EP0377807B1 - Highly alkaline phosphate-free liquid detergent - Google Patents
Highly alkaline phosphate-free liquid detergent Download PDFInfo
- Publication number
- EP0377807B1 EP0377807B1 EP89121135A EP89121135A EP0377807B1 EP 0377807 B1 EP0377807 B1 EP 0377807B1 EP 89121135 A EP89121135 A EP 89121135A EP 89121135 A EP89121135 A EP 89121135A EP 0377807 B1 EP0377807 B1 EP 0377807B1
- Authority
- EP
- European Patent Office
- Prior art keywords
- weight
- detergent
- component
- alkyl
- sodium
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Lifetime
Links
- 239000003599 detergent Substances 0.000 title claims description 22
- 239000007788 liquid Substances 0.000 title claims description 8
- -1 ether alcohols Chemical class 0.000 claims description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 claims description 19
- 229930182478 glucoside Natural products 0.000 claims description 17
- 239000000203 mixture Substances 0.000 claims description 16
- 125000000217 alkyl group Chemical group 0.000 claims description 10
- 150000001298 alcohols Chemical class 0.000 claims description 9
- 239000002736 nonionic surfactant Substances 0.000 claims description 9
- 159000000000 sodium salts Chemical class 0.000 claims description 9
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 8
- 239000004115 Sodium Silicate Substances 0.000 claims description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N ethylene glycol Natural products OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 claims description 6
- 229910052911 sodium silicate Inorganic materials 0.000 claims description 6
- 239000012141 concentrate Substances 0.000 claims description 5
- 239000000470 constituent Substances 0.000 claims description 5
- 239000003752 hydrotrope Substances 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 claims description 4
- ABLZXFCXXLZCGV-UHFFFAOYSA-N Phosphorous acid Chemical compound OP(O)=O ABLZXFCXXLZCGV-UHFFFAOYSA-N 0.000 claims description 4
- 229910052681 coesite Inorganic materials 0.000 claims description 4
- 229910052906 cristobalite Inorganic materials 0.000 claims description 4
- 229940090960 diethylenetriamine pentamethylene phosphonic acid Drugs 0.000 claims description 4
- DUYCTCQXNHFCSJ-UHFFFAOYSA-N dtpmp Chemical compound OP(=O)(O)CN(CP(O)(O)=O)CCN(CP(O)(=O)O)CCN(CP(O)(O)=O)CP(O)(O)=O DUYCTCQXNHFCSJ-UHFFFAOYSA-N 0.000 claims description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 claims description 4
- 239000000377 silicon dioxide Substances 0.000 claims description 4
- 235000012239 silicon dioxide Nutrition 0.000 claims description 4
- 229910052682 stishovite Inorganic materials 0.000 claims description 4
- 229910052905 tridymite Inorganic materials 0.000 claims description 4
- DBVJJBKOTRCVKF-UHFFFAOYSA-N Etidronic acid Chemical compound OP(=O)(O)C(O)(C)P(O)(O)=O DBVJJBKOTRCVKF-UHFFFAOYSA-N 0.000 claims description 3
- 150000002170 ethers Chemical class 0.000 claims description 3
- 230000003287 optical effect Effects 0.000 claims description 3
- 229920000151 polyglycol Polymers 0.000 claims description 3
- 239000010695 polyglycol Substances 0.000 claims description 3
- DZCAZXAJPZCSCU-UHFFFAOYSA-K sodium nitrilotriacetate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CC([O-])=O DZCAZXAJPZCSCU-UHFFFAOYSA-K 0.000 claims description 2
- 229910019142 PO4 Inorganic materials 0.000 claims 1
- 125000002791 glucosyl group Chemical group C1([C@H](O)[C@@H](O)[C@H](O)[C@H](O1)CO)* 0.000 claims 1
- 239000004615 ingredient Substances 0.000 claims 1
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims 1
- 239000010452 phosphate Substances 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 description 8
- 239000004094 surface-active agent Substances 0.000 description 8
- WQZGKKKJIJFFOK-GASJEMHNSA-N Glucose Natural products OC[C@H]1OC(O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-GASJEMHNSA-N 0.000 description 7
- 239000008103 glucose Substances 0.000 description 7
- 150000003839 salts Chemical class 0.000 description 7
- 229920000742 Cotton Polymers 0.000 description 6
- 150000002191 fatty alcohols Chemical class 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 235000008504 concentrate Nutrition 0.000 description 4
- 239000003925 fat Substances 0.000 description 4
- 229940120146 EDTMP Drugs 0.000 description 3
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- 239000004435 Oxo alcohol Substances 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- YDONNITUKPKTIG-UHFFFAOYSA-N [Nitrilotris(methylene)]trisphosphonic acid Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CP(O)(O)=O YDONNITUKPKTIG-UHFFFAOYSA-N 0.000 description 3
- 125000004432 carbon atom Chemical group C* 0.000 description 3
- NFDRPXJGHKJRLJ-UHFFFAOYSA-N edtmp Chemical compound OP(O)(=O)CN(CP(O)(O)=O)CCN(CP(O)(O)=O)CP(O)(O)=O NFDRPXJGHKJRLJ-UHFFFAOYSA-N 0.000 description 3
- MGFYIUFZLHCRTH-UHFFFAOYSA-N nitrilotriacetic acid Chemical compound OC(=O)CN(CC(O)=O)CC(O)=O MGFYIUFZLHCRTH-UHFFFAOYSA-N 0.000 description 3
- HLZKNKRTKFSKGZ-UHFFFAOYSA-N tetradecan-1-ol Chemical compound CCCCCCCCCCCCCCO HLZKNKRTKFSKGZ-UHFFFAOYSA-N 0.000 description 3
- 235000013162 Cocos nucifera Nutrition 0.000 description 2
- 244000060011 Cocos nucifera Species 0.000 description 2
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 2
- FAPWRFPIFSIZLT-UHFFFAOYSA-M Sodium chloride Chemical compound [Na+].[Cl-] FAPWRFPIFSIZLT-UHFFFAOYSA-M 0.000 description 2
- 229920002472 Starch Polymers 0.000 description 2
- 238000006359 acetalization reaction Methods 0.000 description 2
- 230000002378 acidificating effect Effects 0.000 description 2
- 239000003513 alkali Substances 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 238000004140 cleaning Methods 0.000 description 2
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000003438 dodecyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 2
- 125000001033 ether group Chemical group 0.000 description 2
- 239000004744 fabric Substances 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000004519 grease Substances 0.000 description 2
- 239000008267 milk Substances 0.000 description 2
- 230000007935 neutral effect Effects 0.000 description 2
- 125000002347 octyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 238000006384 oligomerization reaction Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 235000019353 potassium silicate Nutrition 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000002904 solvent Substances 0.000 description 2
- 239000008107 starch Substances 0.000 description 2
- 235000019698 starch Nutrition 0.000 description 2
- 239000011550 stock solution Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- XFRVVPUIAFSTFO-UHFFFAOYSA-N 1-Tridecanol Chemical compound CCCCCCCCCCCCCO XFRVVPUIAFSTFO-UHFFFAOYSA-N 0.000 description 1
- LBLYYCQCTBFVLH-UHFFFAOYSA-M 2-methylbenzenesulfonate Chemical compound CC1=CC=CC=C1S([O-])(=O)=O LBLYYCQCTBFVLH-UHFFFAOYSA-M 0.000 description 1
- YMRHEBVRLZFPPU-UHFFFAOYSA-N 2-phenylethenyl 1,2,2-triphenylethenesulfonate Chemical class C1(=CC=CC=C1)C(=C(S(=O)(=O)OC=CC1=CC=CC=C1)C1=CC=CC=C1)C1=CC=CC=C1 YMRHEBVRLZFPPU-UHFFFAOYSA-N 0.000 description 1
- JBVOQKNLGSOPNZ-UHFFFAOYSA-N 2-propan-2-ylbenzenesulfonic acid Chemical compound CC(C)C1=CC=CC=C1S(O)(=O)=O JBVOQKNLGSOPNZ-UHFFFAOYSA-N 0.000 description 1
- ZTGKHKPZSMMHNM-UHFFFAOYSA-N 3-(2-phenylethenyl)benzene-1,2-disulfonic acid Chemical compound OS(=O)(=O)C1=CC=CC(C=CC=2C=CC=CC=2)=C1S(O)(=O)=O ZTGKHKPZSMMHNM-UHFFFAOYSA-N 0.000 description 1
- YGUMVDWOQQJBGA-UHFFFAOYSA-N 5-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-[2-[4-[(4-anilino-6-morpholin-4-yl-1,3,5-triazin-2-yl)amino]-2-sulfophenyl]ethenyl]benzenesulfonic acid Chemical compound C=1C=C(C=CC=2C(=CC(NC=3N=C(N=C(NC=4C=CC=CC=4)N=3)N3CCOCC3)=CC=2)S(O)(=O)=O)C(S(=O)(=O)O)=CC=1NC(N=C(N=1)N2CCOCC2)=NC=1NC1=CC=CC=C1 YGUMVDWOQQJBGA-UHFFFAOYSA-N 0.000 description 1
- SNRUBQQJIBEYMU-UHFFFAOYSA-N Dodecane Natural products CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 1
- 102000004190 Enzymes Human genes 0.000 description 1
- 108090000790 Enzymes Proteins 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- 244000299461 Theobroma cacao Species 0.000 description 1
- 235000009470 Theobroma cacao Nutrition 0.000 description 1
- ZZXDRXVIRVJQBT-UHFFFAOYSA-M Xylenesulfonate Chemical compound CC1=CC=CC(S([O-])(=O)=O)=C1C ZZXDRXVIRVJQBT-UHFFFAOYSA-M 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 229910052910 alkali metal silicate Inorganic materials 0.000 description 1
- 150000001346 alkyl aryl ethers Chemical class 0.000 description 1
- 239000003945 anionic surfactant Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- WQZGKKKJIJFFOK-VFUOTHLCSA-N beta-D-glucose Chemical compound OC[C@H]1O[C@@H](O)[C@H](O)[C@@H](O)[C@@H]1O WQZGKKKJIJFFOK-VFUOTHLCSA-N 0.000 description 1
- 239000008280 blood Substances 0.000 description 1
- 210000004369 blood Anatomy 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 229940071118 cumenesulfonate Drugs 0.000 description 1
- 239000007857 degradation product Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 1
- 150000002009 diols Chemical class 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 239000003205 fragrance Substances 0.000 description 1
- 150000008131 glucosides Chemical class 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 235000014666 liquid concentrate Nutrition 0.000 description 1
- 239000012263 liquid product Substances 0.000 description 1
- 230000005923 long-lasting effect Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 235000013336 milk Nutrition 0.000 description 1
- 210000004080 milk Anatomy 0.000 description 1
- 229940043348 myristyl alcohol Drugs 0.000 description 1
- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 239000012188 paraffin wax Substances 0.000 description 1
- UEZVMMHDMIWARA-UHFFFAOYSA-M phosphonate Chemical compound [O-]P(=O)=O UEZVMMHDMIWARA-UHFFFAOYSA-M 0.000 description 1
- 150000003009 phosphonic acids Chemical class 0.000 description 1
- 239000000047 product Substances 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- 238000005204 segregation Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000000344 soap Substances 0.000 description 1
- 239000011780 sodium chloride Substances 0.000 description 1
- 235000019795 sodium metasilicate Nutrition 0.000 description 1
- 229910052938 sodium sulfate Inorganic materials 0.000 description 1
- 235000011152 sodium sulphate Nutrition 0.000 description 1
- 238000001308 synthesis method Methods 0.000 description 1
- 239000003760 tallow Substances 0.000 description 1
- 239000004753 textile Substances 0.000 description 1
- 229940087291 tridecyl alcohol Drugs 0.000 description 1
- JSPLKZUTYZBBKA-UHFFFAOYSA-N trioxidane Chemical compound OOO JSPLKZUTYZBBKA-UHFFFAOYSA-N 0.000 description 1
- HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
- 125000002948 undecyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 229940071104 xylenesulfonate Drugs 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/26—Organic compounds containing nitrogen
- C11D3/33—Amino carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/662—Carbohydrates or derivatives
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/825—Mixtures of compounds all of which are non-ionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/66—Non-ionic compounds
- C11D1/72—Ethers of polyoxyalkylene glycols
Definitions
- Textile detergents to be used in commercial laundries differ considerably in their composition from those which are usually used in the household.
- softened, ie Ca and Mg-free water is used regularly in commercial companies.
- the commercially used agents often contain highly alkaline builder salts and alkalis, such as sodium metasilicate and sodium hydroxide, which can be handled safely by a person skilled in the art, but are unsuitable in the household for safety reasons.
- These highly alkaline constituents can in turn interact with the surfactants usually present, in particular the nonionics from the class of the alkyl polyglycol ethers, and more or less decompose them if they are stored together for a long time.
- surfactants which are made from natural, i.e. renewable raw materials are available and are characterized by their complete and rapid biodegradability in wastewater.
- Highly alkaline cleaner concentrates for the industrial cleaning of metallic surfaces were known from EP-A-282 863. These agents contain 80 to 99.7 wt .-% of an aqueous solution of a builder mixture of alkali metal silicates and alkali metal hydroxides and 0.3 to 20 wt .-% of a surfactant combination of anionic surfactants, alkyl glucosides and other nonionic surfactants, with amounts of 0.1 to 10% by weight of alkyl glucosides and 0.1 to 5% by weight of nonionic surfactants in combination with 0.1 to 5% by weight of fatty acids or soaps are preferred.
- EP-A-202 638 describes liquid cleaning agents for strongly alkaline cleaning formulations. These surfactant concentrates, which contain nonionic surfactants and alkyl glucosides, but no alkaline builder substances, are only mixed with alkaline builder substances during practical use.
- WO-A-87/06949 further describes a liquid detergent which contains alkyl glucosides and builder substances which have a particular solubility. The solubility of relatively poorly soluble builder substances is supported by the use of alkyl glucosides.
- R is preferably a C8 ⁇ 12 alkyl radical, in particular a C8 ⁇ 10 alkyl radical.
- the alkyl glucosides can still contain small amounts of free fatty alcohol and glucose in their production. Those alkyl glucosides are preferably used whose content of fatty alcohols is less than 5% by weight, in particular less than 2% by weight (based on alkyl glucoside).
- the agents can optionally also contain nonionic surfactants of the ethoxylated fatty alcohol and oxo alcohol type with 12 to 18 carbon atoms and 5 to 10 ethylene glycol ether groups (EO).
- EO ethylene glycol ether groups
- Suitable are e.g. Ethoxylates derived from coconut, tallow or palm kernel fatty alcohols with an HLB value of more than 12, for example from 13 to 18, and corresponding ethoxylates from oxo alcohols with 12 to 16 carbon atoms and 6 to 8 EO groups.
- the builder component consists of sodium hydroxide (component B1), sodium silicate (component B2) and sequestering polyanionic salts derived from nitrilotriacetic acid (NTA) and possibly phosphonic acids (components B3 and B4).
- the Na2O: SiO2 ratio can be 1: 1 (metasilicate) to 1: 3.4 (water glass).
- metasilicate is preferably used in agents with a low proportion of sodium hydroxide, while in agents with a higher sodium hydroxide content the sodium silicate can consist predominantly or entirely of water glass.
- the NTA is available as a trisodium salt and is also used in this form of quantity calculation. In particular, its proportion is 5 to 10% by weight.
- the sodium salt of 1-hydroxyethane-1,1-diphosphonic acid is primarily suitable as the phosphonate.
- the quantity calculation is based on the tetrasodium salt.
- the sodium salts of aminotrimethylenephosphonic acid (ATMP), ethylenediaminetetramethylenephosphonic acid (EDTMP), diethylenetriaminepentamethylenephosphonic acid (DTPMP) and their higher homologs are also usable. unexplained function in wastewater less preferred.
- Your quantity calculation is based on neutral reacting sodium salts (Na3 salt with ATMP, Na5 salt with EDTMP, Na6 salt with DTPMP).
- the sum of components B3 + B4 is 3 to 12% by weight, preferably 6 to 11% by weight.
- the detergents can also contain conventional detergent constituents which do not act as surfactants and builders. These include optical brighteners in proportions of up to 1% by weight, preferably 0.05 to 0.3% by weight. Examples of these are derivatives of bis (triazinylamino) stilbene disulfonic acid, for example the sodium salt of 4,4'-bis (2-anilino-4-morpholino-1,3,5-triazin-6-yl-amino) -stilbene-2,2'-disulfonic acid and the chlorinated diphenyldistyrylsulfonic acids.
- optical brighteners in proportions of up to 1% by weight, preferably 0.05 to 0.3% by weight. Examples of these are derivatives of bis (triazinylamino) stilbene disulfonic acid, for example the sodium salt of 4,4'-bis (2-anilino-4-morpholino-1,3,5-triazin-6-yl-amino) -stilbene-2,2'-disulfonic acid and the
- hydrotropes are e.g. Toluene sulfonate, xylene sulfonate and cumene sulfonate, each in the form of the sodium salts.
- Usable solvents are, for example, ethanol, propanol, isopropanol and ether alcohols, such as diglycol and C1-C3 monoalkyl ethers of C2-C4 diols.
- the hydrotropes can be present in proportions up to 6% by weight, the alcohols or ether alcohols in proportions up to 10% by weight.
- the agents can also contain neutral salts, such as sodium sulfate and sodium chloride, as minor substances in the raw materials used. The difference of up to 100% by weight is water.
- the agents are long-lasting, pourable liquids that are suitable for automatic dosing as well as for the preparation of stock solutions (base liquors).
- the concentrates are still liquid down to temperatures of -10 ° C and are resistant to segregation.
- Their application concentration is generally 2 to 10, preferably 3 to 7 g / l.
- the amount of laundry was 7.5 kg, the water hardness 0 ° dH, normal program (without prewash), detergent concentration 4 g / l, 5 minutes at 40 ° C and 15 minutes at 90 ° C, three rinsing, low foaming.
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Molecular Biology (AREA)
- Detergent Compositions (AREA)
Description
In gewerblichen Wäschereien anzuwendende Textilwaschmittel unterscheiden sich in ihrer ihrer Zusammensetzung erheblich von solchen, die üblicherweise im Haushalt verwendet werden. Einerseits wird in gewerblichen Betrieben regelmäßig mit enthärtetem, d.h. Ca- und Mg-freiem Wasser gearbeitet. Zum anderen enthalten die gewerblich angewendeten Mittel vielfach hochalkalische Buildersalze und Alkalien, wie Natriummetasilikat und Natriumhydroxid, die zwar vom Fachmann gefahrlos gehandhabt werden können, im Haushalt jedoch aus Sicherheitsgründen unangebracht sind. Diese hochalkalischen Bestandteile können ihrerseits mit den üblicherweise anwesenden Tensiden, insbesondere den Nonionics aus der Klasse der Alkylpolyglykolether, in Wechselwirkung treten und sie bei längerer gemeinsamer Lagerung mehr oder weniger zersetzen. Diese Probleme existieren insbesondere bei flüssigen Konzentraten und Produkten, die zum Ansetzen konzentrierter Stammlaugen (Stock-solutions) bestimmt sind und bei denen mangels einer räumlich Trennung von Tensid- und Alakalikomponente der zersetzende Einfluß besonders intensiv ist. Hochalkalische Flüssigprodukte und Stammlaugen haben vor pulverförmigen, gleichartig zusammengesetzten Mitteln den Vorzug, daß sie staubfrei und insbesondere automatisch dosiert werden können und somit keine Bedienungsprobleme aufwerfen.Textile detergents to be used in commercial laundries differ considerably in their composition from those which are usually used in the household. On the one hand, softened, ie Ca and Mg-free water is used regularly in commercial companies. On the other hand, the commercially used agents often contain highly alkaline builder salts and alkalis, such as sodium metasilicate and sodium hydroxide, which can be handled safely by a person skilled in the art, but are unsuitable in the household for safety reasons. These highly alkaline constituents can in turn interact with the surfactants usually present, in particular the nonionics from the class of the alkyl polyglycol ethers, and more or less decompose them if they are stored together for a long time. These problems exist in particular in the case of liquid concentrates and products which are intended for the preparation of concentrated stock liquors (stock solutions) and in which, due to the lack of a spatial separation of the surfactant and alkali components, the decomposing influence is particularly intense. Highly alkaline liquid products and base liquors have the advantage over powdery, similar compositions that they can be dosed dust-free and in particular automatically and therefore do not pose any operating problems.
Ein weiterer Aspekt ist eine möglichst weitgehende Verwendung von Tensiden, die aus natürlichen, d.h. nachwachsenden Rohstoffen erhältlich sind und sich durch eine vollständige und schnelle biologische Abbaufähigkeit im Abwasser auszeichnen.Another aspect is the greatest possible use of surfactants, which are made from natural, i.e. renewable raw materials are available and are characterized by their complete and rapid biodegradability in wastewater.
Weiterhin sollen derartige Mittel im Hauptwaschgang und während des Nachspülens keine störende Schaummengen entwickeln. Da übliche Entschäumer, wie Polysiloxane und Paraffinkohlenwasserstoffe beim Dispergieren in Flüssigwaschmitteln Wirkungsverluste erleiden bzw. im Falle der Polysiloxane durch Alkali zersetzt werden, muß die Tensidkomponente von sich aus schwach schäumend sein.Furthermore, such agents should not develop any troublesome amounts of foam in the main wash and during the rinsing. Since conventional defoamers, such as polysiloxanes and paraffin hydrocarbons, lose their effectiveness when dispersed in liquid detergents or, in the case of the polysiloxanes, are decomposed by alkali, the surfactant component must be inherently low-foaming.
Aus der EP-A-282 863 waren hochalkalische Reinigerkonzentrate für die industrielle Reinigung von metallischen Oberflächen bekannt. Diese Mittel enthalten 80 bis 99,7 Gew.-% einer wäßrigen Lösung eines Buildergemisches von Alkalimetallsilikaten und Alkalimetallhydroxiden und 0,3 bis 20 Gew.-% einer Tensidkombination aus anionischen Tensiden, Alkylglucosiden und anderen nichtionischen Tensiden, wobei Mengen von 0,1 bis 10 Gew.-% Alkylglucosiden und 0,1 bis 5 Gew.-% nichtionischen Tensiden in Kombination mit 0,1 bis 5 Gew.-% Fettsäuren bzw. Seifen bevorzugt sind. Zusätzliche Builder wie Nitrilotriessigsäure und Phosphonate können in Mengen von 0,1 bis 10 Gew.-% zugesetzt werden. EP-A-202 638 beschreibt flüssige Reinigungsmittel für stark alkalische Reinigungsformulierungen. Diese Tensidkonzentrate, die nichtionische Tenside und Alkylglucoside, aber keine alkalischen Buildersubstanzen enthalten, werden erst bei der praktischen Anwendung mit alkalischen Buildersubstanzen versetzt. WO-A-87/06949 beschreibt weiterhin ein Flüssigwaschmittel, das Alkylglucoside und Buildersubstanzen enthält, die eine spezielle Löslichkeit aufweisen. Dabei wird die Löslichkeit relativ schwerlöslicher Buildersubstanzen durch den Einsatz von Alkylglucosiden unterstützt.Highly alkaline cleaner concentrates for the industrial cleaning of metallic surfaces were known from EP-A-282 863. These agents contain 80 to 99.7 wt .-% of an aqueous solution of a builder mixture of alkali metal silicates and alkali metal hydroxides and 0.3 to 20 wt .-% of a surfactant combination of anionic surfactants, alkyl glucosides and other nonionic surfactants, with amounts of 0.1 to 10% by weight of alkyl glucosides and 0.1 to 5% by weight of nonionic surfactants in combination with 0.1 to 5% by weight of fatty acids or soaps are preferred. Additional builders such as nitrilotriacetic acid and phosphonates can be added in amounts of 0.1 to 10% by weight. EP-A-202 638 describes liquid cleaning agents for strongly alkaline cleaning formulations. These surfactant concentrates, which contain nonionic surfactants and alkyl glucosides, but no alkaline builder substances, are only mixed with alkaline builder substances during practical use. WO-A-87/06949 further describes a liquid detergent which contains alkyl glucosides and builder substances which have a particular solubility. The solubility of relatively poorly soluble builder substances is supported by the use of alkyl glucosides.
Gegenstand der Erfindung, mit der die oben erwähnten Probleme gelöst werden, ist ein flüssiges, wäßriges, phosphatfreies Waschmittelkonzentrat, enthaltend 5 bis 20 Gew.-% einer nichtionischen Tensidkomponente (A), 15 bis 40 Gew.-% einer Builderkomponente (B), 0 bis 1 Gew.-% optische Aufheller, 0 bis 6 Gew.-% Hydrotrope, 0 bis 10 Gew.-% mit Wasser mischbare Alkohole bzw. Etheralkohole und sonstige fakultative nicht tensidische und nicht builderhaltige Waschmittelbestandteile sowie Wasser (Differenz bis 100 Gew.-%), wobei die Komponenten, bezogen auf das Waschmittel wie folgt zusammengesetzt sind:
- A1) 4 bis 20 Gew.-% eines Alkylglucosids der Formel I
R-O-Gx (I)
mit R = C₈-C₁₄-Alkylrest, G = Glucoserest und x = Zahlen von 1,2 bis 5, - A2) 0 bis 2 Gew.-% mindestens eines nichtionischen Tensids aus der Klasse der Alkylpolyglykolether mit C₁₂-C₁₈-Alkylgruppen und 5 bis 10 Ethylenglykolethergruppen,
- B1) 4 bis 20 Gew.-% Natriumhydroxid,
- B2) 0,5 is 12 Gew.-% Natriumsilikat der Zusammensetzung Na₂O : SiO₂ = 1:1 bis 1:3,4
- B3) 2 bis 12 Gew.-% Natrium-nitrilotriacetat,
- B4) 0 bis 3,5 Gew.-% Natriumsalz mindestens einer Phosphonsäure, mit der Maßgabe, daß der Anteil der Bestandteile (B3 + B4) 3 bis 12 Gew.-% beträgt.
- A1) 4 to 20% by weight of an alkyl glucoside of the formula I.
ROG x (I)
with R = C₈-C₁₄ alkyl radical, G = glucose radical and x = numbers from 1.2 to 5, - A2) 0 to 2% by weight of at least one nonionic surfactant from the class of the alkyl polyglycol ethers with C₁₂-C₁₈ alkyl groups and 5 to 10 ethylene glycol ether groups,
- B1) 4 to 20% by weight of sodium hydroxide,
- B2) 0.5 to 12% by weight sodium silicate of the composition Na₂O: SiO₂ = 1: 1 to 1: 3.4
- B3) 2 to 12% by weight of sodium nitrilotriacetate,
- B4) 0 to 3.5% by weight of sodium salt of at least one phosphonic acid, with the proviso that the proportion of constituents (B3 + B4) is 3 to 12% by weight.
Vorzugsweise beträgt der Gehalt der Mittel an den Einzelkomponenten
- A1) 5 bis 12 Gew.-%
- A2) 0,5 bis 1,5 Gew.-%
- B1) 6 bis 15 Gew.-%
- B2) 0,5 bis 3 Gew.%
- B3) 3 bis 10 Gew.-%
- B4) 0,2 bis 2 Gew.
- A1) 5 to 12% by weight
- A2) 0.5 to 1.5% by weight
- B1) 6 to 15% by weight
- B2) 0.5 to 3% by weight
- B3) 3 to 10% by weight
- B4) 0.2 to 2 wt.
Beispiele hierfür sind Octyl-, Nonyl-, Decyl-, Undecyl-, Dodecyl-und Tridecylalkohol sowie deren Gemische untereinander. Vozugsweise steht R für einen C₈₋₁₂-Alkylrest, insbesondere für einen C₈₋₁₀-Alkylrest. Bei der Umsetzung der Glucose oder glucosehaltigen Stärkeabbauprodukte mit den Alkoholen kommt es in Gegenwart saurer Acetalisierungs-Katalysatoren zu einer teilweisen Oligomerisierung der Glucose, wobei sich Gemische aus Alkylmonoglucosiden und Alkyloligogucosiden bilden. Der Parameter x gemäß Formel I bezeichnet somit einen mittleren Oligomerisierungsgrad. Dieser soll vorzugsweise 1,3 bis 3 betragen. Derartige Gemische sind gemeint, wenn im Zusammenhang mit der Erfindung allgemein von Alkylglucosiden die Rede ist.Examples include octyl, nonyl, decyl, undecyl, dodecyl and tridecyl alcohol and their mixtures with one another. R is preferably a C₈₋₁₂ alkyl radical, in particular a C₈₋₁₀ alkyl radical. When the glucose or starch degradation products containing glucose are reacted with the alcohols, partial glucose oligomerization occurs in the presence of acidic acetalization catalysts, with mixtures of alkyl monoglucosides and alkyl oligogucosides being formed. The parameter x according to formula I thus denotes an average degree of oligomerization. This should preferably be 1.3 to 3. Such mixtures are meant when the context of the invention generally refers to alkyl glucosides.
Von ihrer Herstellung her können die Alkylglucoside noch geringe Mengen an freiem Fettalkohol und Glucose enthalten. Vorzugsweise werden solche Alkylglucoside eingesetzt, deren Gehalt an Fettalkoholen weniger als 5 Gew.-%, insbesondere weniger als 2 Gew.-% (bezogen auf Alkylglucosid) beträgt.The alkyl glucosides can still contain small amounts of free fatty alcohol and glucose in their production. Those alkyl glucosides are preferably used whose content of fatty alcohols is less than 5% by weight, in particular less than 2% by weight (based on alkyl glucoside).
Fakultativ können die Mittel außer den Alkylglucosiden als Komponente (A2) noch nichtionische Tenside vom Typ der ethoxylierten Fettalkohole und Oxoalkohole mit 12 bis 18 C-Atomen und 5 bis 10 Ethylenglykolethergruppen (EO) enthalten. Geeignet sind z.B. von Kokos-, Talg- oder Palmkernfettalkoholen abgeleitete Ethoxylate mit einem HLB-Wert von mehr als 12, beispielsweise von 13 bis 18, sowie entsprechende Ethoxylate von Oxoalkoholen mit 12 bis 16 C-Atomen und 6 bis 8 EO-Gruppen.In addition to the alkyl glucosides as component (A2), the agents can optionally also contain nonionic surfactants of the ethoxylated fatty alcohol and oxo alcohol type with 12 to 18 carbon atoms and 5 to 10 ethylene glycol ether groups (EO). Suitable are e.g. Ethoxylates derived from coconut, tallow or palm kernel fatty alcohols with an HLB value of more than 12, for example from 13 to 18, and corresponding ethoxylates from oxo alcohols with 12 to 16 carbon atoms and 6 to 8 EO groups.
Die Builderkomponente besteht aus Natriumhydroxid (Bestandteil B1), Natriumsilikat (Bestandteil B2) und sequestrierend wirkenden polyanionischen Salzen, abgeleitet von Nitrilotriessigsäure (NTA) und ggf. Phosphonsäuren (Bestandteil B3 und B4).The builder component consists of sodium hydroxide (component B1), sodium silicate (component B2) and sequestering polyanionic salts derived from nitrilotriacetic acid (NTA) and possibly phosphonic acids (components B3 and B4).
Im Natriumsilikat kann das Na₂O : SiO₂-Verhältnis 1:1 (Metasilikat) bis 1:3,4 (Wasserglas) betragen. In Mitteln mit geringeren Anteilen an Natriumhydroxid wird im Interesse einer hohen Alkalität bevorzugt Metasilikat eingesetzt, während in Mitteln mit höheren Natriumhydroxid-Gehalten das Natriumsilikat überwiegend oder vollständig aus Wasserglas bestehen kann.In sodium silicate, the Na₂O: SiO₂ ratio can be 1: 1 (metasilicate) to 1: 3.4 (water glass). In the interest of a high alkalinity, metasilicate is preferably used in agents with a low proportion of sodium hydroxide, while in agents with a higher sodium hydroxide content the sodium silicate can consist predominantly or entirely of water glass.
Das NTA liegt als Trinatriumsalz vor und wird auch in dieser Form der Mengenberechnung zugrunde gelegt. Insbesondere beträgt sein Anteil 5 bis 10 Gew.-%.The NTA is available as a trisodium salt and is also used in this form of quantity calculation. In particular, its proportion is 5 to 10% by weight.
Als Phosphonat kommt in erster Linie das Natriumsalz der 1-Hydroxyethan-1,1-diphosphonsäure (HEDP) in Frage. Der Mengenberechnung wird das Tetranatriumsalz zugrunde gelegt. Brauchbar sind auch die Natriumsalze der Aminotrimethylenphosphonsäure (ATMP), Ethylendiamintetramethylenphosphonsäure (EDTMP), Diethylentriaminpentamethylenphosphonsäure (DTPMP) und deren höhere Homologen, jedoch ist EDTMP wegen ihrer z.Zt. ungeklärten Funktion im Abwasser weniger bevorzugt. Ihre Mengenberechnung basiert auf neutral reagierenden Natriumsalzen (Na₃-Salz bei ATMP, Na₅-Salz bei EDTMP, Na₆-Salz bei DTPMP). Die Summe der Komponenten B3 + B4 beträgt 3 bis 12 Gew.-%, vorzugsweise 6 bis 11 Gew.-%.The sodium salt of 1-hydroxyethane-1,1-diphosphonic acid (HEDP) is primarily suitable as the phosphonate. The quantity calculation is based on the tetrasodium salt. The sodium salts of aminotrimethylenephosphonic acid (ATMP), ethylenediaminetetramethylenephosphonic acid (EDTMP), diethylenetriaminepentamethylenephosphonic acid (DTPMP) and their higher homologs are also usable. unexplained function in wastewater less preferred. Your quantity calculation is based on neutral reacting sodium salts (Na₃ salt with ATMP, Na₅ salt with EDTMP, Na₆ salt with DTPMP). The sum of components B3 + B4 is 3 to 12% by weight, preferably 6 to 11% by weight.
Neben den vorgenannten Bestandteilen können die Mittel noch übliche, nicht als Tenside und Builder wirkende Waschmittelbestandteile enthalten. Hierzu zählen optische Aufheller in Anteilen bis zu 1 Gew.-%, vorzugsweise 0,05 bis 0,3 Gew.-%. Beispiele hierfür sind Derivate der Bis-(triazinylamino)-stilbendisulfonsäure, beispielsweise das Natriumsalz der 4,4'-Bis-(2-anilino-4-morpholino-1,3,5-triazin-6-yl-amino)-stilben-2,2'-disulfonsäure sowie der chlorierten Diphenyldistyryl-sulfonsäuren.In addition to the aforementioned constituents, the detergents can also contain conventional detergent constituents which do not act as surfactants and builders. These include optical brighteners in proportions of up to 1% by weight, preferably 0.05 to 0.3% by weight. Examples of these are derivatives of bis (triazinylamino) stilbene disulfonic acid, for example the sodium salt of 4,4'-bis (2-anilino-4-morpholino-1,3,5-triazin-6-yl-amino) -stilbene-2,2'-disulfonic acid and the chlorinated diphenyldistyrylsulfonic acids.
Weitere fakultative Bestandteile sind Enzyme, Duftstoffe, Farbstoffe, Hydrotrope und mit Wasser mischbare Lösungsmittel. Als Hydrotrope eignen sich z.B. Toluolsulfonat, Xylolsulfonat und Cumolsulfonat, jeweils in Form der Natriumsalze. Brauchbare Lösungsmittel sind beispielsweise Ethanol, Propanol, Isopropanol sowie Etheralkohole, wie Diglykol und C₁-C₃-Monoalkylether von C₂-C₄-Diolen. Die Hydrotrope können in Anteilen bis 6 Gew.-%, die Alkohole bzw. Etheralkohole in Anteilen bis 10 Gew.-% anwesend sein. Ferner können die Mittel Neutralsalze, wie Natriumsulfat und Natriumchlorid, als Begleitstoffe der eingesetzten Rohstoffe in untergeordneter Menge enthalten. Die Differenz bis 100 Gew.-% entfällt auf Wasser.Other optional components are enzymes, fragrances, dyes, hydrotropes and water-miscible solvents. Suitable hydrotropes are e.g. Toluene sulfonate, xylene sulfonate and cumene sulfonate, each in the form of the sodium salts. Usable solvents are, for example, ethanol, propanol, isopropanol and ether alcohols, such as diglycol and C₁-C₃ monoalkyl ethers of C₂-C₄ diols. The hydrotropes can be present in proportions up to 6% by weight, the alcohols or ether alcohols in proportions up to 10% by weight. The agents can also contain neutral salts, such as sodium sulfate and sodium chloride, as minor substances in the raw materials used. The difference of up to 100% by weight is water.
Die Mittel sind haltbare, gießbare Flüssigkeiten, die sich sowohl zur automatischen Dosierung als auch zum Ansetzen von Vorratslösungen (Stammlaugen) eignen. Die Konzentrate sind bis zu Temperaturen von -10 °C noch flüssig und gegen Entmischen beständig. Ihre Anwendungskonzentration beträgt im allgemeinen 2 bis 10, vorzugsweise 3 bis 7 g/l.The agents are long-lasting, pourable liquids that are suitable for automatic dosing as well as for the preparation of stock solutions (base liquors). The concentrates are still liquid down to temperatures of -10 ° C and are resistant to segregation. Their application concentration is generally 2 to 10, preferably 3 to 7 g / l.
Es wurden Waschmittel folgender Zusammensetzung hergestellt. Im Alkylglucosid war R ein Gemisch von C₈₋₁₀-Alkylgruppen und x = 1,8, hergestellt nach der Methode der Direktsynthese.
Eine Waschmaschine (Typ Frista (R)) wurde mit leicht verschmutzter Füllwäsche (einmal benutzte Bett- und Tischwäsche) und Testlappen mit folgenden Anschmutzungen beladen:
- A1 Staub-Wollfett auf Baumwolle,
- A2 Blut-Milch-Tusche auf Baumwolle,
- A3 Blut auf Baumwolle,
- A4 Milchkakao auf Baumwolle,
- A5 Staub-Hautfett auf veredelter Baumwolle,
- A6 Staub-Hautfett auf Mischgewebe aus veredelter Baumwolle und Polyester,
- A7 Staub-Wollfett auf Mischgewebe (wie A6).
- A1 dust-wool grease on cotton,
- A2 blood-milk ink on cotton,
- A3 blood on cotton,
- A4 milk cocoa on cotton,
- A5 dusty skin fat on refined cotton,
- A6 Dust-skin fat on mixed fabrics made from refined cotton and polyester,
- A7 Dust-wool grease on mixed fabrics (like A6).
Die Wäschemenge betrug 7,5 kg, die Wasserhärte 0 °dH, Normalprogramm (ohne Vorwäsche), Waschmittelkonzentration 4 g/l, 5 Minuten bei 40 °C und 15 Minuten bei 90 °C, dreimaliges Nachspülen, geringe Schaumentwicklung.The amount of laundry was 7.5 kg, the water hardness 0 ° dH, normal program (without prewash), detergent concentration 4 g / l, 5 minutes at 40 ° C and 15 minutes at 90 ° C, three rinsing, low foaming.
Die prozentuale Remission (gegen Weißstandard) wurde photometrisch ausgewertet. Die Zahlenwerte sind Mittelwerte aus 3 Parallelbestimmungen (Streuung 2 %). De Ergebnisse sind in der folgenden Tabelle 2 zusammengestellt. Zum Vergleich V wurde ein ähnlich zusammengesetztes Mittel des Handels (ohne Glucosid) herangezogen. Vergleichbar gute Waschergebnisse wurden auch erhalten, wenn anstelle des Alkylglucosids mit x = 1,8 solche mit x = 1,4 und x = 2,2 eingesetzt wurden.
Claims (8)
- A liquid, aqueous, non-phosphate detergent concentrate containing 5 to 20% by weight of a nonionic surfactant component (A), 15 to 40% by weight of a builder component (B), 0 to 1% by weight optical brighteners, 0 to 6% by weight hydrotropes, 0 to 10% by weight water-miscible alcohols or ether alcohols and other non-surface-active and non-builder-containing detergent ingredients and water (balance to 100% by weight), characterized in that the components have the following composition, based on the detergent:A1) 4 to 20% by weight of an alkyl glucoside corresponding to formula I
R-O-Gx (I)
where R = a C₈₋₁₄ alkyl radical, G = a glucose unit and x = a number of 1.2 to 5,A2) 0 to 2% by weight of at least one nonionic surfactant from the class of alkyl polyglycol ethers containing C₁₂₋₁₈ alkyl groups and 5 to 10 ethylene glycol ether groups,B1) 4 to 20% by weight sodium hydroxide,B2) 0.5 to 12% by weight sodium silicate having the composition Na₂O : SiO₂ = 1:1 to 1:3.4,B3) 2 to 12% by weight sodium nitrilotriacetate,B4) 0 to 3.5% by weight of the sodium salt of at least one phosphonic acid, with the proviso that the content of constituents (B3 + B4) is from 3 to 12% by weight. - A detergent as claimed in claim 1, characterized in that the individual components are present in the following quantities:A1) 5 to 12 % by weightA2) 0.5 to 1.5 % by weightB1) 6 to 15 % by weightB2) 0.5 to 3 % by weightB3) 3 to 10 % by weightB4) 0.2 to 2 % by weight
- A detergent as claimed in claim 1 or 2, characterized in that, in formula (I), R = C₈₋₁₂ alkyl radicals and x = a number of 1.3 to 3.
- A detergent as claimed in one or more of claims 1 to 3, characterized in that the nonionic surfactant of component (A2) has an HLB value of 12 to 18.
- A detergent as claimed in one or more of claims 1 to 4, characterized in that component (B4) consists of the sodium salt of 1-hydroxyethane-1,1-diphosphonic acid.
- A detergent as claimed in claim 5, characterized in that component (B4) additionally contains the sodium salt of diethylenetriamine pentamethylene phosphonic acid.
- A detergent as claimed in one or more of claims 1 to 6, characterized in that the content of component (B3) is from 5 to 10% by weight.
- A detergent as claimed in claims 5 to 7, characterized in that the sum of components (B3 + B4) is from 6 to 11% by weight.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| AT89121135T ATE101412T1 (en) | 1988-12-07 | 1989-11-15 | PHOSPHATE-FREE LIQUID DETERGENT WITH HIGH ALKALINE. |
Applications Claiming Priority (4)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| DE3841129 | 1988-12-07 | ||
| DE3841129A DE3841129A1 (en) | 1988-12-07 | 1988-12-07 | Phosphate-free, liquid detergent with high alkalinity |
| DE19893906766 DE3906766A1 (en) | 1989-03-03 | 1989-03-03 | Phosphate-free liquid detergent of high alkalinity |
| DE3906766 | 1989-03-03 |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| EP0377807A1 EP0377807A1 (en) | 1990-07-18 |
| EP0377807B1 true EP0377807B1 (en) | 1994-02-09 |
Family
ID=25874879
Family Applications (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89912958A Pending EP0447413A1 (en) | 1988-12-07 | 1989-11-15 | Phosphate-free liquid washing agent with high alkalinity |
| EP89121135A Expired - Lifetime EP0377807B1 (en) | 1988-12-07 | 1989-11-15 | Highly alkaline phosphate-free liquid detergent |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| EP89912958A Pending EP0447413A1 (en) | 1988-12-07 | 1989-11-15 | Phosphate-free liquid washing agent with high alkalinity |
Country Status (9)
| Country | Link |
|---|---|
| EP (2) | EP0447413A1 (en) |
| JP (1) | JPH04502337A (en) |
| AU (1) | AU626954B2 (en) |
| CA (1) | CA2004895A1 (en) |
| DE (1) | DE58906948D1 (en) |
| DK (1) | DK101291A (en) |
| ES (1) | ES2061894T3 (en) |
| PT (1) | PT92396A (en) |
| WO (1) | WO1990006353A1 (en) |
Families Citing this family (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE4009533A1 (en) * | 1990-03-24 | 1991-09-26 | Henkel Kgaa | LOW-EFFICIENT NON-ionic surfactant mix |
| DE4225224A1 (en) * | 1992-07-30 | 1994-02-03 | Henkel Kgaa | Process for the production of storage-stable nonionic surfactants |
| US5503754A (en) * | 1993-11-10 | 1996-04-02 | Henkel Corporation | Wet treatment of leather hides |
| US5542950A (en) * | 1994-11-10 | 1996-08-06 | Henkel Corporation | Alkyl polyglycosides in textile scour/bleach processing |
| US5525256A (en) * | 1995-02-16 | 1996-06-11 | Henkel Corporation | Industrial and institutional liquid cleaning compositions containing alkyl polyglycoside surfactants |
| FR2744132B1 (en) | 1996-01-31 | 1998-04-24 | Rhone Poulenc Chimie | BASIC SYSTEM OF A NON-IONIC SURFACTANT AND AN ALKALINE METAL SILICATE, IN THE FORM OF A DISPERSION OR PELLETS AND ITS USE IN DETERGENCE |
| US6194371B1 (en) | 1998-05-01 | 2001-02-27 | Ecolab Inc. | Stable alkaline emulsion cleaners |
| US6369021B1 (en) * | 1999-05-07 | 2002-04-09 | Ecolab Inc. | Detergent composition and method for removing soil |
| US7041177B2 (en) | 2002-08-16 | 2006-05-09 | Ecolab Inc. | High temperature rapid soil removal method |
| US20170369819A1 (en) * | 2016-06-27 | 2017-12-28 | The Procter & Gamble Company | Removal of hydrophilic body soils |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0202638A2 (en) * | 1985-05-24 | 1986-11-26 | BASF Aktiengesellschaft | Liquid cleaning concentrate for strongly alkaline cleaning formulations |
| EP0282863A2 (en) * | 1987-03-14 | 1988-09-21 | Henkel Kommanditgesellschaft auf Aktien | Liquid alkaline cleaning concentrates |
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| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US3772259A (en) | 1965-07-12 | 1973-11-13 | American Cyanamid Co | 2-vinyl-1-cycloamidinepropionamide polymers |
| US3547828A (en) | 1968-09-03 | 1970-12-15 | Rohm & Haas | Alkyl oligosaccharides and their mixtures with alkyl glucosides and alkanols |
| US3721633A (en) * | 1969-10-06 | 1973-03-20 | Atlas Chem Ind | Aqueous built liquid detergents containing alkyl glycosides |
| US3839318A (en) | 1970-09-27 | 1974-10-01 | Rohm & Haas | Process for preparation of alkyl glucosides and alkyl oligosaccharides |
| GR76286B (en) * | 1981-09-28 | 1984-08-04 | Procter & Gamble | |
| FR2540511B1 (en) * | 1983-02-04 | 1985-08-09 | Henkel France | LIQUID CLEANING COMPOSITION AND METHOD FOR CLEANING USING THE SAME |
| JPS63503389A (en) * | 1986-05-06 | 1988-12-08 | エー・イー・ステーレイ・マニフアクチユアリング・コムパニー | Liquid laundry detergent with builder containing alkyl glycoside surfactants |
-
1989
- 1989-11-15 JP JP2500169A patent/JPH04502337A/en active Pending
- 1989-11-15 AU AU46260/89A patent/AU626954B2/en not_active Ceased
- 1989-11-15 EP EP89912958A patent/EP0447413A1/en active Pending
- 1989-11-15 DE DE89121135T patent/DE58906948D1/en not_active Expired - Fee Related
- 1989-11-15 ES ES89121135T patent/ES2061894T3/en not_active Expired - Lifetime
- 1989-11-15 EP EP89121135A patent/EP0377807B1/en not_active Expired - Lifetime
- 1989-11-15 WO PCT/EP1989/001370 patent/WO1990006353A1/en not_active Application Discontinuation
- 1989-11-23 PT PT92396A patent/PT92396A/en not_active Application Discontinuation
- 1989-12-07 CA CA002004895A patent/CA2004895A1/en not_active Abandoned
-
1991
- 1991-05-28 DK DK101291A patent/DK101291A/en not_active Application Discontinuation
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0202638A2 (en) * | 1985-05-24 | 1986-11-26 | BASF Aktiengesellschaft | Liquid cleaning concentrate for strongly alkaline cleaning formulations |
| EP0282863A2 (en) * | 1987-03-14 | 1988-09-21 | Henkel Kommanditgesellschaft auf Aktien | Liquid alkaline cleaning concentrates |
Also Published As
| Publication number | Publication date |
|---|---|
| AU4626089A (en) | 1990-06-26 |
| PT92396A (en) | 1990-06-29 |
| JPH04502337A (en) | 1992-04-23 |
| AU626954B2 (en) | 1992-08-13 |
| WO1990006353A1 (en) | 1990-06-14 |
| ES2061894T3 (en) | 1994-12-16 |
| DE58906948D1 (en) | 1994-03-24 |
| EP0447413A1 (en) | 1991-09-25 |
| DK101291D0 (en) | 1991-05-28 |
| CA2004895A1 (en) | 1990-06-07 |
| DK101291A (en) | 1991-05-28 |
| EP0377807A1 (en) | 1990-07-18 |
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