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EP0886686A1 - Electrodes pour systemes de protection electrochimique contre la corrosion - Google Patents

Electrodes pour systemes de protection electrochimique contre la corrosion

Info

Publication number
EP0886686A1
EP0886686A1 EP97910479A EP97910479A EP0886686A1 EP 0886686 A1 EP0886686 A1 EP 0886686A1 EP 97910479 A EP97910479 A EP 97910479A EP 97910479 A EP97910479 A EP 97910479A EP 0886686 A1 EP0886686 A1 EP 0886686A1
Authority
EP
European Patent Office
Prior art keywords
electrode
active part
barriers
conducting
corrosion protection
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
EP97910479A
Other languages
German (de)
English (en)
Inventor
Yuri Iossel
Grigory Kazarov
Veijo Koski
Alexey Poliakov
Heiko Gebhardt
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Iossel Yuri
Kazarov Grigory
Koski Veijo
Poliakov Alexey
Original Assignee
Iossel Yuri
Kazarov Grigory
Koski Veijo
Poliakov Alexey
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from RU96121149/02A external-priority patent/RU96121149A/ru
Priority claimed from US08/906,075 external-priority patent/US5910236A/en
Application filed by Iossel Yuri, Kazarov Grigory, Koski Veijo, Poliakov Alexey filed Critical Iossel Yuri
Publication of EP0886686A1 publication Critical patent/EP0886686A1/fr
Withdrawn legal-status Critical Current

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F13/00—Inhibiting corrosion of metals by anodic or cathodic protection
    • C23F13/02—Inhibiting corrosion of metals by anodic or cathodic protection cathodic; Selection of conditions, parameters or procedures for cathodic protection, e.g. of electrical conditions
    • C23F13/06—Constructional parts, or assemblies of cathodic-protection apparatus
    • C23F13/08—Electrodes specially adapted for inhibiting corrosion by cathodic protection; Manufacture thereof; Conducting electric current thereto
    • C23F13/16—Electrodes characterised by the combination of the structure and the material

Definitions

  • Electrodes for electro-chemical corrosion protection systems are Electrodes for electro-chemical corrosion protection systems.
  • the invention relates to electrodes for use in electro-chemical corrosion protection systems, such as cathodic and anodic metal corrosion protection.
  • Electrodes for the in the introduction mentioned applications are used to prevent or at least to slow down corrosion processes on the surface of various metallic structures, exposed to a ionically conducting medium. They comprise an active current transferring surface, which is in electric contact with the medium and which transfers a direct current between that surface and the surface of the structure, through the medium.
  • the electrodes shall be designed and located in such a way that they provide a desired current distribution on the surface to be protected. In addition to requirements as to current and /or resistance, a major requirement is that they have a sufficiently long service life. Furthermore, they shall have a high operational reliability and be electrically safe.
  • Cathodic metal corrosion protection systems are used to prevent or at least to slow down corrosion processes on metallic structures, typically steel structures such as pipe lines and storage tanks, exposed to, in this context, a medium such as sea water and soil.
  • the structure to be protected is made a part of an electric direct current (DC) circuit, comprising at least one electrode, which is the subject of this application.
  • the DC current is distributed over the surface of the structure to be protected and will then give the desired effect of preventing or at least slowing down corrosion processes on the surface of the structure.
  • a plurality of electrodes are used to in order to improve the current distribution on the surface to be protected.
  • the electrode becomes an anode in the current circuit, that is, the current is transferred from the electrode to the structure.
  • ICCP impressed current
  • the electrode can either be located at some distance from the structure to be protected or, in certain cases, on the surface of the structure. In both cases, the current influencing the corrosion processes is transferred between the electrode and the structure via the ionically conducting medium-
  • Systems operating according to the ICCP principle comprise a current source, connected between the electrode and at least one so-called drainage point at the structure via a cable. Several drainage points, spaced out on the structure, may be used.
  • the output current of the current source is controlled in dependence on a measured voltage between the surface of the structure and a point in the medium to which it is exposed, so as to keep the protective current density at the surface at an optimum level, high enough to prevent or at least slow down the natural corrosion processes, but less than a level, where, in this case, excess hydrogen ions may appear on the structure, making the material of the structure brittle or destroy the coating (paint) on the structure.
  • the active part of the electrode is typically made of materials with a low dissolution rate, such as silicon iron and magnetite, or titanium, coated with platinum or with mixed metal oxides.
  • the anode material has to be electro-positive in relation to the material of the structure to be protected.
  • the protective current is then maintained by the electric potential difference between the two materials.
  • such material as magnesium, zinc or aluminum are used for protection of steel structures. These materials have, however, usually higher dissolution rates than the above mentioned materials used in systems operating according to the ICCP principle.
  • Electrodes for use as sacrificial anodes are installed either directly on the surface of the structure or at some distance from it, in which case they are connected to the structure via a feeder cable.
  • cathodic corrosion protection systems are for protection of pipelines, both against corrosion on their outer surfaces and, when they carry ionically conducting liquids, also against corrosion on their inner surfaces.
  • Other typical application are for protection of the inner and outer surfaces of storage tanks, the inner surfaces of condensers and heat exchangers, and for armored cables, for power transmission as well as for communication purposes.
  • anodic corrosion protection systems the electrode becomes a cathode in the current circuit, that is, current is transferred from the structure to the electrode.
  • Such systems usually operate in a way similar to the ICCP principle, however with reversed polarity of the current source. After that a first stage of operation is completed, during which a protective passivation layer is build up on the structure, the current transferred by the electrode will drop to a lower level, high enough to maintain the layer on the structure.
  • Anodic protection systems have a more restricted use than cathodic protection systems, typically they are used for protection of structures immersed in particular media, such as for instance protection of highly alloyed steels in an acid environment with an electrode made of copper.
  • Such applications for anodic protection systems are for example in storage tanks, in heat exchangers and in the pulp and paper industry.
  • Figure 1 illustrates schematically an electrical configuration typical for a known system for cathodic corrosion protection of the outer surface of a pipeline, operating according to the ICCP principle.
  • a power unit 60 supplied with electric power from an alternating current supply (not shown) delivers on its output terminals 601, 602 a DC current.
  • the terminal 601 is, via a conductor 63, connected to the outer surface of a pipeline 61 (only a part of which is shown) at a drainage point 62, and, via a feeder cable 64, to a ground bed 15.
  • the ground bed comprises a plurality of electrodes 16, interconnection cables 2, interconnecting the electrodes among themselves, and a backfill (not indicated in the figure), for example coke, in which the electrodes are embedded.
  • Each of the electrodes which are made of for example silicon iron, are electrically connected to the feeder cable.
  • a plurality of systems such as described in connection with figures 1 are distributed along the pipe line, typically with an intermediate distance in the range of 10-15 km.
  • FIG. 2 shows a known alternative to the electrical configuration as illustrated in figure 1.
  • the structure to be protected comprises a tank 65 and a piping system 66, located under ground.
  • the electrodes 16 are not comprised in a ground bed but are located as discrete anodes at the tank and at the piping system.
  • the electrodes are connected to the power unit via interconnection cables 2 and feeder cables 64,
  • Figure 3 illustrates schematically an electrical configuration typical for a known system for cathodic corrosion protection of the outer surface of a pipe, operating according to the sacrificial anode principle.
  • the structure to be protected is a pipe 65, located under ground.
  • An electrode 16 is embedded in a backfill 67 and is connected to the pipe via a connection cable 68 at a drainage point 62.
  • Figures 4A-4C illustrate various prior art rod-shaped electrodes designed in an attempt to prolong their service lifetime, used for instance in corrosion protection systems operating according to the ICCP principle, for protection of the outer surfaces of pipelines and other structures.
  • Figure 4A shows an electrode 16 with two ends 101 and 102 and with a feeder cable 64 connected to the end 101. In the feeding end 101, the electrode has an increased diameter and is in addition protected by a sleeve 3, made of a non-conducting material.
  • the active part S of the surface of the electrode is in this case its total surface less that part of the total surface which is covered by the sleeve.
  • FIG 5 shows a prior art electrode for use as a sacrificial anode, for example in a configuration as illustrated in figure 3.
  • the electrode is made of magnesium and comprises a steel insert 68a embedded in the electrode.
  • At the feeding end 101 of the electrode there is a recess 69 such that the cross section at the end 101 exhibits a groove in which the feeder cable 68 is connected to the steel insert via a feeder cable connection 68b (only indicated in the figure).
  • the active parts of the electrode are manufactured in the form of rods or tubular elements, which makes them easy to manufacture and to mount.
  • the surface of an electrode comprises an active part, which is in electric contact with the medium in which the electrode is embedded and through which the current is transferred, and often some part or parts covered with a nonconducting material, and which thus is/are not an active part of the surface of the electrode.
  • suitable electrode materials are magnesium, zinc or aluminum.
  • a sacrificial anode of zinc or aluminum will typically lose 85 a 90 % of its weight through electrolysis when the protective current to the protected structure is provided, the rest of the electrode being dissolved as a result of corrosion processes on the anode.
  • magnesium is typically used as electrode material, due to the lower specific conductivity of soil as compared to sea water, limiting the protective current.
  • a sacrificial anode of magnesium has, however, a high self corrosion rate, typically up to 50 %.
  • the object of the invention is to provide an electrode of the kind stated in the introduction, which is improved with respect to the above-mentioned disadvan- tages connected with the prior art, in particular the limited service lifetime connected with the rate of dissolution of the material of electrodes.
  • An electrode according to the invention is characterized in that it comprises at least two electrically non-conducting barriers, spaced apart along the electrode, and between which is formed an active part of the surface of the electrode, which active part is in electric contact with a ionically conducting medium, said barriers having a substantial extension outwards from said active part of the surface of the electrode into the medium, so as to homogenize the current distribution along said active part of the surface of the electrode.
  • the barriers act as barriers to the current lines at the electrode, which current lines, in the vicinity of the surfaces of the barriers, will be directed along these surfaces, and the barriers will thereby homogenize the current distribution along the active part of its surface.
  • a current line is to be understood as a line such that, at every point of it, the current density vector at that point is tangential to the line.
  • Figure 1 shows schematically an example of a prior art system for cathodic corrosion protection with a ground bed
  • figure 2 shows an example of a prior art system for cathodic corrosion protection with discrete electrodes
  • figure 3 shows an example of a prior art system for cathodic corrosion protection with a sacrificial anode
  • FIGS. 4A-4C show various prior art electrodes for use in systems operating according to the ICCP principle
  • figure 5 shows a prior art electrode for use as a sacrificial anode
  • figure 6A shows a prior art cylinder-shaped electrode
  • figure 6B shows the current distribution along an electrode according to figure 6A, embedded in sea water
  • figure 6C shows the current distribution along an electrode according to figure 6A, embedded in soil
  • figure 7A shows an embodiment of a cylinder-shaped electrode, provided with non-conducting barriers according to the invention
  • figure 7B illustrates the homogenizing effect of non-conducting barriers according to figure 7A, on the current distribution along a cylinder-shaped electrode embedded in sea water
  • figure 7C illustrates the homogenizing effect of non-conducting barriers according to figure 7A, on the current distribution along a cylinder-shaped electrode embedded in soil
  • figure 7D illustrates a development of the invention according to figure 7A, wherein the electrode is enclosed by a cylindrical metal tube,
  • FIG. 7E illustrates an alternative embodiment of the invention
  • figure 8 shows in an exploded view an embodiment of an electrode according to figure 5, provided with non-conducting barriers according to the invention
  • figure 9 shows in an exploded view an embodiment of an electrode according to the invention, for use in a system operating according to the ICCP principle,
  • figure 10 shows an embodiment of an electrode according to the invention, for use in a system for cathodic corrosion protection operating according to the ICCP principle, for protection of the inner surface of a structure
  • FIG. HA shows schematically an embodiment of a cathodic protection system for protection of a condenser, with electrodes according to the invention
  • figure 11B shows details of an electrode for use in a system according to figure HA
  • figure IIC shows a development of the embodiment of the invention according to figure 11B
  • figure 12 shows a system for anodic corrosion protection of a heat exchanger, with electrodes according to the invention
  • FIG 13 A shows schematically another embodiment of non-conducting barriers according to the invention.
  • figure 13B shows schematically an embodiment of non-conducting barriers of the same kind as illustrated in figure 13A, with an electrode of a different shape.
  • Electrodes operating as anodes tend to send positive ions into the surrounding medium, resulting in a dissolution of the electrode material.
  • the dissolution rate increases with increasing current density on the electrode surface, and the electrode will gradually be dissolved, limiting its service lifetime.
  • the feeder cable connection is located at one end of the electrode and the connection to the feeder cable may finally be broken by dissolution of the electrode. For most materials, the dissolution rate increases dramatically above certain current density levels.
  • Electrodes operating as cathodes can be deteriorated by incorporation of alien metal atoms /ions into the electrode material, thereby reducing the mechanical integrity of the electrodes. Also the speed of such a process increases with increasing current density.
  • An electrode according to the invention is characterized in that it comprises at least two electrically non-conducting barriers, spaced apart along the electrode, and between which is formed an active part of the surface of the electrode, which active part is in electric contact with the surrounding medium, said barriers having a substantial extension outwards from said active part of the surface of the electrode into the medium.
  • the barriers act as barriers to the current lines at the electrode, which current lines, in the vicinity of the surfaces of the barriers, will be directed along these surfaces, and will homogenize the current distribution along the active part of the surface of the electrode.
  • Figure 6A shows a conventional cylinder-shaped electrode 16 of a highly conducting material.
  • the electrode is embedded in a surrounding conducting medium 28, such as sea water or soil (only indicated in the figure), with a specific conductivity several orders of magnitude below the specific conductivity of the material of the electrode, and also assumed to transfer a current to the medium.
  • the length of the electrode is 2L and the envelope surface S of it constitutes the active part of its surface.
  • the cylinder is 1 m long and has a diameter of 3 cm.
  • Figure 6B shows on the vertical axis the normalized local current density
  • J(x)/Javg at the surface of the electrode, where J(x) is the actual current density at a relative distance x/L along the electrode from the mid of it, and Javg is the average value of the current density along the electrode.
  • the horizontal axis shows the relative distance x/L with positive direction to the right in the figure. It is known that the current distribution is dependent on the so called specific anodic polarization resistivity b a .
  • Figure 6C shows on the horizontal axis the same entity as the horizontal axis in figure 6B, and on the vertical axis the calculated normalized local current density
  • FIG. 7A shows schematically an electrode 16 of the same kind as described in connection with figure 6A and embedded in a medium 28 with similar properties.
  • the electrode is, according to the invention, equipped with two barriers 8a, 8b, one at each end.
  • the barriers are made of a non-conducting material, chosen such that they maintain their non-conducting properties during the service lifetime of the electrode, for instance polyethylene or polypropylene. They have the shape of circular discs, with their plane perpendicular to the electrode.
  • the radius of the barriers is such that their circumferences extend with a distance h outwards from the envelope surface of the cylinder.
  • the border lines BL', BL" of the active part S of the surface of the electrode are in this case the lines along which the envelope surface of the electrode adjoins the respective barriers.
  • the effect of the barriers on the current distribution along the active part of the electrode surface is to homogenize the current distribution.
  • the barriers act as barriers to the current lines, which, in the vicinity of the surfaces of the barriers, will be directed along these surfaces. Thus, the barriers homogenize the current distribution along the electrode.
  • Figure 7B shows on the horizontal and on the vertical axis the same entities as figure 6B, for an electrode according to figure 7A.
  • the diagram is calculated for an electrode embedded in sea water.
  • the same ratio is plotted as a whole line for a similar electrode but without barriers.
  • Figure 7C shows on the horizontal and on the vertical axis the same entities as figure 7B, for an electrode according to figure 7A. It is in this case assumed that the electrode is embedded in soil with a specific electric resistivity of 50 ohm *m.
  • a plurality of barriers, spaced along the whole electrode can be used to obtain the desired homogenizing effect.
  • the same effect as described above is then achieved for each part of the electrode located between two adjacent barriers, spaced along the cylinder with the distance 2L between them, and with each barrier having the height ratio h/L.
  • the same homogenizing effect can be achieved also with barriers and electrodes with different geometries.
  • the barriers as described in connection with figure 7A must not necessarily be in the shape of circular discs, but could also be in the shape of plates with, for example, a rectangular or quadratic form, for instance such as is illustrated in the figure 9 described below.
  • the barriers could exhibit a convex surface towards that part of the electrode on which the homogenizing effect is desired.
  • the homogenizing effect achieved will depend on the dimensions of the barriers as projected on a plane substantially perpendicular to the active part of the surface of the electrode, as well as on the shape of the barriers.
  • the barriers could preferably be given the shape of a plate, adapted to the dimensions of the electrode.
  • FIG. 7D A development of the invention is illustrated in figure 7D.
  • the figure shows schematically a cut-up view of an electrode 16 of the same kind as described in connection with figure 7A, provided with a feeder cable 64b, two barriers 8a, 8b, one at each end of the electrode, and a third barrier 8c located in between these barriers.
  • the barriers are of the same kind as described in connection with figure 7A.
  • a cylindrical metal tube 5 for example made of steel, encloses the electrode so as to form together with the two end barriers 8a, 8c, a closed canister containing the electrode.
  • the canister is filled with a backfill 67, for example of coke.
  • a mechanically robust package is achieved, which can easily be embedded in the groundbed.
  • the homogenizing effect of the barriers on the current distribution at the electrode will, with an arrangement according to figure 7D, be similar or, at least temporarily, even better than as described in connection with figures 7A-7C.
  • the metal tube will then, in course of time, gradually dissolve, starting at the parts closest to the barriers 8a and 8b, where the current density at the metal tube is highest.
  • a transition phase where the ends of the remaining part of the metal tube no longer touches the barriers 8a, 8b, that remaining part, which surrounds the electrode, may still contribute to the homogenization of the current distribution at the electrode, as it usually has a specific resistivity which is lower than the specific resistivity of the backfill.
  • the metal tube is completely dissolved and the barriers will influence the current distribution as described in connection with figures 7A-7C
  • FIG 7E An alternative embodiment of the invention is illustrated in figure 7E.
  • the barriers 8a, 8b have in this case substantially the same diameter, that is the same cross-section dimension, as the original diameter of the electrode 16.
  • an electrode dissolution process as mentioned above may start, in particular at the border lines BL' and BL" of the active part of the surface of the electrode.
  • the homogenizing effect of the barriers will, during this process, gradually influence the current distribution along the active part of electrode, so as to achieve a more homogeneous current distribution along the active part of the surface of the electrode.
  • FIG Figure 8 shows in an exploded view an embodiment of an electrode 16 for use as a sacrificial anode, similar to the one described in connection with figure 5 (the same reference numbers refers to the same parts in both figures), but provided with two barriers 8a, 8b according to the invention, one at each end.
  • the barriers are in the shape of circular discs.
  • the barriers are provided with sleeves 3 (shown only at the barrier located at the end 102 of the electrode) of nonconducting material to facilitate mounting of the barriers on the electrode.
  • the barrier located at the end 101 of the electrode is provided with a hole 81 through which the feeder cable passes.
  • the barrier 8a is shown moved away from its normal location at the end 101 of the electrode.
  • the border lines BL', BL" of the active part S of the surface of the electrode are in this case the lines along which the envelope surface of the electrode adjoins the respective sleeves of the barriers.
  • FIG 9 shows in an exploded view an embodiment of an electrode for use in a system operating according to the ICCP principle.
  • the electrode is similar to the one described in connection with figure 4A (the same reference numbers refers to the same parts in both figures), but of cylindrical shape and provided with two barriers 8a, 8b according to the invention, one at each end.
  • the barriers are in the shape of rectangular plates with rounded corners and provided with sleeves 3 of a non-conducting material, as described in connection with figure 8, serving as mechanical supports for the barriers when they are mounted on the electrode.
  • the electrode, the two barriers and four wooden supports 70 (of which only three are shown in the figure) are mounted together, in a manner known per se, to form one unit, so that the barriers serve as mechanical supports for the electrode.
  • the two barriers are located at the ends of the cylindrical electrode, projecting from it in a direction perpendicular to the active part of its surface, which active part is the part not covered by the two sleeves 3 (and the barriers in mounted position).
  • the border lines BL', BL" (only BL' is shown in the figure) of the active part S of the surface of the electrode are in this case the lines along which the envelope surface of the electrode adjoins the respective sleeves of the barriers, that is, at the edges of the sleeves facing the active part of the surface.
  • the barriers shall preferably be located at these border lines, but for practical purposes, a sufficiently homogenizing effect on the current distribution is achieved also when the barriers, for instance for mechanical design reasons as described above in connection with figures 8 and 9, are displaced from these border lines along the longitudinal direction of the electrode.
  • the displacement of the barriers from the mentioned border lines shall preferably be small in relation to the dimensions of the barriers in a plane perpendicular to the active part of the surface, so that the barriers are located at or close to these border lines, the wording 'close to' to be understood as so close that the desired homogenizing effect of the barriers is achieved.
  • the barriers, at least at the surface of the electrode shall project in a direction which is substantially perpendicular to the active part of the surface of the electrode.
  • the barriers at least at the surface of the electrode, shall project in a direction which is substantially perpendicular to the active part of the surface of the electrode.
  • an embodiment of the invention where, for example, the barriers exhibit a convex surface towards that part of the electrode on which the homogenizing effect is desired, can be designed to achieve the desired homogenizing effect, provided the dimensions of the barriers as projected on a plane substantially perpendicular to the active part of the surface of the electrode are made sufficiently large.
  • FIG 10 shows an electrode 16 according to the invention, for use as an anode in a system for cathodic corrosion protection operating according to the ICCP principle, for protection of the inner surface of a structure 12, for instance a heat exchanger or a pipeline.
  • the material of the electrode is for instance of titanium coated with platinum.
  • the electrode is of cylindrical shape and mounted on the structure 12 with an attachment member 13, providing a water tight and from the structure electrically insulating mounting of the electrode.
  • the electrode is connected to a feeder cable (not shown) via a cable connector 14.
  • the electrode is provided with a barrier 8' located, along the electrode, at some distance from the attachment member 13 and a barrier 8", located at the end 102 of the electrode which is opposite to the attachment member.
  • a sleeve 31 of a non-conducting material covers that part of the electrode surface which is located between the attachment member and the barrier 8' and provides an electric isolation of the electrode from the medium along its extension between the inner surface of the structure and the barrier 8'.
  • the active part S of the surface of the electrode body is in this case that part of the envelope surface of the electrode which is not covered by the sleeve and is limited by the border lines BL', BL" along which the envelope surface of the electrode adjoins the barriers 8', 8" respectively.
  • the barriers 8, 8' are made of a flexible material, to facilitate mounting of the electrode through a hole in the wall of the structure to be protected.
  • one or more additional barriers can be placed along the electrode in between the shown barriers 8', 8".
  • FIG 11 A shows schematically a condenser (heat exchanger) 12 with a water chamber 121 and tube plates 122, only one of which is shown. Tubes, kept in place by the tube plates, are indicated with the reference number 123.
  • the water chamber has a water inlet 124.
  • the inner wall of the water chamber and the tube plates are provided with electrodes 16 according to the invention, operating as sacrificial anodes.
  • Figure 11B shows details of such an electrode, for protection of the inner surface of the water chamber.
  • the electrode 16 is from both ends, via connector bars 68a, 68b, connected to the inner surface of the water chamber 121.
  • the connection bars are mechanically designed to carry and to hold the electrode in its position in the water chamber.
  • attachment members 131a, 131b respectively, provide an electrically conducting mechanical attachment of the connection bars to the walls.
  • the electrode is provided with barriers 8a, 8b according to the invention.
  • the electrodes for protection of the tube plates are of similar design.
  • the dissolution rate of the electrode material is reduced, and for a specified service lifetime of the electrodes, the amount of electrode material in an electrode can be reduced.
  • a corresponding reduction of the dimensions of the electrode that is a reduction of that portion of the surface of the active part of the electrode which is in electric contact with the surrounding conducting medium, will increase the resistance of the electrode and in certain cases, with a specified service life time and a specified maximum resistance, the requirements would, for an substantially homogeneous electrode, lead to a design comprising an unnecessarily great amount of electrode material.
  • figure IIC An advantageous development of the invention is illustrated in figure IIC.
  • the figure shows in a cut-up view details of a cylinder-shaped electrode 16, operating as sacrificial anode.
  • the electrode is attached to the inner surface of a water chamber 121 via connector bars 68a, 68b and attachment members 131a,
  • the electrode is further provided with an insert member 161 with a cylindrical outer surface, preferably of tubular shape.
  • the active part 162 of the electrode comprising the electrode material, typically such as magnesium, zinc or aluminum, thus has the shape of a hollow cylinder arranged outside and surrounding the insert member.
  • the insert member is manufactured of an electrically conductive material, typically steel or aluminum, and its outer surface is in electrical and mechanical contact with the inner surface of the active part of the electrode along the total length 2L of the active part of the electrode.
  • the insert member serves as a mechanical support for the active part of the electrode and also provides the electric connection between the active part of the electrode and the connector bars 68a, 68b, for example by being welded to these bars (not shown in the figure).
  • the connector bars as well as the attachment members 131a, 131b are covered by a non- conductive layer (not shown in the figure) so as to prevent electric contact between the surrounding medium on one hand and the insert member, the connector bars and the attachment members on the other hand.
  • the minimum required amount of electrode material and the dimensions of the electrode can be calculated in a per se known way for a chosen electrode material.
  • the outer dimensions of the insert member for example, when the insert member has the shape of a circular tube, its length and its outer diameter, are then selected in such a way that the active part of the electrode gets dimensions which fulfill the requirement on specified maximum resistance and, at the same time, contains only the minimum required amount of electrode material.
  • An insert member such as described in connection with figure IIC can also be applied to electrodes intended for use in systems working according to the ICCP principle.
  • FIG. 12 shows schematically a heat exchanger 12.
  • the heat exchanger is enclosed in a vessel 126 with an inlet 125a and an outlet 125b for a cooling medium.
  • the cooling medium is passed through a plurality of tubes 123 of a highly alloyed steel.
  • the vessel is, in order to illustrate the invention, shown partly cut up.
  • An inlet 127a an acid liquid to be cooled passes into the vessel, surrounding the tubes 123, and leaves the vessel through an outlet 127b.
  • a power unit 60 supplied with electric power from an alternating current supply (not shown) delivers on its output terminals 601, 602 a DC current.
  • the terminal 601 is, via a conductor 63, connected to the outer surface of the vessel 126 at a drainage point 62, and, via a feeder cable 64, to a an electrode 16, located inside the vessel.
  • the electrode which is of cylindrical shape and is oriented along the tubes 123, operates as a cathode for anodic protection of the tubes according to the impressed current principle as described above.
  • the electrode is provided with barriers 8a, 8b according to the invention (two of which are shown in the figure) and it shall be understood that the electrode shown in the figure may be provided with a plurality of barriers, spaced along the electrode to provide an optimal homogenizing effect of the current distribution along the electrode.
  • the barriers are shown as circular discs but their shape may also be adapted to configuration of the surroundings of the electrode.
  • the heat exchanger may also, as the case may be, be equipped with one or more additional electrodes of similar kind as the one described above.
  • FIG. 13A An embodiment of the invention, advantageous in particular where the active part S of the surface of the electrode has a flat shape, is illustrated schematically in figure 13A.
  • the electrode 16 has the shape of a straight circular cylinder with a longitudinal extension less than its diameter.
  • a barrier 8 of a non-conducting material is arranged in such a way that it forms a tube completely enveloping the electrode.
  • the electrode is fed at its envelope surface via an electrically insulated feeder cable 64, penetrating the barrier.
  • the location of penetration is covered with a non-conducting material to ensure that all of the envelope surface of the electrode is covered by non-conducting material.
  • the active part S of the surface of the electrode is both its cross section surfaces, that is its total surface less its envelope surface.
  • the border lines BL', BL" are in this case the contour lines of the cross section surfaces of the cylinder, that is the two circles making up the circumferences of the cylinder at its both ends.
  • the extension of the barrier from the active part of the surface of the electrode is indicated with the distance EXT in the figure, and by increasing the length EXT of the barrier in the longitudinal direction of the cylinder, the current distribution on the cross section areas of the electrode can be homogenized to any desired degree, in the theoretical limiting case of infinite length of the barrier, to be totally uniform.
  • the contour of the electrode and the form of the tubular barrier, as seen from the active part of the surface of the electrode both have the same form, that is in the embodiment illustrated in figure 13A, a circular form.
  • the contour of the barrier is easily adapted to any shape of the contour of the electrode, one example of which is illustrated in figure 13B.
  • the electrode 16 has the shape of a rectangular plate with a height less than its length and width, the length and width determining its flat surfaces.
  • a barrier 8 of a non-conducting material is arranged in such a way that it forms a tube of rectangular shape completely enveloping the electrode.
  • the electrode is fed at one of the side surfaces of the electrode in the same manner as described in connection with figure 13A.
  • the active part S of the surface of the electrode is thus its total surface less all of its four side surfaces, that is both of its flat surfaces.
  • the dissolution rate of the electrode material is reduced, thereby increasing the service lifetime of the electrodes and /or reducing the amount of electrode material needed for a specified service life time .
  • Sacrificial anodes as illustrated in figure 5 will operate with higher efficiency during their lifetime.
  • the electrodes For cathodic protection systems operating according to the ICCP principle, for example on inner surfaces, the electrodes often are made of titanium or niobium, plated with a very thin layer of platinum or mixed metal oxides. Both types of plating imposes a maximum voltage on the anode in order to rninirnize the risk for break down of the plating (about 8.5 V for titanium and about 40 V for niobium). With a more homogeneous current distribution, a lower anode voltage can be used with the same or even increased efficiency at the same time as the risk for break down of the plating is reduced. Accumulation of residual products due to anodic and cathodic reaction processes, for example on the inner surface of a pipeline at the attachment point of an electrode, which are due to high current densities at these points, can be reduced to lower levels.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Prevention Of Electric Corrosion (AREA)

Abstract

Electrode (16) conçue pour être utilisée dans des systèmes de protection électrochimique contre la corrosion, telle que la protection cathodique et anodique contre la corrosion du métal, et se trouvant en contact électrique avec un milieu (28) ioniquement conducteur. Elle comprend au moins deux barrières (8a, 8b, 8', 8') non conductrices électriquement et situées à distance l'une de l'autre le long de l'électrode. Une partie active (S) de la surface de l'électrode est située entre les barrières, cette partie active étant en contact électrique avec le milieu conducteur. Ces barrières présentent une prolongation importante vers l'extérieur depuis ladite partie active de la surface de l'électrode, vers l'intérieur du milieu conducteur, de manière à homogénéiser la distribution du courant le long de ladite partie active de la surface de l'électrode.
EP97910479A 1996-10-28 1997-10-27 Electrodes pour systemes de protection electrochimique contre la corrosion Withdrawn EP0886686A1 (fr)

Applications Claiming Priority (5)

Application Number Priority Date Filing Date Title
RU96121149/02A RU96121149A (ru) 1996-10-28 Электроды для систем электрохимической защиты от коррозии
RU96121149 1996-10-28
US08/906,075 US5910236A (en) 1996-10-28 1997-08-05 Electrodes for electro-chemical corrosion protection systems
US906075 1997-08-05
PCT/FI1997/000656 WO1998018981A1 (fr) 1996-10-28 1997-10-27 Electrodes pour systemes de protection electrochimique contre la corrosion

Publications (1)

Publication Number Publication Date
EP0886686A1 true EP0886686A1 (fr) 1998-12-30

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EP97910479A Withdrawn EP0886686A1 (fr) 1996-10-28 1997-10-27 Electrodes pour systemes de protection electrochimique contre la corrosion

Country Status (2)

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EP (1) EP0886686A1 (fr)
WO (1) WO1998018981A1 (fr)

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US2204823A (en) * 1935-07-17 1940-06-18 George I Rhodes Composite electrode for protecting buried metallic structures from corrosion
GB777816A (en) * 1954-05-19 1957-06-26 Dow Chemical Co Improvements in or relating to consumable galvanic anodes for use in the cathodic protection of metal structures
GB879289A (en) * 1959-02-24 1961-10-11 Dov Spector Improvements in or relating to the cathodic protection of the interior of tanks
DE1922151A1 (de) * 1969-04-25 1970-11-12 Hansen Neuerburg & Co Gmbh Heizoelbehaelter mit Unterschichtungsfluessigkeit an dem Schirmstock
US3907658A (en) * 1974-08-02 1975-09-23 Corrosion Service Co Ltd Anode fitting
US4401540A (en) * 1980-10-29 1983-08-30 C.E. Equipment Co., Inc. Apparatus for reducing end effect in anodes
US4457821A (en) * 1983-01-17 1984-07-03 Pennwalt Corporation Cathodic protection apparatus for well coated metal vessels having a gross bare area
NL8300352A (nl) * 1983-01-31 1984-08-16 Hommema Van 1825 B V Anodesamenstel voor een kathodisch beschermingsstelsel.
US4874487A (en) * 1986-07-18 1989-10-17 Raychem Corporation Corrosion protection
GB8809750D0 (en) * 1988-04-25 1988-06-02 Beckswift Ltd Electrical apparatus

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
See references of WO9818981A1 *

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