EP1474654A1 - Method and device for optically measuring the surface shape and for the optical surface inspection of moving strips in rolling and processing installations - Google Patents
Method and device for optically measuring the surface shape and for the optical surface inspection of moving strips in rolling and processing installationsInfo
- Publication number
- EP1474654A1 EP1474654A1 EP03704560A EP03704560A EP1474654A1 EP 1474654 A1 EP1474654 A1 EP 1474654A1 EP 03704560 A EP03704560 A EP 03704560A EP 03704560 A EP03704560 A EP 03704560A EP 1474654 A1 EP1474654 A1 EP 1474654A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- measurement
- strip
- surface shape
- measuring
- pattern
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01B—MEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
- G01B11/00—Measuring arrangements characterised by the use of optical techniques
- G01B11/30—Measuring arrangements characterised by the use of optical techniques for measuring roughness or irregularity of surfaces
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01B—MEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
- G01B11/00—Measuring arrangements characterised by the use of optical techniques
- G01B11/24—Measuring arrangements characterised by the use of optical techniques for measuring contours or curvatures
- G01B11/25—Measuring arrangements characterised by the use of optical techniques for measuring contours or curvatures by projecting a pattern, e.g. one or more lines, moiré fringes on the object
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B38/00—Methods or devices for measuring, detecting or monitoring specially adapted for metal-rolling mills, e.g. position detection, inspection of the product
- B21B38/02—Methods or devices for measuring, detecting or monitoring specially adapted for metal-rolling mills, e.g. position detection, inspection of the product for measuring flatness or profile of strips
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01B—MEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
- G01B11/00—Measuring arrangements characterised by the use of optical techniques
- G01B11/24—Measuring arrangements characterised by the use of optical techniques for measuring contours or curvatures
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01B—MEASURING LENGTH, THICKNESS OR SIMILAR LINEAR DIMENSIONS; MEASURING ANGLES; MEASURING AREAS; MEASURING IRREGULARITIES OF SURFACES OR CONTOURS
- G01B11/00—Measuring arrangements characterised by the use of optical techniques
- G01B11/30—Measuring arrangements characterised by the use of optical techniques for measuring roughness or irregularity of surfaces
- G01B11/306—Measuring arrangements characterised by the use of optical techniques for measuring roughness or irregularity of surfaces for measuring evenness
-
- G—PHYSICS
- G01—MEASURING; TESTING
- G01N—INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
- G01N21/00—Investigating or analysing materials by the use of optical means, i.e. using sub-millimetre waves, infrared, visible or ultraviolet light
- G01N21/84—Systems specially adapted for particular applications
- G01N21/88—Investigating the presence of flaws or contamination
- G01N21/89—Investigating the presence of flaws or contamination in moving material, e.g. running paper or textiles
- G01N21/8901—Optical details; Scanning details
- G01N21/8903—Optical details; Scanning details using a multiple detector array
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B21—MECHANICAL METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL; PUNCHING METAL
- B21B—ROLLING OF METAL
- B21B38/00—Methods or devices for measuring, detecting or monitoring specially adapted for metal-rolling mills, e.g. position detection, inspection of the product
Definitions
- the invention relates to a method and device for the optical measurement of the surface shape and for the optical surface inspection of moving strips in rolling and further processing plants.
- the strip flatness is therefore preferably measured contactlessly in hot strip mills.
- it is known to measure flatness deviations with the aid of light points projected onto the strip.
- the spatial position of the light spot which is preferably generated with the aid of a laser beam on the strip surface, is detected with a distance sensor.
- the two plane location coordinates of a certain surface point are known from the relative position between the scanning or illuminating beam and the surface of the strip.
- the height coordinate of the surface point that is currently being measured is detected by a location-sensitive detector. With the height coordinate, the position of the imaging point on the sensor changes at the same time.
- a flatness image can be created across the entire width of the strip, which is composed of the measurement results of the light points projected onto the strip at certain intervals.
- the areas between the light points are which, however, are not recorded in this method and form strip-shaped measurement gaps in the case of a continuous strip, the flatness of which is not determined.
- An interference pattern is generated on the object surface by means of a light source.
- CCD Charge-Coupled Device
- the camera is arranged so that there is an angle between the surface light source and the camera.
- a reference grid in the image plane creates a so-called moire effect by superimposing the recorded pattern on the reference pattern.
- the height differences can be determined quantitatively from the Moire lines.
- Moire technology provides more precise measurement results than measuring with light points; it also covers essentially the entire measurement area and avoids the measurement gaps mentioned above. However, use in a hot strip mill is problematic.
- a device for measuring the surface of a metal strip is known from US Pat. No. 5,488,478, in which lines are generated on the metal surface with the aid of a laser beam, which lines are recorded by a plurality of linescan cameras and evaluated by comparison with a reference pattern for determining the surface geometry. This device requires considerable design effort and, moreover, only allows a rough partial statement about the surface geometry of the belt.
- DE 197 98 992 B1 discloses a method in which a line pattern is generated on the measurement surface by projection, the line pattern is recorded with a camera that resolves the line pattern, and the recorded measurement data are compared with a reference measurement. With the help of a process computer, the measurement results are immediately converted and coordinated into control parameters for the finishing train and the reel.
- This method has the particular advantage of high immunity to interference, which is important in a rolling mill, since no sensitive laser optics are used, but an insensitive slide projector can be used.
- the measuring surface is to be understood here as the surface of the moving or stationary rolling stock (strips or sheets).
- a projector with a slide creates a line pattern on the surface of the rolling stock.
- the projector is arranged above the hot strip and projects the line pattern onto the surface of the rolling stock, so that the lines preferably extend transversely to the longitudinal axis of the strip or sheet metal and thus cover the entire strip or sheet width.
- a CCD camera with a resolution of, for example, eight pixels per line captures the lines running across the surface of the tape. At a absolute band flatness, a uniform pattern of straight lines with unchanged line spacing is created.
- Deviations of the belt surface from the ideal level cause a change in the line spacing in the area of the unevenness.
- the camera detects this change. It can be easily converted into height differences by comparison with an ideal pattern.
- This system enables the actual height differences of the strip surface to be determined quickly and thus enables real-time detection of continuous strip sections. This has the advantage that the measurement results allow the rolling parameters to be adjusted immediately after an unevenness has occurred.
- the invention also allows the transverse curvature of the band to be determined.
- Conventional measuring systems only record the ribbon fiber length.
- the measuring lines can also be adapted to different conditions with regard to their intensity and line thickness. The problems of fine, low-intensity and low-contrast moire lines do not arise.
- the system is particularly suitable for measuring on the hot strip running out of the finished batch in conjunction with a measurement of the strip on the reel. With this arrangement, changes in the flatness of the strip due to the strip cooling between the finished stack and the reel can be recorded and used for flatness control.
- the measurement data can be used to regulate the finished batch, the reel and to control the cooling section. Measurement results that contain a deviation of the soli value result in an immediate and coordinated adjustment of the parameters for the finishing batch, the cooling section and the reel.
- the system can also be used in downstream production lines, for example in the control of stretch leveling systems and in pickling lines.
- the relevant quality characteristics for the rolling and further processing of strips and sheets also include the dimensional accuracy of the geometric sizes, such as thickness, thickness cross profile and width, as well as the surface quality, which is recorded with the help of surface inspection systems. Adherence to narrow tolerances is desirable and not only a measure of the quality of the ready-to-sell product, but also important for a trouble-free operation of the entire processing process, especially with ever increasing automation of production processes.
- single-purpose devices such as, for example, optical systems for recording the flatness (flatness measurement systems), the bandwidth (width measurement systems) and the surface quality (surface inspection systems) and radiometric systems for recording the strip thickness or the strip thickness transverse profile.
- optical systems for recording the flatness (flatness measurement systems), the bandwidth (width measurement systems) and the surface quality (surface inspection systems) and radiometric systems for recording the strip thickness or the strip thickness transverse profile.
- These systems work independently of one another and are spatially separated from one another in order to prevent mutual interference, which requires a considerable amount of installation space.
- Optical systems are preferably used in the prior art for surface inspection. These usually have the following components:
- Illumination unit for illuminating the belt surface, a camera unit for seamless recording of the belt surface, a computer unit for processing the camera image information and an interface unit for process integration and display of the classification results.
- the lighting should preferably be designed so that the errors that can occur on the special production line are detected with the best possible optical contrast.
- stroboscopic illuminations are usually used, which emit the required amount of light in a short time interval.
- Narrow continuous lighting units are usually used in line scan camera systems, the motion blur being suppressed by the electronic shutter of the cameras.
- the camera technology is preferably dimensioned such that the minimum error size can still be resolved under all speed conditions of the belt.
- the image is recorded based on the tape length.
- the image brightness is preferably regulated automatically.
- Line scan cameras are clearly overweight, since line scan camera systems were first available on the market and were initially used on relatively easy to inspect surfaces with lower requirements , Many systems that use matrix cameras have only been set up in the last two to three years and, not least because of this, partly in the run-in phase or in the performance test. At present it can be said that there is in principle no significant difference between the performance and the matrix and line scan camera systems. Line scan camera systems are, however, less complex to set up and operate.
- the resolution of the cameras is determined by the smallest error size to be classified and is subject to the optical imaging laws.
- the minimum error size is preferably covered by at least 16 pixels that are detected, ie recognized by the system as defective, in order to achieve a good classification in the subsequent processing.
- the choice of the direction of observation and the inclination of the cameras is important in order to optimize the special error maps. Bright field and dark field observations are predominant, and side field observations have recently also been used.
- the optimal installation conditions for the respective application can be developed from the combination of the different lighting and camera arrangements.
- the continuously recorded surface images can be checked for their information content in the image processing unit.
- the characteristics of the "fault patterns” can be compared with stored fault characteristics. If there is a corresponding match, the automatic classification into one of the "pre-trained” error classes can take place.
- the extraction and comparison of image features currently requires high computing power.
- the inspection systems currently available compare the recorded pixels with threshold values. Pixels recognized as defective are set, all others are not set. Parameters for classification are obtained from these "binary images" and the brightness information stored for each pixel.
- the interface unit is usually designed to be application-specific in order to provide the surface inspection system with the important belt and control information at the right time. This is a standard task in automation and data technology.
- the invention is based on the object of creating a system which allows improved measurement and can also be designed to save space. To achieve this object, a method and a device according to the independent claims are provided.
- the invention is based on the idea of merging the flatness measurement and the surface inspection on the basis of an image acquisition with preferably high-resolution, fast line cameras.
- the system can also be used to measure the strip or sheet width.
- the number of components required is reduced by "multiple use", in particular the lighting unit.
- the space required is significantly reduced compared to single-purpose measurement systems.
- Including the results of the surface shape measurement in the width measurement increases the measurement reliability of the width measurement in the case of a non-flat strip shape.
- Including the results of the surface shape measurement in the surface inspection enables a distortion-free representation of the error, in particular in the case of strips which are not in the pass-line or have no flat strip shape as a result of fluttering movements.
- the image capture by line scan cameras is also made possible in an area in which the tape is not tightened by additional devices, for example on a deflection roller. Including the results of the surface shape evaluability significantly reduces the pseudo-error proportion of the surface inspection.
- the method according to the invention for the optical measurement of the surface shape and for the optical surface inspection can be used for any moving or stationary long body, preferably for strips and sheets.
- Fi ⁇ . 2 the arrangement of a projector and a camera behind a finishing line
- Fig. 4 a block diagram of the flatness control.
- EicL_5 and 6 the integration according to the invention of the flatness measurement and surface inspection in one device.
- the device according to the invention preferably has a structure according to FIG. 5, in which the line cameras lie on the same axis as the projector.
- Measuring lines 2 running transversely to the tape 1 are generated by a projector 3 on the measuring or tape surface 4.
- the measuring arrangement is arranged on the one hand in the outlet of the finished series 6 and on the other hand in front of the reel 7 on a measuring house 13.
- the CCD camera 5 is located on the side of the measuring house facing away from the reel 6 in a water-cooled housing.
- the projector 3 is arranged on the side of the measuring house facing the reel 6. Cooling air is applied to the housing to dissipate heat. The cooling of the projector 3 and the camera 5 is necessary to dissipate the internal heat and the heat radiation emanating from the band 1, which is approximately 1000 ° C.
- a xenon light source for example, can be used as the projector, which also produces a legible line pattern on hot rolled material.
- Unevenness on the belt surface 4 causes an irregular course of the measuring lines 2 or their deviation from the geometrical straight line.
- the measuring lines 2 and thus also their course changed by unevenness are recorded.
- the measurement image is compared arithmetically with a previously recorded reference pattern. The differences directly result in the height differences and the parameters for controlling the finishing train. This creates a complete flatness of the strip or sheet 1 moving in the direction of the arrow. In principle, however, the measurement can also take place when the rolling stock is at rest.
- the structure according to the invention results from the diagram of the flatness control (FIG. 4).
- the hot strip 1 passes through the finishing train 6 and the strip cooling 8 to the reel 7 in the reel pit.
- the flatness of the hot strip is recorded, analyzed and used to control the last stands of the finishing train (roll bending and swiveling).
- This inner flatness control loop 9 is supplemented by an outer flatness control loop 10.
- the outer flatness control loop 10 is set up to adapt the setpoint of the inner control loop.
- a first subordinate control loop 11 is also generated, which allows the setpoint for the cooling section 8 to be adjusted, and a second subordinate control loop 12, which allows the setpoint for the reel train 7 to be adjusted.
- the belt surface is scanned for the detection of defects by additionally installed high-resolution fast line cameras (FIG. 5), which enable the surface to be recorded over the entire bandwidth.
- Both line scan cameras are aligned with a ("bright") strip that is illuminated by the projector.
- the optical axis of the camera is in each case in the direction of the projection beams, so that the respective illuminated strip is detected by the line camera even if the height of the strip surface changes.
- the adapted arrangement of the two line scan cameras taking into account the arrangement of the projector relative to the surface of the tape, means that one camera works in the "bright field” and the second in the "dark field” (FIG. 5), which is necessary to optimize the detection performance in the case of surface defects of different characteristics ,
- the Images from both cameras are fed to an image processing unit for error identification.
- the height profiles determined with the flatness measuring system along the measuring fields of the line cameras can be used for geometrically correcting the images of the line cameras.
- the identification of faults such as cross cracks and edge cracks, which can occur in the rolling process due to the local exceeding of the breaking strength, can be improved by directly linking the information from the flatness measurement - in particular the elongation profile transversely to the longitudinal direction - and the fault patterns , at the same time an indication of the cause of the error can be derived.
- the image information from both line scan cameras can be used in combination with the results of the parallel flatness measurement for the quantitative determination of the strip edge position and the bandwidth with high resolution.
- the height profiles along the measuring fields of the line scan cameras determined with the flatness measuring system and the strip edge information detected by the line scan cameras are used for a geometric transformation.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Textile Engineering (AREA)
- Health & Medical Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Analytical Chemistry (AREA)
- Biochemistry (AREA)
- General Health & Medical Sciences (AREA)
- Immunology (AREA)
- Pathology (AREA)
- Computer Vision & Pattern Recognition (AREA)
- Length Measuring Devices By Optical Means (AREA)
Abstract
Description
Claims
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
DE10205132A DE10205132A1 (en) | 2002-02-07 | 2002-02-07 | Method and device for the optical measurement of the surface shape and for the optical surface inspection of moving strips in rolling and further processing plants |
DE10205132 | 2002-02-07 | ||
PCT/EP2003/001182 WO2003067188A1 (en) | 2002-02-07 | 2003-02-06 | Method and device for optically measuring the surface shape and for the optical surface inspection of moving strips in rolling and processing installations |
Publications (1)
Publication Number | Publication Date |
---|---|
EP1474654A1 true EP1474654A1 (en) | 2004-11-10 |
Family
ID=27634797
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP03704560A Withdrawn EP1474654A1 (en) | 2002-02-07 | 2003-02-06 | Method and device for optically measuring the surface shape and for the optical surface inspection of moving strips in rolling and processing installations |
Country Status (7)
Country | Link |
---|---|
US (1) | US7317542B2 (en) |
EP (1) | EP1474654A1 (en) |
JP (1) | JP2005517165A (en) |
KR (1) | KR100914897B1 (en) |
AU (1) | AU2003206853A1 (en) |
DE (1) | DE10205132A1 (en) |
WO (1) | WO2003067188A1 (en) |
Families Citing this family (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2000016040A1 (en) * | 1998-09-14 | 2000-03-23 | Betriebsforschungsinstitut Vdeh Institut Für Angewandte Forschung Gmbh | System for measuring the surface geometry and surface evenness of flat products |
WO2001051887A1 (en) * | 2000-01-07 | 2001-07-19 | Cyberoptics Corporation | Phase profilometry system with telecentric projector |
DE10205132A1 (en) * | 2002-02-07 | 2003-08-28 | Bfi Vdeh Inst Angewandte Forschung Gmbh | Method and device for the optical measurement of the surface shape and for the optical surface inspection of moving strips in rolling and further processing plants |
JP5089166B2 (en) * | 2003-03-14 | 2012-12-05 | ルドルフテクノロジーズ インコーポレイテッド | How to reduce the effects of component deflection in a probe card analyzer |
DE102005018855B4 (en) * | 2005-04-22 | 2010-01-28 | Theta System Elektronik Gmbh | Apparatus for inspecting printed products |
DE102005023270A1 (en) * | 2005-05-20 | 2006-11-23 | Sms Demag Ag | Method and device for producing a metal strip |
JP2006349534A (en) * | 2005-06-16 | 2006-12-28 | Fujinon Corp | Interferometer system and method of optical interferometry for measuring moving body |
US8205474B2 (en) * | 2006-03-08 | 2012-06-26 | Nucor Corporation | Method and plant for integrated monitoring and control of strip flatness and strip profile |
CN101422787B (en) * | 2008-12-10 | 2011-04-20 | 北京科技大学 | Strip-steel flatness measuring method based on single-step phase-shift method |
DE102009002569A1 (en) * | 2009-04-22 | 2010-10-28 | Manroland Ag | Method for determining the quality of a printed product |
CN102749336B (en) * | 2012-07-09 | 2015-01-07 | 南京航空航天大学 | Structured light-based surface defect high-speed detection system and detection method thereof |
WO2015175702A1 (en) * | 2014-05-14 | 2015-11-19 | Kla-Tencor Corporation | Image acquisition system, image acquisition method, and inspection system |
CN105651211B (en) * | 2016-03-08 | 2018-05-18 | 哈尔滨工程大学 | A kind of minute surface based on geometric optics goes out planar displacement measurement device and its measuring method |
KR101881752B1 (en) | 2016-11-24 | 2018-08-24 | 한국표준과학연구원 | defect sensing module based on line-beam and defect sensing device using its arrays for detection of the defects on surface |
JP6645526B2 (en) * | 2017-02-24 | 2020-02-14 | Jfeスチール株式会社 | Steel plate shape measuring device and steel plate shape correcting device |
DE102017108786A1 (en) | 2017-04-25 | 2018-06-14 | Muhr Und Bender Kg | Method and device for determining the flatness of strip material and processing plant with such a device |
US11833560B2 (en) * | 2019-07-22 | 2023-12-05 | Jfe Steel Corporation | Meandering control method, meandering control device, and hot rolling equipment for hot rolled steel strip |
JP2023005915A (en) * | 2021-06-29 | 2023-01-18 | 京セラドキュメントソリューションズ株式会社 | Image processing apparatus, image forming apparatus, and image processing method |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1170572A2 (en) * | 2000-06-30 | 2002-01-09 | Thermo Radiometrie Oy | Apparatus and method for determining surface shapes |
Family Cites Families (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4165939A (en) * | 1975-01-22 | 1979-08-28 | Tsn Company, Inc. | Apparatus for inspection and dimensional measurement by sequential reading |
US4349277A (en) * | 1980-06-11 | 1982-09-14 | General Electric Company | Non-contact measurement of surface profile |
DE3115634A1 (en) | 1981-04-18 | 1982-11-04 | Feldmühle AG, 4000 Düsseldorf | METHOD AND DEVICE FOR TESTING SURFACES LIMITED BY CIRCULAR LINES |
JPH03274405A (en) * | 1990-03-26 | 1991-12-05 | Kanegafuchi Chem Ind Co Ltd | Instrument for measuring surface properties of object |
US5309222A (en) * | 1991-07-16 | 1994-05-03 | Mitsubishi Denki Kabushiki Kaisha | Surface undulation inspection apparatus |
GB9203448D0 (en) * | 1992-02-18 | 1992-04-01 | British Steel Plc | Shape detection |
JPH06102197A (en) * | 1992-09-21 | 1994-04-15 | Kawasaki Steel Corp | Surface flaw detection method |
US5367378A (en) * | 1993-06-01 | 1994-11-22 | Industrial Technology Institute | Highlighted panel inspection |
DE19709992C1 (en) | 1997-03-11 | 1998-10-01 | Betr Forsch Inst Angew Forsch | Method for measuring the surface geometry of hot strip |
SE9902753D0 (en) | 1999-07-21 | 1999-07-21 | Regis Munoz | Device for observing and controlling or more textile yarns by a succession of numerical photographs |
DE10205132A1 (en) * | 2002-02-07 | 2003-08-28 | Bfi Vdeh Inst Angewandte Forschung Gmbh | Method and device for the optical measurement of the surface shape and for the optical surface inspection of moving strips in rolling and further processing plants |
-
2002
- 2002-02-07 DE DE10205132A patent/DE10205132A1/en not_active Withdrawn
-
2003
- 2003-02-06 WO PCT/EP2003/001182 patent/WO2003067188A1/en active Application Filing
- 2003-02-06 JP JP2003566494A patent/JP2005517165A/en active Pending
- 2003-02-06 KR KR1020047012273A patent/KR100914897B1/en not_active IP Right Cessation
- 2003-02-06 EP EP03704560A patent/EP1474654A1/en not_active Withdrawn
- 2003-02-06 US US10/503,665 patent/US7317542B2/en not_active Expired - Fee Related
- 2003-02-06 AU AU2003206853A patent/AU2003206853A1/en not_active Abandoned
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1170572A2 (en) * | 2000-06-30 | 2002-01-09 | Thermo Radiometrie Oy | Apparatus and method for determining surface shapes |
Also Published As
Publication number | Publication date |
---|---|
AU2003206853A1 (en) | 2003-09-02 |
JP2005517165A (en) | 2005-06-09 |
US7317542B2 (en) | 2008-01-08 |
KR100914897B1 (en) | 2009-08-31 |
WO2003067188A1 (en) | 2003-08-14 |
KR20040083442A (en) | 2004-10-01 |
DE10205132A1 (en) | 2003-08-28 |
US20050157302A1 (en) | 2005-07-21 |
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