon atoms.
  • the alcohols can be synthetic or they can be derived from fats, e.g., coconut oil, palm kernel oil, tallow. Lauryl alcohol and straight chain alcohols derived from coconut oil or palm kernel oil are preferred.
  • Such alcohols are reacted with between from 0 and 10, preferably from 2 to 5, more preferably from 3, molar proportions of ethylene oxide, and the resulting mixture of molecular species having, for example, an average of 3 moles of ethylene oxide per mole of alcohol, is sulfated and neutralized.
  • alkyl ether sulfates which may be used in the personal care compositions of the present invention include sodium and ammonium salts of coconut alkyl triethylene glycol ether sulfate, tallow alkyl triethylene glycol ether sulfate, and tallow alkyl hexa-oxyethylene sulfate.
  • Highly preferred alkyl ether sulfates are those comprising a mixture of individual compounds, wherein the compounds in the mixture have an average alkyl chain length of from 10 to 16 carbon atoms and an average degree of ethoxylation of from 1 to 4 moles of ethylene oxide.
  • Such a mixture also comprises from 0 to 20% by weight C 12-13 compounds; from 60 to 100% by weight of C 14-15-16 compounds; from 0 to 20% by weight of C 17-18-19 compounds; from 3 to 30% by weight of compounds having a degree of ethoxylation of 0; from 45 to 90% by weight of compounds having a degree of ethoxylation, of from 1 to 4; from 10 to 25% by weight of compounds having a degree of ethoxylation of from 4 to 8; and from 0.1 to 15% by weight of compounds having a degree of ethoxylation greater than 8.
  • a percent ethoxylate can be calculated based on the stochiometry of the surfactant structure, based on a particular molecular weight of the surfactant where the number of moles of ethoxylation is known. Likewise, given a specific molecular weight of a surfactant and a sulfation reaction completion measurement, the percent sulfate can be calculated. Analytical techniques have been developed to measure percent ethoxylation or percent sulfates within surfactant systems. The level of ethoxylate and the level of sulfate representative of a particular surfactant system is calculated from the percent ethoxylation and percent sulfates of individual surfactants in the following manner:
  • anionic surfactants are the water-soluble salts of the organic, sulfuric acid reaction products of the general formula R 1 -SO 3 -M wherein R 1 is chosen from the group consisting of a straight or branched chain, saturated aliphatic hydro-carbon radical having from 8 to 24, preferably 12 to 18, carbon atoms; and M is a cation.
  • salts of an organic sulfuric acid reaction product of a hydrocarbon of the methane series including iso-, neo-, ineso-, and n-paraffins, having 8 to 24 carbon atoms, preferably 12 to 18 carbon atoms, and a sulfonating agent e.g., SO 3 , H 2 SO 4 , oleum, obtained according to known sulfonation methods, including bleaching and hydrolysis.
  • a sulfonating agent e.g., SO 3 , H 2 SO 4 , oleum, obtained according to known sulfonation methods, including bleaching and hydrolysis.
  • alkali metal and ammonium sulfonated C 12-18 -n-paraffins are preferred.
  • Preferred anionic surfactants for use in the shampoo compositions include ammonium lauryl sulfate, ammonium laureth sulfate, triethylamine lauryl sulfate, triethylamine laureth sulfate, triethanolamine lauryl sulfate, triethanolamine laureth sulfate, monoethanolamine lauryl sulfate, monoethanolamine laureth sulfate, diethanolamine lauryl sulfate, diethanolamine laureth sulfate, lauric monoglyceride sodium sulfate, sodium lauryl sulfate, sodium laureth sulfate, potassium lauryl sulfate, potassium laureth sulfate, sodium lauryl sarcosinate, sodium lauroyl sarcosinate, lauryl sarcosine, cocoyl sarcosine, ammonium cocoyl sulfate, ammonium
  • Suitable amphoteric or zwitterionic surfactants for use in the shampoo compositions herein include those which are known for use in hair care or other personal care compositions. Concentration of such amphoteric surfactants preferably ranges from about 0.5% to about 20%, preferably from about 1% to about 10%, by weight of the composition. Non limiting examples of suitable zwitterionic or amphoteric surfactants are described in U.S. Pat. Nos. 5,104,646 , and 5,106,609 .
  • Amphoteric surfactants suitable for use in the shampoo compositions are well known in the art, and include those surfactants broadly described as derivatives of aliphatic secondary and tertiary amines in which the aliphatic radical can be straight or branched chain and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic water solubilizing group such as carboxy, sulfonate, sulfate, phosphate, or phosphonate.
  • Preferred amphoteric surfactants for use in the present invention include cocoamphoacetate, cocoamphodiacetate, lauroamphoacetate, lauroamphodiacetate, and mixtures thereof.
  • Zwitterionic surfactants suitable for use in the shampoo compositions are well known in the art, and include those surfactants broadly described as derivatives of aliphatic quaternary ammonium, phosphonium, and sulfonium compounds, in which the aliphatic radicals can be straight or branched chain, and wherein one of the aliphatic substituents contains from about 8 to about 18 carbon atoms and one contains an anionic group such as carboxy, sulfonate, sulfate, phosphate or phosphonate. Zwitterionics such as betaines are preferred.
  • the shampoo compositions of the present invention may further comprise additional surfactants for use in combination with the surfactant component described hereinbefore.
  • suitable anionic surfactants are the water-soluble salts of organic, sulfuric acid reaction products conforming to the formula [ R 1 -SO 3 -M ] where R 1 is a straight or branched chain, saturated, aliphatic hydrocarbon radical having from about 8 to about 24, preferably from about 10 to about 18, carbon atoms; and M is a cation described hereinbefore.
  • Non limiting examples of such surfactants are the salts of an organic sulfuric acid reaction product of a hydrocarbon of the methane series, including iso-, neo-, and n-paraffins, having from about 8 to about 24 carbon atoms, preferably about 12 to about 18 carbon atoms and a sulfonating agent, e.g., SO 3 , H 2 SO 4 , obtained according to known sulfonation methods, including bleaching and hydrolysis.
  • a sulfonating agent e.g., SO 3 , H 2 SO 4
  • Preferred are alkali metal and ammonium sulfonated C 10 to C 18 n-paraffins.
  • anionic surfactants are the reaction products of fatty acids esterified with isethionic acid and neutralized with sodium hydroxide where, for example, the fatty acids are derived from coconut oil or palm kernel oil; sodium or potassium salts of fatty acid amides of methyl tauride in which the fatty acids, for example, are derived from coconut oil or palm kernel oil.
  • Other similar anionic surfactants are described in U.S. Pat. Nos. 2,486,921 ; 2,486,922 ; and 2,396,278 .
  • anionic surfactants suitable for use in the shampoo compositions are the succinnates, examples of which include disodium N-octadecylsulfosuccinnate; disodium lauryl sulfosuccinate; diammonium lauryl sulfosuccinate; tetrasodium N-(1,2-dicarboxyethyl)-N-octadecylsulfosuccinnate; diamyl ester of sodium sulfosuccinic acid; dihexyl ester of sodium sulfosuccinic acid; and dioctyl esters of sodium sulfosuccinic acid.
  • succinnates examples of which include disodium N-octadecylsulfosuccinnate; disodium lauryl sulfosuccinate; diammonium lauryl sulfosuccinate; tetrasodium N-(1,2-dicarboxye
  • olefin sulfonates having about 10 to about 24 carbon atoms.
  • olefin sulfonates refers to compounds which can be produced by the sulfonation of alpha-olefins by means of uncomplexed sulfur trioxide, followed by neutralization of the acid reaction mixture in conditions such that any sulfonates which have been formed in the reaction are hydrolyzed to give the corresponding hydroxy-alkanesulfonates.
  • the sulfur trioxide can be liquid or gaseous, and is usually, but not necessarily, diluted by inert diluents, for example by liquid SO 2 , chlorinated hydrocarbons, etc., when used in the liquid form, or by air, nitrogen, gaseous SO 2 , etc., when used in the gaseous form.
  • the alpha-olefins from which the olefin sulfonates are derived are mono-olefins having from 10 to 24 carbon atoms, preferably from 12 to 16 carbon atoms. Preferably, they are straight chain olefins.
  • the olefm sulfonates can contain minor amounts of other materials, such as alkene disulfonates depending upon the reaction conditions, proportion of reactants, the nature of the starting olefins and impurities in the olefin stock and side reactions during the sulfonation process.
  • alkene disulfonates depending upon the reaction conditions, proportion of reactants, the nature of the starting olefins and impurities in the olefin stock and side reactions during the sulfonation process.
  • a non limiting example of such an alpha-olefin sulfonate mixture is described in U.S. Patent 3,332,880 .
  • anionic surfactants suitable for use in the shampoo compositions are the beta-alkyloxy alkane sulfonates. These surfactants conform to the formula: where R 1 is a straight chain alkyl group having from about 6 to about 20 carbon atoms, R 2 is a lower alkyl group having from about 1 to about 3 carbon atoms, preferably 1 carbon atom, and M is a water-soluble cation as described hereinbefore.
  • Preferred anionic surfactants for use in the personal care compositions include sodium tridecyl benzene sulfonate, sodium dodecyl benzene sulfonate.
  • Amides including alkanol amides, are the condensation products of fatty acids with primary and secondary amines or alkanolamines to yield products of the general formula: wherein RCO is a fatty acid radical and R is C 8-20 ; X is an alkyl, aromatic or alkanol (CHR'CH 2 OH wherein R' is H or C 1-6 alkyl); Y is H, alkyl, alkanol or X.
  • Suitable amides include, but are not limited to cocamide, lauramide, oleamide and stearamide.
  • Suitable alkanolamides include, but are not limited to, cocamide DEA, cocamide MEA, cocamide MIPA, isostearamide DEA, isostearamide MEA, isostearamide MIPA, lanolinamide DEA, lauramide DEA, lauramide MEA, lauramide MIPA, linoleamide DEA, linoleamide MEA, linoleamide MIPA, myristamide DEA, myristamide MEA, myristamide MIPA, Oleamide DEA, Oleamide MEA, Oleamide MIPA, palmamide DEA, palmamide MEA, palmamide MIPA, palmitamide DEA, palmitamide MEA, palm kernelamide DEA, palm kernelamide MEA, palm kernelamide MIPA, peanutamide MEA, peanutamide MIPA, soyamide DEA, stearamide DEA, stearamide MEA, stearamide MIPA, tallamide DEA, tallowamide DEA, tallowamide MEA, undecylenamide
  • the condensation reaction may be carried out with free fatty acids or with all types of esters of the fatty acids, such as fats and oils, and particularly methyl esters.
  • the reaction conditions and the raw material sources determine the blend of materials in the end product and the nature of any impurities.
  • Suitable optional surfactants include nonionic surfactants. Any such surfactant known in the art for use in hair or personal care products may be used, provided that the optional additional surfactant is also chemically and physically compatible with the essential components of the personal care composition, or does not otherwise unduly impair product performance, aesthetics or stability.
  • concentration of the optional additional surfactants in the personal care composition may vary with the cleansing or lather performance desired, the optional surfactant selected, the desired product concentration, the presence of other components in the composition, and other factors well known in the art.
  • Non-limiting examples of other surfactants suitable for use in the personal care compositions are described in McCutcheon's, Emulsifiers and Detergents, 1989 Annual, published by M. C. Publishing Co. , and U.S. Pat. Nos. 3,929,678 , 2,658,072 ; 2,438,091 ; 2,528,378 .
  • Preferred silicones for use in the present invention include non-volatile silicones, siloxane gums and resins, aminofunctional silicones, quaternary silicones, and mixtures thereof with each other and with volatile silicones.
  • suitable silicone polymers for use in the present invention include those disclosed in US Patent No. 6,316,541 .
  • Silicone oils are flowable silicone materials having a viscosity, as measured at 25° C, of less than about 50,000 m 2 /s [centistokes (csk)], preferably less than 30,000 m 2 /s (csk) more preferably from 5 to 50,000 m 2 /s (csk), and even more preferably from 10 to 30,000 m 2 /s (csk)
  • Suitable silicone oils for use in the personal care compositions of the present invention include polyalkyl siloxanes, polyaryl siloxanes, polyalkylaryl siloxanes, polyether siloxane copolymers, and mixtures thereof. Other insoluble, non-volatile silicone fluids having hair conditioning properties may also be used.
  • Silicone oils include polyalkyl or polyaryl siloxanes which conform to the following formula: wherein R is aliphatic, preferably alkyl or alkenyl, or aryl, R can be substituted or unsubstituted, and x is an integer from 1 to 8,000.
  • Suitable substituted R groups for use in the personal care compositions of the present invention include, but are not limited to: alkoxy, aryloxy, alkaryl, arylalkyl, arylalkenyl, alkamino, and ether-substituted, hydroxyl-substituted, and halogen-substituted aliphatic and aryl groups.
  • dimethiconols Hydroxyl-substituted forms, commonly known as dimethiconols, are the most common silicone found in preformed microemulsions. Examples of dimethiconol microemulsions consistent with the present invention include but are not limited to DC-2-1865 silicone microemulsion, available from Dow Coming. These hydroxyl groups may be further reacted or substituted as desired to further improve performance characteristics or stability of the shampoo composition. Suitable R groups also include timethyl siloxane, cationic amines and quaternary ammonium groups.
  • Preferred alkyl and alkenyl substituents are C 1 to C 5 alkyls and alkenyls, more preferably from C 1 to C 4 , more preferably from C 1 to C 2 .
  • the aliphatic portions of other alkyl-, alkenyl-, or alkynyl-containing groups can be straight or branched chains, and are preferably from C 1 to C 5 , more preferably from C 1 to C 4 , even more preferably from C 1 to C 3 , more preferably from C 1 to C 2 .
  • the R substituents can also contain amino functionalities (e.g.
  • alkamino groups which can be primary, secondary or tertiary amines or quaternary ammonium. These include mono-, di- and tri- alkylamino and alkoxyamino groups, wherein the aliphatic portion chain length is described above.
  • microemulsions of particles of silicones for use in the invention are available and are well known and documented in the art.
  • the silicone may, for example, be a liquid at ambient temperatures, so as to be of a suitable viscosity to enable the material itself to be readily emulsified to the required particle size of about 0.15 microns or less.
  • the amount of silicone incorporated into the compositions of the invention depends on the type of composition and the material used. A preferred amount is from about 0.01 to about 10% by weight of the shampoo composition, although these limits are not absolute. The lower limit is determined by the minimum level to achieve acceptable conditioning for a target consumer group and the upper limit by the maximum level to avoid making the hair and/or skin unacceptably greasy.
  • the activity of the microemulsion can be adjusted accordingly to achieve the desired amount of silicone or a lower level of the preformed microemulsion may be added to the composition.
  • the microemulsion of silicone oil may be further stabilized by sodium lauryl sulfate or sodium lauryl ether sulfate with 1-10 moles of ethoxylation.
  • Additional emulsifier preferably chosen from anionic, cationic, nonionic, amphoteric and zwitterionic surfactants, and mixtures thereof may be present.
  • the amount of emulsifier will typically be in the ratio of 1:1 to 1:7 parts by weight of the silicone, although larger amounts of emulsifier can be used, eg. 5:1 parts by weight of the silicone or more. Use of these emulsifiers may be necessary to maintain clarity of the microemulsion if the microemulsion is diluted prior to addition to the shampoo composition.
  • the detersive surfactant of the shampoo composition may be the same surfactant as the emulsifier in the preformed microemulsion.
  • the silicone microemulsion may be further stabilized in the shampoo composition by selection of specific emulsifiers for use during the emulsion polymerization process used to make the silicone microemulsion.
  • a suitable emulsion polymerization process is described by US Patent No. 6,316,541 .
  • a typical emulsifier is TEA dodecyl benzene sulfonate which is formed in the process when triethanolamine (TEA) is used to neutralize the dodecyl benzene sulfonic acid used as the emulsion polymerization catalyst.
  • selection of the anionic counterion, typically an amine, and/or selection of the alkyl or alkenyl group in the sulfonic acid catalyst can further improve the stability of the microemulsion in the shampoo composition.
  • more hydrophobic amines than triethanol amine and more hydrophobic alkyl or alkenyl groups than dodecyl are preferred.
  • amine neutralizers which have a solubility parameter between 9.5 and 13.2 are preferred. Examples of preferred amines include but are not limited to triisopropanol amine, diisopropanol amine, and aminomethyl propanol.
  • This amine selection is not limited to use with neutralization of dodedeycl benzene sulfonic acid, it may be used with the other acid catalysts, for example other aliphatic sulfonic acids or aliphatic sulfuric acids. Other acids such as strong acids without aliphatic groups like hydrochloric acid or sulfuric acid are not as useful in the present invention.
  • Alkyl or alkenyl groups that are more hydrophobic than dodecyl are defined as those having a greater number of carbons than the 12 carbons found in the dodecyl group.
  • examples of groups, which are more hydrophobic than dodecyl include but is not limited to those with 14 or more carbon atoms, for example, groups which contain 14 carbons (tetradecyl), 16 carbons (hexadecyl), and 18 carbons (octadecyl).
  • a commercially available example of a higher chain length acid is tridecyl benzene sulfonic acid, which is available from Stepan Corporation.
  • the total level of acid emulsion polymerization catalyst present in the reaction medium is from 0.01 to 30% by weight of the total silicone.
  • Ionic surfactant catalysts are those catalysts which are neutralized acid catalysts containing alkyl or alkenyl groups as described above and are typically used at the higher end of this range.
  • compositions of the present invention contain a cationic cellulose polymer to aid in deposition of the silicone oil component and enhance conditioning performance.
  • Concentrations of the cationic polymer in the composition typically range from a 0.01% to 10%.
  • Suitable cationic polymers will have cationic charge densities of at least about 0.4 meq/gm, preferably at least about 0.0.6 meq/gm, , but also preferably less than about 7 meq/gm, more preferably less than about 5 meq/gm, at the pH of intended use of the shampoo composition, which pH will generally range from about pH 3 to about pH 9, preferably between about pH 4 and about pH 8.
  • cationic charge density of a polymer refers to the ratio of the number of positive charges on the polymer to the molecular weight of the polymer.
  • the average molecular weight of such suitable cationic cellulose polymers will be of at least 800,000 Suitable cationic polymers for use in the compositions of the present invention contain cationic nitrogen-containing moieties such as quaternary ammonium or cationic protonated amino moieties.
  • the cationic protonated amines can be primary, secondary, or tertiary amines (preferably secondary or tertiary), depending upon the particular species and the selected pH of the composition.
  • Any anionic counterions can be used in association with the cationic polymers so long as the polymers remain soluble in water, in the composition, or in a coacervate phase of the composition, and so long as the counterions are physically and chemically compatible with the essential components of the composition or do not otherwise unduly impair product performance, stability or aesthetics.
  • Non limiting examples of such counterions include halides (e.g., chloride, fluoride, bromide, iodide), sulfate and methylsulfate.
  • Non limiting examples of such polymers are described in the CTFA Cosmetic Ingredient Dictionary, 3rd edition, edited by Estrin, Crosley, and Haynes, (The Cosmetic, Toiletry, and Fragrance Association, Inc., Washington, D.C. (1982 )).
  • Suitable cationic polymers for use in the composition include polysaccharide polymers, such as cationic cellulose derivatives.
  • Suitable cationic polysaccharide polymers include those which conform to the formula: wherein A is an anhydroglucose residual group, such as cellulose anhydroglucose residual; R is an alkylene oxyalkylene, polyoxyalkylene, or hydroxyalkylene group, or combination thereof; R1, R2, and R3 independently are alkyl, aryl, alkylaryl, arylalkyl, alkoxyalkyl, or alkoxyaryl groups, each group containing up to about 18 carbon atoms, and the total number of carbon atoms for each cationic moiety (i.e., the sum of carbon atoms in R1, R2 and R3) preferably being about 20 or less; and X is an anionic counterion as described in hereinbefore.
  • Preferred cationic cellulose polymers are salts of hydroxyethyl cellulose reacted with trimethyl ammonium substituted epoxide, referred to in the industry (CTFA) as Polyquaternium 10 and available from Amerchol Corporation (Edison, N.3., USA) in their Polymer LR, JR, JP and KG series of polymers.
  • CTFA trimethyl ammonium substituted epoxide
  • Other suitable types of cationic cellulose includes the polymeric quaternary ammonium salts of hydroxyethyl cellulose reacted with lauryl dimethyl ammonium-substituted epoxide referred to in the industry (CTFA) as Polyquaternium 24. These materials are available from Amerchol Corporation under the tradename Polymer LM-200.
  • the cationic polymers herein are either soluble in the composition or are soluble in a complex coacervate phase in the composition formed by the cationic polymer and the anionic, amphoteric and/or zwitterionic detersive surfactant component described hereinbefore.
  • Complex coacervates of the cationic polymer can also be formed with other charged materials in the composition.
  • Preferred cationic polymers include polymers of sufficiently high cationic charge density to effectively enhance deposition efficiency of the solid particle components described herein.
  • Preferred cationic polymers comprise cationic cellulose polymers with cationic charge densities of at least about 0.5 meq/gm and preferably less than about 7 meq/gm.
  • Preferred cationic cellulose polymers salts of hydroxyethyl cellulose reacted with trimethyl ammonium substituted epoxide, referred to in the industry (CTFA) as Polyquaternium 10 and available from Amerchol Corp.
  • CTFA trimethyl ammonium substituted epoxide
  • Ucare Polymer JR30M with a charge density of 1.32 and a molecular weight of approximately 2,000,000
  • Ucare Polymer KG30M with a charge density of 1.96 and a molecular weight of approximately 2,000,000
  • Ucare Polymer JP with a charge density of 0.7 and a molecular weight of approximately 2,000,000.
  • Suitable electrolytes include but are not limited to sodium chloride, sodium benzoate, magnesium chloride, and magnesium sulfate.
  • the deposition polymer is present in an amount of from 0.01 to 10% by weight of the total composition, preferably from 0.01 to 1% by weight, even more preferably from 0.04 to 0.6% by weight.
  • compositions of the invention are preferably aqueous based, water forming the basis of the continuous phase of the microemulsion.
  • the compositions preferably comprise water in an amount of from about 20 to about 99% by weight of the total composition.
  • Compositions of the present invention may contain a stabilizing component, which helps to maintain the viscosity of the shampoo base containing the silicone microemulsion. Upon storage, the viscosity of shampoo bases containing silicone microemulsion can drop nearly 50%, to a level below consumer preference. By adding a stabilizing component, the viscosity of the shampoo composition itself is maintained at a consumer preferred viscosity of at least about 1500 cps.
  • Suitable stabilizing components stabilize the microemulsion structure by preventing the migration of a small weight fraction of silicone from the internal phase of the microemulsion into the continuous phase of the shampoo composition.
  • Said stabilizing components include but are not limited to water soluble thickeners, non-ionic surfactants, and polymeric emulsifiers.
  • a thickener added in addition to the cationic deposition polymer is an example of a stabilizing component.
  • thickeners include hydroxyl ethyl cellulose derivatives such as Methocel series available from Amerchol Corporation and the Natrosol series available from Aqualon, crosslinked polyacrylates such the Carbopol series available from Noveon, and Gellan Gum available from CP Kelco Corporation.
  • Nonionic surfactants are typically found in the preformed silicone microemulsion. Addition of more nonionic surfactants to the shampoo can further enhance stability. Preferred non-ionic surfactants have an HLB range of 9-18. These surfactants can be either straight chained or branched typically containing various levels of ethoxylation/propoxylation.
  • the nonionic surfactants useful in the present invention are preferably formed from a fatty alcohol, a fatty acid, or a glyceride with a C 8 to C 24 carbon chain, preferably a C 12 to C 18 carbon chain derivatized to yield a Hydrophilic-Lipophilic Balance (HLB) of at least 9.
  • HLB Hydrophilic-Lipophilic Balance
  • HLB is understood to mean the balance between the size and strength of the hydrophilic group and the size and strength of the lipophilic group of the surfactant.
  • Such derivatives can be polymers such as ethoxylates, propoxylates, polyglucosides, polyglycerins, polylactates, polyglycolates, polysorbates, and others that would be apparent to one of ordinary skill in the art.
  • Such derivatives may also be mixed monomers of the above, such as ethoxylate/propoxylate species, where the total HLB is preferably greater than or equal to 9.
  • nonionic surfactants examples include but are not limited to BRIJ 35, BRIJ 30, Arlasolve 200, Surfonic L22-24, Tween 20, Volpo-20, Pluronic L64, Pluronic P103, Pluronic L35.
  • Polymeric emulsifiers such as Plantaren 2000 from Cognis, Pemulen TR-1 and Pemulen TR-2 from Noveon, and the Arlacel series from Unichema may also be useful in the present invention. These materials if present are included at a concentration of from about 0.1 % to about 0.5 % by weight of the total composition.
  • compositions of the invention are preferably rinse-off compositions, i.e., suitable for applying to the hair and/or skin, left thereon for an appropriate period of time and then rinsed off with water.
  • compositions in accordance with the present invention are most preferably optically clear.
  • additional ingredients conventionally incorporated into shampoo formulations may be included in the compositions of the invention.
  • additional ingredients include antibacterial agents, antidandruff agents, foam boosters, perfumes, coloring agents, preservatives, viscosity modifiers, proteins, polymers, buffering or pH adjusting agents, moisturizing agents, herb or other plant extracts and other natural ingredients.
  • Examples 5, 6 and 11 are not representative of the present invention.
  • Examples 1-6 Ingredient 1 2 3 4 5 6 Water q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. q.s. s.
  • Polyquaterium 10 0.5 0.5 Polyquaterium 10 2 0.25 Guar Hydroxypropyl Trimonium Chloride 3 0.1 0.2 Polyquaterium 10 4 0.1 Sodium Laureth Sulfate (SLE3S-29% active) 5 41.38 51.72 41.38 41.38 24.12 27.58 Sodium Laurel Sulfate (SLS - 29% active) 6 10.34 17.24 6.9 6.9 24.12 22.07 Dimethiconol Microemulsion A 7 4.0 1.0 4.0 Low D4 Dimethiconol Microemulsion B 8 8.0 8.0 Dimethiconol Microemulsion C 9 1.0 Disodium Coco Amphodiacetate 10 5.0 5.0 Cocoamdopropyl Betaine 11 2.0 6.67 6.67 6.67 PPG-2 Hydroxyethyl Coco/IsoStearamde 12 2.0 2.0 2.0 2.0 2.0 2.0 2 Magnesium Chloride, hexahydrate 13 0.5 0.5 Sodium Chloride 14 0.5 0.75 1.0 0.5 1.0

Landscapes

  • Health & Medical Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Animal Behavior & Ethology (AREA)
  • Public Health (AREA)
  • Veterinary Medicine (AREA)
  • Epidemiology (AREA)
  • Birds (AREA)
  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Nanotechnology (AREA)
  • Biophysics (AREA)
  • General Engineering & Computer Science (AREA)
  • Medical Informatics (AREA)
  • Medicinal Chemistry (AREA)
  • Molecular Biology (AREA)
  • Pharmacology & Pharmacy (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Biotechnology (AREA)
  • Bioinformatics & Cheminformatics (AREA)
  • Dermatology (AREA)
  • Dispersion Chemistry (AREA)
  • Cosmetics (AREA)

Claims (12)

  1. Shampoozusammensetzung, umfassend:
    (a) von 2 Gew.-% bis 35 Gew.-% mindestens ein Tensid, wobei ein anionisches Tensid vorhanden ist;
    (b) von 0,01 Gew.-% bis 10 Gew.-% ein Silikonöl mit einer Viskosität der internen Phase von weniger als 50.000 m2/s (cST), wobei das Silikonöl als vorgefertigte Mikroemulsion von Teilchen mit einer durchschnittlichen Teilchengröße von weniger als 0,15 Mikrometern vorhanden ist, wobei die Emulsion Wasser, Tensid und die Teilchen umfasst;
    wobei das Moläquivalent von Tensid in der Shampoozusammensetzung gleich oder größer als das Moläquivalent von Tensid in der vorgefertigten Mikroemulsion ist;
    (c) von 0,01 Gew.-% bis 10 Gew.-% ein kationisches Abscheidepolymer, ausgewählt aus der Gruppe bestehend aus kationischen Cellulosepolymeren mit einem Molekulargewicht von mindestens 800.000;
    (d) einen wässrigen Träger; und
    (e) wahlweise von 0 % bis 5 % ein Stabilisierungsmittel.
  2. Zusammensetzung nach Anspruch 1, wobei das Silikonöl aus nichtflüchtigen Silikonen, Siloxangummis und Harzen, aminofunktionellen Silikonen, quartären Silikonen und Mischungen davon miteinander und mit flüchtigen Silikonen ausgewählt ist.
  3. Zusammensetzung nach Anspruch 2, wobei das Silikonöl ausgewählt ist aus der Gruppe bestehend aus Polyalkylsiloxanen und Polyarylsiloxanen, wobei die Polyalkylsiloxane und Polyarylsiloxane Hydroxylgruppen enthalten.
  4. Zusammensetzung nach Anspruch 3, wobei die Hydroxylgruppen mit Trimethylsiloxan substituiert sind.
  5. Zusammensetzung nach Anspruch 1, wobei die Teilchen von Silikonöl eine Teilchengröße von weniger als 0,1 Mikrometern aufweisen.
  6. Zusammensetzung nach Anspruch 1, wobei das Silikonöl in einer Menge von 0,1 bis 5 Gew.-% in der Zusammensetzung vorhanden ist.
  7. Zusammensetzung nach Anspruch 1, wobei das Stabilisierungsmittel ein polymeres wasserlösliches Verdickungsmittel ist.
  8. Zusammensetzung nach Anspruch 1, wobei das Stabilisierungsmittel ein nichtionisches Tensid zusätzlich zu jeglichem Tensid, das bereits in der vorgefertigten Emulsion vorhanden ist, ist, wobei das nichtionische Tensid ausgewählt ist aus der Gruppe bestehend aus nichtionischen Tensiden mit einem HLB-Bereich von 9 bis 18, und von 0,05 % bis 5 % der gesamten Shampoozusammensetzung.
  9. Zusammensetzung nach Anspruch 1, wobei das Silikon zu weniger als 1 % Cyclotetrasiloxan umfasst.
  10. Zusammensetzung nach Anspruch 1, wobei die Shampoozusammensetzung vor der Zugabe von Farbstoffen und/oder Pigmenten eine prozentuale Durchlässigkeit bei 600 nm von mindestens 75 % aufweist.
  11. Zusammensetzung nach Anspruch 1, wobei die Zusammensetzung nach einem Zeitraum von mindestens sieben Tagen bei einer Temperatur von 120 °C mindestens 60 % der ursprünglichen Viskosität der Zusammensetzungen behält.
  12. Shampoozusammensetzung nach Anspruch 1, wobei das Silikonöl eine Viskosität der internen Phase von weniger als 30.000 m2/s (cST) aufweist.
EP05711564A 2004-01-16 2005-01-11 Konditionierungsshampoo-zusammensetzungen Active EP1722860B1 (de)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US53711904P 2004-01-16 2004-01-16
PCT/US2005/001516 WO2005072687A1 (en) 2004-01-16 2005-01-11 Conditioning shampoo compositions

Publications (2)

Publication Number Publication Date
EP1722860A1 EP1722860A1 (de) 2006-11-22
EP1722860B1 true EP1722860B1 (de) 2010-07-07

Family

ID=34825915

Family Applications (1)

Application Number Title Priority Date Filing Date
EP05711564A Active EP1722860B1 (de) 2004-01-16 2005-01-11 Konditionierungsshampoo-zusammensetzungen

Country Status (11)

Country Link
US (1) US8435501B2 (de)
EP (1) EP1722860B1 (de)
JP (1) JP2007517805A (de)
CN (1) CN1909884A (de)
AT (1) ATE473035T1 (de)
AU (1) AU2005209211B2 (de)
BR (1) BRPI0506874B1 (de)
CA (1) CA2551850A1 (de)
DE (1) DE602005022166D1 (de)
ES (1) ES2347798T3 (de)
WO (1) WO2005072687A1 (de)

Families Citing this family (53)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2862221B1 (fr) * 2003-11-18 2008-10-10 Oreal Composition cosmetique comprenant de la gomme de gellane ou un derive, un sel monovalent et un compose en suspension, procedes mettant en oeuvre cette composition et utilisations
US8399001B2 (en) 2003-11-18 2013-03-19 L'oreal Cosmetic composition comprising at least one gellan gum or derivative thereof, at least one monovalent salt, and at least one suspension compound, processes using this composition, and uses thereof
US7915214B2 (en) * 2006-01-12 2011-03-29 Amcol International Corporation Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles
US7871972B2 (en) * 2005-01-12 2011-01-18 Amcol International Corporation Compositions containing benefit agents pre-emulsified using colloidal cationic particles
US7569533B2 (en) * 2005-01-12 2009-08-04 Amcol International Corporation Detersive compositions containing hydrophobic benefit agents pre-emulsified using sub-micrometer-sized insoluble cationic particles
US7977288B2 (en) * 2005-01-12 2011-07-12 Amcol International Corporation Compositions containing cationically surface-modified microparticulate carrier for benefit agents
WO2007096046A1 (en) * 2006-02-20 2007-08-30 Unilever Plc Conditioning shampoo compositions
US20080097070A1 (en) * 2006-10-19 2008-04-24 L'oreal Aqueous polyamine-containing systems for water-insoluble materials
CN101568326A (zh) * 2006-12-21 2009-10-28 宝洁公司 包含硅氧烷弹性体的个人护理组合物
CA2691036A1 (en) 2007-05-14 2008-11-27 Amcol International Corporation Compositions containing benefit agent composites pre-emulsified using colloidal cationic particles
DE102007037122A1 (de) 2007-08-01 2009-02-05 Beiersdorf Ag Haarbehandlungsmittel mit einem Gehalt an Diamanten
DE102007050371A1 (de) 2007-10-17 2009-04-23 Beiersdorf Ag Haarbehandlungsmittel VII
EP2249769B1 (de) * 2008-03-14 2016-10-05 Unilever PLC Haarkonditionierungszusammensetzungen
US8188022B2 (en) 2008-04-11 2012-05-29 Amcol International Corporation Multilayer fragrance encapsulation comprising kappa carrageenan
DE102008034388A1 (de) * 2008-07-23 2010-01-28 Henkel Ag & Co. Kgaa Tensidhaltige Zusammensetzung mit spezieller Emulgatormischung
WO2010051151A2 (en) * 2008-10-09 2010-05-06 Hercules Incorporated Cleansing formulations comprising non-cellulosic polysaccharides with mixed cationic substituents
US20100202985A1 (en) * 2009-02-11 2010-08-12 Amcol International Corporation Sunscreen compositions including particulate sunscreen actives that exhibit boosting of sun protection factor
KR101600021B1 (ko) * 2009-06-19 2016-03-04 애경산업(주) 투명 컨디셔닝 샴푸 조성물
FR2954129B1 (fr) * 2009-12-23 2012-03-02 Oreal Composition cosmetique comprenant au moins un compose organique du silicium, au moins deux tensioactifs anioniques et au moins un tensioactif amphotere
FR2954100B1 (fr) * 2009-12-23 2012-03-09 Oreal Composition cosmetique comprenant au moins un compose organique du silicium, au moins un tensioactif anionique et au moins un polymere cationique
FR2954128B1 (fr) * 2009-12-23 2012-02-17 Oreal Composition cosmetique comprenant au moins un compose organique du silicium, au moins un tensioactif anionique et au moins un agent epaississant non ionique ainsi qu'un procede mettant en oeuvre la composition
CN103826600A (zh) 2011-04-01 2014-05-28 考格尼斯知识产权管理有限责任公司 毛发护理剂
US8980239B2 (en) 2011-10-07 2015-03-17 The Procter & Gamble Company Personal care compositions and methods of making same
CN104053477B (zh) * 2012-01-18 2017-06-09 荷兰联合利华有限公司 毛发处理组合物
CN105338953B (zh) 2013-05-22 2018-09-28 宝洁公司 实现改善的产品流变特性、化妆品消费者接受度和沉积的方法
CN104800118B (zh) * 2015-04-17 2017-08-22 云南健牛生物科技有限公司 一种防脱止痒半透明洗发水及其制备方法
CN114601744A (zh) 2015-04-23 2022-06-10 宝洁公司 表面活性剂可溶性去头皮屑剂的递送
JP6813586B2 (ja) 2016-03-03 2021-01-13 ザ プロクター アンド ギャンブル カンパニーＴｈｅ Ｐｒｏｃｔｅｒ ＆ Ｇａｍｂｌｅ Ｃｏｍｐａｎｙ エアゾールフケ防止組成物
CN109310320B (zh) 2016-03-23 2022-09-06 宝洁公司 用于确定杂散纤维的成像方法
EP3528899B1 (de) 2016-10-21 2024-04-10 The Procter & Gamble Company Darreichungsform von schaum zur abgabe einer benutzerseitig gewünschten dosiermenge und tensidmenge in einer optimalen formulierung
WO2018075833A1 (en) 2016-10-21 2018-04-26 The Procter & Gamble Company Low viscosity hair care composition
WO2018075841A1 (en) 2016-10-21 2018-04-26 The Procter & Gamble Company Concentrated shampoo dosage of foam for providing hair care benefits
EP3528894A1 (de) 2016-10-21 2019-08-28 The Procter and Gamble Company Konzentrierte shampoodosierung von schaum zur bereitstellung von haarpflegenutzen
US11154467B2 (en) 2016-10-21 2021-10-26 The Procter And Gamble Plaza Concentrated shampoo dosage of foam designating hair conditioning benefits
WO2018075855A1 (en) 2016-10-21 2018-04-26 The Procter & Gamble Company Dosage of foam for delivering consumer desired dosage volume, surfactant amount, and scalp health agent amount in an optimal formulation space
CN109789076A (zh) 2016-10-21 2019-05-21 宝洁公司 具有低粘度和粘度降低剂的稳定致密洗发剂产品
EP3528774A1 (de) 2016-10-21 2019-08-28 The Procter and Gamble Company Konzentrierte shampoo-dosierung von schaum zur bestimmung von haarpflegevorteilen
US11679073B2 (en) 2017-06-06 2023-06-20 The Procter & Gamble Company Hair compositions providing improved in-use wet feel
US11141370B2 (en) 2017-06-06 2021-10-12 The Procter And Gamble Company Hair compositions comprising a cationic polymer mixture and providing improved in-use wet feel
US11224567B2 (en) 2017-06-06 2022-01-18 The Procter And Gamble Company Hair compositions comprising a cationic polymer/silicone mixture providing improved in-use wet feel
WO2019074991A1 (en) 2017-10-10 2019-04-18 The Procter & Gamble Company COMPACT SHAMPOO COMPOSITION COMPRISING ANIONIC AMINO ACID SURFACTANTS AND CATIONIC POLYMERS
US10426713B2 (en) 2017-10-10 2019-10-01 The Procter And Gamble Company Method of treating hair or skin with a personal care composition in a foam form
EP4427727A2 (de) 2017-10-10 2024-09-11 The Procter & Gamble Company Kompakte shampoozusammensetzung mit sulfatfreien tensiden
CN111278417A (zh) 2017-10-10 2020-06-12 宝洁公司 含低无机盐的无硫酸盐澄清个人清洁组合物
US10912732B2 (en) 2017-12-20 2021-02-09 The Procter And Gamble Company Clear shampoo composition containing silicone polymers
EP3813774A1 (de) 2018-06-29 2021-05-05 The Procter & Gamble Company Tensidarme aerosolantischuppenzusammensetzung
WO2021051133A1 (en) 2019-09-10 2021-03-18 The Procter & Gamble Company Personal care compositions comprising anti-dandruff agents
CN114746153A (zh) 2019-12-06 2022-07-12 宝洁公司 具有增强头皮活性物质沉积的不含硫酸盐的组合物
MX2022009191A (es) 2020-02-27 2022-08-18 Procter & Gamble Composiciones anticaspa con azufre que tienen eficacia y estetica mejoradas.
CA3181421A1 (en) * 2020-05-15 2021-11-18 The Procter & Gamble Company Shampoo composition comprising decyl glucoside and a cationic guar
WO2022120109A1 (en) 2020-12-04 2022-06-09 The Procter & Gamble Company Hair care compositions comprising malodor reduction materials
US11771635B2 (en) 2021-05-14 2023-10-03 The Procter & Gamble Company Shampoo composition
US11986543B2 (en) 2021-06-01 2024-05-21 The Procter & Gamble Company Rinse-off compositions with a surfactant system that is substantially free of sulfate-based surfactants

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5037818A (en) * 1982-04-30 1991-08-06 Chesebrough-Pond's Usa Co., Division Of Conopco, Inc. Washing composition for the hair
PH27596A (en) * 1989-12-04 1993-08-31 Unilever Nv Hair treatment composition
CA2041599A1 (en) * 1990-06-01 1991-12-02 Michael Gee Method for making polysiloxane emulsions
GB9016100D0 (en) * 1990-07-23 1990-09-05 Unilever Plc Shampoo composition
GB9117740D0 (en) * 1991-08-16 1991-10-02 Unilever Plc Cosmetic composition
ZA931613B (en) * 1992-04-15 1993-11-15 Curtis Helene Ind Inc Conditioning shampoo composition and method of preparing and using the same
GB9320556D0 (en) * 1993-10-06 1993-11-24 Unilever Plc Hair conditioning composition
BR9408437A (pt) 1993-12-30 1997-08-05 Procter & Gamble Xampús de alta deposição e de alta formação de espuma com sistema tensoativo suave
GB9406555D0 (en) 1994-03-31 1994-05-25 Unilever Plc Shampoo composition
US6180117B1 (en) * 1994-05-27 2001-01-30 General Electric Company Method of preparing microemulsions of amino silicone fluids and MQ resin mixtures
ATE204737T1 (de) * 1995-04-21 2001-09-15 Procter & Gamble Shampoos mit konditionierungsmittel aus unlöslichen silikon, und kationischem polymer
GB9619761D0 (en) * 1996-09-23 1996-11-06 Unilever Plc Shampoo composition
US6200554B1 (en) * 1996-10-16 2001-03-13 The Procter & Gamble Company Conditioning shampoo compositions having improved silicone deposition
US5756720A (en) * 1996-10-25 1998-05-26 Rhodia Inc. Derivatized guar gum composition including nonionic and cationic groups which demonstrate excellent solution clarity properties
GB9726969D0 (en) * 1997-12-19 1998-02-18 Unilever Plc Mousse-forming shampoo compositions
FR2773710B1 (fr) * 1998-01-19 2000-04-28 Rhodia Chimie Sa Utilisation dans les compositions cosmetiques, d'agents tensioactifs amphoteres pour precipiter, a la dilution, des polymeres cationiques
WO1999039683A1 (en) 1998-02-06 1999-08-12 The Procter & Gamble Company Anti-dandruff shampoo composition comprising a cool-feeling agent
GB9808310D0 (en) * 1998-04-20 1998-06-17 Unilever Plc Shampoo compositions
GB9810856D0 (en) 1998-05-20 1998-07-22 Unilever Plc Hair treatment composition
GB9827224D0 (en) * 1998-12-10 1999-02-03 Unilever Plc Washing compositions
US20030133899A1 (en) * 2000-10-31 2003-07-17 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Personal cleansing compositions that contain surfactants, co-surfactants, water insoluble solids and/or liquids and cationic conditioning polymers
AU2002223648A1 (en) 2000-10-31 2002-05-15 Unilever Plc Personal cleansing composition
MX275023B (es) 2002-06-04 2010-04-08 Procter & Gamble Champu que contiene una red de gel.
CA2682799A1 (en) 2002-06-04 2003-12-11 The Procter & Gamble Company Conditioning shampoo compositions containing surfactant and cationic copolymer combination that forms liquid crystals
CA2487124C (en) 2002-06-18 2010-12-14 The Procter & Gamble Company Composition containing a cationic polymer with a high charge density and a conditioning agent
US7541320B2 (en) * 2004-01-23 2009-06-02 Unilever Home & Personal Care Usa, Division Of Conopco, Inc. Mild, viscous cleansing composition with versatile compatibility and enhanced conditioning

Also Published As

Publication number Publication date
WO2005072687A1 (en) 2005-08-11
ATE473035T1 (de) 2010-07-15
CN1909884A (zh) 2007-02-07
BRPI0506874B1 (pt) 2017-05-16
US8435501B2 (en) 2013-05-07
AU2005209211A1 (en) 2005-08-11
EP1722860A1 (de) 2006-11-22
DE602005022166D1 (de) 2010-08-19
JP2007517805A (ja) 2007-07-05
BRPI0506874A (pt) 2007-11-20
ES2347798T3 (es) 2010-11-04
AU2005209211B2 (en) 2008-05-22
US20050158266A1 (en) 2005-07-21
CA2551850A1 (en) 2005-08-11

Similar Documents

Publication Publication Date Title
EP1722860B1 (de) Konditionierungsshampoo-zusammensetzungen
EP0975311B1 (de) Styling-shampoo-zusammensetzungen enthaltend kationische styling polymere
AU2004243022B2 (en) Clear personal care compositions containing a cationic conditioning polymer and an anionic surfactant system
EP0889716B1 (de) Shampoo mit haarkonditionierenden eigenschaften
EP2763651B1 (de) Verfahren zur erzielung eines besseren haargefühls
AU709662B2 (en) Conditioning shampoo composition
US20040158940A1 (en) Phase-separated rinse-off hair coloring/cleansing products
WO1998031327A1 (en) Personal cleansing compositions
EP0981326A1 (de) Körperpflegemittel
WO2000051556A1 (en) Hair care compositions comprising amino acid compounds
US7300647B1 (en) Hair care compositions
JP2006526023A (ja) カチオン性コンディショニングポリマー及びアニオン性界面活性剤系を含有する透明なパーソナルケア組成物
EP2143417A1 (de) Reinigende kosmetische Zusammensetzungen enthaltend ein aminosilikon und deren Verwendung
MXPA06007606A (en) Conditioning shampoo compositions
AU2007221984A1 (en) Composition containing a cationic polymer with a high charge density and a conditioning agent

Legal Events

Date Code Title Description
PUAI Public reference made under article 153(3) epc to a published international application that has entered the european phase

Free format text: ORIGINAL CODE: 0009012

17P Request for examination filed

Effective date: 20060616

AK Designated contracting states

Kind code of ref document: A1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

17Q First examination report despatched

Effective date: 20070205

DAX Request for extension of the european patent (deleted)
GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAC Information related to communication of intention to grant a patent modified

Free format text: ORIGINAL CODE: EPIDOSCIGR1

GRAJ Information related to disapproval of communication of intention to grant by the applicant or resumption of examination proceedings by the epo deleted

Free format text: ORIGINAL CODE: EPIDOSDIGR1

GRAP Despatch of communication of intention to grant a patent

Free format text: ORIGINAL CODE: EPIDOSNIGR1

GRAS Grant fee paid

Free format text: ORIGINAL CODE: EPIDOSNIGR3

GRAA (expected) grant

Free format text: ORIGINAL CODE: 0009210

AK Designated contracting states

Kind code of ref document: B1

Designated state(s): AT BE BG CH CY CZ DE DK EE ES FI FR GB GR HU IE IS IT LI LT LU MC NL PL PT RO SE SI SK TR

REG Reference to a national code

Ref country code: GB

Ref legal event code: FG4D

REG Reference to a national code

Ref country code: CH

Ref legal event code: EP

REG Reference to a national code

Ref country code: IE

Ref legal event code: FG4D

REF Corresponds to:

Ref document number: 602005022166

Country of ref document: DE

Date of ref document: 20100819

Kind code of ref document: P

REG Reference to a national code

Ref country code: SE

Ref legal event code: TRGR

REG Reference to a national code

Ref country code: NL

Ref legal event code: VDEP

Effective date: 20100707

REG Reference to a national code

Ref country code: ES

Ref legal event code: FG2A

Ref document number: 2347798

Country of ref document: ES

Kind code of ref document: T3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

LTIE Lt: invalidation of european patent or patent extension

Effective date: 20100707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: NL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

Ref country code: LT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

Ref country code: FI

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

Ref country code: AT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IS

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101107

Ref country code: BG

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101007

Ref country code: PL

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

Ref country code: PT

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101108

Ref country code: CY

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: BE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

Ref country code: GR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20101008

PLBI Opposition filed

Free format text: ORIGINAL CODE: 0009260

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: DK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

PLAX Notice of opposition and request to file observation + time limit sent

Free format text: ORIGINAL CODE: EPIDOSNOBS2

26 Opposition filed

Opponent name: KPSS-KAO PROFESSIONAL SALON SERVICES GMBH

Effective date: 20110406

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SK

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

Ref country code: CZ

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

Ref country code: EE

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

Ref country code: RO

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

REG Reference to a national code

Ref country code: DE

Ref legal event code: R026

Ref document number: 602005022166

Country of ref document: DE

Effective date: 20110406

PLBB Reply of patent proprietor to notice(s) of opposition received

Free format text: ORIGINAL CODE: EPIDOSNOBS3

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: MC

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110131

REG Reference to a national code

Ref country code: CH

Ref legal event code: PL

REG Reference to a national code

Ref country code: IE

Ref legal event code: MM4A

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LI

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110131

Ref country code: CH

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110131

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110111

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

R26 Opposition filed (corrected)

Opponent name: KAO GERMANY GMBH

Effective date: 20110406

PLCK Communication despatched that opposition was rejected

Free format text: ORIGINAL CODE: EPIDOSNREJ1

APBM Appeal reference recorded

Free format text: ORIGINAL CODE: EPIDOSNREFNO

APBP Date of receipt of notice of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA2O

APAH Appeal reference modified

Free format text: ORIGINAL CODE: EPIDOSCREFNO

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: LU

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20110111

APBQ Date of receipt of statement of grounds of appeal recorded

Free format text: ORIGINAL CODE: EPIDOSNNOA3O

PLAB Opposition data, opponent's data or that of the opponent's representative modified

Free format text: ORIGINAL CODE: 0009299OPPO

R26 Opposition filed (corrected)

Opponent name: KAO GERMANY GMBH

Effective date: 20110406

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: TR

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: HU

Free format text: LAPSE BECAUSE OF FAILURE TO SUBMIT A TRANSLATION OF THE DESCRIPTION OR TO PAY THE FEE WITHIN THE PRESCRIBED TIME-LIMIT

Effective date: 20100707

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 12

REG Reference to a national code

Ref country code: DE

Ref legal event code: R100

Ref document number: 602005022166

Country of ref document: DE

APBU Appeal procedure closed

Free format text: ORIGINAL CODE: EPIDOSNNOA9O

PLBN Opposition rejected

Free format text: ORIGINAL CODE: 0009273

STAA Information on the status of an ep patent application or granted ep patent

Free format text: STATUS: OPPOSITION REJECTED

27O Opposition rejected

Effective date: 20160705

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 13

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: SE

Payment date: 20170109

Year of fee payment: 13

REG Reference to a national code

Ref country code: FR

Ref legal event code: PLFP

Year of fee payment: 14

REG Reference to a national code

Ref country code: SE

Ref legal event code: EUG

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: SE

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20180112

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: IT

Payment date: 20201211

Year of fee payment: 17

PG25 Lapsed in a contracting state [announced via postgrant information from national office to epo]

Ref country code: IT

Free format text: LAPSE BECAUSE OF NON-PAYMENT OF DUE FEES

Effective date: 20220111

P01 Opt-out of the competence of the unified patent court (upc) registered

Effective date: 20230429

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: GB

Payment date: 20231130

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: FR

Payment date: 20231212

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: ES

Payment date: 20240208

Year of fee payment: 20

PGFP Annual fee paid to national office [announced via postgrant information from national office to epo]

Ref country code: DE

Payment date: 20231205

Year of fee payment: 20