EP0717097A1 - Auf pflanzlichem Öl und aromatenreicher Petroleumfraktion basierter Brennstoff - Google Patents
Auf pflanzlichem Öl und aromatenreicher Petroleumfraktion basierter Brennstoff Download PDFInfo
- Publication number
- EP0717097A1 EP0717097A1 EP95402747A EP95402747A EP0717097A1 EP 0717097 A1 EP0717097 A1 EP 0717097A1 EP 95402747 A EP95402747 A EP 95402747A EP 95402747 A EP95402747 A EP 95402747A EP 0717097 A1 EP0717097 A1 EP 0717097A1
- Authority
- EP
- European Patent Office
- Prior art keywords
- oil
- fuel
- fuel according
- volume
- type
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 51
- 239000003921 oil Substances 0.000 title claims description 10
- 125000003118 aryl group Chemical group 0.000 title claims description 5
- 235000015112 vegetable and seed oil Nutrition 0.000 claims abstract description 29
- 239000008158 vegetable oil Substances 0.000 claims abstract description 29
- 239000000295 fuel oil Substances 0.000 claims abstract description 15
- 239000003208 petroleum Substances 0.000 claims abstract description 15
- 239000000203 mixture Substances 0.000 claims description 22
- 150000001491 aromatic compounds Chemical class 0.000 claims description 16
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 14
- 238000004523 catalytic cracking Methods 0.000 claims description 13
- 239000003502 gasoline Substances 0.000 claims description 12
- 150000001875 compounds Chemical class 0.000 claims description 9
- 235000019198 oils Nutrition 0.000 claims description 9
- 238000006243 chemical reaction Methods 0.000 claims description 7
- 229930195733 hydrocarbon Natural products 0.000 claims description 5
- 150000002430 hydrocarbons Chemical class 0.000 claims description 5
- 238000004821 distillation Methods 0.000 claims description 4
- 239000004215 Carbon black (E152) Substances 0.000 claims description 3
- 235000019486 Sunflower oil Nutrition 0.000 claims description 3
- 150000001336 alkenes Chemical class 0.000 claims description 3
- 230000000295 complement effect Effects 0.000 claims description 3
- 235000019482 Palm oil Nutrition 0.000 claims description 2
- 238000001833 catalytic reforming Methods 0.000 claims description 2
- 239000003240 coconut oil Substances 0.000 claims description 2
- 235000019864 coconut oil Nutrition 0.000 claims description 2
- 238000012986 modification Methods 0.000 claims description 2
- 230000004048 modification Effects 0.000 claims description 2
- 239000002540 palm oil Substances 0.000 claims description 2
- 238000000197 pyrolysis Methods 0.000 claims description 2
- 239000003549 soybean oil Substances 0.000 claims description 2
- 235000012424 soybean oil Nutrition 0.000 claims description 2
- 238000004230 steam cracking Methods 0.000 claims description 2
- 239000002600 sunflower oil Substances 0.000 claims description 2
- 238000002485 combustion reaction Methods 0.000 description 7
- 238000003860 storage Methods 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 3
- 238000010438 heat treatment Methods 0.000 description 3
- 240000002791 Brassica napus Species 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 229940082150 encore Drugs 0.000 description 2
- 238000010348 incorporation Methods 0.000 description 2
- 239000003607 modifier Substances 0.000 description 2
- 238000007254 oxidation reaction Methods 0.000 description 2
- 238000011084 recovery Methods 0.000 description 2
- 230000000717 retained effect Effects 0.000 description 2
- 238000005507 spraying Methods 0.000 description 2
- 150000005691 triesters Chemical class 0.000 description 2
- 235000006008 Brassica napus var napus Nutrition 0.000 description 1
- 235000004977 Brassica sinapistrum Nutrition 0.000 description 1
- 238000001159 Fisher's combined probability test Methods 0.000 description 1
- 244000020551 Helianthus annuus Species 0.000 description 1
- 230000001580 bacterial effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003517 fume Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000009434 installation Methods 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 150000004702 methyl esters Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000000746 purification Methods 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- 230000008685 targeting Effects 0.000 description 1
- 238000005809 transesterification reaction Methods 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10L—FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
- C10L1/00—Liquid carbonaceous fuels
- C10L1/02—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only
- C10L1/023—Liquid carbonaceous fuels essentially based on components consisting of carbon, hydrogen, and oxygen only for spark ignition
Definitions
- the subject of the present invention is a fuel formed from a composition based on natural vegetable oil, capable of being burnt in combustion plants, either directly or as a mixture with one or more hydrocarbons.
- the Applicant has, for its part, set itself the objective of direct recovery of vegetable oils, by their incorporation, in the state and at high contents, in a fuel meeting the standards of use of domestic fuels and not requiring therefore, no modifications to existing combustion plants.
- a fuel comprising high contents of natural vegetable oil - that is to say unprocessed - and a petroleum cut rich in aromatic compounds, in determined volume ratios, can be burned either directly or in a mixture with other fuels of conventional type such as domestic fuel oil, which eliminates the problems mentioned above.
- the refined vegetable oil can be present in the fuel according to the invention at contents as high as 50% by volume. Beyond such vegetable oil concentrations, it becomes necessary to change the burner (s) of the boiler.
- the present invention therefore has for first object a fuel based on vegetable oil, characterized in that it contains between 100% and 1% by volume of a basic composition comprising at least one vegetable oil and at least one cut.
- a basic composition comprising at least one vegetable oil and at least one cut.
- petroleum rich in aromatic compounds of the heavy petrol type originating from a non-hydrogenating conversion, and in that the volume ratio of vegetable oil / petrol of the aromatic type is less than 2.
- the vegetable oil which can be used in the fuel according to the invention is preferably an oil from a plant which can be cultivated with a high yield per hectare. It can be chosen from the group comprising in particular sunflower oil, palm oil, coconut oil, soybean oil, rapeseed oil and their mixtures. Preferably, the vegetable oil is rapeseed oil.
- the vegetable oil is present in the fuel according to the invention in an amount of 10% to 50%, preferably from 20% to 30% by volume.
- the petroleum cut rich in aromatic compounds of the heavy gasoline type originating from a non-hydrogenating conversion, usable in the fuel according to the invention can be chosen from the group comprising petrol obtained from catalytic reforming, petrol from steam cracking, gasoline from pyrolysis, gasoline from catalytic cracking or mixtures thereof. Preferably use the gasoline from catalytic cracking.
- the petroleum fraction rich in aromatic compounds which can be used in the fuel according to the invention, preferably has a distillation range of between 140 ° C and 240 ° C at atmospheric pressure. It preferably has a viscosity of a value between 1.1 and 1.5 10 -6 m 2 s -1 at 20 ° C.
- the basic composition which contains the fuel according to the invention comprises at least one petroleum fraction having a distillation range comprised substantially between 240 ° C and 380 ° C.
- Such an oil cut preferably consists of FOD or equivalent of the light gas oil type of catalytic cracking (or "LCO" in English).
- the volume ratio between the monoaromatic compounds and the diaromatic compounds of the basic composition, which the fuel according to the invention contains has a value chosen between 2 and 6.5, and is, preferably around 3.5.
- This volume content of mono- and diaromatic compounds is measured by the Fisher method, well known to those skilled in the art.
- the monoaromatic compounds and the diaromatic compounds which it comprises are present in a volume ratio of a chosen value, preferably between 8 and 12.
- the basic composition contained in the fuel according to the invention comprises 5 to 50% and, preferably, 20 to 40% by volume of gasoline of aromatic type.
- the hydrocarbon possibly present in the fuel according to the invention is a product meeting the intersyndical specifications of a fuel oil of the domestic fuel oil type, hereinafter "FOD", or an equivalent.
- composition which contains the fuel according to the invention comprises up to 3 volume parts of FOD or an equivalent.
- the invention finally relates to the use of the fuel according to the invention in boilers and / or furnaces of the collective and / or industrial type.
- compositions referenced 1 to 7 containing rapeseed oil (“HC”), heavy gasoline of catalytic cracking (“ELCC”) and heating oil (“FOD”) .
- HC rapeseed oil
- ELCC heavy gasoline of catalytic cracking
- FOD heating oil
- rapeseed oil (HC) used here is a refined oil, marketed under the name LUBRIROB by the company ROBBE in Compiègne. Its pour point is less than -21 ° C and its viscosity at 20 ° C is 75.10 -6 m 2 / s (75 mm 2 / s).
- the heavy gasoline of catalytic cracking used here is a 140 ° C-203 ° C cut coming from a catalytic cracking unit comprising 65% of aromatics, 12% of olefins and 23% of saturated molecules.
- this ratio is preferably chosen to be less than 1.
- the fuel according to the invention comprising rapeseed oil perfectly meets the inter-union specifications adopted for use on a FOD boiler, in particular cloud and flow points. , as well as flash point, and constitutes a "green fuel” substitute for the conventional fuel of the state of the art.
Landscapes
- Chemical & Material Sciences (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Liquid Carbonaceous Fuels (AREA)
- Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Applications Claiming Priority (2)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| FR9415041 | 1994-12-14 | ||
| FR9415041A FR2728267B1 (fr) | 1994-12-14 | 1994-12-14 | Nouveau combustible a base d'huile vegetale et d'une coupe petroliere riche en composes aromatiques |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0717097A1 true EP0717097A1 (de) | 1996-06-19 |
| EP0717097B1 EP0717097B1 (de) | 2000-01-19 |
Family
ID=9469793
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP95402747A Expired - Lifetime EP0717097B1 (de) | 1994-12-14 | 1995-12-06 | Auf pflanzlichem Öl und aromatenreicher Petroleumfraktion basierter Brennstoff |
Country Status (6)
| Country | Link |
|---|---|
| EP (1) | EP0717097B1 (de) |
| AT (1) | ATE188987T1 (de) |
| DE (1) | DE69514631T2 (de) |
| DK (1) | DK0717097T3 (de) |
| ES (1) | ES2143607T3 (de) |
| FR (1) | FR2728267B1 (de) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0816476A1 (de) * | 1996-06-19 | 1998-01-07 | Total Raffinage Distribution S.A. | Auf pflanzlichen Ölen basierter Heizkesselbrennstoff mit niedrigem Schwefelgehalt |
| EP2333032B1 (de) | 2009-12-09 | 2018-07-25 | ENI S.p.A. | Herstellung einer kohlenwasserstoffzusammensetzung verwendbar als kraftstoff oder brennstoff |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE20105611U1 (de) | 2000-03-29 | 2001-10-18 | Noack, Detlef, 04916 Herzberg | Heizungsanlage |
| ES2207415B1 (es) * | 2002-11-13 | 2005-10-01 | Angel L. Samper Montes | Biocombustible versatil utilizable en cualquier tipo de motor de combustion interna o quemador convencional. |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2292033A1 (fr) * | 1974-11-22 | 1976-06-18 | Puget Marcel | Nouveau carburant et procede pour sa preparation |
| DE4116905C1 (de) * | 1991-05-23 | 1992-08-13 | Tessol Kraftstoffe, Mineraloele Und Tankanlagen Gmbh, 7000 Stuttgart, De | |
| DE4333418C1 (de) * | 1993-09-30 | 1994-10-13 | Tessol Kraftstoffe Mineraloele | Treibstoffgemisch |
-
1994
- 1994-12-14 FR FR9415041A patent/FR2728267B1/fr not_active Expired - Fee Related
-
1995
- 1995-12-06 EP EP95402747A patent/EP0717097B1/de not_active Expired - Lifetime
- 1995-12-06 DE DE69514631T patent/DE69514631T2/de not_active Expired - Lifetime
- 1995-12-06 ES ES95402747T patent/ES2143607T3/es not_active Expired - Lifetime
- 1995-12-06 DK DK95402747T patent/DK0717097T3/da active
- 1995-12-06 AT AT95402747T patent/ATE188987T1/de not_active IP Right Cessation
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR2292033A1 (fr) * | 1974-11-22 | 1976-06-18 | Puget Marcel | Nouveau carburant et procede pour sa preparation |
| DE4116905C1 (de) * | 1991-05-23 | 1992-08-13 | Tessol Kraftstoffe, Mineraloele Und Tankanlagen Gmbh, 7000 Stuttgart, De | |
| DE4333418C1 (de) * | 1993-09-30 | 1994-10-13 | Tessol Kraftstoffe Mineraloele | Treibstoffgemisch |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0816476A1 (de) * | 1996-06-19 | 1998-01-07 | Total Raffinage Distribution S.A. | Auf pflanzlichen Ölen basierter Heizkesselbrennstoff mit niedrigem Schwefelgehalt |
| EP2333032B1 (de) | 2009-12-09 | 2018-07-25 | ENI S.p.A. | Herstellung einer kohlenwasserstoffzusammensetzung verwendbar als kraftstoff oder brennstoff |
Also Published As
| Publication number | Publication date |
|---|---|
| ES2143607T3 (es) | 2000-05-16 |
| ATE188987T1 (de) | 2000-02-15 |
| FR2728267A1 (fr) | 1996-06-21 |
| FR2728267B1 (fr) | 1997-03-14 |
| DE69514631D1 (de) | 2000-02-24 |
| DK0717097T3 (da) | 2000-06-26 |
| EP0717097B1 (de) | 2000-01-19 |
| DE69514631T2 (de) | 2000-08-10 |
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Free format text: FUEL BASED ON VEGETABLE OIL AND AN AROMATIC-RICH FRACTION |
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